test3.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 528, "width": 1368, "height": 1880, "file_name": "jo0014414-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [382.7, 1222.6, 232.3, 237.8], "category_id": 1}, {"id": 1, "bbox": [783.5, 1224.0, 229.5, 243.0], "category_id": 1}, {"id": 2, "bbox": [389.0, 1536.2, 221.7, 270.9], "category_id": 1}, {"id": 3, "bbox": [764.0, 249.0, 604.0, 504.1], "category_id": 1}, {"id": 4, "bbox": [527.6, 371.6, 202.0, 295.9], "category_id": 1}, {"id": 5, "bbox": [107.2, 394.7, 272.6, 208.4], "category_id": 1}, {"id": 6, "bbox": [974.2, 871.2, 324.8, 263.1], "category_id": 1}, {"id": 7, "bbox": [803.9, 1540.5, 202.2, 292.9], "category_id": 1}, {"id": 8, "bbox": [458.6, 867.7, 272.4, 266.9], "category_id": 1}, {"id": 9, "bbox": [226.4, 991.6, 215.6, 210.4], "category_id": 2}, {"id": 10, "bbox": [811.0, 1012.6, 109.6, 65.3], "category_id": 2}, {"id": 11, "bbox": [231.6, 1288.8, 94.4, 65.2], "category_id": 2}, {"id": 12, "bbox": [205.6, 1365.0, 152.2, 109.0], "category_id": 2}, {"id": 13, "bbox": [176.41, 960.33, 40.93, 60.03], "category_id": 3}, {"id": 14, "bbox": [1039.0, 1358.0, 165.0, 116.3], "category_id": 2}, {"id": 15, "bbox": [630.0, 1598.1, 132.8, 85.9], "category_id": 2}, {"id": 16, "bbox": [649.2, 1713.0, 121.9, 59.5], "category_id": 2}, {"id": 17, "bbox": [562.06, 1148.0, 58.4, 55.3], "category_id": 3}, {"id": 18, "bbox": [888.3, 1827.5, 63.7, 52.5], "category_id": 3}, {"id": 19, "bbox": [478.0, 1829.0, 76.0, 40.0], "category_id": 3}, {"id": 20, "bbox": [608.0, 1365.0, 156.0, 94.0], "category_id": 2}, {"id": 21, "bbox": [630.0, 1282.0, 105.0, 65.0], "category_id": 2}, {"id": 22, "bbox": [1017.0, 1260.0, 224.0, 87.0], "category_id": 2}, {"id": 23, "bbox": [731.0, 898.0, 243.0, 84.0], "category_id": 2}, {"id": 24, "bbox": [221.0, 869.0, 203.0, 105.0], "category_id": 2}, {"id": 25, "bbox": [210.0, 648.0, 69.0, 83.0], "category_id": 3}, {"id": 26, "bbox": [812.17, 1140.42, 100.96, 65.48], "category_id": 2}, {"id": 27, "bbox": [583.0, 681.0, 65.0, 61.0], "category_id": 3}, {"id": 28, "bbox": [1129.0, 684.0, 69.0, 69.0], "category_id": 3}, {"id": 29, "bbox": [1082.0, 1148.0, 69.0, 50.0], "category_id": 3}, {"id": 30, "bbox": [467.0, 1474.0, 65.0, 65.0], "category_id": 3}, {"id": 31, "bbox": [876.0, 1474.0, 61.0, 61.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [3]}, {"reactants": [13], "conditions": [24, 9], "products": [8]}, {"reactants": [8], "conditions": [23, 10], "products": [6]}, {"reactants": [6], "conditions": [11, 12], "products": [0]}, {"reactants": [0], "conditions": [21, 20], "products": [1]}, {"reactants": [1], "conditions": [22, 14], "products": [2]}, {"reactants": [2], "conditions": [15, 16], "products": [7]}], "corefs": [[5, 25], [4, 27], [3, 28], [8, 17], [6, 29], [0, 30], [1, 31], [2, 19], [7, 18]], "caption": "Table 1. Stereo- and Regioselectivities in the Reduction                    of Hajos Dione (1) ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [441, 518, 772, 543], "ImageBB": [424, 35, 766, 505]}, "diagram_type": "multiple"}, {"id": 291, "width": 1348, "height": 1388, "file_name": "ol401042b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [562.0, 578.0, 69.0, 56.0], "category_id": 3}, {"id": 1, "bbox": [530.0, 254.0, 73.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [133.0, 576.0, 62.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [1030.0, 250.0, 75.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [8.0, 667.0, 1340.0, 721.0], "category_id": 4}, {"id": 5, "bbox": [905.0, 0.0, 410.0, 289.0], "category_id": 1}, {"id": 6, "bbox": [165.0, 246.0, 69.0, 56.0], "category_id": 3}, {"id": 7, "bbox": [496.3, 29.9, 140.5, 220.6], "category_id": 1}, {"id": 8, "bbox": [16.0, 368.5, 387.4, 240.2], "category_id": 1}, {"id": 9, "bbox": [20.9, 40.5, 390.1, 211.5], "category_id": 1}, {"id": 10, "bbox": [517.6, 372.0, 312.8, 250.4], "category_id": 1}, {"id": 11, "bbox": [911.21, 528.0, 412.0, 119.0], "category_id": 3}, {"id": 12, "bbox": [954.9, 374.3, 249.9, 149.8], "category_id": 1}], "reactions": [{"reactants": [9, 7], "conditions": [], "products": [5]}], "corefs": [[9, 6], [7, 1], [5, 3], [8, 2], [10, 0], [12, 11]], "caption": "Table 1. Screening of Organocatalysts and Optimization of the Reaction Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 346, 404, 373], "ImageBB": [71, 384, 408, 731]}, "diagram_type": "single"}, {"id": 86, "width": 1348, "height": 760, "file_name": "ja063878k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [489.02, 33.9, 384.24, 35.54], "category_id": 2}, {"id": 1, "bbox": [535.79, 100.99, 261.23, 39.61], "category_id": 2}, {"id": 2, "bbox": [71.2, 5.43, 130.09, 152.46], "category_id": 1}, {"id": 3, "bbox": [7.16, 183.33, 1335.74, 568.27], "category_id": 4}, {"id": 4, "bbox": [257.24, 14.58, 210.4, 150.42], "category_id": 1}, {"id": 5, "bbox": [391.43, 139.62, 20.3, 27.42], "category_id": 3}, {"id": 6, "bbox": [137.28, 139.62, 38.6, 28.43], "category_id": 3}, {"id": 7, "bbox": [896.68, 5.43, 309.01, 153.47], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [0, 1], "products": [7]}], "corefs": [[2, 6], [4, 5]], "caption": "Table 1. Preliminary Screen of Vinylsilane Alkenylation", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 250, 718, 262], "ImageBB": [439, 264, 776, 454]}, "diagram_type": "single"}, {"id": 675, "width": 1348, "height": 1368, "file_name": "ol4017244-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [597.4, 15.51, 301.8, 98.9], "category_id": 2}, {"id": 1, "bbox": [901.8, 5.0, 401.8, 212.2], "category_id": 1}, {"id": 2, "bbox": [51.7, 43.8, 375.1, 165.6], "category_id": 1}, {"id": 3, "bbox": [1055.2, 215.7, 78.6, 57.0], "category_id": 3}, {"id": 4, "bbox": [3.4, 322.0, 1342.6, 1046.0], "category_id": 4}, {"id": 5, "bbox": [466.87, 211.05, 72.4, 57.6], "category_id": 3}, {"id": 6, "bbox": [176.37, 216.41, 74.48, 51.29], "category_id": 3}, {"id": 7, "bbox": [440.6, 105.2, 143.3, 60.2], "category_id": 2}], "reactions": [{"reactants": [2, 7], "conditions": [0], "products": [1]}], "corefs": [[2, 6], [7, 5], [1, 3]], "caption": "Table 1. Optimization of the Reaction Conditiona", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 702, 101], "ImageBB": [436, 112, 773, 454]}, "diagram_type": "single"}, {"id": 173, "width": 1352, "height": 2624, "file_name": "op500224x-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [505.0, 1956.0, 230.0, 127.0], "category_id": 3}, {"id": 1, "bbox": [456.0, 62.2, 186.0, 187.6], "category_id": 1}, {"id": 2, "bbox": [0.0, 3.0, 295.3, 313.0], "category_id": 1}, {"id": 3, "bbox": [997.7, 25.9, 346.7, 268.1], "category_id": 1}, {"id": 4, "bbox": [719.6, 191.0, 134.2, 64.0], "category_id": 2}, {"id": 5, "bbox": [1045.0, 709.0, 223.0, 121.0], "category_id": 3}, {"id": 6, "bbox": [741.0, 712.0, 230.0, 109.0], "category_id": 3}, {"id": 7, "bbox": [415.0, 703.0, 237.0, 127.0], "category_id": 3}, {"id": 8, "bbox": [66.0, 709.0, 234.0, 112.0], "category_id": 3}, {"id": 9, "bbox": [3.0, 2467.0, 1349.0, 137.0], "category_id": 4}, {"id": 10, "bbox": [85.0, 2352.0, 208.0, 115.0], "category_id": 3}, {"id": 11, "bbox": [514.0, 2355.0, 198.0, 118.0], "category_id": 3}, {"id": 12, "bbox": [910.0, 2358.0, 224.0, 109.0], "category_id": 3}, {"id": 13, "bbox": [898.0, 869.0, 421.0, 272.0], "category_id": 1}, {"id": 14, "bbox": [6.0, 1265.0, 415.0, 313.0], "category_id": 1}, {"id": 15, "bbox": [450.0, 1265.0, 422.0, 304.0], "category_id": 1}, {"id": 16, "bbox": [894.0, 1262.0, 425.0, 316.0], "category_id": 1}, {"id": 17, "bbox": [846.0, 1688.0, 429.0, 267.0], "category_id": 1}, {"id": 18, "bbox": [418.0, 1690.0, 406.0, 266.0], "category_id": 1}, {"id": 19, "bbox": [3.0, 1687.0, 390.0, 275.0], "category_id": 1}, {"id": 20, "bbox": [3.0, 2090.0, 374.0, 271.0], "category_id": 1}, {"id": 21, "bbox": [412.0, 2087.0, 377.0, 262.0], "category_id": 1}, {"id": 22, "bbox": [824.0, 2074.0, 425.0, 281.0], "category_id": 1}, {"id": 23, "bbox": [719.0, 105.0, 140.0, 67.0], "category_id": 2}, {"id": 24, "bbox": [1125.0, 319.0, 134.0, 58.0], "category_id": 3}, {"id": 25, "bbox": [511.0, 313.0, 134.0, 64.0], "category_id": 3}, {"id": 26, "bbox": [95.0, 322.0, 109.0, 64.0], "category_id": 3}, {"id": 27, "bbox": [102.0, 1141.0, 265.0, 108.0], "category_id": 3}, {"id": 28, "bbox": [543.0, 1147.0, 297.0, 102.0], "category_id": 3}, {"id": 29, "bbox": [987.0, 1141.0, 284.0, 111.0], "category_id": 3}, {"id": 30, "bbox": [978.0, 1562.0, 265.0, 121.0], "category_id": 3}, {"id": 31, "bbox": [539.0, 1559.0, 256.0, 119.0], "category_id": 3}, {"id": 32, "bbox": [85.0, 1566.0, 237.0, 118.0], "category_id": 3}, {"id": 33, "bbox": [69.0, 1959.0, 240.0, 131.0], "category_id": 3}, {"id": 34, "bbox": [936.0, 1962.0, 217.0, 115.0], "category_id": 3}, {"id": 35, "bbox": [709.0, 428.0, 294.0, 284.0], "category_id": 1}, {"id": 36, "bbox": [0.0, 850.0, 473.0, 300.0], "category_id": 1}, {"id": 37, "bbox": [1009.0, 431.0, 307.0, 268.0], "category_id": 1}, {"id": 38, "bbox": [479.0, 853.0, 399.0, 307.0], "category_id": 1}, {"id": 39, "bbox": [370.0, 418.0, 333.0, 285.0], "category_id": 1}, {"id": 40, "bbox": [6.0, 409.0, 361.0, 306.0], "category_id": 1}], "reactions": [{"reactants": [2, 1], "conditions": [23, 4], "products": [3]}], "corefs": [[2, 26], [1, 25], [3, 24], [40, 8], [39, 7], [35, 6], [37, 5], [36, 27], [38, 28], [13, 29], [14, 32], [15, 31], [16, 30], [19, 33], [18, 0], [17, 34], [20, 10], [21, 11], [22, 12]], "caption": "Table 8. Diels\u2212Alder cycloaddition of 1,2-dihydropyridines", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 416, 110], "ImageBB": [82, 116, 420, 772]}, "diagram_type": "single"}, {"id": 754, "width": 1348, "height": 684, "file_name": "jo990938e-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [340.0, 166.0, 31.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [1.0, 240.0, 1347.0, 444.0], "category_id": 4}, {"id": 2, "bbox": [840.0, 165.0, 124.0, 40.0], "category_id": 1}, {"id": 3, "bbox": [780.0, 7.0, 330.9, 171.5], "category_id": 1}, {"id": 4, "bbox": [243.2, 27.0, 294.8, 136.0], "category_id": 1}, {"id": 5, "bbox": [550.0, 110.0, 181.0, 86.0], "category_id": 2}, {"id": 6, "bbox": [545.0, 1.0, 188.0, 82.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [6, 5], "products": [3]}], "corefs": [[4, 0], [3, 2]], "caption": "Table 2. Additions of Allenylmetal Reagents Prepared          from Allenyl Iodide 6 to Aldehyde 3a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [447, 64, 767, 89], "ImageBB": [439, 98, 776, 269]}, "diagram_type": "single"}, {"id": 1003, "width": 1356, "height": 608, "file_name": "ja900722q-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [400.9, 294.92, 449.06, 89.5], "category_id": 3}, {"id": 1, "bbox": [0.0, 423.74, 80.04, 58.31], "category_id": 3}, {"id": 2, "bbox": [111.93, 475.95, 210.96, 86.78], "category_id": 2}, {"id": 3, "bbox": [1022.26, 0.0, 333.74, 292.89], "category_id": 1}, {"id": 4, "bbox": [403.61, 549.85, 260.48, 56.27], "category_id": 2}, {"id": 5, "bbox": [111.93, 358.65, 174.33, 86.79], "category_id": 2}, {"id": 6, "bbox": [498.58, 437.98, 150.59, 54.24], "category_id": 2}, {"id": 7, "bbox": [707.51, 96.27, 237.42, 58.99], "category_id": 2}, {"id": 8, "bbox": [339.17, 0.0, 326.28, 292.21], "category_id": 1}, {"id": 9, "bbox": [1022.26, 297.64, 256.41, 89.49], "category_id": 3}], "caption": "Scheme 10. Synthesis of (R)-QUINAP by Dynamic Thermodynamic Resolution ", "pdf": {"Page": 11, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 588, 677, 612], "ImageBB": [424, 624, 763, 776]}, "reactions": [{"reactants": [8], "conditions": [7], "products": [3]}, {"reactants": [1], "conditions": [5, 2], "products": []}, {"reactants": [8], "conditions": [6], "products": [4]}, {"reactants": [4], "conditions": [], "products": [8]}], "diagram_type": "tree"}, {"id": 813, "width": 2820, "height": 1184, "file_name": "jo402399n-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1048.0, 1073.0, 514.0, 71.7], "category_id": 2}, {"id": 1, "bbox": [1649.0, 414.0, 493.0, 346.7], "category_id": 1}, {"id": 2, "bbox": [487.0, 2.0, 383.5, 321.5], "category_id": 1}, {"id": 3, "bbox": [490.0, 410.8, 460.9, 348.2], "category_id": 1}, {"id": 4, "bbox": [1775.75, 1066.28, 106.33, 65.93], "category_id": 2}, {"id": 5, "bbox": [1738.0, 822.0, 496.0, 323.5], "category_id": 1}, {"id": 6, "bbox": [1850.18, 736.64, 110.59, 59.55], "category_id": 2}, {"id": 7, "bbox": [645.0, 1049.0, 50.0, 63.0], "category_id": 3}, {"id": 8, "bbox": [1915.0, 1049.0, 92.0, 69.0], "category_id": 3}, {"id": 9, "bbox": [1781.0, 667.0, 73.0, 72.0], "category_id": 3}, {"id": 10, "bbox": [1820.0, 305.0, 85.0, 64.0], "category_id": 3}, {"id": 11, "bbox": [597.0, 657.0, 82.0, 73.0], "category_id": 3}, {"id": 12, "bbox": [584.0, 253.0, 55.0, 58.0], "category_id": 3}, {"id": 13, "bbox": [963.0, 685.0, 512.0, 69.0], "category_id": 2}, {"id": 14, "bbox": [966.0, 237.0, 527.0, 61.0], "category_id": 2}, {"id": 15, "bbox": [995.0, 878.0, 670.0, 168.0], "category_id": 2}, {"id": 16, "bbox": [950.0, 498.0, 691.0, 150.0], "category_id": 2}, {"id": 17, "bbox": [958.0, 42.0, 688.0, 161.0], "category_id": 2}, {"id": 18, "bbox": [492.0, 817.0, 464.0, 335.0], "category_id": 1}, {"id": 19, "bbox": [1668.0, 5.0, 413.0, 319.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [17, 14], "products": [19]}, {"reactants": [3], "conditions": [16, 13], "products": [1]}, {"reactants": [18], "conditions": [15, 0], "products": [5]}], "corefs": [[2, 12], [19, 10], [3, 11], [1, 9], [18, 7], [5, 8]], "caption": "Table 4. Solvent-Free Regioselective Allylation Catalyzed by Bu2SnOa", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 412, 476, 434], "ImageBB": [82, 116, 787, 412]}, "diagram_type": "multiple"}, {"id": 1126, "width": 988, "height": 776, "file_name": "jo991524o-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [268.38, 388.96, 92.42, 76.61], "category_id": 2}, {"id": 1, "bbox": [736.92, 392.92, 215.99, 256.01], "category_id": 1}, {"id": 2, "bbox": [0.0, 514.0, 265.9, 234.76], "category_id": 3}, {"id": 3, "bbox": [551.58, 250.08, 267.88, 135.92], "category_id": 3}, {"id": 4, "bbox": [405.78, 676.61, 279.25, 96.37], "category_id": 3}, {"id": 5, "bbox": [392.93, 426.52, 214.5, 223.4], "category_id": 1}, {"id": 6, "bbox": [267.39, 175.45, 205.6, 124.06], "category_id": 2}, {"id": 7, "bbox": [534.78, 1.98, 217.46, 225.86], "category_id": 1}, {"id": 8, "bbox": [9.39, 270.84, 215.49, 211.53], "category_id": 1}, {"id": 9, "bbox": [753.73, 666.72, 175.95, 47.94], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 64, 636, 78], "ImageBB": [489, 84, 736, 278]}, "reactions": [{"reactants": [8], "conditions": [6], "products": [7]}, {"reactants": [8], "conditions": [0], "products": [5]}, {"reactants": [5], "conditions": [], "products": [1]}], "diagram_type": "tree"}, {"id": 975, "width": 1140, "height": 1864, "file_name": "ja0547477-Scheme-c13.png", "license": 0, "bboxes": [{"id": 0, "bbox": [858.74, 1295.54, 281.26, 53.7], "category_id": 3}, {"id": 1, "bbox": [6.0, 440.12, 507.01, 333.83], "category_id": 1}, {"id": 2, "bbox": [0.0, 0.0, 514.88, 339.42], "category_id": 1}, {"id": 3, "bbox": [564.3, 0.0, 539.14, 339.42], "category_id": 1}, {"id": 4, "bbox": [556.85, 1257.9, 219.2, 96.04], "category_id": 2}, {"id": 5, "bbox": [0.0, 916.61, 514.88, 331.96], "category_id": 1}, {"id": 6, "bbox": [0.0, 0.0, 514.88, 339.42], "category_id": 1}, {"id": 7, "bbox": [242.51, 711.47, 74.62, 53.15], "category_id": 3}, {"id": 8, "bbox": [493.42, 1107.77, 154.84, 91.38], "category_id": 2}, {"id": 9, "bbox": [259.6, 1243.91, 191.5, 47.99], "category_id": 3}, {"id": 10, "bbox": [834.81, 1242.98, 238.09, 46.42], "category_id": 3}, {"id": 11, "bbox": [468.24, 179.03, 209.87, 52.22], "category_id": 2}, {"id": 12, "bbox": [251.84, 277.87, 81.15, 48.49], "category_id": 3}, {"id": 13, "bbox": [14.92, 811.25, 261.17, 55.94], "category_id": 2}, {"id": 14, "bbox": [835.74, 705.88, 83.95, 58.74], "category_id": 3}, {"id": 15, "bbox": [495.29, 925.94, 65.29, 43.82], "category_id": 3}, {"id": 16, "bbox": [468.24, 1813.65, 92.34, 47.55], "category_id": 3}, {"id": 17, "bbox": [801.23, 276.01, 79.28, 48.49], "category_id": 3}, {"id": 18, "bbox": [586.7, 918.48, 513.01, 332.89], "category_id": 1}, {"id": 19, "bbox": [558.72, 353.4, 277.02, 56.89], "category_id": 2}, {"id": 20, "bbox": [590.8, 433.6, 510.78, 337.55], "category_id": 1}, {"id": 21, "bbox": [188.42, 1409.89, 573.64, 380.45], "category_id": 1}, {"id": 22, "bbox": [413.21, 809.38, 235.05, 125.88], "category_id": 1}, {"id": 23, "bbox": [509.66, 610.8, 138.73, 49.23], "category_id": 2}, {"id": 24, "bbox": [259.03, 1293.3, 232.73, 49.23], "category_id": 3}, {"id": 25, "bbox": [0.0, 1247.64, 198.68, 111.9], "category_id": 2}], "caption": "Scheme 13. Synthesis of Vinyl Stannane 98a", "pdf": {"Page": 12, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 63, 669, 76], "ImageBB": [465, 80, 750, 546]}, "reactions": [{"reactants": [6], "conditions": [11], "products": [3]}, {"reactants": [3], "conditions": [19], "products": [20]}, {"reactants": [20], "conditions": [23], "products": [1]}, {"reactants": [1], "conditions": [13], "products": [5]}, {"reactants": [5], "conditions": [8], "products": [18]}, {"reactants": [9], "conditions": [25], "products": [24]}, {"reactants": [10], "conditions": [4], "products": [0]}], "diagram_type": "tree"}, {"id": 219, "width": 1356, "height": 812, "file_name": "op0256183-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 29.0, 360.0, 140.0], "category_id": 1}, {"id": 1, "bbox": [380.0, 6.0, 567.0, 80.0], "category_id": 2}, {"id": 2, "bbox": [530.0, 125.0, 261.0, 53.0], "category_id": 2}, {"id": 3, "bbox": [12.0, 202.0, 1332.0, 610.0], "category_id": 4}, {"id": 4, "bbox": [974.0, 26.1, 370.0, 139.4], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 2], "products": [4]}], "corefs": [], "caption": "Table 3. Effect of substrate concentration and addition of triethylamine ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 326, 391, 354], "ImageBB": [73, 358, 412, 561]}, "diagram_type": "single"}, {"id": 692, "width": 1356, "height": 1336, "file_name": "ol051245p-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [852.54, 469.19, 118.28, 56.24], "category_id": 2}, {"id": 1, "bbox": [852.54, 969.47, 118.28, 52.35], "category_id": 2}, {"id": 2, "bbox": [173.88, 781.38, 127.97, 60.11], "category_id": 2}, {"id": 3, "bbox": [0.0, 349.0, 845.0, 986.0], "category_id": 1}, {"id": 4, "bbox": [968.9, 319.6, 225.4, 364.0], "category_id": 1}, {"id": 5, "bbox": [859.4, 674.8, 496.6, 661.2], "category_id": 1}, {"id": 6, "bbox": [1016.8, 139.1, 266.7, 177.5], "category_id": 1}, {"id": 7, "bbox": [572.7, 141.9, 297.1, 192.5], "category_id": 1}, {"id": 8, "bbox": [246.8, 151.0, 224.8, 143.5], "category_id": 1}, {"id": 9, "bbox": [36.3, 166.0, 193.7, 164.6], "category_id": 1}, {"id": 10, "bbox": [883.0, 204.33, 97.3, 47.3], "category_id": 1}], "reactions": [{"reactants": [9, 8], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [10], "products": [6]}], "corefs": [], "caption": "Figure 1. Synthesis and structure of uridopyrimidine dendimers 1-3. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 398, 409, 425], "ImageBB": [73, 52, 412, 386]}, "diagram_type": "single"}, {"id": 839, "width": 2820, "height": 1336, "file_name": "jo202324f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1698.0, 15.0, 252.0, 149.0], "category_id": 1}, {"id": 1, "bbox": [856.0, 0.0, 351.0, 173.0], "category_id": 1}, {"id": 2, "bbox": [792.0, 1242.0, 214.0, 61.0], "category_id": 2}, {"id": 3, "bbox": [726.0, 778.0, 310.0, 105.0], "category_id": 2}, {"id": 4, "bbox": [1171.0, 716.0, 470.0, 172.0], "category_id": 2}, {"id": 5, "bbox": [1189.0, 929.0, 286.0, 292.0], "category_id": 1}, {"id": 6, "bbox": [1824.0, 931.0, 269.0, 301.0], "category_id": 1}, {"id": 7, "bbox": [1662.0, 278.0, 495.0, 484.0], "category_id": 1}, {"id": 8, "bbox": [657.0, 45.0, 183.0, 105.0], "category_id": 2}, {"id": 9, "bbox": [1333.0, 315.0, 240.0, 109.0], "category_id": 2}, {"id": 10, "bbox": [790.0, 216.0, 182.0, 101.0], "category_id": 2}, {"id": 11, "bbox": [908.0, 189.0, 286.0, 96.0], "category_id": 2}, {"id": 12, "bbox": [1194.0, 1244.0, 303.0, 50.0], "category_id": 2}, {"id": 13, "bbox": [1863.0, 1239.0, 219.0, 53.0], "category_id": 2}, {"id": 14, "bbox": [1593.0, 1098.0, 137.0, 59.0], "category_id": 2}, {"id": 15, "bbox": [1502.0, 997.0, 297.0, 73.0], "category_id": 2}, {"id": 16, "bbox": [1797.0, 776.0, 308.0, 100.0], "category_id": 2}, {"id": 17, "bbox": [1970.0, 41.0, 196.0, 64.0], "category_id": 2}, {"id": 18, "bbox": [787.0, 938.0, 251.0, 294.0], "category_id": 1}, {"id": 19, "bbox": [1324.0, 45.0, 57.0, 37.0], "category_id": 3}, {"id": 20, "bbox": [1790.0, 34.0, 48.0, 48.0], "category_id": 3}, {"id": 21, "bbox": [1267.0, 1180.0, 50.0, 36.0], "category_id": 3}, {"id": 22, "bbox": [1863.0, 221.0, 182.0, 97.1], "category_id": 2}, {"id": 23, "bbox": [1209.6, 2.0, 443.9, 390.4], "category_id": 1}, {"id": 24, "bbox": [658.5, 372.1, 535.5, 387.9], "category_id": 1}, {"id": 25, "bbox": [1712.13, 190.63, 131.2, 47.47], "category_id": 2}], "reactions": [{"reactants": [23], "conditions": [1, 10, 11], "products": [24]}, {"reactants": [23], "conditions": [0, 25, 22], "products": [7]}, {"reactants": [24], "conditions": [3], "products": [18]}, {"reactants": [7], "conditions": [16], "products": [6]}, {"reactants": [6], "conditions": [15, 14], "products": [5]}], "corefs": [[23, 19], [0, 20], [5, 21]], "caption": "Table 1. Condition Optimization for the Enantioselective Cascade [4 + 1] Annulation/Rearrangement Reactiona", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 450, 718, 471], "ImageBB": [82, 116, 787, 450]}, "diagram_type": "tree"}, {"id": 453, "width": 1356, "height": 556, "file_name": "op2001047-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 8.0, 332.8, 206.8], "category_id": 1}, {"id": 1, "bbox": [412.4, 50.9, 232.4, 119.4], "category_id": 1}, {"id": 2, "bbox": [931.5, 3.0, 423.5, 211.5], "category_id": 1}, {"id": 3, "bbox": [718.0, 80.0, 136.0, 50.0], "category_id": 2}, {"id": 4, "bbox": [538.0, 241.0, 39.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [698.0, 159.0, 195.0, 45.0], "category_id": 2}, {"id": 6, "bbox": [1188.0, 239.0, 58.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [14.0, 327.0, 1326.0, 229.0], "category_id": 4}, {"id": 8, "bbox": [180.0, 237.0, 65.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [0, 1], "conditions": [3, 5], "products": [2]}], "corefs": [[0, 8], [1, 4], [2, 6]], "caption": "Table 2. Reaction optimization for the Wittig reaction of p-anisaldehyde (4b) and (acetylmethylene)triphenylphospho- rane (5) under microwave batch conditionsa ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 770, 137], "ImageBB": [436, 148, 775, 287]}, "diagram_type": "single"}, {"id": 1314, "width": 1356, "height": 1272, "file_name": "op3001788-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [994.45, 1011.07, 318.81, 188.64], "category_id": 1}, {"id": 1, "bbox": [674.27, 321.64, 265.91, 110.61], "category_id": 2}, {"id": 2, "bbox": [930.0, 510.96, 362.24, 260.57], "category_id": 1}, {"id": 3, "bbox": [183.15, 38.68, 62.41, 54.96], "category_id": 3}, {"id": 4, "bbox": [1130.11, 558.46, 75.3, 59.04], "category_id": 3}, {"id": 5, "bbox": [69.87, 776.96, 162.8, 57.68], "category_id": 2}, {"id": 6, "bbox": [46.81, 935.07, 357.48, 270.75], "category_id": 1}, {"id": 7, "bbox": [615.25, 178.46, 579.98, 58.36], "category_id": 2}, {"id": 8, "bbox": [972.74, 69.89, 63.08, 61.75], "category_id": 3}, {"id": 9, "bbox": [1046.68, 0.0, 164.83, 161.5], "category_id": 1}, {"id": 10, "bbox": [46.81, 499.43, 303.89, 268.71], "category_id": 1}, {"id": 11, "bbox": [582.02, 570.0, 67.15, 52.93], "category_id": 3}, {"id": 12, "bbox": [1178.28, 1163.75, 69.86, 61.75], "category_id": 3}, {"id": 13, "bbox": [230.64, 16.29, 193.32, 137.07], "category_id": 1}, {"id": 14, "bbox": [263.87, 577.46, 68.52, 59.04], "category_id": 3}, {"id": 15, "bbox": [646.46, 61.75, 164.16, 99.75], "category_id": 1}, {"id": 16, "bbox": [695.98, 1176.64, 75.97, 55.64], "category_id": 3}, {"id": 17, "bbox": [455.84, 613.43, 369.02, 158.78], "category_id": 1}, {"id": 18, "bbox": [534.53, 951.35, 320.86, 264.65], "category_id": 1}, {"id": 19, "bbox": [392.76, 919.46, 243.52, 94.32], "category_id": 2}, {"id": 20, "bbox": [1093.48, 781.03, 162.8, 59.04], "category_id": 2}, {"id": 21, "bbox": [643.74, 48.86, 68.52, 54.96], "category_id": 3}, {"id": 22, "bbox": [230.64, 1165.1, 73.26, 60.4], "category_id": 3}, {"id": 23, "bbox": [847.25, 919.46, 278.11, 95.68], "category_id": 2}, {"id": 24, "bbox": [1093.48, 346.75, 171.62, 63.11], "category_id": 2}, {"id": 25, "bbox": [674.27, 774.93, 99.04, 57.0], "category_id": 2}, {"id": 26, "bbox": [46.81, 326.39, 187.9, 68.54], "category_id": 2}], "caption": "Scheme 4. Pathways to 1-Benzyl-pyrrolidin-3-on 12, Precursor of Route B ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 742, 125], "ImageBB": [448, 131, 787, 449]}, "reactions": [{"reactants": [13], "conditions": [26], "products": [10]}, {"reactants": [15], "conditions": [1], "products": [17]}, {"reactants": [9], "conditions": [24], "products": [2]}, {"reactants": [10], "conditions": [5], "products": [6]}, {"reactants": [17], "conditions": [25], "products": [6]}, {"reactants": [2], "conditions": [20], "products": [6]}, {"reactants": [6], "conditions": [19], "products": [18]}, {"reactants": [18], "conditions": [23], "products": [0]}], "diagram_type": "graph"}, {"id": 330, "width": 1344, "height": 1440, "file_name": "ol300808c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [757.74, 198.46, 25.08, 29.26], "category_id": 2}, {"id": 1, "bbox": [682.0, 552.6, 204.6, 42.1], "category_id": 3}, {"id": 2, "bbox": [0.3, 623.3, 1343.1, 816.7], "category_id": 4}, {"id": 3, "bbox": [282.8, 312.1, 970.2, 267.4], "category_id": 1}, {"id": 4, "bbox": [88.0, 6.0, 646.0, 261.9], "category_id": 1}, {"id": 5, "bbox": [831.0, 50.7, 410.9, 116.8], "category_id": 1}, {"id": 6, "bbox": [983.7, 168.3, 110.9, 45.3], "category_id": 3}, {"id": 7, "bbox": [327.74, 228.84, 62.3, 50.6], "category_id": 3}], "reactions": [{"reactants": [4, 5], "conditions": [0], "products": [3]}], "corefs": [[4, 7], [5, 6], [3, 1]], "caption": "Table 1. Effects of Various Alkene-Containing Sugar Deriva- tives on Solid-Phase CMa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 433, 397, 460], "ImageBB": [71, 471, 407, 831]}, "diagram_type": "tree"}, {"id": 671, "width": 1348, "height": 1644, "file_name": "ol401881n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [625.35, 118.59, 101.69, 52.96], "category_id": 2}, {"id": 1, "bbox": [936.0, 177.0, 66.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [6.0, 302.0, 1342.0, 1342.0], "category_id": 4}, {"id": 3, "bbox": [318.0, 177.0, 66.0, 52.0], "category_id": 3}, {"id": 4, "bbox": [130.8, 2.0, 424.2, 153.4], "category_id": 1}, {"id": 5, "bbox": [561.7, 24.2, 242.7, 65.2], "category_id": 2}, {"id": 6, "bbox": [818.9, 4.2, 401.7, 173.7], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [5, 0], "products": [6]}], "corefs": [[4, 3], [6, 1]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 376, 707, 392], "ImageBB": [436, 403, 773, 814]}, "diagram_type": "single"}, {"id": 622, "width": 1352, "height": 3096, "file_name": "ol502664f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [423.0, 402.0, 563.5, 191.7], "category_id": 2}, {"id": 1, "bbox": [419.6, 0.0, 562.5, 188.0], "category_id": 2}, {"id": 2, "bbox": [397.3, 221.0, 617.8, 191.0], "category_id": 2}, {"id": 3, "bbox": [1058.9, 126.2, 145.5, 138.9], "category_id": 1}, {"id": 4, "bbox": [22.7, 610.0, 1329.3, 2486.0], "category_id": 4}, {"id": 5, "bbox": [155.2, 119.9, 166.6, 145.2], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1, 2, 0], "products": [3]}], "corefs": [], "caption": "Table 1. Visible-Light-Enhanced Oxidation of Allylic and Benzylic Alcohols with Catalytic Amounts of DDQ (Reactions Carried out on 1 mmol Scale in Pyrex Vessels) ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 780, 140], "ImageBB": [448, 146, 786, 920]}, "diagram_type": "single"}, {"id": 594, "width": 1352, "height": 1340, "file_name": "acs.oprd.6b00128-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.0, 19.0, 322.1, 283.0], "category_id": 1}, {"id": 1, "bbox": [894.0, 5.0, 380.0, 345.0], "category_id": 1}, {"id": 2, "bbox": [654.0, 239.0, 217.0, 46.0], "category_id": 2}, {"id": 3, "bbox": [442.49, 55.76, 188.6, 229.92], "category_id": 1}, {"id": 4, "bbox": [697.0, 293.0, 137.0, 51.0], "category_id": 2}, {"id": 5, "bbox": [97.0, 322.0, 348.0, 65.0], "category_id": 2}, {"id": 6, "bbox": [8.0, 407.0, 1344.0, 933.0], "category_id": 4}], "reactions": [{"reactants": [0, 3], "conditions": [2, 4], "products": [1]}], "corefs": [], "caption": "Table 1. Suzuki Coupling Conditions for Biaryl Synthesisa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 413, 110], "ImageBB": [82, 116, 420, 451]}, "diagram_type": "single"}, {"id": 805, "width": 1352, "height": 1096, "file_name": "jo402763m-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [618.0, 92.0, 82.0, 47.0], "category_id": 2}, {"id": 1, "bbox": [1000.0, 5.0, 305.0, 230.0], "category_id": 1}, {"id": 2, "bbox": [1117.0, 239.0, 152.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [22.0, 266.0, 1316.0, 800.0], "category_id": 4}, {"id": 4, "bbox": [30.0, 6.0, 337.0, 232.0], "category_id": 1}, {"id": 5, "bbox": [126.0, 242.0, 111.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [0], "products": [1]}], "corefs": [[4, 5], [1, 2]], "caption": "Table 2. Pd-Catalysis of Primary and Secondary Alcohols (2 and 9) ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 405, 125], "ImageBB": [82, 131, 420, 405]}, "diagram_type": "single"}, {"id": 1260, "width": 832, "height": 1444, "file_name": "op050087e-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [9.39, 516.49, 92.47, 54.9], "category_id": 2}, {"id": 1, "bbox": [562.75, 712.25, 104.03, 59.95], "category_id": 2}, {"id": 2, "bbox": [122.81, 458.7, 270.9, 140.86], "category_id": 2}, {"id": 3, "bbox": [0.0, 1141.33, 210.94, 302.67], "category_id": 1}, {"id": 4, "bbox": [317.86, 787.37, 39.73, 44.07], "category_id": 3}, {"id": 5, "bbox": [562.75, 565.61, 269.25, 101.13], "category_id": 2}, {"id": 6, "bbox": [122.81, 1006.25, 262.95, 92.46], "category_id": 2}, {"id": 7, "bbox": [317.86, 1251.85, 39.73, 52.73], "category_id": 3}, {"id": 8, "bbox": [0.0, 1033.7, 98.25, 48.4], "category_id": 2}, {"id": 9, "bbox": [0.0, 664.57, 244.89, 303.39], "category_id": 1}, {"id": 10, "bbox": [0.0, 0.0, 244.89, 415.36], "category_id": 1}, {"id": 11, "bbox": [317.86, 137.25, 39.73, 46.95], "category_id": 3}], "caption": "Scheme 4", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [138, 71, 346, 432]}, "reactions": [{"reactants": [10], "conditions": [5, 1], "products": [3]}, {"reactants": [10], "conditions": [0, 2], "products": [9]}, {"reactants": [9], "conditions": [8, 6], "products": [3]}], "diagram_type": "graph"}, {"id": 997, "width": 1356, "height": 640, "file_name": "ja407179c-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [315.43, 297.86, 97.0, 45.46], "category_id": 2}, {"id": 1, "bbox": [987.66, 200.83, 48.84, 38.0], "category_id": 3}, {"id": 2, "bbox": [943.57, 504.12, 69.87, 49.53], "category_id": 3}, {"id": 3, "bbox": [489.76, 214.4, 71.23, 46.14], "category_id": 3}, {"id": 4, "bbox": [802.48, 4.07, 376.47, 201.51], "category_id": 1}, {"id": 5, "bbox": [613.22, 42.75, 93.61, 49.53], "category_id": 2}, {"id": 6, "bbox": [769.24, 377.24, 254.37, 188.62], "category_id": 1}, {"id": 7, "bbox": [173.65, 2.71, 289.55, 164.89], "category_id": 1}, {"id": 8, "bbox": [318.14, 381.99, 246.24, 211.81], "category_id": 1}, {"id": 9, "bbox": [469.41, 300.57, 105.82, 44.78], "category_id": 2}, {"id": 10, "bbox": [260.48, 113.99, 287.62, 121.45], "category_id": 1}, {"id": 11, "bbox": [333.74, 109.92, 46.81, 42.74], "category_id": 3}], "caption": "Scheme 6. Dynamic Kinetic Resolution Model", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 711, 110], "ImageBB": [448, 116, 787, 276]}, "reactions": [{"reactants": [7, 10], "conditions": [5], "products": [4]}, {"reactants": [7, 10], "conditions": [9], "products": [8]}, {"reactants": [8], "conditions": [0], "products": [7, 10]}, {"reactants": [8], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [8]}], "diagram_type": "tree"}, {"id": 294, "width": 1344, "height": 760, "file_name": "ol400025a-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [301.0, 259.06, 67.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [920.04, 260.04, 67.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [837.6, 11.8, 294.5, 239.3], "category_id": 1}, {"id": 3, "bbox": [218.5, 3.9, 294.6, 241.2], "category_id": 1}, {"id": 4, "bbox": [567.0, 189.0, 178.0, 35.0], "category_id": 2}, {"id": 5, "bbox": [6.0, 346.0, 1338.0, 414.0], "category_id": 4}, {"id": 6, "bbox": [494.0, 57.0, 329.0, 105.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [6, 4], "products": [2]}], "corefs": [[3, 0], [2, 1]], "caption": "Table 4. Study on the Cascade Reaction Pathwaya", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 339, 101], "ImageBB": [71, 112, 407, 302]}, "diagram_type": "single"}, {"id": 312, "width": 1352, "height": 2260, "file_name": "ol302400p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [35.6, 2.0, 277.8, 165.2], "category_id": 1}, {"id": 1, "bbox": [919.0, 27.0, 399.2, 166.4], "category_id": 1}, {"id": 2, "bbox": [15.0, 313.0, 1328.0, 1947.0], "category_id": 4}, {"id": 3, "bbox": [361.0, 199.0, 139.0, 44.0], "category_id": 2}, {"id": 4, "bbox": [606.0, 149.0, 248.0, 101.0], "category_id": 2}, {"id": 5, "bbox": [586.0, 37.0, 295.0, 94.0], "category_id": 2}, {"id": 6, "bbox": [285.0, 65.0, 230.0, 127.0], "category_id": 1}, {"id": 7, "bbox": [1063.0, 214.0, 84.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [0, 6], "conditions": [5, 4], "products": [1]}], "corefs": [[1, 7]], "caption": "Table 2. Pd-Catalyzed Dehydrogenative Olefination of Term- inal Alkynes with Allyl Methyl Ethers (Sulfide)a,b ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 368, 399, 395], "ImageBB": [71, 406, 409, 971]}, "diagram_type": "single"}, {"id": 0, "width": 1348, "height": 340, "file_name": "jacs.6b01306-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [62.6, 118.47, 347.18, 103.57], "category_id": 1}, {"id": 1, "bbox": [420.69, 152.04, 502.12, 83.77], "category_id": 2}, {"id": 2, "bbox": [6.11, 263.0, 1335.8, 76.25], "category_id": 4}, {"id": 3, "bbox": [936.3, 118.47, 348.04, 102.71], "category_id": 1}, {"id": 4, "bbox": [474.06, 3.12, 412.6, 135.38], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [4, 1], "products": [3]}], "corefs": [], "caption": "Table 1. Asymmetric Hydrogenation of Dimethyl Itaconate with Mixtures of BTA Ligand, [Rh(cod)2]BArF, and Ester BTA: Screening of Various Comonomersa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 373, 415, 418], "ImageBB": [82, 425, 419, 510]}, "diagram_type": "single"}, {"id": 562, "width": 1304, "height": 2228, "file_name": "acs.orglett.5b01754-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [56.0, 17.0, 328.0, 265.0], "category_id": 1}, {"id": 1, "bbox": [921.0, 4.0, 324.0, 274.0], "category_id": 1}, {"id": 2, "bbox": [530.0, 32.0, 274.0, 107.0], "category_id": 2}, {"id": 3, "bbox": [454.0, 186.0, 424.0, 51.0], "category_id": 2}, {"id": 4, "bbox": [326.0, 226.0, 54.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [649.0, 250.0, 31.0, 34.0], "category_id": 3}, {"id": 6, "bbox": [1185.0, 230.0, 37.0, 32.0], "category_id": 3}, {"id": 7, "bbox": [4.0, 308.0, 1300.0, 1920.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [1]}], "corefs": [[0, 4], [1, 6]], "caption": "Table 2. Formation of H8-BINOL-Based CPA from BINOL- Based CPAs ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [88, 131, 414, 688]}, "diagram_type": "single"}, {"id": 416, "width": 1704, "height": 896, "file_name": "op400055z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [59.0, 355.0, 1352.0, 283.0], "category_id": 4}, {"id": 1, "bbox": [106.0, 3.0, 340.0, 218.0], "category_id": 1}, {"id": 2, "bbox": [963.0, 0.0, 356.0, 221.0], "category_id": 1}, {"id": 3, "bbox": [303.0, 210.0, 68.0, 64.0], "category_id": 3}, {"id": 4, "bbox": [1188.0, 179.0, 64.0, 57.0], "category_id": 3}, {"id": 5, "bbox": [533.0, 143.0, 320.0, 198.0], "category_id": 2}, {"id": 6, "bbox": [652.0, 82.0, 52.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [1043.0, 239.0, 315.0, 91.6], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [6, 5], "products": [2]}], "corefs": [[1, 3], [2, 4]], "caption": "Table 2. Asymmetric hydrogenation of 7b with high TONs", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 875, 782, 890], "ImageBB": [433, 903, 859, 1127]}, "diagram_type": "single"}, {"id": 309, "width": 1300, "height": 1376, "file_name": "ol302668y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.55, 312.0, 71.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [39.0, 257.0, 193.0, 52.7], "category_id": 2}, {"id": 2, "bbox": [643.0, 211.5, 314.4, 162.5], "category_id": 2}, {"id": 3, "bbox": [323.3, 144.7, 320.2, 107.1], "category_id": 1}, {"id": 4, "bbox": [948.6, 0.0, 341.4, 406.0], "category_id": 1}, {"id": 5, "bbox": [478.0, 317.0, 35.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [1027.0, 305.0, 38.0, 52.0], "category_id": 3}, {"id": 7, "bbox": [638.0, 57.0, 346.0, 138.8], "category_id": 2}, {"id": 8, "bbox": [8.0, 518.9, 1292.0, 857.1], "category_id": 4}, {"id": 9, "bbox": [0.0, 142.1, 279.0, 100.5], "category_id": 1}], "reactions": [{"reactants": [9, 3], "conditions": [7, 2], "products": [4]}], "corefs": [[9, 0], [3, 5], [4, 6]], "caption": "Table 3. Click Reaction of 2b with Various Acetylenes 3 and Fluorescence Properties of Various 5-Methyl-1,3a,6a-triaza- pentalenes in Dichloromethane ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 392, 128], "ImageBB": [77, 139, 402, 483]}, "diagram_type": "single"}, {"id": 583, "width": 2820, "height": 2680, "file_name": "acs.oprd.6b00188-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1853.0, 1003.0, 50.0, 5.0], "category_id": 4}, {"id": 1, "bbox": [1179.0, 66.0, 445.0, 77.0], "category_id": 2}, {"id": 2, "bbox": [1298.0, 200.0, 187.0, 173.0], "category_id": 2}, {"id": 3, "bbox": [897.0, 69.0, 198.0, 160.0], "category_id": 1}, {"id": 4, "bbox": [1643.0, 5.0, 277.0, 242.0], "category_id": 1}, {"id": 5, "bbox": [1.0, 390.0, 2446.0, 2285.0], "category_id": 4}], "reactions": [{"reactants": [3], "conditions": [1, 2], "products": [4]}], "corefs": [], "caption": "Table 2. Scope of the Condensation of Ketones Mediated by Titanium(IV) Isopropoxide (Method A)", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 655, 110], "ImageBB": [82, 116, 787, 786]}, "diagram_type": "single"}, {"id": 631, "width": 1348, "height": 280, "file_name": "ol501422k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [109.0, 141.0, 47.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [438.0, 78.0, 218.0, 82.0], "category_id": 2}, {"id": 2, "bbox": [1148.0, 140.0, 51.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [13.0, 206.0, 1335.0, 74.0], "category_id": 4}, {"id": 4, "bbox": [334.7, 136.28, 59.0, 35.4], "category_id": 3}, {"id": 5, "bbox": [38.7, 6.6, 222.0, 125.4], "category_id": 1}, {"id": 6, "bbox": [1035.6, 4.0, 279.2, 127.6], "category_id": 1}, {"id": 7, "bbox": [674.9, 6.0, 338.0, 123.9], "category_id": 1}, {"id": 8, "bbox": [321.7, 11.4, 92.1, 115.5], "category_id": 1}, {"id": 9, "bbox": [423.0, 12.6, 231.0, 42.4], "category_id": 2}, {"id": 10, "bbox": [753.42, 141.14, 57.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [5, 8], "conditions": [9, 1], "products": [7, 6]}], "corefs": [[5, 0], [8, 4], [7, 10], [6, 2]], "caption": "Table 1. Optimization of the Br\u00f8nsted Acid Promoted Benzylic Nucleophilic Addition of Azaarenesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 383, 125], "ImageBB": [82, 131, 419, 201]}, "diagram_type": "single"}, {"id": 1368, "width": 1312, "height": 1628, "file_name": "op9600419-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [391.82, 618.95, 65.17, 58.64], "category_id": 3}, {"id": 1, "bbox": [610.95, 461.77, 364.13, 351.82], "category_id": 1}, {"id": 2, "bbox": [551.49, 124.6, 247.64, 56.2], "category_id": 2}, {"id": 3, "bbox": [180.84, 369.74, 43.99, 48.87], "category_id": 3}, {"id": 4, "bbox": [307.11, 1118.18, 693.22, 365.67], "category_id": 1}, {"id": 5, "bbox": [0.0, 7.33, 461.88, 346.12], "category_id": 1}, {"id": 6, "bbox": [727.44, 928.42, 316.88, 56.2], "category_id": 2}, {"id": 7, "bbox": [878.96, 0.0, 433.04, 349.38], "category_id": 1}, {"id": 8, "bbox": [688.34, 1494.44, 46.43, 52.93], "category_id": 3}, {"id": 9, "bbox": [347.02, 928.42, 313.62, 64.34], "category_id": 2}, {"id": 10, "bbox": [746.99, 779.39, 41.55, 50.49], "category_id": 3}, {"id": 11, "bbox": [514.02, 1559.59, 439.07, 68.41], "category_id": 2}, {"id": 12, "bbox": [588.96, 193.83, 156.4, 48.86], "category_id": 2}, {"id": 13, "bbox": [1017.44, 361.6, 62.73, 48.86], "category_id": 3}], "caption": "Scheme 7. Preparation of CI-1011 (1) from acid 2 and sulfamate 3 ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 510, 748, 538], "ImageBB": [443, 545, 771, 952]}, "reactions": [{"reactants": [5], "conditions": [2, 12], "products": [7]}, {"reactants": [0, 1], "conditions": [9, 6], "products": [4]}], "diagram_type": "tree"}, {"id": 767, "width": 1288, "height": 1696, "file_name": "jo961049j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [577.0, 1336.0, 171.0, 60.0], "category_id": 2}, {"id": 1, "bbox": [577.0, 275.0, 176.0, 85.0], "category_id": 2}, {"id": 2, "bbox": [502.0, 1407.0, 334.0, 124.0], "category_id": 2}, {"id": 3, "bbox": [1100.0, 1029.0, 33.0, 51.0], "category_id": 3}, {"id": 4, "bbox": [236.0, 1027.0, 32.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [1086.0, 1647.0, 36.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [227.0, 1645.0, 38.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [914.8, 1217.0, 336.8, 368.5], "category_id": 1}, {"id": 8, "bbox": [495.0, 369.0, 371.4, 117.0], "category_id": 2}, {"id": 9, "bbox": [572.0, 813.5, 188.5, 62.5], "category_id": 2}, {"id": 10, "bbox": [461.6, 883.0, 436.8, 137.0], "category_id": 2}, {"id": 11, "bbox": [865.5, 697.6, 417.5, 286.9], "category_id": 1}, {"id": 12, "bbox": [933.7, 188.1, 335.8, 258.6], "category_id": 1}, {"id": 13, "bbox": [88.0, 114.8, 317.6, 399.8], "category_id": 1}, {"id": 14, "bbox": [1086.91, 490.36, 73.99, 73.04], "category_id": 3}, {"id": 15, "bbox": [240.35, 492.18, 45.2, 59.6], "category_id": 3}, {"id": 16, "bbox": [73.5, 1162.3, 315.4, 488.2], "category_id": 1}, {"id": 17, "bbox": [59.5, 630.2, 384.0, 399.3], "category_id": 1}], "reactions": [{"reactants": [13], "conditions": [1, 8], "products": [12]}, {"reactants": [17], "conditions": [9, 10], "products": [11]}, {"reactants": [16], "conditions": [0, 2], "products": [7]}], "corefs": [[13, 15], [12, 14], [17, 4], [11, 3], [16, 6], [7, 5]], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 456, 130, 469], "ImageBB": [73, 20, 395, 444]}, "diagram_type": "multiple"}, {"id": 694, "width": 1344, "height": 916, "file_name": "ol050791f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 19.0, 231.5, 186.4], "category_id": 1}, {"id": 1, "bbox": [720.0, 13.0, 178.0, 82.0], "category_id": 2}, {"id": 2, "bbox": [682.0, 138.0, 250.0, 75.0], "category_id": 2}, {"id": 3, "bbox": [4.0, 337.0, 1337.0, 579.0], "category_id": 4}, {"id": 4, "bbox": [1163.0, 253.0, 36.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [112.0, 254.0, 31.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [376.0, 42.0, 227.0, 144.0], "category_id": 1}, {"id": 7, "bbox": [1029.0, 0.0, 301.0, 228.0], "category_id": 1}], "reactions": [{"reactants": [0, 6], "conditions": [1, 2], "products": [7]}], "corefs": [[0, 5], [7, 4]], "caption": "Table 1. Preparation of Fluorinated \u03b3-Amino Alcohols 2 from Propanal and Aldimines 1 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 259, 403, 288], "ImageBB": [74, 292, 410, 521]}, "diagram_type": "single"}, {"id": 1108, "width": 1344, "height": 756, "file_name": "jo980767y-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [311.96, 86.04, 92.11, 46.38], "category_id": 2}, {"id": 1, "bbox": [425.59, 635.87, 279.69, 52.43], "category_id": 2}, {"id": 2, "bbox": [600.4, 8.74, 173.46, 49.07], "category_id": 2}, {"id": 3, "bbox": [0.0, 281.64, 340.2, 60.49], "category_id": 2}, {"id": 4, "bbox": [858.57, 49.74, 331.47, 56.46], "category_id": 2}, {"id": 5, "bbox": [816.89, 540.42, 323.39, 131.08], "category_id": 1}, {"id": 6, "bbox": [858.57, 289.03, 267.59, 58.48], "category_id": 2}, {"id": 7, "bbox": [0.0, 41.0, 196.99, 57.14], "category_id": 2}, {"id": 8, "bbox": [482.74, 336.08, 161.36, 53.78], "category_id": 2}, {"id": 9, "bbox": [1192.72, 592.85, 127.08, 57.14], "category_id": 2}, {"id": 10, "bbox": [453.83, 543.11, 215.14, 57.81], "category_id": 2}, {"id": 11, "bbox": [1214.91, 51.08, 129.09, 53.78], "category_id": 2}, {"id": 12, "bbox": [311.96, 4.03, 94.13, 43.02], "category_id": 2}, {"id": 13, "bbox": [818.23, 389.19, 382.56, 59.15], "category_id": 2}, {"id": 14, "bbox": [22.19, 561.26, 333.48, 78.64], "category_id": 1}, {"id": 15, "bbox": [457.86, 702.42, 215.82, 49.74], "category_id": 2}, {"id": 16, "bbox": [457.86, 224.5, 248.09, 73.94], "category_id": 1}, {"id": 17, "bbox": [1212.22, 301.13, 113.63, 55.79], "category_id": 2}], "caption": "Scheme 6", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 724, 270, 738], "ImageBB": [75, 742, 411, 931]}, "reactions": [{"reactants": [7], "conditions": [12, 0, 2], "products": [4]}, {"reactants": [3, 16], "conditions": [8], "products": [6, 13]}, {"reactants": [14], "conditions": [10, 1, 15], "products": [5]}], "diagram_type": "multiple"}, {"id": 881, "width": 1348, "height": 416, "file_name": "ol503708v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [713.7, 43.3, 204.3, 271.3], "category_id": 1}, {"id": 1, "bbox": [1075.0, 265.9, 52.7, 38.1], "category_id": 3}, {"id": 2, "bbox": [977.6, 38.6, 205.1, 273.7], "category_id": 1}, {"id": 3, "bbox": [164.4, 3.0, 235.6, 245.1], "category_id": 1}, {"id": 4, "bbox": [21.0, 346.0, 1310.0, 70.0], "category_id": 4}, {"id": 5, "bbox": [807.46, 265.68, 52.51, 45.62], "category_id": 3}, {"id": 6, "bbox": [243.0, 258.0, 27.0, 34.0], "category_id": 3}, {"id": 7, "bbox": [469.0, 128.0, 121.0, 37.0], "category_id": 2}, {"id": 8, "bbox": [418.0, 177.0, 201.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [7, 8], "products": [0, 2]}], "corefs": [[3, 6], [0, 5], [2, 1]], "caption": "Table 1. Azide Rearrangement Optimization", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 172, 332, 187], "ImageBB": [82, 193, 419, 297]}, "diagram_type": "single"}, {"id": 431, "width": 2820, "height": 316, "file_name": "op3001355-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1028.0, 0.0, 313.0, 199.0], "category_id": 1}, {"id": 1, "bbox": [402.75, 221.87, 39.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [2286.0, 227.0, 31.0, 39.0], "category_id": 3}, {"id": 3, "bbox": [1911.0, 227.0, 52.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1158.0, 226.0, 38.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [1513.0, 227.0, 51.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [686.0, 136.0, 221.0, 40.0], "category_id": 2}, {"id": 7, "bbox": [700.0, 46.0, 90.0, 46.0], "category_id": 2}, {"id": 8, "bbox": [2225.63, 14.0, 237.27, 190.1], "category_id": 1}, {"id": 9, "bbox": [1456.8, 6.3, 230.5, 198.2], "category_id": 1}, {"id": 10, "bbox": [1773.0, 0.0, 317.4, 212.6], "category_id": 1}, {"id": 11, "bbox": [355.0, 0.0, 229.4, 193.5], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [7, 6], "products": [0, 9, 10, 8]}], "corefs": [[11, 1], [0, 4], [9, 5], [10, 3], [8, 2]], "caption": "Table 2. Reaction conditions and the results for selective bromination of compound 7 to 8", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 463, 596, 478], "ImageBB": [82, 377, 787, 456]}, "diagram_type": "single"}, {"id": 197, "width": 1344, "height": 1024, "file_name": "op0501242-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [629.0, 101.0, 150.0, 44.8], "category_id": 2}, {"id": 1, "bbox": [627.0, 176.0, 137.0, 45.0], "category_id": 2}, {"id": 2, "bbox": [4.0, 370.0, 1340.0, 654.0], "category_id": 4}, {"id": 3, "bbox": [788.0, 6.0, 379.9, 284.0], "category_id": 1}, {"id": 4, "bbox": [176.5, 26.4, 253.9, 209.9], "category_id": 1}, {"id": 5, "bbox": [247.49, 285.75, 56.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [452.2, 29.9, 212.8, 255.2], "category_id": 1}, {"id": 7, "bbox": [956.63, 289.37, 49.1, 40.9], "category_id": 3}, {"id": 8, "bbox": [534.75, 286.0, 59.98, 41.45], "category_id": 3}], "reactions": [{"reactants": [4, 6], "conditions": [0, 1], "products": [3]}], "corefs": [[4, 5], [6, 8], [3, 7]], "caption": "Table 1. Base and solvent screen for the coupling of 2-chloro-4-iodoaniline (1a) with 2,3,4-trifluorobenzoic acid (2a) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 366, 95], "ImageBB": [74, 99, 410, 355]}, "diagram_type": "single"}, {"id": 1009, "width": 1264, "height": 560, "file_name": "ja974106e-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [235.85, 377.22, 36.68, 46.76], "category_id": 3}, {"id": 1, "bbox": [780.91, 100.47, 73.98, 59.39], "category_id": 2}, {"id": 2, "bbox": [826.44, 496.01, 317.42, 56.23], "category_id": 2}, {"id": 3, "bbox": [777.12, 391.12, 94.21, 54.97], "category_id": 2}, {"id": 4, "bbox": [80.94, 502.33, 323.74, 57.67], "category_id": 2}, {"id": 5, "bbox": [889.67, 350.05, 261.15, 121.95], "category_id": 1}, {"id": 6, "bbox": [488.15, 498.53, 285.8, 57.5], "category_id": 2}, {"id": 7, "bbox": [382.55, 407.55, 103.7, 49.91], "category_id": 2}, {"id": 8, "bbox": [83.47, 193.35, 238.38, 164.91], "category_id": 1}, {"id": 9, "bbox": [675.31, 243.26, 52.49, 48.03], "category_id": 3}, {"id": 10, "bbox": [515.97, 74.56, 244.71, 165.55], "category_id": 1}, {"id": 11, "bbox": [777.12, 166.81, 94.84, 55.6], "category_id": 2}, {"id": 12, "bbox": [515.97, 309.61, 237.75, 167.44], "category_id": 1}, {"id": 13, "bbox": [901.05, 74.56, 183.37, 166.81], "category_id": 1}], "caption": "Scheme 1. These", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [314, 442, 409, 456], "ImageBB": [74, 469, 390, 609]}, "reactions": [{"reactants": [8], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [1, 11], "products": [13]}, {"reactants": [8], "conditions": [7], "products": [12]}, {"reactants": [12], "conditions": [3], "products": [5]}], "diagram_type": "tree"}, {"id": 568, "width": 1352, "height": 1672, "file_name": "acs.orglett.5b01077-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.0, 692.0, 1343.0, 980.0], "category_id": 4}, {"id": 1, "bbox": [443.0, 240.0, 87.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [142.0, 237.0, 50.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [599.0, 124.0, 292.0, 52.0], "category_id": 2}, {"id": 4, "bbox": [593.0, 10.0, 342.0, 103.0], "category_id": 2}, {"id": 5, "bbox": [44.0, 296.0, 344.0, 261.0], "category_id": 1}, {"id": 6, "bbox": [362.0, 16.0, 280.0, 195.0], "category_id": 1}, {"id": 7, "bbox": [50.0, 30.0, 242.0, 183.0], "category_id": 1}, {"id": 8, "bbox": [834.0, 3.2, 468.0, 238.8], "category_id": 1}, {"id": 9, "bbox": [894.0, 280.0, 256.1, 126.1], "category_id": 1}, {"id": 10, "bbox": [44.0, 564.0, 380.0, 106.0], "category_id": 3}, {"id": 11, "bbox": [849.0, 242.0, 448.0, 38.0], "category_id": 3}, {"id": 12, "bbox": [517.0, 508.0, 633.0, 165.0], "category_id": 3}, {"id": 13, "bbox": [522.0, 342.0, 324.0, 115.0], "category_id": 3}, {"id": 14, "bbox": [891.51, 383.44, 314.58, 131.44], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [4, 3], "products": [8]}], "corefs": [[7, 2], [6, 1], [8, 11], [5, 10], [5, 13], [5, 12]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 265, 111], "ImageBB": [82, 116, 420, 534]}, "diagram_type": "single"}, {"id": 303, "width": 1348, "height": 1728, "file_name": "ol303154k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [355.0, 328.0, 45.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [680.0, 250.0, 228.0, 41.0], "category_id": 2}, {"id": 2, "bbox": [1120.0, 330.0, 32.0, 34.0], "category_id": 3}, {"id": 3, "bbox": [510.0, 328.0, 45.0, 33.0], "category_id": 3}, {"id": 4, "bbox": [146.0, 330.0, 26.0, 28.0], "category_id": 3}, {"id": 5, "bbox": [2.5, 392.0, 1345.5, 1336.0], "category_id": 4}, {"id": 6, "bbox": [318.0, 87.0, 112.0, 220.1], "category_id": 1}, {"id": 7, "bbox": [908.1, 2.0, 415.9, 321.0], "category_id": 1}, {"id": 8, "bbox": [25.7, 107.1, 262.8, 195.2], "category_id": 1}, {"id": 9, "bbox": [660.0, 187.0, 280.0, 37.0], "category_id": 2}, {"id": 10, "bbox": [456.0, 91.0, 173.0, 166.7], "category_id": 1}], "reactions": [{"reactants": [8, 6, 10], "conditions": [9, 1], "products": [7]}], "corefs": [[8, 4], [6, 0], [10, 3], [7, 2]], "caption": "Table 2. Substrate Scope of Isatinsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 627, 101], "ImageBB": [436, 112, 773, 544]}, "diagram_type": "single"}, {"id": 714, "width": 1352, "height": 392, "file_name": "ol034469l-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [951.06, 323.14, 51.8, 49.8], "category_id": 3}, {"id": 1, "bbox": [642.3, 207.3, 412.6, 182.7], "category_id": 1}, {"id": 2, "bbox": [149.18, 326.26, 43.5, 43.6], "category_id": 3}, {"id": 3, "bbox": [1060.1, 250.0, 277.9, 96.8], "category_id": 2}, {"id": 4, "bbox": [316.4, 142.1, 298.5, 148.7], "category_id": 2}, {"id": 5, "bbox": [28.2, 223.4, 242.5, 154.4], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [4], "products": [1]}], "corefs": [[5, 2], [1, 0]], "caption": "Figure 1. Original observation.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 450, 240, 463], "ImageBB": [73, 340, 411, 438]}, "diagram_type": "single"}, {"id": 413, "width": 1352, "height": 1564, "file_name": "op400278d-Table-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1015.0, 1474.0, 137.0, 62.0], "category_id": 2}, {"id": 1, "bbox": [204.0, 1148.0, 95.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [446.0, 1404.0, 94.0, 65.0], "category_id": 3}, {"id": 3, "bbox": [993.0, 966.0, 107.0, 67.0], "category_id": 3}, {"id": 4, "bbox": [185.0, 894.0, 118.9, 60.6], "category_id": 2}, {"id": 5, "bbox": [202.0, 560.4, 96.7, 58.2], "category_id": 2}, {"id": 6, "bbox": [1040.0, 1408.8, 84.9, 62.2], "category_id": 3}, {"id": 7, "bbox": [207.5, 499.7, 84.4, 49.4], "category_id": 3}, {"id": 8, "bbox": [1105.0, 559.3, 85.6, 75.7], "category_id": 3}, {"id": 9, "bbox": [1087.0, 637.0, 127.0, 52.0], "category_id": 2}, {"id": 10, "bbox": [175.0, 1200.0, 126.0, 77.0], "category_id": 2}, {"id": 11, "bbox": [195.0, 829.0, 104.0, 62.0], "category_id": 3}, {"id": 12, "bbox": [441.5, 43.3, 524.3, 111.5], "category_id": 2}, {"id": 13, "bbox": [282.5, 209.9, 209.9, 58.1], "category_id": 2}, {"id": 14, "bbox": [27.2, 211.6, 195.1, 64.3], "category_id": 2}, {"id": 15, "bbox": [441.5, 1474.1, 116.6, 60.6], "category_id": 2}, {"id": 16, "bbox": [29.1, 980.1, 440.7, 246.2], "category_id": 1}, {"id": 17, "bbox": [37.4, 663.9, 471.2, 244.8], "category_id": 1}, {"id": 18, "bbox": [689.0, 304.5, 627.6, 440.6], "category_id": 1}, {"id": 19, "bbox": [24.3, 333.0, 543.0, 242.1], "category_id": 1}, {"id": 20, "bbox": [920.9, 37.2, 416.7, 189.3], "category_id": 1}, {"id": 21, "bbox": [314.2, 3.6, 170.8, 200.3], "category_id": 1}, {"id": 22, "bbox": [48.2, 6.5, 174.1, 194.0], "category_id": 1}, {"id": 23, "bbox": [203.5, 1236.7, 552.4, 253.7], "category_id": 1}, {"id": 24, "bbox": [774.0, 1038.0, 549.1, 116.7], "category_id": 2}, {"id": 25, "bbox": [759.6, 1203.9, 557.5, 310.3], "category_id": 1}, {"id": 26, "bbox": [504.0, 759.5, 806.1, 277.1], "category_id": 1}, {"id": 27, "bbox": [517.7, 168.2, 350.9, 96.7], "category_id": 2}], "reactions": [{"reactants": [22, 21], "conditions": [12, 27], "products": [20]}], "corefs": [[19, 7], [18, 8], [17, 11], [26, 3], [16, 1], [23, 2], [25, 6]], "caption": "Table 10. Examining the substrate scope of room temperature aryl aminations catalyzed by Pd-PEPPSI- IPentCl-o-picoline (35) ", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 492, 384, 539], "ImageBB": [82, 544, 420, 935]}, "diagram_type": "single"}, {"id": 1296, "width": 1356, "height": 1208, "file_name": "op200312m-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [367.66, 1118.8, 40.02, 46.78], "category_id": 3}, {"id": 1, "bbox": [388.69, 709.93, 43.41, 47.46], "category_id": 3}, {"id": 2, "bbox": [284.9, 827.23, 208.25, 278.01], "category_id": 1}, {"id": 3, "bbox": [234.71, 371.58, 483.65, 351.91], "category_id": 1}, {"id": 4, "bbox": [839.11, 1118.8, 44.09, 46.78], "category_id": 3}, {"id": 5, "bbox": [776.02, 825.2, 206.89, 276.65], "category_id": 1}, {"id": 6, "bbox": [1008.01, 388.53, 347.99, 292.24], "category_id": 1}, {"id": 7, "bbox": [10.18, 834.69, 238.77, 83.4], "category_id": 1}, {"id": 8, "bbox": [42.74, 487.52, 113.96, 60.35], "category_id": 2}, {"id": 9, "bbox": [822.83, 260.37, 46.8, 48.83], "category_id": 3}, {"id": 10, "bbox": [145.84, 262.41, 44.77, 45.43], "category_id": 3}, {"id": 11, "bbox": [669.52, 0.0, 447.7, 244.1], "category_id": 1}, {"id": 12, "bbox": [1107.05, 706.54, 45.45, 50.85], "category_id": 3}, {"id": 13, "bbox": [8.82, 0.0, 447.02, 244.1], "category_id": 1}, {"id": 14, "bbox": [736.0, 352.59, 198.75, 203.42], "category_id": 1}], "caption": "Scheme 1. Strategy of the new synthesis route", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 431, 710, 446], "ImageBB": [448, 452, 787, 754]}, "reactions": [{"reactants": [13], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [8], "products": [3]}, {"reactants": [3], "conditions": [], "products": [14, 6]}, {"reactants": [6], "conditions": [], "products": [7, 2]}, {"reactants": [2], "conditions": [], "products": [5]}], "diagram_type": "multiple"}, {"id": 1198, "width": 1172, "height": 756, "file_name": "ol5028392-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [914.62, 325.34, 104.36, 58.03], "category_id": 2}, {"id": 1, "bbox": [844.85, 201.06, 44.56, 49.24], "category_id": 3}, {"id": 2, "bbox": [799.7, 467.2, 218.1, 56.86], "category_id": 2}, {"id": 3, "bbox": [636.71, 418.54, 100.85, 47.48], "category_id": 2}, {"id": 4, "bbox": [7.62, 378.68, 589.23, 235.06], "category_id": 1}, {"id": 5, "bbox": [739.9, 12.9, 432.1, 231.54], "category_id": 1}, {"id": 6, "bbox": [624.4, 41.62, 96.15, 51.58], "category_id": 2}, {"id": 7, "bbox": [205.79, 202.82, 36.94, 45.14], "category_id": 3}, {"id": 8, "bbox": [678.93, 662.4, 435.03, 91.44], "category_id": 2}, {"id": 9, "bbox": [205.79, 566.85, 46.9, 45.72], "category_id": 3}, {"id": 10, "bbox": [5.28, 0.0, 586.29, 249.13], "category_id": 1}], "caption": "Scheme 1. Mechanism of Ferrous Iron-Promoted Drug Release from Trioxolane 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 392, 125], "ImageBB": [104, 131, 397, 320]}, "reactions": [{"reactants": [10], "conditions": [6], "products": [5]}, {"reactants": [5], "conditions": [0], "products": [2]}], "diagram_type": "tree"}, {"id": 1123, "width": 1080, "height": 748, "file_name": "jo991198c-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [926.56, 489.6, 57.81, 51.88], "category_id": 2}, {"id": 1, "bbox": [1043.26, 531.76, 36.74, 45.93], "category_id": 3}, {"id": 2, "bbox": [635.9, 703.6, 35.12, 43.78], "category_id": 3}, {"id": 3, "bbox": [885.5, 75.12, 57.27, 51.87], "category_id": 2}, {"id": 4, "bbox": [122.1, 458.26, 41.6, 48.64], "category_id": 3}, {"id": 5, "bbox": [0.0, 207.51, 239.88, 258.32], "category_id": 1}, {"id": 6, "bbox": [268.51, 128.62, 60.51, 49.71], "category_id": 2}, {"id": 7, "bbox": [563.5, 267.5, 38.36, 45.39], "category_id": 3}, {"id": 8, "bbox": [247.98, 493.39, 51.33, 51.34], "category_id": 2}, {"id": 9, "bbox": [1029.75, 119.97, 32.42, 50.8], "category_id": 3}, {"id": 10, "bbox": [415.47, 0.0, 398.72, 257.77], "category_id": 1}, {"id": 11, "bbox": [404.66, 415.57, 443.56, 273.44], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 64, 636, 78], "ImageBB": [473, 84, 743, 271]}, "reactions": [{"reactants": [5], "conditions": [6], "products": [10]}, {"reactants": [10], "conditions": [3], "products": [9]}, {"reactants": [5], "conditions": [8], "products": [11]}, {"reactants": [11], "conditions": [0], "products": [1]}], "diagram_type": "tree"}, {"id": 317, "width": 1344, "height": 952, "file_name": "ol3023903-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [492.0, 775.0, 131.0, 41.0], "category_id": 2}, {"id": 1, "bbox": [887.3, 424.0, 365.7, 151.1], "category_id": 2}, {"id": 2, "bbox": [667.0, 189.8, 208.5, 97.7], "category_id": 1}, {"id": 3, "bbox": [65.6, 425.5, 132.6, 110.4], "category_id": 1}, {"id": 4, "bbox": [674.9, 426.0, 151.0, 115.0], "category_id": 1}, {"id": 5, "bbox": [665.0, 662.9, 205.3, 122.1], "category_id": 1}, {"id": 6, "bbox": [685.5, 820.3, 178.8, 115.9], "category_id": 1}, {"id": 7, "bbox": [1263.2, 796.0, 48.8, 44.1], "category_id": 3}, {"id": 8, "bbox": [1266.0, 464.0, 50.0, 47.3], "category_id": 3}, {"id": 9, "bbox": [1263.0, 210.0, 58.0, 49.5], "category_id": 3}, {"id": 10, "bbox": [266.1, 444.0, 183.9, 74.0], "category_id": 2}, {"id": 11, "bbox": [48.4, 190.7, 172.9, 102.3], "category_id": 1}, {"id": 12, "bbox": [369.0, 786.0, 79.0, 62.0], "category_id": 2}, {"id": 13, "bbox": [292.0, 162.0, 172.0, 145.0], "category_id": 2}, {"id": 14, "bbox": [904.0, 764.0, 316.0, 106.0], "category_id": 2}, {"id": 15, "bbox": [497.0, 835.0, 99.0, 44.0], "category_id": 2}, {"id": 16, "bbox": [516.0, 497.0, 87.0, 39.0], "category_id": 2}, {"id": 17, "bbox": [511.0, 448.0, 101.0, 37.0], "category_id": 2}, {"id": 18, "bbox": [519.0, 239.0, 90.0, 47.0], "category_id": 2}, {"id": 19, "bbox": [506.0, 189.0, 106.0, 33.0], "category_id": 2}, {"id": 20, "bbox": [771.0, 343.0, 184.0, 39.0], "category_id": 2}, {"id": 21, "bbox": [900.0, 182.0, 352.0, 104.0], "category_id": 2}, {"id": 22, "bbox": [85.0, 692.0, 230.0, 212.0], "category_id": 1}, {"id": 23, "bbox": [274.0, 572.0, 165.0, 37.5], "category_id": 2}, {"id": 24, "bbox": [30.0, 567.0, 210.0, 45.5], "category_id": 2}, {"id": 25, "bbox": [275.0, 330.0, 236.0, 37.9], "category_id": 2}, {"id": 26, "bbox": [24.0, 321.0, 212.0, 78.1], "category_id": 2}], "reactions": [{"reactants": [11, 13], "conditions": [19, 18], "products": [2]}, {"reactants": [3, 10], "conditions": [17, 16], "products": [4]}, {"reactants": [22, 12], "conditions": [0, 15], "products": [5, 6]}], "corefs": [], "caption": "Figure 1. Synthetic approaches for the construction of C(sp2) CF3 bonds. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 932, 405, 962], "ImageBB": [71, 683, 407, 921]}, "diagram_type": "tree"}, {"id": 520, "width": 1348, "height": 536, "file_name": "jo0109321-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.13, 333.55, 1337.87, 198.24], "category_id": 4}, {"id": 1, "bbox": [711.0, 52.0, 302.0, 144.0], "category_id": 1}, {"id": 2, "bbox": [1055.0, 211.0, 34.0, 37.0], "category_id": 3}, {"id": 3, "bbox": [822.0, 265.0, 251.0, 41.0], "category_id": 2}, {"id": 4, "bbox": [1010.0, 0.0, 223.0, 199.8], "category_id": 1}, {"id": 5, "bbox": [394.0, 145.0, 173.0, 36.8], "category_id": 2}, {"id": 6, "bbox": [127.2, 71.0, 214.8, 132.9], "category_id": 1}, {"id": 7, "bbox": [758.1, 203.0, 34.8, 40.9], "category_id": 3}, {"id": 8, "bbox": [627.0, 95.0, 49.0, 40.0], "category_id": 2}, {"id": 9, "bbox": [397.0, 38.1, 160.0, 88.6], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [9, 5, 8], "products": [1, 4]}], "corefs": [[1, 7], [4, 2]], "caption": "Table 8. Hydroboration of Styrene with BH3-THF in                       THF ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [450, 62, 763, 89], "ImageBB": [439, 99, 776, 233]}, "diagram_type": "single"}, {"id": 308, "width": 1344, "height": 848, "file_name": "ol302863r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.8, 7.5, 490.0, 191.9], "category_id": 1}, {"id": 1, "bbox": [775.7, 3.1, 395.2, 205.4], "category_id": 1}, {"id": 2, "bbox": [955.0, 214.0, 39.0, 33.0], "category_id": 3}, {"id": 3, "bbox": [0.0, 262.0, 1344.0, 378.0], "category_id": 4}, {"id": 4, "bbox": [399.0, 209.0, 37.0, 33.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [], "products": [1]}], "corefs": [[0, 4], [1, 2]], "caption": "Table 1. Anodic Disulfide Bond Formation by Peptide 1", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 154, 371, 167], "ImageBB": [71, 178, 407, 390]}, "diagram_type": "single"}, {"id": 738, "width": 1344, "height": 1276, "file_name": "ol0157003-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [173.7, 265.0, 975.4, 264.9], "category_id": 4}, {"id": 1, "bbox": [487.3, 84.0, 142.7, 58.0], "category_id": 2}, {"id": 2, "bbox": [1090.0, 229.0, 58.0, 45.6], "category_id": 3}, {"id": 3, "bbox": [76.6, 5.0, 377.4, 213.4], "category_id": 1}, {"id": 4, "bbox": [952.0, 0.0, 324.0, 222.0], "category_id": 1}, {"id": 5, "bbox": [773.0, 229.0, 66.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [4.0, 566.0, 1340.0, 710.0], "category_id": 4}, {"id": 7, "bbox": [640.0, 2.0, 314.0, 221.6], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1], "products": [7, 4]}], "corefs": [[7, 5], [4, 2]], "caption": "Table 2. Rearrangements of Anti Acetals 6a-10aa", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 361, 344, 375], "ImageBB": [74, 380, 410, 699]}, "diagram_type": "single"}, {"id": 127, "width": 1348, "height": 676, "file_name": "op900197r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [413.0, 1.0, 90.0, 48.0], "category_id": 2}, {"id": 1, "bbox": [372.0, 84.0, 173.0, 79.0], "category_id": 2}, {"id": 2, "bbox": [10.0, 192.0, 1331.0, 474.0], "category_id": 4}, {"id": 3, "bbox": [719.0, 9.0, 483.0, 171.0], "category_id": 1}, {"id": 4, "bbox": [155.0, 50.0, 50.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [0, 1], "products": [3]}], "corefs": [], "caption": "Table 1. Cyclization/reduction of 18", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 625, 60], "ImageBB": [425, 74, 762, 243]}, "diagram_type": "single"}, {"id": 869, "width": 1356, "height": 2468, "file_name": "jo102193q-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1058.9, 123.53, 61.78, 54.92], "category_id": 3}, {"id": 1, "bbox": [688.18, 0.0, 367.28, 300.9], "category_id": 1}, {"id": 2, "bbox": [355.0, 0.1, 372.8, 305.3], "category_id": 1}, {"id": 3, "bbox": [818.04, 270.37, 50.88, 54.06], "category_id": 3}, {"id": 4, "bbox": [484.09, 273.55, 44.53, 50.88], "category_id": 3}, {"id": 5, "bbox": [274.0, 568.0, 327.0, 263.0], "category_id": 1}, {"id": 6, "bbox": [547.0, 603.0, 601.0, 342.0], "category_id": 1}, {"id": 7, "bbox": [297.0, 1055.0, 510.0, 342.0], "category_id": 1}, {"id": 8, "bbox": [842.0, 945.0, 222.0, 147.0], "category_id": 2}, {"id": 9, "bbox": [253.0, 846.0, 291.0, 153.0], "category_id": 2}, {"id": 10, "bbox": [882.0, 1284.0, 227.0, 162.0], "category_id": 2}, {"id": 11, "bbox": [629.0, 1308.0, 229.0, 62.0], "category_id": 3}, {"id": 12, "bbox": [642.0, 1383.0, 198.0, 53.0], "category_id": 3}, {"id": 13, "bbox": [898.0, 885.0, 71.0, 43.0], "category_id": 3}, {"id": 14, "bbox": [202.0, 814.0, 55.0, 47.0], "category_id": 3}, {"id": 15, "bbox": [224.79, 126.96, 37.76, 48.06], "category_id": 3}, {"id": 16, "bbox": [0.0, 1584.0, 1356.0, 884.0], "category_id": 4}], "reactions": [{"reactants": [15], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [0]}, {"reactants": [14], "conditions": [5, 9], "products": [6]}, {"reactants": [6], "conditions": [8], "products": [7]}, {"reactants": [11], "conditions": [10], "products": [12]}], "corefs": [[2, 4], [1, 3], [6, 13], [7, 11], [7, 12]], "caption": "Figure 2. Anti-proliferative activity of compound 2 against HeLa cells incubated with di\ufb00erent concentrations at di\ufb00erent times (24 96 h). The data are expressed as a percentage of the control MTT reduction (always taken as 100%) and represent the average ( SEM (n = 3). * denotes more signi\ufb01cant value (P < 0.05).13 ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 748, 405, 817], "ImageBB": [71, 117, 410, 734]}, "diagram_type": "tree"}, {"id": 680, "width": 1344, "height": 988, "file_name": "ol401535k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 287.0, 1338.0, 701.0], "category_id": 4}, {"id": 1, "bbox": [503.0, 90.0, 344.0, 98.1], "category_id": 2}, {"id": 2, "bbox": [38.0, 4.0, 425.0, 164.4], "category_id": 1}, {"id": 3, "bbox": [881.0, 4.0, 431.0, 163.9], "category_id": 1}, {"id": 4, "bbox": [220.0, 182.0, 65.0, 54.0], "category_id": 3}, {"id": 5, "bbox": [518.0, 27.0, 303.0, 61.0], "category_id": 2}, {"id": 6, "bbox": [1061.0, 180.0, 67.0, 58.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5, 1], "products": [3]}], "corefs": [[2, 4], [3, 6]], "caption": "Table 1. Optimization of C H Oxygenation with Carbamate 1aa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 264, 405, 280], "ImageBB": [71, 291, 407, 538]}, "diagram_type": "single"}, {"id": 989, "width": 1356, "height": 1712, "file_name": "ja207331m-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [725.17, 1440.8, 215.8, 78.1], "category_id": 2}, {"id": 1, "bbox": [943.02, 6.25, 267.18, 207.58], "category_id": 1}, {"id": 2, "bbox": [1054.01, 211.78, 49.32, 39.04], "category_id": 3}, {"id": 3, "bbox": [83.94, 382.36, 279.51, 123.31], "category_id": 2}, {"id": 4, "bbox": [490.87, 489.23, 43.16, 39.05], "category_id": 3}, {"id": 5, "bbox": [507.32, 583.77, 339.11, 256.9], "category_id": 1}, {"id": 6, "bbox": [901.92, 725.58, 295.95, 84.26], "category_id": 2}, {"id": 7, "bbox": [548.87, 212.39, 50.52, 35.97], "category_id": 3}, {"id": 8, "bbox": [1108.02, 1628.93, 52.23, 39.39], "category_id": 3}, {"id": 9, "bbox": [253.46, 1258.95, 463.24, 357.99], "category_id": 1}, {"id": 10, "bbox": [125.02, 20.55, 279.14, 177.28], "category_id": 1}, {"id": 11, "bbox": [911.93, 530.13, 276.58, 154.16], "category_id": 1}, {"id": 12, "bbox": [125.02, 712.55, 306.54, 127.61], "category_id": 2}, {"id": 13, "bbox": [12.84, 1389.13, 275.72, 45.39], "category_id": 2}, {"id": 14, "bbox": [83.06, 286.05, 256.88, 90.78], "category_id": 2}, {"id": 15, "bbox": [125.02, 617.48, 258.59, 90.79], "category_id": 2}, {"id": 16, "bbox": [1031.81, 670.58, 43.67, 35.97], "category_id": 3}, {"id": 17, "bbox": [911.93, 1255.52, 443.55, 361.42], "category_id": 1}, {"id": 18, "bbox": [833.16, 861.57, 446.11, 363.98], "category_id": 1}, {"id": 19, "bbox": [709.0, 383.68, 200.36, 40.25], "category_id": 2}, {"id": 20, "bbox": [355.35, 262.07, 314.26, 228.66], "category_id": 1}, {"id": 21, "bbox": [458.11, 7.71, 233.76, 198.69], "category_id": 1}, {"id": 22, "bbox": [648.2, 827.31, 53.95, 41.11], "category_id": 3}, {"id": 23, "bbox": [519.76, 951.49, 283.43, 89.07], "category_id": 2}, {"id": 24, "bbox": [709.0, 1391.7, 250.03, 40.25], "category_id": 2}, {"id": 25, "bbox": [1109.73, 490.73, 46.24, 37.69], "category_id": 3}, {"id": 26, "bbox": [976.15, 250.08, 310.83, 261.21], "category_id": 1}, {"id": 27, "bbox": [460.68, 1627.21, 56.51, 41.11], "category_id": 3}, {"id": 28, "bbox": [519.76, 1044.84, 303.12, 85.65], "category_id": 2}, {"id": 29, "bbox": [13.7, 1439.66, 282.57, 79.64], "category_id": 2}, {"id": 30, "bbox": [77.92, 861.57, 411.87, 362.27], "category_id": 1}, {"id": 31, "bbox": [1031.81, 1227.26, 50.52, 41.97], "category_id": 3}, {"id": 32, "bbox": [709.0, 109.62, 163.54, 36.83], "category_id": 2}, {"id": 33, "bbox": [250.03, 212.39, 50.52, 41.11], "category_id": 3}, {"id": 34, "bbox": [709.0, 383.68, 200.36, 40.25], "category_id": 2}, {"id": 35, "bbox": [648.2, 288.62, 317.68, 87.35], "category_id": 2}, {"id": 36, "bbox": [709.0, 0.0, 160.12, 105.34], "category_id": 2}, {"id": 37, "bbox": [253.46, 1227.26, 54.8, 45.39], "category_id": 3}], "caption": "Scheme 3. Synthesis of the Right Fragment of Psymberin", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 756, 107], "ImageBB": [436, 117, 775, 545]}, "reactions": [{"reactants": [10, 21], "conditions": [36, 32], "products": [1]}, {"reactants": [1], "conditions": [14, 3], "products": [20]}, {"reactants": [20], "conditions": [35, 34], "products": [26]}, {"reactants": [26], "conditions": [15, 12], "products": [5]}, {"reactants": [5], "conditions": [11, 6], "products": [30]}, {"reactants": [30], "conditions": [23, 28], "products": [18]}, {"reactants": [18], "conditions": [13, 29], "products": [9]}, {"reactants": [9], "conditions": [24, 0], "products": [17]}], "diagram_type": "multiple"}, {"id": 1193, "width": 1356, "height": 888, "file_name": "ol501019y-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [259.03, 303.8, 58.63, 46.91], "category_id": 2}, {"id": 1, "bbox": [974.77, 539.24, 161.45, 135.66], "category_id": 1}, {"id": 2, "bbox": [345.27, 416.47, 78.69, 55.62], "category_id": 2}, {"id": 3, "bbox": [548.1, 183.82, 241.49, 60.36], "category_id": 2}, {"id": 4, "bbox": [823.5, 676.26, 200.11, 58.33], "category_id": 2}, {"id": 5, "bbox": [583.37, 436.14, 139.06, 409.69], "category_id": 1}, {"id": 6, "bbox": [430.07, 89.53, 202.14, 61.05], "category_id": 2}, {"id": 7, "bbox": [666.13, 789.53, 42.73, 50.19], "category_id": 3}, {"id": 8, "bbox": [139.06, 643.7, 350.02, 129.55], "category_id": 1}, {"id": 9, "bbox": [824.86, 374.42, 390.05, 128.87], "category_id": 1}, {"id": 10, "bbox": [986.06, 271.82, 55.43, 43.71], "category_id": 2}, {"id": 11, "bbox": [875.06, 107.85, 152.44, 128.85], "category_id": 1}, {"id": 12, "bbox": [185.19, 208.8, 205.53, 52.2], "category_id": 2}, {"id": 13, "bbox": [960.53, 492.44, 35.27, 49.51], "category_id": 3}, {"id": 14, "bbox": [554.88, 0.0, 184.51, 58.33], "category_id": 2}], "caption": "Scheme 2. Plausible Mechanism for the Homecoupling", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 542, 759, 557], "ImageBB": [448, 563, 787, 785]}, "reactions": [{"reactants": [5], "conditions": [], "products": [2, 8]}, {"reactants": [12, 0, 2], "conditions": [], "products": [3]}, {"reactants": [14], "conditions": [6], "products": [3]}, {"reactants": [3, 11], "conditions": [], "products": [10, 9]}, {"reactants": [9, 1], "conditions": [], "products": [4, 5]}], "diagram_type": "graph"}, {"id": 1200, "width": 1356, "height": 1156, "file_name": "ol502998n-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [161.44, 897.07, 248.28, 155.4], "category_id": 1}, {"id": 1, "bbox": [851.99, 42.75, 215.72, 179.14], "category_id": 1}, {"id": 2, "bbox": [851.99, 428.18, 219.11, 206.29], "category_id": 1}, {"id": 3, "bbox": [478.91, 451.93, 52.23, 171.0], "category_id": 1}, {"id": 4, "bbox": [565.06, 87.54, 200.11, 48.85], "category_id": 2}, {"id": 5, "bbox": [561.66, 981.22, 275.41, 116.03], "category_id": 2}, {"id": 6, "bbox": [478.91, 41.39, 56.3, 173.04], "category_id": 1}, {"id": 7, "bbox": [161.81, 344.16, 227.59, 145.72], "category_id": 1}, {"id": 8, "bbox": [476.19, 887.57, 52.91, 173.72], "category_id": 1}, {"id": 9, "bbox": [134.99, 825.15, 864.88, 48.85], "category_id": 2}, {"id": 10, "bbox": [637.64, 487.89, 61.73, 42.75], "category_id": 2}, {"id": 11, "bbox": [136.35, 236.82, 1087.37, 56.32], "category_id": 2}, {"id": 12, "bbox": [161.44, 629.04, 241.49, 152.0], "category_id": 1}, {"id": 13, "bbox": [447.03, 634.47, 395.47, 50.21], "category_id": 2}, {"id": 14, "bbox": [851.99, 863.15, 286.26, 249.03], "category_id": 1}, {"id": 15, "bbox": [134.99, 0.0, 632.89, 43.43], "category_id": 2}, {"id": 16, "bbox": [147.2, 61.07, 267.94, 153.36], "category_id": 1}, {"id": 17, "bbox": [637.64, 900.47, 99.04, 70.57], "category_id": 2}, {"id": 18, "bbox": [158.3, 484.4, 200.8, 154.7], "category_id": 1}], "caption": "Scheme 1. Indole Synthesis via C\u2212H Activation and N\u2212N Cleavage ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 493, 771, 523], "ImageBB": [448, 530, 787, 819]}, "reactions": [{"reactants": [16, 6], "conditions": [4], "products": [1]}, {"reactants": [7, 3], "conditions": [10], "products": [2]}, {"reactants": [18, 3], "conditions": [10], "products": [2]}, {"reactants": [12, 3], "conditions": [10], "products": [2]}, {"reactants": [0, 8], "conditions": [17, 5], "products": [14]}], "diagram_type": "multiple"}, {"id": 681, "width": 1228, "height": 1252, "file_name": "ol401443a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [252.0, 223.0, 45.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [978.0, 225.0, 52.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [475.0, 207.0, 178.0, 71.0], "category_id": 2}, {"id": 3, "bbox": [0.0, 330.0, 1228.0, 922.0], "category_id": 4}, {"id": 4, "bbox": [794.0, 0.0, 205.1, 284.7], "category_id": 1}, {"id": 5, "bbox": [197.0, 63.6, 154.9, 161.4], "category_id": 1}, {"id": 6, "bbox": [383.0, 7.0, 375.0, 187.5], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [6, 2], "products": [4]}], "corefs": [[5, 0], [4, 1]], "caption": "Table 3. Synthesis of R-Azido-peroxides from Ketonesa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 732, 103], "ImageBB": [451, 112, 758, 425]}, "diagram_type": "single"}, {"id": 930, "width": 2820, "height": 1260, "file_name": "acs.oprd.5b00209-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2065.27, 38.06, 362.55, 131.11], "category_id": 1}, {"id": 1, "bbox": [2254.31, 631.57, 84.64, 66.26], "category_id": 3}, {"id": 2, "bbox": [1599.74, 128.29, 159.41, 57.8], "category_id": 2}, {"id": 3, "bbox": [292.02, 407.42, 397.81, 143.79], "category_id": 2}, {"id": 4, "bbox": [1747.86, 642.85, 77.59, 62.02], "category_id": 3}, {"id": 5, "bbox": [512.09, 25.38, 404.87, 66.25], "category_id": 2}, {"id": 6, "bbox": [359.73, 979.78, 119.91, 67.66], "category_id": 2}, {"id": 7, "bbox": [2086.43, 473.68, 420.39, 128.28], "category_id": 1}, {"id": 8, "bbox": [732.16, 446.89, 397.81, 184.68], "category_id": 1}, {"id": 9, "bbox": [933.57, 256.86, 274.35, 44.66], "category_id": 3}, {"id": 10, "bbox": [1352.53, 205.82, 129.73, 165.88], "category_id": 2}, {"id": 11, "bbox": [1892.71, 254.73, 340.28, 59.55], "category_id": 3}, {"id": 12, "bbox": [1061.18, 1101.16, 233.93, 112.71], "category_id": 2}, {"id": 13, "bbox": [306.12, 800.74, 235.59, 131.1], "category_id": 2}, {"id": 14, "bbox": [2320.61, 198.77, 214.43, 174.81], "category_id": 2}, {"id": 15, "bbox": [1230.14, 427.15, 210.19, 114.19], "category_id": 2}, {"id": 16, "bbox": [606.6, 128.29, 158.0, 63.44], "category_id": 2}, {"id": 17, "bbox": [1709.77, 824.7, 393.59, 208.65], "category_id": 1}, {"id": 18, "bbox": [1582.81, 441.25, 421.8, 193.14], "category_id": 1}, {"id": 19, "bbox": [933.9, 190.3, 336.0, 64.2], "category_id": 3}, {"id": 20, "bbox": [897.21, 649.89, 83.23, 63.44], "category_id": 3}, {"id": 21, "bbox": [1285.15, 797.92, 362.55, 131.1], "category_id": 2}, {"id": 22, "bbox": [1052.39, 43.7, 393.58, 125.47], "category_id": 1}, {"id": 23, "bbox": [1389.54, 964.27, 126.97, 67.67], "category_id": 2}, {"id": 24, "bbox": [1285.15, 587.87, 150.95, 59.2], "category_id": 2}, {"id": 25, "bbox": [417.57, 590.68, 107.21, 64.85], "category_id": 2}, {"id": 26, "bbox": [1880.47, 1046.03, 53.61, 52.16], "category_id": 3}, {"id": 27, "bbox": [310.36, 0.0, 187.62, 208.64], "category_id": 1}, {"id": 28, "bbox": [1498.17, 22.56, 385.12, 70.48], "category_id": 2}, {"id": 29, "bbox": [732.16, 851.49, 411.92, 190.31], "category_id": 1}, {"id": 30, "bbox": [640.46, 1151.76, 271.14, 62.04], "category_id": 3}, {"id": 31, "bbox": [1891.76, 190.3, 352.67, 55.3], "category_id": 3}, {"id": 32, "bbox": [378.9, 243.9, 54.1, 57.7], "category_id": 3}, {"id": 33, "bbox": [644.69, 1097.5, 318.51, 56.0], "category_id": 3}], "caption": "Scheme 3. Synthesis of Amino Diol 4 though Sharpless Epoxidation", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 465, 110], "ImageBB": [82, 116, 787, 431]}, "reactions": [{"reactants": [27], "conditions": [5, 16], "products": [22]}, {"reactants": [22], "conditions": [28, 2], "products": [0]}, {"reactants": [0], "conditions": [3, 25], "products": [8]}, {"reactants": [8], "conditions": [15, 24], "products": [18, 7]}, {"reactants": [18, 7], "conditions": [13, 6], "products": [29]}, {"reactants": [29], "conditions": [21, 23], "products": [17]}, {"reactants": [19], "conditions": [10], "products": [9]}, {"reactants": [31], "conditions": [14], "products": [11]}, {"reactants": [33], "conditions": [12], "products": [30]}], "diagram_type": "multiple"}, {"id": 442, "width": 1348, "height": 640, "file_name": "op200234j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [26.0, 1.0, 322.0, 241.0], "category_id": 1}, {"id": 1, "bbox": [628.0, 131.0, 163.0, 58.0], "category_id": 2}, {"id": 2, "bbox": [1040.0, 4.0, 267.0, 148.0], "category_id": 1}, {"id": 3, "bbox": [417.0, 26.0, 587.0, 66.0], "category_id": 2}, {"id": 4, "bbox": [83.0, 258.0, 237.0, 59.0], "category_id": 3}, {"id": 5, "bbox": [0.0, 339.0, 1345.0, 301.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [3, 1], "products": [2]}], "corefs": [], "caption": "Table 2. Hydrogenation of methyl (R)-lactate", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 718, 339, 733], "ImageBB": [82, 739, 419, 899]}, "diagram_type": "single"}, {"id": 373, "width": 1352, "height": 392, "file_name": "ol1022036-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1145.0, 175.16, 84.0, 46.7], "category_id": 3}, {"id": 1, "bbox": [0.0, 249.0, 1352.0, 143.0], "category_id": 4}, {"id": 2, "bbox": [665.0, 0.0, 259.0, 56.0], "category_id": 2}, {"id": 3, "bbox": [672.0, 101.0, 252.0, 104.0], "category_id": 2}, {"id": 4, "bbox": [452.0, 32.1, 144.1, 62.8], "category_id": 1}, {"id": 5, "bbox": [31.0, 29.0, 289.7, 66.8], "category_id": 1}, {"id": 6, "bbox": [1040.2, 0.0, 286.8, 131.6], "category_id": 1}, {"id": 7, "bbox": [468.0, 154.0, 93.0, 45.8], "category_id": 3}, {"id": 8, "bbox": [152.0, 158.0, 86.0, 46.8], "category_id": 3}], "reactions": [{"reactants": [5, 4], "conditions": [2, 3], "products": [6]}], "corefs": [[5, 8], [4, 7], [6, 0]], "caption": "Table 1. Microwave-Assisted One-Pot TMS-Deprotection of Compounds 1a-g and Cycloaddition with Azides 2a-c to Give Triazoles 3a-i ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 703, 390, 744], "ImageBB": [58, 753, 396, 851]}, "diagram_type": "single"}, {"id": 1150, "width": 1352, "height": 1168, "file_name": "ol048585f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [75.07, 175.78, 198.85, 58.15], "category_id": 2}, {"id": 1, "bbox": [33.14, 780.89, 254.3, 233.93], "category_id": 2}, {"id": 2, "bbox": [899.53, 36.51, 424.06, 307.62], "category_id": 1}, {"id": 3, "bbox": [769.0, 214.32, 93.33, 52.06], "category_id": 2}, {"id": 4, "bbox": [300.97, 413.77, 442.33, 306.95], "category_id": 1}, {"id": 5, "bbox": [899.53, 1054.03, 46.67, 54.09], "category_id": 3}, {"id": 6, "bbox": [301.65, 795.09, 465.32, 315.06], "category_id": 1}, {"id": 7, "bbox": [438.94, 300.86, 40.58, 49.36], "category_id": 3}, {"id": 8, "bbox": [403.77, 1055.38, 38.56, 52.74], "category_id": 3}, {"id": 9, "bbox": [258.36, 79.78, 187.35, 96.0], "category_id": 2}, {"id": 10, "bbox": [899.53, 660.54, 35.85, 52.74], "category_id": 3}, {"id": 11, "bbox": [850.83, 401.6, 441.65, 313.03], "category_id": 1}, {"id": 12, "bbox": [724.36, 967.49, 96.04, 51.39], "category_id": 2}, {"id": 13, "bbox": [32.46, 1052.68, 334.12, 62.88], "category_id": 2}, {"id": 14, "bbox": [129.18, 299.51, 52.08, 50.71], "category_id": 3}, {"id": 15, "bbox": [108.21, 624.04, 96.72, 56.11], "category_id": 2}, {"id": 16, "bbox": [47.34, 420.53, 226.58, 179.84], "category_id": 2}, {"id": 17, "bbox": [726.39, 0.0, 182.61, 181.19], "category_id": 2}, {"id": 18, "bbox": [853.54, 793.74, 449.09, 314.38], "category_id": 1}, {"id": 19, "bbox": [411.89, 43.27, 366.58, 288.02], "category_id": 1}, {"id": 20, "bbox": [707.45, 796.44, 128.5, 148.06], "category_id": 2}, {"id": 21, "bbox": [920.5, 299.51, 43.28, 50.03], "category_id": 3}], "caption": "Scheme 1. Synthesis of hin(2S4R7R9R) Monomer", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [106, 75, 376, 88], "ImageBB": [73, 93, 411, 385]}, "reactions": [{"reactants": [0], "conditions": [5], "products": [19]}, {"reactants": [19], "conditions": [17, 3], "products": [2]}, {"reactants": [2], "conditions": [16, 15], "products": [4]}, {"reactants": [4], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [1, 13], "products": [6]}, {"reactants": [6], "conditions": [20, 12], "products": [18]}], "diagram_type": "multiple"}, {"id": 687, "width": 1476, "height": 3808, "file_name": "ol4012794-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [519.0, 63.0, 175.0, 154.0], "category_id": 1}, {"id": 1, "bbox": [162.0, 53.0, 289.0, 212.0], "category_id": 1}, {"id": 2, "bbox": [710.0, 39.0, 389.0, 90.0], "category_id": 2}, {"id": 3, "bbox": [834.0, 153.0, 111.0, 36.0], "category_id": 2}, {"id": 4, "bbox": [1241.0, 265.0, 37.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [283.0, 271.0, 38.0, 34.0], "category_id": 3}, {"id": 6, "bbox": [584.0, 211.0, 32.0, 32.0], "category_id": 3}, {"id": 7, "bbox": [102.0, 3552.0, 1374.0, 256.0], "category_id": 2}, {"id": 8, "bbox": [118.0, 3129.0, 1351.0, 375.0], "category_id": 2}, {"id": 9, "bbox": [133.0, 319.0, 1343.0, 2755.0], "category_id": 4}, {"id": 10, "bbox": [1119.0, 0.0, 321.0, 259.0], "category_id": 1}], "reactions": [{"reactants": [1, 0], "conditions": [2, 3], "products": [10]}], "corefs": [[1, 5], [0, 6], [10, 4]], "caption": "Table 1. Reaction of Phenylphosphinic Acids 1 with Alkynes 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 771, 101], "ImageBB": [404, 108, 773, 1060]}, "diagram_type": "single"}, {"id": 971, "width": 1212, "height": 1112, "file_name": "ja040054z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [130.96, 1055.59, 56.39, 55.78], "category_id": 3}, {"id": 1, "bbox": [0.0, 591.15, 135.81, 100.04], "category_id": 2}, {"id": 2, "bbox": [0.0, 181.29, 375.3, 323.77], "category_id": 1}, {"id": 3, "bbox": [546.89, 726.36, 506.86, 319.53], "category_id": 1}, {"id": 4, "bbox": [328.62, 479.59, 140.05, 101.26], "category_id": 2}, {"id": 5, "bbox": [503.84, 180.68, 524.45, 326.8], "category_id": 1}, {"id": 6, "bbox": [637.22, 548.11, 138.24, 101.25], "category_id": 2}, {"id": 7, "bbox": [391.67, 275.27, 129.14, 61.84], "category_id": 2}, {"id": 8, "bbox": [779.71, 517.79, 55.78, 56.99], "category_id": 3}, {"id": 9, "bbox": [399.55, 361.97, 97.62, 48.5], "category_id": 2}, {"id": 10, "bbox": [117.62, 515.36, 50.33, 60.03], "category_id": 3}, {"id": 11, "bbox": [746.97, 1057.41, 56.99, 54.56], "category_id": 3}, {"id": 12, "bbox": [391.03, 902.45, 129.49, 98.78], "category_id": 2}, {"id": 13, "bbox": [0.0, 731.82, 387.3, 317.7], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 125, 76], "ImageBB": [124, 35, 427, 313]}, "reactions": [{"reactants": [2], "conditions": [7, 9], "products": [5]}, {"reactants": [2], "conditions": [4], "products": [3]}, {"reactants": [2], "conditions": [1], "products": [13]}, {"reactants": [13], "conditions": [6], "products": [5]}], "diagram_type": "graph"}, {"id": 760, "width": 1412, "height": 1688, "file_name": "jo9716338-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [235.0, 1048.0, 128.0, 64.0], "category_id": 3}, {"id": 1, "bbox": [982.0, 1051.0, 83.0, 55.0], "category_id": 3}, {"id": 2, "bbox": [698.0, 872.0, 89.0, 67.0], "category_id": 2}, {"id": 3, "bbox": [976.0, 1627.0, 96.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [261.0, 1624.0, 86.0, 64.0], "category_id": 3}, {"id": 5, "bbox": [210.0, 1202.0, 83.0, 89.0], "category_id": 2}, {"id": 6, "bbox": [309.0, 636.0, 197.2, 70.0], "category_id": 2}, {"id": 7, "bbox": [234.9, 1404.3, 291.4, 185.4], "category_id": 1}, {"id": 8, "bbox": [1017.1, 1192.8, 219.4, 71.1], "category_id": 2}, {"id": 9, "bbox": [941.6, 1195.0, 66.4, 76.9], "category_id": 2}, {"id": 10, "bbox": [300.4, 1208.0, 209.5, 80.0], "category_id": 2}, {"id": 11, "bbox": [225.1, 243.0, 295.2, 195.9], "category_id": 1}, {"id": 12, "bbox": [232.1, 820.9, 294.6, 193.7], "category_id": 1}, {"id": 13, "bbox": [251.0, 473.0, 83.9, 64.0], "category_id": 3}, {"id": 14, "bbox": [951.4, 793.9, 299.8, 238.3], "category_id": 1}, {"id": 15, "bbox": [953.5, 1374.2, 290.1, 229.3], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [6], "products": [12]}, {"reactants": [12], "conditions": [2], "products": [14]}, {"reactants": [12], "conditions": [5, 10], "products": [7]}, {"reactants": [14], "conditions": [9, 8], "products": [15]}], "corefs": [[11, 13], [12, 0], [14, 1], [7, 4], [15, 3]], "caption": "Table 1. Kinetic Data for the Reaction of Bromide 4  with (TMS)3SiH in Toluene or Benzene at Various                   Temperaturesa ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [453, 469, 761, 506], "ImageBB": [424, 35, 777, 457]}, "diagram_type": "tree"}, {"id": 737, "width": 1344, "height": 1104, "file_name": "ol015948s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [843.0, 115.0, 432.0, 172.6], "category_id": 1}, {"id": 1, "bbox": [76.0, 55.5, 364.0, 229.8], "category_id": 1}, {"id": 2, "bbox": [2.5, 342.2, 1338.5, 761.8], "category_id": 4}, {"id": 3, "bbox": [533.0, 178.0, 238.0, 55.0], "category_id": 2}, {"id": 4, "bbox": [465.0, 5.0, 372.0, 147.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [4, 3], "products": [0]}], "corefs": [], "caption": "Table 1. Organosilane Reductants for Catalytic Reductive Amination ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 380, 104], "ImageBB": [74, 116, 410, 392]}, "diagram_type": "single"}, {"id": 704, "width": 1280, "height": 820, "file_name": "ol035681s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [438.0, 61.0, 157.0, 61.6], "category_id": 1}, {"id": 1, "bbox": [37.4, 162.3, 316.2, 129.0], "category_id": 3}, {"id": 2, "bbox": [1073.0, 181.0, 35.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [652.0, 0.0, 265.0, 100.0], "category_id": 2}, {"id": 4, "bbox": [1014.8, 4.2, 226.5, 182.3], "category_id": 1}, {"id": 5, "bbox": [8.0, 313.0, 1256.0, 507.0], "category_id": 4}, {"id": 6, "bbox": [90.0, 1.1, 217.0, 156.6], "category_id": 1}], "reactions": [{"reactants": [6, 0], "conditions": [3], "products": [4]}], "corefs": [[6, 1], [4, 2]], "caption": "Table 2. Comparison of Cu(II)-Catalyzed Methods", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 710, 89], "ImageBB": [448, 94, 768, 299]}, "diagram_type": "single"}, {"id": 552, "width": 1352, "height": 676, "file_name": "acs.orglett.5b02680-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [556.0, 177.0, 274.0, 46.0], "category_id": 2}, {"id": 1, "bbox": [470.0, 336.0, 424.0, 247.0], "category_id": 1}, {"id": 2, "bbox": [864.0, 9.0, 399.0, 251.0], "category_id": 1}, {"id": 3, "bbox": [91.0, 29.0, 435.0, 230.0], "category_id": 1}, {"id": 4, "bbox": [198.0, 307.0, 218.0, 93.0], "category_id": 2}, {"id": 5, "bbox": [559.0, 63.0, 216.0, 92.0], "category_id": 2}, {"id": 6, "bbox": [936.0, 309.0, 178.0, 90.0], "category_id": 2}, {"id": 7, "bbox": [629.0, 583.0, 78.0, 39.0], "category_id": 3}, {"id": 8, "bbox": [278.0, 234.0, 77.0, 40.0], "category_id": 3}, {"id": 9, "bbox": [951.0, 233.0, 76.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [5, 0], "products": [2]}, {"reactants": [3], "conditions": [4], "products": [1]}, {"reactants": [1], "conditions": [6], "products": [2]}], "corefs": [[3, 8], [1, 7], [2, 9]], "caption": "Table 2. Substituents and Yields for DBNs 5a\u2212d", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 716, 347, 731], "ImageBB": [82, 544, 420, 713]}, "diagram_type": "graph"}, {"id": 826, "width": 1340, "height": 2404, "file_name": "jo4007046-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [712.0, 765.0, 435.0, 126.0], "category_id": 1}, {"id": 1, "bbox": [160.0, 765.0, 379.0, 123.0], "category_id": 1}, {"id": 2, "bbox": [933.0, 477.0, 379.0, 108.0], "category_id": 1}, {"id": 3, "bbox": [459.0, 480.0, 399.0, 123.0], "category_id": 1}, {"id": 4, "bbox": [24.0, 462.0, 397.0, 144.0], "category_id": 1}, {"id": 5, "bbox": [1118.0, 193.0, 93.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [629.0, 184.0, 284.0, 62.0], "category_id": 2}, {"id": 7, "bbox": [978.0, 2.0, 154.0, 350.0], "category_id": 1}, {"id": 8, "bbox": [436.0, 15.0, 128.0, 291.0], "category_id": 1}, {"id": 9, "bbox": [988.0, 1496.0, 221.0, 430.0], "category_id": 1}, {"id": 10, "bbox": [780.0, 1966.0, 226.0, 435.0], "category_id": 1}, {"id": 11, "bbox": [411.0, 1966.0, 216.0, 432.0], "category_id": 1}, {"id": 12, "bbox": [173.0, 1316.0, 65.0, 49.0], "category_id": 3}, {"id": 13, "bbox": [871.0, 1376.0, 107.0, 48.0], "category_id": 3}, {"id": 14, "bbox": [476.0, 1284.0, 287.0, 56.0], "category_id": 2}, {"id": 15, "bbox": [210.0, 1113.0, 126.0, 287.0], "category_id": 1}, {"id": 16, "bbox": [818.0, 1097.0, 356.0, 326.0], "category_id": 1}, {"id": 17, "bbox": [544.0, 636.0, 281.0, 65.0], "category_id": 3}, {"id": 18, "bbox": [621.09, 87.26, 69.79, 62.8], "category_id": 2}, {"id": 19, "bbox": [394.3, 1186.33, 76.76, 62.8], "category_id": 2}, {"id": 20, "bbox": [175.0, 1486.0, 226.1, 436.4], "category_id": 1}, {"id": 21, "bbox": [557.0, 1863.0, 178.6, 58.0], "category_id": 3}, {"id": 22, "bbox": [125.0, 1870.0, 157.7, 51.5], "category_id": 3}, {"id": 23, "bbox": [286.0, 2284.51, 173.6, 48.0], "category_id": 3}, {"id": 24, "bbox": [1048.0, 2271.51, 178.1, 47.5], "category_id": 3}, {"id": 25, "bbox": [948.0, 1865.0, 150.7, 57.5], "category_id": 3}, {"id": 26, "bbox": [711.2, 67.0, 251.8, 91.0], "category_id": 1}, {"id": 27, "bbox": [106.7, 36.9, 275.8, 252.1], "category_id": 4}, {"id": 28, "bbox": [267.0, 916.0, 134.7, 46.0], "category_id": 3}, {"id": 29, "bbox": [1024.0, 638.0, 160.0, 53.0], "category_id": 3}, {"id": 30, "bbox": [867.0, 924.0, 159.2, 48.5], "category_id": 3}, {"id": 31, "bbox": [77.0, 646.0, 301.0, 53.0], "category_id": 3}, {"id": 32, "bbox": [487.7, 1179.0, 323.1, 73.0], "category_id": 1}, {"id": 33, "bbox": [582.0, 1496.0, 228.0, 427.7], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [18, 26, 6], "products": [7]}, {"reactants": [15], "conditions": [19, 32, 14], "products": [16]}], "corefs": [[7, 5], [4, 31], [3, 17], [2, 29], [1, 28], [0, 30], [15, 12], [16, 13], [20, 22], [33, 21], [9, 25], [11, 23], [10, 24]], "caption": "Table 2. Synthesis of (a) Allylbenzenes 6\u221210 and (b) \u03b3- Benzyl Lactones 11\u221215a ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 400, 125], "ImageBB": [83, 131, 418, 732]}, "diagram_type": "multiple"}, {"id": 533, "width": 1348, "height": 1788, "file_name": "jo000745n-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [236.0, 94.0, 283.0, 62.0], "category_id": 3}, {"id": 1, "bbox": [568.0, 133.0, 189.0, 109.0], "category_id": 2}, {"id": 2, "bbox": [574.0, 44.0, 170.0, 65.0], "category_id": 2}, {"id": 3, "bbox": [885.0, 230.0, 116.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [793.0, 25.0, 315.0, 208.0], "category_id": 1}, {"id": 5, "bbox": [15.0, 301.0, 1322.0, 1348.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [2, 1], "products": [4]}], "corefs": [[4, 3]], "caption": "Table 2. Preparation of Thioureas 17-27 from         Ethylenediamines 7, 8R, and 8S ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [470, 64, 744, 89], "ImageBB": [439, 90, 776, 537]}, "diagram_type": "single"}, {"id": 1249, "width": 984, "height": 1740, "file_name": "op049803n-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 115.77, 414.24, 310.23], "category_id": 1}, {"id": 1, "bbox": [0.0, 1399.66, 389.87, 329.89], "category_id": 1}, {"id": 2, "bbox": [281.09, 423.96, 127.41, 56.4], "category_id": 2}, {"id": 3, "bbox": [19.98, 536.8, 350.92, 317.46], "category_id": 1}, {"id": 4, "bbox": [734.49, 987.94, 249.51, 161.03], "category_id": 1}, {"id": 5, "bbox": [610.04, 629.32, 325.47, 378.64], "category_id": 1}, {"id": 6, "bbox": [609.17, 207.16, 326.34, 273.32], "category_id": 1}, {"id": 7, "bbox": [281.09, 849.54, 201.9, 114.03], "category_id": 2}, {"id": 8, "bbox": [610.04, 1138.53, 340.27, 601.47], "category_id": 1}, {"id": 9, "bbox": [707.51, 508.33, 175.79, 73.99], "category_id": 2}, {"id": 10, "bbox": [141.85, 0.0, 225.39, 70.51], "category_id": 2}, {"id": 11, "bbox": [282.83, 1267.35, 109.65, 70.51], "category_id": 2}, {"id": 12, "bbox": [587.41, 0.0, 214.96, 72.25], "category_id": 2}, {"id": 13, "bbox": [2.1, 962.3, 375.2, 323.0], "category_id": 1}], "caption": "Scheme 5", "pdf": {"Page": 12, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [181, 71, 427, 506]}, "reactions": [{"reactants": [0], "conditions": [2], "products": [3]}, {"reactants": [3], "conditions": [7], "products": [13]}, {"reactants": [13], "conditions": [11], "products": [1]}, {"reactants": [6], "conditions": [9], "products": [5]}, {"reactants": [5, 4], "conditions": [], "products": [8]}], "diagram_type": "tree"}, {"id": 1021, "width": 1356, "height": 1364, "file_name": "jacs.5b07904-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [118.74, 397.12, 249.09, 297.5], "category_id": 1}, {"id": 1, "bbox": [920.6, 954.6, 298.23, 202.65], "category_id": 1}, {"id": 2, "bbox": [1029.79, 365.73, 249.09, 297.51], "category_id": 1}, {"id": 3, "bbox": [199.27, 1190.0, 66.2, 47.08], "category_id": 2}, {"id": 4, "bbox": [813.46, 348.68, 36.85, 52.54], "category_id": 3}, {"id": 5, "bbox": [410.14, 345.26, 48.46, 47.09], "category_id": 3}, {"id": 6, "bbox": [781.39, 0.0, 179.48, 220.4], "category_id": 1}, {"id": 7, "bbox": [232.03, 1014.64, 297.54, 201.97], "category_id": 1}, {"id": 8, "bbox": [322.11, 2.73, 177.43, 222.44], "category_id": 1}, {"id": 9, "bbox": [560.96, 146.7, 192.45, 173.32], "category_id": 1}, {"id": 10, "bbox": [1200.4, 703.49, 155.6, 107.13], "category_id": 2}, {"id": 11, "bbox": [1029.11, 751.26, 51.18, 62.09], "category_id": 3}, {"id": 12, "bbox": [199.27, 260.65, 99.64, 53.91], "category_id": 2}, {"id": 13, "bbox": [745.22, 1263.7, 66.19, 57.31], "category_id": 2}, {"id": 14, "bbox": [889.89, 1131.32, 63.47, 49.81], "category_id": 2}, {"id": 15, "bbox": [686.53, 1125.86, 71.66, 58.68], "category_id": 2}, {"id": 16, "bbox": [979.98, 249.05, 94.17, 56.64], "category_id": 2}, {"id": 17, "bbox": [0.0, 798.34, 152.87, 112.59], "category_id": 2}, {"id": 18, "bbox": [195.86, 803.8, 73.7, 60.73], "category_id": 2}], "caption": "Scheme 3. Proposed Strategy for Translating Chiral Information to an Originally Racemic Heterogeneous Hydrogenation of a Prochiral Substrate ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 751, 140], "ImageBB": [448, 146, 787, 487]}, "reactions": [{"reactants": [9, 6], "conditions": [4], "products": [16, 2]}, {"reactants": [2, 10], "conditions": [11], "products": [1]}, {"reactants": [1, 13], "conditions": [15], "products": [7]}, {"reactants": [7], "conditions": [18], "products": [17, 0]}, {"reactants": [0, 12], "conditions": [5], "products": [8, 9]}], "diagram_type": "graph"}, {"id": 1155, "width": 1352, "height": 644, "file_name": "ol0513995-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1092.96, 236.02, 222.52, 47.34], "category_id": 2}, {"id": 1, "bbox": [848.8, 2.71, 499.14, 150.13], "category_id": 1}, {"id": 2, "bbox": [879.24, 367.9, 450.44, 154.87], "category_id": 1}, {"id": 3, "bbox": [85.89, 57.48, 420.69, 94.01], "category_id": 1}, {"id": 4, "bbox": [4.06, 367.9, 512.66, 206.94], "category_id": 1}, {"id": 5, "bbox": [530.93, 16.23, 281.35, 85.21], "category_id": 2}, {"id": 6, "bbox": [1092.29, 282.01, 225.22, 45.99], "category_id": 2}, {"id": 7, "bbox": [554.6, 359.11, 281.35, 94.68], "category_id": 2}, {"id": 8, "bbox": [530.93, 140.67, 289.47, 91.3], "category_id": 2}, {"id": 9, "bbox": [553.92, 495.72, 198.17, 89.27], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 75, 265, 88], "ImageBB": [73, 93, 411, 254]}, "reactions": [{"reactants": [3], "conditions": [5, 8], "products": [1]}, {"reactants": [1], "conditions": [0, 6], "products": [2]}, {"reactants": [2], "conditions": [7, 9], "products": [4]}], "diagram_type": "tree"}, {"id": 45, "width": 1296, "height": 1368, "file_name": "ja410533y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [67.09, 323.95, 169.44, 41.15], "category_id": 2}, {"id": 1, "bbox": [1089.53, 281.2, 91.06, 37.63], "category_id": 3}, {"id": 2, "bbox": [416.22, 281.2, 87.5, 35.84], "category_id": 3}, {"id": 3, "bbox": [131.22, 281.2, 42.97, 35.84], "category_id": 3}, {"id": 4, "bbox": [638.88, 90.61, 290.56, 82.15], "category_id": 2}, {"id": 5, "bbox": [377.28, 326.53, 164.81, 38.46], "category_id": 2}, {"id": 6, "bbox": [4.75, 388.08, 1284.5, 972.78], "category_id": 4}, {"id": 7, "bbox": [1005.81, 6.89, 249.6, 258.5], "category_id": 1}, {"id": 8, "bbox": [40.38, 85.26, 219.31, 180.13], "category_id": 1}, {"id": 9, "bbox": [647.78, 199.26, 269.19, 123.13], "category_id": 2}, {"id": 10, "bbox": [359.22, 97.73, 203.28, 173.0], "category_id": 1}], "reactions": [{"reactants": [8, 10], "conditions": [4, 9], "products": [7]}], "corefs": [[8, 3], [10, 2], [7, 1]], "caption": "Table 4. Ruthenium(0)-Catalyzed Hydrohydroxyalkylation of Acrylic Esters 2a\u22122h with N-Benzyl-3-hydroxyoxindole 1o to Form Spirolactones 4a\u22124ha ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 140], "ImageBB": [455, 146, 779, 488]}, "diagram_type": "single"}, {"id": 261, "width": 1348, "height": 392, "file_name": "ol801791g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [972.2, 0.0, 230.8, 173.0], "category_id": 1}, {"id": 1, "bbox": [722.0, 55.0, 86.0, 51.4], "category_id": 2}, {"id": 2, "bbox": [143.0, 19.3, 448.0, 173.7], "category_id": 1}, {"id": 3, "bbox": [6.0, 251.0, 1342.0, 141.0], "category_id": 4}, {"id": 4, "bbox": [384.0, 180.0, 32.0, 39.0], "category_id": 3}, {"id": 5, "bbox": [1073.0, 185.0, 31.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [1], "products": [0]}], "corefs": [[2, 4], [0, 5]], "caption": "Table 1. Intramolecular Hydroacylation of 8a", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 409, 661, 424], "ImageBB": [425, 433, 762, 531]}, "diagram_type": "single"}, {"id": 195, "width": 1348, "height": 472, "file_name": "op0501242-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [9.0, 327.0, 1339.0, 145.0], "category_id": 4}, {"id": 1, "bbox": [170.0, 232.0, 25.0, 38.0], "category_id": 3}, {"id": 2, "bbox": [493.0, 233.0, 36.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [589.7, 146.0, 167.3, 51.0], "category_id": 2}, {"id": 4, "bbox": [130.5, 3.0, 193.4, 188.9], "category_id": 1}, {"id": 5, "bbox": [397.1, 3.0, 217.9, 191.9], "category_id": 1}, {"id": 6, "bbox": [589.0, 80.0, 214.0, 53.0], "category_id": 2}, {"id": 7, "bbox": [1000.1, 231.1, 95.9, 46.8], "category_id": 3}, {"id": 8, "bbox": [878.3, 5.0, 344.3, 189.8], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [6, 3], "products": [8]}], "corefs": [[4, 1], [5, 2], [8, 7]], "caption": "Table 3. Coupling reactions of N-substituted anilines with 2-fluorobenzoic acids in THF ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 758, 81], "ImageBB": [439, 85, 776, 203]}, "diagram_type": "single"}, {"id": 591, "width": 1356, "height": 480, "file_name": "acs.oprd.6b00180-Table-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1210.9, 209.0, 33.1, 46.0], "category_id": 3}, {"id": 1, "bbox": [15.0, 281.0, 1340.0, 197.0], "category_id": 4}, {"id": 2, "bbox": [645.0, 163.0, 221.0, 44.0], "category_id": 2}, {"id": 3, "bbox": [290.1, 79.4, 267.9, 142.4], "category_id": 1}, {"id": 4, "bbox": [47.0, 213.0, 34.1, 48.1], "category_id": 3}, {"id": 5, "bbox": [2.0, 65.2, 185.0, 138.8], "category_id": 1}, {"id": 6, "bbox": [600.0, 80.0, 307.0, 60.0], "category_id": 2}, {"id": 7, "bbox": [1091.7, 9.0, 258.2, 205.2], "category_id": 1}], "reactions": [{"reactants": [5, 3], "conditions": [6, 2], "products": [7]}], "corefs": [[5, 4], [7, 0]], "caption": "Table 10. Suzuki Reaction of 2-Bromopyridine (4) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 649, 760, 679], "ImageBB": [448, 685, 787, 805]}, "diagram_type": "single"}, {"id": 395, "width": 1352, "height": 488, "file_name": "op5001226-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [38.1, 0.0, 524.9, 424.0], "category_id": 1}, {"id": 1, "bbox": [794.0, 46.0, 513.0, 378.5], "category_id": 1}, {"id": 2, "bbox": [268.0, 398.0, 48.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [588.0, 177.0, 183.0, 100.0], "category_id": 2}, {"id": 4, "bbox": [1025.0, 398.0, 34.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3], "products": [1]}], "corefs": [[0, 2], [1, 4]], "caption": "Table 1. Screening of Ag(I) catalyst and N\u2212F reagent of decarboxylative \ufb02uorination of 10a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 639, 402, 670], "ImageBB": [82, 510, 420, 632]}, "diagram_type": "single"}, {"id": 1141, "width": 1036, "height": 544, "file_name": "ol016689+-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.1, 0.0, 38.87, 48.71], "category_id": 2}, {"id": 1, "bbox": [603.25, 289.69, 421.87, 206.25], "category_id": 1}, {"id": 2, "bbox": [168.43, 487.65, 46.13, 56.35], "category_id": 3}, {"id": 3, "bbox": [131.12, 155.47, 41.98, 50.27], "category_id": 3}, {"id": 4, "bbox": [398.02, 4.66, 39.39, 38.35], "category_id": 2}, {"id": 5, "bbox": [23.84, 323.89, 376.77, 128.0], "category_id": 1}, {"id": 6, "bbox": [644.2, 148.21, 45.08, 50.79], "category_id": 3}, {"id": 7, "bbox": [795.53, 482.99, 43.01, 52.85], "category_id": 3}, {"id": 8, "bbox": [0.0, 16.06, 355.53, 118.68], "category_id": 1}, {"id": 9, "bbox": [518.78, 0.0, 352.41, 120.75], "category_id": 1}, {"id": 10, "bbox": [460.73, 327.0, 37.84, 41.46], "category_id": 2}], "caption": "Scheme 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 74, 635, 88], "ImageBB": [479, 93, 738, 229]}, "reactions": [{"reactants": [8], "conditions": [4], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [5]}, {"reactants": [5], "conditions": [10], "products": [1]}], "diagram_type": "multiple"}, {"id": 524, "width": 1348, "height": 620, "file_name": "jo0109321-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [459.0, 2.0, 178.0, 97.0], "category_id": 2}, {"id": 1, "bbox": [811.0, 67.0, 53.0, 39.0], "category_id": 2}, {"id": 2, "bbox": [446.0, 130.0, 208.0, 38.0], "category_id": 2}, {"id": 3, "bbox": [74.0, 48.0, 260.0, 106.0], "category_id": 1}, {"id": 4, "bbox": [12.0, 244.0, 1334.0, 373.0], "category_id": 4}, {"id": 5, "bbox": [939.0, 167.0, 312.0, 46.0], "category_id": 2}, {"id": 6, "bbox": [939.0, 87.0, 341.0, 43.0], "category_id": 2}, {"id": 7, "bbox": [939.0, 15.0, 245.0, 45.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [0, 2, 1], "products": [7, 6, 5]}], "corefs": [], "caption": "Table 3. RhCl3\u201anH2O-Promoted Hydroboration of     Isomeric Octenes with BH3-THF in THFa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [461, 514, 752, 542], "ImageBB": [439, 552, 776, 707]}, "diagram_type": "single"}, {"id": 621, "width": 1352, "height": 1752, "file_name": "ol502664f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.0, 425.0, 1345.0, 1327.0], "category_id": 4}, {"id": 1, "bbox": [432.0, 232.0, 541.0, 188.0], "category_id": 2}, {"id": 2, "bbox": [1059.0, 125.0, 135.0, 130.0], "category_id": 1}, {"id": 3, "bbox": [399.0, 0.0, 597.0, 195.0], "category_id": 2}, {"id": 4, "bbox": [150.0, 123.0, 165.0, 126.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 1], "products": [2]}], "corefs": [], "caption": "Table 2. Photochemical Alcohol Oxidations in Natural Light (Reactions Carried out on 1 mmol Scale in Pyrex Vessels) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 324, 417, 354], "ImageBB": [82, 361, 420, 799]}, "diagram_type": "single"}, {"id": 447, "width": 1344, "height": 700, "file_name": "op200174k-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [586.8, 413.99, 133.0, 48.0], "category_id": 2}, {"id": 1, "bbox": [611.08, 223.04, 86.77, 58.78], "category_id": 2}, {"id": 2, "bbox": [586.01, 643.06, 92.1, 53.9], "category_id": 2}, {"id": 3, "bbox": [932.4, 25.0, 269.4, 185.9], "category_id": 1}, {"id": 4, "bbox": [418.0, 89.0, 202.0, 74.8], "category_id": 1}, {"id": 5, "bbox": [472.1, 482.1, 202.8, 75.8], "category_id": 1}, {"id": 6, "bbox": [922.7, 496.4, 269.7, 135.2], "category_id": 1}, {"id": 7, "bbox": [675.0, 52.0, 188.0, 58.9], "category_id": 2}, {"id": 8, "bbox": [161.6, 497.5, 149.9, 135.1], "category_id": 1}, {"id": 9, "bbox": [160.3, 23.1, 177.6, 136.8], "category_id": 1}], "reactions": [{"reactants": [9, 4], "conditions": [7], "products": [3]}, {"reactants": [9], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [5], "products": [6, 2]}], "corefs": [], "caption": "Figure 1. Redox-neutral (borrowing hydrogen, hydrogen autotransfer) aminations. 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Stereoselective Reduction of Oxime Disaccharides 4 7", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 405, 100], "ImageBB": [71, 112, 407, 637]}, "diagram_type": "single"}, {"id": 806, "width": 2820, "height": 2656, "file_name": "jo402763m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [299.0, 2587.0, 196.0, 69.0], "category_id": 3}, {"id": 1, "bbox": [2186.0, 2212.0, 579.0, 335.0], "category_id": 3}, {"id": 2, "bbox": [1657.0, 2596.0, 179.0, 60.0], "category_id": 3}, {"id": 3, "bbox": [955.0, 2590.0, 174.0, 66.0], "category_id": 3}, {"id": 4, "bbox": [754.0, 2203.0, 585.0, 344.0], "category_id": 3}, {"id": 5, "bbox": [219.0, 2195.0, 370.0, 364.0], "category_id": 3}, {"id": 6, "bbox": [2385.0, 2071.0, 184.0, 62.0], "category_id": 3}, {"id": 7, "bbox": [1648.0, 2074.0, 195.0, 54.0], "category_id": 3}, {"id": 8, "bbox": [946.0, 2074.0, 192.0, 59.0], "category_id": 3}, {"id": 9, "bbox": [293.0, 2068.0, 205.0, 60.0], "category_id": 3}, {"id": 10, "bbox": [2342.0, 1634.0, 173.0, 62.0], "category_id": 3}, {"id": 11, "bbox": [1640.0, 1639.0, 195.0, 57.0], "category_id": 3}, {"id": 12, "bbox": [919.0, 1639.0, 173.0, 59.0], "category_id": 3}, {"id": 13, "bbox": [236.0, 1623.0, 176.0, 46.0], "category_id": 3}, {"id": 14, "bbox": [91.0, 1709.0, 615.0, 373.0], "category_id": 1}, {"id": 15, "bbox": [868.0, 1739.0, 348.0, 302.0], "category_id": 1}, {"id": 16, "bbox": [1454.0, 1747.0, 584.0, 294.0], "category_id": 1}, {"id": 17, "bbox": [2167.0, 1755.0, 599.0, 340.0], "category_id": 1}, {"id": 18, "bbox": [1441.0, 382.0, 579.3, 382.0], "category_id": 1}, {"id": 19, "bbox": [29.2, 1275.0, 595.8, 326.0], "category_id": 1}, {"id": 20, "bbox": [741.0, 176.2, 321.0, 95.8], "category_id": 2}, {"id": 21, "bbox": [2142.0, 1289.0, 608.0, 358.0], "category_id": 1}, {"id": 22, "bbox": [1879.0, 72.0, 195.0, 175.0], "category_id": 1}, {"id": 23, "bbox": [711.0, 64.0, 372.0, 96.2], "category_id": 2}, {"id": 24, "bbox": [1457.0, 1289.0, 554.0, 358.0], "category_id": 1}, {"id": 25, "bbox": [703.0, 1280.0, 643.0, 373.0], "category_id": 1}, {"id": 26, "bbox": [54.0, 843.0, 553.0, 355.0], "category_id": 1}, {"id": 27, "bbox": [714.0, 808.0, 593.0, 387.0], "category_id": 1}, {"id": 28, "bbox": [1444.0, 797.0, 574.0, 374.0], "category_id": 1}, {"id": 29, "bbox": [2206.0, 832.0, 458.0, 307.0], "category_id": 1}, {"id": 30, "bbox": [2341.0, 1158.0, 202.0, 72.0], "category_id": 3}, {"id": 31, "bbox": [1646.0, 1174.0, 175.0, 48.0], "category_id": 3}, {"id": 32, "bbox": [919.0, 1163.0, 178.0, 67.0], "category_id": 3}, {"id": 33, "bbox": [235.0, 1163.0, 188.0, 62.0], "category_id": 3}, {"id": 34, "bbox": [237.0, 713.0, 184.0, 70.0], "category_id": 3}, {"id": 35, "bbox": [908.0, 716.0, 189.0, 62.0], "category_id": 3}, {"id": 36, "bbox": [1638.0, 711.0, 183.0, 61.0], "category_id": 3}, {"id": 37, "bbox": [2344.0, 719.0, 185.0, 56.0], "category_id": 3}, {"id": 38, "bbox": [182.7, 38.2, 354.3, 243.8], "category_id": 1}, {"id": 39, "bbox": [1244.7, 0.0, 431.4, 273.9], "category_id": 1}, {"id": 40, "bbox": [2203.0, 358.0, 472.0, 406.0], "category_id": 1}, {"id": 41, "bbox": [717.0, 379.0, 590.0, 310.0], "category_id": 1}, {"id": 42, "bbox": [154.0, 385.0, 353.0, 307.0], "category_id": 1}, {"id": 43, "bbox": [278.0, 274.0, 113.0, 51.0], "category_id": 3}, {"id": 44, "bbox": [1393.0, 269.0, 118.0, 59.0], "category_id": 3}, {"id": 45, "bbox": [2084.0, 67.0, 558.0, 248.0], "category_id": 2}, {"id": 46, "bbox": [1455.0, 2206.0, 594.0, 418.0], "category_id": 3}, {"id": 47, "bbox": [2385.0, 2601.0, 173.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [38], "conditions": [23, 20], "products": [39, 22]}], "corefs": [[38, 43], [39, 44], [22, 45], [42, 34], [41, 35], [18, 36], [40, 37], [26, 33], [27, 32], [28, 31], [29, 30], [19, 13], [25, 12], [24, 11], [21, 10], [14, 9], [15, 8], [16, 7], [17, 6], [5, 0], [4, 3], [46, 2], [1, 47]], "caption": "Table 1. Synthesis of Chromenes 5 from Tertiary Alcohols 4 under Optimized Conditionsa,b,c", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 613, 110], "ImageBB": [82, 116, 787, 780]}, "diagram_type": "single"}, {"id": 747, "width": 1348, "height": 1080, "file_name": "jo991283k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1053.0, 273.0, 204.0, 52.0], "category_id": 3}, {"id": 1, "bbox": [101.0, 274.0, 218.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [469.0, 277.0, 423.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [112.0, 0.0, 196.0, 137.0], "category_id": 1}, {"id": 4, "bbox": [1064.0, 0.0, 184.1, 137.0], "category_id": 1}, {"id": 5, "bbox": [5.0, 362.0, 1343.0, 712.0], "category_id": 4}, {"id": 6, "bbox": [583.0, 0.0, 186.0, 134.9], "category_id": 1}, {"id": 7, "bbox": [534.0, 137.0, 303.0, 138.0], "category_id": 2}, {"id": 8, "bbox": [44.0, 177.0, 336.0, 53.0], "category_id": 2}, {"id": 9, "bbox": [991.0, 177.0, 321.0, 46.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [], "products": [3]}, {"reactants": [6], "conditions": [], "products": [4]}], "corefs": [[3, 1], [6, 2], [4, 0]], "caption": "Table 1. Reduction of Methyl Ketones and          Trifluoromethyl Ketonesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [481, 64, 733, 89], "ImageBB": [439, 94, 776, 364]}, "diagram_type": "single"}, {"id": 354, "width": 1344, "height": 1316, "file_name": "ol200849k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [111.0, 287.2, 454.0, 251.3], "category_id": 1}, {"id": 1, "bbox": [15.0, 613.0, 1329.0, 703.0], "category_id": 4}, {"id": 2, "bbox": [703.9, 281.0, 506.8, 255.5], "category_id": 1}, {"id": 3, "bbox": [1070.33, 14.0, 273.67, 231.5], "category_id": 1}, {"id": 4, "bbox": [532.0, 0.0, 352.0, 99.4], "category_id": 2}, {"id": 5, "bbox": [538.0, 182.7, 348.6, 56.5], "category_id": 2}, {"id": 6, "bbox": [68.3, 205.8, 49.4, 56.4], "category_id": 3}, {"id": 7, "bbox": [365.3, 202.1, 51.4, 52.8], "category_id": 3}, {"id": 8, "bbox": [1151.9, 205.9, 43.5, 49.0], "category_id": 3}, {"id": 9, "bbox": [954.2, 497.9, 45.5, 50.0], "category_id": 3}, {"id": 10, "bbox": [280.0, 75.8, 242.0, 68.1], "category_id": 1}, {"id": 11, "bbox": [304.1, 506.3, 41.8, 45.8], "category_id": 3}, {"id": 12, "bbox": [542.0, 121.0, 212.2, 65.0], "category_id": 2}, {"id": 13, "bbox": [5.0, 33.0, 199.0, 170.4], "category_id": 1}], "reactions": [{"reactants": [13, 10], "conditions": [4, 12, 5], "products": [3]}], "corefs": [[13, 6], [10, 7], [3, 8], [0, 11], [2, 9]], "caption": "Table 1. CDC between Various Nitrones 1 and Alkynes 2 Using a Stoichiometric Amount of Oxidant 3 ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 164, 405, 191], "ImageBB": [71, 202, 407, 531]}, "diagram_type": "single"}, {"id": 445, "width": 1344, "height": 1492, "file_name": "op200174k-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [33.0, 510.0, 323.0, 264.0], "category_id": 1}, {"id": 1, "bbox": [806.0, 880.0, 504.0, 485.0], "category_id": 1}, {"id": 2, "bbox": [402.0, 887.0, 442.0, 241.0], "category_id": 2}, {"id": 3, "bbox": [411.0, 1151.0, 433.0, 207.0], "category_id": 2}, {"id": 4, "bbox": [420.0, 643.0, 366.0, 169.0], "category_id": 2}, {"id": 5, "bbox": [413.0, 550.0, 341.0, 72.0], "category_id": 2}, {"id": 6, "bbox": [24.0, 850.0, 400.0, 524.0], "category_id": 1}, {"id": 7, "bbox": [6.0, 9.0, 1333.0, 318.0], "category_id": 4}, {"id": 8, "bbox": [1014.0, 738.0, 70.0, 58.0], "category_id": 3}, {"id": 9, "bbox": [948.0, 1392.0, 41.0, 48.0], "category_id": 3}, {"id": 10, "bbox": [115.0, 1392.0, 65.0, 59.0], "category_id": 3}, {"id": 11, "bbox": [243.0, 740.0, 41.0, 52.0], "category_id": 3}, {"id": 12, "bbox": [826.0, 510.0, 389.0, 270.0], "category_id": 1}, {"id": 13, "bbox": [258.3, 1151.98, 129.93, 64.97], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [5, 4], "products": [12]}, {"reactants": [6, 13], "conditions": [2, 3], "products": [1]}], "corefs": [[0, 11], [12, 8], [6, 10], [1, 9]], "caption": "Table 6. Low-Catalyst Scale-Up Runs", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 646, 107], "ImageBB": [437, 111, 773, 484]}, "diagram_type": "multiple"}, {"id": 611, "width": 2820, "height": 1132, "file_name": "acs.oprd.5b00312-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [795.5, 171.0, 1594.5, 961.0], "category_id": 4}, {"id": 1, "bbox": [506.0, 572.0, 106.0, 33.0], "category_id": 1}, {"id": 2, "bbox": [327.0, 764.2, 349.6, 259.8], "category_id": 1}, {"id": 3, "bbox": [325.9, 678.0, 259.1, 44.0], "category_id": 3}, {"id": 4, "bbox": [318.0, 168.4, 347.6, 256.6], "category_id": 1}, {"id": 5, "bbox": [299.0, 462.0, 421.6, 68.0], "category_id": 2}, {"id": 6, "bbox": [710.27, 119.48, 59.55, 38.28], "category_id": 2}, {"id": 7, "bbox": [727.29, 729.84, 55.29, 38.28], "category_id": 2}, {"id": 8, "bbox": [616.7, 54.0, 89.3, 50.0], "category_id": 2}, {"id": 9, "bbox": [323.7, 61.0, 241.3, 40.0], "category_id": 3}, {"id": 10, "bbox": [320.0, 1054.0, 409.8, 75.0], "category_id": 2}, {"id": 11, "bbox": [611.3, 679.0, 92.7, 44.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [1], "products": [2]}], "corefs": [[4, 9], [4, 5], [2, 3], [2, 10]], "caption": "Figure 3. (A) UHPLC/UV chromatogram at 254 nm for the TiCl3 treated sample and (B, C) high-resolution mass spectra of (B) compound 7 and (C)the reduced aniline compound 7a. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 886, 784, 914], "ImageBB": [82, 593, 787, 876]}, "diagram_type": "tree"}, {"id": 111, "width": 1220, "height": 1080, "file_name": "ja001164i-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [29.21, 7.36, 301.05, 172.45], "category_id": 1}, {"id": 1, "bbox": [958.91, 5.81, 218.93, 174.0], "category_id": 1}, {"id": 2, "bbox": [151.62, 211.9, 23.69, 34.54], "category_id": 3}, {"id": 3, "bbox": [755.93, 33.7, 133.7, 34.54], "category_id": 2}, {"id": 4, "bbox": [410.39, 112.73, 271.61, 74.82], "category_id": 2}, {"id": 5, "bbox": [452.22, 32.16, 203.44, 42.28], "category_id": 2}, {"id": 6, "bbox": [1059.63, 210.35, 25.24, 34.54], "category_id": 3}, {"id": 7, "bbox": [5.94, 262.77, 1206.03, 810.26], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [5, 4, 3], "products": [1]}], "corefs": [[0, 2], [1, 6]], "caption": "Table 2. Enantioselective Protonation of 5a-e by (R)-1\u201aSnCl4a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 389, 78], "ImageBB": [90, 80, 395, 350]}, "diagram_type": "single"}, {"id": 982, "width": 1252, "height": 420, "file_name": "ja1078199-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [147.26, 182.19, 80.25, 38.72], "category_id": 2}, {"id": 1, "bbox": [796.67, 262.53, 88.31, 50.12], "category_id": 2}, {"id": 2, "bbox": [317.54, 266.91, 95.2, 50.13], "category_id": 2}, {"id": 3, "bbox": [330.69, 25.06, 58.25, 48.87], "category_id": 2}, {"id": 4, "bbox": [917.55, 246.86, 317.54, 147.87], "category_id": 1}, {"id": 5, "bbox": [28.81, 5.64, 264.93, 146.61], "category_id": 1}, {"id": 6, "bbox": [318.79, 87.09, 65.77, 38.85], "category_id": 2}, {"id": 7, "bbox": [35.84, 184.93, 82.15, 38.71], "category_id": 2}, {"id": 8, "bbox": [784.77, 30.07, 87.68, 52.01], "category_id": 2}, {"id": 9, "bbox": [427.15, 228.07, 355.12, 191.1], "category_id": 1}, {"id": 10, "bbox": [784.77, 318.92, 110.23, 41.98], "category_id": 2}, {"id": 11, "bbox": [917.55, 6.27, 334.45, 152.25], "category_id": 1}, {"id": 12, "bbox": [429.65, 8.15, 331.32, 147.24], "category_id": 1}, {"id": 13, "bbox": [0.0, 253.75, 312.53, 151.63], "category_id": 1}], "caption": "Scheme 3. A Possible Pathway for the Photoreduction of CO2 with H2 to CO and H2O with a ReI(L)(CO)3(CH3CN)-MHPW12O40 Catalyst ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 266, 390, 302], "ImageBB": [70, 313, 383, 418]}, "reactions": [{"reactants": [5], "conditions": [3, 6], "products": [12]}, {"reactants": [12], "conditions": [8], "products": [11]}, {"reactants": [11], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [10], "products": [9]}, {"reactants": [9], "conditions": [1], "products": [4]}, {"reactants": [9], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [2], "products": [9]}, {"reactants": [13], "conditions": [7], "products": [5]}, {"reactants": [5], "conditions": [0], "products": [13]}], "diagram_type": "graph"}, {"id": 1063, "width": 1132, "height": 568, "file_name": "jo202294k-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [531.17, 345.36, 199.34, 125.69], "category_id": 1}, {"id": 1, "bbox": [617.25, 300.63, 52.66, 39.63], "category_id": 3}, {"id": 2, "bbox": [773.54, 411.03, 122.89, 50.96], "category_id": 2}, {"id": 3, "bbox": [258.23, 202.12, 125.71, 46.99], "category_id": 2}, {"id": 4, "bbox": [0.0, 229.3, 74.75, 52.08], "category_id": 3}, {"id": 5, "bbox": [651.79, 165.32, 237.27, 126.25], "category_id": 1}, {"id": 6, "bbox": [0.0, 229.3, 75.32, 52.08], "category_id": 2}, {"id": 7, "bbox": [321.08, 370.3, 206.7, 93.95], "category_id": 2}, {"id": 8, "bbox": [23.0, 409.33, 79.5, 52.66], "category_id": 2}, {"id": 9, "bbox": [438.87, 189.4, 208.96, 97.08], "category_id": 2}, {"id": 10, "bbox": [934.37, 411.03, 54.93, 52.09], "category_id": 3}, {"id": 11, "bbox": [934.37, 229.3, 54.93, 52.08], "category_id": 3}, {"id": 12, "bbox": [105.33, 129.65, 127.98, 237.22], "category_id": 1}, {"id": 13, "bbox": [514.19, 481.24, 50.39, 41.33], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 565, 505, 580], "ImageBB": [504, 554, 787, 696]}, "reactions": [{"reactants": [6, 12], "conditions": [3], "products": [9, 5]}, {"reactants": [8], "conditions": [], "products": [7, 0, 2]}], "diagram_type": "multiple"}, {"id": 595, "width": 1352, "height": 1244, "file_name": "acs.oprd.6b00126-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [101.7, 7.2, 238.5, 140.4], "category_id": 1}, {"id": 1, "bbox": [997.8, 7.0, 286.5, 186.2], "category_id": 1}, {"id": 2, "bbox": [4.0, 278.0, 1348.0, 966.0], "category_id": 4}, {"id": 3, "bbox": [450.4, 133.0, 359.7, 136.0], "category_id": 2}, {"id": 4, "bbox": [451.2, 3.0, 388.2, 102.0], "category_id": 2}, {"id": 5, "bbox": [63.98, 171.59, 79.44, 48.75], "category_id": 2}, {"id": 6, "bbox": [139.81, 157.14, 231.11, 115.56], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4, 3], "products": [1]}], "corefs": [], "caption": "Table 2. Application of the Developed Conditions to Other Aryl and Vinyl Sulfonatese ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 485, 784, 515], "ImageBB": [448, 521, 786, 832]}, "diagram_type": "single"}, {"id": 182, "width": 1316, "height": 1224, "file_name": "op0602270-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [928.0, 9.0, 386.0, 237.8], "category_id": 1}, {"id": 1, "bbox": [78.0, 257.0, 217.8, 60.8], "category_id": 3}, {"id": 2, "bbox": [13.0, 360.0, 1269.0, 863.0], "category_id": 4}, {"id": 3, "bbox": [391.0, 17.0, 482.3, 72.0], "category_id": 2}, {"id": 4, "bbox": [391.0, 147.0, 508.0, 67.0], "category_id": 2}, {"id": 5, "bbox": [1082.0, 255.0, 81.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [2.0, 11.0, 378.0, 237.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 4], "products": [0]}], "corefs": [[6, 1], [0, 5]], "caption": "Figure 2. Dependency of enantioselectivity versus temperature. Reactions were carried out at corresponding temperature for 1-24 h with 0.0024 mmol [Rh(cod)2]BF4, 0.005 mmol ligand 6a and 0.24 mmol substrate in 2.0 mL of 2-propanol. Conver- sions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 362, 775, 446], "ImageBB": [444, 53, 773, 359]}, "diagram_type": "single"}, {"id": 1030, "width": 1228, "height": 1060, "file_name": "jo001386z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [541.2, 44.22, 200.27, 164.58], "category_id": 1}, {"id": 1, "bbox": [735.94, 303.99, 216.85, 97.64], "category_id": 3}, {"id": 2, "bbox": [465.03, 550.24, 105.66, 56.5], "category_id": 2}, {"id": 3, "bbox": [505.57, 797.73, 191.67, 116.07], "category_id": 1}, {"id": 4, "bbox": [888.29, 44.22, 281.97, 241.34], "category_id": 1}, {"id": 5, "bbox": [488.37, 467.34, 84.16, 64.48], "category_id": 2}, {"id": 6, "bbox": [488.37, 961.09, 239.58, 98.91], "category_id": 3}, {"id": 7, "bbox": [221.15, 59.57, 170.16, 49.13], "category_id": 2}, {"id": 8, "bbox": [678.81, 467.95, 353.84, 141.86], "category_id": 1}, {"id": 9, "bbox": [221.76, 146.16, 191.05, 50.97], "category_id": 2}, {"id": 10, "bbox": [0.0, 294.16, 221.15, 100.71], "category_id": 3}, {"id": 11, "bbox": [765.43, 652.19, 218.08, 93.96], "category_id": 3}, {"id": 12, "bbox": [38.7, 70.01, 124.09, 116.68], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [89, 83, 396, 348]}, "reactions": [{"reactants": [12], "conditions": [7, 9], "products": [0, 4]}, {"reactants": [4], "conditions": [5, 2], "products": [8]}], "diagram_type": "multiple"}, {"id": 899, "width": 1244, "height": 3156, "file_name": "acs.joc.6b00116-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [968.0, 205.0, 38.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [124.0, 106.0, 182.0, 69.0], "category_id": 1}, {"id": 2, "bbox": [9.0, 267.0, 1227.0, 2880.0], "category_id": 4}, {"id": 3, "bbox": [889.0, 76.0, 232.0, 108.0], "category_id": 1}, {"id": 4, "bbox": [209.0, 205.0, 32.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [360.0, 113.0, 215.0, 55.0], "category_id": 2}, {"id": 6, "bbox": [589.0, 4.0, 239.0, 130.0], "category_id": 2}], "reactions": [{"reactants": [1, 5], "conditions": [6], "products": [3]}], "corefs": [[1, 4], [3, 0]], "caption": "Table 3. Substrate Scopea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 229, 110], "ImageBB": [95, 116, 406, 905]}, "diagram_type": "single"}, {"id": 1212, "width": 1352, "height": 816, "file_name": "ol801788t-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [577.59, 391.37, 257.01, 102.07], "category_id": 1}, {"id": 1, "bbox": [106.19, 602.94, 287.44, 139.92], "category_id": 1}, {"id": 2, "bbox": [1046.97, 604.3, 239.43, 154.11], "category_id": 1}, {"id": 3, "bbox": [669.57, 601.59, 53.44, 50.7], "category_id": 2}, {"id": 4, "bbox": [68.99, 0.0, 357.78, 133.16], "category_id": 1}, {"id": 5, "bbox": [614.12, 504.26, 182.61, 52.04], "category_id": 1}, {"id": 6, "bbox": [65.6, 171.01, 142.71, 52.05], "category_id": 1}, {"id": 7, "bbox": [1046.97, 0.0, 239.43, 135.87], "category_id": 1}, {"id": 8, "bbox": [156.23, 311.61, 60.87, 47.32], "category_id": 2}], "caption": "Scheme 2. Disilylation via Cross-Coupling", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [115, 74, 337, 89], "ImageBB": [58, 96, 396, 300]}, "reactions": [{"reactants": [4, 6], "conditions": [8], "products": [1, 0, 5]}, {"reactants": [1], "conditions": [3], "products": [2]}, {"reactants": [2, 0], "conditions": [], "products": [7]}, {"reactants": [2, 5], "conditions": [], "products": [7]}], "diagram_type": "graph"}, {"id": 28, "width": 1348, "height": 720, "file_name": "ja9039289-Table-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.13, 220.08, 1342.6, 498.02], "category_id": 4}, {"id": 1, "bbox": [1025.0, 173.54, 30.8, 36.38], "category_id": 3}, {"id": 2, "bbox": [802.96, 53.79, 474.88, 108.84], "category_id": 1}, {"id": 3, "bbox": [478.73, 135.54, 276.07, 42.88], "category_id": 2}, {"id": 4, "bbox": [524.25, 4.46, 187.81, 90.35], "category_id": 2}, {"id": 5, "bbox": [67.17, 127.18, 368.03, 46.6], "category_id": 2}, {"id": 6, "bbox": [71.95, 43.71, 363.35, 46.49], "category_id": 2}], "reactions": [{"reactants": [6, 5], "conditions": [4, 3], "products": [2]}], "corefs": [[2, 1]], "caption": "Table 10. Reaction of Cobalt and Nickel Salts with p-TolMgBr in the Presence of IPr \u00b7 HCl ", "pdf": {"Page": 9, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 245, 747, 269], "ImageBB": [425, 277, 762, 457]}, "diagram_type": "single"}, {"id": 340, "width": 1348, "height": 740, "file_name": "ol202499g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [48.0, 225.0, 201.0, 46.0], "category_id": 2}, {"id": 1, "bbox": [399.0, 15.0, 201.0, 154.0], "category_id": 1}, {"id": 2, "bbox": [980.0, 3.0, 343.0, 180.0], "category_id": 1}, {"id": 3, "bbox": [660.0, 13.0, 245.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [667.0, 109.0, 233.0, 42.0], "category_id": 2}, {"id": 5, "bbox": [10.0, 330.0, 1337.0, 405.0], "category_id": 4}, {"id": 6, "bbox": [1130.0, 198.0, 24.0, 32.0], "category_id": 3}, {"id": 7, "bbox": [460.0, 193.0, 42.0, 31.0], "category_id": 3}, {"id": 8, "bbox": [155.0, 195.0, 23.0, 29.0], "category_id": 3}, {"id": 9, "bbox": [26.0, 11.0, 247.0, 175.0], "category_id": 1}], "reactions": [{"reactants": [9, 1], "conditions": [3, 4], "products": [2]}], "corefs": [[9, 8], [1, 7], [2, 6]], "caption": "Table 2. Direct Allylic Alkylation of O-Protected Allylic Cya- nohydrin 1 with MBH Adducts 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 765, 114], "ImageBB": [436, 126, 773, 311]}, "diagram_type": "single"}, {"id": 550, "width": 1348, "height": 428, "file_name": "acs.orglett.5b02743-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [380.2, 1.0, 434.5, 95.0], "category_id": 2}, {"id": 1, "bbox": [1036.05, 235.0, 72.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [8.0, 305.0, 1339.0, 122.0], "category_id": 4}, {"id": 3, "bbox": [179.0, 234.0, 65.0, 61.0], "category_id": 3}, {"id": 4, "bbox": [16.2, 17.3, 302.7, 214.8], "category_id": 1}, {"id": 5, "bbox": [452.3, 153.4, 178.4, 78.3], "category_id": 1}, {"id": 6, "bbox": [919.3, 2.0, 409.5, 229.9], "category_id": 1}, {"id": 7, "bbox": [376.07, 141.98, 58.0, 56.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [0, 7, 5], "products": [6]}], "corefs": [[4, 3], [6, 1]], "caption": "Table 1. Exploration of Optimal Conditions for Activation of tert-Butyl Sul\ufb01nyl Groupa ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 631, 784, 662], "ImageBB": [449, 668, 786, 775]}, "diagram_type": "single"}, {"id": 864, "width": 1356, "height": 640, "file_name": "jo2003264-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [517.0, 117.0, 277.0, 80.7], "category_id": 2}, {"id": 1, "bbox": [306.0, 90.0, 134.8, 48.2], "category_id": 1}, {"id": 2, "bbox": [351.6, 151.13, 36.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [83.27, 152.27, 50.0, 38.0], "category_id": 3}, {"id": 4, "bbox": [5.8, 429.8, 1330.2, 210.2], "category_id": 4}, {"id": 5, "bbox": [707.0, 318.0, 46.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [1112.0, 315.0, 46.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [1.0, 87.0, 210.0, 56.0], "category_id": 1}, {"id": 8, "bbox": [436.0, 1.0, 687.0, 107.0], "category_id": 2}, {"id": 9, "bbox": [555.0, 187.0, 286.0, 131.0], "category_id": 1}, {"id": 10, "bbox": [945.0, 186.0, 409.0, 129.0], "category_id": 1}], "reactions": [{"reactants": [7, 1], "conditions": [8, 0], "products": [9, 10]}], "corefs": [[7, 3], [1, 2], [9, 5], [10, 6]], "caption": "Table 1. Ir-Catalyzed Oxidative Methyl Esteri\ufb01cation of 1a with 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 398, 122], "ImageBB": [71, 133, 410, 293]}, "diagram_type": "multiple"}, {"id": 696, "width": 1352, "height": 1136, "file_name": "ol0480731-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [77.0, 1.0, 476.0, 311.0], "category_id": 1}, {"id": 1, "bbox": [810.0, 94.0, 138.0, 65.0], "category_id": 2}, {"id": 2, "bbox": [782.0, 171.0, 205.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [3.0, 413.0, 1349.0, 723.0], "category_id": 4}, {"id": 4, "bbox": [1025.0, 77.0, 256.0, 212.0], "category_id": 1}, {"id": 5, "bbox": [184.0, 323.0, 194.0, 55.4], "category_id": 2}, {"id": 6, "bbox": [601.0, 81.91, 153.0, 139.0], "category_id": 1}, {"id": 7, "bbox": [99.0, 257.0, 146.0, 57.0], "category_id": 3}], "reactions": [{"reactants": [0, 6], "conditions": [1, 2], "products": [4]}], "corefs": [[0, 7]], "caption": "Table 2. Anti-Selective Aldehyde Crotylation with (R,R)-3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 226, 749, 239], "ImageBB": [439, 245, 777, 529]}, "diagram_type": "single"}, {"id": 410, "width": 1348, "height": 444, "file_name": "op400278d-Table-c13.png", "license": 0, "bboxes": [{"id": 0, "bbox": [627.0, 192.1, 330.0, 102.9], "category_id": 2}, {"id": 1, "bbox": [627.0, 67.0, 330.0, 109.8], "category_id": 2}, {"id": 2, "bbox": [35.2, 39.2, 190.7, 192.5], "category_id": 1}, {"id": 3, "bbox": [329.1, 76.2, 214.9, 152.8], "category_id": 1}, {"id": 4, "bbox": [1021.0, 5.0, 324.0, 248.0], "category_id": 1}, {"id": 5, "bbox": [299.0, 279.0, 204.0, 64.0], "category_id": 2}, {"id": 6, "bbox": [7.0, 287.0, 201.0, 64.0], "category_id": 2}, {"id": 7, "bbox": [69.0, 249.0, 75.0, 44.0], "category_id": 3}, {"id": 8, "bbox": [374.0, 243.0, 60.0, 48.0], "category_id": 3}, {"id": 9, "bbox": [1194.0, 250.0, 56.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [2, 3], "conditions": [1, 0], "products": [4]}], "corefs": [[2, 7], [3, 8], [4, 9]], "caption": "Table 13. Direct comparison between Pd-PEPPSI-IPr* (100) and IPent (1, 33) PEPPSI sca\ufb00olds under identical reaction conditions ", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 279, 417, 324], "ImageBB": [82, 330, 419, 441]}, "diagram_type": "single"}, {"id": 522, "width": 1344, "height": 636, "file_name": "jo0109321-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [948.0, 359.0, 290.0, 48.0], "category_id": 2}, {"id": 1, "bbox": [948.1, 308.0, 267.9, 41.0], "category_id": 2}, {"id": 2, "bbox": [611.1, 132.1, 42.8, 37.8], "category_id": 2}, {"id": 3, "bbox": [380.0, 82.0, 150.9, 87.9], "category_id": 2}, {"id": 4, "bbox": [741.0, 141.0, 33.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [735.0, 365.0, 36.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [697.1, 3.0, 345.7, 131.9], "category_id": 1}, {"id": 7, "bbox": [964.1, 92.3, 267.4, 130.7], "category_id": 1}, {"id": 8, "bbox": [694.2, 158.0, 261.6, 197.9], "category_id": 1}, {"id": 9, "bbox": [1006.0, 235.1, 43.0, 44.8], "category_id": 3}, {"id": 10, "bbox": [373.0, 181.1, 174.0, 39.9], "category_id": 2}, {"id": 11, "bbox": [109.1, 101.1, 263.9, 141.8], "category_id": 1}, {"id": 12, "bbox": [3.03, 434.1, 1339.95, 201.7], "category_id": 4}], "reactions": [{"reactants": [11], "conditions": [3, 10, 2], "products": [6, 8, 7]}], "corefs": [[6, 4], [8, 5], [7, 9]], "caption": "Table 6. Hydroboration of Allylbenzene with BH3-THF                       in THF ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [77, 479, 404, 506], "ImageBB": [74, 515, 410, 674]}, "diagram_type": "single"}, {"id": 657, "width": 1348, "height": 2160, "file_name": "ol402981z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [22.0, 345.0, 408.0, 285.0], "category_id": 3}, {"id": 1, "bbox": [1149.0, 758.0, 46.0, 32.0], "category_id": 3}, {"id": 2, "bbox": [564.0, 759.0, 36.0, 31.0], "category_id": 3}, {"id": 3, "bbox": [854.0, 762.0, 44.0, 33.0], "category_id": 3}, {"id": 4, "bbox": [1020.0, 435.0, 306.0, 324.0], "category_id": 1}, {"id": 5, "bbox": [738.0, 420.0, 282.0, 335.0], "category_id": 1}, {"id": 6, "bbox": [443.0, 405.0, 311.0, 379.0], "category_id": 1}, {"id": 7, "bbox": [875.0, 2.0, 334.0, 407.0], "category_id": 1}, {"id": 8, "bbox": [611.0, 128.0, 188.0, 151.0], "category_id": 1}, {"id": 9, "bbox": [183.0, 115.0, 217.0, 167.0], "category_id": 1}, {"id": 10, "bbox": [4.5, 822.0, 1343.5, 1338.0], "category_id": 4}, {"id": 11, "bbox": [420.0, 233.0, 154.0, 58.0], "category_id": 2}, {"id": 12, "bbox": [412.0, 143.0, 164.0, 69.0], "category_id": 2}], "reactions": [{"reactants": [9], "conditions": [12, 11], "products": [8]}], "corefs": [[6, 2], [5, 3], [4, 1]], "caption": "Table 1. Optimization of the Reaction Conditionsa,f", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 713, 101], "ImageBB": [436, 112, 773, 652]}, "diagram_type": "single"}, {"id": 360, "width": 1344, "height": 1280, "file_name": "ol1030487-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [361.6, 50.0, 189.5, 54.6], "category_id": 1}, {"id": 1, "bbox": [65.0, 160.0, 86.0, 38.0], "category_id": 3}, {"id": 2, "bbox": [742.0, 225.0, 92.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [1122.0, 222.0, 95.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [330.11, 25.99, 44.58, 42.73], "category_id": 2}, {"id": 5, "bbox": [342.0, 121.0, 243.7, 43.7], "category_id": 2}, {"id": 6, "bbox": [6.0, 28.43, 271.7, 141.0], "category_id": 1}, {"id": 7, "bbox": [655.0, 2.0, 299.0, 209.0], "category_id": 1}, {"id": 8, "bbox": [558.68, 60.06, 44.61, 37.75], "category_id": 3}, {"id": 9, "bbox": [0.0, 289.0, 1344.0, 991.0], "category_id": 4}, {"id": 10, "bbox": [329.0, 179.0, 223.0, 53.0], "category_id": 2}, {"id": 11, "bbox": [1043.0, 2.0, 297.0, 209.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 0, 5, 10], "products": [7, 11]}], "corefs": [[6, 1], [0, 8], [7, 2], [11, 3]], "caption": "Table 2. Screening of Catalyst, Solvent, and Reaction Condi- tions for the Synthesis of Pentasubstituted Cyclohexanecar- boxylatesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 396, 128], "ImageBB": [71, 129, 407, 449]}, "diagram_type": "single"}, {"id": 932, "width": 1356, "height": 1400, "file_name": "acs.oprd.5b00303-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.81, 0.0, 589.04, 63.73], "category_id": 2}, {"id": 1, "bbox": [371.22, 1116.36, 167.39, 132.36], "category_id": 1}, {"id": 2, "bbox": [69.34, 467.13, 220.63, 187.7], "category_id": 1}, {"id": 3, "bbox": [16.81, 1076.44, 243.74, 54.63], "category_id": 2}, {"id": 4, "bbox": [619.86, 1162.58, 244.44, 161.78], "category_id": 1}, {"id": 5, "bbox": [470.67, 336.87, 219.93, 126.06], "category_id": 1}, {"id": 6, "bbox": [462.27, 684.24, 131.68, 62.33], "category_id": 1}, {"id": 7, "bbox": [981.27, 841.82, 196.82, 201.0], "category_id": 1}, {"id": 8, "bbox": [69.34, 72.14, 220.63, 186.29], "category_id": 1}, {"id": 9, "bbox": [69.34, 834.12, 307.48, 240.92], "category_id": 1}, {"id": 10, "bbox": [981.27, 476.94, 218.53, 196.8], "category_id": 1}, {"id": 11, "bbox": [17.51, 769.68, 261.95, 66.54], "category_id": 2}, {"id": 12, "bbox": [404.14, 1299.15, 108.56, 50.42], "category_id": 2}, {"id": 13, "bbox": [470.67, 134.47, 217.83, 57.43], "category_id": 1}, {"id": 14, "bbox": [716.52, 69.33, 250.04, 59.53], "category_id": 2}, {"id": 15, "bbox": [716.52, 463.63, 277.36, 97.35], "category_id": 2}, {"id": 16, "bbox": [766.25, 859.33, 153.39, 60.23], "category_id": 2}, {"id": 17, "bbox": [925.94, 1146.47, 195.41, 102.25], "category_id": 2}, {"id": 18, "bbox": [423.75, 839.02, 293.47, 193.3], "category_id": 1}, {"id": 19, "bbox": [981.27, 76.34, 216.43, 197.5], "category_id": 1}, {"id": 20, "bbox": [69.34, 1211.61, 238.14, 114.85], "category_id": 1}, {"id": 21, "bbox": [17.51, 286.44, 330.59, 61.63], "category_id": 2}, {"id": 22, "bbox": [1140.96, 1155.58, 197.52, 203.1], "category_id": 1}, {"id": 23, "bbox": [462.27, 518.96, 175.8, 76.34], "category_id": 1}], "caption": "Scheme 1. Synthetic Routes to N-Vinylalkylamide", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 407, 729, 427], "ImageBB": [448, 432, 787, 782]}, "reactions": [{"reactants": [8, 13], "conditions": [14], "products": [19]}, {"reactants": [2, 5], "conditions": [15], "products": [10]}, {"reactants": [2, 23], "conditions": [15], "products": [10]}, {"reactants": [2, 6], "conditions": [15], "products": [10]}, {"reactants": [9], "conditions": [16], "products": [7]}, {"reactants": [18], "conditions": [16], "products": [7]}, {"reactants": [20], "conditions": [1, 12], "products": [4]}, {"reactants": [4], "conditions": [17], "products": [22]}], "diagram_type": "multiple"}, {"id": 792, "width": 1348, "height": 348, "file_name": "jo501785d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1057.0, 200.0, 74.0, 52.0], "category_id": 3}, {"id": 1, "bbox": [338.0, 55.0, 303.0, 126.0], "category_id": 1}, {"id": 2, "bbox": [950.0, 9.0, 345.0, 216.0], "category_id": 1}, {"id": 3, "bbox": [654.0, 137.0, 298.0, 95.0], "category_id": 2}, {"id": 4, "bbox": [696.0, 33.0, 214.0, 82.0], "category_id": 2}, {"id": 5, "bbox": [172.0, 203.0, 52.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [463.0, 203.0, 51.0, 39.0], "category_id": 3}, {"id": 7, "bbox": [55.0, 49.0, 246.0, 178.0], "category_id": 1}, {"id": 8, "bbox": [0.0, 274.0, 1339.0, 74.0], "category_id": 4}], "reactions": [{"reactants": [7, 1], "conditions": [4, 3], "products": [2]}], "corefs": [[7, 5], [1, 6], [2, 0]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 371, 110], "ImageBB": [82, 116, 419, 203]}, "diagram_type": "single"}, {"id": 71, "width": 1764, "height": 2364, "file_name": "ja2070522-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [723.67, 861.96, 140.57, 102.0], "category_id": 2}, {"id": 1, "bbox": [750.81, 790.53, 83.43, 46.28], "category_id": 2}, {"id": 2, "bbox": [977.96, 586.23, 424.88, 437.73], "category_id": 1}, {"id": 3, "bbox": [207.93, 583.37, 404.87, 440.63], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [2]}], "corefs": [], "caption": "Figure 1. Knoevenagel condensation using benzaldehyde with active methylene compounds. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 503, 784, 531], "ImageBB": [418, 536, 859, 1127]}, "diagram_type": "single"}, {"id": 980, "width": 2520, "height": 812, "file_name": "ja065718e-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1854.39, 80.59, 353.71, 143.51], "category_id": 1}, {"id": 1, "bbox": [729.9, 118.37, 179.01, 39.03], "category_id": 2}, {"id": 2, "bbox": [1381.65, 400.44, 123.54, 40.29], "category_id": 2}, {"id": 3, "bbox": [1679.16, 171.26, 127.32, 44.07], "category_id": 2}, {"id": 4, "bbox": [2072.48, 647.24, 126.06, 40.3], "category_id": 2}, {"id": 5, "bbox": [813.11, 594.36, 108.41, 44.07], "category_id": 2}, {"id": 6, "bbox": [292.47, 0.0, 581.15, 54.15], "category_id": 2}, {"id": 7, "bbox": [505.51, 186.37, 63.03, 49.11], "category_id": 3}, {"id": 8, "bbox": [1047.58, 211.55, 455.09, 49.11], "category_id": 2}, {"id": 9, "bbox": [153.96, 180.76, 108.33, 39.91], "category_id": 2}, {"id": 10, "bbox": [2419.3, 344.2, 51.32, 47.51], "category_id": 3}, {"id": 11, "bbox": [325.0, 346.1, 55.12, 47.51], "category_id": 3}, {"id": 12, "bbox": [2398.4, 712.89, 53.21, 43.71], "category_id": 3}, {"id": 13, "bbox": [1967.0, 709.09, 58.91, 49.41], "category_id": 3}, {"id": 14, "bbox": [1731.34, 427.82, 57.01, 45.61], "category_id": 3}, {"id": 15, "bbox": [191.97, 709.09, 57.02, 47.51], "category_id": 3}, {"id": 16, "bbox": [2010.71, 192.16, 55.11, 39.91], "category_id": 3}, {"id": 17, "bbox": [2312.88, 182.66, 112.12, 47.51], "category_id": 2}, {"id": 18, "bbox": [1200.12, 370.21, 147.49, 50.37], "category_id": 2}, {"id": 19, "bbox": [1355.18, 270.73, 190.35, 114.59], "category_id": 1}, {"id": 20, "bbox": [695.87, 318.59, 306.33, 146.07], "category_id": 1}, {"id": 21, "bbox": [1009.76, 270.73, 187.84, 114.59], "category_id": 1}, {"id": 22, "bbox": [1047.58, 399.18, 121.02, 41.55], "category_id": 2}, {"id": 23, "bbox": [287.42, 760.57, 591.24, 49.11], "category_id": 2}, {"id": 24, "bbox": [2216.19, 515.02, 303.81, 239.26], "category_id": 1}, {"id": 25, "bbox": [1582.09, 318.59, 306.33, 156.14], "category_id": 1}, {"id": 26, "bbox": [345.41, 590.58, 153.8, 46.59], "category_id": 2}, {"id": 27, "bbox": [847.14, 424.36, 61.77, 51.63], "category_id": 3}, {"id": 28, "bbox": [1664.82, 762.3, 701.27, 45.61], "category_id": 2}, {"id": 29, "bbox": [2212.41, 270.73, 262.21, 219.11], "category_id": 1}, {"id": 30, "bbox": [118.5, 273.25, 264.73, 222.89], "category_id": 1}, {"id": 31, "bbox": [526.94, 567.91, 279.86, 188.89], "category_id": 1}, {"id": 32, "bbox": [2048.52, 522.58, 185.32, 113.33], "category_id": 1}, {"id": 33, "bbox": [729.9, 171.26, 186.58, 52.88], "category_id": 2}, {"id": 34, "bbox": [1652.69, 590.58, 108.41, 46.59], "category_id": 2}, {"id": 35, "bbox": [1776.23, 566.65, 281.12, 190.15], "category_id": 1}, {"id": 36, "bbox": [1653.95, 50.37, 177.75, 110.81], "category_id": 1}, {"id": 37, "bbox": [1653.95, 590.58, 107.15, 46.59], "category_id": 2}, {"id": 38, "bbox": [348.3, 74.29, 353.87, 145.41], "category_id": 1}, {"id": 39, "bbox": [1652.69, 0.0, 709.73, 56.67], "category_id": 2}, {"id": 40, "bbox": [3.8, 512.51, 312.62, 244.29], "category_id": 1}, {"id": 41, "bbox": [334.0, 647.24, 175.29, 47.85], "category_id": 2}], "caption": "Scheme 1. Possible Mechanisms for Oxidative Coupling", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 359, 76], "ImageBB": [110, 80, 740, 283]}, "reactions": [{"reactants": [38], "conditions": [9], "products": [30]}, {"reactants": [20], "conditions": [1, 33], "products": [38]}, {"reactants": [20], "conditions": [5], "products": [31]}, {"reactants": [31], "conditions": [26, 41], "products": [40]}, {"reactants": [40], "conditions": [], "products": [30]}, {"reactants": [18], "conditions": [21, 22], "products": [20]}, {"reactants": [18], "conditions": [19, 2], "products": [25]}, {"reactants": [25], "conditions": [36, 3], "products": [0]}, {"reactants": [0], "conditions": [17], "products": [29]}, {"reactants": [25], "conditions": [37], "products": [35]}, {"reactants": [35], "conditions": [32, 4], "products": [24]}, {"reactants": [24], "conditions": [], "products": [29]}], "diagram_type": "graph"}, {"id": 1273, "width": 2120, "height": 1432, "file_name": "op100072y-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [248.16, 911.4, 45.61, 49.87], "category_id": 3}, {"id": 1, "bbox": [327.7, 296.02, 106.06, 56.23], "category_id": 2}, {"id": 2, "bbox": [1851.69, 1381.43, 66.81, 50.57], "category_id": 3}, {"id": 3, "bbox": [160.14, 1381.43, 71.06, 50.57], "category_id": 3}, {"id": 4, "bbox": [48.78, 674.8, 440.12, 216.45], "category_id": 1}, {"id": 5, "bbox": [1360.66, 352.25, 56.21, 62.6], "category_id": 2}, {"id": 6, "bbox": [453.91, 1218.03, 269.37, 163.4], "category_id": 2}, {"id": 7, "bbox": [1591.2, 412.59, 36.1, 44.7], "category_id": 3}, {"id": 8, "bbox": [1060.53, 1381.43, 65.75, 50.57], "category_id": 3}, {"id": 9, "bbox": [965.08, 197.35, 49.85, 56.23], "category_id": 3}, {"id": 10, "bbox": [746.61, 978.25, 567.39, 409.55], "category_id": 1}, {"id": 11, "bbox": [802.82, 667.37, 425.27, 213.27], "category_id": 1}, {"id": 12, "bbox": [1564.28, 669.49, 414.67, 213.27], "category_id": 1}, {"id": 13, "bbox": [1469.89, 493.37, 101.82, 56.23], "category_id": 2}, {"id": 14, "bbox": [522.5, 701.33, 259.11, 75.33], "category_id": 2}, {"id": 15, "bbox": [596.02, 448.81, 41.36, 51.98], "category_id": 3}, {"id": 16, "bbox": [1729.72, 0.0, 383.92, 558.09], "category_id": 1}, {"id": 17, "bbox": [1729.72, 908.22, 67.88, 55.17], "category_id": 3}, {"id": 18, "bbox": [777.37, 305.57, 308.61, 124.14], "category_id": 2}, {"id": 19, "bbox": [865.39, 4.24, 156.96, 264.19], "category_id": 1}, {"id": 20, "bbox": [551.48, 140.05, 180.29, 291.78], "category_id": 1}, {"id": 21, "bbox": [458.15, 1025.99, 243.92, 167.64], "category_id": 2}, {"id": 22, "bbox": [1114.62, 0.0, 234.37, 559.15], "category_id": 1}, {"id": 23, "bbox": [48.78, 146.42, 174.99, 292.84], "category_id": 1}, {"id": 24, "bbox": [1772.15, 569.76, 46.66, 47.75], "category_id": 3}, {"id": 25, "bbox": [86.96, 448.81, 48.79, 51.98], "category_id": 3}, {"id": 26, "bbox": [1328.84, 1221.22, 230.14, 125.2], "category_id": 2}, {"id": 27, "bbox": [1367.02, 1135.28, 150.6, 58.35], "category_id": 2}, {"id": 28, "bbox": [1273.7, 707.69, 264.07, 68.97], "category_id": 2}, {"id": 29, "bbox": [261.95, 201.59, 224.83, 70.03], "category_id": 2}, {"id": 30, "bbox": [979.93, 906.1, 54.09, 55.17], "category_id": 3}, {"id": 31, "bbox": [1552.62, 971.88, 567.38, 409.55], "category_id": 1}, {"id": 32, "bbox": [1360.66, 822.28, 100.75, 58.36], "category_id": 2}, {"id": 33, "bbox": [1406.26, 291.78, 221.65, 192.04], "category_id": 1}, {"id": 34, "bbox": [0.0, 1119.36, 412.55, 214.32], "category_id": 1}, {"id": 35, "bbox": [1360.66, 207.96, 303.31, 67.9], "category_id": 2}, {"id": 36, "bbox": [551.48, 805.3, 180.29, 58.36], "category_id": 2}, {"id": 37, "bbox": [1167.64, 569.76, 43.49, 45.62], "category_id": 3}], "caption": "Scheme 1. Medicinal Chemistry route (conversion of sodium salt 12 to target acid 1 not shown)", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 394, 587, 408], "ImageBB": [145, 413, 675, 771]}, "reactions": [{"reactants": [23], "conditions": [29, 1], "products": [20]}, {"reactants": [20, 19], "conditions": [18], "products": [22]}, {"reactants": [22, 33], "conditions": [35, 13], "products": [16]}, {"reactants": [4], "conditions": [14, 36], "products": [11]}, {"reactants": [11], "conditions": [28, 32], "products": [12]}, {"reactants": [34], "conditions": [21, 6], "products": [10]}, {"reactants": [10], "conditions": [27, 26], "products": [31]}], "diagram_type": "multiple"}, {"id": 337, "width": 1348, "height": 988, "file_name": "ol203001w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [252.0, 340.0, 52.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [1055.0, 330.0, 44.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [473.8, 50.2, 339.3, 112.8], "category_id": 2}, {"id": 3, "bbox": [499.0, 209.6, 280.8, 49.4], "category_id": 2}, {"id": 4, "bbox": [4.5, 416.0, 1343.5, 569.0], "category_id": 4}, {"id": 5, "bbox": [110.2, 0.0, 341.5, 360.1], "category_id": 1}, {"id": 6, "bbox": [898.6, 28.9, 336.5, 305.7], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [2, 3], "products": [6]}], "corefs": [[5, 0], [6, 1]], "caption": "Table 2. Copper-Catalyzed Reactions of 1b fa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 320, 101], "ImageBB": [71, 112, 408, 359]}, "diagram_type": "single"}, {"id": 409, "width": 1352, "height": 1536, "file_name": "op400278d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.6, 306.8, 435.9, 373.1], "category_id": 1}, {"id": 1, "bbox": [1004.0, 1.4, 278.0, 222.7], "category_id": 1}, {"id": 2, "bbox": [310.3, 52.4, 187.3, 131.7], "category_id": 1}, {"id": 3, "bbox": [22.6, 19.0, 172.8, 171.3], "category_id": 1}, {"id": 4, "bbox": [45.96, 208.0, 65.89, 51.48], "category_id": 3}, {"id": 5, "bbox": [1145.46, 212.12, 67.94, 45.3], "category_id": 3}, {"id": 6, "bbox": [912.5, 312.9, 435.4, 365.9], "category_id": 1}, {"id": 7, "bbox": [615.0, 144.0, 285.1, 63.9], "category_id": 2}, {"id": 8, "bbox": [547.2, 19.5, 412.1, 97.0], "category_id": 2}, {"id": 9, "bbox": [260.06, 206.94, 243.74, 53.26], "category_id": 3}, {"id": 10, "bbox": [909.7, 888.9, 434.1, 417.2], "category_id": 1}, {"id": 11, "bbox": [458.3, 923.9, 437.1, 386.1], "category_id": 1}, {"id": 12, "bbox": [2.0, 891.2, 442.0, 418.8], "category_id": 1}, {"id": 13, "bbox": [464.1, 311.8, 434.2, 367.0], "category_id": 1}, {"id": 14, "bbox": [560.5, 723.6, 226.4, 119.1], "category_id": 3}, {"id": 15, "bbox": [20.0, 724.0, 421.0, 158.0], "category_id": 3}, {"id": 16, "bbox": [926.0, 714.0, 426.0, 142.0], "category_id": 3}, {"id": 17, "bbox": [113.0, 1330.1, 229.0, 130.9], "category_id": 3}, {"id": 18, "bbox": [1026.2, 1335.4, 205.8, 124.1], "category_id": 3}, {"id": 19, "bbox": [457.0, 1329.4, 440.0, 173.7], "category_id": 3}], "reactions": [{"reactants": [3, 2], "conditions": [8, 7], "products": [1]}], "corefs": [[3, 4], [2, 9], [1, 5], [0, 15], [13, 14], [6, 16], [12, 17], [11, 19], [10, 18]], "caption": "Table 2. Optimization of NHC and pyridine ligand sterics in aryl sul\ufb01nations ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 515]}, "diagram_type": "single"}, {"id": 198, "width": 1344, "height": 2476, "file_name": "op049899l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [817.0, 85.0, 343.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [733.0, 741.0, 56.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [1181.0, 748.0, 55.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [276.0, 309.0, 63.0, 59.0], "category_id": 3}, {"id": 4, "bbox": [622.0, 202.0, 62.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [811.0, 149.0, 349.0, 263.0], "category_id": 1}, {"id": 6, "bbox": [563.0, 99.0, 172.0, 74.0], "category_id": 1}, {"id": 7, "bbox": [88.0, 467.0, 341.0, 282.0], "category_id": 1}, {"id": 8, "bbox": [501.0, 458.0, 316.0, 348.0], "category_id": 1}, {"id": 9, "bbox": [914.0, 436.0, 326.0, 342.0], "category_id": 1}, {"id": 10, "bbox": [193.3, 3.0, 268.7, 317.0], "category_id": 1}, {"id": 11, "bbox": [8.0, 842.0, 1336.0, 1634.0], "category_id": 4}, {"id": 12, "bbox": [312.0, 739.0, 58.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [10, 6], "conditions": [0, 5], "products": [7, 8, 9]}], "corefs": [[10, 3], [6, 4], [7, 12], [8, 1], [9, 2]], "caption": "Table 2. Optimization of the coupling of 5a and 18", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 355, 67], "ImageBB": [74, 75, 410, 694]}, "diagram_type": "multiple"}, {"id": 676, "width": 1344, "height": 1304, "file_name": "ol4017244-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.0, 751.0, 397.0, 205.0], "category_id": 1}, {"id": 1, "bbox": [49.0, 751.0, 355.0, 195.0], "category_id": 1}, {"id": 2, "bbox": [748.0, 1029.0, 433.0, 216.0], "category_id": 1}, {"id": 3, "bbox": [127.0, 1051.0, 548.0, 202.0], "category_id": 1}, {"id": 4, "bbox": [506.0, 438.0, 390.0, 206.0], "category_id": 1}, {"id": 5, "bbox": [945.0, 747.0, 374.0, 195.0], "category_id": 1}, {"id": 6, "bbox": [25.0, 438.0, 416.0, 215.0], "category_id": 1}, {"id": 7, "bbox": [954.0, 171.0, 368.0, 215.0], "category_id": 1}, {"id": 8, "bbox": [611.0, 661.0, 151.0, 41.0], "category_id": 3}, {"id": 9, "bbox": [197.0, 391.0, 16.0, 31.0], "category_id": 3}, {"id": 10, "bbox": [457.0, 391.0, 24.0, 31.0], "category_id": 3}, {"id": 11, "bbox": [1116.0, 387.0, 24.0, 33.0], "category_id": 3}, {"id": 12, "bbox": [165.0, 657.0, 149.0, 40.0], "category_id": 3}, {"id": 13, "bbox": [408.1, 292.32, 122.67, 58.82], "category_id": 2}, {"id": 14, "bbox": [1004.0, 662.0, 129.0, 43.0], "category_id": 3}, {"id": 15, "bbox": [175.0, 952.0, 142.0, 41.0], "category_id": 3}, {"id": 16, "bbox": [616.0, 956.0, 147.0, 43.0], "category_id": 3}, {"id": 17, "bbox": [1006.0, 957.0, 141.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [290.0, 1256.0, 145.0, 42.0], "category_id": 3}, {"id": 19, "bbox": [970.0, 1254.0, 123.0, 38.0], "category_id": 3}, {"id": 20, "bbox": [916.3, 451.0, 373.7, 196.0], "category_id": 1}, {"id": 21, "bbox": [582.0, 154.0, 369.0, 173.3], "category_id": 2}, {"id": 22, "bbox": [26.0, 229.0, 369.6, 161.0], "category_id": 1}], "reactions": [{"reactants": [22, 13], "conditions": [21], "products": [7]}], "corefs": [[22, 9], [13, 10], [7, 11], [6, 12], [4, 8], [20, 14], [1, 15], [0, 16], [5, 17], [3, 18], [2, 19]], "caption": "Figure 2. Scope of isocyanides. Reaction conditions: All reac- tions were performed with 1 (0.2 mmol) and 2 (3 equiv), in 0.4 mL of H2O and 1.0 mL of acetone at 0 \u00b0C, in Ar, for 20 min; isolated yields of 3. a The reaction was performed with 5 equiv of 2. b The reaction was performed with 3 equiv of 1, and 2 (0.2 mmol, 1 equiv). ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 398, 771, 481], "ImageBB": [437, 59, 773, 385]}, "diagram_type": "single"}, {"id": 24, "width": 1348, "height": 1228, "file_name": "ja905415r-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [545.22, 89.83, 331.58, 108.17], "category_id": 2}, {"id": 1, "bbox": [527.79, 213.43, 363.27, 54.28], "category_id": 2}, {"id": 2, "bbox": [256.84, 313.25, 54.29, 44.78], "category_id": 3}, {"id": 3, "bbox": [1099.8, 313.25, 59.05, 44.78], "category_id": 3}, {"id": 4, "bbox": [969.87, 2.68, 263.45, 304.65], "category_id": 1}, {"id": 5, "bbox": [1.73, 367.12, 1342.5, 859.23], "category_id": 4}, {"id": 6, "bbox": [107.9, 61.31, 350.59, 244.43], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [0, 1], "products": [4]}], "corefs": [[6, 2], [4, 3]], "caption": "Table 3. Asymmetric Au(I)-Catalyzed [4C+2C] Cycloadditions and Development of an Efficient Enantioselective Chiral Gold Catalysta ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 57, 758, 81], "ImageBB": [425, 90, 762, 397]}, "diagram_type": "single"}, {"id": 1239, "width": 1340, "height": 1424, "file_name": "op025538z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [565.06, 572.73, 58.43, 32.77], "category_id": 2}, {"id": 1, "bbox": [438.94, 250.75, 419.7, 42.03], "category_id": 2}, {"id": 2, "bbox": [324.93, 1376.27, 590.0, 47.73], "category_id": 2}, {"id": 3, "bbox": [652.0, 573.45, 71.25, 33.48], "category_id": 2}, {"id": 4, "bbox": [517.32, 1064.26, 286.45, 304.89], "category_id": 1}, {"id": 5, "bbox": [350.58, 348.3, 207.36, 150.9], "category_id": 1}, {"id": 6, "bbox": [583.59, 0.0, 166.51, 247.9], "category_id": 1}, {"id": 7, "bbox": [0.0, 975.93, 599.27, 92.6], "category_id": 2}, {"id": 8, "bbox": [188.12, 618.33, 218.75, 348.34], "category_id": 1}, {"id": 9, "bbox": [872.18, 475.14, 43.47, 38.47], "category_id": 2}, {"id": 10, "bbox": [692.29, 188.0, 75.22, 46.15], "category_id": 2}, {"id": 11, "bbox": [372.62, 475.19, 76.93, 46.16], "category_id": 2}, {"id": 12, "bbox": [878.59, 608.35, 297.14, 349.77], "category_id": 1}, {"id": 13, "bbox": [676.22, 975.93, 659.84, 91.18], "category_id": 2}, {"id": 14, "bbox": [773.85, 423.14, 90.49, 38.47], "category_id": 2}], "caption": "Scheme 1. Reaction scheme of solid-liquid phase transfer catalysed C-alkylation of p-chlorophenyl acetonitrile with isopropyl bromide under alkaline conditions ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 768, 95], "ImageBB": [440, 103, 775, 459]}, "reactions": [{"reactants": [6, 5, 14], "conditions": [], "products": [8, 12, 4]}], "diagram_type": "tree"}, {"id": 234, "width": 1344, "height": 772, "file_name": "op000095p-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [328.0, 8.0, 232.0, 336.0], "category_id": 1}, {"id": 1, "bbox": [788.0, 2.0, 230.0, 343.0], "category_id": 1}, {"id": 2, "bbox": [635.0, 147.0, 39.0, 49.0], "category_id": 2}, {"id": 3, "bbox": [7.0, 376.0, 1337.0, 395.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [2], "products": [1]}], "corefs": [], "caption": "Table 3. Results from Oxidation of Benzaldehydes with the Modified Alkaline Nitrobenzene Method ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 400, 81], "ImageBB": [74, 89, 410, 282]}, "diagram_type": "single"}, {"id": 893, "width": 3396, "height": 1176, "file_name": "acs.oprd.5b00070-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2345.0, 904.0, 265.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [1513.0, 890.0, 285.0, 64.0], "category_id": 3}, {"id": 2, "bbox": [766.0, 897.0, 278.0, 57.0], "category_id": 3}, {"id": 3, "bbox": [639.0, 444.0, 558.0, 452.0], "category_id": 1}, {"id": 4, "bbox": [1389.0, 444.0, 517.0, 438.0], "category_id": 1}, {"id": 5, "bbox": [2188.0, 477.0, 527.0, 398.0], "category_id": 1}, {"id": 6, "bbox": [1896.0, 397.0, 222.0, 83.0], "category_id": 2}, {"id": 7, "bbox": [1455.0, 279.0, 419.0, 72.0], "category_id": 2}, {"id": 8, "bbox": [1231.0, 393.0, 222.0, 93.0], "category_id": 2}, {"id": 9, "bbox": [1557.0, 1028.0, 219.0, 54.0], "category_id": 2}, {"id": 10, "bbox": [1438.0, 1109.0, 455.0, 58.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [8], "products": [4]}, {"reactants": [4], "conditions": [6], "products": [5]}, {"reactants": [3], "conditions": [9, 10], "products": [5]}], "corefs": [[3, 2], [4, 1], [5, 0]], "caption": "Figure 1. Comparison of the industrially used two-step process (red) and the presented new one-step process (green).", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 325, 660, 339], "ImageBB": [10, 22, 859, 316]}, "diagram_type": "graph"}, {"id": 815, "width": 1348, "height": 500, "file_name": "jo4014707-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1034.0, 28.0, 257.0, 253.0], "category_id": 1}, {"id": 1, "bbox": [15.0, 386.0, 1313.0, 114.0], "category_id": 4}, {"id": 2, "bbox": [115.0, 307.0, 36.9, 41.0], "category_id": 3}, {"id": 3, "bbox": [60.05, 38.0, 166.0, 244.0], "category_id": 1}, {"id": 4, "bbox": [1111.0, 304.0, 96.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [672.0, 183.0, 206.0, 68.0], "category_id": 2}, {"id": 6, "bbox": [378.0, 232.0, 36.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [312.0, 141.0, 183.0, 56.0], "category_id": 2}, {"id": 8, "bbox": [526.0, 4.0, 490.0, 147.0], "category_id": 2}], "reactions": [{"reactants": [3, 7], "conditions": [8, 5], "products": [0]}], "corefs": [[3, 2], [7, 6], [0, 4]], "caption": "Table 4. Asymmetric 1,4-Addition of Arylboronic Acids (2) to N-R-maleimide (6)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 126], "ImageBB": [449, 131, 786, 256]}, "diagram_type": "single"}, {"id": 841, "width": 1352, "height": 540, "file_name": "jo201996w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1142.0, 357.0, 27.0, 35.0], "category_id": 3}, {"id": 1, "bbox": [8.0, 421.0, 1336.0, 119.0], "category_id": 4}, {"id": 2, "bbox": [740.0, 132.0, 181.0, 35.0], "category_id": 2}, {"id": 3, "bbox": [15.0, 61.0, 379.0, 205.0], "category_id": 1}, {"id": 4, "bbox": [955.0, 3.0, 384.0, 319.0], "category_id": 1}, {"id": 5, "bbox": [509.0, 59.0, 191.0, 201.0], "category_id": 1}, {"id": 6, "bbox": [129.0, 353.0, 121.0, 37.0], "category_id": 3}, {"id": 7, "bbox": [521.0, 352.0, 94.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [3, 5], "conditions": [2], "products": [4]}], "corefs": [[3, 6], [5, 7], [4, 0]], "caption": "Table 2. Synthesis of 2,2\u2033-Dinitrogen-Substituted Bisazo- benzenes 4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [436, 81, 771, 112], "ImageBB": [436, 119, 774, 254]}, "diagram_type": "single"}, {"id": 313, "width": 1356, "height": 1580, "file_name": "ol302400p-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1239.0, 207.0, 48.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [206.0, 61.0, 184.0, 67.0], "category_id": 1}, {"id": 2, "bbox": [675.0, 26.0, 365.0, 169.0], "category_id": 1}, {"id": 3, "bbox": [1066.0, 77.0, 290.0, 117.0], "category_id": 1}, {"id": 4, "bbox": [294.0, 209.0, 50.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [409.0, 113.0, 228.0, 49.0], "category_id": 2}, {"id": 6, "bbox": [449.0, 49.0, 131.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [3.0, 299.0, 1346.0, 1281.0], "category_id": 4}, {"id": 8, "bbox": [26.0, 207.0, 44.0, 40.0], "category_id": 3}, {"id": 9, "bbox": [796.0, 205.0, 37.0, 42.0], "category_id": 3}, {"id": 10, "bbox": [3.0, 0.0, 186.0, 153.0], "category_id": 1}], "reactions": [{"reactants": [10, 1], "conditions": [6, 5], "products": [2, 3]}], "corefs": [[10, 8], [1, 4], [2, 9], [3, 0]], "caption": "Table 1. Reaction Condition Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 450, 669, 466], "ImageBB": [436, 477, 775, 872]}, "diagram_type": "single"}, {"id": 359, "width": 1396, "height": 2168, "file_name": "ol1030487-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [780.0, 908.0, 267.0, 219.0], "category_id": 1}, {"id": 1, "bbox": [363.0, 920.0, 306.0, 226.0], "category_id": 1}, {"id": 2, "bbox": [393.0, 773.0, 33.0, 41.0], "category_id": 3}, {"id": 3, "bbox": [751.0, 441.0, 91.0, 48.0], "category_id": 2}, {"id": 4, "bbox": [575.0, 428.0, 147.0, 77.0], "category_id": 2}, {"id": 5, "bbox": [54.0, 527.0, 290.0, 166.0], "category_id": 1}, {"id": 6, "bbox": [48.0, 924.0, 316.0, 218.0], "category_id": 1}, {"id": 7, "bbox": [0.0, 1261.0, 1373.0, 907.0], "category_id": 4}, {"id": 8, "bbox": [659.0, 688.0, 40.0, 41.0], "category_id": 3}, {"id": 9, "bbox": [1314.0, 824.0, 24.0, 44.0], "category_id": 3}, {"id": 10, "bbox": [1269.0, 640.0, 34.0, 47.0], "category_id": 3}, {"id": 11, "bbox": [1021.0, 736.0, 156.0, 129.0], "category_id": 2}, {"id": 12, "bbox": [256.0, 716.0, 203.0, 84.0], "category_id": 1}, {"id": 13, "bbox": [267.0, 836.0, 188.0, 45.0], "category_id": 2}, {"id": 14, "bbox": [78.0, 716.0, 158.0, 131.0], "category_id": 2}, {"id": 15, "bbox": [333.0, 619.0, 244.0, 89.0], "category_id": 2}, {"id": 16, "bbox": [840.0, 613.0, 174.0, 133.0], "category_id": 2}, {"id": 17, "bbox": [1194.0, 756.0, 193.0, 81.0], "category_id": 1}, {"id": 18, "bbox": [1060.0, 523.0, 281.0, 177.0], "category_id": 1}, {"id": 19, "bbox": [612.0, 248.0, 231.0, 110.0], "category_id": 1}, {"id": 20, "bbox": [650.0, 70.0, 198.0, 81.0], "category_id": 1}, {"id": 21, "bbox": [180.0, 283.0, 323.0, 214.0], "category_id": 1}, {"id": 22, "bbox": [533.0, 533.0, 294.0, 149.0], "category_id": 1}, {"id": 23, "bbox": [727.0, 137.0, 25.0, 48.0], "category_id": 3}, {"id": 24, "bbox": [315.0, 208.0, 37.0, 35.0], "category_id": 3}, {"id": 25, "bbox": [381.0, 460.0, 50.0, 37.0], "category_id": 3}, {"id": 26, "bbox": [1167.0, 204.0, 35.0, 40.0], "category_id": 3}, {"id": 27, "bbox": [722.0, 351.0, 34.0, 39.0], "category_id": 3}, {"id": 28, "bbox": [101.0, 642.0, 33.0, 43.0], "category_id": 3}, {"id": 29, "bbox": [1116.0, 903.0, 274.0, 220.0], "category_id": 1}, {"id": 30, "bbox": [447.0, 1157.0, 86.0, 39.0], "category_id": 3}, {"id": 31, "bbox": [873.0, 1139.0, 88.0, 42.0], "category_id": 3}, {"id": 32, "bbox": [968.0, 29.0, 316.0, 218.0], "category_id": 1}, {"id": 33, "bbox": [98.0, 16.0, 475.0, 222.0], "category_id": 1}, {"id": 34, "bbox": [1206.0, 1131.0, 88.0, 46.0], "category_id": 3}, {"id": 35, "bbox": [156.0, 1158.0, 92.0, 36.0], "category_id": 3}, {"id": 36, "bbox": [853.0, 556.0, 127.0, 52.0], "category_id": 1}, {"id": 37, "bbox": [387.0, 566.0, 123.0, 49.0], "category_id": 1}], "reactions": [{"reactants": [20, 19], "conditions": [4, 3], "products": [22]}, {"reactants": [22], "conditions": [37, 15], "products": [5]}, {"reactants": [5], "conditions": [14, 12, 13], "products": [6, 1]}, {"reactants": [22], "conditions": [36, 16], "products": [18]}, {"reactants": [18], "conditions": [11, 17], "products": [0, 29]}], "corefs": [[33, 24], [20, 23], [32, 26], [19, 27], [21, 25], [22, 8], [5, 28], [12, 2], [6, 35], [1, 30], [18, 10], [17, 9], [0, 31], [29, 34]], "caption": "Table 3. Scope of the Organocatalytic Michael- Wittig-Michael-Michael Reaction ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 329, 114], "ImageBB": [71, 126, 420, 668]}, "diagram_type": "tree"}, {"id": 1180, "width": 1356, "height": 648, "file_name": "ol3023903-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.11, 385.3, 290.32, 169.59], "category_id": 1}, {"id": 1, "bbox": [339.85, 198.08, 170.94, 71.9], "category_id": 2}, {"id": 2, "bbox": [527.75, 37.31, 438.88, 225.89], "category_id": 1}, {"id": 3, "bbox": [321.53, 438.21, 206.9, 33.24], "category_id": 2}, {"id": 4, "bbox": [0.0, 2.71, 341.2, 304.58], "category_id": 1}, {"id": 5, "bbox": [572.52, 297.12, 312.71, 291.69], "category_id": 1}, {"id": 6, "bbox": [718.36, 267.27, 40.7, 33.92], "category_id": 3}, {"id": 7, "bbox": [195.36, 267.95, 42.06, 33.24], "category_id": 3}, {"id": 8, "bbox": [106.5, 563.03, 29.85, 33.92], "category_id": 3}, {"id": 9, "bbox": [353.41, 330.36, 156.02, 108.53], "category_id": 1}, {"id": 10, "bbox": [718.36, 563.03, 41.38, 35.27], "category_id": 3}, {"id": 11, "bbox": [1290.88, 161.45, 65.12, 44.09], "category_id": 3}, {"id": 12, "bbox": [323.57, 147.88, 204.86, 36.63], "category_id": 2}, {"id": 13, "bbox": [1292.91, 459.24, 59.02, 40.7], "category_id": 3}, {"id": 14, "bbox": [335.78, 487.73, 168.23, 78.01], "category_id": 2}, {"id": 15, "bbox": [1001.91, 341.21, 215.71, 71.23], "category_id": 2}, {"id": 16, "bbox": [353.41, 101.75, 143.13, 46.13], "category_id": 1}, {"id": 17, "bbox": [1017.51, 128.89, 196.72, 201.47], "category_id": 1}], "caption": "Scheme 5. Combination of the Xanthate Addition with the Allylation Reaction ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 446, 750, 473], "ImageBB": [436, 484, 775, 646]}, "reactions": [{"reactants": [4, 16], "conditions": [12, 1], "products": [2]}, {"reactants": [0, 9], "conditions": [3, 14], "products": [5]}, {"reactants": [2], "conditions": [17, 15], "products": [11]}, {"reactants": [5], "conditions": [17, 15], "products": [13]}], "diagram_type": "tree"}, {"id": 1331, "width": 2820, "height": 916, "file_name": "op400242j-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [571.34, 330.1, 57.83, 47.96], "category_id": 3}, {"id": 1, "bbox": [1877.65, 323.04, 59.25, 49.38], "category_id": 3}, {"id": 2, "bbox": [842.19, 60.66, 407.69, 269.44], "category_id": 1}, {"id": 3, "bbox": [2173.9, 145.3, 163.64, 55.01], "category_id": 2}, {"id": 4, "bbox": [658.8, 483.86, 641.87, 371.01], "category_id": 1}, {"id": 5, "bbox": [1090.48, 334.33, 53.6, 46.55], "category_id": 3}, {"id": 6, "bbox": [2176.72, 203.14, 81.82, 42.32], "category_id": 2}, {"id": 7, "bbox": [428.85, 94.51, 339.98, 222.89], "category_id": 1}, {"id": 8, "bbox": [1862.13, 829.47, 36.68, 43.73], "category_id": 3}, {"id": 9, "bbox": [1496.76, 0.0, 639.05, 366.77], "category_id": 1}, {"id": 10, "bbox": [1496.76, 455.65, 643.28, 402.04], "category_id": 1}], "caption": "Scheme 9. Formation of the 22 in the coupling process and conversion to 5", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 512, 110], "ImageBB": [82, 116, 787, 345]}, "reactions": [{"reactants": [7, 2], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [3, 6], "products": [4]}, {"reactants": [4], "conditions": [], "products": [10]}], "diagram_type": "multiple"}, {"id": 837, "width": 1236, "height": 2336, "file_name": "jo300771f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [861.0, 1079.3, 309.0, 344.7], "category_id": 1}, {"id": 1, "bbox": [79.0, 744.0, 295.0, 248.0], "category_id": 1}, {"id": 2, "bbox": [471.0, 375.0, 304.0, 233.0], "category_id": 1}, {"id": 3, "bbox": [368.8, 688.0, 454.2, 341.0], "category_id": 1}, {"id": 4, "bbox": [815.5, 683.4, 393.7, 320.6], "category_id": 1}, {"id": 5, "bbox": [77.3, 1143.0, 301.7, 262.0], "category_id": 1}, {"id": 6, "bbox": [446.4, 1115.9, 372.6, 296.1], "category_id": 1}, {"id": 7, "bbox": [868.0, 21.5, 358.0, 233.5], "category_id": 1}, {"id": 8, "bbox": [14.0, 2.0, 362.1, 242.0], "category_id": 1}, {"id": 9, "bbox": [79.0, 1525.7, 299.6, 300.9], "category_id": 1}, {"id": 10, "bbox": [830.6, 1555.5, 362.3, 253.6], "category_id": 1}, {"id": 11, "bbox": [63.0, 1934.2, 618.0, 334.8], "category_id": 1}, {"id": 12, "bbox": [80.9, 380.3, 300.3, 219.7], "category_id": 1}, {"id": 13, "bbox": [859.7, 380.3, 310.3, 219.7], "category_id": 1}, {"id": 14, "bbox": [606.0, 1945.0, 615.0, 321.0], "category_id": 1}, {"id": 15, "bbox": [138.0, 1851.0, 166.8, 58.8], "category_id": 3}, {"id": 16, "bbox": [924.0, 1014.92, 167.0, 51.0], "category_id": 3}, {"id": 17, "bbox": [529.0, 1020.0, 190.3, 46.9], "category_id": 3}, {"id": 18, "bbox": [143.0, 1014.0, 183.5, 53.0], "category_id": 3}, {"id": 19, "bbox": [139.0, 621.0, 175.2, 42.0], "category_id": 3}, {"id": 20, "bbox": [545.0, 1428.0, 169.7, 52.7], "category_id": 3}, {"id": 21, "bbox": [477.3, 1511.3, 312.2, 348.2], "category_id": 1}, {"id": 22, "bbox": [545.11, 613.0, 164.0, 57.0], "category_id": 3}, {"id": 23, "bbox": [931.0, 613.0, 182.1, 52.0], "category_id": 3}, {"id": 24, "bbox": [487.78, 271.92, 58.3, 45.0], "category_id": 3}, {"id": 25, "bbox": [578.0, 32.0, 282.0, 93.1], "category_id": 2}, {"id": 26, "bbox": [657.0, 142.0, 123.3, 94.1], "category_id": 2}, {"id": 27, "bbox": [928.73, 1851.85, 164.27, 57.35], "category_id": 3}, {"id": 28, "bbox": [925.0, 1426.0, 175.4, 52.8], "category_id": 3}, {"id": 29, "bbox": [547.0, 1856.1, 167.8, 51.8], "category_id": 3}, {"id": 30, "bbox": [285.0, 2282.0, 186.8, 49.0], "category_id": 3}, {"id": 31, "bbox": [823.0, 2277.0, 170.9, 50.9], "category_id": 3}, {"id": 32, "bbox": [458.0, 100.0, 103.0, 63.0], "category_id": 2}, {"id": 33, "bbox": [1032.0, 276.0, 30.0, 43.0], "category_id": 3}, {"id": 34, "bbox": [172.0, 273.0, 37.0, 41.0], "category_id": 3}, {"id": 35, "bbox": [141.78, 1422.6, 172.66, 56.9], "category_id": 3}], "reactions": [{"reactants": [8, 32], "conditions": [25, 26], "products": [7]}], "corefs": [[8, 34], [32, 24], [7, 33], [12, 19], [2, 22], [13, 23], [1, 18], [3, 17], [4, 16], [5, 35], [6, 20], [0, 28], [9, 15], [21, 29], [10, 27], [11, 30], [14, 31]], "caption": "Table 2. Substrate Scopea,b", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 239, 109], "ImageBB": [96, 116, 405, 700]}, "diagram_type": "single"}, {"id": 1068, "width": 1356, "height": 1408, "file_name": "jo302142v-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1146.2, 929.7, 180.88, 192.69], "category_id": 1}, {"id": 1, "bbox": [1188.03, 1127.67, 131.69, 60.57], "category_id": 3}, {"id": 2, "bbox": [454.23, 1098.09, 197.18, 203.55], "category_id": 1}, {"id": 3, "bbox": [68.31, 1306.57, 140.14, 58.46], "category_id": 3}, {"id": 4, "bbox": [481.69, 1304.46, 141.55, 61.28], "category_id": 3}, {"id": 5, "bbox": [520.42, 172.57, 161.27, 55.64], "category_id": 2}, {"id": 6, "bbox": [479.58, 526.86, 164.08, 109.87], "category_id": 2}, {"id": 7, "bbox": [19.01, 726.19, 503.53, 312.03], "category_id": 3}, {"id": 8, "bbox": [90.85, 36.63, 320.42, 211.3], "category_id": 1}, {"id": 9, "bbox": [986.62, 767.74, 132.4, 64.1], "category_id": 3}, {"id": 10, "bbox": [283.8, 1306.57, 131.69, 54.24], "category_id": 3}, {"id": 11, "bbox": [1079.58, 636.73, 192.25, 253.57], "category_id": 1}, {"id": 12, "bbox": [773.24, 757.18, 142.25, 100.02], "category_id": 2}, {"id": 13, "bbox": [986.62, 1126.96, 135.92, 61.28], "category_id": 3}, {"id": 14, "bbox": [232.39, 1098.09, 201.41, 206.37], "category_id": 1}, {"id": 15, "bbox": [660.56, 1099.49, 194.37, 235.96], "category_id": 1}, {"id": 16, "bbox": [938.73, 901.0, 191.97, 228.08], "category_id": 1}, {"id": 17, "bbox": [751.3, 262.9, 512.8, 348.2], "category_id": 3}, {"id": 18, "bbox": [521.83, 757.18, 245.78, 250.75], "category_id": 1}, {"id": 19, "bbox": [732.39, 1304.46, 134.51, 61.28], "category_id": 3}, {"id": 20, "bbox": [775.35, 901.57, 158.45, 52.12], "category_id": 2}, {"id": 21, "bbox": [810.56, 0.0, 325.36, 249.34], "category_id": 1}, {"id": 22, "bbox": [454.93, 16.9, 292.96, 124.67], "category_id": 2}, {"id": 23, "bbox": [16.9, 1098.09, 200.71, 205.67], "category_id": 1}, {"id": 24, "bbox": [16.9, 258.5, 509.86, 361.33], "category_id": 3}], "caption": "Scheme 2. Synthesis of Aldehydes 5a\u2212c", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 422, 673, 437], "ImageBB": [448, 444, 787, 796]}, "reactions": [{"reactants": [8], "conditions": [22, 5], "products": [21]}, {"reactants": [17], "conditions": [6], "products": [18]}, {"reactants": [18], "conditions": [12, 20], "products": [11, 16, 0]}], "diagram_type": "tree"}, {"id": 228, "width": 1292, "height": 716, "file_name": "op000298d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [217.0, 651.0, 33.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [971.0, 651.0, 24.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [562.0, 532.0, 70.0, 41.0], "category_id": 2}, {"id": 3, "bbox": [484.0, 457.0, 226.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [1046.0, 225.0, 69.0, 34.0], "category_id": 2}, {"id": 5, "bbox": [934.0, 136.0, 304.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [667.0, 276.0, 33.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [235.0, 280.0, 22.0, 35.0], "category_id": 3}, {"id": 8, "bbox": [598.9, 78.9, 255.1, 248.1], "category_id": 1}, {"id": 9, "bbox": [131.0, 163.2, 296.0, 70.8], "category_id": 1}, {"id": 10, "bbox": [49.0, 428.2, 363.0, 287.8], "category_id": 1}, {"id": 11, "bbox": [803.0, 429.8, 363.0, 286.2], "category_id": 1}], "reactions": [{"reactants": [9, 8], "conditions": [5, 4], "products": [10]}, {"reactants": [10], "conditions": [3, 2], "products": [11]}], "corefs": [[9, 7], [8, 6], [10, 0], [11, 1]], "caption": "Table 1. Pilot plant lots of acrylate 5", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 244, 278, 258], "ImageBB": [74, 52, 397, 231]}, "diagram_type": "multiple"}, {"id": 1205, "width": 1352, "height": 700, "file_name": "ol8001706-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [926.58, 357.87, 83.87, 50.73], "category_id": 2}, {"id": 1, "bbox": [0.0, 347.04, 136.62, 50.74], "category_id": 2}, {"id": 2, "bbox": [0.0, 217.16, 140.0, 52.09], "category_id": 2}, {"id": 3, "bbox": [146.09, 432.96, 208.99, 54.79], "category_id": 2}, {"id": 4, "bbox": [128.5, 145.45, 206.29, 59.53], "category_id": 2}, {"id": 5, "bbox": [477.49, 2.71, 290.15, 202.95], "category_id": 1}, {"id": 6, "bbox": [417.3, 589.91, 434.21, 52.09], "category_id": 2}, {"id": 7, "bbox": [601.94, 543.9, 39.9, 43.3], "category_id": 3}, {"id": 8, "bbox": [1126.78, 178.6, 225.22, 203.62], "category_id": 1}, {"id": 9, "bbox": [397.01, 363.96, 495.76, 207.0], "category_id": 1}, {"id": 10, "bbox": [1204.56, 402.52, 60.87, 45.32], "category_id": 3}, {"id": 11, "bbox": [457.88, 260.45, 345.61, 51.42], "category_id": 2}, {"id": 12, "bbox": [620.88, 213.77, 42.61, 41.27], "category_id": 3}], "caption": "Scheme 1. Possible Pathways for the HDA Reaction between                Diene 1 and Benzaldehyde ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [443, 671, 772, 698], "ImageBB": [439, 702, 777, 877]}, "reactions": [{"reactants": [1, 2], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [], "products": [8]}, {"reactants": [9], "conditions": [0], "products": [8]}], "diagram_type": "graph"}, {"id": 880, "width": 1272, "height": 2092, "file_name": "ol7014434-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [405.0, 38.0, 99.0, 30.0], "category_id": 2}, {"id": 1, "bbox": [23.0, 277.0, 1197.0, 1815.0], "category_id": 4}, {"id": 2, "bbox": [195.0, 235.0, 22.0, 30.0], "category_id": 3}, {"id": 3, "bbox": [661.0, 229.0, 108.0, 38.0], "category_id": 3}, {"id": 4, "bbox": [933.0, 3.0, 268.0, 196.0], "category_id": 1}, {"id": 5, "bbox": [586.0, 10.0, 264.0, 202.0], "category_id": 1}, {"id": 6, "bbox": [1049.0, 223.0, 21.0, 28.0], "category_id": 3}, {"id": 7, "bbox": [75.0, 18.0, 260.0, 197.0], "category_id": 1}, {"id": 8, "bbox": [380.0, 112.0, 137.0, 32.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [0, 8], "products": [5, 4]}], "corefs": [[7, 2], [5, 3], [4, 6]], "caption": "Table 1. Selective Suzuki and Stille Reactions on 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 75, 719, 89], "ImageBB": [449, 90, 767, 613]}, "diagram_type": "single"}, {"id": 1217, "width": 1352, "height": 964, "file_name": "ol901584g-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [169.08, 682.07, 144.74, 183.38], "category_id": 1}, {"id": 1, "bbox": [344.93, 200.29, 390.25, 115.03], "category_id": 2}, {"id": 2, "bbox": [359.81, 327.5, 341.55, 175.26], "category_id": 1}, {"id": 3, "bbox": [344.93, 783.57, 389.57, 117.74], "category_id": 2}, {"id": 4, "bbox": [389.57, 686.81, 280.0, 74.43], "category_id": 1}, {"id": 5, "bbox": [745.32, 90.67, 423.39, 181.35], "category_id": 1}, {"id": 6, "bbox": [729.09, 682.07, 450.44, 183.38], "category_id": 1}, {"id": 7, "bbox": [531.6, 464.87, 39.23, 38.57], "category_id": 3}, {"id": 8, "bbox": [344.93, 527.12, 392.28, 117.74], "category_id": 2}, {"id": 9, "bbox": [359.81, 6.09, 340.88, 173.23], "category_id": 1}, {"id": 10, "bbox": [903.59, 853.95, 101.45, 43.3], "category_id": 2}, {"id": 11, "bbox": [745.32, 414.12, 421.36, 182.69], "category_id": 1}, {"id": 12, "bbox": [903.59, 581.25, 101.45, 43.31], "category_id": 2}, {"id": 13, "bbox": [169.08, 87.97, 144.74, 185.4], "category_id": 1}, {"id": 14, "bbox": [531.6, 140.07, 37.2, 39.25], "category_id": 3}, {"id": 15, "bbox": [903.59, 264.57, 101.45, 42.63], "category_id": 2}, {"id": 16, "bbox": [169.08, 414.12, 144.74, 184.72], "category_id": 1}], "caption": "Scheme 1. Synthesis of ADBP, ACBP, and DABP", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [94, 480, 357, 495], "ImageBB": [58, 502, 396, 743]}, "reactions": [{"reactants": [13, 9], "conditions": [1], "products": [5]}, {"reactants": [16, 2], "conditions": [8], "products": [11]}, {"reactants": [0, 4], "conditions": [3], "products": [6]}], "diagram_type": "multiple"}, {"id": 894, "width": 1352, "height": 1804, "file_name": "acs.joc.6b01262-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [891.6, 0.0, 342.9, 197.9], "category_id": 1}, {"id": 1, "bbox": [112.0, 46.0, 337.4, 150.7], "category_id": 1}, {"id": 2, "bbox": [579.0, 136.0, 237.0, 86.0], "category_id": 2}, {"id": 3, "bbox": [552.0, 18.0, 226.0, 117.0], "category_id": 2}, {"id": 4, "bbox": [1050.0, 187.0, 34.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [0.0, 297.0, 1352.0, 1507.0], "category_id": 4}, {"id": 6, "bbox": [267.0, 192.0, 28.0, 35.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [3, 2], "products": [0]}], "corefs": [[1, 6], [0, 4]], "caption": "Table 3. Substrate Scope of 2-Arylacetimidates for the Formation of Primary \u03b1-Ketoamidesa,b ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 321, 388, 352], "ImageBB": [82, 357, 420, 808]}, "diagram_type": "single"}, {"id": 392, "width": 3396, "height": 1520, "file_name": "op500221s-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2276.0, 337.1, 339.5, 266.7], "category_id": 1}, {"id": 1, "bbox": [1496.7, 390.0, 263.1, 217.0], "category_id": 1}, {"id": 2, "bbox": [1984.0, 308.0, 61.0, 44.0], "category_id": 2}, {"id": 3, "bbox": [1204.0, 305.0, 78.0, 57.0], "category_id": 2}, {"id": 4, "bbox": [1535.0, 613.0, 202.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [736.0, 692.0, 1913.0, 810.0], "category_id": 4}, {"id": 6, "bbox": [1027.0, 359.0, 441.0, 146.0], "category_id": 2}, {"id": 7, "bbox": [1808.0, 356.0, 437.0, 156.0], "category_id": 2}, {"id": 8, "bbox": [810.0, 618.0, 163.0, 43.0], "category_id": 3}, {"id": 9, "bbox": [746.0, 366.0, 258.0, 234.0], "category_id": 1}, {"id": 10, "bbox": [1808.0, 535.0, 434.0, 116.0], "category_id": 2}, {"id": 11, "bbox": [1048.0, 542.0, 417.0, 102.0], "category_id": 2}, {"id": 12, "bbox": [2344.0, 620.0, 200.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [9], "conditions": [6, 11], "products": [1]}, {"reactants": [1], "conditions": [7, 10], "products": [0]}], "corefs": [[9, 8], [1, 4], [0, 12]], "caption": "Figure 3. In situ IR monitoring of a series of shot-addition lithiation and borylation reactions at \u221265 \u00b0C.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 408, 587, 426], "ImageBB": [10, 22, 859, 402]}, "diagram_type": "single"}, {"id": 1151, "width": 1328, "height": 1520, "file_name": "ol048861q-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [127.7, 276.02, 86.66, 66.91], "category_id": 3}, {"id": 1, "bbox": [1027.7, 504.89, 298.73, 262.33], "category_id": 1}, {"id": 2, "bbox": [633.95, 281.34, 84.38, 59.31], "category_id": 3}, {"id": 3, "bbox": [906.08, 560.4, 43.33, 48.66], "category_id": 2}, {"id": 4, "bbox": [852.87, 89.72, 103.38, 60.07], "category_id": 2}, {"id": 5, "bbox": [1107.51, 796.88, 220.49, 63.87], "category_id": 3}, {"id": 6, "bbox": [514.61, 0.0, 309.37, 260.81], "category_id": 1}, {"id": 7, "bbox": [680.32, 1208.24, 99.58, 57.03], "category_id": 2}, {"id": 8, "bbox": [820.94, 1009.78, 507.01, 501.1], "category_id": 1}, {"id": 9, "bbox": [384.63, 625.79, 117.82, 61.59], "category_id": 2}, {"id": 10, "bbox": [344.34, 89.72, 107.18, 63.12], "category_id": 2}, {"id": 11, "bbox": [407.43, 564.96, 57.77, 51.71], "category_id": 2}, {"id": 12, "bbox": [127.7, 793.08, 82.86, 64.63], "category_id": 3}, {"id": 13, "bbox": [127.7, 1458.41, 86.66, 61.59], "category_id": 3}, {"id": 14, "bbox": [170.27, 952.76, 101.1, 60.07], "category_id": 2}, {"id": 15, "bbox": [1107.51, 279.06, 82.86, 58.55], "category_id": 3}, {"id": 16, "bbox": [1029.22, 0.0, 296.45, 263.09], "category_id": 1}, {"id": 17, "bbox": [636.23, 793.08, 84.38, 64.63], "category_id": 3}, {"id": 18, "bbox": [680.32, 1273.64, 103.38, 56.26], "category_id": 2}, {"id": 19, "bbox": [874.91, 32.7, 52.45, 44.1], "category_id": 2}, {"id": 20, "bbox": [874.91, 841.74, 145.95, 59.31], "category_id": 2}, {"id": 21, "bbox": [631.12, 401.39, 91.24, 45.62], "category_id": 2}, {"id": 22, "bbox": [123.85, 952.46, 40.14, 60.21], "category_id": 2}, {"id": 23, "bbox": [1101.9, 372.19, 38.32, 49.27], "category_id": 2}, {"id": 24, "bbox": [1151.17, 372.19, 94.89, 51.09], "category_id": 2}, {"id": 25, "bbox": [384.63, 25.09, 55.49, 55.51], "category_id": 2}, {"id": 26, "bbox": [514.61, 478.6, 315.46, 292.43], "category_id": 1}, {"id": 27, "bbox": [972.97, 1461.45, 78.29, 58.55], "category_id": 3}, {"id": 28, "bbox": [1107.51, 888.12, 220.49, 64.64], "category_id": 3}, {"id": 29, "bbox": [0.0, 475.24, 348.9, 296.55], "category_id": 1}, {"id": 30, "bbox": [0.0, 1083.54, 679.56, 336.09], "category_id": 1}, {"id": 31, "bbox": [874.91, 628.83, 105.66, 58.55], "category_id": 2}, {"id": 32, "bbox": [104.9, 12.17, 189.27, 142.19], "category_id": 1}], "caption": "Scheme 3. Synthesis of Asymmetric Cyclic COA Trimer 24a", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [78, 74, 405, 88], "ImageBB": [76, 93, 408, 473]}, "reactions": [{"reactants": [32], "conditions": [25, 10], "products": [6]}, {"reactants": [6], "conditions": [19, 4], "products": [16]}, {"reactants": [16], "conditions": [23, 24], "products": [1]}, {"reactants": [1], "conditions": [3, 31], "products": [26]}, {"reactants": [26], "conditions": [11, 9], "products": [29]}, {"reactants": [29], "conditions": [22, 14], "products": [30]}, {"reactants": [30], "conditions": [7, 18], "products": [8]}], "diagram_type": "tree"}, {"id": 719, "width": 1348, "height": 1000, "file_name": "ol026509b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [727.0, 190.0, 38.3, 46.0], "category_id": 3}, {"id": 1, "bbox": [116.7, 4.0, 240.0, 145.0], "category_id": 1}, {"id": 2, "bbox": [1125.0, 197.0, 41.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [0.0, 292.0, 1348.0, 708.0], "category_id": 4}, {"id": 4, "bbox": [252.0, 193.0, 37.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [998.0, 7.0, 239.0, 148.0], "category_id": 1}, {"id": 6, "bbox": [596.0, 1.0, 241.0, 147.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [6, 5]}], "corefs": [[1, 4], [6, 0], [5, 2]], "caption": "Table 1. Lithiation of Azabicycle 4 and Electrophile Additions to Provide Methylene 6 and Bridgehead 8 E-Substituted Productsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 406, 120], "ImageBB": [74, 130, 411, 380]}, "diagram_type": "single"}, {"id": 807, "width": 1356, "height": 956, "file_name": "jo4027148-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [536.0, 217.0, 54.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [1005.0, 459.0, 58.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [421.0, 0.0, 90.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [404.0, 294.0, 315.0, 142.0], "category_id": 2}, {"id": 4, "bbox": [1.0, 531.0, 1355.0, 406.0], "category_id": 4}, {"id": 5, "bbox": [193.16, 460.0, 51.0, 54.0], "category_id": 3}, {"id": 6, "bbox": [789.0, 0.0, 481.1, 483.2], "category_id": 1}, {"id": 7, "bbox": [81.0, 70.3, 270.7, 329.7], "category_id": 1}, {"id": 8, "bbox": [462.0, 1.0, 199.7, 214.5], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [2, 8, 3], "products": [6]}], "corefs": [[7, 5], [8, 0], [6, 1]], "caption": "Table 1. Surprising E\ufb00ects of \u03b1 Substituents on C\u2212H Arylation Chemistry ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 752, 125], "ImageBB": [448, 131, 787, 370]}, "diagram_type": "single"}, {"id": 1315, "width": 2820, "height": 508, "file_name": "op300181r-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [626.35, 364.16, 114.27, 50.81], "category_id": 3}, {"id": 1, "bbox": [1491.2, 153.85, 61.99, 55.05], "category_id": 3}, {"id": 2, "bbox": [1309.13, 118.56, 77.59, 45.17], "category_id": 2}, {"id": 3, "bbox": [2053.99, 406.5, 117.09, 50.81], "category_id": 3}, {"id": 4, "bbox": [1579.99, 300.64, 172.11, 160.91], "category_id": 1}, {"id": 5, "bbox": [562.87, 211.72, 244.05, 132.68], "category_id": 1}, {"id": 6, "bbox": [1904.45, 76.22, 347.04, 321.81], "category_id": 1}, {"id": 7, "bbox": [1440.33, 4.23, 349.86, 228.66], "category_id": 1}, {"id": 8, "bbox": [1067.9, 203.25, 204.56, 149.62], "category_id": 1}, {"id": 9, "bbox": [1148.31, 379.68, 55.02, 47.99], "category_id": 3}, {"id": 10, "bbox": [1471.37, 366.98, 93.1, 50.81], "category_id": 2}], "caption": "Scheme 6. Proposed Mechanism of the Formation of Impurity 17", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 229, 453, 244], "ImageBB": [82, 251, 787, 378]}, "reactions": [{"reactants": [2, 8], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [8]}, {"reactants": [7, 8], "conditions": [], "products": [6]}], "diagram_type": "single"}, {"id": 274, "width": 1348, "height": 1616, "file_name": "ol8006259-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [890.67, 322.78, 122.87, 56.23], "category_id": 3}, {"id": 1, "bbox": [217.0, 280.0, 503.8, 71.4], "category_id": 2}, {"id": 2, "bbox": [378.0, 62.2, 350.2, 151.8], "category_id": 2}, {"id": 3, "bbox": [108.2, 48.9, 243.7, 128.9], "category_id": 1}, {"id": 4, "bbox": [792.6, 0.0, 500.2, 382.6], "category_id": 1}, {"id": 5, "bbox": [50.0, 214.0, 48.0, 72.0], "category_id": 3}, {"id": 6, "bbox": [9.0, 426.0, 1339.0, 1181.0], "category_id": 4}, {"id": 7, "bbox": [211.0, 184.0, 96.0, 63.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [3, 2, 1], "products": [4]}], "corefs": [[3, 7], [4, 0]], "caption": "Table 1. \u201cClick\u201d Synthesis of R-(N-Glycosyltriazolyl)-\u03b2-lactams 10a-e from R-Propargyl-\u03b2-lactam 4 and Glycosyl Azides 5 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 71, 757, 101], "ImageBB": [425, 111, 762, 515]}, "diagram_type": "single"}, {"id": 255, "width": 1352, "height": 1064, "file_name": "ol802141g-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [451.0, 127.0, 339.0, 231.0], "category_id": 1}, {"id": 1, "bbox": [1105.0, 168.0, 189.0, 171.0], "category_id": 1}, {"id": 2, "bbox": [747.0, 202.0, 70.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [725.0, 263.0, 126.0, 51.0], "category_id": 2}, {"id": 4, "bbox": [875.0, 141.0, 206.0, 217.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [4, 1]}], "corefs": [], "caption": "Figure 1. UV spectra of 6b (solid line, ca. 1 \u00d7 10-4 M in 20% aqueous methanol) and its 300 nm photolysis (dashed lines, every 4 min). ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 317, 393, 361], "ImageBB": [58, 47, 396, 313]}, "diagram_type": "single"}, {"id": 977, "width": 1232, "height": 572, "file_name": "ja0551382-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [26.5, 443.05, 29.58, 31.43], "category_id": 2}, {"id": 1, "bbox": [4.31, 19.1, 247.76, 178.08], "category_id": 1}, {"id": 2, "bbox": [696.43, 179.93, 483.8, 219.98], "category_id": 1}, {"id": 3, "bbox": [279.8, 80.11, 27.74, 31.42], "category_id": 2}, {"id": 4, "bbox": [103.54, 372.19, 404.91, 194.1], "category_id": 1}, {"id": 5, "bbox": [334.66, 320.42, 30.19, 38.21], "category_id": 3}, {"id": 6, "bbox": [824.62, 2.46, 403.68, 138.65], "category_id": 1}, {"id": 7, "bbox": [628.02, 496.04, 157.77, 38.82], "category_id": 3}, {"id": 8, "bbox": [24.65, 256.96, 25.27, 32.04], "category_id": 2}, {"id": 9, "bbox": [779.01, 73.94, 27.74, 36.36], "category_id": 2}, {"id": 10, "bbox": [1034.17, 133.72, 32.04, 35.12], "category_id": 3}, {"id": 11, "bbox": [104.77, 182.4, 479.49, 222.44], "category_id": 1}, {"id": 12, "bbox": [619.39, 249.56, 27.73, 36.36], "category_id": 2}, {"id": 13, "bbox": [537.42, 127.55, 28.97, 36.98], "category_id": 3}, {"id": 14, "bbox": [823.39, 333.98, 25.88, 36.36], "category_id": 3}, {"id": 15, "bbox": [335.27, 2.46, 427.72, 138.65], "category_id": 1}, {"id": 16, "bbox": [537.01, 469.46, 26.01, 38.09], "category_id": 2}, {"id": 17, "bbox": [634.56, 442.52, 129.15, 40.88], "category_id": 3}], "caption": "Scheme 1. Synthesis of E-Olefin Isosterea", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 457, 656, 470], "ImageBB": [454, 475, 762, 618]}, "reactions": [{"reactants": [1], "conditions": [3], "products": [15]}, {"reactants": [15], "conditions": [9], "products": [6]}, {"reactants": [6], "conditions": [8], "products": [11]}, {"reactants": [11], "conditions": [12], "products": [2]}, {"reactants": [2], "conditions": [0], "products": [4]}, {"reactants": [17], "conditions": [16], "products": [7]}], "diagram_type": "multiple"}, {"id": 753, "width": 1344, "height": 544, "file_name": "jo990938e-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [479.0, 1.0, 123.0, 76.0], "category_id": 2}, {"id": 1, "bbox": [2.0, 244.0, 1342.0, 300.0], "category_id": 4}, {"id": 2, "bbox": [183.12, 25.04, 294.0, 129.0], "category_id": 1}, {"id": 3, "bbox": [299.0, 170.0, 33.0, 34.0], "category_id": 3}, {"id": 4, "bbox": [906.0, 13.0, 260.0, 174.9], "category_id": 1}, {"id": 5, "bbox": [465.0, 108.0, 164.0, 91.0], "category_id": 2}, {"id": 6, "bbox": [632.0, 5.0, 256.0, 178.0], "category_id": 1}, {"id": 7, "bbox": [696.0, 167.0, 104.0, 41.0], "category_id": 3}, {"id": 8, "bbox": [978.0, 169.0, 93.0, 37.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [0, 5], "products": [6, 4]}], "corefs": [[2, 3], [6, 7], [4, 8]], "caption": "Table 3. Additions of Allenylindium Reagent Prepared        from Allenyl Iodide 6 to Aldehydes 3a-d ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [79, 64, 403, 89], "ImageBB": [74, 98, 410, 234]}, "diagram_type": "single"}, {"id": 885, "width": 1348, "height": 404, "file_name": "ol503404p-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [752.0, 0.0, 273.0, 308.8], "category_id": 1}, {"id": 1, "bbox": [49.0, 96.9, 262.6, 166.4], "category_id": 1}, {"id": 2, "bbox": [422.7, 75.2, 59.0, 181.8], "category_id": 1}, {"id": 3, "bbox": [1031.0, 45.7, 265.9, 215.9], "category_id": 1}, {"id": 4, "bbox": [522.0, 169.0, 208.0, 49.0], "category_id": 2}, {"id": 5, "bbox": [4.0, 327.0, 1344.0, 77.0], "category_id": 4}, {"id": 6, "bbox": [189.0, 250.0, 50.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [825.0, 248.0, 67.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [423.0, 253.0, 55.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [1171.0, 233.0, 36.0, 41.0], "category_id": 3}, {"id": 10, "bbox": [589.0, 126.0, 69.0, 40.0], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [10, 4], "products": [0, 3]}], "corefs": [[1, 6], [2, 8], [0, 7], [3, 9]], "caption": "Table 1. Reaction Optimization for the Synthesis of 7aaa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 764, 110], "ImageBB": [449, 116, 786, 217]}, "diagram_type": "single"}, {"id": 686, "width": 1476, "height": 2472, "file_name": "ol4012794-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [111.0, 2226.0, 1365.0, 169.0], "category_id": 2}, {"id": 1, "bbox": [1097.0, 12.0, 330.0, 214.0], "category_id": 1}, {"id": 2, "bbox": [701.0, 114.0, 311.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [1200.0, 234.0, 38.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [244.0, 232.0, 43.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [111.0, 1896.0, 1365.0, 271.0], "category_id": 2}, {"id": 6, "bbox": [666.13, 0.0, 397.5, 84.0], "category_id": 2}, {"id": 7, "bbox": [534.0, 175.6, 45.2, 41.4], "category_id": 3}, {"id": 8, "bbox": [456.2, 70.0, 202.8, 77.6], "category_id": 1}, {"id": 9, "bbox": [174.0, 22.3, 218.7, 205.7], "category_id": 1}, {"id": 10, "bbox": [119.0, 375.7, 1357.0, 1478.3], "category_id": 4}], "reactions": [{"reactants": [9, 8], "conditions": [6, 2], "products": [1]}], "corefs": [[9, 4], [8, 7], [1, 3]], "caption": "Table 2. Reaction of Phenylphosphine Oxides 4 with Acrylates 5a", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 417, 771, 433], "ImageBB": [404, 444, 773, 1062]}, "diagram_type": "single"}, {"id": 1120, "width": 1348, "height": 2096, "file_name": "jo9906328-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1235.58, 1820.24, 53.5, 47.18], "category_id": 3}, {"id": 1, "bbox": [740.51, 163.57, 47.2, 39.84], "category_id": 2}, {"id": 2, "bbox": [95.45, 1756.28, 38.81, 46.13], "category_id": 2}, {"id": 3, "bbox": [168.87, 1498.34, 44.05, 44.04], "category_id": 3}, {"id": 4, "bbox": [281.1, 1711.19, 578.98, 321.9], "category_id": 1}, {"id": 5, "bbox": [170.97, 633.31, 61.88, 52.42], "category_id": 3}, {"id": 6, "bbox": [353.47, 868.18, 433.19, 204.46], "category_id": 1}, {"id": 7, "bbox": [0.0, 430.94, 437.38, 204.47], "category_id": 1}, {"id": 8, "bbox": [0.0, 1297.02, 442.63, 197.13], "category_id": 1}, {"id": 9, "bbox": [699.6, 0.0, 167.2, 117.43], "category_id": 1}, {"id": 10, "bbox": [554.8, 1230.97, 217.18, 169.03], "category_id": 1}, {"id": 11, "bbox": [775.12, 436.19, 420.6, 197.12], "category_id": 1}, {"id": 12, "bbox": [526.54, 1050.62, 45.1, 47.18], "category_id": 3}, {"id": 13, "bbox": [120.43, 883.09, 32.71, 52.84], "category_id": 2}, {"id": 14, "bbox": [226.11, 893.16, 37.74, 37.74], "category_id": 2}, {"id": 15, "bbox": [505.41, 1338.53, 37.74, 40.26], "category_id": 2}, {"id": 16, "bbox": [671.48, 1237.88, 35.23, 42.77], "category_id": 3}, {"id": 17, "bbox": [860.08, 45.09, 47.2, 52.42], "category_id": 3}, {"id": 18, "bbox": [860.08, 877.61, 40.91, 52.43], "category_id": 2}, {"id": 19, "bbox": [1055.17, 1808.7, 53.93, 55.58], "category_id": 3}, {"id": 20, "bbox": [504.51, 699.37, 96.5, 61.86], "category_id": 2}, {"id": 21, "bbox": [217.12, 22.02, 354.52, 195.02], "category_id": 1}, {"id": 22, "bbox": [483.53, 2045.67, 110.14, 46.14], "category_id": 3}, {"id": 23, "bbox": [1006.93, 630.16, 70.27, 51.38], "category_id": 3}, {"id": 24, "bbox": [773.03, 1249.84, 571.64, 282.05], "category_id": 1}, {"id": 25, "bbox": [906.23, 1756.28, 26.23, 44.04], "category_id": 2}, {"id": 26, "bbox": [1126.5, 1488.9, 102.79, 52.43], "category_id": 3}, {"id": 27, "bbox": [403.82, 372.23, 454.17, 56.62], "category_id": 2}, {"id": 28, "bbox": [350.33, 223.34, 39.85, 45.08], "category_id": 3}], "caption": "Scheme 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 63, 276, 77], "ImageBB": [74, 84, 411, 608]}, "reactions": [{"reactants": [21, 9], "conditions": [], "products": [7, 11]}, {"reactants": [11], "conditions": [20], "products": [7]}, {"reactants": [11], "conditions": [18], "products": [6]}, {"reactants": [6], "conditions": [14], "products": [7]}, {"reactants": [7], "conditions": [13], "products": [8]}, {"reactants": [8, 10], "conditions": [15], "products": [24]}, {"reactants": [24], "conditions": [2], "products": [4]}, {"reactants": [4], "conditions": [25], "products": [19, 0]}], "diagram_type": "graph"}, {"id": 422, "width": 1352, "height": 1340, "file_name": "op300331b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1088.0, 654.0, 59.0, 58.0], "category_id": 3}, {"id": 1, "bbox": [44.0, 0.0, 412.0, 244.0], "category_id": 1}, {"id": 2, "bbox": [53.0, 367.0, 513.0, 241.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 734.0, 1349.0, 569.0], "category_id": 4}, {"id": 4, "bbox": [377.0, 146.0, 558.0, 138.0], "category_id": 2}, {"id": 5, "bbox": [456.0, 48.0, 363.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [679.0, 657.0, 64.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [517.0, 376.0, 482.0, 241.0], "category_id": 1}, {"id": 8, "bbox": [966.0, 367.0, 336.0, 244.0], "category_id": 1}, {"id": 9, "bbox": [157.0, 272.0, 55.0, 55.0], "category_id": 3}, {"id": 10, "bbox": [215.0, 657.0, 61.0, 50.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [5, 4], "products": [2, 7, 8]}], "corefs": [[1, 9], [2, 10], [7, 6], [8, 0]], "caption": "Table 2. Screening of reaction conditions for carbonylation of 17 ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 589, 417, 619], "ImageBB": [82, 626, 420, 961]}, "diagram_type": "multiple"}, {"id": 953, "width": 1352, "height": 1392, "file_name": "acs.orglett.6b00661-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [469.92, 497.89, 390.68, 55.31], "category_id": 3}, {"id": 1, "bbox": [63.35, 1085.61, 286.13, 70.33], "category_id": 2}, {"id": 2, "bbox": [970.48, 471.43, 349.49, 428.95], "category_id": 1}, {"id": 3, "bbox": [472.01, 395.53, 388.47, 98.18], "category_id": 1}, {"id": 4, "bbox": [735.87, 16.71, 191.45, 293.16], "category_id": 1}, {"id": 5, "bbox": [36.9, 15.32, 216.51, 296.64], "category_id": 1}, {"id": 6, "bbox": [103.04, 306.39, 77.97, 63.37], "category_id": 3}, {"id": 7, "bbox": [299.36, 184.53, 327.21, 107.94], "category_id": 2}, {"id": 8, "bbox": [991.37, 79.38, 249.93, 64.76], "category_id": 2}, {"id": 9, "bbox": [470.5, 554.72, 394.37, 51.81], "category_id": 3}, {"id": 10, "bbox": [1017.13, 181.05, 199.1, 107.24], "category_id": 2}, {"id": 11, "bbox": [749.57, 1224.82, 304.13, 50.13], "category_id": 3}, {"id": 12, "bbox": [921.69, 892.28, 299.12, 48.46], "category_id": 2}, {"id": 13, "bbox": [886.6, 825.44, 317.5, 45.11], "category_id": 3}, {"id": 14, "bbox": [886.6, 776.97, 262.35, 46.79], "category_id": 3}, {"id": 15, "bbox": [405.18, 926.14, 460.87, 425.47], "category_id": 1}, {"id": 16, "bbox": [297.27, 0.0, 344.61, 148.32], "category_id": 2}, {"id": 17, "bbox": [806.18, 308.48, 66.14, 57.1], "category_id": 3}, {"id": 18, "bbox": [36.9, 497.19, 344.61, 251.38], "category_id": 1}, {"id": 19, "bbox": [103.04, 1185.18, 206.07, 68.94], "category_id": 2}, {"id": 20, "bbox": [747.7, 1183.1, 373.0, 43.6], "category_id": 3}, {"id": 21, "bbox": [530.5, 732.69, 312.4, 95.01], "category_id": 2}, {"id": 22, "bbox": [886.9, 729.2, 308.0, 48.9], "category_id": 3}, {"id": 23, "bbox": [472.01, 644.12, 394.04, 48.18], "category_id": 2}, {"id": 24, "bbox": [108.1, 775.0, 213.3, 45.2], "category_id": 3}, {"id": 25, "bbox": [351.57, 770.86, 148.99, 153.19], "category_id": 2}, {"id": 26, "bbox": [134.62, 822.09, 168.77, 48.46], "category_id": 3}], "caption": "Scheme 2. Synthesis of Alkynyl Silyl Enol Ethers 10 and 19", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 470, 417, 485], "ImageBB": [82, 491, 420, 839]}, "reactions": [{"reactants": [5], "conditions": [16, 7], "products": [4]}, {"reactants": [4], "conditions": [8, 10], "products": [18]}, {"reactants": [18], "conditions": [3, 23], "products": [2]}, {"reactants": [2], "conditions": [1, 19], "products": [15]}, {"reactants": [24], "conditions": [25], "products": [26]}, {"reactants": [22], "conditions": [21], "products": [14]}], "diagram_type": "multiple"}, {"id": 802, "width": 3396, "height": 1248, "file_name": "jo501006u-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1061.0, 382.0, 302.0, 85.0], "category_id": 1}, {"id": 1, "bbox": [2422.0, 376.88, 247.0, 85.0], "category_id": 1}, {"id": 2, "bbox": [2011.0, 377.12, 316.0, 91.0], "category_id": 1}, {"id": 3, "bbox": [732.0, 385.0, 262.0, 82.0], "category_id": 1}, {"id": 4, "bbox": [1594.68, 442.32, 228.0, 64.0], "category_id": 2}, {"id": 5, "bbox": [1382.61, 280.2, 533.0, 142.07], "category_id": 2}], "reactions": [{"reactants": [3, 0], "conditions": [5, 4], "products": [2, 1]}], "corefs": [], "caption": "Figure 2. Time-courses of coupling product (a) and reduced product (b) in the reaction of n-NonBr with n-BuMgCl with 25 mol ppm of CuCl2 and 100 mol % (\u25c6), 50 mol % (\u25a0), 25 mol % (\u25b2), 5 mol % (\u25cf), or 0 mol % (\u25c7) of phenylpropyne. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 343, 784, 371], "ImageBB": [10, 22, 859, 334]}, "diagram_type": "single"}, {"id": 1201, "width": 1356, "height": 856, "file_name": "ol502998n-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [280.83, 382.12, 96.33, 38.01], "category_id": 2}, {"id": 1, "bbox": [1121.93, 615.52, 25.69, 28.78], "category_id": 3}, {"id": 2, "bbox": [445.76, 651.49, 77.07, 30.83], "category_id": 2}, {"id": 3, "bbox": [493.83, 260.63, 221.82, 42.08], "category_id": 2}, {"id": 4, "bbox": [238.1, 447.28, 200.11, 253.17], "category_id": 1}, {"id": 5, "bbox": [976.01, 734.73, 77.07, 29.8], "category_id": 2}, {"id": 6, "bbox": [531.82, 6.11, 210.96, 168.19], "category_id": 1}, {"id": 7, "bbox": [1017.51, 241.95, 50.2, 43.44], "category_id": 3}, {"id": 8, "bbox": [954.42, 126.24, 219.79, 155.36], "category_id": 1}, {"id": 9, "bbox": [665.45, 145.93, 43.41, 42.08], "category_id": 3}, {"id": 10, "bbox": [1164.03, 221.94, 45.45, 161.54], "category_id": 1}, {"id": 11, "bbox": [510.11, 528.73, 280.16, 42.08], "category_id": 2}, {"id": 12, "bbox": [390.72, 373.3, 157.38, 89.59], "category_id": 1}, {"id": 13, "bbox": [799.08, 772.39, 229.96, 34.62], "category_id": 2}, {"id": 14, "bbox": [849.96, 92.31, 76.65, 44.11], "category_id": 2}, {"id": 15, "bbox": [187.9, 96.38, 225.89, 138.46], "category_id": 1}, {"id": 16, "bbox": [531.82, 600.67, 244.2, 211.77], "category_id": 1}, {"id": 17, "bbox": [905.58, 373.3, 215.71, 40.04], "category_id": 2}, {"id": 18, "bbox": [252.34, 226.69, 48.84, 40.73], "category_id": 3}, {"id": 19, "bbox": [970.7, 488.0, 221.82, 196.16], "category_id": 1}, {"id": 20, "bbox": [579.3, 769.68, 33.92, 39.36], "category_id": 3}, {"id": 21, "bbox": [144.49, 397.06, 122.78, 37.33], "category_id": 2}, {"id": 22, "bbox": [390.72, 251.13, 88.19, 38.69], "category_id": 2}], "caption": "Scheme 5. Proposed Catalytic Cycle for the Indole Synthesis", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 187, 784, 202], "ImageBB": [448, 208, 787, 422]}, "reactions": [{"reactants": [21], "conditions": [0], "products": [12]}, {"reactants": [12, 15], "conditions": [22, 3], "products": [6]}, {"reactants": [6], "conditions": [14], "products": [8]}, {"reactants": [8, 10], "conditions": [17], "products": [19]}, {"reactants": [19, 5], "conditions": [13], "products": [16]}, {"reactants": [16, 2], "conditions": [11], "products": [4, 12]}], "diagram_type": "graph"}, {"id": 1295, "width": 1688, "height": 1280, "file_name": "op2001832-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [270.22, 807.96, 28.71, 32.08], "category_id": 2}, {"id": 1, "bbox": [220.39, 653.46, 53.2, 43.05], "category_id": 3}, {"id": 2, "bbox": [671.32, 415.38, 366.47, 197.55], "category_id": 1}, {"id": 3, "bbox": [1296.19, 0.0, 237.28, 174.76], "category_id": 1}, {"id": 4, "bbox": [433.19, 969.21, 411.23, 233.86], "category_id": 1}, {"id": 5, "bbox": [653.58, 29.55, 38.85, 38.84], "category_id": 2}, {"id": 6, "bbox": [1485.34, 271.01, 28.71, 43.05], "category_id": 2}, {"id": 7, "bbox": [1465.07, 655.15, 52.36, 43.05], "category_id": 3}, {"id": 8, "bbox": [226.31, 42.21, 343.67, 130.86], "category_id": 1}, {"id": 9, "bbox": [1324.9, 1206.45, 35.46, 43.05], "category_id": 3}, {"id": 10, "bbox": [1242.15, 415.38, 445.85, 206.84], "category_id": 1}, {"id": 11, "bbox": [558.16, 429.73, 40.54, 44.74], "category_id": 2}, {"id": 12, "bbox": [83.6, 431.42, 359.72, 192.49], "category_id": 1}, {"id": 13, "bbox": [804.73, 35.46, 363.11, 130.86], "category_id": 1}, {"id": 14, "bbox": [831.76, 653.46, 52.35, 43.05], "category_id": 3}, {"id": 15, "bbox": [365.63, 1230.93, 55.74, 45.59], "category_id": 3}, {"id": 16, "bbox": [937.31, 995.38, 40.53, 50.66], "category_id": 2}, {"id": 17, "bbox": [1134.9, 962.46, 403.64, 231.32], "category_id": 1}, {"id": 18, "bbox": [1134.9, 429.73, 37.16, 39.68], "category_id": 2}, {"id": 19, "bbox": [0.0, 974.28, 408.7, 236.39], "category_id": 1}], "caption": "Scheme 4. Mandelic acid resolution route to (3S,5R)-3-(aminomethyl)-5-methyloctanoic acida", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 644, 595, 665], "ImageBB": [211, 675, 633, 995]}, "reactions": [{"reactants": [8], "conditions": [5], "products": [13]}, {"reactants": [13, 3], "conditions": [6], "products": [10]}, {"reactants": [10], "conditions": [18], "products": [2]}, {"reactants": [2], "conditions": [11], "products": [12]}, {"reactants": [12], "conditions": [0], "products": [19]}, {"reactants": [19, 4], "conditions": [16], "products": [17]}], "diagram_type": "tree"}, {"id": 755, "width": 1344, "height": 748, "file_name": "jo990938e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [572.0, 178.0, 327.0, 177.9], "category_id": 1}, {"id": 1, "bbox": [1.0, 443.0, 1342.0, 301.0], "category_id": 4}, {"id": 2, "bbox": [128.0, 170.0, 215.9, 82.9], "category_id": 2}, {"id": 3, "bbox": [387.0, 7.0, 351.0, 52.0], "category_id": 2}, {"id": 4, "bbox": [157.2, 285.0, 132.8, 80.0], "category_id": 2}, {"id": 5, "bbox": [657.01, 370.92, 134.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [1035.2, 373.0, 59.7, 37.0], "category_id": 3}, {"id": 7, "bbox": [775.1, 6.0, 373.7, 130.0], "category_id": 1}, {"id": 8, "bbox": [836.1, 129.0, 384.9, 233.1], "category_id": 1}, {"id": 9, "bbox": [138.4, 0.0, 242.6, 142.9], "category_id": 1}, {"id": 10, "bbox": [300.4, 181.0, 324.5, 174.0], "category_id": 1}, {"id": 11, "bbox": [394.0, 95.0, 304.0, 59.0], "category_id": 2}, {"id": 12, "bbox": [357.0, 369.0, 150.0, 51.0], "category_id": 3}, {"id": 13, "bbox": [196.0, 101.0, 38.0, 39.0], "category_id": 3}, {"id": 14, "bbox": [938.0, 108.0, 42.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [9], "conditions": [3, 11], "products": [7]}, {"reactants": [7], "conditions": [2, 4], "products": [10, 0, 8]}], "corefs": [[9, 13], [7, 14], [10, 12], [0, 5], [8, 6]], "caption": "Table 1. Addition of Allenylmetal Reagents Prepared         from Allenylstannane 2 to Aldehyde 3a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [84, 64, 399, 89], "ImageBB": [74, 99, 410, 286]}, "diagram_type": "multiple"}, {"id": 183, "width": 1336, "height": 2728, "file_name": "op0602270-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1070.41, 288.94, 149.93, 58.51], "category_id": 3}, {"id": 1, "bbox": [394.0, 65.0, 460.0, 66.0], "category_id": 2}, {"id": 2, "bbox": [474.0, 191.0, 289.0, 66.0], "category_id": 2}, {"id": 3, "bbox": [526.0, 1419.0, 292.0, 62.0], "category_id": 2}, {"id": 4, "bbox": [977.0, 1269.0, 357.0, 243.0], "category_id": 1}, {"id": 5, "bbox": [69.0, 1271.0, 370.0, 241.0], "category_id": 1}, {"id": 6, "bbox": [903.6, 34.0, 379.4, 249.9], "category_id": 1}, {"id": 7, "bbox": [452.0, 1296.0, 459.8, 56.0], "category_id": 2}, {"id": 8, "bbox": [286.0, 291.0, 77.0, 49.0], "category_id": 3}, {"id": 9, "bbox": [33.0, 1590.0, 1280.0, 1138.0], "category_id": 4}, {"id": 10, "bbox": [250.96, 338.64, 963.7, 854.8], "category_id": 4}, {"id": 11, "bbox": [0.0, 0.0, 249.0, 331.0], "category_id": 1}, {"id": 12, "bbox": [1135.0, 1522.0, 122.0, 46.0], "category_id": 3}, {"id": 13, "bbox": [221.0, 1525.0, 75.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [11], "conditions": [1, 2], "products": [6]}, {"reactants": [5], "conditions": [7, 3], "products": [4]}], "corefs": [[11, 8], [6, 0], [5, 13], [4, 12]], "caption": "Figure 1. Solvent and pressure variation. Reactions were carried out at 10 \u00b0C for 24 h with 0.0024 mmol [Rh(cod)2]BF4, 0.005 mmol ligand 6a and 0.24 mmol substrate in 2.0 mL of solvent. Conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). The absolute configuration was determined by comparison with reported data.3l ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 738, 409, 835], "ImageBB": [75, 53, 409, 735]}, "diagram_type": "multiple"}, {"id": 25, "width": 1348, "height": 800, "file_name": "ja905415r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [230.23, 295.26, 51.55, 41.23], "category_id": 3}, {"id": 1, "bbox": [3.14, 345.84, 1340.83, 450.0], "category_id": 4}, {"id": 2, "bbox": [64.04, 32.04, 346.77, 242.52], "category_id": 1}, {"id": 3, "bbox": [656.55, 41.33, 306.52, 247.68], "category_id": 1}, {"id": 4, "bbox": [1019.91, 2.1, 260.06, 291.04], "category_id": 1}, {"id": 5, "bbox": [421.2, 123.91, 187.81, 46.39], "category_id": 2}, {"id": 6, "bbox": [425.33, 194.1, 175.37, 51.55], "category_id": 2}, {"id": 7, "bbox": [838.23, 295.26, 56.71, 41.23], "category_id": 3}, {"id": 8, "bbox": [1192.3, 295.26, 52.58, 41.23], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5, 6], "products": [3, 4]}], "corefs": [[2, 0], [3, 7], [4, 8]], "caption": "Table 1. Au-Catalyzed [4C+2C] vs [4C+3C] Cycloaddition of 1aa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 462, 752, 476], "ImageBB": [425, 485, 762, 685]}, "diagram_type": "single"}, {"id": 423, "width": 1352, "height": 896, "file_name": "op3002883-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [229.0, 200.0, 51.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [505.0, 137.0, 281.0, 127.0], "category_id": 2}, {"id": 2, "bbox": [501.0, 0.0, 295.0, 131.0], "category_id": 2}, {"id": 3, "bbox": [792.0, 1.0, 560.0, 203.0], "category_id": 1}, {"id": 4, "bbox": [985.0, 217.0, 49.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [2.0, 50.0, 488.0, 141.0], "category_id": 1}, {"id": 6, "bbox": [10.0, 290.8, 1332.0, 578.2], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [2, 1], "products": [3]}], "corefs": [[5, 0], [3, 4]], "caption": "Table 1. Ligand and Solvent Optimization", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 324, 321, 339], "ImageBB": [82, 346, 420, 570]}, "diagram_type": "single"}, {"id": 903, "width": 1352, "height": 1828, "file_name": "acs.joc.5b02057-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [567.0, 33.0, 463.0, 102.0], "category_id": 2}, {"id": 1, "bbox": [988.0, 1456.0, 316.0, 262.0], "category_id": 1}, {"id": 2, "bbox": [679.0, 1458.0, 285.0, 283.0], "category_id": 1}, {"id": 3, "bbox": [378.0, 1452.0, 281.0, 293.0], "category_id": 1}, {"id": 4, "bbox": [4.0, 1469.0, 330.0, 267.0], "category_id": 1}, {"id": 5, "bbox": [1024.0, 1070.0, 271.0, 317.0], "category_id": 1}, {"id": 6, "bbox": [685.0, 1064.0, 281.0, 325.0], "category_id": 1}, {"id": 7, "bbox": [360.0, 1059.0, 303.0, 328.0], "category_id": 1}, {"id": 8, "bbox": [15.0, 1064.0, 316.0, 320.0], "category_id": 1}, {"id": 9, "bbox": [1024.0, 654.0, 280.0, 316.0], "category_id": 1}, {"id": 10, "bbox": [690.0, 659.0, 296.0, 305.0], "category_id": 1}, {"id": 11, "bbox": [376.0, 654.0, 283.0, 321.0], "category_id": 1}, {"id": 12, "bbox": [6.0, 650.0, 290.0, 305.0], "category_id": 1}, {"id": 13, "bbox": [1028.0, 302.0, 260.0, 294.0], "category_id": 1}, {"id": 14, "bbox": [674.0, 291.0, 301.0, 290.0], "category_id": 1}, {"id": 15, "bbox": [369.0, 400.0, 274.0, 190.0], "category_id": 1}, {"id": 16, "bbox": [13.0, 398.0, 285.0, 192.0], "category_id": 1}, {"id": 17, "bbox": [1030.0, 0.0, 319.0, 207.0], "category_id": 1}, {"id": 18, "bbox": [340.0, 66.0, 236.0, 141.0], "category_id": 1}, {"id": 19, "bbox": [0.0, 69.0, 289.0, 120.0], "category_id": 1}, {"id": 20, "bbox": [1150.0, 218.0, 61.0, 40.0], "category_id": 3}, {"id": 21, "bbox": [409.0, 215.0, 76.0, 47.0], "category_id": 3}, {"id": 22, "bbox": [78.0, 211.0, 71.0, 53.0], "category_id": 3}, {"id": 23, "bbox": [1064.0, 1743.0, 187.0, 44.0], "category_id": 3}, {"id": 24, "bbox": [716.0, 1741.0, 196.0, 53.0], "category_id": 3}, {"id": 25, "bbox": [391.0, 1747.0, 210.0, 49.0], "category_id": 3}, {"id": 26, "bbox": [42.0, 1750.0, 185.0, 40.0], "category_id": 3}, {"id": 27, "bbox": [1055.0, 1391.0, 209.0, 51.0], "category_id": 3}, {"id": 28, "bbox": [710.0, 1398.0, 213.0, 42.0], "category_id": 3}, {"id": 29, "bbox": [398.0, 1393.0, 234.0, 38.0], "category_id": 3}, {"id": 30, "bbox": [49.0, 1391.0, 187.0, 45.0], "category_id": 3}, {"id": 31, "bbox": [1057.0, 970.0, 203.0, 56.0], "category_id": 3}, {"id": 32, "bbox": [716.0, 977.0, 203.0, 53.0], "category_id": 3}, {"id": 33, "bbox": [407.0, 984.0, 196.0, 46.0], "category_id": 3}, {"id": 34, "bbox": [46.0, 981.0, 174.0, 45.0], "category_id": 3}, {"id": 35, "bbox": [1070.0, 594.0, 178.0, 47.0], "category_id": 3}, {"id": 36, "bbox": [721.0, 587.0, 191.0, 56.0], "category_id": 3}, {"id": 37, "bbox": [398.0, 592.0, 200.0, 49.0], "category_id": 3}, {"id": 38, "bbox": [33.0, 598.0, 220.0, 45.0], "category_id": 3}, {"id": 39, "bbox": [688.0, 160.0, 233.0, 100.0], "category_id": 2}], "reactions": [{"reactants": [19, 18], "conditions": [0, 39], "products": [17]}], "corefs": [[19, 22], [18, 21], [17, 20], [16, 38], [15, 37], [14, 36], [13, 35], [12, 34], [11, 33], [10, 32], [9, 31], [8, 30], [7, 29], [6, 28], [5, 27], [4, 26], [3, 25], [2, 24], [1, 24]], "caption": "Table 2. Reaction Scope of Ynamides 1 with Vinyl Azide 2ba", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 380, 417, 401], "ImageBB": [82, 407, 420, 864]}, "diagram_type": "single"}, {"id": 181, "width": 1344, "height": 1192, "file_name": "op0602270-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [419.0, 32.0, 470.0, 63.0], "category_id": 2}, {"id": 1, "bbox": [8.0, 11.0, 367.0, 229.8], "category_id": 1}, {"id": 2, "bbox": [42.6, 336.0, 1262.4, 853.5], "category_id": 1}, {"id": 3, "bbox": [983.2, 7.0, 360.8, 232.6], "category_id": 1}, {"id": 4, "bbox": [73.0, 243.4, 227.3, 50.5], "category_id": 3}, {"id": 5, "bbox": [382.0, 149.0, 570.0, 68.6], "category_id": 2}, {"id": 6, "bbox": [1127.4, 240.0, 67.6, 59.8], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [0, 5], "products": [3]}], "corefs": [[1, 4], [3, 6]], "caption": "Figure 3. Dependency of enantioselectivity versus E/Z ratio. Reactions were carried out at 10 \u00b0C for 24 h with 0.0024 mmol [Rh(cod)2]BF4, 0.005 mmol ligand 6a and 0.24 mmol substrate in 2.0 mL of ethanol. Conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 757, 775, 840], "ImageBB": [440, 456, 776, 754]}, "diagram_type": "single"}, {"id": 831, "width": 1348, "height": 408, "file_name": "jo4004426-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [549.0, 204.0, 383.9, 59.7], "category_id": 2}, {"id": 1, "bbox": [285.4, 28.0, 179.8, 279.0], "category_id": 1}, {"id": 2, "bbox": [963.0, 3.0, 352.9, 301.9], "category_id": 1}, {"id": 3, "bbox": [32.1, 16.0, 132.2, 296.0], "category_id": 1}, {"id": 4, "bbox": [545.0, 42.0, 401.0, 113.0], "category_id": 2}, {"id": 5, "bbox": [451.0, 236.0, 34.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [1124.0, 229.0, 45.0, 63.0], "category_id": 3}, {"id": 7, "bbox": [2.0, 324.0, 1346.0, 83.0], "category_id": 4}, {"id": 8, "bbox": [149.0, 239.0, 42.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [3, 1], "conditions": [4, 0], "products": [2]}], "corefs": [[3, 8], [1, 5], [2, 6]], "caption": "Table 2. Optimization Studies with Heterogeneous Copper Catalysts ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 205, 415, 235], "ImageBB": [82, 242, 419, 344]}, "diagram_type": "single"}, {"id": 820, "width": 1352, "height": 1656, "file_name": "jo401195c-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [844.0, 294.0, 149.0, 49.0], "category_id": 3}, {"id": 1, "bbox": [1060.0, 286.0, 252.0, 59.4], "category_id": 3}, {"id": 2, "bbox": [387.0, 3.0, 279.0, 48.0], "category_id": 2}, {"id": 3, "bbox": [1084.0, 20.0, 265.0, 255.0], "category_id": 1}, {"id": 4, "bbox": [58.0, 292.0, 116.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [319.0, 219.0, 311.0, 51.0], "category_id": 2}, {"id": 6, "bbox": [264.0, 89.0, 179.0, 77.0], "category_id": 2}, {"id": 7, "bbox": [451.0, 58.0, 200.0, 125.0], "category_id": 1}, {"id": 8, "bbox": [793.0, 119.0, 208.0, 159.0], "category_id": 1}, {"id": 9, "bbox": [0.0, 121.0, 224.0, 153.0], "category_id": 1}, {"id": 10, "bbox": [8.0, 369.0, 1340.0, 1287.0], "category_id": 4}], "reactions": [{"reactants": [9], "conditions": [2, 6, 7, 5], "products": [8, 3]}], "corefs": [[9, 4], [8, 0], [3, 1]], "caption": "Table 7. KR of trans-Diol (\u00b1)-1 with Peptide Catalyst 12b Using Various Acyl Donors ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 403, 781, 437], "ImageBB": [448, 444, 786, 858]}, "diagram_type": "single"}, {"id": 166, "width": 1352, "height": 1088, "file_name": "op500334b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1117.0, 1041.0, 40.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [7.0, 309.0, 1344.0, 424.0], "category_id": 4}, {"id": 2, "bbox": [811.0, 4.0, 510.0, 290.0], "category_id": 1}, {"id": 3, "bbox": [1.0, 736.0, 489.0, 315.0], "category_id": 1}, {"id": 4, "bbox": [98.0, 243.0, 47.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [921.0, 228.0, 45.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [198.0, 1036.0, 43.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [661.0, 1043.0, 51.0, 42.0], "category_id": 3}, {"id": 8, "bbox": [433.0, 27.0, 377.0, 120.2], "category_id": 2}, {"id": 9, "bbox": [34.5, 0.0, 349.5, 285.4], "category_id": 1}, {"id": 10, "bbox": [550.0, 736.0, 367.0, 305.2], "category_id": 1}, {"id": 11, "bbox": [1012.0, 743.3, 335.0, 297.7], "category_id": 1}, {"id": 12, "bbox": [501.0, 194.3, 230.0, 54.7], "category_id": 2}], "reactions": [{"reactants": [9], "conditions": [8, 12], "products": [2]}], "corefs": [[9, 4], [2, 5], [3, 6], [10, 7], [11, 0]], "caption": "Table 2. Optimization of the copper catalyst and main impurities ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 463, 757, 493], "ImageBB": [448, 499, 786, 771]}, "diagram_type": "single"}, {"id": 886, "width": 1348, "height": 344, "file_name": "ol502998n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [445.0, 204.0, 36.0, 32.0], "category_id": 3}, {"id": 1, "bbox": [543.0, 74.0, 395.0, 38.0], "category_id": 2}, {"id": 2, "bbox": [121.0, 32.0, 214.0, 132.0], "category_id": 1}, {"id": 3, "bbox": [977.0, 4.0, 251.0, 238.0], "category_id": 1}, {"id": 4, "bbox": [598.0, 133.0, 257.0, 37.0], "category_id": 2}, {"id": 5, "bbox": [5.0, 269.0, 1341.0, 75.0], "category_id": 4}, {"id": 6, "bbox": [203.0, 205.0, 36.0, 31.0], "category_id": 3}, {"id": 7, "bbox": [1029.0, 204.0, 36.0, 31.0], "category_id": 3}, {"id": 8, "bbox": [452.0, 38.0, 40.0, 151.0], "category_id": 1}], "reactions": [{"reactants": [2, 8], "conditions": [1, 4], "products": [3]}], "corefs": [[2, 6], [8, 0], [3, 7]], "caption": "Table 1. Condition Investigation Using Pyrazolidin-3-one as an Oxidative DGa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 449, 416, 479], "ImageBB": [82, 486, 419, 572]}, "diagram_type": "single"}, {"id": 243, "width": 1308, "height": 2248, "file_name": "ol901684h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1086.0, 223.0, 37.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [552.0, 149.0, 334.0, 43.0], "category_id": 2}, {"id": 2, "bbox": [553.0, 0.0, 335.0, 129.0], "category_id": 2}, {"id": 3, "bbox": [907.0, 75.0, 367.0, 146.0], "category_id": 1}, {"id": 4, "bbox": [275.0, 113.0, 231.0, 61.0], "category_id": 1}, {"id": 5, "bbox": [37.0, 68.0, 191.0, 162.0], "category_id": 1}, {"id": 6, "bbox": [5.0, 311.0, 1303.0, 1937.0], "category_id": 4}, {"id": 7, "bbox": [143.0, 228.0, 38.0, 35.0], "category_id": 3}, {"id": 8, "bbox": [381.0, 223.0, 33.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [5, 4], "conditions": [2, 1], "products": [3]}], "corefs": [[5, 7], [4, 8], [3, 0]], "caption": "Table 3. Nickel-Catalyzed Direct Alkynylation of Various 5-Aryloxazoles 4 with Alkynyl Bromides 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 360, 102], "ImageBB": [63, 111, 390, 673]}, "diagram_type": "single"}, {"id": 952, "width": 1356, "height": 932, "file_name": "acs.orglett.6b00233-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1021.58, 187.94, 305.93, 48.17], "category_id": 3}, {"id": 1, "bbox": [661.38, 495.97, 44.09, 40.71], "category_id": 3}, {"id": 2, "bbox": [548.1, 316.85, 301.86, 185.23], "category_id": 1}, {"id": 3, "bbox": [14.92, 345.35, 314.07, 135.69], "category_id": 1}, {"id": 4, "bbox": [349.34, 358.92, 167.55, 45.45], "category_id": 2}, {"id": 5, "bbox": [346.63, 434.23, 175.01, 122.12], "category_id": 2}, {"id": 6, "bbox": [851.99, 318.21, 146.53, 89.56], "category_id": 2}, {"id": 7, "bbox": [769.91, 143.16, 111.25, 85.49], "category_id": 2}, {"id": 8, "bbox": [1035.15, 302.6, 300.5, 213.72], "category_id": 1}, {"id": 9, "bbox": [390.05, 249.0, 102.42, 98.38], "category_id": 1}, {"id": 10, "bbox": [993.77, 2.71, 320.17, 168.95], "category_id": 1}, {"id": 11, "bbox": [753.63, 591.64, 197.4, 96.34], "category_id": 2}, {"id": 12, "bbox": [991.05, 627.6, 303.22, 204.22], "category_id": 1}, {"id": 13, "bbox": [1130.79, 533.29, 122.78, 43.42], "category_id": 3}, {"id": 14, "bbox": [1105.69, 846.07, 123.46, 44.1], "category_id": 3}], "caption": "Scheme 3. Concise Synthesis Crispine A and Analogues", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 141, 757, 156], "ImageBB": [448, 162, 787, 395]}, "reactions": [{"reactants": [3], "conditions": [9, 4, 5], "products": [2]}, {"reactants": [2], "conditions": [7], "products": [10]}, {"reactants": [2], "conditions": [6], "products": [8]}, {"reactants": [2], "conditions": [11], "products": [12]}], "diagram_type": "tree"}, {"id": 1136, "width": 1144, "height": 656, "file_name": "ol0069002-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [592.89, 569.71, 32.05, 41.22], "category_id": 3}, {"id": 1, "bbox": [1063.88, 469.51, 31.48, 43.51], "category_id": 3}, {"id": 2, "bbox": [101.29, 111.65, 33.77, 34.93], "category_id": 2}, {"id": 3, "bbox": [871.02, 242.2, 26.9, 38.36], "category_id": 3}, {"id": 4, "bbox": [755.42, 27.48, 388.58, 242.77], "category_id": 1}, {"id": 5, "bbox": [651.83, 101.34, 76.12, 45.24], "category_id": 2}, {"id": 6, "bbox": [0.0, 131.12, 40.06, 48.09], "category_id": 3}, {"id": 7, "bbox": [940.84, 436.3, 25.75, 42.94], "category_id": 2}, {"id": 8, "bbox": [438.37, 443.17, 36.63, 38.36], "category_id": 2}, {"id": 9, "bbox": [231.78, 2.29, 358.25, 245.06], "category_id": 1}, {"id": 10, "bbox": [374.28, 246.2, 32.62, 40.08], "category_id": 3}, {"id": 11, "bbox": [136.2, 563.98, 34.34, 44.09], "category_id": 3}, {"id": 12, "bbox": [57.8, 351.56, 325.06, 245.06], "category_id": 1}, {"id": 13, "bbox": [22.32, 435.73, 34.34, 47.52], "category_id": 2}, {"id": 14, "bbox": [517.35, 316.06, 390.87, 334.95], "category_id": 1}], "caption": "Scheme 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 437, 269, 451], "ImageBB": [100, 455, 386, 619]}, "reactions": [{"reactants": [6], "conditions": [2], "products": [9]}, {"reactants": [9], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [13], "products": [12]}, {"reactants": [12], "conditions": [8], "products": [14]}, {"reactants": [14], "conditions": [7], "products": [1]}], "diagram_type": "multiple"}, {"id": 158, "width": 2816, "height": 1176, "file_name": "op700060e-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [962.0, 56.0, 172.0, 67.0], "category_id": 2}, {"id": 1, "bbox": [995.0, 123.0, 102.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [1799.5, 12.6, 279.9, 199.2], "category_id": 1}, {"id": 3, "bbox": [734.4, 36.5, 217.7, 161.3], "category_id": 1}, {"id": 4, "bbox": [1213.7, 28.7, 293.8, 171.9], "category_id": 1}, {"id": 5, "bbox": [1544.4, 59.0, 249.6, 53.0], "category_id": 2}, {"id": 6, "bbox": [1538.0, 131.5, 237.0, 52.3], "category_id": 2}, {"id": 7, "bbox": [14.0, 239.0, 2802.0, 937.0], "category_id": 4}], "reactions": [{"reactants": [3], "conditions": [0, 1], "products": [4]}, {"reactants": [4], "conditions": [5, 6], "products": [2]}], "corefs": [], "caption": "Table 3. Tandem SNAr/oxidation evaluation with alternative pyridine and aromatic substrates (HPLC purity data is reported for isolated solids) ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 746, 73], "ImageBB": [58, 88, 762, 382]}, "diagram_type": "single"}, {"id": 768, "width": 1348, "height": 1216, "file_name": "jo9602433-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [804.6, 294.6, 483.1, 516.4], "category_id": 1}, {"id": 1, "bbox": [118.1, 279.0, 480.2, 519.0], "category_id": 1}, {"id": 2, "bbox": [1094.5, 242.82, 195.61, 57.05], "category_id": 2}, {"id": 3, "bbox": [1138.52, 531.33, 202.12, 61.94], "category_id": 2}, {"id": 4, "bbox": [314.0, 811.7, 66.5, 57.3], "category_id": 3}, {"id": 5, "bbox": [1014.0, 813.0, 73.0, 58.7], "category_id": 3}, {"id": 6, "bbox": [14.0, 529.0, 38.0, 60.0], "category_id": 3}, {"id": 7, "bbox": [1.0, 902.0, 1347.0, 314.0], "category_id": 4}, {"id": 8, "bbox": [510.96, 650.32, 254.28, 58.68], "category_id": 2}, {"id": 9, "bbox": [540.3, 506.88, 193.97, 53.79], "category_id": 2}, {"id": 10, "bbox": [540.3, 575.34, 193.97, 58.68], "category_id": 2}, {"id": 11, "bbox": [283.0, 188.0, 65.0, 52.0], "category_id": 2}, {"id": 12, "bbox": [8.0, 51.0, 113.0, 69.0], "category_id": 2}, {"id": 13, "bbox": [217.0, 0.0, 195.0, 62.0], "category_id": 2}, {"id": 14, "bbox": [225.0, 106.0, 176.0, 60.0], "category_id": 2}, {"id": 15, "bbox": [525.63, 270.53, 193.97, 66.83], "category_id": 2}], "reactions": [{"reactants": [12], "conditions": [13, 14, 11], "products": [6, 1, 0]}], "corefs": [[1, 4], [0, 5]], "caption": "Table 4. Treatment of (Z)-4 with BTMBr3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [474, 55, 718, 68], "ImageBB": [429, 75, 766, 379]}, "diagram_type": "multiple"}, {"id": 636, "width": 1356, "height": 1212, "file_name": "ol501085y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [343.0, 229.0, 150.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [538.0, 122.0, 447.0, 97.0], "category_id": 2}, {"id": 2, "bbox": [596.0, 17.0, 333.0, 98.0], "category_id": 2}, {"id": 3, "bbox": [1042.8, 0.0, 308.5, 241.0], "category_id": 1}, {"id": 4, "bbox": [1.0, 301.0, 1352.0, 911.0], "category_id": 4}, {"id": 5, "bbox": [6.2, 2.6, 260.3, 234.8], "category_id": 1}, {"id": 6, "bbox": [46.0, 229.0, 204.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [338.0, 85.0, 160.0, 71.0], "category_id": 2}], "reactions": [{"reactants": [5, 7], "conditions": [2, 1], "products": [3]}], "corefs": [[5, 6]], "caption": "Table 2. Reaction Optimization for PyBidine-NiCl2- Catalyzed Asymmetric Nitro-Mannich Reaction ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 251, 742, 281], "ImageBB": [448, 287, 787, 590]}, "diagram_type": "single"}, {"id": 1042, "width": 2488, "height": 1480, "file_name": "jo010230b-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1942.86, 843.79, 545.14, 201.62], "category_id": 1}, {"id": 1, "bbox": [570.6, 1016.78, 47.98, 59.74], "category_id": 3}, {"id": 2, "bbox": [497.5, 48.54, 358.8, 197.88], "category_id": 1}, {"id": 3, "bbox": [958.75, 367.52, 31.9, 39.41], "category_id": 2}, {"id": 4, "bbox": [960.63, 1148.07, 26.27, 48.79], "category_id": 2}, {"id": 5, "bbox": [1848.13, 219.29, 52.53, 61.92], "category_id": 3}, {"id": 6, "bbox": [2164.4, 107.03, 32.36, 39.82], "category_id": 2}, {"id": 7, "bbox": [1286.94, 509.01, 507.81, 200.37], "category_id": 1}, {"id": 8, "bbox": [1575.69, 1018.03, 80.9, 67.2], "category_id": 3}, {"id": 9, "bbox": [0.0, 59.74, 344.76, 131.92], "category_id": 1}, {"id": 10, "bbox": [0.0, 837.57, 158.07, 192.9], "category_id": 1}, {"id": 11, "bbox": [1202.31, 573.73, 33.6, 34.85], "category_id": 2}, {"id": 12, "bbox": [2334.91, 682.0, 52.28, 60.99], "category_id": 3}, {"id": 13, "bbox": [581.24, 426.87, 598.66, 339.76], "category_id": 1}, {"id": 14, "bbox": [441.84, 840.06, 430.64, 160.54], "category_id": 1}, {"id": 15, "bbox": [1858.22, 567.51, 41.07, 42.31], "category_id": 2}, {"id": 16, "bbox": [576.26, 1237.06, 883.68, 204.11], "category_id": 1}, {"id": 17, "bbox": [995.7, 1412.54, 89.61, 67.21], "category_id": 3}, {"id": 18, "bbox": [2334.91, 1016.78, 82.15, 68.45], "category_id": 3}, {"id": 19, "bbox": [902.35, 677.03, 52.28, 64.71], "category_id": 3}, {"id": 20, "bbox": [1712.6, 38.58, 358.45, 212.82], "category_id": 1}, {"id": 21, "bbox": [1321.79, 215.3, 52.27, 67.21], "category_id": 3}, {"id": 22, "bbox": [1202.31, 836.33, 632.26, 209.08], "category_id": 1}, {"id": 23, "bbox": [2039.94, 1415.03, 74.67, 63.47], "category_id": 3}, {"id": 24, "bbox": [1529.64, 1294.31, 33.61, 43.56], "category_id": 2}, {"id": 25, "bbox": [500.34, 216.55, 57.25, 65.96], "category_id": 3}, {"id": 26, "bbox": [1634.19, 110.76, 31.11, 36.09], "category_id": 2}, {"id": 27, "bbox": [1858.22, 903.53, 47.3, 43.56], "category_id": 2}, {"id": 28, "bbox": [0.0, 2482.84, 16.18, -1002.84], "category_id": 3}, {"id": 29, "bbox": [2290.11, 53.51, 182.95, 133.17], "category_id": 1}, {"id": 30, "bbox": [281.28, 901.04, 27.39, 43.56], "category_id": 2}, {"id": 31, "bbox": [1942.86, 505.28, 545.14, 197.88], "category_id": 1}, {"id": 32, "bbox": [1138.83, 3.73, 420.68, 334.78], "category_id": 1}, {"id": 33, "bbox": [83.39, 220.28, 44.81, 59.74], "category_id": 3}, {"id": 34, "bbox": [1641.66, 1228.35, 838.87, 204.11], "category_id": 1}], "caption": "Scheme 1. Synthesis of (5Z,8Z)-[10,11,12,12-2H]Tetradeca-5,8-dienoic Acid (13)a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [167, 63, 682, 77], "ImageBB": [115, 84, 737, 454]}, "reactions": [{"reactants": [9], "conditions": [], "products": [2]}, {"reactants": [2, 32], "conditions": [3], "products": [13]}, {"reactants": [29], "conditions": [6], "products": [20]}, {"reactants": [20], "conditions": [26], "products": [32]}, {"reactants": [13], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [15], "products": [31]}, {"reactants": [31], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [27], "products": [22]}, {"reactants": [14, 22], "conditions": [4], "products": [16]}, {"reactants": [16], "conditions": [24], "products": [34]}, {"reactants": [10], "conditions": [30], "products": [14]}], "diagram_type": "tree"}, {"id": 896, "width": 1348, "height": 380, "file_name": "acs.joc.6b01262-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1025.0, 5.0, 301.0, 189.0], "category_id": 1}, {"id": 1, "bbox": [677.0, 11.0, 323.0, 186.0], "category_id": 1}, {"id": 2, "bbox": [4.0, 271.0, 1343.0, 100.0], "category_id": 4}, {"id": 3, "bbox": [404.0, 127.0, 176.0, 82.0], "category_id": 2}, {"id": 4, "bbox": [22.0, 30.0, 307.0, 153.0], "category_id": 1}, {"id": 5, "bbox": [1160.0, 183.0, 47.0, 34.0], "category_id": 3}, {"id": 6, "bbox": [355.0, 21.0, 268.0, 99.0], "category_id": 2}, {"id": 7, "bbox": [104.0, 198.0, 37.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [831.0, 188.0, 45.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [6, 3], "products": [1, 0]}], "corefs": [[4, 7], [1, 8], [0, 5]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 365, 738, 386], "ImageBB": [449, 392, 786, 487]}, "diagram_type": "single"}, {"id": 906, "width": 1348, "height": 376, "file_name": "acs.joc.5b01366-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [15.0, 304.0, 1326.0, 69.0], "category_id": 4}, {"id": 1, "bbox": [631.0, 68.0, 181.0, 48.0], "category_id": 2}, {"id": 2, "bbox": [188.0, 203.0, 68.0, 66.0], "category_id": 3}, {"id": 3, "bbox": [1128.0, 224.0, 71.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [987.3, 1.0, 295.6, 236.0], "category_id": 1}, {"id": 5, "bbox": [61.0, 3.0, 377.0, 216.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1], "products": [4]}], "corefs": [[5, 2], [4, 3]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 371, 110], "ImageBB": [82, 116, 419, 210]}, "diagram_type": "single"}, {"id": 574, "width": 1356, "height": 1132, "file_name": "acs.orglett.5b00740-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [341.0, 370.0, 200.0, 72.0], "category_id": 3}, {"id": 1, "bbox": [969.0, 507.0, 335.0, 75.0], "category_id": 3}, {"id": 2, "bbox": [525.0, 253.0, 364.0, 85.0], "category_id": 3}, {"id": 3, "bbox": [1012.0, 156.0, 316.0, 201.0], "category_id": 2}, {"id": 4, "bbox": [383.0, 6.0, 681.0, 272.0], "category_id": 1}, {"id": 5, "bbox": [17.0, 222.0, 377.0, 290.0], "category_id": 1}, {"id": 6, "bbox": [660.0, 366.0, 678.0, 281.0], "category_id": 1}, {"id": 7, "bbox": [241.0, 571.0, 37.0, 61.0], "category_id": 3}, {"id": 8, "bbox": [67.0, 717.0, 1239.0, 411.0], "category_id": 4}, {"id": 9, "bbox": [0.0, 26.0, 191.0, 197.0], "category_id": 2}, {"id": 10, "bbox": [22.0, 520.0, 534.0, 96.4], "category_id": 1}], "reactions": [{"reactants": [10, 5], "conditions": [9], "products": [4]}, {"reactants": [4], "conditions": [3], "products": [6]}], "corefs": [[10, 7], [5, 0], [4, 2], [6, 1]], "caption": "Figure 1. TEM images of Oxime-MSNPs: (a) 150,000\u00d7 magni\ufb01ca- tion; (b,c) 500,000\u00d7 magni\ufb01cation of nanoparticles at two di\ufb00erent locations on the dried nanoparticle aggregate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 409, 784, 451], "ImageBB": [448, 116, 787, 399]}, "diagram_type": "tree"}, {"id": 799, "width": 1348, "height": 288, "file_name": "jo501006u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.0, 214.0, 1341.0, 73.0], "category_id": 4}, {"id": 1, "bbox": [347.68, 139.38, 193.16, 50.83], "category_id": 2}, {"id": 2, "bbox": [602.85, 55.01, 246.01, 51.84], "category_id": 1}, {"id": 3, "bbox": [847.85, 55.01, 155.54, 52.86], "category_id": 2}, {"id": 4, "bbox": [601.2, 1.0, 211.5, 48.0], "category_id": 2}, {"id": 5, "bbox": [1125.1, 95.3, 136.4, 51.5], "category_id": 1}, {"id": 6, "bbox": [666.2, 134.2, 293.6, 50.7], "category_id": 2}, {"id": 7, "bbox": [340.3, 86.0, 203.4, 52.3], "category_id": 1}, {"id": 8, "bbox": [81.0, 79.0, 107.0, 64.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [4, 2, 3, 6], "products": [5]}], "corefs": [], "caption": "Table 1. Coupling Reaction of Alkyl (Pseudo)halides with n- BuMgCl Using Phenylpropyne as an Additivea ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 353, 417, 387], "ImageBB": [82, 394, 419, 466]}, "diagram_type": "single"}, {"id": 363, "width": 1120, "height": 720, "file_name": "ol102784c-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.0, 518.0, 238.0, 99.0], "category_id": 1}, {"id": 1, "bbox": [158.0, 417.0, 259.0, 93.0], "category_id": 1}, {"id": 2, "bbox": [185.0, 309.0, 216.0, 100.0], "category_id": 1}, {"id": 3, "bbox": [239.61, 24.1, 139.95, 123.54], "category_id": 1}, {"id": 4, "bbox": [28.0, 218.0, 1061.0, 500.0], "category_id": 4}, {"id": 5, "bbox": [402.0, 96.0, 311.0, 59.0], "category_id": 2}, {"id": 6, "bbox": [796.0, 23.5, 321.0, 137.5], "category_id": 1}, {"id": 7, "bbox": [3.0, 17.7, 199.4, 142.13], "category_id": 1}, {"id": 8, "bbox": [377.07, 2.0, 376.0, 88.0], "category_id": 2}, {"id": 9, "bbox": [506.0, 623.0, 363.0, 89.0], "category_id": 1}, {"id": 10, "bbox": [496.0, 509.0, 376.0, 110.0], "category_id": 1}, {"id": 11, "bbox": [475.0, 408.0, 409.0, 97.0], "category_id": 1}, {"id": 12, "bbox": [521.0, 311.0, 311.0, 91.0], "category_id": 1}, {"id": 13, "bbox": [180.0, 618.0, 233.0, 94.0], "category_id": 1}], "reactions": [{"reactants": [7, 3], "conditions": [8, 5], "products": [6]}], "corefs": [], "caption": "Table 5. Copper-Catalyzed Cross-Coupling Reaction of Different Aryl Iodidesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 493, 713, 520], "ImageBB": [453, 529, 733, 709]}, "diagram_type": "single"}, {"id": 105, "width": 1408, "height": 1760, "file_name": "ja0014685-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [832.04, 258.08, 438.84, 246.94], "category_id": 1}, {"id": 1, "bbox": [113.73, 931.28, 1289.64, 56.5], "category_id": 2}, {"id": 2, "bbox": [155.3, 253.0, 358.05, 246.97], "category_id": 1}, {"id": 3, "bbox": [205.81, 692.4, 289.87, 188.86], "category_id": 1}, {"id": 4, "bbox": [592.16, 727.75, 150.98, 138.36], "category_id": 1}, {"id": 5, "bbox": [746.19, 583.82, 138.35, 100.48], "category_id": 2}, {"id": 6, "bbox": [1152.73, 578.77, 166.13, 92.91], "category_id": 2}, {"id": 7, "bbox": [917.89, 773.21, 113.11, 34.82], "category_id": 2}, {"id": 8, "bbox": [493.68, 467.67, 22.2, 34.82], "category_id": 3}, {"id": 9, "bbox": [1241.11, 467.67, 24.72, 32.3], "category_id": 3}, {"id": 10, "bbox": [465.9, 869.16, 22.2, 34.83], "category_id": 3}, {"id": 11, "bbox": [1114.85, 710.08, 34.83, 44.92], "category_id": 3}, {"id": 12, "bbox": [998.7, 874.21, 27.25, 34.83], "category_id": 3}, {"id": 13, "bbox": [1241.11, 874.21, 22.2, 34.83], "category_id": 3}, {"id": 14, "bbox": [1215.86, 773.21, 42.4, 34.82], "category_id": 2}, {"id": 15, "bbox": [597.2, 336.4, 24.73, 29.74], "category_id": 2}, {"id": 16, "bbox": [733.56, 336.36, 24.74, 34.84], "category_id": 2}, {"id": 17, "bbox": [685.58, 563.62, 22.2, 27.25], "category_id": 2}, {"id": 18, "bbox": [1082.03, 588.87, 22.2, 27.25], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [15, 16], "products": [0]}, {"reactants": [0], "conditions": [17, 5], "products": [3, 4]}, {"reactants": [0], "conditions": [18, 6], "products": [11]}, {"reactants": [11], "conditions": [7], "products": [12]}, {"reactants": [11], "conditions": [14], "products": [13]}], "corefs": [[2, 8], [0, 9], [3, 10]], "caption": "Figure 1. 1H NMR spectrum (400 MHz) for 2 at -50 \u00b0C in CD2Cl2. The signals marked with +, *, and # corresponds to those for 5, mesitylene, and triphenylmethane, respectively. A signal for the two mesityl ring protons of 2 is overlapped with signals for triphenylmethane. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 476, 775, 533], "ImageBB": [424, 36, 776, 475]}, "diagram_type": "tree"}, {"id": 683, "width": 1348, "height": 1156, "file_name": "ol401443a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [61.0, 91.0, 205.0, 168.0], "category_id": 1}, {"id": 1, "bbox": [691.0, 0.0, 250.0, 294.0], "category_id": 1}, {"id": 2, "bbox": [137.0, 263.0, 75.0, 55.0], "category_id": 3}, {"id": 3, "bbox": [766.0, 291.0, 76.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [1014.0, 280.0, 50.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [11.0, 391.9, 1337.0, 764.1], "category_id": 4}, {"id": 6, "bbox": [262.0, 17.0, 443.9, 188.5], "category_id": 2}, {"id": 7, "bbox": [329.0, 213.0, 298.0, 137.0], "category_id": 2}, {"id": 8, "bbox": [933.6, 0.0, 354.4, 280.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [6, 7], "products": [1, 8]}], "corefs": [[0, 2], [1, 3], [8, 4]], "caption": "Table 1. Catalyst Screening", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 583, 100], "ImageBB": [436, 112, 773, 401]}, "diagram_type": "single"}, {"id": 1329, "width": 2820, "height": 1964, "file_name": "op400242j-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1184.99, 541.93, 342.8, 222.98], "category_id": 1}, {"id": 1, "bbox": [1390.96, 220.16, 42.32, 50.8], "category_id": 3}, {"id": 2, "bbox": [1412.12, 1875.58, 53.6, 47.98], "category_id": 3}, {"id": 3, "bbox": [1953.83, 357.05, 166.46, 95.97], "category_id": 2}, {"id": 4, "bbox": [1156.78, 1611.67, 420.39, 269.56], "category_id": 1}, {"id": 5, "bbox": [1410.71, 326.0, 167.87, 135.49], "category_id": 2}, {"id": 6, "bbox": [1410.71, 1350.59, 64.89, 50.8], "category_id": 3}, {"id": 7, "bbox": [1227.31, 1119.14, 325.88, 220.16], "category_id": 1}, {"id": 8, "bbox": [541.71, 541.93, 348.45, 225.8], "category_id": 1}, {"id": 9, "bbox": [1917.15, 0.0, 356.91, 273.79], "category_id": 1}, {"id": 10, "bbox": [850.66, 961.08, 201.73, 138.3], "category_id": 2}, {"id": 11, "bbox": [761.78, 350.0, 150.95, 103.02], "category_id": 2}, {"id": 12, "bbox": [1951.01, 547.57, 324.46, 225.81], "category_id": 1}, {"id": 13, "bbox": [1390.96, 842.53, 239.82, 160.88], "category_id": 2}, {"id": 14, "bbox": [960.69, 182.05, 105.8, 46.58], "category_id": 2}, {"id": 15, "bbox": [541.71, 0.0, 345.62, 225.8], "category_id": 1}, {"id": 16, "bbox": [1667.45, 873.58, 177.75, 50.8], "category_id": 2}, {"id": 17, "bbox": [1158.19, 0.0, 375.25, 217.34], "category_id": 1}, {"id": 18, "bbox": [1574.35, 160.89, 296.25, 139.71], "category_id": 2}, {"id": 19, "bbox": [1458.1, 1422.42, 134.14, 131.61], "category_id": 2}, {"id": 20, "bbox": [1574.35, 72.8, 307.53, 54.9], "category_id": 2}, {"id": 21, "bbox": [966.6, 93.14, 98.9, 44.16], "category_id": 2}], "caption": "Scheme 5. Conversion of pyrrolotriazine 2 to PIV-protected pyrrolotriazine 3", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 479, 519, 494], "ImageBB": [82, 501, 787, 992]}, "reactions": [{"reactants": [17], "conditions": [20, 18], "products": [9]}, {"reactants": [9], "conditions": [3], "products": [12]}, {"reactants": [17], "conditions": [21, 14], "products": [15]}, {"reactants": [15], "conditions": [11], "products": [8]}, {"reactants": [8], "conditions": [10], "products": [7]}, {"reactants": [17], "conditions": [5], "products": [0]}, {"reactants": [0], "conditions": [13], "products": [7]}, {"reactants": [7], "conditions": [19], "products": [4]}], "diagram_type": "graph"}, {"id": 699, "width": 1352, "height": 848, "file_name": "ol047761h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [970.0, 49.0, 235.0, 139.0], "category_id": 1}, {"id": 1, "bbox": [124.0, 0.0, 269.0, 216.0], "category_id": 1}, {"id": 2, "bbox": [427.0, 44.0, 476.0, 57.0], "category_id": 2}, {"id": 3, "bbox": [0.0, 241.0, 1352.0, 607.0], "category_id": 4}, {"id": 4, "bbox": [1189.0, 179.0, 33.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [333.0, 177.0, 28.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [428.0, 134.0, 456.0, 62.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [2, 6], "products": [0]}], "corefs": [[1, 5], [0, 4]], "caption": "Table 1. Lactonization Study of Bn2N-R-Me-Ser", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 196, 699, 210], "ImageBB": [439, 218, 777, 430]}, "diagram_type": "single"}, {"id": 216, "width": 2808, "height": 1784, "file_name": "op030202q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1274.0, 149.9, 234.0, 101.1], "category_id": 2}, {"id": 1, "bbox": [882.2, 0.0, 224.8, 305.2], "category_id": 1}, {"id": 2, "bbox": [1697.8, 11.5, 229.9, 298.5], "category_id": 1}, {"id": 3, "bbox": [1274.0, 5.0, 234.0, 108.3], "category_id": 2}, {"id": 4, "bbox": [955.0, 366.0, 58.0, 70.0], "category_id": 3}, {"id": 5, "bbox": [1780.0, 363.0, 68.0, 70.0], "category_id": 3}, {"id": 6, "bbox": [38.0, 474.0, 2668.0, 1277.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [3, 0], "products": [2]}], "corefs": [[1, 4], [2, 5]], "caption": "Table 2. Aromatic ring hydrogenation of phenyl alanine: catalyst screening", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 490, 67], "ImageBB": [74, 83, 776, 529]}, "diagram_type": "single"}, {"id": 367, "width": 1352, "height": 1784, "file_name": "ol102784c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [38.0, 231.8, 240.6, 107.0], "category_id": 1}, {"id": 1, "bbox": [381.0, 367.0, 53.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [555.0, 2.0, 201.0, 52.0], "category_id": 2}, {"id": 3, "bbox": [482.0, 67.0, 355.0, 62.0], "category_id": 2}, {"id": 4, "bbox": [364.0, 38.0, 116.0, 45.0], "category_id": 2}, {"id": 5, "bbox": [189.0, 6.0, 152.0, 127.0], "category_id": 1}, {"id": 6, "bbox": [669.0, 133.0, 643.0, 252.0], "category_id": 1}, {"id": 7, "bbox": [873.0, 0.0, 290.0, 133.0], "category_id": 1}, {"id": 8, "bbox": [963.0, 367.0, 52.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [585.0, 367.0, 50.0, 39.0], "category_id": 3}, {"id": 10, "bbox": [146.0, 364.0, 47.0, 44.0], "category_id": 3}, {"id": 11, "bbox": [0.0, 430.8, 1352.0, 1353.2], "category_id": 4}, {"id": 12, "bbox": [536.09, 217.62, 217.5, 119.1], "category_id": 1}, {"id": 13, "bbox": [284.94, 194.31, 240.8, 147.59], "category_id": 1}], "reactions": [{"reactants": [5, 4], "conditions": [2, 3], "products": [7]}], "corefs": [[0, 10], [13, 1], [12, 9], [6, 8]], "caption": "Table 1. Optimization of Reaction Conditions in the Copper-Catalyzed Coupling of Iodobenzene and Potassium Thiocyanatea ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 342, 362, 383], "ImageBB": [58, 392, 396, 838]}, "diagram_type": "single"}, {"id": 1005, "width": 1348, "height": 556, "file_name": "ja954050t-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1066.8, 303.35, 275.13, 252.65], "category_id": 1}, {"id": 1, "bbox": [338.52, 155.72, 230.62, 45.16], "category_id": 2}, {"id": 2, "bbox": [662.2, 312.79, 40.46, 45.16], "category_id": 2}, {"id": 3, "bbox": [818.2, 156.39, 212.86, 45.17], "category_id": 2}, {"id": 4, "bbox": [823.37, 88.31, 190.16, 43.14], "category_id": 2}, {"id": 5, "bbox": [1002.07, 407.16, 53.27, 43.82], "category_id": 2}, {"id": 6, "bbox": [602.86, 122.01, 211.74, 50.56], "category_id": 2}, {"id": 7, "bbox": [0.0, 18.88, 299.41, 256.83], "category_id": 1}, {"id": 8, "bbox": [319.64, 91.68, 249.5, 41.12], "category_id": 2}, {"id": 9, "bbox": [0.0, 87.63, 2.7, 45.17], "category_id": 2}, {"id": 10, "bbox": [1056.01, 2.7, 291.99, 254.81], "category_id": 1}, {"id": 11, "bbox": [124.08, 315.48, 54.62, 45.84], "category_id": 3}], "caption": "Scheme 7", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 56, 485, 70], "ImageBB": [429, 75, 766, 214]}, "reactions": [{"reactants": [7], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [1], "products": [7]}, {"reactants": [6], "conditions": [4], "products": [10]}, {"reactants": [10], "conditions": [3], "products": [6]}, {"reactants": [6], "conditions": [2], "products": [0]}, {"reactants": [0], "conditions": [], "products": [6]}], "diagram_type": "tree"}, {"id": 40, "width": 1348, "height": 1012, "file_name": "ja5017206-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [63.44, 216.08, 139.06, 46.4], "category_id": 3}, {"id": 1, "bbox": [908.29, 217.39, 246.19, 45.09], "category_id": 3}, {"id": 2, "bbox": [225.4, 546.45, 161.26, 45.09], "category_id": 3}, {"id": 3, "bbox": [212.3, 824.59, 187.42, 43.79], "category_id": 3}, {"id": 4, "bbox": [772.49, 824.59, 187.42, 43.79], "category_id": 3}, {"id": 5, "bbox": [784.24, 546.45, 166.53, 45.09], "category_id": 3}, {"id": 6, "bbox": [13.81, 5.85, 251.39, 200.45], "category_id": 1}, {"id": 7, "bbox": [903.59, 6.16, 274.41, 200.61], "category_id": 1}, {"id": 8, "bbox": [1234.91, 71.75, 96.15, 43.0], "category_id": 3}, {"id": 9, "bbox": [178.35, 346.67, 256.63, 191.34], "category_id": 1}, {"id": 10, "bbox": [598.82, 346.67, 539.99, 191.34], "category_id": 1}, {"id": 11, "bbox": [179.65, 622.19, 251.41, 191.34], "category_id": 1}, {"id": 12, "bbox": [596.2, 622.19, 543.91, 192.65], "category_id": 1}, {"id": 13, "bbox": [357.24, 46.33, 277.53, 43.78], "category_id": 2}, {"id": 14, "bbox": [721.56, 47.63, 120.83, 43.79], "category_id": 2}, {"id": 15, "bbox": [372.91, 127.29, 242.27, 167.84], "category_id": 2}, {"id": 16, "bbox": [726.79, 128.59, 109.07, 35.96], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [13, 15, 14, 16], "products": [7, 8]}], "corefs": [[6, 0], [7, 1], [9, 2], [10, 5], [11, 3], [12, 4]], "caption": "Table 3. APF Rearrangement of Racemic (Z)-1 Catalyzed by (R)-3a as Reference for Crossover Experimentsa ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 125], "ImageBB": [449, 131, 786, 384]}, "diagram_type": "single"}, {"id": 882, "width": 1348, "height": 484, "file_name": "ol503618m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.0, 252.0, 370.0, 135.0], "category_id": 3}, {"id": 1, "bbox": [54.0, 207.0, 38.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [407.0, 206.0, 56.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [1141.0, 206.0, 32.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [997.0, 243.0, 186.0, 88.0], "category_id": 3}, {"id": 5, "bbox": [584.0, 121.0, 369.0, 83.0], "category_id": 2}, {"id": 6, "bbox": [3.0, 408.0, 1345.0, 76.0], "category_id": 4}, {"id": 7, "bbox": [324.7, 57.7, 192.4, 112.6], "category_id": 1}, {"id": 8, "bbox": [25.8, 8.7, 208.1, 242.0], "category_id": 1}, {"id": 9, "bbox": [577.0, 34.0, 353.0, 82.0], "category_id": 2}, {"id": 10, "bbox": [1034.3, 4.4, 294.0, 208.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [9, 5], "products": [10]}], "corefs": [[8, 1], [7, 2], [10, 3], [8, 0], [10, 4]], "caption": "Table 1. Optimization of the Reaction Parametersa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 138, 372, 157], "ImageBB": [82, 162, 419, 283]}, "diagram_type": "single"}, {"id": 1207, "width": 1352, "height": 1472, "file_name": "ol800418m-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [567.16, 1128.12, 215.07, 94.25], "category_id": 2}, {"id": 1, "bbox": [260.74, 252.57, 62.61, 48.6], "category_id": 3}, {"id": 2, "bbox": [1035.61, 773.19, 52.3, 50.81], "category_id": 3}, {"id": 3, "bbox": [563.47, 24.3, 209.19, 95.73], "category_id": 2}, {"id": 4, "bbox": [104.59, 1100.13, 364.6, 263.62], "category_id": 1}, {"id": 5, "bbox": [739.51, 335.05, 348.4, 146.53], "category_id": 2}, {"id": 6, "bbox": [526.65, 135.49, 282.84, 154.64], "category_id": 2}, {"id": 7, "bbox": [903.03, 534.6, 337.35, 234.9], "category_id": 1}, {"id": 8, "bbox": [261.48, 765.09, 55.98, 50.07], "category_id": 3}, {"id": 9, "bbox": [1072.44, 254.78, 55.25, 45.66], "category_id": 3}, {"id": 10, "bbox": [139.95, 905.0, 155.41, 101.62], "category_id": 2}, {"id": 11, "bbox": [109.01, 505.88, 360.18, 261.42], "category_id": 1}, {"id": 12, "bbox": [280.63, 1365.96, 67.03, 53.02], "category_id": 3}, {"id": 13, "bbox": [486.87, 1248.14, 403.64, 112.67], "category_id": 2}, {"id": 14, "bbox": [525.17, 546.39, 349.87, 105.3], "category_id": 2}, {"id": 15, "bbox": [868.41, 1093.51, 363.13, 270.24], "category_id": 1}, {"id": 16, "bbox": [1104.85, 372.6, 120.8, 64.8], "category_id": 2}, {"id": 17, "bbox": [525.91, 658.31, 349.13, 150.22], "category_id": 2}, {"id": 18, "bbox": [1038.56, 1363.75, 47.14, 50.08], "category_id": 3}, {"id": 19, "bbox": [329.25, 866.71, 702.68, 191.45], "category_id": 2}, {"id": 20, "bbox": [109.01, 0.0, 346.93, 245.95], "category_id": 1}, {"id": 21, "bbox": [902.3, 0.0, 340.29, 245.95], "category_id": 1}], "caption": "Scheme 4. Preparation of Diol 14", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [138, 74, 314, 89], "ImageBB": [58, 96, 396, 464]}, "reactions": [{"reactants": [20], "conditions": [3, 6], "products": [21]}, {"reactants": [21], "conditions": [5, 16], "products": [7]}, {"reactants": [7], "conditions": [14, 17], "products": [11]}, {"reactants": [11], "conditions": [10, 19], "products": [4]}, {"reactants": [4], "conditions": [0, 13], "products": [15]}], "diagram_type": "tree"}, {"id": 816, "width": 1348, "height": 496, "file_name": "jo4014707-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1086.0, 295.0, 144.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [65.5, 44.0, 185.5, 233.0], "category_id": 1}, {"id": 2, "bbox": [521.2, 0.3, 470.7, 149.5], "category_id": 2}, {"id": 3, "bbox": [1022.3, 47.0, 262.7, 229.0], "category_id": 1}, {"id": 4, "bbox": [314.14, 139.18, 178.92, 51.85], "category_id": 2}, {"id": 5, "bbox": [6.0, 379.0, 1334.0, 117.0], "category_id": 4}, {"id": 6, "bbox": [112.0, 301.0, 63.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [635.0, 186.0, 242.0, 49.0], "category_id": 2}, {"id": 8, "bbox": [379.0, 229.0, 53.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [2, 7], "products": [3]}], "corefs": [[1, 6], [4, 8], [3, 0]], "caption": "Table 3. Asymmetric 1,4-Addition of 2a to N-Me-maleimide (6a)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 417, 125], "ImageBB": [82, 131, 419, 255]}, "diagram_type": "single"}, {"id": 955, "width": 1704, "height": 1188, "file_name": "acs.orglett.6b01059-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [234.42, 379.47, 92.91, 63.96], "category_id": 3}, {"id": 1, "bbox": [503.97, 566.15, 139.77, 108.39], "category_id": 1}, {"id": 2, "bbox": [300.03, 578.99, 162.58, 52.77], "category_id": 2}, {"id": 3, "bbox": [185.94, 544.76, 58.47, 42.78], "category_id": 2}, {"id": 4, "bbox": [328.55, 263.8, 159.73, 52.77], "category_id": 2}, {"id": 5, "bbox": [310.01, 316.57, 79.87, 37.08], "category_id": 2}, {"id": 6, "bbox": [245.83, 221.02, 35.66, 39.93], "category_id": 2}, {"id": 7, "bbox": [144.58, 285.2, 38.5, 38.5], "category_id": 2}, {"id": 8, "bbox": [1222.76, 510.53, 85.57, 44.21], "category_id": 2}, {"id": 9, "bbox": [1237.02, 404.99, 136.92, 54.2], "category_id": 2}, {"id": 10, "bbox": [1163.56, 737.62, 41.77, 44.35], "category_id": 3}, {"id": 11, "bbox": [981.14, 470.71, 329.04, 240.48], "category_id": 1}, {"id": 12, "bbox": [981.14, 126.21, 114.23, 43.49], "category_id": 2}, {"id": 13, "bbox": [811.51, 239.62, 58.82, 45.2], "category_id": 3}, {"id": 14, "bbox": [95.47, 422.11, 150.03, 59.69], "category_id": 2}, {"id": 15, "bbox": [627.39, 722.27, 60.52, 53.73], "category_id": 3}, {"id": 16, "bbox": [705.81, 648.08, 315.4, 240.48], "category_id": 1}, {"id": 17, "bbox": [561.75, 661.73, 44.33, 47.75], "category_id": 3}, {"id": 18, "bbox": [519.13, 166.28, 190.94, 115.13], "category_id": 1}, {"id": 19, "bbox": [768.04, 871.5, 47.73, 47.76], "category_id": 3}, {"id": 20, "bbox": [685.35, 3.41, 283.86, 241.33], "category_id": 1}, {"id": 21, "bbox": [575.39, 263.5, 57.96, 43.49], "category_id": 3}, {"id": 22, "bbox": [981.14, 169.7, 394.68, 240.47], "category_id": 1}], "caption": "Scheme 3. Proposed Mechanism", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 797, 633, 812], "ImageBB": [433, 830, 859, 1127]}, "reactions": [{"reactants": [1], "conditions": [15], "products": [16]}, {"reactants": [16], "conditions": [], "products": [11]}, {"reactants": [11, 8], "conditions": [], "products": [22, 9]}, {"reactants": [22], "conditions": [12], "products": [20]}, {"reactants": [6, 4, 5], "conditions": [], "products": [7, 0, 14]}, {"reactants": [14], "conditions": [3], "products": [2]}, {"reactants": [18, 2], "conditions": [], "products": [4, 1]}], "diagram_type": "graph"}, {"id": 920, "width": 2820, "height": 1096, "file_name": "acs.joc.5b02237-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1355.69, 286.41, 47.96, 49.39], "category_id": 3}, {"id": 1, "bbox": [1819.81, 105.82, 187.62, 60.67], "category_id": 2}, {"id": 2, "bbox": [1524.97, 33.86, 260.98, 80.42], "category_id": 2}, {"id": 3, "bbox": [1433.28, 616.57, 272.26, 274.13], "category_id": 1}, {"id": 4, "bbox": [1165.38, 887.21, 68.06, 53.17], "category_id": 3}, {"id": 5, "bbox": [1529.05, 889.34, 63.8, 53.17], "category_id": 3}, {"id": 6, "bbox": [1437.51, 445.85, 850.65, 173.54], "category_id": 2}, {"id": 7, "bbox": [1783.13, 678.65, 93.11, 55.02], "category_id": 2}, {"id": 8, "bbox": [1527.79, 145.32, 255.34, 52.21], "category_id": 2}, {"id": 9, "bbox": [1719.65, 746.37, 221.48, 53.61], "category_id": 2}, {"id": 10, "bbox": [1132.8, 67.72, 80.41, 57.85], "category_id": 2}, {"id": 11, "bbox": [804.1, 0.0, 272.27, 279.36], "category_id": 1}, {"id": 12, "bbox": [1101.58, 215.18, 153.13, 42.53], "category_id": 2}, {"id": 13, "bbox": [591.18, 449.11, 663.53, 168.01], "category_id": 2}, {"id": 14, "bbox": [1958.06, 613.74, 276.5, 280.77], "category_id": 1}, {"id": 15, "bbox": [907.08, 286.41, 36.68, 45.15], "category_id": 3}, {"id": 16, "bbox": [2052.58, 893.1, 84.64, 53.62], "category_id": 3}, {"id": 17, "bbox": [636.23, 894.51, 64.89, 42.33], "category_id": 3}, {"id": 18, "bbox": [536.07, 613.74, 266.62, 275.13], "category_id": 1}, {"id": 19, "bbox": [536.07, 967.88, 847.83, 81.83], "category_id": 2}, {"id": 20, "bbox": [1132.8, 145.32, 80.41, 57.85], "category_id": 2}, {"id": 21, "bbox": [1059.44, 620.8, 259.57, 245.5], "category_id": 1}, {"id": 22, "bbox": [804.1, 736.49, 249.7, 52.21], "category_id": 2}, {"id": 23, "bbox": [1254.12, 0.0, 265.21, 280.77], "category_id": 1}, {"id": 24, "bbox": [1132.8, 375.3, 526.19, 53.62], "category_id": 2}], "caption": "Scheme 1. Photochemical Transformations of Stilbenes/Diarylethenes", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 476, 110], "ImageBB": [82, 116, 787, 390]}, "reactions": [{"reactants": [11], "conditions": [10, 20, 12], "products": [23]}, {"reactants": [23], "conditions": [2, 8], "products": [1]}, {"reactants": [18], "conditions": [22], "products": [21]}, {"reactants": [3], "conditions": [7, 9], "products": [14]}], "diagram_type": "multiple"}, {"id": 374, "width": 1416, "height": 908, "file_name": "ol1018773-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [370.7, 669.2, 458.6, 147.9], "category_id": 1}, {"id": 1, "bbox": [631.3, 861.0, 48.7, 47.0], "category_id": 3}, {"id": 2, "bbox": [1180.0, 861.0, 41.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [356.0, 571.0, 47.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [121.7, 218.3, 452.3, 330.7], "category_id": 1}, {"id": 5, "bbox": [870.5, 220.6, 490.2, 340.7], "category_id": 1}, {"id": 6, "bbox": [1010.3, 690.6, 350.6, 172.4], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [0, 6]}], "corefs": [[4, 3], [0, 1], [6, 2]], "caption": "Figure 1. Retrosynthesis of 1 highlighting the chirons from stereoselective hydrogenations. 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Synthesis of trifluoromethyl olefins via strategy A.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 1007, 756, 1020], "ImageBB": [437, 661, 773, 994]}, "diagram_type": "single"}, {"id": 42, "width": 1352, "height": 344, "file_name": "ja5017206-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [790.24, 46.64, 242.62, 90.7], "category_id": 2}, {"id": 1, "bbox": [1071.65, 43.58, 242.62, 173.29], "category_id": 1}, {"id": 2, "bbox": [528.2, 44.6, 237.53, 169.21], "category_id": 1}, {"id": 3, "bbox": [23.49, 44.6, 233.45, 170.23], "category_id": 1}, {"id": 4, "bbox": [234.55, 157.77, 271.18, 79.49], "category_id": 2}, {"id": 5, "bbox": [1025.73, 248.99, 297.72, 86.66], "category_id": 2}, {"id": 6, "bbox": [572.0, 241.85, 124.39, 30.59], "category_id": 2}, {"id": 7, "bbox": [302.86, 93.54, 144.75, 41.76], "category_id": 2}, {"id": 8, "bbox": [786.16, 155.73, 242.62, 80.51], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [7, 4], "products": [2]}, {"reactants": [2], "conditions": [0, 8], "products": [1]}], "corefs": [[2, 6], [1, 5]], "caption": "Figure 1. Catalytic sequence for providing optically active \u03b2-amino aldehydes having an alkyl substituent at the \u03b2-position. 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Synthetic route and conditions used for large-scale production of 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 509, 67], "ImageBB": [160, 71, 690, 666]}, "reactions": [{"reactants": [15], "conditions": [19, 4], "products": [28]}, {"reactants": [28], "conditions": [2], "products": [37]}, {"reactants": [28], "conditions": [39], "products": [37]}, {"reactants": [37], "conditions": [5], "products": [11]}, {"reactants": [11], "conditions": [3, 6], "products": [10]}, {"reactants": [10], "conditions": [14, 24], "products": [30]}, {"reactants": [30], "conditions": [9], "products": [34]}, {"reactants": [34], "conditions": [17, 32], "products": [33]}, {"reactants": [33], "conditions": [12, 26], "products": [29]}, {"reactants": [29], "conditions": [31], "products": [38, 22]}, {"reactants": [35], "conditions": [0], "products": [25, 1]}, {"reactants": [8], "conditions": [], "products": [27]}], "diagram_type": "tree"}, {"id": 1342, "width": 2152, "height": 736, "file_name": "op700026n-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1779.52, 0.0, 346.64, 320.74], "category_id": 1}, {"id": 1, "bbox": [629.77, 660.84, 47.37, 51.67], "category_id": 3}, {"id": 2, "bbox": [1137.9, 4.31, 345.57, 314.27], "category_id": 1}, {"id": 3, "bbox": [1982.98, 307.82, 50.6, 51.66], "category_id": 3}, {"id": 4, "bbox": [1000.1, 552.14, 46.3, 49.51], "category_id": 3}, {"id": 5, "bbox": [1503.92, 108.71, 218.54, 55.96], "category_id": 2}, {"id": 6, "bbox": [385.4, 424.06, 402.63, 311.94], "category_id": 1}, {"id": 7, "bbox": [1331.68, 311.05, 48.44, 44.13], "category_id": 3}, {"id": 8, "bbox": [348.8, 127.0, 180.86, 47.36], "category_id": 2}, {"id": 9, "bbox": [709.44, 309.97, 48.44, 47.36], "category_id": 3}, {"id": 10, "bbox": [0.0, 4.31, 375.71, 309.97], "category_id": 1}, {"id": 11, "bbox": [123.8, 308.9, 45.22, 48.43], "category_id": 3}, {"id": 12, "bbox": [1638.49, 663.0, 455.38, 59.19], "category_id": 3}, {"id": 13, "bbox": [865.54, 395.0, 447.84, 222.79], "category_id": 1}, {"id": 14, "bbox": [1418.88, 395.0, 733.12, 314.28], "category_id": 1}, {"id": 15, "bbox": [535.04, 3.23, 376.79, 313.2], "category_id": 1}, {"id": 16, "bbox": [87.2, 504.78, 110.88, 53.82], "category_id": 2}], "caption": "Scheme 1. Synthesis of amide 1 (MK-0364, taranabant) via resolution", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 465, 67], "ImageBB": [156, 71, 694, 255]}, "reactions": [{"reactants": [10], "conditions": [8], "products": [15]}, {"reactants": [15], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [5], "products": [0]}, {"reactants": [0], "conditions": [16], "products": [6]}, {"reactants": [6, 13], "conditions": [], "products": [14]}], "diagram_type": "multiple"}, {"id": 151, "width": 1012, "height": 680, "file_name": "op700178q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [110.0, 479.0, 146.0, 51.0], "category_id": 2}, {"id": 1, "bbox": [64.0, 576.0, 261.0, 67.0], "category_id": 2}, {"id": 2, "bbox": [686.6, 29.8, 324.4, 257.2], "category_id": 1}, {"id": 3, "bbox": [1.5, 36.7, 311.8, 255.4], "category_id": 1}, {"id": 4, "bbox": [412.2, 423.8, 515.4, 256.2], "category_id": 1}, {"id": 5, "bbox": [984.0, 267.0, 28.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [262.0, 263.0, 47.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [727.0, 630.0, 53.0, 48.0], "category_id": 3}, {"id": 8, "bbox": [390.0, 59.0, 193.0, 60.0], "category_id": 2}, {"id": 9, "bbox": [394.0, 169.0, 118.0, 44.0], "category_id": 2}, {"id": 10, "bbox": [394.0, 249.0, 161.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [8, 9, 10], "products": [2]}, {"reactants": [2], "conditions": [0, 1], "products": [4]}], "corefs": [[3, 6], [2, 5], [4, 7]], "caption": "Table 1. Catalyst N-substituent optimisation studya", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 456, 341, 470], "ImageBB": [158, 275, 411, 445]}, "diagram_type": "multiple"}, {"id": 566, "width": 1352, "height": 896, "file_name": "acs.orglett.5b01077-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [481.0, 178.0, 331.0, 67.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 472.0, 1339.0, 415.0], "category_id": 4}, {"id": 2, "bbox": [521.0, 258.0, 232.0, 96.0], "category_id": 2}, {"id": 3, "bbox": [459.0, 78.0, 192.0, 58.0], "category_id": 2}, {"id": 4, "bbox": [502.0, 371.0, 187.0, 55.0], "category_id": 2}, {"id": 5, "bbox": [52.0, 354.0, 194.0, 58.0], "category_id": 2}, {"id": 6, "bbox": [1261.0, 396.0, 48.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [17.5, 130.0, 252.5, 200.6], "category_id": 1}, {"id": 8, "bbox": [284.8, 13.8, 197.2, 185.1], "category_id": 1}, {"id": 9, "bbox": [806.3, 4.0, 521.2, 450.1], "category_id": 1}, {"id": 10, "bbox": [300.2, 236.2, 197.5, 186.5], "category_id": 1}], "reactions": [{"reactants": [7, 8, 10], "conditions": [0, 2], "products": [9]}], "corefs": [[9, 6]], "caption": "Table 3. Competition Experiments", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 542, 275, 558], "ImageBB": [82, 563, 420, 787]}, "diagram_type": "single"}, {"id": 597, "width": 2820, "height": 3484, "file_name": "acs.oprd.6b00117-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2127.0, 261.0, 63.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [475.11, 41.06, 329.0, 230.0], "category_id": 1}, {"id": 2, "bbox": [1291.0, 0.0, 496.0, 120.0], "category_id": 2}, {"id": 3, "bbox": [1388.0, 172.0, 286.0, 94.0], "category_id": 2}, {"id": 4, "bbox": [622.0, 257.0, 29.0, 36.0], "category_id": 3}, {"id": 5, "bbox": [1000.0, 266.0, 59.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 321.0, 2820.0, 898.0], "category_id": 4}, {"id": 7, "bbox": [1893.0, 1292.0, 471.0, 285.0], "category_id": 1}, {"id": 8, "bbox": [1288.0, 1306.0, 487.0, 96.0], "category_id": 2}, {"id": 9, "bbox": [1397.0, 1466.0, 277.0, 99.0], "category_id": 2}, {"id": 10, "bbox": [606.0, 1555.0, 25.0, 33.0], "category_id": 3}, {"id": 11, "bbox": [988.0, 1554.0, 52.0, 36.0], "category_id": 3}, {"id": 12, "bbox": [2135.0, 1552.0, 68.0, 43.0], "category_id": 3}, {"id": 13, "bbox": [914.1, 1343.0, 215.6, 199.1], "category_id": 1}, {"id": 14, "bbox": [453.11, 1340.0, 333.0, 219.0], "category_id": 1}, {"id": 15, "bbox": [1871.89, 0.0, 468.61, 276.1], "category_id": 1}, {"id": 16, "bbox": [914.11, 49.83, 229.59, 204.97], "category_id": 1}], "reactions": [{"reactants": [1, 16], "conditions": [2, 3], "products": [15]}, {"reactants": [14, 13], "conditions": [8, 9], "products": [7]}], "corefs": [[1, 4], [16, 5], [15, 0], [14, 10], [13, 11], [7, 12]], "caption": "Table 2. Solvent Screening for the Radical Arylation of Quinoline N-Oxide 16", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 513, 111], "ImageBB": [82, 116, 787, 987]}, "diagram_type": "multiple"}, {"id": 379, "width": 1288, "height": 1792, "file_name": "ol071386m-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [625.0, 52.0, 190.0, 43.0], "category_id": 2}, {"id": 1, "bbox": [651.0, 120.0, 128.0, 92.0], "category_id": 2}, {"id": 2, "bbox": [863.0, 0.0, 274.0, 146.0], "category_id": 1}, {"id": 3, "bbox": [963.0, 163.0, 30.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [3.0, 236.0, 1285.0, 1556.0], "category_id": 4}, {"id": 5, "bbox": [242.0, 167.0, 30.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [404.0, 84.0, 138.0, 51.0], "category_id": 1}, {"id": 7, "bbox": [473.0, 172.0, 39.0, 30.0], "category_id": 3}, {"id": 8, "bbox": [142.4, 28.0, 187.6, 116.0], "category_id": 1}], "reactions": [{"reactants": [8, 6], "conditions": [0, 1], "products": [2]}], "corefs": [[8, 5], [6, 7], [2, 3]], "caption": "Table 2. Pt/SPOs-Catalyzed [2 + 1] Cycloaddition of 4 with 5aa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 475, 736, 507], "ImageBB": [447, 513, 769, 961]}, "diagram_type": "single"}, {"id": 855, "width": 2808, "height": 3020, "file_name": "jo200666z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.0, 405.0, 2765.0, 2615.0], "category_id": 4}, {"id": 1, "bbox": [877.0, 263.0, 34.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [1171.0, 255.0, 40.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [1790.0, 263.0, 28.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [1134.0, 118.0, 130.0, 95.0], "category_id": 1}, {"id": 5, "bbox": [1279.0, 169.0, 356.0, 95.0], "category_id": 2}, {"id": 6, "bbox": [1261.0, 79.0, 343.0, 51.0], "category_id": 2}, {"id": 7, "bbox": [1645.0, 17.0, 418.0, 323.0], "category_id": 1}, {"id": 8, "bbox": [741.0, 8.0, 359.0, 242.0], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [6, 5], "products": [7]}], "corefs": [[8, 1], [4, 2], [7, 3]], "caption": "Table 2. Alkenylation of 2-(Phenylsul\ufb01nyl)pyridines with Alkenesa", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 441, 108], "ImageBB": [71, 117, 773, 872]}, "diagram_type": "single"}, {"id": 36, "width": 1348, "height": 1444, "file_name": "ja5080739-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [70.41, 28.42, 202.19, 108.59], "category_id": 1}, {"id": 1, "bbox": [601.23, 95.15, 289.73, 79.13], "category_id": 2}, {"id": 2, "bbox": [601.66, 12.82, 315.3, 80.43], "category_id": 2}, {"id": 3, "bbox": [1056.22, 27.98, 255.07, 110.77], "category_id": 1}, {"id": 4, "bbox": [301.37, 5.02, 249.43, 159.73], "category_id": 1}, {"id": 5, "bbox": [1.21, 173.2, 1336.07, 1267.11], "category_id": 4}, {"id": 6, "bbox": [1106.06, 133.71, 25.4, 34.07], "category_id": 3}, {"id": 7, "bbox": [483.37, 134.15, 43.59, 33.2], "category_id": 3}, {"id": 8, "bbox": [112.44, 135.01, 19.76, 33.2], "category_id": 3}], "reactions": [{"reactants": [0, 4], "conditions": [2, 1], "products": [3]}], "corefs": [[0, 8], [4, 7], [3, 6]], "caption": "Table 4. Scope of the Asymmetric Reactiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 596, 702, 617], "ImageBB": [449, 623, 786, 984]}, "diagram_type": "single"}, {"id": 559, "width": 1348, "height": 388, "file_name": "acs.orglett.5b02003-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [155.0, 220.0, 59.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [492.0, 216.0, 64.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [655.0, 78.0, 335.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [12.0, 309.0, 1333.0, 74.0], "category_id": 4}, {"id": 4, "bbox": [1110.92, 248.02, 83.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [385.0, 49.1, 278.1, 165.9], "category_id": 1}, {"id": 6, "bbox": [722.2, 140.0, 184.6, 50.0], "category_id": 2}, {"id": 7, "bbox": [981.2, 1.0, 347.6, 253.0], "category_id": 1}, {"id": 8, "bbox": [25.3, 29.0, 341.7, 199.0], "category_id": 1}], "reactions": [{"reactants": [8, 5], "conditions": [2, 6], "products": [7]}], "corefs": [[8, 0], [5, 1], [7, 4]], "caption": "Table 1. Screening of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 288, 352, 309], "ImageBB": [82, 315, 419, 412]}, "diagram_type": "single"}, {"id": 152, "width": 1352, "height": 1204, "file_name": "op7001694-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 902.0, 1351.0, 270.0], "category_id": 2}, {"id": 1, "bbox": [435.0, 57.0, 283.0, 59.0], "category_id": 2}, {"id": 2, "bbox": [983.0, 226.23, 52.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [795.0, 3.0, 399.5, 197.0], "category_id": 1}, {"id": 4, "bbox": [151.0, 45.0, 265.0, 160.0], "category_id": 1}, {"id": 5, "bbox": [259.0, 227.0, 47.9, 56.0], "category_id": 3}, {"id": 6, "bbox": [46.0, 289.0, 1250.0, 598.0], "category_id": 4}, {"id": 7, "bbox": [519.0, 154.0, 112.0, 57.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [1, 7], "products": [3]}], "corefs": [[4, 5], [3, 2]], "caption": "Table 1. 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Di\ufb00erent Approaches to Primary \u03b1-Ketoamides", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 367, 411, 387], "ImageBB": [82, 392, 420, 708]}, "reactions": [{"reactants": [2, 8], "conditions": [28, 10, 12, 16], "products": [14]}, {"reactants": [15, 19], "conditions": [21, 18], "products": [13]}, {"reactants": [0, 1], "conditions": [9, 20], "products": [4]}, {"reactants": [5], "conditions": [17, 11], "products": [7]}], "diagram_type": "multiple"}, {"id": 708, "width": 1316, "height": 1588, "file_name": "ol0349920-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [25.5, 4.1, 287.5, 217.5], "category_id": 1}, {"id": 1, "bbox": [315.13, 31.87, 285.0, 84.0], "category_id": 2}, {"id": 2, "bbox": [966.0, 69.0, 104.0, 52.9], "category_id": 2}, {"id": 3, "bbox": [330.51, 115.13, 255.0, 148.5], "category_id": 2}, {"id": 4, "bbox": [622.29, 2.1, 324.91, 188.39], "category_id": 1}, {"id": 5, "bbox": [1108.0, 57.0, 186.0, 140.0], "category_id": 1}, {"id": 6, "bbox": [949.0, 121.0, 133.0, 44.0], "category_id": 2}, {"id": 7, "bbox": [87.0, 208.0, 58.0, 61.0], "category_id": 3}, {"id": 8, "bbox": [676.0, 205.0, 78.0, 67.0], "category_id": 3}, {"id": 9, "bbox": [1178.0, 205.0, 61.0, 61.0], "category_id": 3}, {"id": 10, "bbox": [17.0, 304.0, 1299.0, 1284.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [1, 3], "products": [4]}, {"reactants": [4], "conditions": [2, 6], "products": [5]}], "corefs": [[0, 7], [4, 8], [5, 9]], "caption": "Table 2. 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Synthesis of the Bromide 12", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 643, 102], "ImageBB": [437, 111, 773, 531]}, "reactions": [{"reactants": [11], "conditions": [19, 4], "products": [5]}, {"reactants": [5], "conditions": [15, 9], "products": [6]}, {"reactants": [6], "conditions": [18, 3], "products": [1]}, {"reactants": [1], "conditions": [17, 21, 16], "products": [10]}, {"reactants": [10], "conditions": [22, 0], "products": [20]}], "diagram_type": "tree"}, {"id": 1216, "width": 1352, "height": 1196, "file_name": "ol9005322-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [302.32, 566.19, 282.71, 78.47], "category_id": 2}, {"id": 1, "bbox": [136.62, 489.07, 45.99, 44.65], "category_id": 2}, {"id": 2, "bbox": [136.62, 915.91, 44.64, 45.32], "category_id": 2}, {"id": 3, "bbox": [135.94, 16.23, 46.67, 49.39], "category_id": 2}, {"id": 4, "bbox": [676.34, 516.81, 129.86, 431.57], "category_id": 1}, {"id": 5, "bbox": [158.26, 976.79, 93.34, 161.67], "category_id": 1}, {"id": 6, "bbox": [713.54, 1009.94, 254.3, 49.38], "category_id": 2}, {"id": 7, "bbox": [1133.54, 625.71, 49.38, 50.06], "category_id": 3}, {"id": 8, "bbox": [522.13, 0.0, 137.3, 486.37], "category_id": 1}, {"id": 9, "bbox": [543.78, 978.14, 140.67, 163.03], "category_id": 1}, {"id": 10, "bbox": [158.26, 546.57, 136.62, 209.7], "category_id": 1}, {"id": 11, "bbox": [256.33, 133.26, 123.77, 233.38], "category_id": 1}, {"id": 12, "bbox": [808.22, 602.04, 265.13, 48.03], "category_id": 2}, {"id": 13, "bbox": [890.06, 654.8, 96.72, 41.94], "category_id": 2}, {"id": 14, "bbox": [832.57, 794.15, 48.02, 46.0], "category_id": 3}, {"id": 15, "bbox": [913.06, 379.49, 58.16, 51.41], "category_id": 3}, {"id": 16, "bbox": [1030.74, 1028.88, 180.58, 56.82], "category_id": 1}, {"id": 17, "bbox": [319.23, 1007.23, 147.44, 52.09], "category_id": 2}, {"id": 18, "bbox": [302.32, 654.13, 260.39, 41.94], "category_id": 2}, {"id": 19, "bbox": [280.68, 383.55, 41.26, 45.32], "category_id": 3}, {"id": 20, "bbox": [835.28, 48.03, 242.8, 302.37], "category_id": 1}, {"id": 21, "bbox": [171.11, 791.44, 56.82, 46.0], "category_id": 3}, {"id": 22, "bbox": [676.34, 380.16, 53.43, 50.74], "category_id": 3}], "caption": "Scheme 3. (a) Nitrile Oxide Precursors 9-11, (b) Synthesis of  the Dabcyl-Oxime 10, and (c) Depiction of the Nitrile Oxide            Preparation via Hydroximoyl Chlorides ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [64, 179, 388, 221], "ImageBB": [58, 229, 396, 528]}, "reactions": [{"reactants": [10], "conditions": [0, 18], "products": [4]}, {"reactants": [4], "conditions": [12, 13], "products": [7]}, {"reactants": [5], "conditions": [17], "products": [9]}, {"reactants": [9], "conditions": [6], "products": [16]}], "diagram_type": "multiple"}, {"id": 1377, "width": 1128, "height": 1016, "file_name": "op990067a-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [870.69, 817.97, 157.43, 46.82], "category_id": 2}, {"id": 1, "bbox": [5.08, 190.11, 59.25, 46.25], "category_id": 3}, {"id": 2, "bbox": [921.47, 230.72, 105.52, 39.49], "category_id": 2}, {"id": 3, "bbox": [640.46, 401.09, 47.96, 36.1], "category_id": 3}, {"id": 4, "bbox": [116.81, 99.85, 211.6, 101.54], "category_id": 2}, {"id": 5, "bbox": [843.6, 76.72, 253.93, 118.46], "category_id": 2}, {"id": 6, "bbox": [919.78, 746.32, 30.47, 50.78], "category_id": 3}, {"id": 7, "bbox": [352.68, 5.08, 468.35, 397.7], "category_id": 1}, {"id": 8, "bbox": [733.0, 248.8, 87.47, 81.77], "category_id": 2}, {"id": 9, "bbox": [459.27, 828.75, 86.42, 79.87], "category_id": 2}, {"id": 10, "bbox": [808.85, 446.44, 291.97, 154.5], "category_id": 4}, {"id": 11, "bbox": [76.74, 584.42, 473.44, 406.17], "category_id": 1}], "caption": "Scheme 5", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [467, 73, 749, 327]}, "reactions": [{"reactants": [1], "conditions": [4], "products": [7]}, {"reactants": [7], "conditions": [5, 2], "products": [11]}, {"reactants": [11], "conditions": [], "products": [6]}], "diagram_type": "multiple"}, {"id": 876, "width": 1352, "height": 660, "file_name": "ol701624y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [852.1, 190.17, 140.72, 47.48], "category_id": 2}, {"id": 1, "bbox": [11.0, 322.0, 1334.0, 327.0], "category_id": 4}, {"id": 2, "bbox": [853.0, 27.0, 409.0, 211.0], "category_id": 1}, {"id": 3, "bbox": [266.0, 256.0, 86.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1054.0, 256.0, 81.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [511.0, 146.0, 280.0, 121.0], "category_id": 2}, {"id": 6, "bbox": [514.0, 8.0, 239.0, 96.0], "category_id": 2}, {"id": 7, "bbox": [85.14, 19.86, 385.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [6, 5], "products": [2]}], "corefs": [[7, 3], [2, 4]], "caption": "Table 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 798, 120, 811], "ImageBB": [73, 814, 411, 979]}, "diagram_type": "single"}, {"id": 905, "width": 1352, "height": 1312, "file_name": "acs.joc.5b01547-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [228.0, 10.0, 192.0, 180.0], "category_id": 1}, {"id": 1, "bbox": [305.0, 218.0, 31.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [967.0, 216.0, 39.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [441.0, 44.0, 350.0, 46.0], "category_id": 2}, {"id": 4, "bbox": [437.0, 111.0, 391.0, 101.8], "category_id": 2}, {"id": 5, "bbox": [869.0, 6.0, 246.0, 183.0], "category_id": 1}, {"id": 6, "bbox": [2.0, 276.0, 1350.0, 1033.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [3, 4], "products": [5]}], "corefs": [[0, 1], [5, 2]], "caption": "Table 1. Synthesis of \u03b1-Functionalized Trichloromethylcarbinols 2a-la ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 366, 299, 400], "ImageBB": [82, 407, 420, 735]}, "diagram_type": "single"}, {"id": 1223, "width": 1324, "height": 572, "file_name": "op010068e-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [502.71, 513.21, 250.36, 52.97], "category_id": 2}, {"id": 1, "bbox": [0.0, 143.04, 53.65, 47.01], "category_id": 3}, {"id": 2, "bbox": [245.06, 2.65, 332.49, 307.92], "category_id": 1}, {"id": 3, "bbox": [623.92, 98.01, 143.06, 50.32], "category_id": 2}, {"id": 4, "bbox": [199.36, 489.37, 27.82, 43.04], "category_id": 3}, {"id": 5, "bbox": [1057.74, 85.42, 219.23, 55.63], "category_id": 2}, {"id": 6, "bbox": [917.99, 305.28, 52.99, 39.07], "category_id": 3}, {"id": 7, "bbox": [260.96, 409.9, 712.67, 90.73], "category_id": 2}, {"id": 8, "bbox": [617.29, 165.55, 157.64, 48.34], "category_id": 2}, {"id": 9, "bbox": [1053.77, 488.04, 153.0, 46.36], "category_id": 3}, {"id": 10, "bbox": [400.71, 324.48, 60.27, 41.06], "category_id": 3}, {"id": 11, "bbox": [75.51, 101.32, 125.84, 56.28], "category_id": 2}, {"id": 12, "bbox": [806.06, 5.96, 215.92, 292.03], "category_id": 1}], "caption": "Scheme 8", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 172, 135, 186], "ImageBB": [77, 192, 408, 335]}, "reactions": [{"reactants": [1], "conditions": [11], "products": [2]}, {"reactants": [2], "conditions": [3, 8], "products": [12]}, {"reactants": [12], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [7, 0], "products": [9]}], "diagram_type": "multiple"}, {"id": 537, "width": 1692, "height": 1828, "file_name": "jo000081h-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [859.38, 13.3, 289.19, 130.0], "category_id": 1}, {"id": 1, "bbox": [980.0, 1724.0, 202.0, 56.8], "category_id": 2}, {"id": 2, "bbox": [306.5, 348.0, 1058.9, 141.5], "category_id": 1}, {"id": 3, "bbox": [477.5, 0.7, 166.7, 138.2], "category_id": 1}, {"id": 4, "bbox": [8.0, 1076.0, 403.0, 301.1], "category_id": 1}, {"id": 5, "bbox": [561.0, 1082.0, 401.0, 286.1], "category_id": 1}, {"id": 6, "bbox": [57.0, 1571.5, 340.0, 256.5], "category_id": 1}, {"id": 7, "bbox": [1081.0, 1076.0, 418.0, 294.0], "category_id": 1}, {"id": 8, "bbox": [509.0, 1503.0, 455.0, 325.0], "category_id": 1}, {"id": 9, "bbox": [471.0, 722.0, 142.0, 106.0], "category_id": 2}, {"id": 10, "bbox": [422.0, 1082.0, 146.0, 113.0], "category_id": 2}, {"id": 11, "bbox": [966.0, 1091.0, 133.0, 99.0], "category_id": 2}, {"id": 12, "bbox": [1398.0, 391.0, 72.0, 61.0], "category_id": 3}, {"id": 13, "bbox": [1212.24, 931.28, 265.31, 47.72], "category_id": 2}, {"id": 14, "bbox": [1211.0, 1580.9, 338.0, 247.1], "category_id": 1}, {"id": 15, "bbox": [404.0, 1605.7, 182.0, 82.3], "category_id": 2}, {"id": 16, "bbox": [1038.0, 578.0, 457.0, 426.4], "category_id": 1}, {"id": 17, "bbox": [543.0, 592.0, 432.8, 412.0], "category_id": 1}, {"id": 18, "bbox": [10.0, 603.7, 439.3, 390.4], "category_id": 1}, {"id": 19, "bbox": [1497.0, 598.0, 166.5, 140.0], "category_id": 2}, {"id": 20, "bbox": [981.2, 1528.4, 220.8, 159.6], "category_id": 2}], "reactions": [{"reactants": [16], "conditions": [19], "products": [4]}, {"reactants": [4], "conditions": [10], "products": [5]}, {"reactants": [5], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [15], "products": [8]}, {"reactants": [8], "conditions": [20, 1], "products": [14]}], "corefs": [[2, 12]], "caption": "Figure 4. Proposed terpenoid biosynthetic pathway, based upon 13C acetate labeling studies, for the production of the mangicol carbon skeleton. ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 535, 775, 562], "ImageBB": [214, 65, 637, 522]}, "diagram_type": "tree"}, {"id": 268, "width": 1356, "height": 3796, "file_name": "ol801035c-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 438.8, 1356.0, 2974.2], "category_id": 4}, {"id": 1, "bbox": [318.0, 194.0, 43.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [255.0, 304.0, 771.0, 77.0], "category_id": 2}, {"id": 3, "bbox": [411.0, 150.0, 464.0, 163.0], "category_id": 2}, {"id": 4, "bbox": [478.0, 71.0, 321.0, 50.0], "category_id": 2}, {"id": 5, "bbox": [109.0, 0.0, 280.0, 194.0], "category_id": 1}, {"id": 6, "bbox": [811.0, 0.0, 445.0, 194.0], "category_id": 1}, {"id": 7, "bbox": [2.0, 3431.0, 1354.0, 365.0], "category_id": 2}, {"id": 8, "bbox": [995.0, 191.0, 110.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 3], "products": [6]}], "corefs": [[5, 1], [6, 8]], "caption": "Table 2. Direct regioselective C-2 arylation of 2", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 677, 88], "ImageBB": [424, 97, 763, 1046]}, "diagram_type": "single"}, {"id": 684, "width": 1344, "height": 2048, "file_name": "ol4013926-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 1227.0, 1336.0, 821.0], "category_id": 4}, {"id": 1, "bbox": [205.0, 834.0, 98.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [668.0, 829.0, 105.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [1076.0, 831.0, 122.0, 48.0], "category_id": 3}, {"id": 4, "bbox": [630.0, 236.0, 238.0, 141.0], "category_id": 2}, {"id": 5, "bbox": [1052.0, 317.0, 78.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [342.9, 148.1, 263.7, 293.3], "category_id": 1}, {"id": 7, "bbox": [460.2, 459.4, 422.8, 363.32], "category_id": 1}, {"id": 8, "bbox": [29.8, 461.0, 428.8, 355.3], "category_id": 1}, {"id": 9, "bbox": [883.6, 458.7, 433.4, 371.3], "category_id": 1}, {"id": 10, "bbox": [662.0, 93.4, 189.2, 108.7], "category_id": 2}, {"id": 11, "bbox": [891.0, 92.0, 421.2, 242.0], "category_id": 1}, {"id": 12, "bbox": [509.0, 889.0, 494.0, 333.0], "category_id": 3}, {"id": 13, "bbox": [18.0, 885.0, 487.0, 294.0], "category_id": 3}, {"id": 14, "bbox": [1001.0, 885.0, 249.0, 101.0], "category_id": 3}, {"id": 15, "bbox": [60.4, 1.2, 430.6, 234.8], "category_id": 1}], "reactions": [{"reactants": [15, 6], "conditions": [10, 4], "products": [11]}], "corefs": [[11, 5], [8, 1], [8, 13], [7, 2], [7, 12], [9, 3], [9, 14]], "caption": "Table 1. Effect of Catalystsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 221, 101], "ImageBB": [71, 112, 407, 624]}, "diagram_type": "single"}, {"id": 7, "width": 1356, "height": 500, "file_name": "jacs.5b05415-Figure-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [797.21, 451.89, 142.27, 39.23], "category_id": 3}, {"id": 1, "bbox": [315.77, 372.22, 326.71, 89.46], "category_id": 2}, {"id": 2, "bbox": [360.79, 267.45, 239.26, 85.13], "category_id": 2}, {"id": 3, "bbox": [368.59, 148.82, 221.94, 46.16], "category_id": 2}, {"id": 4, "bbox": [360.79, 44.91, 239.26, 85.13], "category_id": 2}, {"id": 5, "bbox": [715.81, 274.38, 299.01, 167.38], "category_id": 1}, {"id": 6, "bbox": [18.76, 293.43, 239.24, 128.42], "category_id": 1}, {"id": 7, "bbox": [724.47, 55.3, 299.01, 170.86], "category_id": 1}, {"id": 8, "bbox": [17.03, 57.9, 238.39, 166.52], "category_id": 1}, {"id": 9, "bbox": [1036.2, 119.38, 304.19, 79.07], "category_id": 3}, {"id": 10, "bbox": [1089.88, 276.11, 229.73, 165.65], "category_id": 1}, {"id": 11, "bbox": [1123.65, 451.89, 159.6, 39.23], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [4, 3], "products": [7]}, {"reactants": [6], "conditions": [2, 1], "products": [5, 10]}], "corefs": [[7, 9], [5, 0], [10, 11]], "caption": "Figure 6. Achieving cyclization via synergistic catalysis.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 356, 711, 370], "ImageBB": [448, 222, 787, 347]}, "diagram_type": "multiple"}, {"id": 90, "width": 1348, "height": 1920, "file_name": "ja053650h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [490.55, 84.21, 311.53, 46.22], "category_id": 2}, {"id": 1, "bbox": [951.35, 63.27, 339.46, 218.43], "category_id": 1}, {"id": 2, "bbox": [57.68, 7.41, 316.18, 220.76], "category_id": 1}, {"id": 3, "bbox": [474.26, 158.68, 358.07, 46.22], "category_id": 2}, {"id": 4, "bbox": [6.5, 300.65, 1340.16, 1617.12], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [0, 3], "products": [1]}], "corefs": [], "caption": "Table 2. Intramolecular Carbonylation of 2-(2-Iodophenoxy)aniline (3, R1 ) R2 ) H, X ) I) with Different Palladium-Complexed Dendrimersa ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 772, 100], "ImageBB": [439, 102, 776, 582]}, "diagram_type": "single"}, {"id": 567, "width": 1352, "height": 1368, "file_name": "acs.orglett.5b01077-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1012.0, 237.0, 87.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [220.0, 237.0, 49.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [607.0, 127.0, 291.0, 48.0], "category_id": 2}, {"id": 3, "bbox": [390.0, 21.0, 182.0, 206.0], "category_id": 1}, {"id": 4, "bbox": [868.0, 0.0, 410.0, 249.0], "category_id": 1}, {"id": 5, "bbox": [608.0, 2.0, 366.0, 106.0], "category_id": 2}, {"id": 6, "bbox": [456.0, 229.0, 95.0, 52.0], "category_id": 3}, {"id": 7, "bbox": [76.0, 16.0, 250.0, 197.0], "category_id": 1}, {"id": 8, "bbox": [26.0, 302.0, 1307.0, 1066.0], "category_id": 4}], "reactions": [{"reactants": [7, 3], "conditions": [5, 2], "products": [4]}], "corefs": [[7, 1], [3, 6], [4, 0]], "caption": "Table 2. Nitrone Scopea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 586, 111], "ImageBB": [448, 116, 786, 458]}, "diagram_type": "single"}, {"id": 1154, "width": 1352, "height": 1048, "file_name": "ol051365x-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [913.06, 762.43, 384.83, 186.05], "category_id": 1}, {"id": 1, "bbox": [449.09, 431.62, 77.78, 43.29], "category_id": 2}, {"id": 2, "bbox": [1080.11, 946.45, 50.05, 46.0], "category_id": 3}, {"id": 3, "bbox": [871.8, 516.86, 103.48, 51.41], "category_id": 2}, {"id": 4, "bbox": [703.39, 211.75, 137.97, 168.45], "category_id": 1}, {"id": 5, "bbox": [664.16, 261.81, 48.02, 35.86], "category_id": 2}, {"id": 6, "bbox": [49.37, 8.79, 236.72, 181.31], "category_id": 1}, {"id": 7, "bbox": [526.19, 396.44, 336.14, 184.69], "category_id": 1}, {"id": 8, "bbox": [913.06, 4.06, 393.63, 184.69], "category_id": 1}, {"id": 9, "bbox": [858.95, 408.62, 124.45, 54.12], "category_id": 2}, {"id": 10, "bbox": [158.26, 816.56, 118.36, 64.26], "category_id": 2}, {"id": 11, "bbox": [242.81, 663.66, 137.97, 107.57], "category_id": 2}, {"id": 12, "bbox": [669.57, 31.12, 202.91, 51.41], "category_id": 2}, {"id": 13, "bbox": [1092.29, 581.13, 40.58, 48.03], "category_id": 3}, {"id": 14, "bbox": [503.2, 186.72, 51.4, 47.35], "category_id": 3}, {"id": 15, "bbox": [444.35, 512.12, 102.13, 47.36], "category_id": 2}, {"id": 16, "bbox": [1097.02, 654.19, 102.8, 95.39], "category_id": 2}, {"id": 17, "bbox": [974.6, 391.7, 331.41, 189.43], "category_id": 1}, {"id": 18, "bbox": [664.16, 104.86, 232.66, 94.04], "category_id": 2}, {"id": 19, "bbox": [1092.29, 232.05, 200.19, 140.55], "category_id": 2}, {"id": 20, "bbox": [150.15, 190.78, 37.2, 44.65], "category_id": 3}, {"id": 21, "bbox": [208.99, 593.98, 49.37, 45.33], "category_id": 3}, {"id": 22, "bbox": [329.38, 8.79, 324.64, 181.31], "category_id": 1}, {"id": 23, "bbox": [1085.52, 187.4, 35.85, 46.67], "category_id": 3}, {"id": 24, "bbox": [54.78, 403.88, 387.55, 190.1], "category_id": 1}, {"id": 25, "bbox": [630.35, 585.19, 42.61, 43.97], "category_id": 3}], "caption": "Scheme 1. Synthesis of Twisted \u03c0-System Molecule TM-1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [85, 546, 398, 559], "ImageBB": [73, 563, 411, 825]}, "reactions": [{"reactants": [6, 22], "conditions": [12, 18], "products": [8]}, {"reactants": [8], "conditions": [19], "products": [17]}, {"reactants": [17], "conditions": [9, 3], "products": [7]}, {"reactants": [7], "conditions": [1, 15], "products": [24]}, {"reactants": [24], "conditions": [11], "products": [10]}, {"reactants": [17], "conditions": [16], "products": [0]}], "diagram_type": "tree"}, {"id": 1339, "width": 1704, "height": 1192, "file_name": "op5003165-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [302.61, 11.09, 242.94, 301.91], "category_id": 1}, {"id": 1, "bbox": [1136.28, 540.71, 492.71, 303.62], "category_id": 1}, {"id": 2, "bbox": [1310.18, 875.03, 57.96, 46.91], "category_id": 3}, {"id": 3, "bbox": [901.01, 356.5, 37.51, 39.23], "category_id": 3}, {"id": 4, "bbox": [302.61, 534.74, 485.88, 301.92], "category_id": 1}, {"id": 5, "bbox": [826.0, 28.14, 244.65, 303.62], "category_id": 1}, {"id": 6, "bbox": [900.16, 683.14, 130.42, 45.2], "category_id": 2}, {"id": 7, "bbox": [612.89, 100.64, 137.25, 51.17], "category_id": 2}, {"id": 8, "bbox": [916.36, 619.18, 99.73, 42.64], "category_id": 2}, {"id": 9, "bbox": [1349.39, 448.6, 203.73, 79.32], "category_id": 2}, {"id": 10, "bbox": [479.92, 875.89, 50.29, 44.35], "category_id": 3}, {"id": 11, "bbox": [1310.18, 348.82, 53.7, 46.91], "category_id": 3}, {"id": 12, "bbox": [1184.02, 7.68, 343.53, 232.83], "category_id": 1}, {"id": 13, "bbox": [364.84, 353.08, 38.36, 40.09], "category_id": 3}, {"id": 14, "bbox": [609.48, 173.13, 152.59, 75.91], "category_id": 2}], "caption": "Scheme 5. Formation of core 10", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 797, 266, 812], "ImageBB": [10, 829, 436, 1127]}, "reactions": [{"reactants": [0], "conditions": [7, 14], "products": [5]}, {"reactants": [5, 12], "conditions": [9], "products": [1]}, {"reactants": [1], "conditions": [8, 6], "products": [4]}], "diagram_type": "tree"}, {"id": 104, "width": 1348, "height": 1320, "file_name": "ja011003u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [217.17, 362.46, 182.55, 46.28], "category_id": 3}, {"id": 1, "bbox": [266.57, 1263.46, 56.5, 47.99], "category_id": 3}, {"id": 2, "bbox": [1000.66, 898.97, 56.5, 47.99], "category_id": 3}, {"id": 3, "bbox": [6.33, 7.47, 577.72, 293.65], "category_id": 1}, {"id": 4, "bbox": [761.97, 505.54, 575.83, 363.73], "category_id": 1}, {"id": 5, "bbox": [57.46, 825.6, 539.85, 388.34], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [5]}], "corefs": [[3, 0], [4, 2], [5, 1]], "caption": "Table 2. Experimental and Calculated (DFT) 13C NMR Spectra", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 466, 756, 480], "ImageBB": [440, 125, 777, 455]}, "diagram_type": "tree"}, {"id": 1246, "width": 2192, "height": 1352, "file_name": "op034033l-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [915.62, 204.0, 207.25, 57.04], "category_id": 2}, {"id": 1, "bbox": [0.0, 769.94, 357.47, 137.1], "category_id": 1}, {"id": 2, "bbox": [731.4, 201.81, 126.1, 63.61], "category_id": 2}, {"id": 3, "bbox": [733.59, 103.1, 127.2, 64.71], "category_id": 2}, {"id": 4, "bbox": [1248.97, 489.17, 356.38, 137.1], "category_id": 1}, {"id": 5, "bbox": [537.31, 773.23, 175.45, 140.39], "category_id": 1}, {"id": 6, "bbox": [1463.89, 717.3, 327.87, 185.36], "category_id": 1}, {"id": 7, "bbox": [915.62, 105.29, 276.33, 62.52], "category_id": 2}, {"id": 8, "bbox": [731.4, 347.68, 51.54, 58.13], "category_id": 2}, {"id": 9, "bbox": [803.77, 303.81, 168.87, 136.0], "category_id": 1}, {"id": 10, "bbox": [648.06, 545.1, 166.68, 64.71], "category_id": 2}, {"id": 11, "bbox": [1699.65, 527.55, 175.45, 70.2], "category_id": 2}, {"id": 12, "bbox": [237.95, 99.81, 131.59, 58.13], "category_id": 2}, {"id": 13, "bbox": [26.32, 202.91, 235.76, 64.71], "category_id": 2}, {"id": 14, "bbox": [16.45, 508.91, 346.51, 197.42], "category_id": 1}, {"id": 15, "bbox": [26.32, 99.81, 172.16, 58.13], "category_id": 2}, {"id": 16, "bbox": [9.9, 316.97, 342.09, 133.81], "category_id": 1}, {"id": 17, "bbox": [0.0, 976.14, 561.3, 68.06], "category_id": 2}, {"id": 18, "bbox": [19.8, 1258.6, 108.3, 45.5], "category_id": 2}, {"id": 19, "bbox": [813.7, 822.1, 158.3, 51.5], "category_id": 2}, {"id": 20, "bbox": [1415.1, 1102.9, 264.44, 40.22], "category_id": 2}, {"id": 21, "bbox": [453.97, 554.97, 97.59, 58.13], "category_id": 2}, {"id": 22, "bbox": [1977.08, 522.07, 62.82, 60.33], "category_id": 2}, {"id": 23, "bbox": [1421.7, 1243.8, 267.1, 44.1], "category_id": 2}, {"id": 24, "bbox": [1898.3, 796.27, 126.7, 59.23], "category_id": 2}, {"id": 25, "bbox": [26.4, 2.43, 512.45, 56.2], "category_id": 2}, {"id": 26, "bbox": [1780.33, 1286.88, 128.94, 47.94], "category_id": 2}, {"id": 27, "bbox": [1598.49, 1286.88, 115.71, 51.24], "category_id": 2}, {"id": 28, "bbox": [1464.59, 1286.88, 87.61, 49.59], "category_id": 2}, {"id": 29, "bbox": [1915.88, 1243.9, 186.8, 49.59], "category_id": 2}, {"id": 30, "bbox": [1734.04, 1243.9, 132.25, 44.63], "category_id": 2}, {"id": 31, "bbox": [1777.02, 1144.71, 128.94, 46.29], "category_id": 2}, {"id": 32, "bbox": [1593.53, 1144.71, 114.06, 51.25], "category_id": 2}, {"id": 33, "bbox": [1462.93, 1144.71, 85.96, 51.25], "category_id": 2}, {"id": 34, "bbox": [1986.96, 1103.39, 191.74, 46.31], "category_id": 2}, {"id": 35, "bbox": [1730.73, 1101.73, 206.64, 47.94], "category_id": 2}, {"id": 36, "bbox": [269.4, 1306.72, 148.78, 44.63], "category_id": 2}, {"id": 37, "bbox": [72.68, 1305.06, 150.43, 46.29], "category_id": 2}, {"id": 38, "bbox": [537.2, 1257.12, 284.33, 54.56], "category_id": 2}, {"id": 39, "bbox": [366.93, 1257.12, 110.76, 52.9], "category_id": 2}, {"id": 40, "bbox": [161.95, 1258.78, 157.04, 51.24], "category_id": 2}, {"id": 41, "bbox": [269.4, 1138.1, 148.78, 44.63], "category_id": 2}, {"id": 42, "bbox": [72.68, 1136.45, 150.43, 46.28], "category_id": 2}, {"id": 43, "bbox": [623.16, 1088.51, 287.64, 54.55], "category_id": 2}, {"id": 44, "bbox": [363.63, 1088.51, 203.33, 54.55], "category_id": 2}, {"id": 45, "bbox": [160.3, 1088.51, 157.04, 51.24], "category_id": 2}, {"id": 46, "bbox": [13.17, 1088.51, 114.06, 51.24], "category_id": 2}, {"id": 47, "bbox": [2071.27, 804.18, 117.37, 52.9], "category_id": 2}, {"id": 48, "bbox": [2091.11, 523.15, 85.96, 57.86], "category_id": 2}], "caption": "Scheme 2. Relevant Equations for the One-Pot Synthesis of Oxazolidinone 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 228, 501, 242], "ImageBB": [151, 246, 699, 584]}, "reactions": [{"reactants": [15, 12], "conditions": [], "products": [3, 7]}, {"reactants": [13], "conditions": [], "products": [2, 0]}, {"reactants": [16], "conditions": [], "products": [9]}, {"reactants": [14, 21, 10], "conditions": [], "products": [4, 11, 22, 48]}, {"reactants": [1, 5, 19], "conditions": [], "products": [6, 24, 47]}, {"reactants": [46, 45, 44, 43, 42, 41], "conditions": [], "products": [20, 35, 34, 33, 32, 31]}, {"reactants": [18, 40, 39, 38, 37, 36], "conditions": [], "products": [23, 30, 29, 28, 27, 26]}], "diagram_type": "multiple"}, {"id": 1218, "width": 1352, "height": 812, "file_name": "ol901760a-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [690.54, 0.0, 154.21, 249.44], "category_id": 1}, {"id": 1, "bbox": [848.8, 688.16, 35.85, 42.59], "category_id": 3}, {"id": 2, "bbox": [259.04, 334.62, 204.93, 79.09], "category_id": 2}, {"id": 3, "bbox": [572.86, 672.61, 235.36, 78.42], "category_id": 3}, {"id": 4, "bbox": [436.91, 37.18, 190.73, 80.44], "category_id": 2}, {"id": 5, "bbox": [777.11, 283.24, 180.79, 56.86], "category_id": 1}, {"id": 6, "bbox": [1023.3, 0.0, 135.27, 259.58], "category_id": 1}, {"id": 7, "bbox": [184.64, 0.0, 204.93, 250.12], "category_id": 1}, {"id": 8, "bbox": [748.71, 225.78, 83.86, 40.56], "category_id": 3}, {"id": 9, "bbox": [604.65, 404.92, 135.94, 256.2], "category_id": 1}, {"id": 10, "bbox": [896.82, 73.68, 109.57, 43.27], "category_id": 2}, {"id": 11, "bbox": [436.91, 137.23, 199.52, 48.67], "category_id": 2}, {"id": 12, "bbox": [827.84, 402.21, 198.84, 300.14], "category_id": 1}, {"id": 13, "bbox": [896.82, 135.87, 100.1, 39.89], "category_id": 2}, {"id": 14, "bbox": [239.42, 249.44, 144.06, 48.0], "category_id": 3}, {"id": 15, "bbox": [778.47, 346.11, 211.69, 40.56], "category_id": 2}, {"id": 16, "bbox": [1070.64, 263.64, 93.34, 42.58], "category_id": 3}], "caption": "Scheme 4. Base-Free Cyclization of Enynylpyridine Z-1b and        Intermediate Carbene-Trapping Experiments ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [66, 653, 386, 681], "ImageBB": [58, 689, 396, 892]}, "reactions": [{"reactants": [7], "conditions": [2], "products": [9, 12]}, {"reactants": [7], "conditions": [4, 11], "products": [0]}, {"reactants": [0], "conditions": [10, 13], "products": [6]}, {"reactants": [0, 5], "conditions": [15], "products": [9, 12]}], "diagram_type": "graph"}, {"id": 1035, "width": 1132, "height": 728, "file_name": "jo001614p-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 266.8, 399.8, 57.21], "category_id": 2}, {"id": 1, "bbox": [181.21, 671.82, 44.74, 52.68], "category_id": 3}, {"id": 2, "bbox": [104.2, 457.7, 229.91, 199.96], "category_id": 1}, {"id": 3, "bbox": [555.52, 64.58, 48.7, 53.24], "category_id": 2}, {"id": 4, "bbox": [855.09, 451.47, 195.37, 229.98], "category_id": 1}, {"id": 5, "bbox": [795.82, 270.92, 331.23, 44.58], "category_id": 2}, {"id": 6, "bbox": [536.27, 5.1, 115.52, 47.01], "category_id": 1}, {"id": 7, "bbox": [769.58, 10.76, 161.92, 63.14], "category_id": 1}, {"id": 8, "bbox": [361.29, 594.78, 439.43, 66.84], "category_id": 2}, {"id": 9, "bbox": [416.78, 457.7, 327.88, 51.55], "category_id": 2}, {"id": 10, "bbox": [945.69, 672.95, 40.21, 47.58], "category_id": 3}, {"id": 11, "bbox": [813.18, 98.56, 140.44, 58.35], "category_id": 2}, {"id": 12, "bbox": [190.84, 45.88, 182.34, 143.32], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [101, 83, 384, 265]}, "reactions": [{"reactants": [2], "conditions": [8], "products": [4]}, {"reactants": [4], "conditions": [9], "products": [2]}, {"reactants": [2], "conditions": [0], "products": [12, 6]}, {"reactants": [6, 7, 11], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [], "products": [6]}], "diagram_type": "graph"}, {"id": 541, "width": 1348, "height": 392, "file_name": "acs.orglett.6b00233-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [210.9, 248.0, 50.1, 45.0], "category_id": 3}, {"id": 1, "bbox": [443.0, 9.9, 210.0, 94.1], "category_id": 2}, {"id": 2, "bbox": [739.9, 39.9, 128.1, 51.1], "category_id": 2}, {"id": 3, "bbox": [965.0, 10.0, 373.0, 212.8], "category_id": 1}, {"id": 4, "bbox": [6.0, 313.0, 1342.0, 78.0], "category_id": 4}, {"id": 5, "bbox": [725.0, 140.0, 227.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [14.0, 4.0, 370.0, 227.0], "category_id": 1}, {"id": 7, "bbox": [1181.0, 254.0, 27.0, 38.0], "category_id": 3}, {"id": 8, "bbox": [459.0, 143.0, 124.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [1, 8, 2, 5], "products": [3]}], "corefs": [[6, 0], [3, 7]], "caption": "Table 3. Reaction with Carbon Nucleophilesa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 548, 336, 569], "ImageBB": [82, 575, 419, 673]}, "diagram_type": "single"}, {"id": 417, "width": 1352, "height": 800, "file_name": "op400055z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 471.0, 1342.0, 328.0], "category_id": 4}, {"id": 1, "bbox": [2.0, 0.0, 326.0, 227.0], "category_id": 1}, {"id": 2, "bbox": [609.0, 36.0, 82.0, 73.0], "category_id": 2}, {"id": 3, "bbox": [388.0, 118.0, 538.0, 337.0], "category_id": 1}, {"id": 4, "bbox": [901.0, 388.0, 40.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [1164.0, 235.0, 108.0, 62.0], "category_id": 3}, {"id": 6, "bbox": [81.0, 227.0, 115.0, 51.0], "category_id": 3}, {"id": 7, "bbox": [1026.0, 1.0, 323.0, 227.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2, 3], "products": [7]}], "corefs": [[1, 6], [3, 4], [7, 5]], "caption": "Table 1. Asymmetric hydrogenation of enamides using 9 as catalysta ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 404, 417, 434], "ImageBB": [82, 440, 420, 640]}, "diagram_type": "single"}, {"id": 703, "width": 1352, "height": 1676, "file_name": "ol035681s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [359.87, 148.49, 60.81, 63.24], "category_id": 2}, {"id": 1, "bbox": [654.0, 251.0, 295.0, 76.0], "category_id": 2}, {"id": 2, "bbox": [31.0, 340.0, 1276.0, 1336.0], "category_id": 4}, {"id": 3, "bbox": [934.0, 36.0, 416.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [359.1, 0.0, 522.9, 116.4], "category_id": 2}, {"id": 5, "bbox": [413.0, 150.0, 248.0, 171.0], "category_id": 1}, {"id": 6, "bbox": [3.0, 38.2, 331.0, 172.8], "category_id": 1}, {"id": 7, "bbox": [145.75, 226.86, 44.94, 56.16], "category_id": 3}, {"id": 8, "bbox": [1078.11, 229.1, 42.69, 56.17], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [4, 0, 5, 1], "products": [3]}], "corefs": [[6, 7], [3, 8]], "caption": "Table 3. Cu(II)-Catalyzed N-Arylation of 1,4-Dioxa-8-azaspiro[4.5]decanea ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 296, 104], "ImageBB": [74, 109, 412, 528]}, "diagram_type": "single"}, {"id": 432, "width": 3396, "height": 1160, "file_name": "op300101d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1671.0, 54.0, 51.0, 35.0], "category_id": 2}, {"id": 1, "bbox": [1447.0, 238.0, 29.0, 35.0], "category_id": 3}, {"id": 2, "bbox": [1930.0, 239.0, 24.0, 32.0], "category_id": 3}, {"id": 3, "bbox": [300.0, 306.0, 2809.0, 612.0], "category_id": 4}, {"id": 4, "bbox": [1390.0, 9.0, 138.0, 186.0], "category_id": 1}, {"id": 5, "bbox": [1884.0, 18.0, 114.0, 190.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [5]}], "corefs": [[4, 1], [5, 2]], "caption": "Table 2. Familiarization runs using cyclohexanone oxime 4 as model substratea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 810, 530, 831], "ImageBB": [10, 837, 859, 1127]}, "diagram_type": "single"}, {"id": 578, "width": 1348, "height": 332, "file_name": "acs.orglett.5b00663-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [837.0, 4.0, 316.0, 152.0], "category_id": 1}, {"id": 1, "bbox": [297.0, 151.0, 48.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [960.0, 149.0, 40.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [6.0, 210.0, 1334.0, 122.0], "category_id": 2}, {"id": 4, "bbox": [540.0, 22.0, 252.0, 75.0], "category_id": 2}, {"id": 5, "bbox": [586.0, 110.0, 164.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [199.0, 54.0, 281.0, 103.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 5], "products": [0]}], "corefs": [[6, 1], [0, 2]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 366, 109], "ImageBB": [82, 116, 419, 199]}, "diagram_type": "single"}, {"id": 558, "width": 1348, "height": 352, "file_name": "acs.orglett.5b02003-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [490.92, 201.03, 41.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [128.0, 199.0, 61.0, 49.9], "category_id": 3}, {"id": 2, "bbox": [1148.92, 209.97, 41.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [987.0, 1.0, 342.9, 237.0], "category_id": 1}, {"id": 4, "bbox": [644.3, 67.0, 332.3, 46.1], "category_id": 2}, {"id": 5, "bbox": [20.2, 24.1, 321.7, 184.8], "category_id": 1}, {"id": 6, "bbox": [366.0, 39.0, 273.0, 156.0], "category_id": 1}, {"id": 7, "bbox": [745.17, 126.68, 86.41, 42.69], "category_id": 2}, {"id": 8, "bbox": [8.0, 279.0, 1333.0, 73.0], "category_id": 4}], "reactions": [{"reactants": [5, 6], "conditions": [4, 7], "products": [3]}], "corefs": [[5, 1], [6, 0], [3, 2]], "caption": "Table 2. Scope of Cyclopropane 1,1-Diestersa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 709, 110], "ImageBB": [449, 116, 786, 204]}, "diagram_type": "single"}, {"id": 1343, "width": 2136, "height": 804, "file_name": "op700026n-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 4.27, 343.0, 313.99], "category_id": 1}, {"id": 1, "bbox": [1185.0, 39.52, 313.09, 107.86], "category_id": 2}, {"id": 2, "bbox": [767.21, 4.27, 351.55, 311.86], "category_id": 1}, {"id": 3, "bbox": [712.71, 751.87, 47.02, 50.2], "category_id": 3}, {"id": 4, "bbox": [465.88, 176.22, 101.51, 49.13], "category_id": 2}, {"id": 5, "bbox": [373.99, 0.0, 319.49, 148.45], "category_id": 2}, {"id": 6, "bbox": [1586.77, 4.27, 353.69, 313.99], "category_id": 1}, {"id": 7, "bbox": [1401.92, 466.71, 734.08, 315.06], "category_id": 1}, {"id": 8, "bbox": [922.15, 402.63, 445.57, 221.08], "category_id": 1}, {"id": 9, "bbox": [1073.88, 578.85, 42.74, 45.93], "category_id": 3}, {"id": 10, "bbox": [1307.89, 189.04, 99.37, 48.06], "category_id": 2}, {"id": 11, "bbox": [424.21, 466.71, 477.63, 315.06], "category_id": 1}, {"id": 12, "bbox": [45.95, 524.39, 292.78, 100.39], "category_id": 2}, {"id": 13, "bbox": [260.72, 242.44, 48.09, 51.26], "category_id": 3}, {"id": 14, "bbox": [1766.29, 726.24, 231.87, 55.53], "category_id": 3}, {"id": 15, "bbox": [141.05, 657.89, 102.58, 56.6], "category_id": 2}, {"id": 16, "bbox": [1807.96, 243.5, 56.63, 51.27], "category_id": 3}, {"id": 17, "bbox": [1027.93, 244.57, 47.02, 48.06], "category_id": 3}, {"id": 18, "bbox": [1002.29, 653.61, 267.13, 114.28], "category_id": 2}], "caption": "Scheme 5. Synthesis of amide 1 (MK-0364, taranabant) from bromo alcohol 5", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 510, 67], "ImageBB": [158, 71, 692, 272]}, "reactions": [{"reactants": [0], "conditions": [5, 4], "products": [2]}, {"reactants": [2], "conditions": [1, 10], "products": [6]}, {"reactants": [6], "conditions": [12, 15], "products": [11]}, {"reactants": [11, 8], "conditions": [18], "products": [7]}], "diagram_type": "multiple"}, {"id": 220, "width": 1348, "height": 1044, "file_name": "op0256183-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.0, 253.8, 1345.0, 790.2], "category_id": 4}, {"id": 1, "bbox": [476.0, 123.0, 349.0, 102.0], "category_id": 2}, {"id": 2, "bbox": [42.0, 16.0, 372.0, 125.0], "category_id": 1}, {"id": 3, "bbox": [508.0, 26.0, 271.0, 46.0], "category_id": 2}, {"id": 4, "bbox": [942.0, 12.0, 378.0, 136.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [3, 1], "products": [4]}], "corefs": [], "caption": "Table 1. Effect of reduced precatalyst loadings", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 444, 698, 458], "ImageBB": [439, 462, 776, 723]}, "diagram_type": "single"}, {"id": 237, "width": 1344, "height": 948, "file_name": "op000061h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [62.8, 209.2, 43.6, 50.8], "category_id": 3}, {"id": 1, "bbox": [206.54, 162.44, 164.92, 64.74], "category_id": 2}, {"id": 2, "bbox": [17.1, 43.0, 177.0, 158.0], "category_id": 1}, {"id": 3, "bbox": [850.55, 204.0, 55.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [258.5, 88.5, 76.6, 62.5], "category_id": 1}, {"id": 5, "bbox": [1079.9, 30.8, 250.5, 167.5], "category_id": 1}, {"id": 6, "bbox": [401.0, 2.0, 381.0, 106.7], "category_id": 2}, {"id": 7, "bbox": [807.7, 26.3, 282.0, 173.8], "category_id": 1}, {"id": 8, "bbox": [1115.0, 202.93, 53.8, 56.4], "category_id": 3}, {"id": 9, "bbox": [18.0, 300.0, 1326.0, 648.0], "category_id": 4}, {"id": 10, "bbox": [450.0, 131.0, 274.0, 119.3], "category_id": 2}], "reactions": [{"reactants": [2, 4], "conditions": [6, 10], "products": [7, 5]}], "corefs": [[2, 0], [7, 3], [5, 8]], "caption": "Table 1. Effect of transition metal salt on aerobic oxidation of 3-methylpyridine (1) by NHPIa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 401, 81], "ImageBB": [74, 88, 410, 326]}, "diagram_type": "single"}, {"id": 1333, "width": 2820, "height": 1732, "file_name": "op400269b-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [538.89, 905.35, 210.19, 53.59], "category_id": 2}, {"id": 1, "bbox": [223.0, 587.3, 775.0, 285.62], "category_id": 1}, {"id": 2, "bbox": [853.48, 208.71, 36.68, 46.54], "category_id": 3}, {"id": 3, "bbox": [538.89, 1633.01, 225.71, 55.0], "category_id": 2}, {"id": 4, "bbox": [234.18, 73.33, 125.55, 200.25], "category_id": 1}, {"id": 5, "bbox": [444.37, 104.35, 167.88, 45.13], "category_id": 2}, {"id": 6, "bbox": [478.23, 196.02, 86.05, 47.94], "category_id": 2}, {"id": 7, "bbox": [1082.01, 104.35, 170.7, 47.95], "category_id": 2}, {"id": 8, "bbox": [2460.27, 33.84, 135.43, 279.22], "category_id": 1}, {"id": 9, "bbox": [386.53, 1084.45, 210.2, 49.35], "category_id": 2}, {"id": 10, "bbox": [2202.11, 98.71, 218.66, 50.77], "category_id": 2}, {"id": 11, "bbox": [1702.72, 906.76, 38.09, 42.31], "category_id": 3}, {"id": 12, "bbox": [1015.71, 624.72, 214.43, 53.59], "category_id": 2}, {"id": 13, "bbox": [538.89, 445.62, 31.03, 52.18], "category_id": 3}, {"id": 14, "bbox": [234.18, 1248.03, 766.01, 351.14], "category_id": 1}, {"id": 15, "bbox": [1900.22, 369.47, 153.77, 47.95], "category_id": 2}, {"id": 16, "bbox": [2025.77, 249.61, 110.04, 47.94], "category_id": 2}, {"id": 17, "bbox": [1251.3, 38.08, 433.08, 267.93], "category_id": 1}, {"id": 18, "bbox": [665.85, 29.61, 355.5, 280.63], "category_id": 1}, {"id": 19, "bbox": [1034.05, 1393.28, 220.07, 128.33], "category_id": 1}, {"id": 20, "bbox": [1571.53, 396.27, 143.89, 46.53], "category_id": 2}, {"id": 21, "bbox": [1118.69, 194.61, 84.64, 43.71], "category_id": 2}, {"id": 22, "bbox": [658.8, 1083.04, 87.46, 46.53], "category_id": 2}, {"id": 23, "bbox": [1815.58, 0.0, 325.87, 342.68], "category_id": 1}, {"id": 24, "bbox": [444.37, 291.91, 148.13, 43.72], "category_id": 2}, {"id": 25, "bbox": [1333.12, 585.23, 780.12, 287.69], "category_id": 1}, {"id": 26, "bbox": [1082.01, 730.48, 86.05, 49.36], "category_id": 2}, {"id": 27, "bbox": [2269.82, 194.61, 84.65, 49.35], "category_id": 2}, {"id": 28, "bbox": [537.3, 437.53, 238.82, 180.79], "category_id": 1}, {"id": 29, "bbox": [988.16, 1428.52, 35.71, 51.34], "category_id": 3}, {"id": 30, "bbox": [1437.51, 208.71, 39.5, 46.54], "category_id": 3}], "caption": "Scheme 8. Overall synthesis of 1\u00b7bis maleate salt (17% overall yield) from cyclohexenone", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 585, 110], "ImageBB": [82, 116, 787, 549]}, "reactions": [{"reactants": [4], "conditions": [5, 6], "products": [18]}, {"reactants": [18], "conditions": [7, 21], "products": [17]}, {"reactants": [8], "conditions": [10, 27], "products": [23]}, {"reactants": [17, 23], "conditions": [20], "products": [25]}, {"reactants": [25], "conditions": [12, 26], "products": [1]}, {"reactants": [1, 28], "conditions": [9, 22], "products": [14, 19]}], "diagram_type": "tree"}, {"id": 276, "width": 1352, "height": 1620, "file_name": "ol8006106-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 420.0, 1352.0, 1200.0], "category_id": 4}, {"id": 1, "bbox": [55.4, 61.0, 124.6, 56.5], "category_id": 2}, {"id": 2, "bbox": [832.0, 8.4, 513.7, 354.6], "category_id": 1}, {"id": 3, "bbox": [194.3, 0.0, 503.0, 357.9], "category_id": 1}, {"id": 4, "bbox": [0.0, 114.0, 49.0, 61.0], "category_id": 3}, {"id": 5, "bbox": [711.91, 57.0, 110.0, 65.0], "category_id": 2}, {"id": 6, "bbox": [457.0, 306.0, 98.0, 52.6], "category_id": 3}, {"id": 7, "bbox": [1101.0, 310.0, 98.0, 50.6], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1], "products": [3]}, {"reactants": [3], "conditions": [5], "products": [2]}], "corefs": [[3, 6], [2, 7]], "caption": "Table 1. Synthesis of N2-Modified 2\u2032-Deoxyguanosine Analogues from 3 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 74, 339, 102], "ImageBB": [58, 111, 396, 516]}, "diagram_type": "single"}, {"id": 213, "width": 1352, "height": 1128, "file_name": "op034064g-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [136.0, 608.0, 102.0, 66.0], "category_id": 2}, {"id": 1, "bbox": [981.0, 631.1, 63.0, 57.3], "category_id": 2}, {"id": 2, "bbox": [0.0, 817.1, 1339.0, 310.9], "category_id": 4}, {"id": 3, "bbox": [668.0, 473.1, 233.5, 296.4], "category_id": 1}, {"id": 4, "bbox": [252.0, 580.6, 100.9, 51.8], "category_id": 2}, {"id": 5, "bbox": [949.0, 553.0, 103.0, 58.4], "category_id": 2}, {"id": 6, "bbox": [404.0, 651.1, 234.0, 51.3], "category_id": 2}, {"id": 7, "bbox": [0.0, 4.0, 1343.0, 336.0], "category_id": 4}, {"id": 8, "bbox": [354.0, 472.0, 293.0, 154.0], "category_id": 1}, {"id": 9, "bbox": [1143.17, 595.8, 77.11, 42.34], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [4, 8, 6], "products": [3]}, {"reactants": [3], "conditions": [5, 1], "products": [9]}], "corefs": [], "caption": "Table 5. Coupling temperature effect on selectivity", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 354, 67], "ImageBB": [74, 70, 412, 352]}, "diagram_type": "single"}, {"id": 614, "width": 1352, "height": 364, "file_name": "acs.oprd.5b00303-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [701.0, 213.0, 151.0, 59.0], "category_id": 2}, {"id": 1, "bbox": [12.0, 285.0, 1334.0, 79.0], "category_id": 4}, {"id": 2, "bbox": [1205.0, 219.0, 129.0, 52.0], "category_id": 2}, {"id": 3, "bbox": [37.0, 213.0, 90.0, 63.0], "category_id": 2}, {"id": 4, "bbox": [463.0, 144.0, 136.0, 45.0], "category_id": 2}, {"id": 5, "bbox": [476.0, 46.0, 103.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [954.0, 54.0, 162.0, 55.0], "category_id": 2}, {"id": 7, "bbox": [1150.1, 29.1, 201.9, 182.9], "category_id": 1}, {"id": 8, "bbox": [679.9, 2.0, 220.2, 182.5], "category_id": 1}, {"id": 9, "bbox": [254.3, 70.0, 170.7, 150.9], "category_id": 1}, {"id": 10, "bbox": [6.0, 85.0, 205.0, 100.7], "category_id": 1}], "reactions": [{"reactants": [10, 9], "conditions": [5, 4], "products": [8]}, {"reactants": [8], "conditions": [6], "products": [7]}], "corefs": [[10, 3], [8, 0], [7, 2]], "caption": "Table 1. Preparation of N-Vinylisobutyramidea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 203, 714, 225], "ImageBB": [448, 230, 786, 321]}, "diagram_type": "single"}, {"id": 16, "width": 1348, "height": 524, "file_name": "ja9612413-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [851.09, 5.62, 220.64, 116.48], "category_id": 1}, {"id": 1, "bbox": [6.65, 168.31, 1336.25, 355.69], "category_id": 4}, {"id": 2, "bbox": [265.75, 44.35, 400.54, 66.56], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [0]}], "corefs": [], "caption": "Table 2. Substituent Group Effects on the Turnover Frequencies for Primary Aminoalkyne Hydroamination/Cyclizationa ", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 50, 761, 75], "ImageBB": [438, 84, 775, 214]}, "diagram_type": "single"}, {"id": 620, "width": 1356, "height": 1668, "file_name": "ol502664f-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [392.0, 6.0, 558.0, 189.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 433.0, 1356.0, 1235.0], "category_id": 4}, {"id": 2, "bbox": [137.3, 116.1, 171.0, 140.0], "category_id": 1}, {"id": 3, "bbox": [402.0, 227.8, 552.0, 193.6], "category_id": 2}, {"id": 4, "bbox": [1069.3, 141.7, 150.0, 130.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 3], "products": [4]}], "corefs": [], "caption": "Table 3. Lignin Model Oxidations with Catalytic Amounts of DDQ ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 294, 784, 324], "ImageBB": [448, 330, 787, 747]}, "diagram_type": "single"}, {"id": 1190, "width": 1356, "height": 712, "file_name": "ol500248h-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.01, 61.72, 180.44, 48.16], "category_id": 2}, {"id": 1, "bbox": [1168.78, 403.57, 35.95, 40.02], "category_id": 3}, {"id": 2, "bbox": [482.98, 613.15, 181.11, 40.7], "category_id": 2}, {"id": 3, "bbox": [502.65, 176.35, 103.79, 47.48], "category_id": 2}, {"id": 4, "bbox": [458.9, 270.63, 129.9, 114.62], "category_id": 1}, {"id": 5, "bbox": [681.05, 450.9, 259.13, 207.7], "category_id": 1}, {"id": 6, "bbox": [676.3, 458.9, 29.8, 33.1], "category_id": 3}, {"id": 7, "bbox": [951.71, 236.71, 259.13, 193.31], "category_id": 1}, {"id": 8, "bbox": [191.97, 406.28, 38.67, 35.27], "category_id": 3}, {"id": 9, "bbox": [484.33, 403.57, 42.06, 41.37], "category_id": 3}, {"id": 10, "bbox": [739.9, 307.4, 96.7, 49.2], "category_id": 2}, {"id": 11, "bbox": [679.02, 165.5, 23.74, 36.62], "category_id": 3}, {"id": 12, "bbox": [143.13, 284.87, 207.57, 119.38], "category_id": 1}, {"id": 13, "bbox": [667.49, 19.67, 212.32, 196.7], "category_id": 1}, {"id": 14, "bbox": [979.52, 612.47, 139.74, 37.31], "category_id": 2}, {"id": 15, "bbox": [504.01, 69.86, 139.06, 35.95], "category_id": 2}, {"id": 16, "bbox": [504.01, 507.34, 103.78, 48.84], "category_id": 2}], "caption": "Scheme 1. Possible Pathways for Pd-Catalyzed Double Arylations of 2-Arylbenzimidazoles and 1,2-Dihaloarenes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 545, 768, 575], "ImageBB": [448, 582, 787, 760]}, "reactions": [{"reactants": [12, 4], "conditions": [15], "products": [13]}, {"reactants": [13], "conditions": [0], "products": [7]}, {"reactants": [12, 4], "conditions": [10], "products": [7]}, {"reactants": [12, 4], "conditions": [2], "products": [5]}, {"reactants": [5], "conditions": [14], "products": [7]}], "diagram_type": "graph"}, {"id": 1334, "width": 1356, "height": 1468, "file_name": "op400278d-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.16, 1144.14, 321.0, 198.28], "category_id": 1}, {"id": 1, "bbox": [929.2, 1351.24, 249.75, 45.53], "category_id": 2}, {"id": 2, "bbox": [365.07, 114.56, 172.62, 135.12], "category_id": 2}, {"id": 3, "bbox": [429.71, 847.46, 315.85, 259.23], "category_id": 1}, {"id": 4, "bbox": [17.63, 1352.7, 374.62, 44.07], "category_id": 2}, {"id": 5, "bbox": [33.79, 425.93, 246.81, 160.83], "category_id": 1}, {"id": 6, "bbox": [885.86, 929.71, 96.96, 50.67], "category_id": 2}, {"id": 7, "bbox": [135.89, 35.25, 224.04, 144.67], "category_id": 1}, {"id": 8, "bbox": [462.76, 1133.86, 344.51, 261.44], "category_id": 1}, {"id": 9, "bbox": [929.2, 1128.72, 100.63, 49.2], "category_id": 2}, {"id": 10, "bbox": [789.64, 138.06, 236.52, 88.13], "category_id": 2}, {"id": 11, "bbox": [88.15, 1042.8, 88.88, 47.0], "category_id": 2}, {"id": 12, "bbox": [166.01, 895.19, 103.57, 48.47], "category_id": 2}, {"id": 13, "bbox": [254.15, 534.62, 37.46, 52.14], "category_id": 3}, {"id": 14, "bbox": [860.89, 334.87, 493.61, 316.51], "category_id": 1}, {"id": 15, "bbox": [132.95, 663.87, 246.81, 199.75], "category_id": 1}, {"id": 16, "bbox": [1082.72, 710.87, 146.91, 55.81], "category_id": 2}, {"id": 17, "bbox": [625.83, 405.37, 229.92, 132.19], "category_id": 2}, {"id": 18, "bbox": [600.12, 0.0, 245.34, 136.59], "category_id": 2}, {"id": 19, "bbox": [721.32, 975.97, 39.67, 51.41], "category_id": 3}, {"id": 20, "bbox": [732.92, 1288.33, 39.72, 43.51], "category_id": 3}, {"id": 21, "bbox": [1109.37, 993.22, 88.92, 45.4], "category_id": 2}, {"id": 22, "bbox": [1186.94, 516.5, 39.72, 41.62], "category_id": 3}, {"id": 23, "bbox": [1082.72, 1082.46, 147.64, 47.73], "category_id": 2}], "caption": "Scheme 3. Proposed NHC\u2212Pd-catalyzed amination pathway for alkyl and aryl amines ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 477, 784, 507], "ImageBB": [448, 513, 787, 880]}, "reactions": [{"reactants": [5, 7], "conditions": [2, 18, 10], "products": [14]}, {"reactants": [14, 16], "conditions": [], "products": [3, 8, 21, 23]}, {"reactants": [8], "conditions": [11], "products": [0, 5]}, {"reactants": [3], "conditions": [12], "products": [5, 15]}], "diagram_type": "graph"}, {"id": 584, "width": 1356, "height": 1676, "file_name": "acs.oprd.6b00188-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [243.43, 487.43, 56.0, 50.0], "category_id": 3}, {"id": 1, "bbox": [389.0, 179.0, 442.0, 68.0], "category_id": 2}, {"id": 2, "bbox": [414.0, 290.0, 392.0, 121.0], "category_id": 2}, {"id": 3, "bbox": [834.0, 556.0, 460.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [924.0, 473.0, 68.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [16.0, 624.0, 1340.0, 1014.0], "category_id": 4}, {"id": 6, "bbox": [893.0, 6.0, 324.0, 522.0], "category_id": 1}, {"id": 7, "bbox": [1094.0, 142.0, 6.0, 6.0], "category_id": 1}, {"id": 8, "bbox": [71.2, 37.0, 283.8, 439.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [1, 2], "products": [6]}], "corefs": [[8, 0], [6, 4]], "caption": "Table 1. Condensation of Racemic Tetralone 1 Mediated by Ti(IV) Alkoxides ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 309, 784, 339], "ImageBB": [448, 346, 787, 765]}, "diagram_type": "single"}, {"id": 757, "width": 1344, "height": 820, "file_name": "jo9902998-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [591.0, 292.0, 351.0, 55.0], "category_id": 2}, {"id": 1, "bbox": [247.0, 8.0, 153.0, 233.0], "category_id": 1}, {"id": 2, "bbox": [954.0, 3.0, 146.0, 237.0], "category_id": 1}, {"id": 3, "bbox": [1014.0, 268.0, 27.0, 32.0], "category_id": 3}, {"id": 4, "bbox": [310.0, 266.0, 29.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [709.0, 169.0, 92.0, 38.0], "category_id": 2}, {"id": 6, "bbox": [2.0, 365.0, 1341.0, 455.0], "category_id": 4}, {"id": 7, "bbox": [484.0, 128.0, 90.0, 43.0], "category_id": 2}, {"id": 8, "bbox": [596.0, 32.0, 302.0, 107.0], "category_id": 2}], "reactions": [{"reactants": [1, 7], "conditions": [8, 5], "products": [2]}], "corefs": [[1, 4], [2, 3]], "caption": "Table 2. Pd-Catalyzed Allylic Alkylation of 7a", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [106, 63, 375, 76], "ImageBB": [74, 81, 410, 286]}, "diagram_type": "single"}, {"id": 501, "width": 1352, "height": 720, "file_name": "ol053021c-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [863.8, 156.5, 295.8, 211.1], "category_id": 1}, {"id": 1, "bbox": [1044.0, 429.1, 238.9, 210.9], "category_id": 1}, {"id": 2, "bbox": [592.0, 659.0, 185.0, 61.0], "category_id": 3}, {"id": 3, "bbox": [348.0, 662.0, 198.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [115.0, 660.0, 189.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [186.0, 351.0, 46.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [940.0, 327.0, 62.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [315.1, 429.0, 272.9, 207.9], "category_id": 1}, {"id": 8, "bbox": [562.4, 429.2, 216.6, 212.8], "category_id": 1}, {"id": 9, "bbox": [790.1, 430.2, 235.9, 209.7], "category_id": 1}, {"id": 10, "bbox": [438.6, 270.1, 277.9, 97.8], "category_id": 2}, {"id": 11, "bbox": [403.3, 141.0, 353.7, 99.0], "category_id": 2}, {"id": 12, "bbox": [107.2, 162.0, 208.3, 212.3], "category_id": 1}, {"id": 13, "bbox": [1084.0, 664.0, 173.0, 56.0], "category_id": 3}, {"id": 14, "bbox": [841.0, 660.0, 173.0, 60.0], "category_id": 3}, {"id": 15, "bbox": [75.2, 432.0, 231.8, 207.9], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [11, 10], "products": [0]}], "corefs": [[12, 5], [0, 6], [15, 4], [7, 3], [8, 2], [9, 14], [1, 13]], "caption": "Figure 2. Relative reactivity of (NR)-indoles.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 243, 680, 256], "ImageBB": [439, 51, 777, 231]}, "diagram_type": "single"}, {"id": 1092, "width": 1208, "height": 1112, "file_name": "jo961049j-Scheme-c14.png", "license": 0, "bboxes": [{"id": 0, "bbox": [426.64, 906.5, 326.32, 137.79], "category_id": 2}, {"id": 1, "bbox": [0.0, 0.0, 356.54, 442.37], "category_id": 1}, {"id": 2, "bbox": [0.0, 703.45, 395.21, 339.03], "category_id": 1}, {"id": 3, "bbox": [957.82, 1062.42, 66.47, 49.56], "category_id": 3}, {"id": 4, "bbox": [816.41, 707.07, 332.97, 335.41], "category_id": 1}, {"id": 5, "bbox": [493.11, 829.75, 169.81, 55.0], "category_id": 2}, {"id": 6, "bbox": [956.01, 401.28, 64.66, 49.55], "category_id": 3}, {"id": 7, "bbox": [168.6, 1062.42, 59.22, 47.74], "category_id": 3}, {"id": 8, "bbox": [998.91, 520.94, 209.09, 107.57], "category_id": 2}, {"id": 9, "bbox": [429.66, 255.63, 323.3, 97.91], "category_id": 2}, {"id": 10, "bbox": [788.01, 0.0, 339.62, 394.03], "category_id": 1}, {"id": 11, "bbox": [167.39, 403.09, 55.6, 48.95], "category_id": 3}, {"id": 12, "bbox": [445.37, 121.47, 281.61, 114.82], "category_id": 2}], "caption": "Scheme 14", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [569, 49, 640, 63], "ImageBB": [456, 71, 758, 349]}, "reactions": [{"reactants": [1], "conditions": [12, 9], "products": [10]}, {"reactants": [10], "conditions": [8], "products": [4]}, {"reactants": [4], "conditions": [5, 0], "products": [2]}], "diagram_type": "tree"}, {"id": 715, "width": 1344, "height": 676, "file_name": "ol034434l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [932.03, 140.01, 36.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [3.0, 219.0, 1334.0, 457.0], "category_id": 4}, {"id": 2, "bbox": [270.3, 6.0, 280.7, 118.7], "category_id": 1}, {"id": 3, "bbox": [800.33, 9.9, 280.47, 116.01], "category_id": 1}, {"id": 4, "bbox": [394.01, 139.03, 31.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [644.0, 4.0, 50.0, 45.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [5], "products": [3]}], "corefs": [[2, 4], [3, 0]], "caption": "Table 1. Reduction of N,N-Dibenzylhydroxylamine (1) with Indium Metal ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 437, 392, 465], "ImageBB": [74, 471, 410, 640]}, "diagram_type": "single"}, {"id": 272, "width": 1348, "height": 644, "file_name": "ol801034x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [74.2, 70.0, 301.4, 221.1], "category_id": 1}, {"id": 1, "bbox": [322.2, 31.9, 266.7, 220.1], "category_id": 1}, {"id": 2, "bbox": [612.0, 40.0, 332.0, 101.0], "category_id": 2}, {"id": 3, "bbox": [946.0, 0.0, 329.0, 267.0], "category_id": 1}, {"id": 4, "bbox": [460.0, 277.0, 49.0, 62.0], "category_id": 3}, {"id": 5, "bbox": [1087.0, 285.0, 45.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [116.0, 277.0, 40.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [1.0, 355.0, 1347.0, 289.0], "category_id": 4}, {"id": 8, "bbox": [617.0, 184.0, 358.0, 101.0], "category_id": 2}], "reactions": [{"reactants": [0, 1], "conditions": [2, 8], "products": [3]}], "corefs": [[0, 6], [1, 4], [3, 5]], "caption": "Table 1. Reation of 1 with Isatin to Generate Compound 5a", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 243, 736, 258], "ImageBB": [425, 267, 762, 428]}, "diagram_type": "single"}, {"id": 1077, "width": 3396, "height": 1148, "file_name": "jo500696n-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1383.01, 260.23, 102.44, 48.66], "category_id": 2}, {"id": 1, "bbox": [993.83, 560.14, 67.95, 59.41], "category_id": 2}, {"id": 2, "bbox": [693.13, 531.28, 95.14, 50.93], "category_id": 3}, {"id": 3, "bbox": [2346.11, 607.67, 88.34, 61.1], "category_id": 2}, {"id": 4, "bbox": [1002.32, 363.24, 248.03, 91.66], "category_id": 2}, {"id": 5, "bbox": [1651.28, 100.15, 57.76, 47.52], "category_id": 2}, {"id": 6, "bbox": [1651.28, 612.76, 64.56, 56.01], "category_id": 2}, {"id": 7, "bbox": [1172.21, 548.26, 372.04, 276.67], "category_id": 1}, {"id": 8, "bbox": [1002.32, 203.69, 59.46, 52.62], "category_id": 2}, {"id": 9, "bbox": [1858.54, 548.26, 375.45, 278.37], "category_id": 1}, {"id": 10, "bbox": [2546.58, 288.56, 383.94, 49.22], "category_id": 2}, {"id": 11, "bbox": [1100.85, 40.74, 445.1, 220.66], "category_id": 1}, {"id": 12, "bbox": [445.1, 290.25, 530.04, 266.5], "category_id": 1}, {"id": 13, "bbox": [1172.21, 796.08, 110.42, 49.22], "category_id": 2}, {"id": 14, "bbox": [1810.97, 40.74, 441.7, 218.96], "category_id": 1}, {"id": 15, "bbox": [1523.87, 376.82, 334.67, 61.11], "category_id": 2}, {"id": 16, "bbox": [2555.07, 826.63, 375.45, 52.62], "category_id": 2}, {"id": 17, "bbox": [2509.2, 45.83, 438.3, 213.87], "category_id": 1}, {"id": 18, "bbox": [2264.57, 364.94, 251.43, 86.57], "category_id": 2}, {"id": 19, "bbox": [2346.11, 86.57, 81.55, 64.5], "category_id": 2}, {"id": 20, "bbox": [2568.66, 549.96, 363.55, 271.58], "category_id": 1}], "caption": "Scheme 2. Possible Photocyclization Pathways for 2-Styrylquinolines", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 808, 468, 823], "ImageBB": [10, 840, 859, 1127]}, "reactions": [{"reactants": [12], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [8], "products": [12]}, {"reactants": [11], "conditions": [5], "products": [14]}, {"reactants": [14], "conditions": [], "products": [11]}, {"reactants": [14], "conditions": [19], "products": [17]}, {"reactants": [12], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [1], "products": [12]}, {"reactants": [7], "conditions": [6], "products": [9]}, {"reactants": [9], "conditions": [], "products": [7]}, {"reactants": [9], "conditions": [3], "products": [20]}], "diagram_type": "tree"}, {"id": 1036, "width": 1336, "height": 1816, "file_name": "jo001614p-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [343.28, 1385.39, 69.02, 52.69], "category_id": 3}, {"id": 1, "bbox": 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[], "products": [6]}, {"reactants": [6], "conditions": [], "products": [17]}, {"reactants": [6], "conditions": [], "products": [21]}, {"reactants": [21], "conditions": [], "products": [6]}, {"reactants": [21], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [21]}, {"reactants": [8], "conditions": [], "products": [10]}, {"reactants": [8], "conditions": [], "products": [26]}, {"reactants": [26], "conditions": [], "products": [8]}, {"reactants": [26], "conditions": [], "products": [20]}], "diagram_type": "tree"}, {"id": 437, "width": 2820, "height": 760, "file_name": "op200351g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [237.0, 25.0, 605.0, 337.0], "category_id": 1}, {"id": 1, "bbox": [1776.0, 204.0, 180.0, 62.0], "category_id": 2}, {"id": 2, "bbox": [2219.0, 271.0, 73.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [1422.0, 266.0, 85.0, 66.0], "category_id": 3}, {"id": 4, "bbox": [495.0, 271.0, 66.0, 56.0], "category_id": 3}, {"id": 5, "bbox": [223.0, 419.0, 2382.0, 293.0], "category_id": 4}, {"id": 6, "bbox": [1971.0, 66.0, 632.0, 235.0], "category_id": 1}, {"id": 7, "bbox": [1781.0, 102.0, 157.0, 77.0], "category_id": 2}, {"id": 8, "bbox": [783.0, 68.0, 308.0, 111.0], "category_id": 2}, {"id": 9, "bbox": [728.3, 227.4, 415.6, 119.0], "category_id": 2}, {"id": 10, "bbox": [1141.0, 63.0, 619.0, 244.7], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [8, 9], "products": [10]}, {"reactants": [10], "conditions": [7, 1], "products": [6]}], "corefs": [[0, 4], [10, 3], [6, 2]], "caption": "Table 2. PFR cyclization results for ketoamide (11) cyclization and deprotection", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 656, 537, 671], "ImageBB": [82, 677, 787, 867]}, "diagram_type": "single"}, {"id": 150, "width": 1196, "height": 404, "file_name": "op7001886-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [137.1, 336.0, 279.4, 65.2], "category_id": 3}, {"id": 1, "bbox": [1019.0, 341.0, 55.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [914.0, 0.0, 279.0, 330.0], "category_id": 1}, {"id": 3, "bbox": [665.5, 64.9, 228.7, 194.7], "category_id": 1}, {"id": 4, "bbox": [7.0, 65.1, 501.0, 291.9], "category_id": 1}, {"id": 5, "bbox": [726.0, 336.0, 44.2, 60.8], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [], "products": [3, 2]}], "corefs": [[4, 0], [3, 5], [2, 1]], "caption": "Figure 2", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 541, 476, 555], "ImageBB": [444, 437, 743, 538]}, "diagram_type": "single"}, {"id": 205, "width": 1344, "height": 756, "file_name": "op034181b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [813.0, 7.0, 326.0, 202.0], "category_id": 1}, {"id": 1, "bbox": [284.0, 200.0, 55.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [0.0, 276.0, 1339.0, 363.0], "category_id": 4}, {"id": 3, "bbox": [42.0, 668.0, 959.0, 71.0], "category_id": 2}, {"id": 4, "bbox": [598.1, 136.1, 129.7, 47.9], "category_id": 2}, {"id": 5, "bbox": [511.9, 63.1, 333.1, 50.8], "category_id": 2}, {"id": 6, "bbox": [901.05, 199.0, 45.0, 54.0], "category_id": 3}, {"id": 7, "bbox": [199.0, 1.0, 305.8, 191.8], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 4], "products": [0]}], "corefs": [[7, 1], [0, 6]], "caption": "Table 2. Esterification of 2,4,6-trimethylbenzoic acid", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 367, 67], "ImageBB": [74, 70, 410, 259]}, "diagram_type": "single"}, {"id": 938, "width": 1352, "height": 1408, "file_name": "acs.orglett.5b01044-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [902.97, 717.03, 331.74, 285.26], "category_id": 1}, {"id": 1, "bbox": [198.62, 950.88, 238.78, 90.86], "category_id": 3}, {"id": 2, "bbox": [607.85, 953.69, 243.7, 87.34], "category_id": 3}, {"id": 3, "bbox": [674.06, 640.96, 55.64, 39.04], "category_id": 3}, {"id": 4, "bbox": [488.11, 1044.55, 374.01, 312.74], "category_id": 1}, {"id": 5, "bbox": [185.24, 291.6, 214.83, 84.52], "category_id": 3}, {"id": 6, "bbox": [962.13, 111.99, 299.35, 226.8], "category_id": 1}, {"id": 7, "bbox": [197.92, 1310.8, 238.07, 50.71], "category_id": 3}, {"id": 8, "bbox": [1067.08, 643.07, 47.89, 38.74], "category_id": 3}, {"id": 9, "bbox": [185.24, 645.19, 100.02, 42.26], "category_id": 3}, {"id": 10, "bbox": [900.85, 1125.55, 360.63, 231.74], "category_id": 1}, {"id": 11, "bbox": [490.93, 737.46, 319.77, 266.24], "category_id": 1}, {"id": 12, "bbox": [612.07, 1313.62, 220.46, 51.41], "category_id": 3}, {"id": 13, "bbox": [534.6, 460.65, 295.12, 221.16], "category_id": 1}, {"id": 14, "bbox": [89.45, 111.99, 269.06, 226.8], "category_id": 1}, {"id": 15, "bbox": [226.8, 381.76, 281.03, 82.41], "category_id": 2}, {"id": 16, "bbox": [1088.91, 354.29, 160.59, 109.88], "category_id": 2}, {"id": 17, "bbox": [393.73, 0.0, 627.57, 80.3], "category_id": 2}, {"id": 18, "bbox": [926.21, 460.65, 296.53, 223.98], "category_id": 1}, {"id": 19, "bbox": [1012.14, 953.69, 245.82, 86.64], "category_id": 3}, {"id": 20, "bbox": [1086.1, 293.71, 86.63, 45.79], "category_id": 3}, {"id": 21, "bbox": [806.47, 151.44, 164.11, 81.0], "category_id": 2}, {"id": 22, "bbox": [659.97, 364.15, 273.99, 84.52], "category_id": 2}, {"id": 23, "bbox": [87.34, 1129.08, 324.7, 229.62], "category_id": 1}, {"id": 24, "bbox": [88.04, 460.65, 284.56, 221.16], "category_id": 1}, {"id": 25, "bbox": [87.34, 778.31, 326.11, 225.39], "category_id": 1}, {"id": 26, "bbox": [1012.84, 1310.1, 238.78, 53.53], "category_id": 3}, {"id": 27, "bbox": [525.44, 116.22, 260.61, 222.57], "category_id": 1}, {"id": 28, "bbox": [376.12, 151.44, 128.89, 78.88], "category_id": 2}, {"id": 29, "bbox": [638.8, 289.08, 141.99, 43.95], "category_id": 3}], "caption": "Scheme 5. Conversion of Pyridones 2 to Pyridine Derivatives", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 110], "ImageBB": [82, 116, 420, 468]}, "reactions": [{"reactants": [27], "conditions": [28], "products": [14]}, {"reactants": [27], "conditions": [21], "products": [6]}, {"reactants": [14], "conditions": [17], "products": [6]}, {"reactants": [14], "conditions": [15], "products": [24]}, {"reactants": [27], "conditions": [22], "products": [13]}, {"reactants": [13], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [13]}, {"reactants": [18], "conditions": [16], "products": [6]}], "diagram_type": "graph"}, {"id": 19, "width": 1312, "height": 1020, "file_name": "ja9535975-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [531.65, 101.94, 191.52, 54.64], "category_id": 2}, {"id": 1, "bbox": [815.94, 8.49, 421.84, 140.19], "category_id": 1}, {"id": 2, "bbox": [538.23, 23.6, 171.78, 29.7], "category_id": 2}, {"id": 3, "bbox": [92.06, 4.54, 299.45, 144.14], "category_id": 1}, {"id": 4, "bbox": [1021.25, 170.37, 44.12, 37.54], "category_id": 3}, {"id": 5, "bbox": [3.88, 241.45, 1299.71, 770.61], "category_id": 4}, {"id": 6, "bbox": [289.48, 171.69, 42.8, 37.54], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [2, 0], "products": [1]}], "corefs": [[3, 6], [1, 4]], "caption": "Table 1. Comparison of Reaction Conditions for the Photopromoted Pauson-Khand Reaction ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 70, 693, 95], "ImageBB": [434, 100, 762, 355]}, "diagram_type": "single"}, {"id": 148, "width": 2816, "height": 2116, "file_name": "op700249f-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1182.0, 211.0, 241.9, 134.2], "category_id": 2}, {"id": 1, "bbox": [591.0, 354.9, 258.0, 87.1], "category_id": 3}, {"id": 2, "bbox": [65.0, 465.0, 2689.0, 433.0], "category_id": 4}, {"id": 3, "bbox": [1967.0, 358.0, 115.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [1626.0, 30.0, 743.0, 309.0], "category_id": 1}, {"id": 5, "bbox": [1163.0, 3.0, 266.0, 147.0], "category_id": 1}, {"id": 6, "bbox": [464.0, 71.0, 627.0, 258.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 0], "products": [4]}], "corefs": [[6, 1], [4, 3]], "caption": "Figure 3. Reaction profile of triazole-linked glycosidic amino acid 45 with glycinamide. identity of the impurities could not be established, although it    concomitant decreas was clear that enzymatic hydrolysis of the starting material was    by HPLC resulting  not an issue. Since glycinamide was added to the reaction           2). Next, a slightly  mixture in excess, formation of a tripeptide (NTGA-Gly-Gly-         involving addition of NH2) might be one of the possibilities.                             to methyl ester 45 in ", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 841, 536, 940], "ImageBB": [58, 308, 762, 837]}, "diagram_type": "single"}, {"id": 1082, "width": 1356, "height": 1224, "file_name": "jo501736w-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1202.02, 854.2, 51.55, 54.28], "category_id": 3}, {"id": 1, "bbox": [727.98, 26.5, 101.39, 55.83], "category_id": 2}, {"id": 2, "bbox": [630.7, 50.3, 261.32, 182.1], "category_id": 1}, {"id": 3, "bbox": [174.02, 646.58, 61.72, 63.18], "category_id": 2}, {"id": 4, "bbox": [182.84, 980.13, 58.78, 64.65], "category_id": 2}, {"id": 5, "bbox": [944.93, 2.71, 170.94, 108.39], "category_id": 1}, {"id": 6, "bbox": [754.31, 230.68, 54.27, 50.21], "category_id": 3}, {"id": 7, "bbox": [93.61, 322.28, 396.83, 174.36], "category_id": 1}, {"id": 8, "bbox": [388.01, 926.8, 383.94, 194.72], "category_id": 1}, {"id": 9, "bbox": [223.85, 207.61, 43.42, 49.53], "category_id": 3}, {"id": 10, "bbox": [733.96, 316.85, 385.3, 196.75], "category_id": 1}, {"id": 11, "bbox": [328.32, 855.56, 79.36, 67.84], "category_id": 2}, {"id": 12, "bbox": [421.25, 48.85, 126.85, 56.31], "category_id": 2}, {"id": 13, "bbox": [991.05, 507.5, 50.2, 50.88], "category_id": 3}, {"id": 14, "bbox": [269.98, 515.64, 48.16, 52.24], "category_id": 3}, {"id": 15, "bbox": [506.04, 588.92, 86.83, 54.95], "category_id": 2}, {"id": 16, "bbox": [972.06, 700.19, 383.94, 147.22], "category_id": 1}, {"id": 17, "bbox": [1019.54, 93.63, 48.84, 46.81], "category_id": 3}, {"id": 18, "bbox": [389.37, 668.3, 383.94, 196.75], "category_id": 1}, {"id": 19, "bbox": [97.68, 54.96, 253.7, 147.23], "category_id": 1}, {"id": 20, "bbox": [623.39, 860.98, 43.42, 46.82], "category_id": 3}, {"id": 21, "bbox": [623.39, 1129.66, 42.06, 47.49], "category_id": 3}], "caption": "Scheme 3. A Proposed Mechanism for the Halide-Mediated Electrochemical Synthesis of 2-Aminobenzoxazoles ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 233, 784, 263], "ImageBB": [448, 269, 787, 575]}, "reactions": [{"reactants": [19], "conditions": [12], "products": [1, 2]}, {"reactants": [1, 2], "conditions": [], "products": [19]}, {"reactants": [2, 5], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [2, 5]}, {"reactants": [10], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [10]}, {"reactants": [8, 4], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [16, 3]}], "diagram_type": "graph"}, {"id": 936, "width": 1356, "height": 1304, "file_name": "acs.orglett.5b00776-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [849.96, 970.61, 147.2, 61.05], "category_id": 2}, {"id": 1, "bbox": [328.99, 312.69, 45.45, 56.97], "category_id": 3}, {"id": 2, "bbox": [586.76, 308.62, 56.31, 59.01], "category_id": 3}, {"id": 3, "bbox": [609.83, 1209.37, 64.44, 50.87], "category_id": 3}, {"id": 4, "bbox": [951.71, 595.53, 385.97, 383.9], "category_id": 1}, {"id": 5, "bbox": [476.19, 425.28, 297.12, 271.99], "category_id": 1}, {"id": 6, "bbox": [499.26, 871.59, 294.4, 337.78], "category_id": 1}, {"id": 7, "bbox": [46.13, 843.78, 269.3, 361.52], "category_id": 1}, {"id": 8, "bbox": [1177.6, 314.72, 49.52, 54.26], "category_id": 3}, {"id": 9, "bbox": [819.43, 315.4, 63.77, 54.26], "category_id": 3}, {"id": 10, "bbox": [299.15, 612.48, 197.39, 64.44], "category_id": 2}, {"id": 11, "bbox": [819.43, 915.0, 41.38, 47.47], "category_id": 2}, {"id": 12, "bbox": [136.35, 1199.19, 50.87, 48.84], "category_id": 3}, {"id": 13, "bbox": [951.71, 0.0, 381.23, 312.01], "category_id": 1}, {"id": 14, "bbox": [183.5, 64.9, 72.23, 65.33], "category_id": 2}, {"id": 15, "bbox": [819.43, 694.56, 50.2, 54.94], "category_id": 2}, {"id": 16, "bbox": [770.29, 9.33, 164.37, 299.0], "category_id": 1}, {"id": 17, "bbox": [550.13, 14.92, 140.67, 231.58], "category_id": 1}, {"id": 18, "bbox": [22.39, 18.31, 124.81, 234.01], "category_id": 1}, {"id": 19, "bbox": [865.78, 626.11, 73.57, 50.1], "category_id": 2}, {"id": 20, "bbox": [48.16, 440.2, 290.33, 264.53], "category_id": 1}, {"id": 21, "bbox": [608.47, 707.44, 60.37, 61.73], "category_id": 3}, {"id": 22, "bbox": [1207.1, 435.2, 62.7, 66.4], "category_id": 1}, {"id": 23, "bbox": [63.09, 308.62, 61.05, 61.04], "category_id": 3}, {"id": 24, "bbox": [1178.95, 986.89, 48.17, 54.26], "category_id": 3}, {"id": 25, "bbox": [299.15, 25.1, 147.88, 235.36], "category_id": 1}, {"id": 26, "bbox": [136.35, 707.44, 54.94, 56.98], "category_id": 3}], "caption": "Scheme 5. Plausible Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 630, 110], "ImageBB": [448, 116, 787, 442]}, "reactions": [{"reactants": [18], "conditions": [14], "products": [25]}, {"reactants": [25], "conditions": [], "products": [18]}, {"reactants": [25], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [25]}, {"reactants": [17, 16], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [17, 16]}, {"reactants": [4], "conditions": [15, 19], "products": [5]}, {"reactants": [5], "conditions": [10], "products": [20]}, {"reactants": [4], "conditions": [11, 0], "products": [6]}, {"reactants": [6], "conditions": [], "products": [7]}], "diagram_type": "tree"}, {"id": 615, "width": 1356, "height": 808, "file_name": "acs.oprd.5b00282-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [961.0, 45.0, 277.0, 326.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 98.0, 276.0, 272.0], "category_id": 1}, {"id": 2, "bbox": [531.0, 180.0, 210.0, 33.0], "category_id": 2}, {"id": 3, "bbox": [339.0, 211.0, 37.0, 33.0], "category_id": 2}, {"id": 4, "bbox": [84.0, 409.0, 138.0, 67.0], "category_id": 2}, {"id": 5, "bbox": [336.0, 411.0, 172.0, 30.0], "category_id": 2}, {"id": 6, "bbox": [823.0, 400.0, 97.0, 29.0], "category_id": 2}, {"id": 7, "bbox": [1036.0, 408.0, 175.0, 69.0], "category_id": 2}, {"id": 8, "bbox": [1295.0, 208.0, 54.0, 40.0], "category_id": 2}, {"id": 9, "bbox": [805.0, 734.0, 99.0, 28.0], "category_id": 2}, {"id": 10, "bbox": [585.0, 590.0, 68.0, 28.0], "category_id": 2}, {"id": 11, "bbox": [304.0, 661.0, 280.0, 36.0], "category_id": 2}, {"id": 12, "bbox": [285.0, 775.0, 169.0, 28.0], "category_id": 2}], "reactions": [{"reactants": [1, 3, 5], "conditions": [2], "products": [0, 8, 6]}, {"reactants": [0, 8, 6], "conditions": [], "products": [1, 3, 5]}, {"reactants": [9], "conditions": [10], "products": [11]}, {"reactants": [11], "conditions": [], "products": [12]}], "corefs": [[1, 4], [0, 7]], "caption": "Figure 1. Bio-oxidation/hydroxylation reaction of \u03b1-isophorone to 4- hydroxy-\u03b1-isophorone. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 820, 784, 851], "ImageBB": [448, 612, 787, 814]}, "diagram_type": "graph"}, {"id": 269, "width": 1352, "height": 524, "file_name": "ol801035c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [910.0, 191.0, 350.0, 199.0], "category_id": 1}, {"id": 1, "bbox": [424.0, 80.0, 220.0, 57.0], "category_id": 2}, {"id": 2, "bbox": [260.0, 210.0, 33.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [884.0, 200.0, 27.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1253.0, 191.0, 46.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [1180.0, 347.0, 53.0, 42.0], "category_id": 3}, {"id": 6, "bbox": [313.0, 156.0, 437.0, 156.1], "category_id": 2}, {"id": 7, "bbox": [0.0, 424.0, 1342.0, 100.0], "category_id": 4}, {"id": 8, "bbox": [1037.1, 2.0, 265.9, 196.8], "category_id": 1}, {"id": 9, "bbox": [681.6, 14.0, 348.4, 181.5], "category_id": 1}, {"id": 10, "bbox": [49.1, 24.7, 263.9, 177.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [1, 6], "products": [9, 8, 0]}], "corefs": [[10, 2], [9, 3], [8, 4], [0, 5]], "caption": "Table 1. Study of the Direct Phenylation of 2", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 296, 88], "ImageBB": [58, 97, 396, 228]}, "diagram_type": "single"}, {"id": 1277, "width": 1356, "height": 2360, "file_name": "op100104z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 0.0, 231.37, 253.83], "category_id": 1}, {"id": 1, "bbox": [734.24, 316.4, 499.33, 514.74], "category_id": 1}, {"id": 2, "bbox": [565.44, 577.31, 31.87, 38.96], "category_id": 2}, {"id": 3, "bbox": [621.22, 1303.15, 36.83, 36.84], "category_id": 3}, {"id": 4, "bbox": [397.81, 10.63, 213.66, 253.82], "category_id": 1}, {"id": 5, "bbox": [238.45, 1322.26, 28.33, 36.6], "category_id": 3}, {"id": 6, "bbox": [1110.81, 96.81, 36.59, 34.24], "category_id": 2}, {"id": 7, "bbox": [49.58, 1050.73, 409.62, 337.64], "category_id": 1}, {"id": 8, "bbox": [766.11, 7.08, 265.6, 249.11], "category_id": 1}, {"id": 9, "bbox": [653.97, 92.09, 40.14, 40.14], "category_id": 2}, {"id": 10, "bbox": [1023.45, 1369.48, 36.6, 37.78], "category_id": 3}, {"id": 11, "bbox": [0.0, 1581.99, 1356.0, 691.83], "category_id": 2}, {"id": 12, "bbox": [238.45, 822.87, 28.33, 37.78], "category_id": 3}, {"id": 13, "bbox": [844.02, 251.47, 33.06, 33.05], "category_id": 3}, {"id": 14, "bbox": [0.0, 1419.07, 1356.0, 114.52], "category_id": 2}, {"id": 15, "bbox": [82.63, 265.63, 31.87, 36.6], "category_id": 3}, {"id": 16, "bbox": [822.77, 891.35, 533.23, 518.27], "category_id": 1}, {"id": 17, "bbox": [275.05, 94.45, 29.51, 33.05], "category_id": 2}, {"id": 18, "bbox": [47.22, 344.73, 537.1, 515.92], "category_id": 1}, {"id": 19, "bbox": [537.11, 1021.21, 259.69, 252.65], "category_id": 1}, {"id": 20, "bbox": [912.49, 783.91, 24.79, 33.06], "category_id": 3}, {"id": 21, "bbox": [478.08, 259.73, 29.51, 33.06], "category_id": 3}], "caption": "Scheme 1. Original synthesis of 1a", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 425, 619, 439], "ImageBB": [424, 448, 763, 1038]}, "reactions": [{"reactants": [0], "conditions": [17], "products": [4]}, {"reactants": [4], "conditions": [9], "products": [8]}, {"reactants": [8], "conditions": [6], "products": [18]}, {"reactants": [18], "conditions": [2], "products": [1]}], "diagram_type": "multiple"}, {"id": 1114, "width": 1120, "height": 2248, "file_name": "jo9816515-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [559.02, 1583.38, 420.66, 286.77], "category_id": 1}, {"id": 1, "bbox": [913.32, 2105.18, 200.21, 142.82], "category_id": 1}, {"id": 2, "bbox": [669.24, 2135.3, 230.58, 75.59], "category_id": 3}, {"id": 3, "bbox": [887.45, 647.75, 129.35, 61.85], "category_id": 2}, {"id": 4, "bbox": [825.59, 253.03, 131.6, 69.72], "category_id": 3}, {"id": 5, "bbox": [701.86, 900.77, 391.43, 330.63], "category_id": 1}, {"id": 6, "bbox": [575.89, 1257.26, 60.74, 60.73], "category_id": 3}, {"id": 7, "bbox": [92.23, 51.73, 383.55, 151.82], "category_id": 1}, {"id": 8, "bbox": [125.98, 1880.27, 177.71, 71.97], "category_id": 3}, {"id": 9, "bbox": [743.48, 3.37, 271.07, 224.92], "category_id": 1}, {"id": 10, "bbox": [202.46, 253.03, 173.22, 69.72], "category_id": 3}, {"id": 11, "bbox": [701.86, 1897.14, 138.35, 64.1], "category_id": 3}, {"id": 12, "bbox": [602.88, 405.97, 147.35, 93.34], "category_id": 2}, {"id": 13, "bbox": [0.0, 1997.22, 620.88, 213.67], "category_id": 3}, {"id": 14, "bbox": [0.0, 1583.38, 409.42, 282.27], "category_id": 1}, {"id": 15, "bbox": [916.7, 1966.86, 192.33, 139.45], "category_id": 1}, {"id": 16, "bbox": [311.56, 1376.46, 192.34, 114.71], "category_id": 2}, {"id": 17, "bbox": [95.61, 900.77, 439.78, 330.63], "category_id": 1}, {"id": 18, "bbox": [165.34, 654.5, 132.73, 62.97], "category_id": 2}, {"id": 19, "bbox": [669.24, 2002.85, 235.08, 75.34], "category_id": 3}, {"id": 20, "bbox": [885.2, 1378.71, 201.34, 97.84], "category_id": 2}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [102, 83, 382, 645]}, "reactions": [{"reactants": [7, 9], "conditions": [12], "products": [17]}, {"reactants": [7, 9], "conditions": [12], "products": [5]}, {"reactants": [17], "conditions": [16], "products": [14]}, {"reactants": [5], "conditions": [20], "products": [0]}], "diagram_type": "tree"}, {"id": 489, "width": 1352, "height": 2216, "file_name": "ol060473w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [118.0, 57.0, 184.0, 138.4], "category_id": 1}, {"id": 1, "bbox": [335.0, 151.0, 564.0, 68.0], "category_id": 2}, {"id": 2, "bbox": [3.0, 282.0, 1349.0, 1934.0], "category_id": 4}, {"id": 3, "bbox": [924.8, 0.0, 355.5, 255.1], "category_id": 1}, {"id": 4, "bbox": [345.0, 64.0, 546.0, 63.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [4, 1], "products": [3]}], "corefs": [], "caption": "Table 2. Direct Amidation of Quinoline and Isoquinoline N-Oxides with Various Amides ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 193, 743, 221], "ImageBB": [439, 222, 777, 776]}, "diagram_type": "single"}, {"id": 644, "width": 1352, "height": 2752, "file_name": "ol500618w-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [417.0, 276.0, 157.5, 52.9], "category_id": 2}, {"id": 1, "bbox": [395.1, 52.0, 167.9, 137.4], "category_id": 1}, {"id": 2, "bbox": [1134.7, 17.1, 217.3, 197.9], "category_id": 1}, {"id": 3, "bbox": [678.0, 128.55, 351.5, 140.15], "category_id": 2}, {"id": 4, "bbox": [19.0, 276.0, 140.0, 48.0], "category_id": 2}, {"id": 5, "bbox": [3.0, 375.0, 460.0, 110.0], "category_id": 2}, {"id": 6, "bbox": [1224.0, 223.0, 47.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [80.0, 225.0, 36.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [0.0, 18.0, 195.0, 197.0], "category_id": 1}, {"id": 9, "bbox": [459.0, 227.0, 33.0, 38.0], "category_id": 3}, {"id": 10, "bbox": [11.0, 487.0, 1341.0, 2265.0], "category_id": 4}, {"id": 11, "bbox": [684.0, 8.0, 349.0, 79.0], "category_id": 2}], "reactions": [{"reactants": [8, 1], "conditions": [11, 3], "products": [2]}], "corefs": [[8, 7], [1, 9], [2, 6]], "caption": "Table 3. Cyanation of Alkenyl Halides", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 666, 110], "ImageBB": [448, 116, 786, 804]}, "diagram_type": "single"}, {"id": 419, "width": 2820, "height": 1804, "file_name": "op300364p-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [646.0, 256.0, 65.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [2390.0, 241.0, 56.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [317.0, 98.0, 253.0, 162.0], "category_id": 1}, {"id": 3, "bbox": [1934.0, 244.0, 49.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [1101.0, 104.0, 402.0, 65.3], "category_id": 2}, {"id": 5, "bbox": [1780.0, 82.09, 331.0, 185.0], "category_id": 1}, {"id": 6, "bbox": [858.0, 192.9, 878.0, 69.4], "category_id": 2}, {"id": 7, "bbox": [2216.0, 49.42, 291.0, 214.0], "category_id": 1}, {"id": 8, "bbox": [621.0, 123.0, 183.6, 83.3], "category_id": 1}, {"id": 9, "bbox": [0.3, 351.0, 2715.7, 1453.0], "category_id": 4}], "reactions": [{"reactants": [2, 8], "conditions": [4, 6], "products": [5, 7]}], "corefs": [[8, 0], [5, 3], [7, 1]], "caption": "Table 5. A Generic Heck\u2212Mizoroki Protocol for Dimethylpentene", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 574, 450, 590], "ImageBB": [82, 117, 787, 568]}, "diagram_type": "single"}, {"id": 535, "width": 1336, "height": 1152, "file_name": "jo000694u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [959.4, 82.7, 376.6, 423.3], "category_id": 1}, {"id": 1, "bbox": [15.69, 667.69, 380.91, 444.0], "category_id": 1}, {"id": 2, "bbox": [534.0, 95.69, 385.0, 420.0], "category_id": 1}, {"id": 3, "bbox": [683.0, 512.0, 47.0, 36.3], "category_id": 3}, {"id": 4, "bbox": [1091.0, 503.7, 59.3, 43.3], "category_id": 3}, {"id": 5, "bbox": [4.0, 106.0, 313.4, 407.7], "category_id": 1}, {"id": 6, "bbox": [351.0, 125.0, 162.0, 47.0], "category_id": 2}, {"id": 7, "bbox": [162.0, 557.0, 233.0, 96.0], "category_id": 2}, {"id": 8, "bbox": [150.0, 1104.0, 47.0, 43.0], "category_id": 3}, {"id": 9, "bbox": [131.0, 507.0, 48.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [6], "products": [2, 0]}, {"reactants": [5], "conditions": [7], "products": [1]}, {"reactants": [1], "conditions": [], "products": [2]}], "corefs": [[5, 9], [2, 3], [0, 4], [1, 8]], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 148, 131, 161], "ImageBB": [75, 171, 409, 459]}, "diagram_type": "graph"}, {"id": 648, "width": 1352, "height": 2200, "file_name": "ol500248h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [87.7, 85.0, 245.3, 138.0], "category_id": 1}, {"id": 1, "bbox": [393.8, 76.0, 181.2, 131.0], "category_id": 1}, {"id": 2, "bbox": [946.0, 2.0, 311.0, 237.0], "category_id": 1}, {"id": 3, "bbox": [1230.0, 219.0, 28.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [467.0, 219.0, 27.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [197.0, 223.0, 34.0, 32.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 271.0, 1352.0, 1924.0], "category_id": 4}, {"id": 7, "bbox": [599.33, 148.33, 378.0, 44.0], "category_id": 2}, {"id": 8, "bbox": [596.0, 46.0, 371.0, 83.5], "category_id": 2}], "reactions": [{"reactants": [0, 1], "conditions": [8, 7], "products": [2]}], "corefs": [[0, 5], [1, 4], [2, 3]], "caption": "Table 1. Pd-Catalyzed Annulation of Benzimidazole Derivative with o-Dihalobenzenea ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 248, 374, 279], "ImageBB": [82, 285, 420, 835]}, "diagram_type": "single"}, {"id": 1070, "width": 1352, "height": 1076, "file_name": "jo400755q-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.23, 588.35, 77.78, 56.13], "category_id": 2}, {"id": 1, "bbox": [75.5, 273.89, 470.98, 287.41], "category_id": 1}, {"id": 2, "bbox": [371.31, 568.06, 223.59, 107.34], "category_id": 2}, {"id": 3, "bbox": [498.46, 696.55, 114.98, 61.54], "category_id": 2}, {"id": 4, "bbox": [685.81, 697.9, 392.27, 288.09], "category_id": 1}, {"id": 5, "bbox": [622.23, 248.19, 504.55, 345.57], "category_id": 1}, {"id": 6, "bbox": [344.93, 2.71, 181.94, 233.31], "category_id": 1}, {"id": 7, "bbox": [526.87, 248.19, 177.87, 86.56], "category_id": 2}, {"id": 8, "bbox": [101.45, 702.64, 395.66, 287.41], "category_id": 1}, {"id": 9, "bbox": [885.2, 625.18, 60.71, 47.79], "category_id": 2}, {"id": 10, "bbox": [601.02, 569.64, 202.8, 85.25], "category_id": 2}, {"id": 11, "bbox": [253.55, 476.63, 31.0, 46.5], "category_id": 3}, {"id": 12, "bbox": [792.2, 510.22, 36.17, 46.5], "category_id": 3}, {"id": 13, "bbox": [1123.4, 778.38, 150.82, 252.24], "category_id": 1}], "caption": "Scheme 3. Plausible Catalytic Cycle", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 675, 284, 690], "ImageBB": [82, 696, 420, 965]}, "reactions": [{"reactants": [1, 6], "conditions": [7], "products": [5]}, {"reactants": [5, 9], "conditions": [10], "products": [3, 4, 13]}, {"reactants": [3, 8], "conditions": [2], "products": [0, 1]}], "diagram_type": "graph"}, {"id": 859, "width": 1344, "height": 2528, "file_name": "jo200480h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [63.0, 160.0, 257.0, 164.0], "category_id": 1}, {"id": 1, "bbox": [409.0, 1.0, 397.0, 120.0], "category_id": 1}, {"id": 2, "bbox": [583.0, 91.0, 34.0, 33.0], "category_id": 3}, {"id": 3, "bbox": [72.0, 384.0, 193.0, 54.0], "category_id": 2}, {"id": 4, "bbox": [953.0, 392.0, 189.0, 41.0], "category_id": 2}, {"id": 5, "bbox": [973.0, 332.0, 135.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [94.0, 332.0, 99.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [906.0, 34.0, 378.0, 293.0], "category_id": 1}, {"id": 8, "bbox": [2.0, 2445.0, 578.0, 58.0], "category_id": 2}, {"id": 9, "bbox": [75.0, 514.4, 1200.0, 1870.6], "category_id": 4}, {"id": 10, "bbox": [274.26, 123.74, 599.0, 102.1], "category_id": 2}, {"id": 11, "bbox": [440.69, 234.47, 332.29, 55.43], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [1, 10, 11], "products": [7]}], "corefs": [[0, 6], [1, 2], [7, 5]], "caption": "Table 2. Heteroannulation Reaction between Halogenated 4-Acetamido-3-iodopyridines 4 9 and Diphenylacetylene (2) ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 397, 122], "ImageBB": [71, 133, 407, 765]}, "diagram_type": "single"}, {"id": 167, "width": 1348, "height": 516, "file_name": "op500334b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [763.0, 5.0, 477.0, 277.0], "category_id": 1}, {"id": 1, "bbox": [108.0, 2.0, 313.0, 280.0], "category_id": 1}, {"id": 2, "bbox": [891.0, 251.0, 123.0, 73.0], "category_id": 3}, {"id": 3, "bbox": [157.0, 261.0, 125.0, 70.0], "category_id": 3}, {"id": 4, "bbox": [513.0, 44.0, 179.0, 112.0], "category_id": 2}, {"id": 5, "bbox": [554.0, 209.0, 65.0, 41.0], "category_id": 2}, {"id": 6, "bbox": [6.0, 352.0, 1337.0, 164.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [0]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Optimization of the Hurtley reaction of 6a, 6b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 463, 396, 478], "ImageBB": [82, 484, 419, 613]}, "diagram_type": "single"}, {"id": 81, "width": 1412, "height": 2660, "file_name": "ja075824w-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [309.2, 271.79, 184.1, 53.11], "category_id": 2}, {"id": 1, "bbox": [1026.15, 119.39, 289.47, 299.87], "category_id": 1}, {"id": 2, "bbox": [28.65, 119.4, 220.2, 299.86], "category_id": 1}, {"id": 3, "bbox": [619.27, 322.71, 265.81, 48.32], "category_id": 2}, {"id": 4, "bbox": [516.57, 169.66, 471.21, 107.44], "category_id": 2}, {"id": 5, "bbox": [291.7, 342.85, 210.76, 50.33], "category_id": 2}], "reactions": [{"reactants": [2, 0], "conditions": [4, 3], "products": [1]}], "corefs": [], "caption": "Figure 3. Effect of auxiliary base on the DMAP-catalyzed acetylation, isobutyrylation, and pivaloylation of l-menthol with acid anhydride. The reaction of l-menthol (5 mmol) was conducted with (RCO)2O (5.5 mmol) under solvent-free conditions or in heptane (5 mL): red squares, 1 (0.1 mol %) and i-Pr2NEt (1.1 equiv); green circles, 1 (0.1 mol %) without i-Pr2- NEt; blue triangles, i-Pr2NEt (1.1 equiv) without 1. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 704, 409, 779], "ImageBB": [74, 35, 427, 700]}, "diagram_type": "single"}, {"id": 505, "width": 1348, "height": 1012, "file_name": "ol051920v-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [668.0, 122.0, 183.0, 51.0], "category_id": 2}, {"id": 1, "bbox": [627.0, 52.0, 278.0, 54.0], "category_id": 2}, {"id": 2, "bbox": [464.0, 208.0, 54.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [211.0, 190.0, 25.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [1004.0, 185.0, 30.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [932.0, 0.0, 286.0, 182.0], "category_id": 1}, {"id": 6, "bbox": [143.0, 5.0, 227.0, 178.0], "category_id": 1}, {"id": 7, "bbox": [31.0, 301.0, 1294.0, 711.0], "category_id": 4}, {"id": 8, "bbox": [416.0, 50.0, 184.0, 153.0], "category_id": 1}], "reactions": [{"reactants": [6, 8], "conditions": [1, 0], "products": [5]}], "corefs": [[6, 3], [8, 2], [5, 4]], "caption": "Table 2. Reactions of Salicylic Aldehydes 1 (0.5 mmol) with 3-Methylpenta-3,4-dien-2-one 2a (1.0 mmol) in the Presence of DBU (10 mol %) in DMSO at Room Temperature ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 768, 120], "ImageBB": [439, 125, 776, 378]}, "diagram_type": "single"}, {"id": 246, "width": 1348, "height": 380, "file_name": "ol9005079-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [683.0, 4.0, 192.0, 92.0], "category_id": 2}, {"id": 1, "bbox": [526.0, 204.0, 56.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [104.0, 204.0, 31.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [5.0, 277.0, 1339.0, 97.0], "category_id": 2}, {"id": 4, "bbox": [685.0, 137.0, 159.0, 90.0], "category_id": 2}, {"id": 5, "bbox": [1134.0, 199.0, 35.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [348.0, 21.0, 266.0, 203.0], "category_id": 1}, {"id": 7, "bbox": [30.0, 41.0, 238.0, 166.0], "category_id": 1}, {"id": 8, "bbox": [927.0, 18.0, 395.0, 197.0], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [0, 4], "products": [8]}], "corefs": [[7, 2], [6, 1], [8, 5]], "caption": "Table 3. Proving the Scope of Indoles in the tBuTMG-Catalyzed Alkylation Process with 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 176, 670, 203], "ImageBB": [425, 212, 762, 307]}, "diagram_type": "single"}, {"id": 827, "width": 1352, "height": 968, "file_name": "jo4007046-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1106.0, 738.0, 33.6, 30.0], "category_id": 3}, {"id": 1, "bbox": [1217.8, 524.5, 92.9, 254.5], "category_id": 1}, {"id": 2, "bbox": [1072.0, 520.3, 97.8, 203.7], "category_id": 1}, {"id": 3, "bbox": [922.5, 519.0, 87.5, 200.6], "category_id": 1}, {"id": 4, "bbox": [668.0, 559.0, 241.9, 57.0], "category_id": 1}, {"id": 5, "bbox": [545.0, 523.8, 91.6, 196.5], "category_id": 1}, {"id": 6, "bbox": [635.0, 687.0, 20.0, 29.0], "category_id": 3}, {"id": 7, "bbox": [1310.0, 665.0, 19.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [946.0, 735.0, 37.0, 30.0], "category_id": 3}, {"id": 9, "bbox": [716.0, 648.0, 95.0, 31.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [4, 9], "products": [3, 2, 1]}], "corefs": [[5, 6], [3, 8], [2, 0], [1, 7]], "caption": "Figure 3. Ratio between the yield of 4-allyltoluene (6) and that of the other photoproducts (toluene 1a and 4-methylanisole 1b) from the irradiation of 4-chlorotoluene (1) in MeOH in the presence of an increasing amount of allyltrimethylsilane (ATMS). ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1004, 417, 1059], "ImageBB": [82, 743, 420, 985]}, "diagram_type": "single"}, {"id": 482, "width": 1344, "height": 1088, "file_name": "ol0616236-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [905.0, 231.8, 356.8, 92.4], "category_id": 3}, {"id": 1, "bbox": [95.0, 309.0, 416.5, 97.4], "category_id": 3}, {"id": 2, "bbox": [646.0, 0.0, 146.0, 134.6], "category_id": 1}, {"id": 3, "bbox": [926.9, 16.2, 270.8, 178.2], "category_id": 1}, {"id": 4, "bbox": [601.0, 159.0, 248.6, 99.8], "category_id": 2}, {"id": 5, "bbox": [83.9, 25.2, 399.5, 237.0], "category_id": 1}, {"id": 6, "bbox": [325.0, 226.0, 50.0, 52.0], "category_id": 3}, {"id": 7, "bbox": [2.0, 448.0, 1342.0, 640.0], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [2, 4], "products": [3]}], "corefs": [[5, 6], [3, 0]], "caption": "Table 2. Condensations of 2b and 2c with Aldehydes", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 580, 359, 593], "ImageBB": [74, 602, 410, 874]}, "diagram_type": "single"}, {"id": 139, "width": 1284, "height": 1228, "file_name": "op8001596-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [969.0, 0.0, 307.1, 229.7], "category_id": 1}, {"id": 1, "bbox": [362.0, 43.5, 494.0, 64.5], "category_id": 2}, {"id": 2, "bbox": [119.5, 251.2, 60.3, 69.8], "category_id": 3}, {"id": 3, "bbox": [1080.0, 296.9, 40.7, 63.1], "category_id": 3}, {"id": 4, "bbox": [363.91, 130.58, 392.09, 64.22], "category_id": 2}, {"id": 5, "bbox": [8.0, 373.0, 1276.0, 855.0], "category_id": 4}, {"id": 6, "bbox": [7.7, 23.4, 309.1, 178.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [1, 4], "products": [0]}], "corefs": [[6, 2], [0, 3]], "caption": "Figure 2. Decomposition profile of 2-lithio-3,4-difluoroanisole 6 (0.47 M). 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Overall comparison of productivities", "pdf": {"Page": 12, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 311, 60], "ImageBB": [58, 61, 411, 424]}, "diagram_type": "multiple"}, {"id": 381, "width": 1348, "height": 1760, "file_name": "ol071385u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [514.4, 135.1, 315.6, 68.9], "category_id": 2}, {"id": 1, "bbox": [196.58, 205.78, 66.64, 56.08], "category_id": 3}, {"id": 2, "bbox": [925.5, 0.0, 348.0, 283.6], "category_id": 1}, {"id": 3, "bbox": [1000.52, 197.6, 54.9, 63.6], "category_id": 3}, {"id": 4, "bbox": [6.0, 299.0, 1342.0, 1461.0], "category_id": 4}, {"id": 5, "bbox": [620.6, 52.0, 136.8, 57.1], "category_id": 2}, {"id": 6, "bbox": [85.6, 13.0, 368.7, 254.7], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 0], "products": [2]}], "corefs": [[6, 1], [2, 3]], "caption": "Table 2. Pd-Catalyzed Cyclization of Propargylic Compounds 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 356, 774, 369], "ImageBB": [439, 371, 776, 811]}, "diagram_type": "single"}, {"id": 164, "width": 1348, "height": 476, "file_name": "op500334b-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [97.0, 242.0, 38.0, 30.0], "category_id": 3}, {"id": 1, "bbox": [438.0, 33.0, 326.0, 99.8], "category_id": 2}, {"id": 2, "bbox": [24.0, 7.0, 349.0, 271.0], "category_id": 1}, {"id": 3, "bbox": [809.0, 15.0, 501.0, 273.0], "category_id": 1}, {"id": 4, "bbox": [560.0, 187.0, 59.0, 37.0], "category_id": 2}, {"id": 5, "bbox": [482.0, 235.0, 221.0, 29.0], "category_id": 2}, {"id": 6, "bbox": [920.0, 226.0, 36.0, 33.0], "category_id": 3}, {"id": 7, "bbox": [9.0, 311.0, 1334.0, 165.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [1, 4, 5], "products": [3]}], "corefs": [[2, 0], [3, 6]], "caption": "Table 4. Optimization of the base and copper catalyst of the Hurtley reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 125], "ImageBB": [449, 131, 786, 250]}, "diagram_type": "single"}, {"id": 1040, "width": 1324, "height": 1336, "file_name": "jo010170+-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.39, 499.91, 403.02, 203.85], "category_id": 1}, {"id": 1, "bbox": [880.88, 496.57, 367.59, 204.51], "category_id": 1}, {"id": 2, "bbox": [842.12, 0.0, 457.82, 245.28], "category_id": 1}, {"id": 3, "bbox": [1037.28, 255.3, 52.8, 42.78], "category_id": 3}, {"id": 4, "bbox": [880.88, 987.8, 342.86, 201.17], "category_id": 1}, {"id": 5, "bbox": [126.99, 49.46, 457.81, 202.5], "category_id": 1}, {"id": 6, "bbox": [189.81, 1010.52, 332.84, 205.18], "category_id": 1}, {"id": 7, "bbox": [926.33, 706.8, 296.08, 132.63], "category_id": 3}, {"id": 8, "bbox": [260.4, 255.2, 178.4, 101.0], "category_id": 3}, {"id": 9, "bbox": [214.54, 1226.9, 260.66, 101.08], "category_id": 3}, {"id": 10, "bbox": [6.02, 713.8, 760.57, 137.5], "category_id": 3}, {"id": 11, "bbox": [856.4, 1199.8, 401.0, 121.5], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 271, 636, 285], "ImageBB": [442, 291, 773, 625]}, "reactions": [{"reactants": [5], "conditions": [], "products": [0]}, {"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [0], "conditions": [], "products": [1]}, {"reactants": [0, 1], "conditions": [], "products": [6]}], "diagram_type": "graph"}, {"id": 116, "width": 1196, "height": 1184, "file_name": "op9802071-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 891.0, 246.0, 207.3], "category_id": 1}, {"id": 1, "bbox": [464.0, 165.4, 377.0, 332.6], "category_id": 1}, {"id": 2, "bbox": [660.0, 898.0, 349.0, 205.6], "category_id": 1}, {"id": 3, "bbox": [290.0, 834.0, 380.0, 157.4], "category_id": 2}, {"id": 4, "bbox": [694.0, 585.0, 65.9, 47.8], "category_id": 3}, {"id": 5, "bbox": [72.0, 94.0, 342.0, 442.0], "category_id": 1}, {"id": 6, "bbox": [266.0, 588.0, 59.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [60.0, 1114.0, 99.0, 50.0], "category_id": 3}, {"id": 8, "bbox": [831.0, 1139.0, 47.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3], "products": [2]}], "corefs": [[5, 6], [1, 4], [0, 7], [2, 8]], "caption": "Figure 1.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 432, 129, 446], "ImageBB": [128, 269, 427, 565]}, "diagram_type": "single"}, {"id": 323, "width": 1476, "height": 3744, "file_name": "ol301556a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [417.94, 241.88, 244.0, 50.0], "category_id": 2}, {"id": 1, "bbox": [1273.0, 235.0, 106.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [401.0, 16.0, 265.0, 85.0], "category_id": 2}, {"id": 3, "bbox": [152.0, 383.0, 1324.0, 1937.0], "category_id": 4}, {"id": 4, "bbox": [125.0, 2313.0, 1351.0, 1342.0], "category_id": 2}, {"id": 5, "bbox": [781.0, 237.0, 102.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [143.0, 39.0, 241.0, 149.8], "category_id": 1}, {"id": 7, "bbox": [1229.0, 31.0, 229.0, 198.9], "category_id": 1}, {"id": 8, "bbox": [706.9, 6.0, 234.1, 202.4], "category_id": 1}, {"id": 9, "bbox": [946.9, 134.0, 269.1, 85.0], "category_id": 2}, {"id": 10, "bbox": [947.0, 16.0, 273.0, 92.0], "category_id": 2}, {"id": 11, "bbox": [516.6, 128.8, 152.6, 115.2], "category_id": 1}, {"id": 12, "bbox": [727.0, 272.0, 201.0, 43.0], "category_id": 2}, {"id": 13, "bbox": [401.9, 130.3, 118.3, 96.92], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [2, 13, 11, 0], "products": [8]}, {"reactants": [8], "conditions": [10, 9], "products": [7]}], "corefs": [[8, 5], [7, 1]], "caption": "Table 2. 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