test1.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 922, "width": 2820, "height": 1656, "file_name": "acs.joc.5b02345-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [788.58, 479.51, 355.5, 301.8], "category_id": 1}, {"id": 1, "bbox": [1794.42, 318.73, 167.87, 108.6], "category_id": 1}, {"id": 2, "bbox": [1922.79, 1509.04, 110.04, 107.18], "category_id": 3}, {"id": 3, "bbox": [1750.69, 954.78, 379.48, 538.74], "category_id": 1}, {"id": 4, "bbox": [411.93, 816.57, 179.16, 56.41], "category_id": 2}, {"id": 5, "bbox": [1660.9, 491.01, 308.38, 274.34], "category_id": 1}, {"id": 6, "bbox": [1279.51, 593.74, 167.87, 62.06], "category_id": 2}, {"id": 7, "bbox": [1374.03, 1516.09, 124.14, 104.36], "category_id": 3}, {"id": 8, "bbox": [743.9, 1133.89, 350.81, 355.4], "category_id": 1}, {"id": 9, "bbox": [636.23, 1514.5, 112.85, 101.72], "category_id": 3}, {"id": 10, "bbox": [1639.24, 4.23, 316.0, 263.73], "category_id": 1}, {"id": 11, "bbox": [924.01, 954.78, 356.91, 538.74], "category_id": 1}, {"id": 12, "bbox": [455.66, 1506.22, 101.57, 107.18], "category_id": 3}, {"id": 13, "bbox": [753.32, 67.7, 321.64, 208.72], "category_id": 1}, {"id": 14, "bbox": [1220.26, 671.31, 347.03, 57.82], "category_id": 2}, {"id": 15, "bbox": [1121.51, 52.18, 469.77, 101.54], "category_id": 2}, {"id": 16, "bbox": [2210.58, 1513.27, 112.85, 107.18], "category_id": 3}, {"id": 17, "bbox": [411.93, 1139.53, 440.14, 353.99], "category_id": 1}, {"id": 18, "bbox": [1639.24, 1513.27, 122.73, 107.18], "category_id": 3}, {"id": 19, "bbox": [1121.51, 173.47, 325.87, 94.49], "category_id": 2}, {"id": 20, "bbox": [1221.67, 885.68, 344.21, 610.66], "category_id": 1}, {"id": 21, "bbox": [1794.42, 713.62, 42.32, 50.77], "category_id": 3}, {"id": 22, "bbox": [1121.51, 1513.27, 117.09, 107.18], "category_id": 3}, {"id": 23, "bbox": [898.62, 1513.27, 118.5, 102.95], "category_id": 3}, {"id": 24, "bbox": [1503.81, 954.78, 338.57, 538.74], "category_id": 1}, {"id": 25, "bbox": [2049.75, 884.27, 371.02, 609.25], "category_id": 1}, {"id": 26, "bbox": [1754.92, 215.78, 63.48, 52.18], "category_id": 3}], "caption": "Scheme 1. Synthetic Route of A\u2212A\u2212\u03c0\u2212D Bipyridine Chromophores", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 468, 110], "ImageBB": [82, 116, 787, 530]}, "reactions": [{"reactants": [13], "conditions": [15, 19], "products": [10]}, {"reactants": [10], "conditions": [1], "products": [5]}, {"reactants": [5], "conditions": [6, 14], "products": [0]}], "diagram_type": "tree"}, {"id": 1076, "width": 1352, "height": 1256, "file_name": "jo500412w-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [50.05, 0.0, 361.16, 287.52], "category_id": 1}, {"id": 1, "bbox": [526.87, 896.4, 363.87, 254.38], "category_id": 1}, {"id": 2, "bbox": [1220.11, 332.85, 131.89, 64.27], "category_id": 2}, {"id": 3, "bbox": [789.96, 1153.48, 45.99, 52.77], "category_id": 3}, {"id": 4, "bbox": [931.99, 533.78, 360.49, 174.12], "category_id": 1}, {"id": 5, "bbox": [0.0, 483.04, 377.4, 282.79], "category_id": 1}, {"id": 6, "bbox": [1074.08, 707.23, 108.56, 46.74], "category_id": 2}, {"id": 7, "bbox": [189.0, 690.65, 110.07, 49.75], "category_id": 2}, {"id": 8, "bbox": [143.77, 954.51, 54.28, 52.78], "category_id": 2}, {"id": 9, "bbox": [1114.79, 752.47, 25.63, 42.22], "category_id": 3}, {"id": 10, "bbox": [65.36, 428.29, 123.64, 51.26], "category_id": 2}, {"id": 11, "bbox": [1162.63, 973.53, 104.83, 55.47], "category_id": 1}, {"id": 12, "bbox": [261.74, 223.25, 63.58, 49.39], "category_id": 3}, {"id": 13, "bbox": [651.99, 1157.54, 119.04, 50.74], "category_id": 2}, {"id": 14, "bbox": [541.75, 194.16, 331.4, 65.63], "category_id": 2}, {"id": 15, "bbox": [1113.93, 194.84, 67.63, 56.83], "category_id": 3}, {"id": 16, "bbox": [714.89, 97.42, 157.59, 62.92], "category_id": 2}, {"id": 17, "bbox": [938.08, 0.0, 359.81, 214.46], "category_id": 1}, {"id": 18, "bbox": [577.59, 0.0, 258.36, 65.62], "category_id": 2}, {"id": 19, "bbox": [204.93, 748.92, 62.22, 43.97], "category_id": 3}], "caption": "Scheme 5. Proposed Mechanism for the Synthesis of 3a from 1a ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 405, 125], "ImageBB": [82, 131, 420, 445]}, "reactions": [{"reactants": [1], "conditions": [], "products": [5, 8]}, {"reactants": [5], "conditions": [10], "products": [0, 14]}, {"reactants": [18], "conditions": [16], "products": [14]}, {"reactants": [17, 14], "conditions": [], "products": [2, 4]}, {"reactants": [4, 6], "conditions": [11], "products": [1]}], "diagram_type": "graph"}, {"id": 606, "width": 1352, "height": 608, "file_name": "acs.oprd.5b00379-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 1.0, 461.0, 450.2], "category_id": 1}, {"id": 1, "bbox": [472.5, 400.0, 89.9, 42.0], "category_id": 2}, {"id": 2, "bbox": [1040.0, 470.0, 36.0, 39.0], "category_id": 3}, {"id": 3, "bbox": [245.0, 470.0, 40.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [5.0, 535.0, 1341.0, 73.0], "category_id": 4}, {"id": 5, "bbox": [505.1, 142.1, 187.8, 94.8], "category_id": 1}, {"id": 6, "bbox": [722.4, 0.0, 629.6, 484.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 5], "products": [6]}], "corefs": [[0, 3], [6, 2]], "caption": "Table 1. Solvent Evaluation for Succinate Amidationa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 385, 110], "ImageBB": [82, 116, 420, 268]}, "diagram_type": "single"}, {"id": 551, "width": 1352, "height": 1152, "file_name": "acs.orglett.5b02709-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [355.0, 105.0, 158.0, 42.0], "category_id": 2}, {"id": 1, "bbox": [851.0, 146.0, 132.0, 85.0], "category_id": 2}, {"id": 2, "bbox": [9.0, 258.0, 1337.0, 411.0], "category_id": 4}, {"id": 3, "bbox": [250.0, 1029.0, 402.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [5.0, 0.0, 344.0, 233.0], "category_id": 1}, {"id": 5, "bbox": [214.0, 188.0, 49.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [711.0, 180.0, 55.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [998.0, 3.0, 338.0, 231.0], "category_id": 1}, {"id": 8, "bbox": [810.0, 711.0, 351.0, 282.3], "category_id": 1}, {"id": 9, "bbox": [253.0, 735.0, 341.0, 250.6], "category_id": 1}, {"id": 10, "bbox": [857.0, 79.0, 148.0, 53.0], "category_id": 2}, {"id": 11, "bbox": [1197.0, 186.6, 53.0, 49.4], "category_id": 3}, {"id": 12, "bbox": [784.0, 1027.7, 427.0, 39.3], "category_id": 3}, {"id": 13, "bbox": [486.0, 1.0, 353.0, 222.9], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [13]}, {"reactants": [13], "conditions": [10, 1], "products": [7]}], "corefs": [[4, 5], [13, 6], [7, 11], [9, 3], [8, 12]], "caption": "Table 1. Oxidation of the Phenylsul\ufb01de and Its Elimination", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 110], "ImageBB": [82, 116, 420, 404]}, "diagram_type": "single"}, {"id": 1013, "width": 1344, "height": 560, "file_name": "ja9810742-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [93.45, 243.57, 107.58, 41.04], "category_id": 2}, {"id": 1, "bbox": [607.79, 20.86, 254.14, 149.84], "category_id": 1}, {"id": 2, "bbox": [630.65, 178.3, 231.28, 41.72], "category_id": 3}, {"id": 3, "bbox": [617.88, 230.78, 262.21, 45.76], "category_id": 2}, {"id": 4, "bbox": [8.74, 6.06, 190.27, 158.11], "category_id": 1}, {"id": 5, "bbox": [494.84, 507.99, 32.94, 37.01], "category_id": 3}, {"id": 6, "bbox": [439.71, 113.04, 125.05, 51.81], "category_id": 2}, {"id": 7, "bbox": [24.2, 349.2, 264.9, 158.12], "category_id": 1}, {"id": 8, "bbox": [76.65, 176.28, 55.8, 39.03], "category_id": 3}, {"id": 9, "bbox": [119.0, 509.34, 30.26, 36.33], "category_id": 3}, {"id": 10, "bbox": [991.02, 345.17, 350.29, 156.1], "category_id": 1}, {"id": 11, "bbox": [471.31, 10.77, 50.42, 36.33], "category_id": 3}, {"id": 12, "bbox": [353.65, 393.61, 308.6, 53.83], "category_id": 1}, {"id": 13, "bbox": [301.88, 236.17, 124.38, 48.44], "category_id": 2}, {"id": 14, "bbox": [258.18, 54.5, 154.63, 46.43], "category_id": 2}, {"id": 15, "bbox": [1056.91, 509.34, 197.67, 44.41], "category_id": 3}, {"id": 16, "bbox": [714.02, 368.72, 106.23, 108.32], "category_id": 1}, {"id": 17, "bbox": [870.68, 366.7, 51.09, 41.04], "category_id": 2}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 156, 495, 170], "ImageBB": [440, 174, 776, 314]}, "reactions": [{"reactants": [4, 14], "conditions": [11], "products": [1]}, {"reactants": [7], "conditions": [], "products": [12, 16]}, {"reactants": [12, 16], "conditions": [], "products": [7]}, {"reactants": [12, 16], "conditions": [17], "products": [10]}], "diagram_type": "tree"}, {"id": 961, "width": 1256, "height": 484, "file_name": "ja012253d-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [971.37, 5.65, 284.63, 155.1], "category_id": 1}, {"id": 1, "bbox": [1081.33, 440.17, 46.49, 43.83], "category_id": 3}, {"id": 2, "bbox": [588.73, 155.72, 50.89, 43.33], "category_id": 3}, {"id": 3, "bbox": [437.93, 344.1, 368.83, 50.86], "category_id": 2}, {"id": 4, "bbox": [293.62, 13.25, 42.63, 40.73], "category_id": 2}, {"id": 5, "bbox": [115.61, 164.51, 47.75, 48.98], "category_id": 3}, {"id": 6, "bbox": [5.7, 14.8, 286.6, 151.6], "category_id": 1}, {"id": 7, "bbox": [987.08, 282.56, 265.15, 149.44], "category_id": 1}, {"id": 8, "bbox": [805.5, 19.47, 146.4, 54.62], "category_id": 2}, {"id": 9, "bbox": [480.66, 5.65, 306.62, 148.19], "category_id": 1}], "caption": "Scheme 9", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 361, 491, 373], "ImageBB": [451, 372, 765, 493]}, "reactions": [{"reactants": [6, 4], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [8], "products": [0]}, {"reactants": [9], "conditions": [], "products": [3]}, {"reactants": [0], "conditions": [], "products": [7]}], "diagram_type": "tree"}, {"id": 260, "width": 1348, "height": 272, "file_name": "ol801791g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [256.0, 152.6, 203.0, 46.8], "category_id": 2}, {"id": 1, "bbox": [29.8, 9.3, 196.7, 149.2], "category_id": 1}, {"id": 2, "bbox": [709.7, 8.4, 180.9, 152.7], "category_id": 1}, {"id": 3, "bbox": [454.7, 8.7, 224.4, 151.9], "category_id": 1}, {"id": 4, "bbox": [273.9, 11.0, 155.1, 118.4], "category_id": 2}, {"id": 5, "bbox": [1018.0, 196.0, 216.0, 41.0], "category_id": 2}, {"id": 6, "bbox": [772.0, 196.0, 44.0, 36.0], "category_id": 3}, {"id": 7, "bbox": [931.8, 0.9, 389.2, 191.1], "category_id": 1}, {"id": 8, "bbox": [65.86, 195.03, 105.44, 38.77], "category_id": 3}, {"id": 9, "bbox": [527.6, 196.0, 49.4, 38.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 0], "products": [3, 2, 7]}], "corefs": [[1, 8], [3, 9], [2, 6], [7, 5]], "caption": "Table 2. Dynamic Kinetic Resolution of 6a (trans) + 12 (cis)a", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 71, 752, 88], "ImageBB": [425, 97, 762, 165]}, "diagram_type": "single"}, {"id": 174, "width": 1640, "height": 828, "file_name": "op060249m-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [575.0, 107.0, 336.6, 144.3], "category_id": 1}, {"id": 1, "bbox": [222.0, 580.1, 258.0, 130.9], "category_id": 1}, {"id": 2, "bbox": [1249.7, 509.9, 333.7, 249.7], "category_id": 1}, {"id": 3, "bbox": [1.0, 111.1, 337.2, 140.0], "category_id": 1}, {"id": 4, "bbox": [1425.0, 768.0, 42.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [1437.0, 343.0, 37.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [423.0, 131.0, 109.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [873.0, 788.0, 51.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [977.42, 44.51, 138.2, 120.17], "category_id": 1}, {"id": 9, "bbox": [1265.0, 69.0, 330.0, 259.0], "category_id": 1}, {"id": 10, "bbox": [712.0, 461.0, 366.0, 325.0], "category_id": 1}, {"id": 11, "bbox": [103.0, 270.0, 117.0, 49.0], "category_id": 3}, {"id": 12, "bbox": [638.0, 277.0, 209.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [6], "products": [0]}, {"reactants": [0], "conditions": [8], "products": [9]}, {"reactants": [9], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [1]}], "corefs": [[3, 11], [0, 12], [9, 5], [2, 4], [10, 7]], "caption": "Figure 3. Proposed mechanism for the reaction of (S)-propylene oxide with TEPA anions.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 264, 571, 278], "ImageBB": [220, 54, 630, 261]}, "diagram_type": "multiple"}, {"id": 297, "width": 1344, "height": 1048, "file_name": "ol400025a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [705.8, 8.1, 247.4, 198.8], "category_id": 1}, {"id": 1, "bbox": [329.1, 44.2, 244.8, 147.3], "category_id": 1}, {"id": 2, "bbox": [128.2, 93.9, 165.1, 101.6], "category_id": 1}, {"id": 3, "bbox": [976.5, 1.4, 245.1, 196.8], "category_id": 1}, {"id": 4, "bbox": [171.0, 214.0, 37.0, 26.0], "category_id": 3}, {"id": 5, "bbox": [1044.0, 204.0, 56.0, 27.0], "category_id": 3}, {"id": 6, "bbox": [775.0, 213.0, 54.0, 27.0], "category_id": 3}, {"id": 7, "bbox": [384.0, 214.0, 36.0, 29.0], "category_id": 3}, {"id": 8, "bbox": [581.0, 101.0, 101.0, 32.0], "category_id": 2}, {"id": 9, "bbox": [593.0, 143.0, 84.0, 31.0], "category_id": 2}, {"id": 10, "bbox": [4.0, 306.0, 1327.0, 742.0], "category_id": 4}], "reactions": [{"reactants": [2, 1], "conditions": [8, 9], "products": [0, 3]}], "corefs": [[2, 4], [1, 7], [0, 6], [3, 5]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 322, 101], "ImageBB": [71, 112, 407, 374]}, "diagram_type": "single"}, {"id": 740, "width": 1352, "height": 1084, "file_name": "ol0157003-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [144.3, 194.7, 306.6, 172.5], "category_id": 1}, {"id": 1, "bbox": [1044.0, 382.0, 33.0, 41.3], "category_id": 3}, {"id": 2, "bbox": [106.2, 522.8, 376.7, 213.0], "category_id": 1}, {"id": 3, "bbox": [871.0, 516.0, 372.9, 222.2], "category_id": 1}, {"id": 4, "bbox": [273.91, 381.81, 31.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [929.0, 156.0, 283.0, 46.0], "category_id": 2}, {"id": 6, "bbox": [169.0, 147.0, 287.0, 44.0], "category_id": 2}, {"id": 7, "bbox": [272.85, 761.43, 852.1, 314.5], "category_id": 4}, {"id": 8, "bbox": [1073.0, 440.0, 157.0, 71.0], "category_id": 2}, {"id": 9, "bbox": [913.0, 196.0, 319.0, 175.0], "category_id": 1}, {"id": 10, "bbox": [299.8, 445.0, 160.6, 68.1], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [10], "products": [2]}, {"reactants": [9], "conditions": [8], "products": [3]}], "corefs": [[0, 4], [9, 1]], "caption": "Figure 1. Acetal substrates.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 553, 222, 566], "ImageBB": [73, 269, 411, 540]}, "diagram_type": "tree"}, {"id": 35, "width": 1336, "height": 844, "file_name": "ja511335v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.84, 347.54, 1322.99, 463.75], "category_id": 4}, {"id": 1, "bbox": [978.52, 5.58, 290.6, 251.39], "category_id": 1}, {"id": 2, "bbox": [1103.76, 286.55, 77.14, 36.85], "category_id": 3}, {"id": 3, "bbox": [162.84, 285.46, 74.96, 39.03], "category_id": 3}, {"id": 4, "bbox": [388.27, 140.62, 475.73, 138.13], "category_id": 2}, {"id": 5, "bbox": [393.71, 39.34, 465.93, 86.95], "category_id": 2}, {"id": 6, "bbox": [63.73, 18.65, 211.1, 247.03], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 4], "products": [1]}], "corefs": [[6, 3], [1, 2]], "caption": "Table 1. (3 + 1 + 2) Cycloadditions Using a Neutral Rh(I)- System ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 686, 417, 716], "ImageBB": [84, 723, 418, 934]}, "diagram_type": "single"}, {"id": 69, "width": 1344, "height": 1332, "file_name": "ja208286b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [523.14, 256.74, 247.36, 173.92], "category_id": 2}, {"id": 1, "bbox": [4.02, 627.29, 1337.34, 307.46], "category_id": 4}, {"id": 2, "bbox": [207.66, 355.22, 27.04, 33.71], "category_id": 3}, {"id": 3, "bbox": [968.8, 71.46, 270.74, 504.42], "category_id": 1}, {"id": 4, "bbox": [484.74, 3.02, 305.79, 195.63], "category_id": 1}, {"id": 5, "bbox": [105.84, 71.46, 255.72, 275.74], "category_id": 1}, {"id": 6, "bbox": [695.06, 156.58, 48.74, 37.06], "category_id": 3}, {"id": 7, "bbox": [1167.44, 355.22, 48.73, 38.72], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 0], "products": [3]}], "corefs": [[5, 2], [4, 6], [3, 7]], "caption": "Table 1. Optimization Studies for the Ruthenium-Catalyzed Meta Sulfonation of 2-Phenylpyridine (1)a ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 404, 122], "ImageBB": [71, 133, 407, 466]}, "diagram_type": "single"}, {"id": 299, "width": 1476, "height": 1984, "file_name": "ol303482k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [450.0, 871.0, 248.0, 230.0], "category_id": 1}, {"id": 1, "bbox": [456.0, 408.0, 234.0, 225.0], "category_id": 1}, {"id": 2, "bbox": [605.0, 50.0, 172.0, 185.0], "category_id": 1}, {"id": 3, "bbox": [170.0, 2.0, 380.0, 274.0], "category_id": 1}, {"id": 4, "bbox": [802.0, 60.0, 115.0, 65.0], "category_id": 2}, {"id": 5, "bbox": [341.0, 247.0, 65.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [668.0, 221.0, 44.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [1110.0, 235.0, 59.0, 59.0], "category_id": 3}, {"id": 8, "bbox": [909.0, 0.0, 536.0, 276.0], "category_id": 1}, {"id": 9, "bbox": [548.0, 635.0, 77.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [538.0, 749.0, 85.0, 59.0], "category_id": 3}, {"id": 11, "bbox": [538.0, 1102.0, 85.0, 44.0], "category_id": 3}, {"id": 12, "bbox": [542.0, 1366.0, 79.0, 45.0], "category_id": 3}, {"id": 13, "bbox": [499.0, 1658.0, 87.0, 65.0], "category_id": 3}, {"id": 14, "bbox": [434.0, 1406.0, 288.0, 358.0], "category_id": 1}, {"id": 15, "bbox": [393.0, 1146.0, 370.0, 220.0], "category_id": 1}, {"id": 16, "bbox": [193.0, 350.8, 1203.0, 1486.2], "category_id": 4}], "reactions": [{"reactants": [3, 2], "conditions": [4], "products": [8]}], "corefs": [[3, 5], [2, 6], [8, 7], [1, 9], [0, 11], [15, 12], [14, 13]], "caption": "Table 1. Alkylation of Bromide 12 with a Chiral Propionate 7", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 539, 765, 552], "ImageBB": [404, 564, 773, 1060]}, "diagram_type": "single"}, {"id": 97, "width": 1356, "height": 2000, "file_name": "ja030125e-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [697.06, 1188.53, 93.23, 44.33], "category_id": 2}, {"id": 1, "bbox": [30.9, 1799.42, 205.6, 52.28], "category_id": 3}, {"id": 2, "bbox": [219.76, 1876.24, 213.33, 119.03], "category_id": 1}, {"id": 3, "bbox": [30.67, 1902.91, 152.72, 58.18], "category_id": 3}, {"id": 4, "bbox": [701.74, 575.7, 123.64, 41.96], "category_id": 2}, {"id": 5, "bbox": [37.42, 1097.53, 58.18, 43.87], "category_id": 3}, {"id": 6, "bbox": [7.01, 1242.56, 1283.87, 479.19], "category_id": 1}, {"id": 7, "bbox": [95.89, 617.77, 1227.74, 453.69], "category_id": 1}, {"id": 8, "bbox": [35.08, 5.1, 1311.92, 455.83], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [4], "products": [7]}, {"reactants": [7], "conditions": [0], "products": [6]}], "corefs": [[7, 5], [6, 1], [6, 3]], "caption": "Figure 4. Synthetic scheme for polyamide-acridine conjugates: (i) 4:1 piperidine-DMF, 25 \u00b0C (30 min); (ii) Boc2O, DIEA, NMP, 55 \u00b0C (30 min); (iii) 2,2\u2032-(ethylenedioxy)-bis(ethylamine), 55 \u00b0C (18 h); (iv) 9-chloroacridine or N-(2-(dimethylamino)ethyl)-9-chloroacridine-4-carboxamide, phenol, DIEA, 100 \u00b0C (1 h); (v) 80% TFA/DCM, 0.4 M PhSH, 25 \u00b0C (15 min). ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 568, 409, 631], "ImageBB": [73, 64, 412, 564]}, "diagram_type": "tree"}, {"id": 538, "width": 1348, "height": 1052, "file_name": "acs.orglett.6b01181-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [477.0, 251.0, 63.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [198.0, 19.0, 211.0, 227.0], "category_id": 1}, {"id": 2, "bbox": [584.0, 138.0, 213.0, 96.0], "category_id": 2}, {"id": 3, "bbox": [12.0, 319.0, 1336.0, 733.0], "category_id": 4}, {"id": 4, "bbox": [957.0, 251.0, 79.4, 45.9], "category_id": 3}, {"id": 5, "bbox": [481.0, 26.0, 61.8, 218.0], "category_id": 1}, {"id": 6, "bbox": [845.2, 3.0, 309.8, 245.0], "category_id": 1}, {"id": 7, "bbox": [567.3, 25.0, 239.7, 103.0], "category_id": 2}, {"id": 8, "bbox": [227.0, 248.0, 63.0, 47.4], "category_id": 3}], "reactions": [{"reactants": [1, 5], "conditions": [7, 2], "products": [6]}], "corefs": [[1, 8], [5, 0], [6, 4]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 349, 110], "ImageBB": [82, 116, 419, 379]}, "diagram_type": "single"}, {"id": 957, "width": 1328, "height": 260, "file_name": "ja0056062-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [638.42, 60.45, 87.03, 36.53], "category_id": 2}, {"id": 1, "bbox": [963.28, 128.87, 99.65, 72.41], "category_id": 2}, {"id": 2, "bbox": [239.16, 61.78, 134.19, 44.5], "category_id": 2}, {"id": 3, "bbox": [953.98, 66.43, 91.68, 33.88], "category_id": 2}, {"id": 4, "bbox": [1066.25, 8.64, 261.75, 195.96], "category_id": 1}, {"id": 5, "bbox": [393.28, 94.33, 204.62, 43.18], "category_id": 2}, {"id": 6, "bbox": [1158.6, 214.56, 111.6, 40.52], "category_id": 3}, {"id": 7, "bbox": [40.52, 201.28, 166.75, 41.85], "category_id": 3}, {"id": 8, "bbox": [253.77, 123.56, 102.31, 34.54], "category_id": 2}, {"id": 9, "bbox": [0.0, 2.66, 207.94, 192.04], "category_id": 1}, {"id": 10, "bbox": [745.38, 95.66, 189.34, 41.18], "category_id": 2}, {"id": 11, "bbox": [638.42, 127.54, 78.39, 45.17], "category_id": 2}], "caption": "Scheme 1. Reactions with Other Bisphosphines", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 65, 696, 79], "ImageBB": [442, 83, 774, 148]}, "reactions": [{"reactants": [10], "conditions": [3, 1], "products": [4]}, {"reactants": [10], "conditions": [0, 11], "products": [5]}, {"reactants": [5], "conditions": [2, 8], "products": [9]}], "diagram_type": "single"}, {"id": 624, "width": 1752, "height": 4044, "file_name": "ol501514b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1213.0, 3252.0, 39.0, 50.0], "category_id": 3}, {"id": 1, "bbox": [709.0, 3263.0, 37.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [310.0, 3261.0, 73.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [198.4, 231.0, 1178.6, 1924.0], "category_id": 4}, {"id": 4, "bbox": [445.03, 33.05, 290.97, 150.35], "category_id": 1}, {"id": 5, "bbox": [834.0, 3031.0, 36.0, 58.0], "category_id": 3}, {"id": 6, "bbox": [864.0, 2768.0, 40.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [501.0, 2770.0, 35.0, 45.0], "category_id": 3}, {"id": 8, "bbox": [402.0, 2342.0, 256.0, 170.0], "category_id": 1}, {"id": 9, "bbox": [1211.0, 164.0, 41.0, 45.0], "category_id": 3}, {"id": 10, "bbox": [599.0, 164.0, 43.0, 51.0], "category_id": 3}, {"id": 11, "bbox": [229.0, 161.0, 41.0, 59.0], "category_id": 3}, {"id": 12, "bbox": [766.0, 50.0, 373.0, 68.0], "category_id": 2}, {"id": 13, "bbox": [379.0, 3034.0, 41.0, 49.0], "category_id": 3}, {"id": 14, "bbox": [130.57, 18.95, 247.93, 153.0], "category_id": 1}, {"id": 15, "bbox": [1093.0, 3081.0, 289.0, 229.0], "category_id": 1}, {"id": 16, "bbox": [589.0, 3087.0, 272.0, 225.0], "category_id": 1}, {"id": 17, "bbox": [203.0, 3070.0, 285.0, 242.0], "category_id": 1}, {"id": 18, "bbox": [229.0, 2830.0, 313.0, 240.0], "category_id": 1}, {"id": 19, "bbox": [737.0, 2843.0, 270.0, 221.0], "category_id": 1}, {"id": 20, "bbox": [366.0, 2566.0, 294.0, 232.0], "category_id": 1}, {"id": 21, "bbox": [1144.0, 0.0, 291.5, 199.0], "category_id": 1}, {"id": 22, "bbox": [850.0, 126.0, 253.0, 57.0], "category_id": 2}, {"id": 23, "bbox": [1104.0, 2305.0, 259.0, 255.0], "category_id": 1}, {"id": 24, "bbox": [761.0, 2373.0, 236.0, 125.0], "category_id": 1}, {"id": 25, "bbox": [748.0, 2543.0, 300.0, 231.0], "category_id": 1}, {"id": 26, "bbox": [656.0, 2390.0, 90.0, 60.0], "category_id": 2}, {"id": 27, "bbox": [994.0, 2354.0, 105.0, 96.0], "category_id": 2}, {"id": 28, "bbox": [1234.0, 2789.0, 116.0, 69.0], "category_id": 2}, {"id": 29, "bbox": [889.0, 3136.0, 202.0, 69.0], "category_id": 2}, {"id": 30, "bbox": [598.0, 2913.0, 131.0, 73.0], "category_id": 2}, {"id": 31, "bbox": [568.0, 2980.0, 165.0, 54.0], "category_id": 2}, {"id": 32, "bbox": [216.0, 2395.0, 62.0, 55.0], "category_id": 3}, {"id": 33, "bbox": [512.0, 2465.0, 36.0, 50.0], "category_id": 3}, {"id": 34, "bbox": [859.0, 2470.0, 47.0, 43.0], "category_id": 3}, {"id": 35, "bbox": [1226.0, 2504.0, 34.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [14, 4], "conditions": [12, 22], "products": [21]}, {"reactants": [32], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [32]}, {"reactants": [8], "conditions": [26], "products": [24]}, {"reactants": [24], "conditions": [27], "products": [23]}, {"reactants": [24], "conditions": [], "products": [25]}, {"reactants": [25], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [], "products": [25]}, {"reactants": [20], "conditions": [], "products": [19]}, {"reactants": [19], "conditions": [], "products": [20]}, {"reactants": [19], "conditions": [], "products": [15]}, {"reactants": [23], "conditions": [28], "products": [15]}, {"reactants": [19], "conditions": [30, 31], "products": [18]}, {"reactants": [15], "conditions": [29], "products": [16]}, {"reactants": [16], "conditions": [], "products": [17]}], "corefs": [[14, 11], [4, 10], [21, 9], [8, 33], [24, 34], [23, 35], [20, 7], [25, 6], [18, 13], [19, 5], [17, 2], [16, 1], [15, 0]], "caption": "Table 2. Reaction Scopea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 591, 110], "ImageBB": [421, 116, 859, 1127]}, "diagram_type": "graph"}, {"id": 1276, "width": 2096, "height": 1076, "file_name": "op100103v-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1142.89, 199.31, 306.17, 133.22], "category_id": 2}, {"id": 1, "bbox": [572.49, 469.95, 135.26, 66.09], "category_id": 2}, {"id": 2, "bbox": [551.52, 720.66, 139.46, 47.2], "category_id": 2}, {"id": 3, "bbox": [1515.12, 530.79, 40.89, 50.35], "category_id": 3}, {"id": 4, "bbox": [1625.21, 332.53, 470.79, 675.55], "category_id": 1}, {"id": 5, "bbox": [549.43, 602.12, 141.55, 89.17], "category_id": 2}, {"id": 6, "bbox": [48.23, 467.85, 470.79, 398.62], "category_id": 1}, {"id": 7, "bbox": [1314.85, 729.05, 241.16, 109.1], "category_id": 2}, {"id": 8, "bbox": [1142.89, 111.19, 355.45, 55.6], "category_id": 2}, {"id": 9, "bbox": [1018.12, 900.04, 61.86, 48.25], "category_id": 3}, {"id": 10, "bbox": [1342.11, 420.65, 187.69, 265.39], "category_id": 1}, {"id": 11, "bbox": [310.36, 114.34, 331.34, 52.45], "category_id": 2}, {"id": 12, "bbox": [254.79, 903.18, 53.48, 44.06], "category_id": 3}, {"id": 13, "bbox": [791.64, 510.86, 482.32, 309.45], "category_id": 1}, {"id": 14, "bbox": [837.77, 371.34, 56.62, 49.31], "category_id": 3}, {"id": 15, "bbox": [687.83, 32.52, 376.42, 336.73], "category_id": 1}, {"id": 16, "bbox": [100.66, 371.34, 57.67, 46.16], "category_id": 3}, {"id": 17, "bbox": [310.36, 201.41, 299.88, 96.5], "category_id": 2}, {"id": 18, "bbox": [0.0, 62.94, 303.02, 283.23], "category_id": 1}, {"id": 19, "bbox": [1864.28, 1029.06, 39.84, 45.11], "category_id": 3}, {"id": 20, "bbox": [1387.2, 369.25, 127.92, 51.4], "category_id": 2}, {"id": 21, "bbox": [378.52, 0.0, 128.97, 52.45], "category_id": 2}, {"id": 22, "bbox": [1241.45, 0.0, 247.45, 50.35], "category_id": 2}], "caption": "Scheme 7. Pilot scale-up of stage two, five-step synthesis of imidazo[5,1-c][1,4]benzoxazine-3-carboxylate 9", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 643, 60], "ImageBB": [148, 65, 672, 334]}, "reactions": [{"reactants": [18], "conditions": [11, 17], "products": [15]}, {"reactants": [15], "conditions": [8, 0], "products": [6]}, {"reactants": [6], "conditions": [5, 2], "products": [13]}, {"reactants": [13, 10], "conditions": [7], "products": [4]}], "diagram_type": "multiple"}, {"id": 1312, "width": 2820, "height": 1140, "file_name": "op3001788-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1770.44, 700.95, 481.05, 282.08], "category_id": 1}, {"id": 1, "bbox": [928.24, 4.23, 126.06, 211.56], "category_id": 1}, {"id": 2, "bbox": [1453.03, 445.68, 163.64, 101.54], "category_id": 1}, {"id": 3, "bbox": [1929.84, 349.77, 80.42, 57.83], "category_id": 3}, {"id": 4, "bbox": [675.73, 538.76, 338.57, 121.29], "category_id": 2}, {"id": 5, "bbox": [1189.22, 52.18, 385.13, 279.26], "category_id": 1}, {"id": 6, "bbox": [1279.51, 339.9, 272.27, 63.47], "category_id": 3}, {"id": 7, "bbox": [877.46, 241.17, 252.51, 56.42], "category_id": 2}, {"id": 8, "bbox": [1189.22, 700.95, 495.16, 286.31], "category_id": 1}, {"id": 9, "bbox": [1647.7, 157.96, 95.93, 50.77], "category_id": 2}, {"id": 10, "bbox": [1836.74, 71.93, 462.71, 277.84], "category_id": 1}, {"id": 11, "bbox": [553.0, 339.9, 263.8, 66.29], "category_id": 3}, {"id": 12, "bbox": [545.94, 700.95, 292.02, 253.87], "category_id": 1}, {"id": 13, "bbox": [571.34, 1021.11, 221.48, 67.7], "category_id": 3}, {"id": 14, "bbox": [499.39, 60.65, 321.64, 246.81], "category_id": 1}, {"id": 15, "bbox": [1454.44, 585.3, 794.22, 57.83], "category_id": 2}, {"id": 16, "bbox": [1416.35, 1030.98, 749.08, 67.7], "category_id": 3}, {"id": 17, "bbox": [1615.26, 479.53, 40.91, 53.59], "category_id": 3}, {"id": 18, "bbox": [1647.7, 246.81, 119.91, 47.96], "category_id": 2}, {"id": 19, "bbox": [1454.44, 658.64, 286.37, 59.24], "category_id": 2}, {"id": 20, "bbox": [1416.35, 589.54, 46.55, 46.54], "category_id": 3}, {"id": 21, "bbox": [1041.1, 104.37, 50.79, 56.41], "category_id": 3}], "caption": "Scheme 2. Improved Process for the Preparation of Glycopyrrolate 6", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 407, 472, 422], "ImageBB": [82, 116, 787, 401]}, "reactions": [{"reactants": [12], "conditions": [4], "products": [14]}, {"reactants": [14, 1], "conditions": [7], "products": [5]}, {"reactants": [5], "conditions": [9], "products": [10]}, {"reactants": [10], "conditions": [18], "products": [5]}, {"reactants": [5, 2], "conditions": [15, 19], "products": [8, 0]}], "diagram_type": "tree"}, {"id": 242, "width": 1352, "height": 1136, "file_name": "ol901760a-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [450.0, 928.3, 121.1, 47.7], "category_id": 1}, {"id": 1, "bbox": [1022.0, 742.0, 89.0, 66.0], "category_id": 1}, {"id": 2, "bbox": [767.9, 921.8, 113.1, 50.2], "category_id": 2}, {"id": 3, "bbox": [912.1, 490.1, 153.0, 244.0], "category_id": 1}, {"id": 4, "bbox": [781.54, 553.46, 112.0, 56.0], "category_id": 1}, {"id": 5, "bbox": [243.2, 492.6, 221.7, 270.2], "category_id": 1}, {"id": 6, "bbox": [855.5, 117.5, 263.5, 306.3], "category_id": 1}, {"id": 7, "bbox": [566.7, 855.1, 162.4, 276.5], "category_id": 1}, {"id": 8, "bbox": [289.8, 856.4, 150.2, 273.7], "category_id": 1}, {"id": 9, "bbox": [912.2, 845.3, 151.2, 290.7], "category_id": 1}, {"id": 10, "bbox": [727.0, 749.0, 281.0, 82.0], "category_id": 2}, {"id": 11, "bbox": [500.0, 549.0, 66.0, 56.0], "category_id": 2}, {"id": 12, "bbox": [236.0, 492.0, 45.0, 45.0], "category_id": 3}, {"id": 13, "bbox": [232.0, 124.0, 51.0, 39.0], "category_id": 3}, {"id": 14, "bbox": [607.2, 493.0, 158.6, 244.9], "category_id": 1}, {"id": 15, "bbox": [600.0, 267.0, 186.3, 54.1], "category_id": 2}, {"id": 16, "bbox": [589.6, 168.8, 208.4, 86.2], "category_id": 2}, {"id": 17, "bbox": [284.0, 118.8, 268.1, 295.2], "category_id": 1}], "reactions": [{"reactants": [17], "conditions": [16, 15], "products": [6]}, {"reactants": [5], "conditions": [11], "products": [14]}, {"reactants": [14], "conditions": [4], "products": [3]}, {"reactants": [3], "conditions": [10, 1], "products": [9]}, {"reactants": [9], "conditions": [2], "products": [7]}, {"reactants": [7], "conditions": [0], "products": [8]}], "corefs": [[17, 13], [5, 12]], "caption": "Figure 1. Preliminary studies by Hayford and co-workers. (A) Preparation of indolizines from (Z)-2-pyridine- and quinoline- silylated vinylacetylenes (numbering relative to the indolizine structure). (B) Proposed mechanism for the formation of indolizines from enynylpyridines. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 458, 393, 528], "ImageBB": [58, 167, 396, 451]}, "diagram_type": "tree"}, {"id": 569, "width": 1348, "height": 364, "file_name": "acs.orglett.5b01044-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 286.0, 1347.0, 78.0], "category_id": 4}, {"id": 1, "bbox": [1019.0, 27.0, 244.0, 200.0], "category_id": 1}, {"id": 2, "bbox": [713.0, 25.0, 244.0, 204.0], "category_id": 1}, {"id": 3, "bbox": [423.0, 131.0, 190.0, 86.0], "category_id": 2}, {"id": 4, "bbox": [383.0, 0.0, 270.0, 127.0], "category_id": 2}, {"id": 5, "bbox": [84.0, 27.0, 242.0, 202.0], "category_id": 1}, {"id": 6, "bbox": [182.0, 213.0, 121.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [799.0, 208.0, 123.0, 60.0], "category_id": 3}, {"id": 8, "bbox": [1099.0, 208.0, 122.0, 60.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 3], "products": [2, 1]}], "corefs": [[5, 6], [2, 7], [1, 8]], "caption": "Table 2. Enantioselective Acetylation of rac-15 Catalyzed by (S)-1a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 595, 782, 629], "ImageBB": [449, 635, 786, 726]}, "diagram_type": "single"}, {"id": 1170, "width": 1352, "height": 1100, "file_name": "ol1009703-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [829.19, 2.03, 327.35, 228.97], "category_id": 1}, {"id": 1, "bbox": [917.72, 676.06, 54.14, 44.9], "category_id": 2}, {"id": 2, "bbox": [911.7, 320.45, 61.55, 47.32], "category_id": 2}, {"id": 3, "bbox": [1000.3, 672.67, 184.64, 78.42], "category_id": 2}, {"id": 4, "bbox": [516.05, 680.11, 307.05, 87.21], "category_id": 2}, {"id": 5, "bbox": [351.7, 993.8, 37.19, 45.29], "category_id": 3}, {"id": 6, "bbox": [198.17, 8.79, 320.58, 217.01], "category_id": 1}, {"id": 7, "bbox": [333.43, 600.33, 46.0, 41.24], "category_id": 3}, {"id": 8, "bbox": [539.72, 466.48, 263.77, 47.32], "category_id": 2}, {"id": 9, "bbox": [52.75, 665.24, 298.27, 83.15], "category_id": 2}, {"id": 10, "bbox": [336.82, 190.65, 36.52, 45.29], "category_id": 3}, {"id": 11, "bbox": [971.22, 994.47, 37.2, 45.97], "category_id": 3}, {"id": 12, "bbox": [66.96, 249.46, 282.71, 46.65], "category_id": 2}, {"id": 13, "bbox": [520.1, 128.45, 247.54, 45.97], "category_id": 2}, {"id": 14, "bbox": [183.29, 774.08, 323.29, 208.9], "category_id": 1}, {"id": 15, "bbox": [572.86, 58.14, 145.41, 48.68], "category_id": 2}, {"id": 16, "bbox": [973.25, 202.14, 35.17, 43.94], "category_id": 3}, {"id": 17, "bbox": [382.13, 254.87, 60.2, 46.65], "category_id": 2}, {"id": 18, "bbox": [974.5, 602.11, 33.02, 39.62], "category_id": 3}, {"id": 19, "bbox": [632.48, 534.77, 60.75, 48.86], "category_id": 2}, {"id": 20, "bbox": [165.03, 381.97, 321.26, 211.6], "category_id": 1}, {"id": 21, "bbox": [1000.3, 311.66, 294.89, 83.83], "category_id": 2}, {"id": 22, "bbox": [376.3, 668.14, 54.14, 44.9], "category_id": 2}, {"id": 23, "bbox": [846.78, 768.67, 280.0, 230.33], "category_id": 1}, {"id": 24, "bbox": [847.45, 401.58, 285.42, 234.12], "category_id": 1}], "caption": "Scheme 2. Pathways Available to the Organopalladium Species            Where Alternatives Are Lettered A-E ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [62, 487, 391, 515], "ImageBB": [58, 524, 396, 799]}, "reactions": [{"reactants": [6], "conditions": [15, 13], "products": [0]}, {"reactants": [6], "conditions": [12, 17], "products": [20]}, {"reactants": [20], "conditions": [8, 19], "products": [24]}, {"reactants": [24], "conditions": [2, 21], "products": [0]}, {"reactants": [20], "conditions": [9, 22], "products": [14]}, {"reactants": [24], "conditions": [1, 3], "products": [23]}], "diagram_type": "graph"}, {"id": 598, "width": 1352, "height": 1928, "file_name": "acs.oprd.6b00117-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [565.0, 22.0, 407.0, 77.0], "category_id": 2}, {"id": 1, "bbox": [350.0, 32.0, 126.6, 177.0], "category_id": 1}, {"id": 2, "bbox": [3.0, 44.8, 274.0, 172.2], "category_id": 1}, {"id": 3, "bbox": [127.0, 224.0, 197.0, 42.5], "category_id": 3}, {"id": 4, "bbox": [0.0, 286.0, 1352.0, 1642.0], "category_id": 4}, {"id": 5, "bbox": [326.0, 224.0, 289.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [659.0, 141.0, 210.0, 95.0], "category_id": 2}, {"id": 7, "bbox": [1044.0, 0.0, 308.0, 225.0], "category_id": 1}, {"id": 8, "bbox": [1213.6, 219.2, 92.2, 41.6], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [0, 6], "products": [7]}], "corefs": [[2, 3], [1, 5], [7, 8]], "caption": "Table 1. Screening of Heterocyclic N-Oxides", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 697, 111], "ImageBB": [448, 116, 786, 598]}, "diagram_type": "single"}, {"id": 1056, "width": 1356, "height": 796, "file_name": "jo200480h-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [20.35, 58.37, 291.01, 250.47], "category_id": 1}, {"id": 1, "bbox": [868.27, 136.43, 82.76, 51.59], "category_id": 2}, {"id": 2, "bbox": [342.56, 84.17, 221.82, 107.24], "category_id": 2}, {"id": 3, "bbox": [1047.36, 422.2, 269.3, 251.82], "category_id": 1}, {"id": 4, "bbox": [18.32, 696.42, 68.51, 54.98], "category_id": 3}, {"id": 5, "bbox": [0.0, 458.17, 221.14, 264.72], "category_id": 1}, {"id": 6, "bbox": [15.3, 0.0, 60.67, 54.98], "category_id": 3}, {"id": 7, "bbox": [241.9, 509.4, 110.1, 44.7], "category_id": 1}, {"id": 8, "bbox": [841.14, 212.46, 142.45, 52.26], "category_id": 1}, {"id": 9, "bbox": [1046.0, 337.35, 310.0, 63.8], "category_id": 2}, {"id": 10, "bbox": [363.59, 534.87, 219.1, 55.66], "category_id": 2}, {"id": 11, "bbox": [50.2, 312.91, 300.5, 109.29], "category_id": 2}, {"id": 12, "bbox": [1203.37, 696.42, 57.66, 52.27], "category_id": 3}, {"id": 13, "bbox": [1045.32, 61.77, 271.34, 253.86], "category_id": 1}, {"id": 14, "bbox": [363.59, 595.96, 134.99, 48.19], "category_id": 2}, {"id": 15, "bbox": [525.03, 249.11, 314.75, 250.47], "category_id": 1}, {"id": 16, "bbox": [1203.37, 6.11, 61.73, 50.23], "category_id": 3}, {"id": 17, "bbox": [342.56, 200.92, 153.98, 52.94], "category_id": 2}, {"id": 18, "bbox": [242.32, 561.08, 109.42, 42.95], "category_id": 1}, {"id": 19, "bbox": [242.32, 615.28, 109.42, 43.97], "category_id": 1}, {"id": 20, "bbox": [876.35, 541.65, 75.68, 48.06], "category_id": 2}, {"id": 21, "bbox": [814.99, 599.94, 206.57, 48.06], "category_id": 1}], "caption": "Scheme 1. Recent Methods for 5-Azaindole Synthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 370, 107], "ImageBB": [71, 117, 410, 316]}, "reactions": [{"reactants": [0], "conditions": [2, 17], "products": [15]}, {"reactants": [13], "conditions": [1, 8], "products": [15]}, {"reactants": [5, 7, 18, 19], "conditions": [10, 14], "products": [15]}, {"reactants": [3], "conditions": [20, 21], "products": [15]}], "diagram_type": "tree"}, {"id": 1288, "width": 1764, "height": 860, "file_name": "op200112g-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [577.12, 65.29, 310.62, 237.33], "category_id": 1}, {"id": 1, "bbox": [1088.93, 577.01, 362.69, 220.56], "category_id": 1}, {"id": 2, "bbox": [1535.45, 532.89, 228.55, 269.98], "category_id": 1}, {"id": 3, "bbox": [1342.35, 95.45, 109.09, 73.17], "category_id": 2}, {"id": 4, "bbox": [895.37, 425.37, 85.14, 49.22], "category_id": 1}, {"id": 5, "bbox": [1032.39, 99.44, 74.5, 42.57], "category_id": 1}, {"id": 6, "bbox": [1158.65, 3.53, 244.15, 243.07], "category_id": 1}, {"id": 7, "bbox": [377.68, 367.91, 307.82, 240.86], "category_id": 1}, {"id": 8, "bbox": [0.0, 61.76, 305.32, 221.45], "category_id": 1}], "caption": "Scheme 10. Proposed mechanism for Select\ufb02uor-assisted selective r-iodinationa", "pdf": {"Page": 9, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 208, 517, 230], "ImageBB": [202, 239, 643, 454]}, "reactions": [{"reactants": [8], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [8]}, {"reactants": [0, 5, 6, 3], "conditions": [], "products": [4, 1, 2]}, {"reactants": [8], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [8]}, {"reactants": [7, 4], "conditions": [], "products": [1]}], "diagram_type": "graph"}, {"id": 743, "width": 1348, "height": 1100, "file_name": "ol006129v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [561.0, 32.0, 243.0, 86.0], "category_id": 2}, {"id": 1, "bbox": [1059.0, 212.0, 59.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [11.0, 286.0, 1332.0, 814.0], "category_id": 4}, {"id": 3, "bbox": [628.0, 133.0, 89.0, 45.0], "category_id": 2}, {"id": 4, "bbox": [885.0, 1.0, 407.0, 221.0], "category_id": 1}, {"id": 5, "bbox": [64.0, 21.0, 409.0, 181.0], "category_id": 1}, {"id": 6, "bbox": [227.0, 212.0, 53.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [0, 3], "products": [4]}], "corefs": [[5, 6], [4, 1]], "caption": "Table 1. Oxygen Atom Transfer from Oxidoiodane 2 to Unsaturated Diketone 3aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 268, 737, 296], "ImageBB": [439, 306, 776, 581]}, "diagram_type": "single"}, {"id": 78, "width": 2816, "height": 1200, "file_name": "ja1048847-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.42, 591.62, 2807.38, 608.38], "category_id": 4}, {"id": 1, "bbox": [737.09, 5.48, 269.58, 212.24], "category_id": 1}, {"id": 2, "bbox": [1452.77, 16.1, 290.82, 184.64], "category_id": 1}, {"id": 3, "bbox": [1784.06, 16.1, 292.95, 184.64], "category_id": 1}, {"id": 4, "bbox": [766.82, 234.84, 212.24, 80.57], "category_id": 3}, {"id": 5, "bbox": [1450.64, 307.04, 292.95, 212.25], "category_id": 1}, {"id": 6, "bbox": [1057.76, 28.84, 356.66, 91.2], "category_id": 2}, {"id": 7, "bbox": [1057.76, 160.51, 303.57, 89.07], "category_id": 2}, {"id": 8, "bbox": [1550.46, 236.96, 74.2, 42.35], "category_id": 3}, {"id": 9, "bbox": [1881.75, 239.08, 74.21, 40.23], "category_id": 3}, {"id": 10, "bbox": [1550.76, 541.68, 48.81, 36.18], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [6, 7], "products": [2, 3, 5]}], "corefs": [[1, 4], [2, 8], [3, 9], [5, 10]], "caption": "Table 3. Synthesis of Indanes: Study of C(sp3)-H Arylation Parameters", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 56, 418, 69], "ImageBB": [58, 78, 762, 378]}, "diagram_type": "single"}, {"id": 490, "width": 1352, "height": 2088, "file_name": "ol060473w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 329.0, 1344.0, 1759.0], "category_id": 4}, {"id": 1, "bbox": [26.4, 34.4, 320.0, 205.6], "category_id": 1}, {"id": 2, "bbox": [387.0, 8.4, 276.4, 288.6], "category_id": 1}, {"id": 3, "bbox": [868.0, 2.0, 482.0, 300.0], "category_id": 1}, {"id": 4, "bbox": [706.0, 181.0, 121.0, 48.0], "category_id": 2}, {"id": 5, "bbox": [691.0, 87.0, 140.0, 72.0], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [5, 4], "products": [3]}], "corefs": [], "caption": "Table 1. Direct Benzamidation of Quinoline N-oxides with Benzoyl Isocyanate ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 386, 104], "ImageBB": [73, 105, 411, 627]}, "diagram_type": "single"}, {"id": 794, "width": 1348, "height": 376, "file_name": "jo501216h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.0, 257.0, 1339.0, 117.0], "category_id": 2}, {"id": 1, "bbox": [332.0, 142.0, 381.0, 48.0], "category_id": 2}, {"id": 2, "bbox": [339.0, 3.0, 386.0, 92.0], "category_id": 2}, {"id": 3, "bbox": [837.0, 187.0, 108.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [35.0, 191.0, 108.0, 39.0], "category_id": 3}, {"id": 5, "bbox": [805.0, 38.0, 257.0, 132.0], "category_id": 1}, {"id": 6, "bbox": [1091.0, 87.0, 241.0, 48.0], "category_id": 2}, {"id": 7, "bbox": [20.0, 4.0, 262.0, 174.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [2, 1], "products": [5]}], "corefs": [[7, 4], [5, 3]], "caption": "Table 3. 1-Iodo-4-nitrobenzene-Catalyzed Synthesis of Benzothiazoles with Oxonea ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 388, 125], "ImageBB": [82, 131, 419, 225]}, "diagram_type": "single"}, {"id": 1053, "width": 1344, "height": 368, "file_name": "jo102193q-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [224.56, 123.71, 40.34, 59.16], "category_id": 3}, {"id": 1, "bbox": [1064.98, 121.69, 59.17, 56.47], "category_id": 3}, {"id": 2, "bbox": [350.29, 0.0, 378.52, 299.85], "category_id": 1}, {"id": 3, "bbox": [685.11, 2.69, 367.77, 293.13], "category_id": 1}, {"id": 4, "bbox": [482.74, 273.63, 49.08, 49.75], "category_id": 3}, {"id": 5, "bbox": [819.58, 272.29, 47.73, 50.42], "category_id": 3}, {"id": 6, "bbox": [283.79, 82.09, 65.88, 69.94], "category_id": 2}], "caption": "Scheme 3. Formation of 10", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 227, 107], "ImageBB": [71, 117, 407, 209]}, "reactions": [{"reactants": [0], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [1]}], "diagram_type": "single"}, {"id": 1026, "width": 1016, "height": 1032, "file_name": "jo000585f-Scheme-c19.png", "license": 0, "bboxes": [{"id": 0, "bbox": [759.61, 252.45, 136.84, 59.37], "category_id": 3}, {"id": 1, "bbox": [13.94, 721.21, 357.34, 232.84], "category_id": 1}, {"id": 2, "bbox": [13.94, 512.13, 156.47, 59.37], "category_id": 2}, {"id": 3, "bbox": [92.43, 585.95, 107.41, 55.24], "category_id": 2}, {"id": 4, "bbox": [761.67, 540.52, 112.58, 52.66], "category_id": 2}, {"id": 5, "bbox": [436.87, 182.76, 104.82, 48.52], "category_id": 2}, {"id": 6, "bbox": [13.94, 443.47, 260.26, 62.98], "category_id": 2}, {"id": 7, "bbox": [0.0, 0.0, 289.69, 221.99], "category_id": 1}, {"id": 8, "bbox": [310.35, 361.38, 291.24, 230.25], "category_id": 1}, {"id": 9, "bbox": [57.84, 244.19, 136.84, 58.85], "category_id": 3}, {"id": 10, "bbox": [613.47, 446.56, 365.6, 69.7], "category_id": 2}, {"id": 11, "bbox": [310.35, 90.35, 324.29, 62.46], "category_id": 2}, {"id": 12, "bbox": [356.31, 606.09, 135.81, 57.82], "category_id": 3}, {"id": 13, "bbox": [690.93, 6.71, 291.24, 230.25], "category_id": 1}, {"id": 14, "bbox": [55.77, 972.63, 221.01, 59.37], "category_id": 3}], "caption": "Scheme 19", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [570, 524, 641, 538], "ImageBB": [480, 545, 734, 803]}, "reactions": [{"reactants": [7], "conditions": [11], "products": [13]}, {"reactants": [13], "conditions": [6, 2], "products": [8]}, {"reactants": [8], "conditions": [10], "products": [1]}], "diagram_type": "multiple"}, {"id": 812, "width": 1348, "height": 1236, "file_name": "jo4026034-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [916.0, 4.0, 324.0, 224.0], "category_id": 1}, {"id": 1, "bbox": [9.0, 307.0, 1339.0, 929.0], "category_id": 4}, {"id": 2, "bbox": [1065.0, 237.0, 57.0, 61.0], "category_id": 3}, {"id": 3, "bbox": [559.0, 178.0, 54.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [760.0, 74.0, 143.0, 55.0], "category_id": 2}, {"id": 5, "bbox": [113.6, 6.0, 289.4, 272.7], "category_id": 1}, {"id": 6, "bbox": [461.2, 49.0, 271.8, 125.0], "category_id": 1}], "reactions": [{"reactants": [5, 6], "conditions": [4], "products": [0]}], "corefs": [[6, 3], [0, 2]], "caption": "Table 1. Optimization of Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 647, 343, 662], "ImageBB": [82, 668, 419, 977]}, "diagram_type": "single"}, {"id": 209, "width": 1352, "height": 788, "file_name": "op0340816-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [368.4, 567.6, 91.4, 41.1], "category_id": 2}, {"id": 1, "bbox": [331.62, 665.34, 118.88, 45.36], "category_id": 2}, {"id": 2, "bbox": [6.2, 303.7, 226.7, 187.5], "category_id": 1}, {"id": 3, "bbox": [772.39, 418.34, 205.01, 47.06], "category_id": 2}, {"id": 4, "bbox": [758.51, 578.28, 104.99, 42.02], "category_id": 2}, {"id": 5, "bbox": [315.0, 31.19, 93.3, 44.7], "category_id": 2}, {"id": 6, "bbox": [8.5, 538.0, 253.6, 183.9], "category_id": 1}, {"id": 7, "bbox": [1008.61, 609.22, 338.09, 48.18], "category_id": 2}, {"id": 8, "bbox": [549.28, 668.22, 71.42, 40.58], "category_id": 2}, {"id": 9, "bbox": [282.89, 131.45, 125.61, 49.35], "category_id": 2}, {"id": 10, "bbox": [42.4, 6.0, 245.6, 221.4], "category_id": 1}, {"id": 11, "bbox": [225.66, 432.28, 130.64, 47.22], "category_id": 2}, {"id": 12, "bbox": [265.51, 333.6, 87.59, 44.51], "category_id": 2}, {"id": 13, "bbox": [543.0, 84.2, 200.2, 44.8], "category_id": 2}, {"id": 14, "bbox": [527.0, 486.34, 45.9, 50.4], "category_id": 3}, {"id": 15, "bbox": [448.39, 310.94, 285.21, 180.06], "category_id": 1}, {"id": 16, "bbox": [738.94, 650.17, 193.46, 51.33], "category_id": 2}, {"id": 17, "bbox": [30.0, 748.0, 199.0, 40.0], "category_id": 2}, {"id": 18, "bbox": [786.0, 342.0, 117.0, 52.0], "category_id": 2}], "reactions": [{"reactants": [10], "conditions": [5, 9], "products": [13]}, {"reactants": [2], "conditions": [12, 11], "products": [15]}, {"reactants": [15], "conditions": [18, 3], "products": [6]}, {"reactants": [6], "conditions": [0, 1, 8, 4, 16], "products": [7]}], "corefs": [[15, 14]], "caption": "Figure 3. Attempts to extend the methodology to tetrachlo- robenzenes. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 253, 409, 281], "ImageBB": [74, 53, 412, 250]}, "diagram_type": "multiple"}, {"id": 588, "width": 1356, "height": 476, "file_name": "acs.oprd.6b00180-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1227.96, 208.04, 32.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [365.2, 78.6, 246.78, 132.6], "category_id": 1}, {"id": 2, "bbox": [5.0, 64.5, 261.98, 150.61], "category_id": 1}, {"id": 3, "bbox": [1012.0, 7.2, 340.0, 217.8], "category_id": 1}, {"id": 4, "bbox": [131.95, 207.0, 35.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [661.04, 83.0, 276.0, 47.77], "category_id": 2}, {"id": 6, "bbox": [684.0, 150.0, 217.0, 50.0], "category_id": 2}, {"id": 7, "bbox": [24.0, 291.0, 1319.0, 177.0], "category_id": 4}], "reactions": [{"reactants": [2, 1], "conditions": [5, 6], "products": [3]}], "corefs": [[2, 4], [3, 0]], "caption": "Table 5. Screening Conditions for 100\u2212750 mL Scale Pd(OAc)2 Catalyzed Suzuki Reaction of 4-Bromoaniline (2) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 140], "ImageBB": [448, 146, 787, 265]}, "diagram_type": "single"}, {"id": 1032, "width": 1028, "height": 876, "file_name": "jo0014156-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [289.01, 309.04, 32.4, 39.08], "category_id": 3}, {"id": 1, "bbox": [0.0, 6.68, 363.07, 342.98], "category_id": 1}, {"id": 2, "bbox": [5.14, 538.38, 404.21, 270.99], "category_id": 1}, {"id": 3, "bbox": [698.88, 0.0, 305.46, 339.89], "category_id": 1}, {"id": 4, "bbox": [715.85, 534.78, 312.15, 338.87], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [209, 331, 272, 345], "ImageBB": [114, 350, 371, 569]}, "reactions": [{"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [2]}], "diagram_type": "tree"}, {"id": 1263, "width": 1184, "height": 588, "file_name": "op050182n-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [183.02, 209.67, 40.28, 43.24], "category_id": 3}, {"id": 1, "bbox": [763.47, 197.83, 40.28, 47.38], "category_id": 3}, {"id": 2, "bbox": [531.29, 447.77, 107.8, 50.35], "category_id": 2}, {"id": 3, "bbox": [346.49, 41.46, 192.5, 58.64], "category_id": 2}, {"id": 4, "bbox": [738.59, 286.67, 432.97, 216.78], "category_id": 1}, {"id": 5, "bbox": [14.22, 280.75, 435.93, 307.25], "category_id": 1}, {"id": 6, "bbox": [332.87, 135.64, 207.9, 52.12], "category_id": 2}, {"id": 7, "bbox": [999.2, 50.94, 184.8, 56.27], "category_id": 2}, {"id": 8, "bbox": [174.73, 496.93, 39.09, 47.39], "category_id": 3}, {"id": 9, "bbox": [543.73, 2.37, 434.15, 213.22], "category_id": 1}, {"id": 10, "bbox": [0.0, 2.37, 336.42, 215.0], "category_id": 1}, {"id": 11, "bbox": [999.2, 126.75, 163.48, 91.81], "category_id": 2}, {"id": 12, "bbox": [530.11, 360.71, 111.94, 56.26], "category_id": 2}, {"id": 13, "bbox": [999.2, 501.67, 40.28, 46.2], "category_id": 3}], "caption": "Scheme 2. Synthesis of 5 using diastereoselective reduction of 7 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 254, 406, 282], "ImageBB": [94, 286, 390, 433]}, "reactions": [{"reactants": [10], "conditions": [3, 6], "products": [9]}, {"reactants": [9], "conditions": [7, 11], "products": [5]}, {"reactants": [5], "conditions": [12, 2], "products": [4]}], "diagram_type": "multiple"}, {"id": 159, "width": 2820, "height": 844, "file_name": "op700060e-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [932.0, 63.0, 206.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [2.0, 262.0, 2818.0, 582.0], "category_id": 4}, {"id": 2, "bbox": [1758.0, 7.0, 341.0, 199.0], "category_id": 1}, {"id": 3, "bbox": [725.0, 24.0, 194.0, 159.0], "category_id": 1}, {"id": 4, "bbox": [967.0, 136.0, 141.0, 46.0], "category_id": 2}, {"id": 5, "bbox": [1593.0, 72.0, 106.0, 47.0], "category_id": 2}, {"id": 6, "bbox": [1611.0, 133.0, 77.0, 45.0], "category_id": 2}, {"id": 7, "bbox": [1903.0, 208.0, 29.0, 41.0], "category_id": 3}, {"id": 8, "bbox": [1337.0, 188.0, 32.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [1194.6, 9.5, 329.5, 156.3], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [0, 4], "products": [9]}, {"reactants": [9], "conditions": [5, 6], "products": [2]}], "corefs": [[9, 8], [2, 7]], "caption": "Table 2. Optimized oxidation/SNAr synthesis of 2-phenylsulfonyl pyridine, 1", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 276, 475, 290], "ImageBB": [58, 304, 763, 515]}, "diagram_type": "single"}, {"id": 1253, "width": 968, "height": 2124, "file_name": "op049953y-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [310.01, 392.07, 626.38, 72.26], "category_id": 2}, {"id": 1, "bbox": [419.36, 700.21, 122.09, 59.5], "category_id": 2}, {"id": 2, "bbox": [86.0, 1466.29, 882.0, 310.26], "category_id": 1}, {"id": 3, "bbox": [356.7, 1391.92, 113.8, 51.68], "category_id": 2}, {"id": 4, "bbox": [0.0, 1887.06, 968.0, 160.44], "category_id": 1}, {"id": 5, "bbox": [561.62, 578.02, 49.9, 49.94], "category_id": 3}, {"id": 6, "bbox": [313.19, 464.33, 587.11, 158.31], "category_id": 1}, {"id": 7, "bbox": [457.58, 2079.37, 57.33, 44.63], "category_id": 3}, {"id": 8, "bbox": [343.98, 1197.47, 267.54, 185.95], "category_id": 2}, {"id": 9, "bbox": [86.0, 0.0, 475.62, 272.01], "category_id": 1}, {"id": 10, "bbox": [312.13, 631.14, 345.04, 56.32], "category_id": 2}, {"id": 11, "bbox": [86.0, 807.52, 882.0, 313.45], "category_id": 1}, {"id": 12, "bbox": [248.43, 285.82, 45.65, 49.94], "category_id": 3}, {"id": 13, "bbox": [274.97, 1807.37, 35.04, 45.68], "category_id": 3}], "caption": "Scheme 2. Initial route to 1 via the amide intermediate derived from 2 ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 752, 81], "ImageBB": [487, 85, 729, 616]}, "reactions": [{"reactants": [9, 6], "conditions": [0, 10, 1], "products": [11]}, {"reactants": [11], "conditions": [8, 3], "products": [2]}], "diagram_type": "tree"}, {"id": 513, "width": 1272, "height": 1976, "file_name": "ol051342i-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1024.0, 225.0, 53.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [13.0, 0.0, 395.0, 214.0], "category_id": 1}, {"id": 2, "bbox": [29.0, 219.0, 409.0, 65.3], "category_id": 3}, {"id": 3, "bbox": [473.0, 2.0, 275.0, 77.3], "category_id": 2}, {"id": 4, "bbox": [874.0, 8.0, 398.0, 200.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 324.0, 1272.0, 1647.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [3], "products": [4]}], "corefs": [[1, 2], [4, 0]], "caption": "Table 2. Synthesis of 1-Substituted Tetrahydro-\u03b2-carbolines", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 757, 89], "ImageBB": [449, 97, 767, 591]}, "diagram_type": "single"}, {"id": 849, "width": 2808, "height": 852, "file_name": "jo201056f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [754.0, 404.0, 679.1, 314.1], "category_id": 4}, {"id": 1, "bbox": [2.0, 751.0, 2806.0, 101.0], "category_id": 4}, {"id": 2, "bbox": [1666.66, 235.34, 108.0, 55.06], "category_id": 3}, {"id": 3, "bbox": [883.13, 305.22, 105.88, 59.3], "category_id": 3}, {"id": 4, "bbox": [1380.78, 262.87, 95.29, 57.18], "category_id": 2}, {"id": 5, "bbox": [1664.54, 622.87, 103.77, 59.29], "category_id": 3}, {"id": 6, "bbox": [1589.2, 384.2, 461.2, 328.2], "category_id": 1}, {"id": 7, "bbox": [1583.7, 6.0, 465.5, 319.8], "category_id": 1}, {"id": 8, "bbox": [807.9, 57.8, 462.7, 332.0], "category_id": 1}, {"id": 9, "bbox": [1304.0, 142.4, 167.0, 57.6], "category_id": 2}, {"id": 10, "bbox": [1300.0, 264.0, 56.3, 56.0], "category_id": 2}], "reactions": [{"reactants": [8, 10], "conditions": [9], "products": [4, 7, 6]}], "corefs": [[8, 3], [7, 2], [6, 5]], "caption": "Table 2. Yields of BBE-Catalyzed Oxidative Kinetic Resolution via C C Bond Formation", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 650, 568, 665], "ImageBB": [71, 675, 773, 888]}, "diagram_type": "tree"}, {"id": 526, "width": 1352, "height": 564, "file_name": "jo0109321-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [898.0, 55.0, 47.0, 37.0], "category_id": 2}, {"id": 1, "bbox": [10.0, 78.0, 513.0, 68.0], "category_id": 1}, {"id": 2, "bbox": [552.0, 127.0, 252.0, 38.0], "category_id": 2}, {"id": 3, "bbox": [592.0, 53.0, 139.0, 47.0], "category_id": 2}, {"id": 4, "bbox": [569.0, 4.0, 175.0, 41.0], "category_id": 2}, {"id": 5, "bbox": [1005.0, 8.0, 240.0, 43.0], "category_id": 2}, {"id": 6, "bbox": [1003.0, 78.0, 342.0, 43.0], "category_id": 2}, {"id": 7, "bbox": [8.0, 229.0, 1334.0, 335.0], "category_id": 4}, {"id": 8, "bbox": [1004.0, 160.0, 309.0, 45.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [4, 3, 2, 0], "products": [5, 6, 8]}], "corefs": [], "caption": "Table 1. Effect of Solvent on the Regioselectivity of the  RhCl3\u201anH2O-Promoted Hydroboration of 1-Octene with                        BH3-THFa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [443, 64, 771, 102], "ImageBB": [439, 111, 777, 252]}, "diagram_type": "single"}, {"id": 62, "width": 1340, "height": 2028, "file_name": "ja312277g-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [558.2, 3.45, 366.35, 84.25], "category_id": 2}, {"id": 1, "bbox": [1030.44, 22.91, 235.46, 185.06], "category_id": 1}, {"id": 2, "bbox": [2.65, 232.91, 1332.88, 1792.35], "category_id": 4}, {"id": 3, "bbox": [73.95, 40.15, 178.92, 165.72], "category_id": 1}, {"id": 4, "bbox": [372.34, 79.76, 118.19, 53.04], "category_id": 1}, {"id": 5, "bbox": [345.07, 147.6, 163.84, 40.03], "category_id": 2}, {"id": 6, "bbox": [577.66, 121.96, 346.0, 82.47], "category_id": 2}], "reactions": [{"reactants": [3, 4], "conditions": [0, 6], "products": [1]}], "corefs": [], "caption": "Table 3. Substrate Scope of the C\u2212H Alkylation Reaction", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 408, 111], "ImageBB": [83, 116, 418, 623]}, "diagram_type": "multiple"}, {"id": 809, "width": 2740, "height": 588, "file_name": "jo4027148-Figure-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1322.0, 22.0, 328.0, 206.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 67.0, 496.0, 429.0], "category_id": 1}, {"id": 2, "bbox": [1365.0, 317.0, 252.0, 101.0], "category_id": 2}, {"id": 3, "bbox": [2121.0, 304.0, 326.0, 166.0], "category_id": 2}, {"id": 4, "bbox": [2630.0, 389.0, 48.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [1833.0, 490.0, 65.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [1038.0, 538.0, 56.0, 37.0], "category_id": 3}, {"id": 7, "bbox": [117.0, 523.0, 255.0, 64.0], "category_id": 3}, {"id": 8, "bbox": [1686.0, 76.0, 373.0, 373.0], "category_id": 1}, {"id": 9, "bbox": [2510.3, 173.3, 229.7, 184.6], "category_id": 1}, {"id": 10, "bbox": [786.7, 41.0, 513.3, 466.0], "category_id": 1}, {"id": 11, "bbox": [2164.8, 10.0, 243.2, 224.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [0, 2], "products": [8]}, {"reactants": [8], "conditions": [11, 3], "products": [9]}], "corefs": [[1, 7], [10, 6], [8, 5], [9, 4]], "caption": "Figure 6. Retrosynthesis of dictazole A (5) employing C\u2212H arylation and an Ugi reaction.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 702, 525, 716], "ImageBB": [92, 546, 777, 693]}, "diagram_type": "single"}, {"id": 991, "width": 1704, "height": 1388, "file_name": "ja3058138-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [874.59, 946.87, 267.66, 121.02], "category_id": 1}, {"id": 1, "bbox": [596.7, 0.0, 314.54, 292.33], "category_id": 1}, {"id": 2, "bbox": [886.52, 483.24, 173.9, 75.85], "category_id": 2}, {"id": 3, "bbox": [297.5, 1071.3, 55.4, 46.88], "category_id": 3}, {"id": 4, "bbox": [1060.42, 433.81, 322.22, 261.64], "category_id": 1}, {"id": 5, "bbox": [535.32, 395.45, 352.91, 321.15], "category_id": 1}, {"id": 6, "bbox": [135.54, 913.8, 397.23, 187.33], "category_id": 1}, {"id": 7, "bbox": [136.39, 46.0, 306.02, 248.89], "category_id": 1}, {"id": 8, "bbox": [138.78, 9.98, 166.63, 44.99], "category_id": 2}, {"id": 9, "bbox": [583.68, 83.3, 126.63, 43.32], "category_id": 2}, {"id": 10, "bbox": [92.13, 553.18, 153.29, 76.65], "category_id": 2}, {"id": 11, "bbox": [343.73, 668.16, 138.3, 43.32], "category_id": 2}, {"id": 12, "bbox": [597.01, 743.14, 253.27, 44.99], "category_id": 2}, {"id": 13, "bbox": [290.41, 888.1, 178.29, 73.32], "category_id": 2}, {"id": 14, "bbox": [297.5, 707.38, 50.29, 40.91], "category_id": 3}, {"id": 15, "bbox": [971.77, 1070.45, 53.7, 45.17], "category_id": 3}, {"id": 16, "bbox": [725.41, 292.33, 54.56, 43.46], "category_id": 3}, {"id": 17, "bbox": [136.39, 292.33, 280.45, 82.67], "category_id": 3}, {"id": 18, "bbox": [643.58, 923.86, 179.86, 174.72], "category_id": 1}, {"id": 19, "bbox": [178.7, 399.71, 223.1, 316.2], "category_id": 1}, {"id": 20, "bbox": [802.13, 704.83, 55.41, 43.46], "category_id": 3}, {"id": 21, "bbox": [1039.96, 23.01, 318.81, 266.76], "category_id": 1}, {"id": 22, "bbox": [1191.69, 704.83, 57.97, 46.87], "category_id": 3}], "caption": "Scheme 10. Retrosynthetic Analysis of Aspidospermidine", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 748, 770, 763], "ImageBB": [433, 780, 859, 1127]}, "reactions": [{"reactants": [7], "conditions": [8], "products": [1]}, {"reactants": [1], "conditions": [9], "products": [21]}, {"reactants": [4], "conditions": [2], "products": [5]}, {"reactants": [5], "conditions": [12], "products": [19]}, {"reactants": [19], "conditions": [10, 11], "products": [6]}, {"reactants": [6], "conditions": [13], "products": [18, 0]}], "diagram_type": "tree"}, {"id": 1299, "width": 2820, "height": 1136, "file_name": "op200351g-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1609.61, 505.02, 81.83, 52.19], "category_id": 3}, {"id": 1, "bbox": [1082.01, 967.71, 114.27, 57.84], "category_id": 2}, {"id": 2, "bbox": [792.82, 806.9, 476.81, 234.16], "category_id": 1}, {"id": 3, "bbox": [1608.2, 620.69, 100.16, 59.25], "category_id": 2}, {"id": 4, "bbox": [402.05, 488.09, 317.41, 153.76], "category_id": 1}, {"id": 5, "bbox": [2147.09, 1039.65, 46.56, 53.61], "category_id": 3}, {"id": 6, "bbox": [2152.74, 710.97, 74.76, 56.43], "category_id": 3}, {"id": 7, "bbox": [1485.47, 314.58, 366.79, 181.97], "category_id": 1}, {"id": 8, "bbox": [427.44, 962.07, 283.56, 70.53], "category_id": 2}, {"id": 9, "bbox": [524.78, 708.15, 83.23, 59.25], "category_id": 3}, {"id": 10, "bbox": [1014.3, 450.0, 393.58, 222.88], "category_id": 1}, {"id": 11, "bbox": [1199.1, 705.33, 81.82, 64.89], "category_id": 3}, {"id": 12, "bbox": [1390.96, 1014.26, 136.83, 64.89], "category_id": 2}, {"id": 13, "bbox": [758.96, 602.35, 241.23, 66.3], "category_id": 2}, {"id": 14, "bbox": [1673.1, 798.43, 689.83, 249.69], "category_id": 1}, {"id": 15, "bbox": [1361.04, 940.17, 172.26, 61.67], "category_id": 2}, {"id": 16, "bbox": [811.9, 344.2, 129.04, 204.55], "category_id": 1}, {"id": 17, "bbox": [1674.51, 194.67, 270.85, 60.66], "category_id": 2}, {"id": 18, "bbox": [1196.28, 1034.01, 69.12, 59.25], "category_id": 3}, {"id": 19, "bbox": [811.16, 675.7, 135.42, 63.48], "category_id": 2}, {"id": 20, "bbox": [428.85, 832.29, 268.04, 67.71], "category_id": 2}, {"id": 21, "bbox": [1958.06, 399.22, 448.6, 331.5], "category_id": 1}, {"id": 22, "bbox": [1485.47, 0.0, 304.72, 172.1], "category_id": 1}, {"id": 23, "bbox": [1335.94, 839.34, 222.89, 63.48], "category_id": 2}], "caption": "Scheme 10. Synthesis of N-methyl ketoamide 6 from N-Boc sarcosine (20)", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 94, 504, 110], "ImageBB": [82, 116, 787, 400]}, "reactions": [{"reactants": [22], "conditions": [17], "products": [7]}, {"reactants": [4, 16], "conditions": [13, 19], "products": [10]}, {"reactants": [10, 7], "conditions": [3], "products": [21]}, {"reactants": [21], "conditions": [20, 8], "products": [2]}, {"reactants": [2], "conditions": [23, 15, 12], "products": [14]}], "diagram_type": "tree"}, {"id": 67, "width": 1316, "height": 852, "file_name": "ja3058138-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [532.19, 182.74, 302.02, 73.54], "category_id": 2}, {"id": 1, "bbox": [885.59, 33.27, 423.73, 220.87], "category_id": 1}, {"id": 2, "bbox": [232.18, 99.47, 268.92, 104.49], "category_id": 1}, {"id": 3, "bbox": [6.9, 5.51, 259.31, 252.9], "category_id": 1}, {"id": 4, "bbox": [539.67, 69.57, 289.2, 78.87], "category_id": 2}, {"id": 5, "bbox": [4.76, 322.61, 1304.56, 523.02], "category_id": 4}, {"id": 6, "bbox": [1057.49, 266.02, 41.5, 30.83], "category_id": 3}, {"id": 7, "bbox": [333.61, 225.45, 41.5, 32.96], "category_id": 3}, {"id": 8, "bbox": [91.25, 264.96, 40.43, 31.89], "category_id": 3}], "reactions": [{"reactants": [3, 2], "conditions": [4, 0], "products": [1]}], "corefs": [[3, 8], [2, 7], [1, 6]], "caption": "Table 1. Optimization Study for the 2-Alkylation of O-TBS- Tryptophola ", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 186, 417, 220], "ImageBB": [86, 226, 415, 439]}, "diagram_type": "single"}, {"id": 348, "width": 1348, "height": 1328, "file_name": "ol2017998-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [449.73, 146.04, 418.34, 112.15], "category_id": 2}, {"id": 1, "bbox": [9.0, 341.0, 1339.0, 987.0], "category_id": 4}, {"id": 2, "bbox": [171.0, 226.0, 129.0, 59.0], "category_id": 3}, {"id": 3, "bbox": [1153.0, 231.0, 67.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [516.0, 15.0, 75.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [499.3, 5.0, 317.7, 112.5], "category_id": 2}, {"id": 6, "bbox": [914.9, 3.0, 386.1, 287.0], "category_id": 1}, {"id": 7, "bbox": [55.2, 0.0, 345.8, 235.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 4, 0], "products": [6]}], "corefs": [[7, 2], [6, 3]], "caption": "Table 2. Optimization of Cross-Coupling Reaction Using Trialkylphosphonium Tetrafluoroborate Saltsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 323, 742, 350], "ImageBB": [436, 362, 773, 694]}, "diagram_type": "single"}, {"id": 492, "width": 1352, "height": 1076, "file_name": "ol0604623-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [357.0, 55.0, 264.0, 165.0], "category_id": 1}, {"id": 1, "bbox": [0.0, 305.0, 1352.0, 771.0], "category_id": 4}, {"id": 2, "bbox": [554.0, 226.0, 80.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [1025.0, 209.0, 85.0, 48.0], "category_id": 3}, {"id": 4, "bbox": [911.0, 2.0, 344.0, 264.0], "category_id": 1}, {"id": 5, "bbox": [92.0, 22.0, 366.0, 212.0], "category_id": 1}, {"id": 6, "bbox": [620.0, 90.0, 261.0, 51.0], "category_id": 2}, {"id": 7, "bbox": [651.0, 161.0, 225.0, 99.0], "category_id": 2}, {"id": 8, "bbox": [284.0, 231.0, 61.0, 41.0], "category_id": 3}, {"id": 9, "bbox": [115.35, 104.58, 114.0, 59.34], "category_id": 2}], "reactions": [{"reactants": [9, 5, 0], "conditions": [6, 7], "products": [4]}], "corefs": [[5, 8], [0, 2], [4, 3]], "caption": "Table 2. Formation of Functionalized Pyrazoline by Reaction of PPh3-DIAD Zwitterion with 6 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 262, 399, 290], "ImageBB": [73, 295, 411, 564]}, "diagram_type": "single"}, {"id": 625, "width": 1172, "height": 816, "file_name": "ol501514b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [61.0, 231.0, 1055.0, 585.0], "category_id": 4}, {"id": 1, "bbox": [6.0, 20.0, 271.0, 144.0], "category_id": 1}, {"id": 2, "bbox": [344.0, 40.0, 244.0, 126.0], "category_id": 1}, {"id": 3, "bbox": [894.0, 5.0, 274.0, 181.0], "category_id": 1}, {"id": 4, "bbox": [974.0, 167.0, 60.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [444.0, 166.0, 42.0, 33.0], "category_id": 3}, {"id": 6, "bbox": [126.0, 165.0, 44.0, 34.0], "category_id": 3}, {"id": 7, "bbox": [613.0, 53.0, 233.0, 44.0], "category_id": 2}, {"id": 8, "bbox": [594.0, 120.0, 271.0, 38.0], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [7, 8], "products": [3]}], "corefs": [[1, 6], [2, 5], [3, 4]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 345, 110], "ImageBB": [104, 116, 397, 320]}, "diagram_type": "single"}, {"id": 509, "width": 1352, "height": 996, "file_name": "ol051901l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1087.0, 240.0, 51.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [190.0, 253.0, 52.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [627.92, 222.98, 44.06, 44.06], "category_id": 3}, {"id": 3, "bbox": [67.0, 22.0, 336.0, 238.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 327.0, 1352.0, 669.0], "category_id": 4}, {"id": 5, "bbox": [949.0, 23.0, 338.0, 242.0], "category_id": 1}, {"id": 6, "bbox": [630.59, 50.75, 44.06, 45.4], "category_id": 3}, {"id": 7, "bbox": [549.0, 0.0, 197.0, 51.9], "category_id": 2}, {"id": 8, "bbox": [512.0, 162.0, 276.0, 60.9], "category_id": 2}], "reactions": [{"reactants": [3, 7], "conditions": [], "products": [5]}, {"reactants": [3, 8], "conditions": [], "products": [5]}], "corefs": [[3, 1], [7, 6], [8, 2], [5, 0]], "caption": "Table 1. Reaction of Amidine 3a with Acetals 4 and 5 Leading to the Trisubstituted Pyrimidine 6aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 522, 732, 550], "ImageBB": [439, 560, 777, 809]}, "diagram_type": "single"}, {"id": 529, "width": 1412, "height": 1724, "file_name": "jo0007837-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [589.0, 1320.0, 337.0, 95.0], "category_id": 2}, {"id": 1, "bbox": [243.5, 1323.5, 219.0, 166.5], "category_id": 1}, {"id": 2, "bbox": [516.0, 731.0, 59.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [107.0, 1506.0, 524.5, 218.0], "category_id": 3}, {"id": 4, "bbox": [1069.0, 1352.5, 179.5, 139.4], "category_id": 1}, {"id": 5, "bbox": [661.0, 1430.0, 202.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [463.5, 197.5, 390.0, 513.0], "category_id": 1}, {"id": 7, "bbox": [998.66, 202.71, 145.12, 310.27], "category_id": 1}, {"id": 8, "bbox": [743.43, 200.21, 147.63, 235.21], "category_id": 1}, {"id": 9, "bbox": [1136.28, 1498.84, 50.04, 52.55], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [0, 5], "products": [4]}], "corefs": [[6, 2], [1, 3], [4, 9]], "caption": " Table 1. Enantioselective Reduction of Oxime Ether with BH3\u201aTHF Catalyzed by Polymer-Supported Chiral                       Catalysta ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [81, 477, 401, 514], "ImageBB": [74, 35, 427, 466]}, "diagram_type": "multiple"}, {"id": 427, "width": 1348, "height": 588, "file_name": "op300235t-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [460.53, 41.89, 68.11, 59.98], "category_id": 3}, {"id": 1, "bbox": [448.5, 54.0, 300.0, 166.5], "category_id": 1}, {"id": 2, "bbox": [966.0, 446.0, 50.0, 41.0], "category_id": 3}, {"id": 3, "bbox": [81.0, 29.0, 299.0, 384.0], "category_id": 1}, {"id": 4, "bbox": [810.0, 3.0, 456.0, 439.0], "category_id": 1}, {"id": 5, "bbox": [220.0, 444.0, 35.0, 42.0], "category_id": 3}, {"id": 6, "bbox": [9.0, 514.0, 1330.0, 74.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [1], "products": [4]}], "corefs": [[3, 5], [1, 0], [4, 2]], "caption": "Table 1. Optimization of base and temperature for benzimidazole additiona ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 141, 736, 171], "ImageBB": [449, 178, 786, 325]}, "diagram_type": "single"}, {"id": 780, "width": 2028, "height": 1676, "file_name": "jo951894m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [933.0, 1235.0, 58.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [1862.0, 1285.0, 68.0, 60.0], "category_id": 3}, {"id": 2, "bbox": [179.0, 1227.0, 58.0, 77.0], "category_id": 3}, {"id": 3, "bbox": [960.0, 693.0, 52.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [583.0, 1232.0, 223.0, 75.0], "category_id": 2}, {"id": 5, "bbox": [1078.0, 1241.0, 228.0, 66.0], "category_id": 2}, {"id": 6, "bbox": [1331.0, 1023.0, 154.0, 66.0], "category_id": 2}, {"id": 7, "bbox": [1323.0, 487.0, 162.0, 79.0], "category_id": 2}, {"id": 8, "bbox": [1260.0, 118.0, 167.0, 91.0], "category_id": 2}, {"id": 9, "bbox": [413.0, 484.0, 206.0, 74.0], "category_id": 2}, {"id": 10, "bbox": [539.0, 1010.0, 160.0, 66.0], "category_id": 2}, {"id": 11, "bbox": [474.0, 1620.0, 71.0, 56.0], "category_id": 3}, {"id": 12, "bbox": [1636.0, 1620.0, 72.0, 56.0], "category_id": 3}, {"id": 13, "bbox": [94.0, 699.0, 44.0, 63.0], "category_id": 3}, {"id": 14, "bbox": [94.0, 275.0, 52.0, 69.0], "category_id": 3}, {"id": 15, "bbox": [894.0, 283.0, 58.0, 61.0], "category_id": 3}, {"id": 16, "bbox": [1845.0, 729.0, 41.0, 58.0], "category_id": 3}, {"id": 17, "bbox": [1787.0, 368.0, 61.0, 55.0], "category_id": 3}, {"id": 18, "bbox": [867.0, 0.0, 291.0, 60.0], "category_id": 2}, {"id": 19, "bbox": [295.16, 215.62, 220.17, 143.79], "category_id": 1}, {"id": 20, "bbox": [247.98, 141.48, 186.47, 60.66], "category_id": 2}, {"id": 21, "bbox": [155.0, 748.0, 492.0, 116.0], "category_id": 3}, {"id": 22, "bbox": [729.0, 745.0, 193.0, 110.0], "category_id": 2}, {"id": 23, "bbox": [732.0, 115.0, 341.0, 162.0], "category_id": 1}, {"id": 24, "bbox": [850.0, 396.0, 253.0, 294.0], "category_id": 1}, {"id": 25, "bbox": [1683.0, 407.0, 297.0, 308.0], "category_id": 1}, {"id": 26, "bbox": [839.0, 913.0, 286.0, 297.0], "category_id": 1}, {"id": 27, "bbox": [1353.0, 1252.0, 462.0, 401.0], "category_id": 1}, {"id": 28, "bbox": [52.5, 924.0, 286.5, 286.0], "category_id": 1}, {"id": 29, "bbox": [277.0, 1309.0, 429.8, 295.0], "category_id": 1}, {"id": 30, "bbox": [988.0, 743.0, 777.0, 147.8], "category_id": 3}, {"id": 31, "bbox": [3.0, 107.0, 185.2, 129.4], "category_id": 1}, {"id": 32, "bbox": [1668.9, 85.0, 322.9, 272.2], "category_id": 1}, {"id": 33, "bbox": [1021.0, 271.8, 280.0, 116.2], "category_id": 3}, {"id": 34, "bbox": [17.0, 393.0, 223.7, 295.3], "category_id": 1}, {"id": 35, "bbox": [1735.0, 960.0, 290.8, 298.0], "category_id": 1}], "reactions": [{"reactants": [31], "conditions": [20, 19], "products": [23]}, {"reactants": [23], "conditions": [8], "products": [32]}, {"reactants": [32], "conditions": [], "products": [24]}, {"reactants": [24], "conditions": [9], "products": [34]}, {"reactants": [24], "conditions": [7], "products": [25]}, {"reactants": [24], "conditions": [22], "products": [26]}, {"reactants": [26], "conditions": [10], "products": [28]}, {"reactants": [26], "conditions": [6], "products": [35]}, {"reactants": [26], "conditions": [4], "products": [29]}, {"reactants": [26], "conditions": [5], "products": [27]}], "corefs": [[31, 14], [23, 15], [23, 33], [32, 17], [24, 3], [34, 13], [25, 16], [26, 0], [28, 2], [29, 11], [35, 1], [27, 12], [26, 30]], "caption": "Table 1. Reactions of 1,4-Di- and 1,4,5-Trisubstituted-2-[(benzotriazol-1-yl)alkyl]pyrroles 7, 10, 15, 17, and 19", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [99, 486, 729, 498], "ImageBB": [161, 54, 668, 473]}, "diagram_type": "tree"}, {"id": 1189, "width": 1356, "height": 660, "file_name": "ol5000692-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1001.91, 48.83, 227.92, 149.19], "category_id": 1}, {"id": 1, "bbox": [196.04, 425.19, 30.53, 41.37], "category_id": 3}, {"id": 2, "bbox": [10.18, 165.47, 187.9, 158.0], "category_id": 1}, {"id": 3, "bbox": [214.36, 232.6, 49.51, 42.04], "category_id": 3}, {"id": 4, "bbox": [796.37, 80.02, 181.12, 57.64], "category_id": 2}, {"id": 5, "bbox": [1046.0, 219.72, 179.08, 44.07], "category_id": 2}, {"id": 6, "bbox": [419.89, 427.9, 235.39, 149.19], "category_id": 1}, {"id": 7, "bbox": [447.7, 12.88, 315.43, 239.39], "category_id": 1}, {"id": 8, "bbox": [483.66, 576.42, 47.48, 40.68], "category_id": 3}, {"id": 9, "bbox": [12.89, 417.73, 162.51, 58.32], "category_id": 2}, {"id": 10, "bbox": [1255.61, 67.81, 92.25, 93.59], "category_id": 2}, {"id": 11, "bbox": [720.4, 459.1, 133.63, 101.72], "category_id": 2}], "caption": "Scheme 2. Reaction of 1 and 2a; Proposed Formation of 2- Indolylindoline and the Observed Formation of 2,2\u2032- Biindole ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 480, 784, 525], "ImageBB": [448, 532, 787, 697]}, "reactions": [{"reactants": [2], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [4], "products": [0]}, {"reactants": [2, 9], "conditions": [], "products": [6]}], "diagram_type": "tree"}, {"id": 185, "width": 1356, "height": 1024, "file_name": "op060175e-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1148.37, 971.08, 132.9, 48.8], "category_id": 3}, {"id": 1, "bbox": [653.9, 803.0, 54.1, 43.6], "category_id": 3}, {"id": 2, "bbox": [263.0, 945.2, 133.4, 53.7], "category_id": 3}, {"id": 3, "bbox": [3.7, 654.4, 469.3, 342.9], "category_id": 1}, {"id": 4, "bbox": [445.5, 464.7, 499.8, 338.9], "category_id": 1}, {"id": 5, "bbox": [730.4, 259.6, 131.3, 59.4], "category_id": 3}, {"id": 6, "bbox": [481.6, 1.4, 477.0, 342.8], "category_id": 1}, {"id": 7, "bbox": [879.6, 681.0, 476.4, 343.0], "category_id": 1}, {"id": 8, "bbox": [552.0, 875.5, 298.4, 98.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [], "products": [4]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [7], "conditions": [], "products": [4]}], "corefs": [[6, 5], [3, 2], [4, 1], [7, 0]], "caption": "Figure 1. Reported approaches.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 312, 255, 326], "ImageBB": [73, 53, 412, 309]}, "diagram_type": "tree"}, {"id": 372, "width": 1352, "height": 480, "file_name": "ol1022036-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [202.9, 167.62, 201.88, 50.98], "category_id": 1}, {"id": 1, "bbox": [837.0, 0.0, 138.0, 54.0], "category_id": 2}, {"id": 2, "bbox": [27.0, 168.0, 118.1, 49.0], "category_id": 1}, {"id": 3, "bbox": [1159.94, 267.98, 80.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [777.0, 58.0, 233.0, 47.0], "category_id": 2}, {"id": 5, "bbox": [1070.0, 107.0, 252.0, 115.0], "category_id": 1}, {"id": 6, "bbox": [33.0, 266.0, 63.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [447.0, 219.0, 220.0, 80.0], "category_id": 2}, {"id": 8, "bbox": [791.0, 219.0, 218.0, 84.0], "category_id": 2}, {"id": 9, "bbox": [456.0, 29.0, 174.0, 77.0], "category_id": 2}, {"id": 10, "bbox": [11.0, 340.0, 1341.0, 140.0], "category_id": 4}], "reactions": [{"reactants": [2, 0, 9, 1, 4], "conditions": [7, 8], "products": [5]}], "corefs": [[2, 6], [5, 3]], "caption": "Table 2. One-Pot, Three-Step Synthesis of 1,4-Disubstituted Triazoles 3 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 243, 370, 270], "ImageBB": [58, 279, 396, 399]}, "diagram_type": "tree"}, {"id": 1258, "width": 968, "height": 316, "file_name": "op050077d-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [507.0, 57.16, 78.45, 46.02], "category_id": 2}, {"id": 1, "bbox": [0.0, 70.72, 108.47, 64.43], "category_id": 1}, {"id": 2, "bbox": [774.79, 261.58, 56.17, 41.18], "category_id": 3}, {"id": 3, "bbox": [184.98, 4.36, 341.39, 239.3], "category_id": 1}, {"id": 4, "bbox": [307.49, 270.79, 31.48, 39.23], "category_id": 3}, {"id": 5, "bbox": [641.14, 6.3, 326.86, 234.45], "category_id": 1}], "caption": "Scheme 3.13 Activation mechanism", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 273, 67], "ImageBB": [185, 74, 427, 153]}, "reactions": [{"reactants": [1, 3], "conditions": [0], "products": [5]}], "diagram_type": "single"}, {"id": 1145, "width": 1352, "height": 800, "file_name": "ol036111v-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [58.17, 426.64, 286.76, 287.35], "category_id": 1}, {"id": 1, "bbox": [36.52, 16.9, 305.03, 294.8], "category_id": 1}, {"id": 2, "bbox": [356.43, 519.94, 146.77, 36.52], "category_id": 1}, {"id": 3, "bbox": [340.87, 563.89, 169.09, 59.5], "category_id": 2}, {"id": 4, "bbox": [925.91, 513.86, 73.04, 36.51], "category_id": 2}, {"id": 5, "bbox": [865.71, 308.99, 47.35, 48.68], "category_id": 3}, {"id": 6, "bbox": [570.83, 134.55, 91.31, 38.54], "category_id": 2}, {"id": 7, "bbox": [340.87, 186.61, 176.53, 60.18], "category_id": 2}, {"id": 8, "bbox": [243.48, 332.66, 106.19, 38.54], "category_id": 2}, {"id": 9, "bbox": [917.11, 563.89, 102.13, 64.91], "category_id": 2}, {"id": 10, "bbox": [1179.53, 694.39, 52.76, 48.68], "category_id": 3}, {"id": 11, "bbox": [132.56, 350.24, 95.37, 43.27], "category_id": 2}, {"id": 12, "bbox": [622.23, 392.16, 294.21, 330.62], "category_id": 1}, {"id": 13, "bbox": [682.43, 6.09, 301.64, 331.98], "category_id": 1}, {"id": 14, "bbox": [495.08, 625.42, 67.63, 39.22], "category_id": 2}, {"id": 15, "bbox": [543.1, 523.32, 91.31, 37.87], "category_id": 2}, {"id": 16, "bbox": [1021.95, 388.1, 293.53, 329.95], "category_id": 1}, {"id": 17, "bbox": [794.7, 690.33, 50.05, 48.0], "category_id": 3}, {"id": 18, "bbox": [243.48, 389.45, 112.27, 37.19], "category_id": 2}, {"id": 19, "bbox": [517.3, 239.35, 66.38, 38.54], "category_id": 2}, {"id": 20, "bbox": [356.43, 129.82, 154.88, 39.21], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 228, 265, 241], "ImageBB": [73, 245, 411, 445]}, "reactions": [{"reactants": [1, 20], "conditions": [7, 6, 19], "products": [13]}, {"reactants": [1], "conditions": [11, 8, 18], "products": [0]}, {"reactants": [0, 2], "conditions": [3, 15, 14], "products": [12]}, {"reactants": [12], "conditions": [4, 9], "products": [16]}], "diagram_type": "tree"}, {"id": 734, "width": 1348, "height": 572, "file_name": "ol015948s-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [920.0, 34.2, 220.0, 106.6], "category_id": 1}, {"id": 1, "bbox": [596.0, 119.0, 149.9, 43.8], "category_id": 2}, {"id": 2, "bbox": [210.4, 49.3, 226.5, 75.2], "category_id": 1}, {"id": 3, "bbox": [485.0, 0.0, 377.0, 99.0], "category_id": 2}, {"id": 4, "bbox": [14.0, 235.0, 1320.0, 337.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [3, 1], "products": [0]}], "corefs": [], "caption": "Table 4. Reduction of N-Benzylidineaniline with Phenylsilane", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 334, 768, 347], "ImageBB": [439, 355, 776, 498]}, "diagram_type": "single"}, {"id": 663, "width": 1164, "height": 656, "file_name": "ol402047d-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [891.0, 88.0, 95.0, 45.0], "category_id": 1}, {"id": 1, "bbox": [41.9, 98.0, 92.5, 35.6], "category_id": 1}, {"id": 2, "bbox": [4.05, 137.06, 160.91, 39.99], "category_id": 2}, {"id": 3, "bbox": [693.59, 22.8, 89.61, 44.8], "category_id": 1}, {"id": 4, "bbox": [234.0, 46.0, 166.0, 71.0], "category_id": 2}, {"id": 5, "bbox": [37.0, 234.2, 1091.0, 419.8], "category_id": 4}, {"id": 6, "bbox": [475.6, 3.0, 211.9, 80.0], "category_id": 1}, {"id": 7, "bbox": [1006.0, 82.0, 158.0, 70.0], "category_id": 2}, {"id": 8, "bbox": [494.0, 77.0, 184.0, 44.0], "category_id": 2}, {"id": 9, "bbox": [420.0, 117.0, 479.0, 74.0], "category_id": 2}, {"id": 10, "bbox": [160.0, 116.0, 248.0, 73.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [4, 10, 6, 3, 8, 9], "products": [0, 7]}], "corefs": [], "caption": "Table 5. Recyclability of Polymer Using Multiple Nucleophiles", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 392, 771, 405], "ImageBB": [459, 417, 750, 581]}, "diagram_type": "single"}, {"id": 691, "width": 1352, "height": 892, "file_name": "ol401042b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.0, 427.0, 1337.0, 465.0], "category_id": 4}, {"id": 1, "bbox": [145.0, 323.0, 60.0, 25.0], "category_id": 3}, {"id": 2, "bbox": [684.0, 228.0, 147.0, 49.0], "category_id": 2}, {"id": 3, "bbox": [650.0, 159.0, 267.0, 42.0], "category_id": 2}, {"id": 4, "bbox": [26.9, 5.6, 301.1, 316.7], "category_id": 1}, {"id": 5, "bbox": [466.0, 315.0, 113.9, 43.0], "category_id": 2}, {"id": 6, "bbox": [426.15, 175.7, 192.9, 107.0], "category_id": 1}, {"id": 7, "bbox": [925.0, 64.4, 396.0, 251.6], "category_id": 1}, {"id": 8, "bbox": [1057.0, 318.0, 128.0, 36.6], "category_id": 3}, {"id": 9, "bbox": [90.0, 355.4, 174.0, 37.6], "category_id": 2}], "reactions": [{"reactants": [4, 6], "conditions": [3, 2], "products": [7]}], "corefs": [[4, 1], [7, 8]], "caption": "Table 3. Scope of Substrate for Organocatalytic Annulationa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 483, 394, 499], "ImageBB": [71, 510, 409, 733]}, "diagram_type": "single"}, {"id": 933, "width": 1416, "height": 1540, "file_name": "acs.oprd.6b00011-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [437.46, 701.82, 262.63, 60.86], "category_id": 2}, {"id": 1, "bbox": [425.14, 536.19, 271.1, 103.23], "category_id": 2}, {"id": 2, "bbox": [1104.43, 1103.96, 311.57, 356.69], "category_id": 1}, {"id": 3, "bbox": [1177.6, 679.48, 238.4, 54.7], "category_id": 2}, {"id": 4, "bbox": [425.14, 1064.67, 392.79, 429.11], "category_id": 1}, {"id": 5, "bbox": [1335.49, 1449.09, 41.59, 47.0], "category_id": 3}, {"id": 6, "bbox": [970.42, 0.0, 319.63, 341.28], "category_id": 1}, {"id": 7, "bbox": [652.34, 1449.09, 36.2, 43.92], "category_id": 3}, {"id": 8, "bbox": [1177.6, 587.03, 238.4, 68.57], "category_id": 2}, {"id": 9, "bbox": [969.65, 812.76, 53.91, 55.46], "category_id": 3}, {"id": 10, "bbox": [911.89, 1255.73, 99.35, 53.15], "category_id": 2}, {"id": 11, "bbox": [469.81, 62.4, 267.25, 235.74], "category_id": 1}, {"id": 12, "bbox": [566.85, 318.94, 33.12, 40.06], "category_id": 3}, {"id": 13, "bbox": [823.32, 1338.93, 271.1, 113.25], "category_id": 2}, {"id": 14, "bbox": [781.73, 202.61, 136.32, 87.83], "category_id": 2}, {"id": 15, "bbox": [744.76, 413.7, 396.64, 452.98], "category_id": 1}, {"id": 16, "bbox": [1121.38, 317.4, 41.59, 43.91], "category_id": 3}, {"id": 17, "bbox": [789.43, 28.5, 125.54, 142.53], "category_id": 1}], "caption": "Scheme 1. Discovery Chemistry Synthesis of GDC-0084", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 398, 110], "ImageBB": [82, 124, 436, 509]}, "reactions": [{"reactants": [11], "conditions": [17, 14], "products": [6]}, {"reactants": [6], "conditions": [1, 0], "products": [15]}, {"reactants": [15], "conditions": [8, 3], "products": [4]}, {"reactants": [4], "conditions": [10, 13], "products": [2]}], "diagram_type": "multiple"}, {"id": 850, "width": 2072, "height": 636, "file_name": "jo200882k-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1066.0, 3.0, 48.6, 39.0], "category_id": 3}, {"id": 1, "bbox": [32.0, 392.0, 290.0, 181.0], "category_id": 1}, {"id": 2, "bbox": [159.0, 266.0, 40.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [1219.0, 263.0, 61.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [719.0, 57.0, 286.0, 223.0], "category_id": 1}, {"id": 5, "bbox": [36.0, 45.0, 288.0, 231.0], "category_id": 1}, {"id": 6, "bbox": [44.0, 573.0, 274.0, 58.0], "category_id": 2}, {"id": 7, "bbox": [729.0, 575.0, 269.0, 61.0], "category_id": 2}, {"id": 8, "bbox": [1109.0, 582.0, 270.0, 54.0], "category_id": 2}, {"id": 9, "bbox": [1806.0, 577.0, 257.0, 59.0], "category_id": 2}, {"id": 10, "bbox": [1483.0, 498.0, 214.0, 73.0], "category_id": 2}, {"id": 11, "bbox": [1546.0, 397.0, 88.0, 59.0], "category_id": 2}, {"id": 12, "bbox": [394.0, 498.0, 238.0, 60.0], "category_id": 2}, {"id": 13, "bbox": [483.0, 392.0, 89.0, 66.0], "category_id": 2}, {"id": 14, "bbox": [420.0, 157.0, 218.0, 70.0], "category_id": 2}, {"id": 15, "bbox": [478.0, 59.0, 96.0, 58.0], "category_id": 2}, {"id": 16, "bbox": [1476.0, 154.0, 220.0, 63.0], "category_id": 2}, {"id": 17, "bbox": [1542.0, 50.0, 96.0, 62.0], "category_id": 2}, {"id": 18, "bbox": [8.0, 341.0, 31.0, 47.0], "category_id": 3}, {"id": 19, "bbox": [10.0, 6.0, 39.0, 46.0], "category_id": 3}, {"id": 20, "bbox": [1070.0, 346.0, 40.0, 37.0], "category_id": 3}, {"id": 21, "bbox": [1102.0, 52.0, 298.0, 234.0], "category_id": 1}, {"id": 22, "bbox": [1782.0, 42.0, 290.0, 243.0], "category_id": 1}, {"id": 23, "bbox": [1789.0, 390.0, 283.0, 181.0], "category_id": 1}, {"id": 24, "bbox": [1109.0, 390.0, 287.0, 180.0], "category_id": 1}, {"id": 25, "bbox": [728.0, 398.0, 287.0, 160.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [15], "products": [4]}, {"reactants": [4], "conditions": [14], "products": [5]}, {"reactants": [21], "conditions": [17], "products": [22]}, {"reactants": [22], "conditions": [16], "products": [21]}, {"reactants": [1], "conditions": [13], "products": [25]}, {"reactants": [25], "conditions": [12], "products": [1]}, {"reactants": [24], "conditions": [11], "products": [23]}, {"reactants": [23], "conditions": [10], "products": [24]}], "corefs": [[5, 2], [21, 3], [1, 6], [25, 7], [24, 8], [23, 9]], "caption": "Figure 5. Calculated equilibrium constants (Khyd) of the hydration of (a) cis-DHMP 5, (b) trans-DHMP 10, (c) (2R,4S)-DHMF, and (d) (2S,4S)- DHMF. ", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 497, 770, 525], "ImageBB": [163, 324, 681, 483]}, "diagram_type": "multiple"}, {"id": 264, "width": 1352, "height": 612, "file_name": "ol801498u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [49.0, 5.0, 261.0, 146.9], "category_id": 1}, {"id": 1, "bbox": [594.0, 2.0, 242.0, 109.8], "category_id": 2}, {"id": 2, "bbox": [938.0, 7.0, 362.0, 142.0], "category_id": 1}, {"id": 3, "bbox": [640.0, 136.0, 150.0, 60.0], "category_id": 2}, {"id": 4, "bbox": [398.0, 9.0, 146.0, 142.0], "category_id": 1}, {"id": 5, "bbox": [4.0, 219.0, 1344.0, 388.0], "category_id": 4}, {"id": 6, "bbox": [203.73, 148.04, 44.89, 56.98], "category_id": 3}], "reactions": [{"reactants": [0, 4], "conditions": [1, 3], "products": [2]}], "corefs": [[0, 6]], "caption": "Table 1. Comparison of the Direct Crossed-Claisen Coupling of Various Thioesters and Oxoester 8 with 5 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 141, 390, 168], "ImageBB": [58, 177, 396, 330]}, "diagram_type": "single"}, {"id": 700, "width": 1352, "height": 860, "file_name": "ol047761h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.9, 598.2, 220.4, 129.4], "category_id": 1}, {"id": 1, "bbox": [565.0, 241.5, 263.3, 207.5], "category_id": 1}, {"id": 2, "bbox": [311.52, 254.61, 74.9, 44.93], "category_id": 2}, {"id": 3, "bbox": [41.2, 295.2, 222.5, 126.9], "category_id": 1}, {"id": 4, "bbox": [808.3, 217.16, 81.13, 48.68], "category_id": 2}, {"id": 5, "bbox": [131.79, 745.14, 81.13, 52.43], "category_id": 2}, {"id": 6, "bbox": [1048.8, 250.4, 262.0, 203.7], "category_id": 1}, {"id": 7, "bbox": [46.0, 140.0, 303.0, 55.0], "category_id": 2}, {"id": 8, "bbox": [625.0, 576.0, 253.0, 209.0], "category_id": 1}, {"id": 9, "bbox": [46.0, 527.0, 315.0, 55.0], "category_id": 2}], "reactions": [{"reactants": [3, 2], "conditions": [], "products": [1]}, {"reactants": [1, 4], "conditions": [], "products": [6]}, {"reactants": [0, 5], "conditions": [], "products": [8]}], "corefs": [], "caption": "Figure 1. Two mechanistic pathways for \u03b2-lactone ring opening with nucleophiles. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 278, 409, 305], "ImageBB": [73, 51, 411, 266]}, "diagram_type": "multiple"}, {"id": 59, "width": 1356, "height": 1208, "file_name": "ja406383h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1101.35, 93.32, 176.08, 236.63], "category_id": 1}, {"id": 1, "bbox": [194.59, 396.07, 213.93, 106.46], "category_id": 1}, {"id": 2, "bbox": [324.78, 61.53, 176.08, 215.47], "category_id": 1}, {"id": 3, "bbox": [928.78, 1157.51, 221.49, 39.84], "category_id": 2}, {"id": 4, "bbox": [497.35, 1162.05, 223.05, 38.35], "category_id": 2}, {"id": 5, "bbox": [896.99, 751.81, 406.18, 374.4], "category_id": 1}, {"id": 6, "bbox": [745.61, 664.01, 294.16, 79.21], "category_id": 2}, {"id": 7, "bbox": [791.02, 765.44, 183.66, 76.17], "category_id": 2}, {"id": 8, "bbox": [56.83, 82.72, 226.05, 168.52], "category_id": 1}, {"id": 9, "bbox": [545.79, 106.94, 215.44, 191.22], "category_id": 1}, {"id": 10, "bbox": [106.79, 1160.54, 219.98, 38.33], "category_id": 2}, {"id": 11, "bbox": [68.95, 891.08, 328.97, 238.15], "category_id": 1}, {"id": 12, "bbox": [494.32, 807.82, 215.44, 35.31], "category_id": 2}, {"id": 13, "bbox": [454.96, 374.88, 212.42, 167.0], "category_id": 1}, {"id": 14, "bbox": [974.19, 356.72, 256.31, 177.59], "category_id": 1}, {"id": 15, "bbox": [127.98, 644.33, 377.42, 168.52], "category_id": 1}, {"id": 16, "bbox": [518.54, 677.64, 142.78, 121.59], "category_id": 1}, {"id": 17, "bbox": [792.19, 382.2, 96.64, 30.75], "category_id": 2}, {"id": 18, "bbox": [508.12, 554.98, 108.36, 29.29], "category_id": 2}, {"id": 19, "bbox": [232.85, 552.05, 101.03, 29.29], "category_id": 2}, {"id": 20, "bbox": [571.09, 300.2, 190.35, 30.75], "category_id": 2}, {"id": 21, "bbox": [330.95, 303.13, 187.43, 30.75], "category_id": 2}, {"id": 22, "bbox": [79.1, 282.63, 205.0, 71.75], "category_id": 2}, {"id": 23, "bbox": [884.88, 93.32, 194.25, 236.63], "category_id": 1}, {"id": 24, "bbox": [417.12, 889.57, 453.1, 236.63], "category_id": 1}], "reactions": [{"reactants": [15, 16], "conditions": [6, 7], "products": [11, 24, 5]}], "corefs": [[16, 12], [11, 10], [24, 4], [5, 3], [8, 22], [2, 21], [9, 20], [1, 19], [13, 18]], "caption": "Figure 1. (a) Potential utilities of the amidated products obtained in this study. (b) Synthesis of benzanilides bearing peptides using the present Ir-catalyzed C\u2212H amidation. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 533, 784, 575], "ImageBB": [448, 222, 787, 524]}, "diagram_type": "multiple"}, {"id": 388, "width": 2816, "height": 1756, "file_name": "op500224x-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [825.0, 1380.0, 401.0, 260.0], "category_id": 1}, {"id": 1, "bbox": [151.0, 356.0, 57.0, 71.2], "category_id": 3}, {"id": 2, "bbox": [1504.2, 504.0, 483.3, 304.0], "category_id": 1}, {"id": 3, "bbox": [1001.0, 446.0, 488.5, 340.0], "category_id": 1}, {"id": 4, "bbox": [947.0, 1659.0, 170.0, 93.0], "category_id": 3}, {"id": 5, "bbox": [500.0, 1653.0, 167.0, 103.0], "category_id": 3}, {"id": 6, "bbox": [90.0, 1662.0, 176.0, 94.0], "category_id": 3}, {"id": 7, "bbox": [71.0, 19.0, 275.0, 154.0], "category_id": 1}, {"id": 8, "bbox": [0.0, 118.0, 311.0, 229.0], "category_id": 1}, {"id": 9, "bbox": [696.0, 41.0, 315.0, 331.0], "category_id": 1}, {"id": 10, "bbox": [1406.0, 48.0, 308.0, 314.0], "category_id": 1}, {"id": 11, "bbox": [1970.0, 102.0, 318.0, 263.0], "category_id": 1}, {"id": 12, "bbox": [2497.0, 109.0, 311.0, 253.0], "category_id": 1}, {"id": 13, "bbox": [2397.0, 529.0, 389.0, 244.0], "category_id": 1}, {"id": 14, "bbox": [1990.0, 536.0, 305.0, 237.0], "category_id": 1}, {"id": 15, "bbox": [481.0, 459.0, 514.0, 321.0], "category_id": 1}, {"id": 16, "bbox": [6.0, 462.0, 459.0, 321.0], "category_id": 1}, {"id": 17, "bbox": [3.0, 972.0, 427.0, 228.0], "category_id": 1}, {"id": 18, "bbox": [459.0, 969.0, 449.0, 231.0], "category_id": 1}, {"id": 19, "bbox": [979.0, 972.0, 539.0, 238.0], "category_id": 1}, {"id": 20, "bbox": [1585.0, 969.0, 337.0, 238.0], "category_id": 1}, {"id": 21, "bbox": [1987.0, 959.0, 327.0, 241.0], "category_id": 1}, {"id": 22, "bbox": [2388.0, 969.0, 388.0, 244.0], "category_id": 1}, {"id": 23, "bbox": [13.0, 1383.0, 317.0, 251.0], "category_id": 1}, {"id": 24, "bbox": [436.0, 1367.0, 296.0, 263.0], "category_id": 1}, {"id": 25, "bbox": [1348.0, 1402.0, 452.0, 254.0], "category_id": 1}, {"id": 26, "bbox": [1903.0, 1393.0, 366.0, 231.0], "category_id": 1}, {"id": 27, "bbox": [2378.0, 1380.0, 382.0, 254.0], "category_id": 1}, {"id": 28, "bbox": [385.0, 134.0, 237.0, 77.0], "category_id": 2}, {"id": 29, "bbox": [382.0, 240.0, 231.0, 93.0], "category_id": 2}, {"id": 30, "bbox": [1040.0, 93.0, 298.0, 115.0], "category_id": 2}, {"id": 31, "bbox": [1114.0, 224.0, 147.0, 100.0], "category_id": 2}, {"id": 32, "bbox": [812.0, 369.0, 99.0, 61.0], "category_id": 3}, {"id": 33, "bbox": [2468.0, 1656.0, 189.0, 58.0], "category_id": 3}, {"id": 34, "bbox": [1993.0, 1650.0, 176.0, 64.0], "category_id": 3}, {"id": 35, "bbox": [1486.0, 1653.0, 186.0, 103.0], "category_id": 3}, {"id": 36, "bbox": [1662.0, 805.0, 174.0, 93.0], "category_id": 3}, {"id": 37, "bbox": [1053.0, 802.0, 182.0, 93.0], "category_id": 3}, {"id": 38, "bbox": [539.0, 802.0, 183.0, 100.0], "category_id": 3}, {"id": 39, "bbox": [61.0, 805.0, 183.0, 90.0], "category_id": 3}, {"id": 40, "bbox": [2609.0, 362.0, 80.0, 68.0], "category_id": 3}, {"id": 41, "bbox": [2080.0, 365.0, 93.0, 58.0], "category_id": 3}, {"id": 42, "bbox": [1521.0, 365.0, 90.0, 65.0], "category_id": 3}, {"id": 43, "bbox": [250.0, 0.0, 93.0, 60.0], "category_id": 3}, {"id": 44, "bbox": [2047.0, 792.0, 183.0, 106.0], "category_id": 3}, {"id": 45, "bbox": [2494.0, 796.0, 183.0, 99.0], "category_id": 3}, {"id": 46, "bbox": [86.0, 1210.0, 174.0, 99.0], "category_id": 3}, {"id": 47, "bbox": [533.0, 1213.0, 195.0, 99.0], "category_id": 3}, {"id": 48, "bbox": [1155.0, 1216.0, 186.0, 96.0], "category_id": 3}, {"id": 49, "bbox": [1669.0, 1219.0, 173.0, 97.0], "category_id": 3}, {"id": 50, "bbox": [2057.0, 1216.0, 186.0, 96.0], "category_id": 3}, {"id": 51, "bbox": [2481.0, 1216.0, 189.0, 96.0], "category_id": 3}], "reactions": [{"reactants": [7, 8], "conditions": [28, 29], "products": [9]}, {"reactants": [9], "conditions": [30, 31], "products": [10]}, {"reactants": [10], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [], "products": [12]}], "corefs": [[7, 43], [8, 1], [9, 32], [10, 42], [11, 41], [12, 40], [16, 39], [15, 38], [3, 37], [2, 36], [14, 44], [13, 45], [17, 46], [18, 47], [19, 48], [20, 49], [21, 50], [22, 51], [23, 6], [24, 5], [0, 4], [25, 35], [26, 34], [27, 33]], "caption": "Table 2. Rh-catalyzed cyclization using silyl alkynes with kinetic protonation and reduction", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 596, 110], "ImageBB": [82, 116, 786, 555]}, "diagram_type": "single"}, {"id": 1186, "width": 1344, "height": 816, "file_name": "ol401881n-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [357.68, 106.94, 34.96, 48.43], "category_id": 3}, {"id": 1, "bbox": [39.0, 2.02, 379.19, 148.64], "category_id": 1}, {"id": 2, "bbox": [528.46, 548.84, 353.65, 193.04], "category_id": 1}, {"id": 3, "bbox": [635.36, 53.14, 135.14, 125.1], "category_id": 1}, {"id": 4, "bbox": [270.95, 275.09, 335.5, 207.84], "category_id": 1}, {"id": 5, "bbox": [954.05, 6.73, 348.27, 165.46], "category_id": 1}, {"id": 6, "bbox": [634.01, 720.36, 42.36, 46.41], "category_id": 3}, {"id": 7, "bbox": [378.53, 448.63, 30.92, 47.08], "category_id": 3}, {"id": 8, "bbox": [962.11, 468.8, 51.1, 45.74], "category_id": 3}, {"id": 9, "bbox": [810.84, 302.67, 350.96, 191.69], "category_id": 1}, {"id": 10, "bbox": [1033.38, 125.1, 45.72, 47.09], "category_id": 3}, {"id": 11, "bbox": [651.49, 187.66, 116.32, 53.13], "category_id": 2}], "caption": "Scheme 3. Proposed Organocatalyzed Anion Relay Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 653, 771, 666], "ImageBB": [437, 678, 773, 882]}, "reactions": [{"reactants": [1, 3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [3]}, {"reactants": [4], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [5, 3]}], "diagram_type": "graph"}, {"id": 1367, "width": 1316, "height": 952, "file_name": "op9600419-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [617.51, 86.93, 149.44, 46.75], "category_id": 2}, {"id": 1, "bbox": [458.86, 440.56, 126.39, 53.34], "category_id": 2}, {"id": 2, "bbox": [269.26, 435.29, 156.68, 57.29], "category_id": 2}, {"id": 3, "bbox": [414.09, 846.21, 64.52, 47.42], "category_id": 3}, {"id": 4, "bbox": [1012.51, 289.75, 56.62, 42.15], "category_id": 3}, {"id": 5, "bbox": [369.98, 5.93, 228.44, 295.68], "category_id": 1}, {"id": 6, "bbox": [916.39, 552.51, 347.6, 301.61], "category_id": 1}, {"id": 7, "bbox": [240.29, 558.44, 425.28, 298.97], "category_id": 1}, {"id": 8, "bbox": [791.97, 2.63, 409.48, 294.37], "category_id": 1}, {"id": 9, "bbox": [725.48, 725.04, 106.65, 49.39], "category_id": 2}, {"id": 10, "bbox": [1075.71, 842.92, 42.79, 46.1], "category_id": 3}, {"id": 11, "bbox": [0.0, 684.22, 104.67, 57.29], "category_id": 2}, {"id": 12, "bbox": [631.34, 180.44, 120.47, 41.49], "category_id": 2}, {"id": 13, "bbox": [929.56, 896.26, 386.44, 52.69], "category_id": 2}, {"id": 14, "bbox": [0.0, 110.63, 272.55, 104.05], "category_id": 1}, {"id": 15, "bbox": [728.77, 655.24, 100.07, 54.66], "category_id": 2}, {"id": 16, "bbox": [414.09, 298.32, 55.96, 44.12], "category_id": 3}], "caption": "Scheme 6. Pilot scale synthesis of intermediate 3", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 49, 349, 63], "ImageBB": [77, 70, 406, 308]}, "reactions": [{"reactants": [14, 5], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [12], "products": [14, 5]}, {"reactants": [14, 5], "conditions": [2, 1], "products": [7]}, {"reactants": [11, 7], "conditions": [15, 9], "products": [6]}], "diagram_type": "tree"}, {"id": 897, "width": 1352, "height": 2540, "file_name": "acs.joc.6b01001-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 59.0, 187.0, 153.0], "category_id": 1}, {"id": 1, "bbox": [319.0, 193.0, 120.0, 42.0], "category_id": 2}, {"id": 2, "bbox": [252.0, 154.0, 241.0, 43.0], "category_id": 2}, {"id": 3, "bbox": [198.0, 90.0, 368.0, 43.0], "category_id": 2}, {"id": 4, "bbox": [237.0, 48.0, 283.0, 41.0], "category_id": 2}, {"id": 5, "bbox": [214.0, 4.0, 321.0, 47.0], "category_id": 2}, {"id": 6, "bbox": [651.0, 16.0, 281.0, 206.0], "category_id": 1}, {"id": 7, "bbox": [79.0, 245.0, 28.0, 38.0], "category_id": 3}, {"id": 8, "bbox": [788.0, 244.0, 46.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [1065.0, 58.0, 287.0, 159.0], "category_id": 1}, {"id": 10, "bbox": [9.0, 301.0, 1343.0, 2239.0], "category_id": 4}, {"id": 11, "bbox": [1198.0, 244.0, 32.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [5, 4, 3, 2, 1], "products": [6]}, {"reactants": [6], "conditions": [], "products": [9]}], "corefs": [[0, 7], [6, 8], [9, 11]], "caption": "Table 2. Substrate Scope of Photo-redox-Catalyzed Intramolecular Formation of Sultonea ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 187, 741, 217], "ImageBB": [448, 223, 786, 858]}, "diagram_type": "single"}, {"id": 1196, "width": 1352, "height": 860, "file_name": "ol5020043-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [173.14, 391.56, 50.05, 45.99], "category_id": 3}, {"id": 1, "bbox": [1103.78, 717.52, 60.2, 49.37], "category_id": 3}, {"id": 2, "bbox": [683.78, 551.84, 273.91, 233.31], "category_id": 1}, {"id": 3, "bbox": [520.1, 0.0, 334.79, 399.0], "category_id": 1}, {"id": 4, "bbox": [173.14, 760.8, 58.84, 48.69], "category_id": 3}, {"id": 5, "bbox": [744.65, 768.92, 56.81, 47.34], "category_id": 3}, {"id": 6, "bbox": [938.76, 577.53, 60.19, 51.4], "category_id": 3}, {"id": 7, "bbox": [812.28, 401.7, 235.37, 183.95], "category_id": 1}, {"id": 8, "bbox": [665.52, 389.53, 68.98, 52.75], "category_id": 3}, {"id": 9, "bbox": [1003.01, 10.82, 332.76, 373.3], "category_id": 1}, {"id": 10, "bbox": [10.15, 0.0, 356.43, 409.82], "category_id": 1}, {"id": 11, "bbox": [1028.71, 523.43, 205.61, 190.71], "category_id": 1}, {"id": 12, "bbox": [94.01, 445.66, 391.6, 325.29], "category_id": 1}, {"id": 13, "bbox": [1153.83, 380.06, 65.61, 50.72], "category_id": 3}], "caption": "Scheme 2. Retrosynthetic Analysis of 2", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 581, 303, 596], "ImageBB": [82, 602, 420, 817]}, "reactions": [{"reactants": [10], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [9]}, {"reactants": [12], "conditions": [], "products": [2, 7, 11]}], "diagram_type": "multiple"}, {"id": 18, "width": 1224, "height": 1636, "file_name": "ja960062i-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [37.0, 1037.05, 25.79, 31.73], "category_id": 2}, {"id": 1, "bbox": [194.11, 1142.15, 124.44, 35.77], "category_id": 2}, {"id": 2, "bbox": [137.12, 1363.8, 660.62, 265.87], "category_id": 1}, {"id": 3, "bbox": [445.32, 895.16, 654.29, 434.75], "category_id": 1}, {"id": 4, "bbox": [27.35, 570.08, 329.2, 175.09], "category_id": 1}, {"id": 5, "bbox": [375.66, 285.09, 25.22, 29.45], "category_id": 2}, {"id": 6, "bbox": [626.86, 154.21, 441.08, 434.75], "category_id": 1}, {"id": 7, "bbox": [413.65, 240.76, 215.21, 97.0], "category_id": 1}, {"id": 8, "bbox": [10.46, 122.55, 348.2, 394.64], "category_id": 1}, {"id": 9, "bbox": [93.2, 996.49, 335.12, 107.55], "category_id": 1}, {"id": 10, "bbox": [1038.44, 890.31, 25.78, 33.71], "category_id": 3}, {"id": 11, "bbox": [1040.42, 154.61, 25.78, 25.77], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [5, 7], "products": [6]}, {"reactants": [8], "conditions": [0, 9, 1], "products": [3]}], "corefs": [[6, 11], [3, 10]], "caption": "Figure 1. Scheme for coupling CPP with amino-derivatized oligo- nucleotides via an amide bond. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 435, 774, 461], "ImageBB": [469, 21, 775, 430]}, "diagram_type": "multiple"}, {"id": 751, "width": 1348, "height": 876, "file_name": "jo990938e-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [145.0, 100.0, 264.0, 176.0], "category_id": 1}, {"id": 1, "bbox": [474.0, 216.0, 283.0, 87.0], "category_id": 2}, {"id": 2, "bbox": [832.0, 93.0, 383.0, 196.0], "category_id": 1}, {"id": 3, "bbox": [8.0, 376.0, 1340.0, 500.0], "category_id": 4}, {"id": 4, "bbox": [987.0, 294.0, 128.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [614.0, 158.0, 53.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [491.0, 4.0, 211.0, 202.0], "category_id": 1}, {"id": 7, "bbox": [191.0, 297.0, 215.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [6, 1], "products": [2]}], "corefs": [[0, 7], [6, 5], [2, 4]], "caption": "   Table 5. Variations of Solvent in Additions of Allenylindium Reagents Derived from Mesylate 7 to             Cyclohexanecarboxaldehyde ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [456, 259, 758, 296], "ImageBB": [439, 306, 776, 525]}, "diagram_type": "single"}, {"id": 1360, "width": 1308, "height": 1044, "file_name": "op900188v-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [957.93, 0.0, 350.07, 358.56], "category_id": 1}, {"id": 1, "bbox": [1137.22, 355.94, 62.16, 49.07], "category_id": 3}, {"id": 2, "bbox": [777.34, 194.98, 102.08, 51.69], "category_id": 2}, {"id": 3, "bbox": [194.99, 992.57, 84.41, 50.38], "category_id": 3}, {"id": 4, "bbox": [131.52, 191.06, 94.88, 49.07], "category_id": 2}, {"id": 5, "bbox": [1137.22, 992.57, 69.36, 50.38], "category_id": 3}, {"id": 6, "bbox": [810.71, 120.39, 37.95, 45.15], "category_id": 2}, {"id": 7, "bbox": [484.86, 354.63, 65.43, 50.38], "category_id": 3}, {"id": 8, "bbox": [453.45, 620.93, 350.72, 364.44], "category_id": 1}, {"id": 9, "bbox": [313.42, 0.0, 348.76, 358.56], "category_id": 1}, {"id": 10, "bbox": [12.1, 155.72, 58.57, 54.31], "category_id": 3}, {"id": 11, "bbox": [0.0, 623.55, 346.14, 362.48], "category_id": 1}, {"id": 12, "bbox": [1182.37, 475.02, 92.26, 53.65], "category_id": 2}, {"id": 13, "bbox": [651.71, 992.57, 64.12, 50.38], "category_id": 3}, {"id": 14, "bbox": [1110.39, 483.53, 35.99, 38.6], "category_id": 2}, {"id": 15, "bbox": [151.15, 124.32, 47.11, 41.22], "category_id": 2}, {"id": 16, "bbox": [955.32, 626.82, 348.75, 358.55], "category_id": 1}], "caption": "Scheme 7. Synthesis of the bromobenzopyran intermediate 25a ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 274, 753, 301], "ImageBB": [430, 311, 757, 572]}, "reactions": [{"reactants": [10], "conditions": [15, 4], "products": [9]}, {"reactants": [9], "conditions": [6, 2], "products": [0]}, {"reactants": [0], "conditions": [14, 12], "products": [16]}], "diagram_type": "tree"}, {"id": 999, "width": 2800, "height": 2040, "file_name": "ja501560x-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2546.2, 1932.24, 68.58, 48.98], "category_id": 3}, {"id": 1, "bbox": [1577.19, 207.34, 149.87, 140.1], "category_id": 1}, {"id": 2, "bbox": [654.13, 1971.16, 400.6, 67.25], "category_id": 2}, {"id": 3, "bbox": [567.28, 184.93, 267.54, 105.07], "category_id": 2}, {"id": 4, "bbox": [794.2, 1064.74, 72.83, 56.03], "category_id": 3}, {"id": 5, "bbox": [60.23, 1216.04, 392.2, 281.6], "category_id": 1}, {"id": 6, "bbox": [1323.66, 806.96, 225.51, 212.94], "category_id": 1}, {"id": 7, "bbox": [207.3, 634.64, 82.64, 51.83], "category_id": 3}, {"id": 8, "bbox": [0.0, 1669.95, 512.66, 228.36], "category_id": 1}, {"id": 9, "bbox": [2531.51, 1114.29, 93.06, 48.98], "category_id": 2}, {"id": 10, "bbox": [2558.45, 1065.31, 44.08, 48.98], "category_id": 3}, {"id": 11, "bbox": [1853.14, 210.61, 102.86, 44.08], "category_id": 2}, {"id": 12, "bbox": [1284.98, 269.39, 200.82, 41.63], "category_id": 2}, {"id": 13, "bbox": [1351.1, 205.71, 71.02, 48.98], "category_id": 2}, {"id": 14, "bbox": [2409.06, 1981.22, 362.45, 53.88], "category_id": 2}, {"id": 15, "bbox": [1260.49, 1550.2, 347.75, 56.33], "category_id": 2}, {"id": 16, "bbox": [2406.61, 683.27, 345.31, 53.87], "category_id": 2}, {"id": 17, "bbox": [1997.63, 1927.35, 61.23, 56.32], "category_id": 3}, {"id": 18, "bbox": [1402.53, 1932.24, 63.67, 51.43], "category_id": 3}, {"id": 19, "bbox": [800.08, 1929.8, 61.23, 53.87], "category_id": 3}, {"id": 20, "bbox": [227.02, 1932.24, 56.33, 48.98], "category_id": 3}, {"id": 21, "bbox": [2002.53, 1065.31, 51.43, 48.98], "category_id": 3}, {"id": 22, "bbox": [2548.65, 634.29, 164.08, 51.41], "category_id": 3}, {"id": 23, "bbox": [2465.39, 345.31, 134.69, 48.98], "category_id": 3}, {"id": 24, "bbox": [305.39, 288.98, 41.63, 46.53], "category_id": 3}, {"id": 25, "bbox": [48.24, 286.53, 44.09, 51.43], "category_id": 3}, {"id": 26, "bbox": [224.57, 1501.22, 203.27, 53.88], "category_id": 3}, {"id": 27, "bbox": [1404.98, 1501.22, 56.33, 44.09], "category_id": 3}, {"id": 28, "bbox": [1787.29, 1211.84, 477.64, 280.19], "category_id": 1}, {"id": 29, "bbox": [554.68, 1665.75, 544.87, 275.99], "category_id": 1}, {"id": 30, "bbox": [2386.79, 417.49, 379.59, 205.94], "category_id": 1}, {"id": 31, "bbox": [2393.8, 1545.27, 359.98, 67.24], "category_id": 2}, {"id": 32, "bbox": [2545.07, 1497.64, 67.24, 54.63], "category_id": 3}, {"id": 33, "bbox": [2424.61, 1216.04, 306.76, 219.95], "category_id": 1}, {"id": 34, "bbox": [75.64, 1113.77, 350.17, 61.64], "category_id": 2}, {"id": 35, "bbox": [1637.42, 350.24, 39.22, 40.63], "category_id": 3}, {"id": 36, "bbox": [2385.39, 770.53, 385.2, 343.24], "category_id": 1}, {"id": 37, "bbox": [1400.7, 1064.74, 68.63, 51.83], "category_id": 3}, {"id": 38, "bbox": [1843.32, 81.26, 120.46, 50.43], "category_id": 2}, {"id": 39, "bbox": [1245.22, 1113.77, 361.38, 61.64], "category_id": 2}, {"id": 40, "bbox": [1843.32, 1546.67, 361.38, 65.84], "category_id": 2}, {"id": 41, "bbox": [1843.32, 680.87, 366.99, 60.24], "category_id": 2}, {"id": 42, "bbox": [75.64, 1113.77, 350.17, 61.64], "category_id": 2}, {"id": 43, "bbox": [1843.32, 1113.77, 373.99, 58.84], "category_id": 2}, {"id": 44, "bbox": [794.2, 1499.04, 72.83, 51.83], "category_id": 3}, {"id": 45, "bbox": [1834.92, 26.62, 142.87, 51.83], "category_id": 2}, {"id": 46, "bbox": [1834.92, 414.69, 383.79, 228.35], "category_id": 1}, {"id": 47, "bbox": [1245.22, 1113.77, 359.98, 61.64], "category_id": 2}, {"id": 48, "bbox": [1988.99, 1500.44, 75.64, 51.83], "category_id": 3}, {"id": 49, "bbox": [75.64, 678.07, 352.97, 60.24], "category_id": 2}, {"id": 50, "bbox": [1859.03, 1983.41, 386.57, 51.69], "category_id": 2}, {"id": 51, "bbox": [75.64, 1546.67, 357.18, 63.04], "category_id": 2}, {"id": 52, "bbox": [1859.41, 267.38, 87.19, 45.92], "category_id": 2}, {"id": 53, "bbox": [222.0, 1064.74, 67.94, 51.83], "category_id": 3}, {"id": 54, "bbox": [2164.08, 290.0, 53.23, 51.84], "category_id": 3}, {"id": 55, "bbox": [1988.99, 634.64, 75.64, 51.83], "category_id": 3}, {"id": 56, "bbox": [1250.83, 1971.16, 406.2, 68.65], "category_id": 2}, {"id": 57, "bbox": [1329.26, 81.26, 114.86, 40.62], "category_id": 2}, {"id": 58, "bbox": [1407.43, 639.18, 56.33, 41.64], "category_id": 3}, {"id": 59, "bbox": [1833.55, 815.51, 391.84, 210.61], "category_id": 1}, {"id": 60, "bbox": [721.71, 817.96, 215.51, 193.47], "category_id": 1}, {"id": 61, "bbox": [1243.35, 1217.14, 382.04, 200.82], "category_id": 1}, {"id": 62, "bbox": [636.0, 1224.49, 386.94, 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49.03], "category_id": 3}, {"id": 77, "bbox": [654.13, 1113.77, 350.17, 58.84], "category_id": 2}, {"id": 78, "bbox": [1785.89, 1665.75, 479.04, 247.97], "category_id": 1}, {"id": 79, "bbox": [494.45, 33.62, 428.61, 98.07], "category_id": 2}, {"id": 80, "bbox": [207.3, 29.42, 252.13, 268.99], "category_id": 1}, {"id": 81, "bbox": [1323.66, 29.42, 127.47, 47.63], "category_id": 2}, {"id": 82, "bbox": [654.13, 1546.67, 350.17, 65.84], "category_id": 2}, {"id": 83, "bbox": [2358.78, 1664.35, 441.22, 191.93], "category_id": 1}, {"id": 84, "bbox": [976.29, 29.42, 256.33, 284.4], "category_id": 1}, {"id": 85, "bbox": [1245.22, 1113.77, 359.98, 61.64], "category_id": 2}, {"id": 86, "bbox": [75.64, 812.56, 357.18, 207.34], "category_id": 1}, {"id": 87, "bbox": [1834.92, 414.69, 383.79, 228.35], "category_id": 1}, {"id": 88, "bbox": [1245.22, 1113.77, 359.98, 61.64], "category_id": 2}], "caption": "Scheme 3. Pd-Catalyzed Enantioselective Arylation Reactionsa,b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 447, 442, 469], "ImageBB": [84, 474, 784, 984]}, "reactions": [{"reactants": [71, 80], "conditions": [79, 3], "products": [84]}, {"reactants": [84], "conditions": [81, 57], "products": [74]}, {"reactants": [74], "conditions": [45, 38], "products": [67]}, {"reactants": [84], "conditions": [13, 12], "products": [1]}, {"reactants": [1], "conditions": [11, 52], "products": [67]}], "diagram_type": "graph"}, {"id": 411, "width": 1352, "height": 832, "file_name": "op400278d-Table-c12.png", "license": 0, "bboxes": [{"id": 0, "bbox": [279.0, 244.0, 169.0, 54.0], "category_id": 2}, {"id": 1, "bbox": [15.0, 467.0, 393.0, 204.0], "category_id": 1}, {"id": 2, "bbox": [413.0, 493.0, 446.0, 173.0], "category_id": 1}, {"id": 3, "bbox": [866.0, 491.0, 486.0, 182.0], "category_id": 1}, {"id": 4, "bbox": [47.0, 256.0, 181.0, 40.0], "category_id": 2}, {"id": 5, "bbox": [223.0, 685.0, 66.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [1095.0, 683.0, 45.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [640.0, 683.0, 47.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [71.0, 737.0, 382.0, 92.0], "category_id": 2}, {"id": 9, "bbox": [467.0, 732.0, 385.0, 87.0], "category_id": 2}, {"id": 10, "bbox": [913.0, 715.0, 405.0, 117.0], "category_id": 2}, {"id": 11, "bbox": [22.0, 375.0, 1061.0, 44.0], "category_id": 2}, {"id": 12, "bbox": [17.0, 329.0, 951.0, 39.0], "category_id": 2}, {"id": 13, "bbox": [591.0, 193.0, 223.0, 94.0], "category_id": 2}, {"id": 14, "bbox": [518.0, 111.0, 385.0, 52.0], "category_id": 2}, {"id": 15, "bbox": [66.0, 0.0, 136.0, 251.0], "category_id": 1}, {"id": 16, "bbox": [884.0, 97.0, 451.0, 182.0], "category_id": 1}, {"id": 17, "bbox": [301.27, 61.0, 152.0, 181.0], "category_id": 1}], "reactions": [{"reactants": [15, 17], "conditions": [14, 13], "products": [16]}], "corefs": [[1, 5], [2, 7], [3, 6]], "caption": "Table 12. Published comparison of Pd-PEPPSI-IPr (2) with Pd-PEPPSI-IPr*OMe (101) under di\ufb00erent reaction conditions ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 480, 784, 525], "ImageBB": [448, 532, 786, 740]}, "diagram_type": "single"}, {"id": 656, "width": 1352, "height": 680, "file_name": "ol403122a-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [606.0, 49.6, 645.4, 201.9], "category_id": 1}, {"id": 1, "bbox": [96.6, 48.8, 502.4, 200.2], "category_id": 1}, {"id": 2, "bbox": [738.0, 226.0, 250.0, 91.0], "category_id": 2}, {"id": 3, "bbox": [129.0, 356.0, 430.0, 239.0], "category_id": 1}, {"id": 4, "bbox": [709.0, 322.0, 459.0, 271.0], "category_id": 1}, {"id": 5, "bbox": [226.0, 234.0, 227.0, 85.0], "category_id": 2}, {"id": 6, "bbox": [233.0, 593.0, 212.0, 87.0], "category_id": 2}, {"id": 7, "bbox": [742.0, 593.0, 253.0, 87.0], "category_id": 2}], "reactions": [], "corefs": [[1, 5], [0, 2], [3, 6], [4, 7]], "caption": "Figure 1. Representative biologically active sulfones.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 765, 336, 779], "ImageBB": [82, 586, 420, 756]}, "diagram_type": "single"}, {"id": 211, "width": 1800, "height": 632, "file_name": "op0340816-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [254.8, 558.4, 43.3, 52.3], "category_id": 3}, {"id": 1, "bbox": [1197.79, 0.57, 303.31, 214.83], "category_id": 1}, {"id": 2, "bbox": [523.1, 15.0, 341.9, 212.1], "category_id": 1}, {"id": 3, "bbox": [4.0, 6.0, 265.2, 192.6], "category_id": 1}, {"id": 4, "bbox": [268.0, 152.4, 157.3, 60.1], "category_id": 2}, {"id": 5, "bbox": [306.15, 38.72, 110.85, 55.58], "category_id": 2}, {"id": 6, "bbox": [1271.0, 231.0, 67.0, 50.0], "category_id": 3}, {"id": 7, "bbox": [907.86, 141.57, 242.94, 54.03], "category_id": 2}, {"id": 8, "bbox": [922.9, 53.2, 131.6, 52.7], "category_id": 2}, {"id": 9, "bbox": [574.8, 482.1, 89.1, 54.8], "category_id": 2}, {"id": 10, "bbox": [1161.5, 467.64, 227.1, 62.46], "category_id": 2}, {"id": 11, "bbox": [1181.5, 381.4, 128.4, 55.5], "category_id": 2}, {"id": 12, "bbox": [836.5, 340.8, 307.2, 214.6], "category_id": 1}, {"id": 13, "bbox": [165.1, 321.1, 335.4, 219.9], "category_id": 1}, {"id": 14, "bbox": [920.1, 574.2, 47.6, 47.5], "category_id": 3}, {"id": 15, "bbox": [639.08, 238.57, 54.22, 58.93], "category_id": 3}, {"id": 16, "bbox": [1435.5, 344.4, 237.6, 194.2], "category_id": 1}, {"id": 17, "bbox": [1524.43, 583.12, 48.0, 46.6], "category_id": 3}, {"id": 18, "bbox": [1608.3, 36.0, 103.4, 52.8], "category_id": 2}, {"id": 19, "bbox": [1561.7, 146.6, 144.3, 67.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [5, 4], "products": [2]}, {"reactants": [2], "conditions": [8, 7], "products": [1]}, {"reactants": [1], "conditions": [18, 19], "products": [13]}, {"reactants": [13], "conditions": [9], "products": [12]}, {"reactants": [12], "conditions": [11, 10], "products": [16]}], "corefs": [[2, 15], [1, 6], [13, 0], [12, 14], [16, 17]], "caption": "Figure 1. Commercial preparation of 1-chloro-2,6-difluorobenzene.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 215, 447, 229], "ImageBB": [200, 54, 650, 212]}, "diagram_type": "multiple"}, {"id": 168, "width": 2820, "height": 1220, "file_name": "op500250b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [127.9, 237.0, 59.1, 61.0], "category_id": 3}, {"id": 1, "bbox": [398.0, 237.0, 82.1, 59.5], "category_id": 3}, {"id": 2, "bbox": [1179.1, 235.4, 56.9, 60.6], "category_id": 3}, {"id": 3, "bbox": [2112.0, 429.0, 198.0, 80.0], "category_id": 2}, {"id": 4, "bbox": [2114.0, 511.0, 179.0, 105.0], "category_id": 2}, {"id": 5, "bbox": [1777.0, 1111.0, 586.0, 74.0], "category_id": 2}, {"id": 6, "bbox": [1206.0, 1048.0, 74.0, 65.0], "category_id": 3}, {"id": 7, "bbox": [318.0, 1046.0, 65.0, 61.0], "category_id": 3}, {"id": 8, "bbox": [408.0, 625.0, 72.0, 57.0], "category_id": 3}, {"id": 9, "bbox": [1598.0, 959.0, 162.0, 112.0], "category_id": 2}, {"id": 10, "bbox": [1628.0, 865.0, 124.0, 75.0], "category_id": 2}, {"id": 11, "bbox": [667.0, 951.0, 226.0, 107.0], "category_id": 2}, {"id": 12, "bbox": [646.0, 812.0, 295.0, 131.0], "category_id": 2}, {"id": 13, "bbox": [1097.0, 522.0, 265.0, 119.9], "category_id": 2}, {"id": 14, "bbox": [1620.5, 246.44, 223.3, 51.04], "category_id": 3}, {"id": 15, "bbox": [865.51, 629.25, 71.0, 54.0], "category_id": 3}, {"id": 16, "bbox": [2061.4, 1046.0, 69.2, 60.3], "category_id": 3}, {"id": 17, "bbox": [1655.0, 627.25, 76.1, 58.4], "category_id": 3}, {"id": 18, "bbox": [2446.8, 349.3, 72.1, 54.8], "category_id": 3}, {"id": 19, "bbox": [1354.0, 98.0, 202.0, 57.0], "category_id": 2}, {"id": 20, "bbox": [1354.0, 149.0, 198.0, 118.0], "category_id": 2}, {"id": 21, "bbox": [387.6, 69.5, 271.0, 145.0], "category_id": 1}, {"id": 22, "bbox": [634.0, 77.8, 315.0, 60.8], "category_id": 2}, {"id": 23, "bbox": [720.0, 151.0, 115.5, 107.6], "category_id": 2}, {"id": 24, "bbox": [1911.9, 82.0, 174.5, 48.0], "category_id": 2}, {"id": 25, "bbox": [1932.5, 155.0, 124.5, 112.0], "category_id": 2}, {"id": 26, "bbox": [60.8, 450.5, 214.2, 66.5], "category_id": 2}, {"id": 27, "bbox": [86.3, 526.3, 117.5, 60.3], "category_id": 2}, {"id": 28, "bbox": [1076.0, 437.9, 401.7, 70.7], "category_id": 2}, {"id": 29, "bbox": [54.5, 58.9, 266.5, 147.0], "category_id": 1}, {"id": 30, "bbox": [976.4, 92.5, 396.5, 121.3], "category_id": 1}, {"id": 31, "bbox": [1570.4, 25.5, 353.6, 231.4], "category_id": 1}, {"id": 32, "bbox": [2129.0, 0.0, 641.8, 340.2], "category_id": 1}, {"id": 33, "bbox": [282.1, 398.0, 361.3, 239.0], "category_id": 1}, {"id": 34, "bbox": [774.4, 417.0, 274.1, 184.2], "category_id": 1}, {"id": 35, "bbox": [1505.5, 368.6, 589.4, 292.4], "category_id": 1}, {"id": 36, "bbox": [60.5, 843.8, 581.4, 302.9], "category_id": 1}, {"id": 37, "bbox": [960.3, 730.0, 608.6, 416.2], "category_id": 1}, {"id": 38, "bbox": [1812.6, 731.9, 618.3, 408.2], "category_id": 1}], "reactions": [{"reactants": [29, 21], "conditions": [22, 23], "products": [30]}, {"reactants": [30], "conditions": [19, 20], "products": [31]}, {"reactants": [31], "conditions": [24, 25], "products": [32]}, {"reactants": [32], "conditions": [26, 27], "products": [33, 34]}, {"reactants": [33, 34], "conditions": [28, 13], "products": [35]}, {"reactants": [35], "conditions": [3, 4], "products": [36]}, {"reactants": [36], "conditions": [12, 11], "products": [37]}, {"reactants": [37], "conditions": [10, 9], "products": [38]}], "corefs": [[29, 0], [21, 1], [30, 2], [31, 14], [32, 18], [33, 8], [34, 15], [35, 17], [36, 7], [37, 6], [38, 16]], "caption": "Table 1. E\ufb00ect of solvents and additives in the [3 + 2] dipolar cycloadditiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 713, 521, 734], "ImageBB": [82, 407, 787, 712]}, "diagram_type": "multiple"}, {"id": 1322, "width": 3396, "height": 1028, "file_name": "op300331b-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1861.94, 86.54, 122.32, 64.47], "category_id": 2}, {"id": 1, "bbox": [1920.84, 191.34, 225.37, 97.32], "category_id": 2}, {"id": 2, "bbox": [2075.99, 81.45, 158.0, 64.47], "category_id": 2}, {"id": 3, "bbox": [913.98, 566.73, 79.85, 64.48], "category_id": 3}, {"id": 4, "bbox": [1600.32, 668.54, 69.65, 59.38], "category_id": 3}, {"id": 5, "bbox": [2313.83, 27.15, 239.54, 152.71], "category_id": 1}, {"id": 6, "bbox": [1306.42, 86.54, 185.17, 61.08], "category_id": 2}, {"id": 7, "bbox": [1306.42, 352.93, 703.32, 407.23], "category_id": 1}, {"id": 8, "bbox": [910.58, 45.81, 254.83, 154.41], "category_id": 1}, {"id": 9, "bbox": [2408.97, 561.64, 45.87, 59.39], "category_id": 3}, {"id": 10, "bbox": [835.83, 251.13, 353.36, 98.41], "category_id": 2}, {"id": 11, "bbox": [1133.13, 529.4, 64.56, 61.08], "category_id": 3}, {"id": 12, "bbox": [2364.8, 342.75, 59.46, 54.3], "category_id": 3}, {"id": 13, "bbox": [2096.38, 515.83, 191.97, 61.08], "category_id": 2}, {"id": 14, "bbox": [1517.07, 5.09, 292.2, 88.23], "category_id": 2}], "caption": "Scheme 10. Formation of unwanted diacylation side product 23", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 838, 442, 853], "ImageBB": [10, 870, 859, 1127]}, "reactions": [{"reactants": [8, 6], "conditions": [14], "products": [0, 2, 5]}, {"reactants": [5], "conditions": [12], "products": [9]}, {"reactants": [9], "conditions": [13], "products": [7]}, {"reactants": [7], "conditions": [11], "products": [3]}], "diagram_type": "tree"}, {"id": 662, "width": 1348, "height": 1564, "file_name": "ol402138y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [636.0, 127.0, 297.9, 52.9], "category_id": 2}, {"id": 1, "bbox": [10.0, 340.0, 1338.0, 1221.0], "category_id": 4}, {"id": 2, "bbox": [1132.0, 242.0, 55.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [189.0, 236.0, 54.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [468.0, 98.0, 156.0, 57.0], "category_id": 2}, {"id": 5, "bbox": [725.0, 60.0, 110.0, 55.0], "category_id": 2}, {"id": 6, "bbox": [995.1, 0.0, 290.9, 242.4], "category_id": 1}, {"id": 7, "bbox": [68.1, 21.0, 316.8, 224.9], "category_id": 1}], "reactions": [{"reactants": [7, 4], "conditions": [5, 0], "products": [6]}], "corefs": [[7, 3], [6, 2]], "caption": "Table 1. Reaction Condition Screeninga", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 313, 649, 329], "ImageBB": [436, 339, 773, 730]}, "diagram_type": "single"}, {"id": 1215, "width": 920, "height": 916, "file_name": "ol802674r-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [153.72, 227.85, 39.58, 44.19], "category_id": 3}, {"id": 1, "bbox": [0.0, 0.0, 291.79, 221.4], "category_id": 1}, {"id": 2, "bbox": [0.0, 334.64, 313.88, 224.63], "category_id": 1}, {"id": 3, "bbox": [0.0, 642.12, 304.21, 159.26], "category_id": 1}, {"id": 4, "bbox": [288.1, 762.26, 214.47, 54.31], "category_id": 2}, {"id": 5, "bbox": [140.37, 563.41, 40.96, 41.89], "category_id": 3}, {"id": 6, "bbox": [669.63, 865.83, 58.91, 47.41], "category_id": 3}, {"id": 7, "bbox": [289.48, 471.35, 210.33, 52.47], "category_id": 2}, {"id": 8, "bbox": [361.74, 672.5, 52.47, 49.25], "category_id": 2}, {"id": 9, "bbox": [301.45, 168.93, 209.87, 52.47], "category_id": 2}, {"id": 10, "bbox": [361.74, 78.71, 47.86, 48.79], "category_id": 2}, {"id": 11, "bbox": [141.75, 800.0, 42.8, 46.95], "category_id": 3}, {"id": 12, "bbox": [420.65, 614.96, 458.35, 255.47], "category_id": 1}, {"id": 13, "bbox": [432.62, 0.0, 455.48, 300.12], "category_id": 1}, {"id": 14, "bbox": [444.58, 312.08, 460.02, 290.45], "category_id": 1}, {"id": 15, "bbox": [368.72, 390.38, 38.48, 43.98], "category_id": 2}, {"id": 16, "bbox": [661.22, 572.92, 37.39, 39.59], "category_id": 3}, {"id": 17, "bbox": [650.22, 259.52, 36.29, 43.99], "category_id": 3}, {"id": 18, "bbox": [803.07, 821.44, 90.17, 49.48], "category_id": 2}, {"id": 19, "bbox": [820.67, 521.24, 93.47, 49.48], "category_id": 2}, {"id": 20, "bbox": [816.27, 225.43, 91.27, 48.39], "category_id": 2}], "caption": "Scheme 2. Compounds Obtained by Variation of the             Bis-Secondary Aminea ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [456, 74, 729, 102], "ImageBB": [478, 110, 708, 339]}, "reactions": [{"reactants": [1], "conditions": [10, 9], "products": [13]}, {"reactants": [2], "conditions": [15, 7], "products": [14]}, {"reactants": [3], "conditions": [8, 4], "products": [12]}], "diagram_type": "multiple"}, {"id": 1094, "width": 1276, "height": 1140, "file_name": "jo961049j-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [218.31, 473.6, 259.15, 97.02], "category_id": 2}, {"id": 1, "bbox": [155.75, 314.03, 70.21, 52.34], "category_id": 3}, {"id": 2, "bbox": [1013.01, 511.26, 195.97, 99.57], "category_id": 2}, {"id": 3, "bbox": [783.22, 0.0, 479.38, 251.48], "category_id": 1}, {"id": 4, "bbox": [7.66, 30.64, 477.46, 290.41], "category_id": 1}, {"id": 5, "bbox": [490.23, 884.65, 171.71, 53.62], "category_id": 2}, {"id": 6, "bbox": [942.8, 366.37, 125.75, 49.15], "category_id": 2}, {"id": 7, "bbox": [764.71, 755.08, 478.74, 280.92], "category_id": 1}, {"id": 8, "bbox": [976.63, 1082.52, 65.11, 51.06], "category_id": 3}, {"id": 9, "bbox": [976.63, 307.01, 66.38, 54.26], "category_id": 3}, {"id": 10, "bbox": [466.61, 947.21, 225.33, 146.16], "category_id": 2}, {"id": 11, "bbox": [7.66, 792.1, 430.23, 287.23], "category_id": 1}, {"id": 12, "bbox": [52.34, 540.62, 118.73, 55.53], "category_id": 2}, {"id": 13, "bbox": [204.9, 585.3, 285.97, 88.08], "category_id": 2}, {"id": 14, "bbox": [159.58, 1091.46, 62.56, 46.59], "category_id": 3}], "caption": "Scheme 8", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 603, 635, 617], "ImageBB": [447, 623, 766, 908]}, "reactions": [{"reactants": [4], "conditions": [12, 0, 13], "products": [11]}, {"reactants": [11], "conditions": [5, 10], "products": [7]}, {"reactants": [7], "conditions": [2], "products": [3]}], "diagram_type": "tree"}, {"id": 170, "width": 1356, "height": 392, "file_name": "op5002462-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [89.7, 140.7, 329.3, 196.2], "category_id": 1}, {"id": 1, "bbox": [500.0, 234.0, 222.9, 107.9], "category_id": 2}, {"id": 2, "bbox": [826.1, 130.6, 444.8, 209.3], "category_id": 1}, {"id": 3, "bbox": [458.4, 36.4, 310.1, 175.5], "category_id": 1}, {"id": 4, "bbox": [1043.0, 351.0, 47.0, 36.0], "category_id": 3}, {"id": 5, "bbox": [231.0, 347.0, 49.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 1], "products": [2]}], "corefs": [[0, 5], [2, 4]], "caption": "Figure 1. Kharasch\u2212Sosnovsky oxidation of valencene.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 834, 711, 848], "ImageBB": [448, 727, 787, 825]}, "diagram_type": "single"}, {"id": 604, "width": 1352, "height": 644, "file_name": "acs.oprd.5b00418-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.0, 124.5, 112.7, 258.3], "category_id": 1}, {"id": 1, "bbox": [954.0, 536.0, 398.0, 64.0], "category_id": 2}, {"id": 2, "bbox": [1090.1, 480.8, 45.6, 47.2], "category_id": 3}, {"id": 3, "bbox": [793.4, 3.0, 121.6, 437.7], "category_id": 1}, {"id": 4, "bbox": [197.1, 482.0, 52.3, 53.9], "category_id": 3}, {"id": 5, "bbox": [1060.6, 2.9, 135.4, 459.1], "category_id": 1}, {"id": 6, "bbox": [819.0, 478.94, 48.08, 52.86], "category_id": 3}, {"id": 7, "bbox": [454.6, 178.4, 230.2, 55.6], "category_id": 2}, {"id": 8, "bbox": [24.96, 480.98, 45.5, 54.9], "category_id": 3}, {"id": 9, "bbox": [171.0, 124.0, 179.0, 284.0], "category_id": 1}, {"id": 10, "bbox": [490.2, 277.0, 145.8, 51.9], "category_id": 2}], "reactions": [{"reactants": [0, 9], "conditions": [7, 10], "products": [3, 5]}], "corefs": [[0, 8], [9, 4], [3, 6], [5, 2]], "caption": "Table 1. Performance of the Complexes in Batchwise Suzuki Cross-Coupling of 5 and 6 (Laboratory Equipment and Conditions)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 283, 417, 328], "ImageBB": [82, 116, 420, 277]}, "diagram_type": "single"}, {"id": 856, "width": 1344, "height": 496, "file_name": "jo200666z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [994.2, 4.0, 335.8, 310.0], "category_id": 1}, {"id": 1, "bbox": [1062.0, 267.0, 45.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [650.0, 165.0, 302.0, 92.0], "category_id": 2}, {"id": 3, "bbox": [3.0, 402.0, 1332.0, 87.0], "category_id": 4}, {"id": 4, "bbox": [16.0, 6.0, 320.0, 200.0], "category_id": 1}, {"id": 5, "bbox": [393.0, 123.0, 219.0, 89.0], "category_id": 1}, {"id": 6, "bbox": [635.0, 98.0, 311.0, 52.0], "category_id": 2}, {"id": 7, "bbox": [138.0, 265.0, 51.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [443.0, 269.0, 48.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [4, 5], "conditions": [6, 2], "products": [0]}], "corefs": [[4, 7], [5, 8], [0, 1]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 87, 700, 108], "ImageBB": [437, 117, 773, 241]}, "diagram_type": "single"}, {"id": 884, "width": 1356, "height": 1320, "file_name": "ol503587n-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [939.2, 945.5, 210.2, 49.8], "category_id": 3}, {"id": 1, "bbox": [983.3, 1048.3, 265.5, 153.7], "category_id": 1}, {"id": 2, "bbox": [491.1, 1018.8, 391.0, 190.5], "category_id": 1}, {"id": 3, "bbox": [63.8, 1047.2, 391.7, 154.4], "category_id": 1}, {"id": 4, "bbox": [68.8, 744.0, 371.8, 202.9], "category_id": 1}, {"id": 5, "bbox": [493.9, 755.5, 302.6, 182.0], "category_id": 1}, {"id": 6, "bbox": [887.6, 739.5, 405.4, 199.5], "category_id": 1}, {"id": 7, "bbox": [836.8, 474.4, 407.7, 201.6], "category_id": 1}, {"id": 8, "bbox": [517.0, 479.2, 301.7, 181.8], "category_id": 1}, {"id": 9, "bbox": [77.72, 481.2, 303.98, 182.8], "category_id": 1}, {"id": 10, "bbox": [432.6, 260.5, 368.3, 143.8], "category_id": 2}, {"id": 11, "bbox": [841.4, 130.42, 421.9, 186.98], "category_id": 1}, {"id": 12, "bbox": [490.7, 1.7, 234.7, 210.8], "category_id": 1}, {"id": 13, "bbox": [119.6, 253.7, 249.7, 131.4], "category_id": 1}, {"id": 14, "bbox": [93.8, 33.8, 264.1, 181.3], "category_id": 1}, {"id": 15, "bbox": [954.3, 671.0, 203.2, 41.9], "category_id": 3}, {"id": 16, "bbox": [952.7, 1224.7, 208.0, 57.9], "category_id": 3}, {"id": 17, "bbox": [533.4, 1224.4, 312.4, 90.9], "category_id": 3}, {"id": 18, "bbox": [157.2, 1221.0, 297.0, 57.0], "category_id": 3}, {"id": 19, "bbox": [147.7, 938.8, 202.2, 50.1], "category_id": 3}, {"id": 20, "bbox": [541.1, 946.0, 214.1, 51.3], "category_id": 3}, {"id": 21, "bbox": [568.8, 666.6, 187.5, 50.5], "category_id": 3}, {"id": 22, "bbox": [146.2, 665.3, 189.0, 50.1], "category_id": 3}, {"id": 23, "bbox": [879.0, 494.0, 8.0, 3.0], "category_id": 1}, {"id": 24, "bbox": [593.01, 183.74, 185.41, 52.73], "category_id": 2}], "reactions": [{"reactants": [14, 13], "conditions": [12, 24, 10], "products": [11]}], "corefs": [[9, 22], [8, 21], [7, 15], [4, 19], [5, 20], [6, 0], [3, 18], [2, 17], [1, 16]], "caption": "Figure 3. Products formed by coupling of aromatic amines with benzyl alcohols; 7 in toluene, 110 \u00b0C, 48 h, 9\u221216 in xylene, 140 \u00b0C, 24 h. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 470, 784, 499], "ImageBB": [448, 131, 787, 461]}, "diagram_type": "single"}, {"id": 1226, "width": 1248, "height": 888, "file_name": "op0100706-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [547.52, 0.0, 415.79, 194.88], "category_id": 1}, {"id": 1, "bbox": [14.98, 648.99, 494.46, 148.04], "category_id": 1}, {"id": 2, "bbox": [0.0, 255.47, 417.66, 206.13], "category_id": 1}, {"id": 3, "bbox": [0.0, 14.99, 416.42, 143.04], "category_id": 2}, {"id": 4, "bbox": [596.22, 255.47, 466.98, 206.13], "category_id": 1}, {"id": 5, "bbox": [405.8, 337.92, 227.88, 48.73], "category_id": 2}, {"id": 6, "bbox": [0.0, 14.99, 416.42, 143.04], "category_id": 2}, {"id": 7, "bbox": [596.22, 647.12, 367.09, 231.73], "category_id": 1}, {"id": 8, "bbox": [329.81, 782.45, 29.85, 31.98], "category_id": 3}, {"id": 9, "bbox": [809.73, 536.56, 59.94, 51.22], "category_id": 2}, {"id": 10, "bbox": [181.05, 428.5, 41.83, 43.09], "category_id": 3}, {"id": 11, "bbox": [752.3, 416.63, 43.7, 47.47], "category_id": 3}, {"id": 12, "bbox": [1209.29, 294.82, 38.71, 51.85], "category_id": 3}, {"id": 13, "bbox": [962.69, 251.1, 188.54, 54.97], "category_id": 2}, {"id": 14, "bbox": [736.69, 838.88, 45.57, 44.35], "category_id": 3}], "caption": "Scheme 2. Outline of cephalosporin C biosynthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 572, 362, 586], "ImageBB": [86, 591, 398, 813]}, "reactions": [{"reactants": [6], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [13], "products": [12]}, {"reactants": [4], "conditions": [9], "products": [7]}], "diagram_type": "tree"}, {"id": 581, "width": 1352, "height": 1800, "file_name": "acs.orglett.5b00312-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [401.71, 41.71, 188.1, 141.08], "category_id": 1}, {"id": 1, "bbox": [237.13, 138.37, 49.63, 41.8], "category_id": 3}, {"id": 2, "bbox": [425.22, 135.76, 49.64, 47.03], "category_id": 3}, {"id": 3, "bbox": [1020.87, 135.76, 54.86, 47.03], "category_id": 3}, {"id": 4, "bbox": [873.0, 24.0, 361.0, 159.0], "category_id": 1}, {"id": 5, "bbox": [664.0, 9.0, 137.0, 72.0], "category_id": 2}, {"id": 6, "bbox": [695.0, 116.0, 76.0, 37.0], "category_id": 2}, {"id": 7, "bbox": [23.0, 201.0, 1270.0, 1576.0], "category_id": 4}, {"id": 8, "bbox": [127.8, 13.4, 182.1, 172.5], "category_id": 1}], "reactions": [{"reactants": [8, 0], "conditions": [5, 6], "products": [4]}], "corefs": [[8, 1], [0, 2], [4, 3]], "caption": "Table 1. Optimization of the Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 365, 111], "ImageBB": [82, 116, 420, 566]}, "diagram_type": "single"}, {"id": 326, "width": 1472, "height": 3684, "file_name": "ol301535j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [876.0, 467.0, 224.0, 247.0], "category_id": 1}, {"id": 1, "bbox": [862.0, 736.0, 253.0, 252.0], "category_id": 1}, {"id": 2, "bbox": [837.0, 1041.0, 299.0, 252.0], "category_id": 1}, {"id": 3, "bbox": [848.0, 1349.0, 266.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [872.0, 1658.0, 233.0, 256.0], "category_id": 1}, {"id": 5, "bbox": [834.0, 1937.0, 313.0, 252.0], "category_id": 1}, {"id": 6, "bbox": [847.0, 2213.0, 271.0, 256.0], "category_id": 1}, {"id": 7, "bbox": [859.0, 2526.0, 280.0, 241.0], "category_id": 1}, {"id": 8, "bbox": [447.0, 2628.0, 260.0, 59.0], "category_id": 2}, {"id": 9, "bbox": [440.0, 2319.0, 269.0, 65.0], "category_id": 2}, {"id": 10, "bbox": [487.0, 2032.0, 174.0, 79.0], "category_id": 2}, {"id": 11, "bbox": [465.0, 1756.0, 217.0, 87.0], "category_id": 2}, {"id": 12, "bbox": [458.0, 1474.0, 235.0, 72.0], "category_id": 2}, {"id": 13, "bbox": [440.0, 1130.0, 271.0, 94.0], "category_id": 2}, {"id": 14, "bbox": [415.0, 833.0, 322.0, 83.0], "category_id": 2}, {"id": 15, "bbox": [880.0, 2755.0, 61.0, 40.0], "category_id": 3}, {"id": 16, "bbox": [901.0, 2453.0, 52.0, 37.0], "category_id": 3}, {"id": 17, "bbox": [875.0, 2168.0, 46.0, 47.0], "category_id": 3}, {"id": 18, "bbox": [921.0, 1896.0, 51.0, 41.0], "category_id": 3}, {"id": 19, "bbox": [900.0, 1616.0, 52.0, 42.0], "category_id": 3}, {"id": 20, "bbox": [879.0, 1282.0, 49.0, 35.0], "category_id": 3}, {"id": 21, "bbox": [903.0, 970.0, 51.0, 39.0], "category_id": 3}, {"id": 22, "bbox": [918.0, 701.0, 55.0, 35.0], "category_id": 3}, {"id": 23, "bbox": [943.0, 233.0, 80.0, 32.0], "category_id": 3}, {"id": 24, "bbox": [540.0, 229.0, 36.0, 38.0], "category_id": 3}, {"id": 25, "bbox": [487.0, 18.0, 218.0, 213.0], "category_id": 1}, {"id": 26, "bbox": [156.99, 303.68, 1291.31, 2625.33], "category_id": 4}, {"id": 27, "bbox": [440.0, 568.0, 264.0, 83.0], "category_id": 2}, {"id": 28, "bbox": [903.0, 4.0, 205.0, 245.0], "category_id": 1}, {"id": 29, "bbox": [734.0, 49.0, 106.0, 56.0], "category_id": 2}, {"id": 30, "bbox": [696.0, 112.0, 200.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [25], "conditions": [29, 30], "products": [28]}], "corefs": [[25, 24], [28, 23], [0, 22], [1, 21], [2, 20], [3, 19], [4, 18], [5, 17], [6, 16], [7, 15]], "caption": "Table 1. Tandem Reactions Initiated by an Epoxide Ring Opening Using NaN3, Followed by 7-endo-trig Intramolecular Oxa-Michael Addition ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 770, 128], "ImageBB": [405, 139, 773, 1060]}, "diagram_type": "single"}, {"id": 646, "width": 1352, "height": 440, "file_name": "ol500618w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.6, 49.4, 270.5, 136.7], "category_id": 1}, {"id": 1, "bbox": [1065.7, 49.3, 282.8, 140.0], "category_id": 1}, {"id": 2, "bbox": [439.4, 61.5, 151.8, 112.4], "category_id": 1}, {"id": 3, "bbox": [439.0, 248.0, 164.0, 45.5], "category_id": 2}, {"id": 4, "bbox": [675.0, 0.0, 324.0, 96.8], "category_id": 2}, {"id": 5, "bbox": [501.0, 204.0, 38.0, 42.0], "category_id": 3}, {"id": 6, "bbox": [1184.0, 203.0, 53.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [75.0, 247.0, 144.0, 47.0], "category_id": 2}, {"id": 8, "bbox": [702.0, 147.0, 264.0, 154.0], "category_id": 2}, {"id": 9, "bbox": [13.0, 320.0, 1339.0, 120.0], "category_id": 4}, {"id": 10, "bbox": [116.0, 206.0, 55.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [0, 2], "conditions": [4, 8], "products": [1]}], "corefs": [[0, 10], [2, 5], [1, 6]], "caption": "Table 1. Screening Conditions for the Palladium-Catalyzed Cyanation of Alkenyl Bromide 1a ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 435, 782, 465], "ImageBB": [448, 472, 786, 582]}, "diagram_type": "single"}, {"id": 521, "width": 1344, "height": 484, "file_name": "jo0109321-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [5.0, 291.0, 1339.0, 193.0], "category_id": 4}, {"id": 1, "bbox": [325.0, 125.0, 212.0, 39.0], "category_id": 2}, {"id": 2, "bbox": [614.0, 62.0, 55.0, 44.0], "category_id": 2}, {"id": 3, "bbox": [335.0, 2.0, 189.0, 101.0], "category_id": 2}, {"id": 4, "bbox": [1080.0, 17.0, 225.0, 222.0], "category_id": 1}, {"id": 5, "bbox": [712.0, 21.0, 343.0, 174.0], "category_id": 1}, {"id": 6, "bbox": [28.0, 3.0, 243.0, 173.0], "category_id": 1}, {"id": 7, "bbox": [865.0, 197.0, 31.0, 37.0], "category_id": 3}, {"id": 8, "bbox": [1154.0, 209.0, 32.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [3, 1, 2], "products": [5, 4]}], "corefs": [[5, 7], [4, 8]], "caption": "Table 7. Hydroboration of 3,3-Dimethyl-1-butene with                 BH3-THF in THFa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [82, 716, 401, 742], "ImageBB": [74, 750, 410, 871]}, "diagram_type": "single"}, {"id": 92, "width": 1348, "height": 732, "file_name": "ja053368a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [202.2, 4.6, 362.78, 113.7], "category_id": 1}, {"id": 1, "bbox": [1140.74, 57.24, 189.45, 31.56], "category_id": 2}, {"id": 2, "bbox": [17.31, 57.24, 112.42, 32.82], "category_id": 2}, {"id": 3, "bbox": [602.78, 14.87, 479.62, 39.24], "category_id": 2}, {"id": 4, "bbox": [736.31, 90.62, 212.56, 36.67], "category_id": 2}, {"id": 5, "bbox": [7.04, 157.39, 1334.71, 568.21], "category_id": 4}], "reactions": [{"reactants": [2, 0], "conditions": [3, 4], "products": [1]}], "corefs": [], "caption": "Table 3. DA Reaction of Dienes with R-(p-Methoxybenzoyloxy)acroleina ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 628, 88], "ImageBB": [439, 92, 776, 275]}, "diagram_type": "single"}, {"id": 1319, "width": 1356, "height": 1036, "file_name": "op300252n-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [207.57, 891.03, 54.95, 44.11], "category_id": 3}, {"id": 1, "bbox": [712.26, 454.0, 156.01, 46.15], "category_id": 2}, {"id": 2, "bbox": [326.28, 140.48, 124.14, 51.57], "category_id": 2}, {"id": 3, "bbox": [94.97, 409.89, 52.91, 41.4], "category_id": 3}, {"id": 4, "bbox": [429.39, 724.09, 54.94, 46.15], "category_id": 3}, {"id": 5, "bbox": [539.96, 318.27, 268.62, 86.19], "category_id": 2}, {"id": 6, "bbox": [485.01, 452.64, 50.2, 41.4], "category_id": 3}, {"id": 7, "bbox": [0.0, 492.0, 484.33, 375.96], "category_id": 1}, {"id": 8, "bbox": [557.59, 561.9, 292.37, 328.45], "category_id": 1}, {"id": 9, "bbox": [96.32, 935.14, 263.88, 48.19], "category_id": 2}, {"id": 10, "bbox": [0.0, 84.15, 301.18, 213.09], "category_id": 1}, {"id": 11, "bbox": [909.65, 721.38, 58.34, 44.11], "category_id": 2}, {"id": 12, "bbox": [511.47, 16.29, 349.34, 296.56], "category_id": 1}, {"id": 13, "bbox": [980.88, 476.39, 293.72, 403.11], "category_id": 1}, {"id": 14, "bbox": [983.59, 84.15, 294.4, 212.41], "category_id": 1}, {"id": 15, "bbox": [941.53, 345.42, 56.99, 44.11], "category_id": 2}, {"id": 16, "bbox": [1026.33, 403.78, 154.66, 45.47], "category_id": 2}, {"id": 17, "bbox": [175.01, 304.02, 50.2, 42.08], "category_id": 3}, {"id": 18, "bbox": [688.51, 899.86, 56.31, 42.07], "category_id": 3}, {"id": 19, "bbox": [909.65, 936.5, 438.21, 48.86], "category_id": 2}, {"id": 20, "bbox": [940.18, 154.05, 56.98, 42.75], "category_id": 2}, {"id": 21, "bbox": [1137.57, 298.59, 54.95, 40.72], "category_id": 3}, {"id": 22, "bbox": [1102.3, 895.78, 53.59, 42.76], "category_id": 3}], "caption": "Scheme 5. Chlorination of Pyrrolotriazine 12", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 705, 110], "ImageBB": [448, 116, 787, 375]}, "reactions": [{"reactants": [10], "conditions": [2], "products": [12]}, {"reactants": [12], "conditions": [20], "products": [14]}, {"reactants": [10], "conditions": [3], "products": [7]}, {"reactants": [12], "conditions": [6], "products": [7]}, {"reactants": [12], "conditions": [1], "products": [8]}, {"reactants": [8], "conditions": [4], "products": [7]}, {"reactants": [8], "conditions": [15], "products": [14]}, {"reactants": [14], "conditions": [16], "products": [8]}, {"reactants": [8], "conditions": [11], "products": [13]}], "diagram_type": "graph"}, {"id": 945, "width": 1356, "height": 1784, "file_name": "acs.orglett.5b02003-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [675.71, 1535.9, 230.3, 55.33], "category_id": 2}, {"id": 1, "bbox": [813.18, 714.85, 383.83, 262.38], "category_id": 1}, {"id": 2, "bbox": [353.48, 1061.12, 668.57, 340.91], "category_id": 1}, {"id": 3, "bbox": [432.03, 1635.85, 89.26, 56.23], "category_id": 3}, {"id": 4, "bbox": [1005.99, 306.11, 320.45, 55.33], "category_id": 2}, {"id": 5, "bbox": [1112.21, 1643.89, 84.8, 43.73], "category_id": 3}, {"id": 6, "bbox": [148.18, 1640.32, 65.16, 49.97], "category_id": 3}, {"id": 7, "bbox": [22.32, 270.41, 294.56, 54.44], "category_id": 2}, {"id": 8, "bbox": [605.2, 81.21, 364.19, 53.55], "category_id": 2}, {"id": 9, "bbox": [559.67, 788.92, 161.57, 58.01], "category_id": 2}, {"id": 10, "bbox": [680.18, 145.47, 229.4, 54.44], "category_id": 2}, {"id": 11, "bbox": [905.12, 639.88, 239.22, 55.34], "category_id": 3}, {"id": 12, "bbox": [998.84, 1684.05, 327.6, 56.22], "category_id": 2}, {"id": 13, "bbox": [994.87, 1404.99, 334.1, 235.59], "category_id": 1}, {"id": 14, "bbox": [1106.23, 259.21, 74.96, 49.26], "category_id": 3}, {"id": 15, "bbox": [22.32, 1429.7, 332.94, 190.98], "category_id": 1}, {"id": 16, "bbox": [22.32, 49.08, 362.4, 208.84], "category_id": 1}, {"id": 17, "bbox": [494.51, 854.96, 283.86, 56.23], "category_id": 2}, {"id": 18, "bbox": [969.39, 0.0, 364.19, 264.16], "category_id": 1}, {"id": 19, "bbox": [813.18, 374.83, 448.09, 262.38], "category_id": 1}, {"id": 20, "bbox": [680.18, 1351.16, 66.94, 53.55], "category_id": 3}, {"id": 21, "bbox": [605.2, 1472.54, 375.79, 54.44], "category_id": 2}, {"id": 22, "bbox": [22.32, 532.79, 374.0, 270.41], "category_id": 1}, {"id": 23, "bbox": [554.32, 448.9, 177.63, 64.26], "category_id": 2}, {"id": 24, "bbox": [126.75, 223.11, 65.16, 48.19], "category_id": 3}, {"id": 25, "bbox": [160.67, 802.31, 95.51, 57.12], "category_id": 3}, {"id": 26, "bbox": [321.34, 38.38, 294.57, 173.13], "category_id": 1}, {"id": 27, "bbox": [432.03, 217.76, 72.3, 53.54], "category_id": 3}, {"id": 28, "bbox": [353.48, 1435.95, 253.5, 170.45], "category_id": 1}, {"id": 29, "bbox": [494.51, 516.73, 283.86, 54.44], "category_id": 2}, {"id": 30, "bbox": [905.12, 978.12, 237.44, 55.33], "category_id": 3}], "caption": "Scheme 2. Gram-Scale Synthesis and Further Transformations of the Cycloadduct ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 703, 125], "ImageBB": [448, 131, 787, 577]}, "reactions": [{"reactants": [16, 26], "conditions": [8, 10], "products": [18]}, {"reactants": [22], "conditions": [23, 29], "products": [19]}, {"reactants": [22], "conditions": [9, 17], "products": [1]}, {"reactants": [15, 28], "conditions": [21, 0], "products": [13]}], "diagram_type": "tree"}, {"id": 1307, "width": 1356, "height": 880, "file_name": "op300147f-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1085.99, 181.58, 132.61, 60.37], "category_id": 2}, {"id": 1, "bbox": [116.0, 796.44, 53.58, 42.74], "category_id": 3}, {"id": 2, "bbox": [521.64, 0.0, 215.04, 278.82], "category_id": 1}, {"id": 3, "bbox": [21.03, 0.0, 218.42, 280.86], "category_id": 1}, {"id": 4, "bbox": [1274.52, 182.57, 56.7, 58.97], "category_id": 2}, {"id": 5, "bbox": [335.78, 77.34, 53.59, 59.02], "category_id": 2}, {"id": 6, "bbox": [517.57, 502.01, 224.53, 278.82], "category_id": 1}, {"id": 7, "bbox": [1107.05, 690.61, 170.94, 52.23], "category_id": 2}, {"id": 8, "bbox": [1096.87, 499.98, 191.97, 142.46], "category_id": 1}, {"id": 9, "bbox": [613.22, 795.76, 50.87, 40.7], "category_id": 3}, {"id": 10, "bbox": [21.03, 498.62, 324.92, 280.86], "category_id": 1}, {"id": 11, "bbox": [116.0, 274.75, 39.34, 48.17], "category_id": 3}, {"id": 12, "bbox": [381.23, 591.56, 90.89, 50.2], "category_id": 2}, {"id": 13, "bbox": [643.74, 272.72, 48.84, 50.2], "category_id": 3}, {"id": 14, "bbox": [652.56, 358.87, 214.44, 63.09], "category_id": 2}], "caption": "Scheme 3. Proposed reaction scheme for the conversion of 1 to 2 in the presence of sulfur and triethyl amine ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 522, 784, 552], "ImageBB": [448, 559, 787, 779]}, "reactions": [{"reactants": [3], "conditions": [5], "products": [2]}, {"reactants": [2], "conditions": [14], "products": [6]}, {"reactants": [6], "conditions": [12], "products": [10]}, {"reactants": [0, 4], "conditions": [14], "products": [8, 7]}], "diagram_type": "tree"}, {"id": 1306, "width": 1352, "height": 440, "file_name": "op300101d-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [468.7, 139.94, 121.07, 37.19], "category_id": 2}, {"id": 1, "bbox": [626.97, 4.06, 130.53, 161.57], "category_id": 1}, {"id": 2, "bbox": [0.0, 27.04, 131.21, 141.97], "category_id": 1}, {"id": 3, "bbox": [275.4, 307.0, 79.6, 39.5], "category_id": 2}, {"id": 4, "bbox": [953.64, 305.9, 105.66, 41.6], "category_id": 2}, {"id": 5, "bbox": [387.45, 306.7, 114.2, 39.76], "category_id": 2}, {"id": 6, "bbox": [1090.98, 305.68, 132.55, 41.8], "category_id": 2}, {"id": 7, "bbox": [169.08, 75.72, 66.96, 41.24], "category_id": 2}, {"id": 8, "bbox": [1082.14, 128.45, 99.42, 40.56], "category_id": 2}, {"id": 9, "bbox": [1082.14, 69.63, 93.34, 43.95], "category_id": 2}, {"id": 10, "bbox": [778.47, 276.51, 109.56, 104.78], "category_id": 1}, {"id": 11, "bbox": [294.88, 29.07, 133.92, 171.04], "category_id": 1}, {"id": 12, "bbox": [780.49, 140.62, 98.75, 36.51], "category_id": 2}, {"id": 13, "bbox": [801.46, 77.07, 69.66, 38.53], "category_id": 2}, {"id": 14, "bbox": [107.54, 251.49, 126.47, 140.62], "category_id": 1}, {"id": 15, "bbox": [470.06, 73.69, 119.71, 43.27], "category_id": 2}, {"id": 16, "bbox": [1241.76, 65.58, 110.24, 105.46], "category_id": 1}, {"id": 17, "bbox": [940.79, 5.8, 100.09, 163.21], "category_id": 1}], "caption": "Scheme 2. Simpli\ufb01ed mechanism of oxime reduction by sodium in alcohols13 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 258, 397, 288], "ImageBB": [82, 295, 420, 405]}, "reactions": [{"reactants": [2], "conditions": [7], "products": [11]}, {"reactants": [11], "conditions": [15, 0], "products": [1]}, {"reactants": [1], "conditions": [13, 12], "products": [17]}, {"reactants": [17], "conditions": [9, 8], "products": [16]}, {"reactants": [14, 3, 5], "conditions": [], "products": [10, 4, 6]}], "diagram_type": "multiple"}, {"id": 1272, "width": 1880, "height": 1576, "file_name": "op100010n-Scheme-c11.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1184.99, 1100.79, 128.85, 71.51], "category_id": 2}, {"id": 1, "bbox": [1249.88, 1089.5, 624.48, 419.62], "category_id": 1}, {"id": 2, "bbox": [0.0, 1053.75, 604.72, 420.56], "category_id": 1}, {"id": 3, "bbox": [1181.23, 0.0, 698.77, 421.5], "category_id": 1}, {"id": 4, "bbox": [880.28, 1015.18, 240.76, 94.08], "category_id": 2}, {"id": 5, "bbox": [1404.12, 461.96, 62.07, 50.8], "category_id": 3}, {"id": 6, "bbox": [732.63, 555.1, 698.77, 417.74], "category_id": 1}, {"id": 7, "bbox": [220.07, 1527.94, 54.55, 47.98], "category_id": 3}, {"id": 8, "bbox": [1490.65, 1527.94, 63.95, 47.98], "category_id": 3}, {"id": 9, "bbox": [550.18, 1055.63, 111.91, 64.92], "category_id": 2}, {"id": 10, "bbox": [224.77, 478.89, 45.14, 44.22], "category_id": 3}, {"id": 11, "bbox": [0.0, 40.46, 693.13, 425.26], "category_id": 1}], "caption": "Scheme 11. Proposed mechanism for the formation of 20, 21 and 22", "pdf": {"Page": 11, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 438, 60], "ImageBB": [175, 65, 645, 459]}, "reactions": [{"reactants": [11], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [11]}, {"reactants": [3], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [3]}, {"reactants": [6], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [9], "products": [6]}, {"reactants": [6], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [0], "products": [6]}, {"reactants": [2], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [], "products": [2]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [1]}], "diagram_type": "graph"}, {"id": 89, "width": 2064, "height": 1688, "file_name": "ja054378e-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1582.37, 112.48, 474.64, 499.2], "category_id": 1}, {"id": 1, "bbox": [1304.11, 789.73, 711.98, 834.75], "category_id": 1}, {"id": 2, "bbox": [252.43, 806.1, 245.49, 38.8], "category_id": 2}, {"id": 3, "bbox": [561.39, 272.08, 249.57, 34.72], "category_id": 2}, {"id": 4, "bbox": [1295.93, 826.56, 339.6, 38.83], "category_id": 2}, {"id": 5, "bbox": [661.65, 441.9, 22.46, 32.69], "category_id": 3}, {"id": 6, "bbox": [205.38, 568.76, 26.55, 32.69], "category_id": 3}, {"id": 7, "bbox": [56.01, 1509.94, 24.51, 32.66], "category_id": 3}, {"id": 8, "bbox": [1351.17, 1647.03, 22.46, 34.74], "category_id": 3}, {"id": 9, "bbox": [1017.66, 630.14, 24.51, 34.73], "category_id": 3}, {"id": 10, "bbox": [1629.43, 630.1, 24.51, 32.7], "category_id": 3}, {"id": 11, "bbox": [1404.37, 272.08, 237.29, 32.69], "category_id": 2}, {"id": 12, "bbox": [1703.09, 718.12, 149.32, 194.33], "category_id": 1}, {"id": 13, "bbox": [962.42, 6.09, 591.26, 613.77], "category_id": 1}, {"id": 14, "bbox": [6.91, 943.18, 478.73, 552.39], "category_id": 1}, {"id": 15, "bbox": [66.24, 709.93, 149.32, 196.38], "category_id": 1}, {"id": 16, "bbox": [555.25, 341.64, 351.88, 89.98], "category_id": 1}, {"id": 17, "bbox": [152.18, 290.49, 186.14, 265.94], "category_id": 1}], "reactions": [{"reactants": [17], "conditions": [3, 16], "products": [13]}, {"reactants": [13], "conditions": [11], "products": [0]}, {"reactants": [0], "conditions": [12, 4], "products": [1]}, {"reactants": [17], "conditions": [15, 2], "products": [14]}], "corefs": [[17, 6], [16, 5], [13, 9], [0, 10], [1, 8], [14, 7]], "caption": "Figure 1. Schematic for the synthesis of N-isopropyl-N-[4-(thien-3-ylethynyl) phenyl] amine and N-isopropyl-N-(4-{[4-(thien-3-ylethynyl) phenyl] ethynyl} phenyl) amine. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 490, 775, 515], "ImageBB": [167, 64, 683, 486]}, "diagram_type": "tree"}, {"id": 460, "width": 1344, "height": 952, "file_name": "op200011x-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [314.0, 235.0, 34.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [3.0, 867.0, 1228.0, 55.0], "category_id": 2}, {"id": 2, "bbox": [981.0, 236.0, 42.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [6.0, 428.0, 1337.0, 449.0], "category_id": 4}, {"id": 4, "bbox": [523.0, 154.0, 251.0, 53.0], "category_id": 2}, {"id": 5, "bbox": [495.0, 100.0, 37.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [877.5, 82.0, 254.5, 205.8], "category_id": 1}, {"id": 7, "bbox": [543.4, 3.0, 235.6, 127.0], "category_id": 1}, {"id": 8, "bbox": [225.0, 85.4, 225.8, 168.4], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [7, 4], "products": [6]}], "corefs": [[8, 0], [7, 5], [6, 2]], "caption": "Table 3", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 115, 107], "ImageBB": [71, 133, 407, 371]}, "diagram_type": "single"}, {"id": 702, "width": 1352, "height": 860, "file_name": "ol0362663-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [28.6, 6.2, 260.4, 195.8], "category_id": 1}, {"id": 1, "bbox": [631.5, 8.1, 249.7, 194.0], "category_id": 1}, {"id": 2, "bbox": [1157.7, 11.9, 169.8, 146.5], "category_id": 1}, {"id": 3, "bbox": [889.2, 9.9, 224.8, 192.5], "category_id": 1}, {"id": 4, "bbox": [748.0, 210.0, 45.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [290.0, 0.0, 284.0, 111.0], "category_id": 2}, {"id": 6, "bbox": [1.0, 319.0, 1351.0, 512.0], "category_id": 4}, {"id": 7, "bbox": [1264.0, 210.0, 42.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [1008.0, 209.0, 43.0, 51.0], "category_id": 3}, {"id": 9, "bbox": [169.0, 207.0, 43.0, 56.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [5], "products": [1, 3, 2]}], "corefs": [[0, 9], [1, 4], [3, 8], [2, 7]], "caption": "Table 1. Influence of Reoxidant on Product Distribution", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 541, 373, 554], "ImageBB": [73, 564, 411, 779]}, "diagram_type": "single"}, {"id": 137, "width": 2392, "height": 620, "file_name": "op8001799-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [541.2, 302.0, 325.8, 281.6], "category_id": 1}, {"id": 1, "bbox": [518.9, 157.0, 267.1, 100.0], "category_id": 2}, {"id": 2, "bbox": [0.0, 0.0, 436.3, 250.0], "category_id": 1}, {"id": 3, "bbox": [818.8, 40.0, 494.1, 470.9], "category_id": 1}, {"id": 4, "bbox": [526.94, 297.82, 48.87, 47.35], "category_id": 2}, {"id": 5, "bbox": [125.8, 400.0, 232.6, 136.8], "category_id": 1}, {"id": 6, "bbox": [222.0, 240.0, 40.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [692.0, 577.0, 46.0, 36.0], "category_id": 3}, {"id": 8, "bbox": [212.0, 560.0, 41.0, 48.0], "category_id": 3}, {"id": 9, "bbox": [1739.0, 522.0, 55.0, 55.0], "category_id": 3}, {"id": 10, "bbox": [1068.0, 515.0, 50.0, 50.0], "category_id": 3}, {"id": 11, "bbox": [2034.0, 205.0, 269.0, 55.0], "category_id": 2}, {"id": 12, "bbox": [2083.0, 286.0, 132.0, 57.0], "category_id": 2}, {"id": 13, "bbox": [1321.0, 174.0, 172.0, 93.0], "category_id": 2}, {"id": 14, "bbox": [1506.3, 74.2, 497.7, 440.8], "category_id": 1}, {"id": 15, "bbox": [2356.05, 240.0, 35.95, 58.0], "category_id": 3}], "reactions": [{"reactants": [2, 5], "conditions": [1, 4, 0], "products": [3]}, {"reactants": [3], "conditions": [13], "products": [14]}, {"reactants": [14], "conditions": [11, 12], "products": [15]}], "corefs": [[2, 6], [5, 8], [0, 7], [3, 10], [14, 9]], "caption": "Figure 1. Synthesis of 1 via asymmetric [3 + 2] cycloaddition and selective ester reduction.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 203, 559, 219], "ImageBB": [111, 48, 709, 203]}, "diagram_type": "single"}, {"id": 586, "width": 1352, "height": 432, "file_name": "acs.oprd.6b00180-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [135.94, 209.94, 38.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [1215.0, 210.2, 45.0, 50.8], "category_id": 3}, {"id": 2, "bbox": [687.0, 82.2, 210.0, 54.8], "category_id": 2}, {"id": 3, "bbox": [362.2, 78.3, 246.8, 133.7], "category_id": 1}, {"id": 4, "bbox": [658.0, 146.0, 270.7, 52.9], "category_id": 2}, {"id": 5, "bbox": [0.0, 61.3, 267.0, 157.7], "category_id": 1}, {"id": 6, "bbox": [1014.4, 7.1, 335.6, 218.9], "category_id": 1}, {"id": 7, "bbox": [29.0, 282.0, 1323.0, 150.0], "category_id": 4}], "reactions": [{"reactants": [5, 3], "conditions": [2, 4], "products": [6]}], "corefs": [[5, 0], [6, 1]], "caption": "Table 7. E\ufb00ect of Palladium Catalysts on the 100 mL Scale Suzuki Reaction of 4-Bromoaniline (2) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 327, 417, 372], "ImageBB": [82, 378, 420, 486]}, "diagram_type": "single"}, {"id": 773, "width": 1156, "height": 640, "file_name": "jo9519672-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [423.0, 586.0, 59.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [939.0, 586.0, 59.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [990.0, 298.0, 64.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [246.0, 285.0, 54.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [883.4, 346.3, 268.7, 213.1], "category_id": 1}, {"id": 5, "bbox": [7.0, 88.3, 612.0, 185.9], "category_id": 1}, {"id": 6, "bbox": [774.6, 96.5, 378.4, 179.2], "category_id": 1}, {"id": 7, "bbox": [194.5, 385.1, 417.5, 193.9], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [4]}], "corefs": [[5, 3], [6, 2], [7, 0], [4, 1]], "caption": "Figure 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [63, 417, 120, 430], "ImageBB": [87, 440, 376, 600]}, "diagram_type": "multiple"}, {"id": 301, "width": 1344, "height": 608, "file_name": "ol303452r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [780.6, 4.0, 537.4, 307.1], "category_id": 1}, {"id": 1, "bbox": [26.7, 120.2, 532.6, 189.7], "category_id": 1}, {"id": 2, "bbox": [966.0, 338.0, 57.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [174.0, 332.0, 129.0, 59.0], "category_id": 3}, {"id": 4, "bbox": [568.0, 153.0, 150.0, 52.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [4], "products": [0]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Influence of Reaction Conditions on the Synthesis of the N-(Cyanomethyl)ureas 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 287, 765, 314], "ImageBB": [437, 127, 773, 279]}, "diagram_type": "single"}, {"id": 295, "width": 1100, "height": 1448, "file_name": "ol400025a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.7, 91.7, 175.4, 111.7], "category_id": 1}, {"id": 1, "bbox": [219.5, 46.2, 311.6, 170.2], "category_id": 1}, {"id": 2, "bbox": [787.4, 0.0, 310.7, 231.0], "category_id": 1}, {"id": 3, "bbox": [21.0, 324.9, 1026.0, 1123.1], "category_id": 4}, {"id": 4, "bbox": [539.0, 164.0, 248.0, 36.0], "category_id": 2}, {"id": 5, "bbox": [571.0, 111.0, 164.0, 38.0], "category_id": 2}, {"id": 6, "bbox": [46.0, 220.0, 64.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [298.0, 223.0, 73.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [896.0, 242.0, 84.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [0, 1], "conditions": [5, 4], "products": [2]}], "corefs": [[0, 6], [1, 7], [2, 8]], "caption": "Table 3. Squaramide-Catalyzed Asymmetric Cascade Sulfa- Michael/Michael Addition of Thiosalicylates 1 to Nitroalkene Enoates 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 448, 768, 489], "ImageBB": [467, 500, 742, 862]}, "diagram_type": "single"}, {"id": 1153, "width": 1352, "height": 1080, "file_name": "ol050019c-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [484.26, 271.17, 374.01, 327.29], "category_id": 1}, {"id": 1, "bbox": [654.02, 172.44, 169.08, 41.25], "category_id": 2}, {"id": 2, "bbox": [916.44, 438.87, 216.43, 56.13], "category_id": 2}, {"id": 3, "bbox": [112.27, 42.6, 183.97, 242.77], "category_id": 1}, {"id": 4, "bbox": [937.4, 964.3, 176.53, 56.12], "category_id": 3}, {"id": 5, "bbox": [977.98, 307.68, 100.1, 50.04], "category_id": 3}, {"id": 6, "bbox": [169.08, 696.51, 294.89, 236.68], "category_id": 1}, {"id": 7, "bbox": [554.6, 754.67, 231.3, 51.39], "category_id": 2}, {"id": 8, "bbox": [837.31, 0.0, 386.19, 319.18], "category_id": 1}, {"id": 9, "bbox": [350.34, 36.52, 261.07, 246.82], "category_id": 1}, {"id": 10, "bbox": [97.39, 340.14, 422.71, 211.66], "category_id": 3}, {"id": 11, "bbox": [856.24, 646.47, 295.56, 321.21], "category_id": 1}, {"id": 12, "bbox": [654.02, 104.81, 171.11, 53.43], "category_id": 2}, {"id": 13, "bbox": [554.6, 827.7, 235.36, 49.36], "category_id": 2}], "caption": "Scheme 1. Synthesis of Fused Tetracyclics", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [124, 75, 357, 88], "ImageBB": [73, 93, 411, 363]}, "reactions": [{"reactants": [3, 9], "conditions": [12, 1], "products": [8]}, {"reactants": [8], "conditions": [2], "products": [0]}, {"reactants": [6], "conditions": [7, 13], "products": [11]}], "diagram_type": "tree"}, {"id": 879, "width": 1272, "height": 2220, "file_name": "ol7014434-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [919.87, 213.11, 48.01, 43.04], "category_id": 3}, {"id": 1, "bbox": [17.0, 251.3, 1247.0, 1951.7], "category_id": 4}, {"id": 2, "bbox": [267.0, 208.4, 48.4, 39.0], "category_id": 3}, {"id": 3, "bbox": [558.0, 10.9, 130.8, 52.1], "category_id": 2}, {"id": 4, "bbox": [191.5, 0.0, 275.5, 208.3], "category_id": 1}, {"id": 5, "bbox": [502.9, 86.4, 153.5, 54.7], "category_id": 2}, {"id": 6, "bbox": [796.6, 5.7, 345.8, 206.9], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 5], "products": [6]}], "corefs": [[4, 2], [6, 0]], "caption": "Table 2. First Synthesis of Compounds of Type III from Type Ia ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 230, 377, 258], "ImageBB": [83, 258, 401, 813]}, "diagram_type": "single"}, {"id": 523, "width": 1352, "height": 388, "file_name": "jo0109321-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [518.3, 6.0, 189.4, 85.0], "category_id": 2}, {"id": 1, "bbox": [515.0, 117.0, 223.0, 43.7], "category_id": 2}, {"id": 2, "bbox": [3.8, 53.5, 443.2, 77.8], "category_id": 1}, {"id": 3, "bbox": [1011.0, 122.0, 334.0, 61.0], "category_id": 2}, {"id": 4, "bbox": [1014.0, 25.0, 276.0, 56.0], "category_id": 2}, {"id": 5, "bbox": [4.0, 193.0, 1345.0, 195.0], "category_id": 4}, {"id": 6, "bbox": [881.0, 48.0, 72.0, 48.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [0, 1, 6], "products": [4, 3]}], "corefs": [], "caption": "Table 5. Hydroboration of 1-Heptene with BH3-THF in                         THF ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [78, 305, 405, 332], "ImageBB": [74, 342, 412, 439]}, "diagram_type": "single"}, {"id": 1348, "width": 1320, "height": 780, "file_name": "op7001886-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [257.53, 497.03, 96.41, 52.8], "category_id": 2}, {"id": 1, "bbox": [109.61, 532.67, 120.18, 53.47], "category_id": 3}, {"id": 2, "bbox": [464.21, 732.01, 66.7, 47.53], "category_id": 3}, {"id": 3, "bbox": [950.88, 125.41, 369.12, 57.43], "category_id": 2}, {"id": 4, "bbox": [428.55, 2.64, 306.4, 309.57], "category_id": 1}, {"id": 5, "bbox": [879.56, 700.99, 61.41, 41.58], "category_id": 3}, {"id": 6, "bbox": [109.61, 171.62, 276.68, 110.23], "category_id": 2}, {"id": 7, "bbox": [742.21, 91.09, 145.27, 48.18], "category_id": 2}, {"id": 8, "bbox": [0.0, 113.53, 60.09, 50.17], "category_id": 3}, {"id": 9, "bbox": [510.44, 323.43, 122.16, 51.49], "category_id": 3}, {"id": 10, "bbox": [783.81, 378.88, 307.72, 312.21], "category_id": 1}, {"id": 11, "bbox": [738.25, 237.62, 160.46, 46.87], "category_id": 2}, {"id": 12, "bbox": [119.52, 82.51, 255.55, 51.48], "category_id": 2}, {"id": 13, "bbox": [380.35, 410.56, 302.43, 298.35], "category_id": 1}], "caption": "Scheme 9", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 119, 60], "ImageBB": [62, 65, 392, 260]}, "reactions": [{"reactants": [8], "conditions": [12, 6], "products": [4]}, {"reactants": [4], "conditions": [7, 11], "products": [3]}, {"reactants": [1], "conditions": [0], "products": [13]}, {"reactants": [13], "conditions": [], "products": [10]}], "diagram_type": "multiple"}, {"id": 128, "width": 1412, "height": 1248, "file_name": "op9001824-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.0, 1009.7, 421.4, 180.3], "category_id": 1}, {"id": 1, "bbox": [931.2, 1013.0, 422.8, 188.6], "category_id": 1}, {"id": 2, "bbox": [843.8, 370.0, 445.7, 375.7], "category_id": 1}, {"id": 3, "bbox": [1120.5, 147.5, 291.5, 162.5], "category_id": 1}, {"id": 4, "bbox": [1304.0, 310.0, 51.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [1071.0, 757.0, 52.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [667.0, 588.0, 23.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [186.0, 1198.0, 47.0, 48.0], "category_id": 3}, {"id": 8, "bbox": [649.0, 1183.0, 52.0, 40.0], "category_id": 3}, {"id": 9, "bbox": [480.8, 937.3, 390.4, 262.5], "category_id": 1}, {"id": 10, "bbox": [58.0, 814.0, 1354.0, 63.0], "category_id": 2}, {"id": 11, "bbox": [652.6, 304.78, 40.2, 42.0], "category_id": 3}, {"id": 12, "bbox": [485.5, 140.9, 376.0, 167.7], "category_id": 1}, {"id": 13, "bbox": [1112.78, 1206.39, 59.22, 34.0], "category_id": 3}, {"id": 14, "bbox": [486.0, 410.5, 377.7, 179.5], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [14], "products": [2]}], "corefs": [[12, 11], [3, 4], [14, 6], [2, 5], [0, 7], [9, 8], [1, 13]], "caption": "Figure 1", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 360, 109, 374], "ImageBB": [58, 45, 411, 357]}, "diagram_type": "multiple"}, {"id": 527, "width": 2808, "height": 1412, "file_name": "jo0108865-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2221.9, 433.6, 264.0, 276.4], "category_id": 1}, {"id": 1, "bbox": [435.76, 1136.0, 59.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [623.0, 507.0, 202.9, 75.0], "category_id": 2}, {"id": 3, "bbox": [926.29, 483.24, 249.81, 231.76], "category_id": 1}, {"id": 4, "bbox": [1538.5, 457.1, 213.8, 228.2], "category_id": 1}, {"id": 5, "bbox": [328.2, 495.7, 274.4, 233.3], "category_id": 1}, {"id": 6, "bbox": [1620.07, 673.27, 184.24, 63.53], "category_id": 2}, {"id": 7, "bbox": [653.2, 1030.0, 208.9, 271.0], "category_id": 1}, {"id": 8, "bbox": [1857.0, 561.0, 248.0, 156.0], "category_id": 1}, {"id": 9, "bbox": [10.0, 0.0, 2798.0, 334.0], "category_id": 4}, {"id": 10, "bbox": [1338.0, 486.0, 114.0, 61.0], "category_id": 2}, {"id": 11, "bbox": [1861.0, 458.0, 264.0, 67.0], "category_id": 2}, {"id": 12, "bbox": [1576.0, 780.0, 70.0, 56.0], "category_id": 3}, {"id": 13, "bbox": [709.0, 727.0, 729.0, 224.0], "category_id": 3}, {"id": 14, "bbox": [648.0, 1306.0, 300.0, 101.0], "category_id": 3}, {"id": 15, "bbox": [344.0, 745.0, 272.0, 66.0], "category_id": 3}, {"id": 16, "bbox": [2191.0, 755.0, 304.0, 117.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [2], "products": [3]}, {"reactants": [3], "conditions": [10], "products": [4, 6]}, {"reactants": [4], "conditions": [11, 8], "products": [0]}, {"reactants": [0], "conditions": [6], "products": [7]}], "corefs": [[5, 15], [3, 13], [4, 12], [0, 16], [7, 14]], "caption": "Table 1. Reduction of 39 and Derivatives with the Catalyst", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [250, 64, 598, 76], "ImageBB": [74, 78, 776, 431]}, "diagram_type": "multiple"}, {"id": 165, "width": 1348, "height": 432, "file_name": "op500334b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [492.0, 190.0, 204.0, 96.0], "category_id": 2}, {"id": 1, "bbox": [427.0, 24.0, 341.0, 120.0], "category_id": 2}, {"id": 2, "bbox": [89.0, 227.0, 54.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [915.0, 226.0, 47.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [30.0, 0.0, 352.0, 278.0], "category_id": 1}, {"id": 5, "bbox": [805.0, 0.0, 512.0, 286.0], "category_id": 1}, {"id": 6, "bbox": [1.0, 306.0, 1347.0, 126.0], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [1, 0], "products": [5]}], "corefs": [[4, 2], [5, 3]], "caption": "Table 3. Optimization of the base", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 274, 110], "ImageBB": [82, 116, 419, 224]}, "diagram_type": "single"}, {"id": 377, "width": 1356, "height": 2980, "file_name": "ol100734t-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [346.0, 848.0, 73.0, 49.0], "category_id": 2}, {"id": 1, "bbox": [760.4, 582.3, 327.6, 285.7], "category_id": 1}, {"id": 2, "bbox": [116.4, 211.4, 326.6, 287.3], "category_id": 1}, {"id": 3, "bbox": [149.3, 479.7, 125.7, 43.4], "category_id": 3}, {"id": 4, "bbox": [617.0, 209.0, 334.0, 294.0], "category_id": 1}, {"id": 5, "bbox": [318.0, 584.0, 333.0, 284.0], "category_id": 1}, {"id": 6, "bbox": [9.0, 1042.0, 1344.0, 358.0], "category_id": 2}, {"id": 7, "bbox": [453.0, 301.0, 98.0, 47.0], "category_id": 2}, {"id": 8, "bbox": [699.0, 481.0, 46.0, 45.0], "category_id": 3}, {"id": 9, "bbox": [304.0, 856.0, 33.0, 45.0], "category_id": 3}, {"id": 10, "bbox": [734.0, 867.0, 36.0, 38.0], "category_id": 3}, {"id": 11, "bbox": [113.0, 424.0, 125.0, 37.0], "category_id": 2}, {"id": 12, "bbox": [787.0, 858.0, 85.0, 48.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [7], "products": [4]}, {"reactants": [4], "conditions": [], "products": [5, 1]}], "corefs": [[2, 3], [4, 8], [5, 9], [1, 10]], "caption": "Figure 1. (a) VCD spectra of (S,S)-imidazoline 1 at different reaction times during racemization in DMSO solution at 60 \u00b0C. (b) Relationship of ln (ee %) versus time at different temperatures. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 797, 760, 839], "ImageBB": [424, 46, 763, 791]}, "diagram_type": "multiple"}, {"id": 1242, "width": 1316, "height": 1420, "file_name": "op025610t-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [73.19, 612.33, 55.42, 51.85], "category_id": 3}, {"id": 1, "bbox": [1042.4, 414.85, 105.17, 61.8], "category_id": 2}, {"id": 2, "bbox": [932.27, 616.59, 46.89, 47.59], "category_id": 3}, {"id": 3, "bbox": [536.48, 929.14, 113.69, 56.83], "category_id": 2}, {"id": 4, "bbox": [228.8, 1077.61, 296.31, 49.72], "category_id": 2}, {"id": 5, "bbox": [42.63, 1198.37, 343.92, 159.12], "category_id": 1}, {"id": 6, "bbox": [346.05, 614.46, 57.55, 53.98], "category_id": 3}, {"id": 7, "bbox": [816.44, 561.89, 466.85, 57.54], "category_id": 2}, {"id": 8, "bbox": [461.87, 218.79, 54.71, 58.96], "category_id": 3}, {"id": 9, "bbox": [992.66, 1118.1, 60.4, 56.12], "category_id": 3}, {"id": 10, "bbox": [24.16, 851.01, 353.15, 165.51], "category_id": 1}, {"id": 11, "bbox": [560.64, 524.95, 207.49, 44.04], "category_id": 2}, {"id": 12, "bbox": [1152.54, 215.95, 51.87, 60.38], "category_id": 3}, {"id": 13, "bbox": [135.01, 1031.44, 46.19, 48.3], "category_id": 3}, {"id": 14, "bbox": [878.97, 414.85, 110.85, 66.06], "category_id": 2}, {"id": 15, "bbox": [832.08, 831.12, 358.12, 257.85], "category_id": 1}, {"id": 16, "bbox": [461.87, 859.53, 319.05, 49.72], "category_id": 2}, {"id": 17, "bbox": [1045.25, 696.86, 270.75, 53.99], "category_id": 2}, {"id": 18, "bbox": [832.08, 0.0, 354.57, 283.43], "category_id": 1}, {"id": 19, "bbox": [0.0, 556.21, 222.41, 51.85], "category_id": 2}, {"id": 20, "bbox": [274.99, 144.2, 296.31, 65.9], "category_id": 2}, {"id": 21, "bbox": [298.44, 553.37, 201.8, 53.27], "category_id": 2}, {"id": 22, "bbox": [196.12, 1371.7, 59.68, 48.3], "category_id": 3}, {"id": 23, "bbox": [288.6, 369.9, 109.7, 45.5], "category_id": 2}], "caption": "Scheme 2. Proposed mechanism pathway for the reaction of 1 with 2 in the preparation of 6 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 399, 81], "ImageBB": [78, 87, 407, 442]}, "reactions": [{"reactants": [19, 21], "conditions": [23], "products": [20]}, {"reactants": [19, 21], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [14, 1], "products": [18]}, {"reactants": [7], "conditions": [17], "products": [15]}, {"reactants": [15], "conditions": [16, 3], "products": [10]}, {"reactants": [10], "conditions": [4], "products": [5]}], "diagram_type": "tree"}, {"id": 654, "width": 1352, "height": 2544, "file_name": "ol403122a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [711.0, 87.0, 283.8, 53.1], "category_id": 2}, {"id": 1, "bbox": [1062.3, 1.3, 251.6, 135.7], "category_id": 1}, {"id": 2, "bbox": [472.5, 26.6, 156.8, 116.7], "category_id": 1}, {"id": 3, "bbox": [31.0, 60.0, 95.4, 46.6], "category_id": 1}, {"id": 4, "bbox": [185.0, 91.0, 194.5, 53.3], "category_id": 2}, {"id": 5, "bbox": [796.0, 28.0, 131.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [8.0, 184.0, 1344.0, 2360.0], "category_id": 4}, {"id": 7, "bbox": [198.0, 30.0, 164.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [7, 4], "products": [2]}, {"reactants": [2], "conditions": [5, 0], "products": [1]}], "corefs": [], "caption": "Table 2. Organometallic Substrate Scope for the One-Pot Preparation of Benzyl Sulfonesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 774, 125], "ImageBB": [448, 131, 786, 767]}, "diagram_type": "single"}, {"id": 307, "width": 1348, "height": 948, "file_name": "ol302997q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [110.0, 287.0, 51.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [617.0, 241.0, 361.0, 61.0], "category_id": 2}, {"id": 2, "bbox": [603.66, 62.4, 373.04, 90.0], "category_id": 2}, {"id": 3, "bbox": [27.8, 81.1, 267.5, 203.6], "category_id": 1}, {"id": 4, "bbox": [633.63, 170.99, 321.29, 46.42], "category_id": 2}, {"id": 5, "bbox": [346.6, 76.9, 218.8, 165.3], "category_id": 1}, {"id": 6, "bbox": [1012.9, 2.2, 309.4, 247.2], "category_id": 1}, {"id": 7, "bbox": [475.0, 286.0, 54.0, 44.0], "category_id": 3}, {"id": 8, "bbox": [1176.0, 287.0, 63.0, 49.0], "category_id": 3}, {"id": 9, "bbox": [11.0, 365.0, 1337.0, 583.0], "category_id": 4}], "reactions": [{"reactants": [3, 5], "conditions": [2, 4, 1], "products": [6]}], "corefs": [[3, 0], [5, 7], [6, 8]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 479, 707, 495], "ImageBB": [436, 506, 773, 743]}, "diagram_type": "single"}, {"id": 978, "width": 1356, "height": 1596, "file_name": "ja060064v-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [255.39, 1369.25, 318.43, 182.84], "category_id": 1}, {"id": 1, "bbox": [782.92, 179.64, 102.15, 51.1], "category_id": 2}, {"id": 2, "bbox": [231.44, 776.04, 285.72, 45.51], "category_id": 2}, {"id": 3, "bbox": [500.4, 567.66, 271.34, 50.3], "category_id": 2}, {"id": 4, "bbox": [192.34, 159.68, 54.27, 47.9], "category_id": 3}, {"id": 5, "bbox": [79.01, 30.34, 227.45, 93.41], "category_id": 1}, {"id": 6, "bbox": [231.44, 860.67, 201.12, 149.3], "category_id": 1}, {"id": 7, "bbox": [977.65, 1223.95, 57.46, 44.71], "category_id": 3}, {"id": 8, "bbox": [790.9, 1044.31, 472.46, 168.46], "category_id": 1}, {"id": 9, "bbox": [500.4, 38.32, 235.43, 51.1], "category_id": 2}, {"id": 10, "bbox": [760.57, 1328.54, 177.18, 219.56], "category_id": 1}, {"id": 11, "bbox": [500.4, 502.99, 209.89, 52.7], "category_id": 2}, {"id": 12, "bbox": [522.74, 1039.52, 130.09, 57.48], "category_id": 2}, {"id": 13, "bbox": [500.4, 102.2, 178.77, 46.3], "category_id": 2}, {"id": 14, "bbox": [418.99, 1568.85, 60.66, 27.15], "category_id": 3}, {"id": 15, "bbox": [231.44, 818.36, 244.22, 48.7], "category_id": 2}, {"id": 16, "bbox": [786.11, 503.79, 567.44, 179.64], "category_id": 1}, {"id": 17, "bbox": [840.38, 1569.65, 58.26, 26.35], "category_id": 3}, {"id": 18, "bbox": [0.0, 1048.3, 498.8, 164.47], "category_id": 1}, {"id": 19, "bbox": [76.62, 496.6, 347.16, 158.09], "category_id": 1}, {"id": 20, "bbox": [192.34, 1223.95, 54.27, 46.3], "category_id": 3}, {"id": 21, "bbox": [940.57, 199.28, 306.55, 44.07], "category_id": 3}, {"id": 22, "bbox": [980.8, 758.74, 151.36, 34.49], "category_id": 3}, {"id": 23, "bbox": [783.46, 743.42, 132.2, 42.18], "category_id": 2}, {"id": 24, "bbox": [195.26, 724.26, 51.73, 36.4], "category_id": 3}, {"id": 25, "bbox": [940.94, 157.28, 333.16, 41.52], "category_id": 3}, {"id": 26, "bbox": [981.0, 725.6, 194.7, 34.2], "category_id": 3}, {"id": 27, "bbox": [971.26, 332.93, 249.8, 51.9], "category_id": 2}, {"id": 28, "bbox": [841.18, 3.19, 284.91, 117.37], "category_id": 1}], "caption": "Scheme 1. Second Generation Synthesis of Hydroxydecanoic Acid Building Block (15)a ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 387, 88], "ImageBB": [73, 92, 412, 491]}, "reactions": [{"reactants": [5], "conditions": [9, 13], "products": [28]}, {"reactants": [28], "conditions": [27], "products": [16]}, {"reactants": [16], "conditions": [11, 3], "products": [19]}, {"reactants": [19], "conditions": [2, 15, 6], "products": [18]}, {"reactants": [18], "conditions": [12], "products": [8]}, {"reactants": [25], "conditions": [1], "products": [21]}, {"reactants": [26], "conditions": [23], "products": [22]}], "diagram_type": "tree"}, {"id": 480, "width": 1348, "height": 668, "file_name": "ol0619157-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [95.3, 5.0, 293.6, 149.9], "category_id": 1}, {"id": 1, "bbox": [964.8, 6.9, 289.2, 148.0], "category_id": 1}, {"id": 2, "bbox": [8.0, 262.0, 1340.0, 406.0], "category_id": 4}, {"id": 3, "bbox": [215.0, 170.0, 38.1, 57.0], "category_id": 3}, {"id": 4, "bbox": [546.3, 7.0, 236.7, 107.0], "category_id": 2}, {"id": 5, "bbox": [499.0, 142.0, 324.7, 55.8], "category_id": 2}, {"id": 6, "bbox": [1087.9, 170.0, 49.1, 52.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [4, 5], "products": [1]}], "corefs": [[0, 3], [1, 6]], "caption": "Table 2. Catalytic Asymmetric Conjugate Reduction of Enones", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 440, 775, 453], "ImageBB": [439, 457, 776, 624]}, "diagram_type": "single"}, {"id": 253, "width": 1260, "height": 1236, "file_name": "ol802556f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [141.0, 564.0, 241.0, 82.0], "category_id": 1}, {"id": 1, "bbox": [1029.0, 26.0, 206.0, 93.0], "category_id": 1}, {"id": 2, "bbox": [24.0, 2.0, 277.0, 133.0], "category_id": 1}, {"id": 3, "bbox": [146.0, 319.0, 202.0, 85.0], "category_id": 1}, {"id": 4, "bbox": [144.0, 442.0, 216.0, 83.0], "category_id": 1}, {"id": 5, "bbox": [136.0, 677.0, 232.0, 114.0], "category_id": 1}, {"id": 6, "bbox": [107.0, 837.0, 286.0, 115.0], "category_id": 1}, {"id": 7, "bbox": [176.0, 974.0, 150.0, 149.0], "category_id": 1}, {"id": 8, "bbox": [126.0, 1147.0, 245.0, 83.0], "category_id": 1}, {"id": 9, "bbox": [3.0, 203.0, 1201.0, 1033.0], "category_id": 4}, {"id": 10, "bbox": [553.0, 6.0, 333.0, 50.0], "category_id": 2}, {"id": 11, "bbox": [545.0, 74.0, 355.0, 55.0], "category_id": 2}, {"id": 12, "bbox": [157.0, 126.0, 26.0, 35.0], "category_id": 3}, {"id": 13, "bbox": [412.0, 124.0, 33.0, 38.0], "category_id": 3}, {"id": 14, "bbox": [1108.0, 130.0, 29.0, 33.0], "category_id": 3}, {"id": 15, "bbox": [371.0, 50.0, 114.0, 39.0], "category_id": 1}], "reactions": [{"reactants": [2, 15], "conditions": [10, 11], "products": [1]}], "corefs": [[2, 12], [15, 13], [1, 14]], "caption": "Table 1. Scope of the Electrophilea", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 610, 88], "ImageBB": [436, 97, 751, 406]}, "diagram_type": "single"}, {"id": 1325, "width": 1352, "height": 376, "file_name": "op300363s-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [549.86, 22.3, 263.77, 275.06], "category_id": 1}, {"id": 1, "bbox": [686.48, 283.17, 62.23, 47.98], "category_id": 3}, {"id": 2, "bbox": [917.11, 185.17, 63.58, 51.37], "category_id": 2}, {"id": 3, "bbox": [382.81, 190.58, 62.9, 48.66], "category_id": 2}, {"id": 4, "bbox": [19.61, 83.8, 271.89, 217.62], "category_id": 1}, {"id": 5, "bbox": [349.67, 18.25, 108.21, 120.97], "category_id": 1}, {"id": 6, "bbox": [1185.62, 281.82, 64.25, 49.33], "category_id": 3}, {"id": 7, "bbox": [1061.17, 0.0, 270.54, 300.06], "category_id": 1}], "caption": "Scheme 4. Equilibration of Hydrazone and Hydrazine/DHF in Non-Solvolytic Solvents ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 534, 417, 564], "ImageBB": [82, 571, 420, 665]}, "reactions": [{"reactants": [4, 5], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [3], "products": [4]}, {"reactants": [0], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [2], "products": [0]}], "diagram_type": "single"}, {"id": 257, "width": 1348, "height": 1232, "file_name": "ol802073q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [428.0, 151.0, 400.0, 214.0], "category_id": 1}, {"id": 1, "bbox": [671.0, 321.0, 55.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [3.0, 403.0, 1342.0, 829.0], "category_id": 4}, {"id": 3, "bbox": [159.0, 315.0, 59.0, 52.0], "category_id": 3}, {"id": 4, "bbox": [1032.0, 1.0, 158.0, 44.0], "category_id": 2}, {"id": 5, "bbox": [139.46, 28.1, 148.24, 57.55], "category_id": 1}, {"id": 6, "bbox": [112.5, 158.8, 243.9, 201.3], "category_id": 1}, {"id": 7, "bbox": [888.9, 193.3, 342.3, 130.9], "category_id": 1}, {"id": 8, "bbox": [448.6, 4.2, 283.3, 98.8], "category_id": 1}, {"id": 9, "bbox": [184.76, 91.83, 46.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [572.83, 96.65, 51.2, 39.7], "category_id": 3}, {"id": 11, "bbox": [1068.59, 67.83, 55.2, 38.9], "category_id": 2}, {"id": 12, "bbox": [1048.0, 320.6, 43.0, 41.4], "category_id": 3}, {"id": 13, "bbox": [875.0, 30.35, 92.0, 55.3], "category_id": 2}], "reactions": [{"reactants": [5, 8, 13], "conditions": [4, 11], "products": [6, 0, 7]}], "corefs": [[5, 9], [8, 10], [6, 3], [0, 1], [7, 12]], "caption": "Table 1. Reaction Optimization of 1,2,4-Pentatrien-3-ylationa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 743, 88], "ImageBB": [425, 97, 762, 405]}, "diagram_type": "multiple"}, {"id": 1091, "width": 1312, "height": 1304, "file_name": "jo961049j-Scheme-c13.png", "license": 0, "bboxes": [{"id": 0, "bbox": [989.09, 434.45, 307.16, 200.16], "category_id": 3}, {"id": 1, "bbox": [327.51, 185.07, 32.16, 36.09], "category_id": 2}, {"id": 2, "bbox": [953.64, 712.7, 358.36, 330.1], "category_id": 1}, {"id": 3, "bbox": [860.45, 175.88, 31.5, 42.0], "category_id": 2}, {"id": 4, "bbox": [485.03, 437.73, 304.53, 100.41], "category_id": 3}, {"id": 5, "bbox": [452.21, 656.26, 318.32, 386.54], "category_id": 1}, {"id": 6, "bbox": [623.51, 1079.56, 51.85, 40.68], "category_id": 3}, {"id": 7, "bbox": [1021.9, 31.5, 237.59, 341.26], "category_id": 1}, {"id": 8, "bbox": [132.58, 1079.56, 51.19, 40.68], "category_id": 3}, {"id": 9, "bbox": [876.2, 846.58, 33.47, 42.0], "category_id": 2}, {"id": 10, "bbox": [34.13, 0.0, 234.31, 426.57], "category_id": 1}, {"id": 11, "bbox": [529.66, 0.0, 213.3, 375.38], "category_id": 1}, {"id": 12, "bbox": [350.48, 855.77, 31.5, 34.78], "category_id": 2}, {"id": 13, "bbox": [0.0, 437.73, 321.6, 102.38], "category_id": 3}, {"id": 14, "bbox": [0.0, 652.33, 330.79, 446.91], "category_id": 1}, {"id": 15, "bbox": [1130.6, 1072.5, 121.0, 105.7], "category_id": 3}, {"id": 16, "bbox": [32.16, 1200.5, 1274.54, 97.59], "category_id": 2}], "caption": "Scheme 13", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [203, 49, 274, 63], "ImageBB": [78, 70, 406, 396]}, "reactions": [{"reactants": [10], "conditions": [1], "products": [11]}, {"reactants": [11], "conditions": [3], "products": [7]}, {"reactants": [14], "conditions": [12], "products": [5]}, {"reactants": [5], "conditions": [9], "products": [2]}], "diagram_type": "multiple"}, {"id": 1313, "width": 3396, "height": 1704, "file_name": "op3001788-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [828.15, 0.0, 50.97, 52.65], "category_id": 3}, {"id": 1, "bbox": [1378.7, 1260.27, 77.2, 61.15], "category_id": 3}, {"id": 2, "bbox": [843.5, 361.78, 119.75, 169.84], "category_id": 1}, {"id": 3, "bbox": [1251.0, 0.0, 55.42, 52.65], "category_id": 3}, {"id": 4, "bbox": [2504.4, 0.0, 52.37, 51.0], "category_id": 3}, {"id": 5, "bbox": [1455.91, 743.93, 132.51, 61.15], "category_id": 2}, {"id": 6, "bbox": [1948.58, 582.58, 266.72, 271.76], "category_id": 1}, {"id": 7, "bbox": [1370.97, 760.92, 57.76, 59.45], "category_id": 3}, {"id": 8, "bbox": [2069.2, 764.32, 40.77, 59.44], "category_id": 3}, {"id": 9, "bbox": [1457.61, 669.2, 125.72, 59.45], "category_id": 2}, {"id": 10, "bbox": [1289.43, 1025.88, 137.6, 254.78], "category_id": 1}, {"id": 11, "bbox": [1370.97, 864.53, 108.73, 62.84], "category_id": 2}, {"id": 12, "bbox": [2069.2, 883.21, 122.32, 90.02], "category_id": 1}, {"id": 13, "bbox": [1948.58, 91.72, 293.9, 273.45], "category_id": 1}, {"id": 14, "bbox": [1617.3, 251.38, 69.66, 61.14], "category_id": 3}, {"id": 15, "bbox": [1664.87, 344.79, 113.83, 166.45], "category_id": 1}, {"id": 16, "bbox": [2582.25, 307.43, 47.57, 57.74], "category_id": 3}, {"id": 17, "bbox": [2453.14, 1017.39, 214.05, 237.79], "category_id": 1}, {"id": 18, "bbox": [1041.39, 674.3, 95.14, 57.75], "category_id": 2}, {"id": 19, "bbox": [779.77, 268.36, 67.96, 57.75], "category_id": 3}, {"id": 20, "bbox": [1304.8, 409.33, 134.13, 58.57], "category_id": 2}, {"id": 21, "bbox": [1617.3, 1110.81, 147.8, 71.33], "category_id": 1}, {"id": 22, "bbox": [2082.0, 0.0, 61.95, 52.65], "category_id": 3}, {"id": 23, "bbox": [2431.05, 529.93, 249.73, 317.61], "category_id": 1}, {"id": 24, "bbox": [2553.37, 869.62, 127.41, 64.54], "category_id": 2}, {"id": 25, "bbox": [2065.8, 412.73, 100.23, 54.35], "category_id": 2}, {"id": 26, "bbox": [1659.78, 0.0, 64.55, 52.65], "category_id": 3}, {"id": 27, "bbox": [744.1, 582.58, 282.01, 276.85], "category_id": 1}, {"id": 28, "bbox": [1487.5, 157.12, 338.76, 94.18], "category_id": 1}, {"id": 29, "bbox": [1349.71, 283.53, 69.15, 53.79], "category_id": 3}, {"id": 30, "bbox": [1580.21, 606.23, 158.79, 230.5], "category_id": 1}, {"id": 31, "bbox": [1126.34, 95.11, 251.43, 263.27], "category_id": 1}, {"id": 32, "bbox": [694.83, 91.72, 338.07, 220.8], "category_id": 1}, {"id": 33, "bbox": [1997.85, 1044.57, 163.09, 254.77], "category_id": 1}, {"id": 34, "bbox": [2548.27, 429.72, 124.02, 56.05], "category_id": 2}, {"id": 35, "bbox": [1617.3, 1211.02, 135.91, 62.84], "category_id": 2}, {"id": 36, "bbox": [1168.81, 557.1, 249.73, 275.16], "category_id": 1}, {"id": 37, "bbox": [2425.96, 93.42, 222.55, 283.64], "category_id": 1}, {"id": 38, "bbox": [2065.8, 1295.94, 47.57, 54.35], "category_id": 3}], "caption": "Scheme 3. Synthetic Pathways to Prepare 1-Methyl-pyrrolidin-3-ol 2", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 679, 466, 694], "ImageBB": [10, 701, 859, 1127]}, "reactions": [{"reactants": [32, 2], "conditions": [], "products": [27]}, {"reactants": [27], "conditions": [18], "products": [36]}, {"reactants": [31], "conditions": [20], "products": [36]}, {"reactants": [28, 15], "conditions": [], "products": [30]}, {"reactants": [30], "conditions": [5, 9], "products": [36]}, {"reactants": [36], "conditions": [11], "products": [10]}, {"reactants": [10], "conditions": [21, 35], "products": [33]}, {"reactants": [13], "conditions": [25], "products": [6]}, {"reactants": [6, 12], "conditions": [], "products": [33]}, {"reactants": [37], "conditions": [34], "products": [23]}, {"reactants": [23], "conditions": [24], "products": [17]}, {"reactants": [17], "conditions": [], "products": [33]}], "diagram_type": "tree"}, {"id": 661, "width": 1308, "height": 2836, "file_name": "ol402138y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [660.0, 146.0, 255.0, 54.0], "category_id": 2}, {"id": 1, "bbox": [598.0, 39.0, 370.0, 96.0], "category_id": 2}, {"id": 2, "bbox": [165.0, 242.0, 94.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [10.0, 332.0, 1296.0, 2479.0], "category_id": 4}, {"id": 4, "bbox": [22.3, 61.7, 343.7, 175.0], "category_id": 1}, {"id": 5, "bbox": [1009.0, 6.3, 279.4, 237.7], "category_id": 1}, {"id": 6, "bbox": [1062.35, 235.65, 226.0, 44.0], "category_id": 3}, {"id": 7, "bbox": [435.0, 125.35, 129.0, 52.0], "category_id": 2}], "reactions": [{"reactants": [4, 7], "conditions": [1, 0], "products": [5]}], "corefs": [[4, 2], [5, 6]], "caption": "Table 2. Silver-Catalyzed Carboazidation of Different Arylacrylamidesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 724, 114], "ImageBB": [441, 126, 768, 835]}, "diagram_type": "single"}, {"id": 716, "width": 1352, "height": 1012, "file_name": "ol027494k-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [50.1, 3.0, 290.9, 244.5], "category_id": 1}, {"id": 1, "bbox": [851.0, 346.0, 432.0, 55.0], "category_id": 2}, {"id": 2, "bbox": [856.2, 8.0, 441.8, 284.2], "category_id": 1}, {"id": 3, "bbox": [439.0, 142.0, 278.0, 96.0], "category_id": 2}, {"id": 4, "bbox": [441.0, 22.0, 311.0, 94.0], "category_id": 2}, {"id": 5, "bbox": [0.0, 421.1, 1346.0, 541.9], "category_id": 4}, {"id": 6, "bbox": [1014.0, 303.0, 52.0, 44.0], "category_id": 3}, {"id": 7, "bbox": [118.0, 271.0, 47.0, 58.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [4, 3], "products": [2]}], "corefs": [[0, 7], [2, 6]], "caption": "Table 3. Diastereoselective Alkenylation Reaction of Oxazolidinone Derivatives with Alkenylselenonium Salts 1 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 343, 744, 371], "ImageBB": [439, 375, 777, 628]}, "diagram_type": "single"}, {"id": 1129, "width": 1188, "height": 1844, "file_name": "jo991681n-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [573.63, 3.69, 390.1, 312.71], "category_id": 1}, {"id": 1, "bbox": [336.62, 1274.84, 464.8, 103.32], "category_id": 3}, {"id": 2, "bbox": [150.32, 536.87, 332.93, 337.62], "category_id": 1}, {"id": 3, "bbox": [181.68, 1397.53, 428.84, 240.76], "category_id": 1}, {"id": 4, "bbox": [624.35, 804.39, 474.95, 95.01], "category_id": 3}, {"id": 5, "bbox": [487.86, 119.92, 34.12, 36.9], "category_id": 2}, {"id": 6, "bbox": [284.97, 1022.09, 545.96, 238.91], "category_id": 1}, {"id": 7, "bbox": [180.76, 1138.32, 32.28, 38.74], "category_id": 2}, {"id": 8, "bbox": [573.63, 326.55, 459.27, 98.7], "category_id": 3}, {"id": 9, "bbox": [28.59, 655.87, 33.2, 46.12], "category_id": 2}, {"id": 10, "bbox": [150.32, 875.42, 346.76, 97.78], "category_id": 3}, {"id": 11, "bbox": [66.4, 56.27, 394.72, 232.46], "category_id": 1}, {"id": 12, "bbox": [878.89, 1129.09, 28.59, 41.51], "category_id": 2}, {"id": 13, "bbox": [130.4, 1655.82, 990.11, 188.18], "category_id": 3}, {"id": 14, "bbox": [624.35, 539.64, 430.68, 247.22], "category_id": 1}, {"id": 15, "bbox": [233.32, 316.4, 33.21, 37.83], "category_id": 3}], "caption": "Scheme 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 63, 641, 77], "ImageBB": [468, 85, 765, 546]}, "reactions": [{"reactants": [11], "conditions": [5], "products": [0]}, {"reactants": [0], "conditions": [9], "products": [2]}, {"reactants": [2], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [7], "products": [6]}, {"reactants": [6], "conditions": [12], "products": [3]}], "diagram_type": "multiple"}, {"id": 240, "width": 1148, "height": 920, "file_name": "ol9909583-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [821.6, 607.1, 160.5, 148.6], "category_id": 1}, {"id": 1, "bbox": [389.0, 144.9, 197.8, 248.0], "category_id": 1}, {"id": 2, "bbox": [0.0, 148.8, 161.6, 221.3], "category_id": 1}, {"id": 3, "bbox": [788.1, 210.3, 310.4, 200.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 561.3, 166.8, 64.5], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [1]}, {"reactants": [3], "conditions": [], "products": [0]}, {"reactants": [2], "conditions": [], "products": [4]}], "corefs": [], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 254, 491, 267], "ImageBB": [490, 51, 777, 281]}, "diagram_type": "tree"}, {"id": 725, "width": 1284, "height": 3064, "file_name": "ol0171867-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [927.79, 101.89, 325.0, 140.81], "category_id": 1}, {"id": 1, "bbox": [10.0, 110.0, 235.0, 129.8], "category_id": 1}, {"id": 2, "bbox": [343.0, 149.0, 129.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [507.0, 175.0, 240.0, 101.0], "category_id": 2}, {"id": 4, "bbox": [0.0, 273.0, 1284.0, 2791.0], "category_id": 4}, {"id": 5, "bbox": [516.0, 0.0, 393.0, 158.0], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [5, 3], "products": [0]}], "corefs": [], "caption": "Table 2. Copper-Catalyzed Amination of Functionalized Aryl Iodides with Benzylamine ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 153, 400, 181], "ImageBB": [82, 186, 403, 952]}, "diagram_type": "single"}, {"id": 793, "width": 1352, "height": 544, "file_name": "jo501736w-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [611.0, 184.0, 216.0, 55.0], "category_id": 2}, {"id": 1, "bbox": [945.0, 482.0, 51.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [422.0, 499.0, 58.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [1137.9, 233.0, 48.1, 44.0], "category_id": 3}, {"id": 4, "bbox": [251.4, 241.1, 367.5, 236.7], "category_id": 1}, {"id": 5, "bbox": [1003.3, 95.0, 348.7, 144.0], "category_id": 1}, {"id": 6, "bbox": [329.3, 96.1, 134.2, 140.7], "category_id": 1}, {"id": 7, "bbox": [775.2, 311.1, 350.4, 169.0], "category_id": 1}, {"id": 8, "bbox": [658.9, 110.3, 118.2, 46.7], "category_id": 2}, {"id": 9, "bbox": [1.0, 93.3, 240.9, 135.6], "category_id": 1}], "reactions": [{"reactants": [9, 6], "conditions": [8, 0], "products": [5]}, {"reactants": [9, 6], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [9, 6]}, {"reactants": [4], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [4]}, {"reactants": [7], "conditions": [], "products": [5]}], "corefs": [[4, 2], [7, 1], [5, 3]], "caption": "Figure 2. Proposed direct electrochemical amination for the formation of 2-aminobenzoxazoles. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 435, 417, 463], "ImageBB": [82, 290, 420, 426]}, "diagram_type": "graph"}, {"id": 1121, "width": 1276, "height": 928, "file_name": "jo991071n-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 533.25, 161.49, 87.49], "category_id": 2}, {"id": 1, "bbox": [981.1, 227.99, 294.9, 208.83], "category_id": 1}, {"id": 2, "bbox": [0.0, 261.2, 290.44, 141.77], "category_id": 1}, {"id": 3, "bbox": [604.49, 0.0, 287.24, 141.77], "category_id": 1}, {"id": 4, "bbox": [1071.1, 542.83, 189.58, 55.56], "category_id": 2}, {"id": 5, "bbox": [461.5, 714.61, 281.5, 209.47], "category_id": 1}, {"id": 6, "bbox": [400.86, 528.14, 210.65, 92.6], "category_id": 2}, {"id": 7, "bbox": [838.75, 521.11, 220.22, 92.6], "category_id": 2}, {"id": 8, "bbox": [181.92, 544.74, 187.67, 56.84], "category_id": 2}, {"id": 9, "bbox": [135.96, 0.0, 275.12, 115.59], "category_id": 1}, {"id": 10, "bbox": [1072.38, 0.0, 203.62, 0.64], "category_id": 2}, {"id": 11, "bbox": [135.96, 410.63, 48.51, 45.98], "category_id": 3}, {"id": 12, "bbox": [635.77, 412.55, 38.3, 42.79], "category_id": 3}, {"id": 13, "bbox": [1087.7, 408.72, 58.08, 50.45], "category_id": 3}, {"id": 14, "bbox": [213.2, 129.64, 112.34, 51.09], "category_id": 3}, {"id": 15, "bbox": [481.29, 253.53, 297.46, 127.09], "category_id": 1}, {"id": 16, "bbox": [629.38, 542.83, 187.67, 58.11], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 64, 636, 78], "ImageBB": [449, 84, 768, 316]}, "reactions": [{"reactants": [9], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [1]}, {"reactants": [15], "conditions": [6, 16], "products": [5]}], "diagram_type": "tree"}, {"id": 1148, "width": 1352, "height": 980, "file_name": "ol0362663-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [455.18, 639.97, 307.73, 224.59], "category_id": 1}, {"id": 1, "bbox": [708.8, 111.62, 55.46, 49.39], "category_id": 3}, {"id": 2, "bbox": [524.84, 849.68, 78.45, 50.06], "category_id": 3}, {"id": 3, "bbox": [494.4, 204.98, 119.04, 61.56], "category_id": 2}, {"id": 4, "bbox": [741.27, 327.42, 530.92, 304.43], "category_id": 1}, {"id": 5, "bbox": [406.48, 103.5, 40.58, 51.42], "category_id": 3}, {"id": 6, "bbox": [640.49, 0.0, 234.69, 151.54], "category_id": 1}, {"id": 7, "bbox": [524.16, 267.89, 49.37, 57.51], "category_id": 3}, {"id": 8, "bbox": [83.19, 424.84, 308.41, 192.8], "category_id": 1}, {"id": 9, "bbox": [156.91, 860.51, 128.5, 52.76], "category_id": 2}, {"id": 10, "bbox": [315.85, 0.0, 261.74, 151.54], "category_id": 1}, {"id": 11, "bbox": [158.26, 94.03, 91.99, 56.15], "category_id": 2}, {"id": 12, "bbox": [881.94, 82.53, 137.3, 83.21], "category_id": 1}, {"id": 13, "bbox": [162.32, 604.79, 60.87, 52.77], "category_id": 3}, {"id": 14, "bbox": [539.53, 529.41, 112.94, 63.53], "category_id": 2}], "caption": "Scheme 2. Regioselective monooxidation-A Proposal", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [95, 145, 387, 158], "ImageBB": [73, 165, 411, 410]}, "reactions": [{"reactants": [10, 3], "conditions": [], "products": [11, 8]}, {"reactants": [8, 11], "conditions": [], "products": [3, 10]}, {"reactants": [8, 9], "conditions": [], "products": [0, 14]}, {"reactants": [14, 0], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [12, 6, 3]}], "diagram_type": "graph"}, {"id": 384, "width": 1352, "height": 2052, "file_name": "op500224x-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [477.0, 103.0, 211.0, 52.0], "category_id": 2}, {"id": 1, "bbox": [989.0, 358.0, 41.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [872.0, 23.0, 281.0, 312.0], "category_id": 1}, {"id": 3, "bbox": [145.0, 15.0, 239.0, 178.0], "category_id": 1}, {"id": 4, "bbox": [181.0, 357.0, 28.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [1160.0, 720.0, 62.0, 54.0], "category_id": 3}, {"id": 6, "bbox": [719.0, 576.0, 200.0, 90.0], "category_id": 2}, {"id": 7, "bbox": [682.0, 488.0, 279.0, 62.0], "category_id": 2}, {"id": 8, "bbox": [64.0, 580.0, 124.0, 104.0], "category_id": 2}, {"id": 9, "bbox": [3.0, 490.0, 245.0, 58.0], "category_id": 2}, {"id": 10, "bbox": [439.0, 198.0, 281.0, 89.0], "category_id": 2}, {"id": 11, "bbox": [55.0, 1232.0, 303.0, 288.0], "category_id": 1}, {"id": 12, "bbox": [399.0, 1215.0, 387.0, 294.0], "category_id": 1}, {"id": 13, "bbox": [829.0, 1217.0, 423.0, 299.0], "category_id": 1}, {"id": 14, "bbox": [16.0, 1658.0, 314.0, 252.0], "category_id": 1}, {"id": 15, "bbox": [386.0, 1641.0, 395.0, 303.0], "category_id": 1}, {"id": 16, "bbox": [850.0, 1645.0, 447.0, 407.0], "category_id": 1}, {"id": 17, "bbox": [268.0, 11.0, 42.0, 48.0], "category_id": 3}, {"id": 18, "bbox": [455.0, 718.0, 64.0, 47.0], "category_id": 3}, {"id": 19, "bbox": [48.0, 96.0, 319.0, 254.0], "category_id": 1}, {"id": 20, "bbox": [339.0, 397.0, 298.0, 320.0], "category_id": 1}, {"id": 21, "bbox": [1039.0, 383.0, 299.0, 308.0], "category_id": 1}, {"id": 22, "bbox": [29.0, 815.0, 303.0, 299.0], "category_id": 1}, {"id": 23, "bbox": [418.0, 813.0, 378.0, 316.0], "category_id": 1}, {"id": 24, "bbox": [884.0, 821.0, 424.0, 278.0], "category_id": 1}, {"id": 25, "bbox": [448.0, 1938.0, 284.0, 90.0], "category_id": 3}, {"id": 26, "bbox": [59.0, 1533.0, 286.0, 93.0], "category_id": 3}, {"id": 27, "bbox": [513.0, 1525.0, 172.0, 87.1], "category_id": 3}, {"id": 28, "bbox": [968.0, 1525.0, 174.0, 86.0], "category_id": 3}, {"id": 29, "bbox": [878.0, 1944.0, 176.0, 93.1], "category_id": 3}, {"id": 30, "bbox": [40.0, 1120.0, 286.0, 95.0], "category_id": 3}, {"id": 31, "bbox": [536.0, 1120.0, 157.0, 75.0], "category_id": 3}, {"id": 32, "bbox": [949.0, 1120.0, 290.0, 97.0], "category_id": 3}, {"id": 33, "bbox": [0.0, 1929.0, 330.0, 123.0], "category_id": 3}], "reactions": [{"reactants": [3, 19], "conditions": [0, 10], "products": [2]}, {"reactants": [2], "conditions": [9, 8], "products": [20]}, {"reactants": [20], "conditions": [7, 6], "products": [21]}], "corefs": [[3, 17], [19, 4], [2, 1], [20, 18], [21, 5], [22, 30], [23, 31], [24, 32], [11, 26], [12, 27], [13, 28], [14, 33], [15, 25], [16, 29]], "caption": "Table 6. Thermodynamic protonation and reduction tetrahydropyridine products ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 378, 125], "ImageBB": [82, 131, 420, 644]}, "diagram_type": "multiple"}, {"id": 443, "width": 1328, "height": 2400, "file_name": "op200234j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 0.0, 258.0, 176.0], "category_id": 1}, {"id": 1, "bbox": [7.0, 201.0, 1321.0, 2199.0], "category_id": 4}, {"id": 2, "bbox": [593.0, 125.0, 171.0, 81.0], "category_id": 2}, {"id": 3, "bbox": [383.0, 25.0, 586.0, 70.0], "category_id": 2}, {"id": 4, "bbox": [1115.0, 61.1, 213.0, 78.9], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [3, 2], "products": [4]}], "corefs": [], "caption": "                                             a Table 1. Hydrogenation of esters in methanol ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 720, 110], "ImageBB": [451, 116, 783, 716]}, "diagram_type": "single"}, {"id": 157, "width": 1140, "height": 664, "file_name": "op7001485-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [790.0, 343.0, 344.0, 263.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 132.0, 346.0, 270.0], "category_id": 1}, {"id": 2, "bbox": [376.0, 56.0, 400.0, 181.0], "category_id": 1}, {"id": 3, "bbox": [774.0, 5.0, 357.0, 263.0], "category_id": 1}, {"id": 4, "bbox": [423.0, 417.0, 254.0, 170.0], "category_id": 1}, {"id": 5, "bbox": [380.0, 373.0, 53.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [370.0, 258.0, 52.0, 39.0], "category_id": 3}, {"id": 7, "bbox": [1021.0, 267.0, 48.0, 33.0], "category_id": 3}, {"id": 8, "bbox": [153.0, 459.0, 27.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [1035.0, 616.0, 50.0, 43.0], "category_id": 3}, {"id": 10, "bbox": [462.0, 259.0, 191.0, 37.0], "category_id": 2}, {"id": 11, "bbox": [463.0, 356.0, 178.0, 36.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [2, 10, 11, 4], "products": [3, 0]}], "corefs": [[1, 8], [2, 6], [4, 5], [3, 7], [0, 9]], "caption": "Figure 1. Fluorination of steroid with DAST or Deoxofluor. Rings A, B, and C represent the rest of the steroid molecule that remains unchanged in the reaction. ", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 357, 760, 398], "ImageBB": [451, 188, 736, 354]}, "diagram_type": "single"}, {"id": 428, "width": 3396, "height": 1076, "file_name": "op300216x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [839.0, 835.0, 255.0, 177.0], "category_id": 1}, {"id": 1, "bbox": [1919.0, 827.0, 319.0, 188.0], "category_id": 1}, {"id": 2, "bbox": [1362.0, 829.0, 302.0, 247.0], "category_id": 1}, {"id": 3, "bbox": [2044.9, 408.4, 294.2, 166.8], "category_id": 1}, {"id": 4, "bbox": [1097.0, 822.0, 212.0, 90.0], "category_id": 1}, {"id": 5, "bbox": [2378.0, 887.0, 99.0, 77.0], "category_id": 1}, {"id": 6, "bbox": [1102.0, 403.0, 201.0, 74.0], "category_id": 1}, {"id": 7, "bbox": [1344.1, 408.7, 201.7, 159.6], "category_id": 1}, {"id": 8, "bbox": [854.0, 413.6, 232.3, 162.4], "category_id": 1}, {"id": 9, "bbox": [1589.0, 450.0, 206.0, 88.0], "category_id": 1}, {"id": 10, "bbox": [2439.0, 457.0, 99.0, 73.0], "category_id": 1}, {"id": 11, "bbox": [1292.0, 747.0, 239.0, 82.0], "category_id": 2}, {"id": 12, "bbox": [976.0, 697.0, 68.0, 77.0], "category_id": 1}, {"id": 13, "bbox": [1276.0, 277.0, 241.0, 66.0], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [6], "products": [7, 9]}, {"reactants": [7, 9], "conditions": [], "products": [3, 10]}, {"reactants": [3, 10], "conditions": [], "products": [7, 9]}, {"reactants": [7, 9], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [12], "products": [0]}, {"reactants": [0], "conditions": [], "products": [8]}, {"reactants": [0], "conditions": [4], "products": [2]}, {"reactants": [2], "conditions": [], "products": [0]}, {"reactants": [2], "conditions": [], "products": [1, 5]}, {"reactants": [1, 5], "conditions": [], "products": [2]}], "corefs": [], "caption": "Figure 1. Potential reaction pathways associated with the formation of the sulfonate ester MMS.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 300, 551, 314], "ImageBB": [10, 22, 859, 291]}, "diagram_type": "tree"}, {"id": 84, "width": 1224, "height": 1196, "file_name": "ja063878k-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [821.8, 4.3, 302.59, 162.36], "category_id": 1}, {"id": 1, "bbox": [440.3, 136.63, 20.69, 28.47], "category_id": 3}, {"id": 2, "bbox": [159.99, 133.51, 76.71, 31.59], "category_id": 3}, {"id": 3, "bbox": [5.8, 203.59, 1210.47, 986.21], "category_id": 4}, {"id": 4, "bbox": [578.9, 88.35, 146.82, 81.42], "category_id": 2}, {"id": 5, "bbox": [507.26, 30.73, 297.89, 31.57], "category_id": 2}, {"id": 6, "bbox": [300.14, 8.9, 212.24, 154.64], "category_id": 1}, {"id": 7, "bbox": [36.96, 10.49, 182.64, 157.72], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [5, 4], "products": [0]}], "corefs": [[7, 2], [6, 1]], "caption": "Table 3. Alkenylation with 2,2-Disubstituted Vinylsilanes", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 357, 76], "ImageBB": [89, 77, 395, 376]}, "diagram_type": "single"}, {"id": 464, "width": 1356, "height": 1568, "file_name": "op200005e-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [844.01, 310.98, 321.59, 50.44], "category_id": 2}, {"id": 1, "bbox": [60.0, 1020.0, 246.0, 57.0], "category_id": 2}, {"id": 2, "bbox": [1089.0, 1006.0, 223.0, 66.0], "category_id": 2}, {"id": 3, "bbox": [301.0, 495.0, 398.0, 63.0], "category_id": 2}, {"id": 4, "bbox": [361.0, 183.0, 215.0, 117.0], "category_id": 2}, {"id": 5, "bbox": [1022.67, 716.64, 321.59, 44.14], "category_id": 2}, {"id": 6, "bbox": [499.3, 1069.75, 502.35, 90.39], "category_id": 2}, {"id": 7, "bbox": [63.0, 917.0, 238.0, 66.0], "category_id": 2}, {"id": 8, "bbox": [0.0, 624.0, 203.0, 58.0], "category_id": 3}, {"id": 9, "bbox": [1023.0, 670.0, 59.2, 45.8], "category_id": 3}, {"id": 10, "bbox": [853.2, 266.0, 62.9, 43.2], "category_id": 3}, {"id": 11, "bbox": [166.0, 1461.0, 332.0, 107.0], "category_id": 2}, {"id": 12, "bbox": [371.5, 17.0, 221.5, 140.0], "category_id": 1}, {"id": 13, "bbox": [395.5, 800.0, 683.3, 213.0], "category_id": 1}, {"id": 14, "bbox": [139.6, 804.4, 111.7, 103.3], "category_id": 1}, {"id": 15, "bbox": [0.0, 1219.0, 687.6, 210.7], "category_id": 1}, {"id": 16, "bbox": [637.2, 35.5, 494.7, 206.9], "category_id": 1}, {"id": 17, "bbox": [245.8, 521.0, 49.2, 66.0], "category_id": 3}, {"id": 18, "bbox": [1089.0, 925.0, 195.0, 62.7], "category_id": 2}, {"id": 19, "bbox": [123.0, 280.0, 54.0, 49.9], "category_id": 3}, {"id": 20, "bbox": [298.31, 576.0, 350.0, 60.0], "category_id": 2}, {"id": 21, "bbox": [5.0, 35.5, 311.4, 212.8], "category_id": 1}, {"id": 22, "bbox": [0.0, 459.9, 187.6, 156.1], "category_id": 1}, {"id": 23, "bbox": [763.6, 430.3, 592.4, 210.7], "category_id": 1}, {"id": 24, "bbox": [498.0, 1023.0, 52.7, 44.6], "category_id": 3}], "reactions": [{"reactants": [21], "conditions": [12, 4], "products": [16]}, {"reactants": [22, 17], "conditions": [3, 20], "products": [23]}, {"reactants": [23], "conditions": [14, 7, 1], "products": [13]}, {"reactants": [13], "conditions": [18, 2], "products": [15]}], "corefs": [[21, 19], [16, 10], [23, 9], [13, 24]], "caption": "Figure 4. Second generation scale-up synthesis of 1 3 HCl 3 H2O.", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 691, 378, 710], "ImageBB": [71, 285, 410, 677]}, "diagram_type": "multiple"}, {"id": 1282, "width": 1344, "height": 772, "file_name": "op100335q-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [880.76, 284.95, 252.8, 114.25], "category_id": 3}, {"id": 1, "bbox": [28.91, 237.91, 289.78, 61.09], "category_id": 3}, {"id": 2, "bbox": [882.78, 19.8, 217.83, 210.72], "category_id": 1}, {"id": 3, "bbox": [47.06, 418.02, 328.78, 254.04], "category_id": 1}, {"id": 4, "bbox": [703.94, 81.99, 57.82, 45.7], "category_id": 3}, {"id": 5, "bbox": [606.45, 421.38, 388.61, 252.02], "category_id": 1}, {"id": 6, "bbox": [689.82, 163.31, 80.68, 44.36], "category_id": 2}, {"id": 7, "bbox": [748.31, 674.74, 60.51, 51.75], "category_id": 3}, {"id": 8, "bbox": [211.79, 14.79, 224.56, 106.85], "category_id": 2}, {"id": 9, "bbox": [63.2, 109.55, 163.38, 92.07], "category_id": 1}, {"id": 10, "bbox": [178.17, 671.38, 66.56, 53.77], "category_id": 3}, {"id": 11, "bbox": [429.62, 236.56, 256.84, 118.96], "category_id": 3}, {"id": 12, "bbox": [601.07, 24.87, 233.3, 88.04], "category_id": 1}, {"id": 13, "bbox": [452.48, 24.19, 207.08, 168.69], "category_id": 1}, {"id": 14, "bbox": [408.11, 448.26, 194.3, 53.77], "category_id": 2}], "caption": "Scheme 3. Synthesis of imidazoles from acetamidic esters", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 340, 392, 355], "ImageBB": [71, 365, 407, 558]}, "reactions": [{"reactants": [9], "conditions": [8], "products": [13]}, {"reactants": [13, 12], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}], "diagram_type": "multiple"}, {"id": 72, "width": 2800, "height": 1320, "file_name": "ja206047h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1094.02, 100.07, 196.89, 116.43], "category_id": 1}, {"id": 1, "bbox": [952.76, 250.26, 21.67, 35.97], "category_id": 3}, {"id": 2, "bbox": [734.63, 250.26, 212.98, 41.34], "category_id": 2}, {"id": 3, "bbox": [1405.13, 189.47, 309.53, 78.88], "category_id": 2}, {"id": 4, "bbox": [1830.67, 98.28, 234.44, 179.01], "category_id": 1}, {"id": 5, "bbox": [1451.62, 5.31, 216.55, 170.07], "category_id": 1}, {"id": 6, "bbox": [739.99, 98.28, 232.65, 139.68], "category_id": 1}, {"id": 7, "bbox": [5.13, 337.87, 2789.47, 982.13], "category_id": 4}, {"id": 8, "bbox": [1916.49, 257.41, 25.25, 32.59], "category_id": 3}, {"id": 9, "bbox": [1161.96, 252.05, 87.82, 35.95], "category_id": 3}], "reactions": [{"reactants": [6, 0], "conditions": [5, 3], "products": [4]}], "corefs": [[6, 1], [0, 9], [4, 8]], "caption": "Table 3. Scope of Diaryliodonium Salt Component in the Copper-Catalyzed Enantioselective Arylationa,b", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 654, 109], "ImageBB": [72, 117, 772, 447]}, "diagram_type": "single"}, {"id": 1117, "width": 1140, "height": 856, "file_name": "jo9901541-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1017.39, 419.13, 98.66, 59.3], "category_id": 2}, {"id": 1, "bbox": [480.75, 27.37, 422.58, 331.31], "category_id": 1}, {"id": 2, "bbox": [131.74, 127.73, 212.71, 58.74], "category_id": 2}, {"id": 3, "bbox": [628.45, 420.27, 57.6, 47.33], "category_id": 3}, {"id": 4, "bbox": [531.51, 500.1, 396.34, 272.0], "category_id": 1}, {"id": 5, "bbox": [116.34, 219.54, 256.63, 59.88], "category_id": 2}, {"id": 6, "bbox": [626.74, 796.62, 178.5, 53.61], "category_id": 3}, {"id": 7, "bbox": [0.0, 177.91, 57.6, 49.62], "category_id": 3}, {"id": 8, "bbox": [102.65, 799.48, 175.65, 52.46], "category_id": 3}, {"id": 9, "bbox": [5.13, 537.17, 415.17, 236.64], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 208, 636, 222], "ImageBB": [466, 228, 751, 442]}, "reactions": [{"reactants": [7], "conditions": [2, 5], "products": [1]}, {"reactants": [1], "conditions": [0], "products": [4, 9]}], "diagram_type": "tree"}, {"id": 493, "width": 1348, "height": 2308, "file_name": "ol060246u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [203.0, 237.0, 34.0, 33.0], "category_id": 3}, {"id": 1, "bbox": [50.0, 0.0, 234.0, 270.0], "category_id": 1}, {"id": 2, "bbox": [344.0, 95.0, 354.0, 57.0], "category_id": 2}, {"id": 3, "bbox": [909.0, 245.0, 29.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [1260.0, 234.0, 34.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [11.0, 359.0, 1337.0, 1939.0], "category_id": 4}, {"id": 6, "bbox": [1053.7, 24.7, 251.3, 271.3], "category_id": 1}, {"id": 7, "bbox": [710.5, 12.4, 348.5, 279.8], "category_id": 1}, {"id": 8, "bbox": [378.0, 197.7, 188.0, 81.3], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [2], "products": [7, 6]}], "corefs": [[1, 0], [7, 3], [6, 4]], "caption": "Table 1. Effect of Base, Solvent, Temperature, and Reactant Ratio on the Reaction ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 760, 104], "ImageBB": [439, 113, 776, 690]}, "diagram_type": "single"}, {"id": 332, "width": 1344, "height": 748, "file_name": "ol300387f-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.0, 232.0, 47.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [853.0, 229.0, 109.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [1099.0, 231.0, 45.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [121.0, 18.0, 160.0, 192.2], "category_id": 1}, {"id": 4, "bbox": [11.0, 303.0, 1327.0, 437.0], "category_id": 4}, {"id": 5, "bbox": [809.0, 18.0, 170.0, 193.0], "category_id": 1}, {"id": 6, "bbox": [301.0, 3.0, 419.0, 115.0], "category_id": 2}, {"id": 7, "bbox": [1022.0, 20.0, 203.0, 191.0], "category_id": 1}, {"id": 8, "bbox": [298.0, 151.0, 477.0, 112.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [6, 8], "products": [5, 7]}], "corefs": [[3, 0], [5, 1], [7, 2]], "caption": "Table 3. Kinetic Resolution of 1e Followed by 1,4-Addition of Remaining (S)-1e ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 770, 403, 797], "ImageBB": [71, 808, 407, 995]}, "diagram_type": "single"}, {"id": 727, "width": 1352, "height": 3776, "file_name": "ol016693l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [286.0, 2507.0, 42.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [5.0, 1406.0, 1347.0, 642.0], "category_id": 2}, {"id": 2, "bbox": [0.0, 1182.0, 1338.0, 117.0], "category_id": 2}, {"id": 3, "bbox": [540.0, 2503.0, 55.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [100.0, 2.0, 1143.0, 1133.0], "category_id": 4}, {"id": 5, "bbox": [2.0, 2989.0, 1350.0, 787.0], "category_id": 2}, {"id": 6, "bbox": [741.0, 2260.0, 288.0, 61.0], "category_id": 2}, {"id": 7, "bbox": [724.0, 2593.0, 200.0, 199.0], "category_id": 1}, {"id": 8, "bbox": [462.0, 2591.0, 200.0, 206.0], "category_id": 1}, {"id": 9, "bbox": [485.0, 2289.0, 216.0, 191.0], "category_id": 1}, {"id": 10, "bbox": [240.0, 2277.0, 201.0, 210.0], "category_id": 1}, {"id": 11, "bbox": [727.0, 2442.0, 344.0, 57.0], "category_id": 2}, {"id": 12, "bbox": [725.0, 2396.0, 365.0, 55.0], "category_id": 2}, {"id": 13, "bbox": [825.0, 2321.0, 157.0, 50.0], "category_id": 2}, {"id": 14, "bbox": [517.0, 2813.0, 46.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [10, 9], "conditions": [6, 13, 12, 11], "products": [8, 7]}], "corefs": [[10, 0], [9, 3], [8, 14]], "caption": "Table 2. Cleavage of N-Alloc Carbamate Using Ni(0) Catalysis ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 726, 104], "ImageBB": [439, 106, 777, 1050]}, "diagram_type": "multiple"}, {"id": 745, "width": 1320, "height": 1316, "file_name": "jo991700t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [135.9, 522.0, 122.5, 129.0], "category_id": 2}, {"id": 1, "bbox": [24.6, 1007.5, 482.8, 163.9], "category_id": 3}, {"id": 2, "bbox": [797.2, 729.1, 326.3, 250.7], "category_id": 1}, {"id": 3, "bbox": [91.1, 751.2, 291.3, 230.2], "category_id": 1}, {"id": 4, "bbox": [113.6, 199.1, 314.8, 250.1], "category_id": 1}, {"id": 5, "bbox": [502.0, 826.3, 176.0, 61.4], "category_id": 2}, {"id": 6, "bbox": [701.0, 1008.0, 619.0, 308.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [5], "products": [2]}], "corefs": [], "caption": "Table 3. Hydrogen Transfer Reduction of Acetophenone                Using Ligands 16-22ba ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [75, 376, 408, 401], "ImageBB": [74, 35, 404, 364]}, "diagram_type": "tree"}, {"id": 504, "width": 1344, "height": 816, "file_name": "ol051920v-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [148.0, 215.0, 42.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [437.0, 233.0, 58.0, 50.0], "category_id": 3}, {"id": 2, "bbox": [76.3, 11.6, 235.2, 189.0], "category_id": 1}, {"id": 3, "bbox": [651.4, 147.0, 190.6, 47.8], "category_id": 2}, {"id": 4, "bbox": [379.1, 41.8, 198.8, 180.2], "category_id": 1}, {"id": 5, "bbox": [1023.28, 209.09, 52.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [617.0, 66.1, 271.3, 53.9], "category_id": 2}, {"id": 7, "bbox": [956.0, 1.8, 315.9, 196.1], "category_id": 1}, {"id": 8, "bbox": [0.0, 319.7, 1344.0, 496.3], "category_id": 4}], "reactions": [{"reactants": [2, 4], "conditions": [6, 3], "products": [7]}], "corefs": [[2, 0], [4, 1], [7, 5]], "caption": "Table 3. Reactions of Salicylic Aldehydes 1 (0.5 mmol) with 3-Benzylpenta-3,4-dien-2-one 2b (1.0 mmol) in the Presence of DBU (10 mol %) in DMSO at Room Temperature ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 402, 120], "ImageBB": [74, 125, 410, 329]}, "diagram_type": "single"}, {"id": 641, "width": 1348, "height": 280, "file_name": "ol501019y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 194.0, 1340.0, 86.0], "category_id": 4}, {"id": 1, "bbox": [426.6, 4.6, 275.2, 102.4], "category_id": 2}, {"id": 2, "bbox": [441.5, 128.1, 233.0, 53.7], "category_id": 2}, {"id": 3, "bbox": [755.2, 43.3, 406.0, 120.6], "category_id": 1}, {"id": 4, "bbox": [186.7, 44.5, 179.9, 120.3], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [1, 2], "products": [3]}], "corefs": [], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 450, 716, 471], "ImageBB": [449, 477, 786, 547]}, "diagram_type": "single"}, {"id": 101, "width": 1348, "height": 632, "file_name": "ja026703t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [232.99, 11.3, 158.67, 124.09], "category_id": 1}, {"id": 1, "bbox": [474.1, 15.37, 426.24, 91.53], "category_id": 2}, {"id": 2, "bbox": [965.48, 8.25, 158.72, 125.1], "category_id": 1}, {"id": 3, "bbox": [6.65, 224.95, 1337.05, 407.05], "category_id": 4}, {"id": 4, "bbox": [511.74, 150.68, 309.24, 40.66], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [1, 4], "products": [2]}], "corefs": [], "caption": "Table 3. Transfer Hydrogenation Catalyzed by C-6 and C-8a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 63, 745, 76], "ImageBB": [439, 82, 776, 240]}, "diagram_type": "single"}, {"id": 1194, "width": 1752, "height": 1076, "file_name": "ol501424f-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [550.4, 516.89, 369.86, 56.07], "category_id": 2}, {"id": 1, "bbox": [184.93, 75.34, 261.18, 129.66], "category_id": 1}, {"id": 2, "bbox": [1018.42, 5.26, 317.27, 209.38], "category_id": 1}, {"id": 3, "bbox": [1119.21, 667.58, 42.95, 47.3], "category_id": 3}, {"id": 4, "bbox": [300.62, 214.64, 59.6, 46.43], "category_id": 3}, {"id": 5, "bbox": [186.68, 707.88, 402.29, 97.24], "category_id": 2}, {"id": 6, "bbox": [1147.26, 222.53, 56.09, 46.43], "category_id": 3}, {"id": 7, "bbox": [945.68, 707.88, 441.72, 97.24], "category_id": 2}, {"id": 8, "bbox": [758.12, 49.94, 262.05, 94.61], "category_id": 2}, {"id": 9, "bbox": [889.58, 334.66, 262.94, 54.32], "category_id": 2}, {"id": 10, "bbox": [601.24, 584.35, 191.06, 56.94], "category_id": 2}, {"id": 11, "bbox": [942.17, 459.94, 392.65, 207.64], "category_id": 1}, {"id": 12, "bbox": [300.62, 647.43, 40.31, 42.05], "category_id": 3}, {"id": 13, "bbox": [184.93, 467.83, 302.37, 183.98], "category_id": 1}, {"id": 14, "bbox": [604.74, 212.89, 67.49, 49.06], "category_id": 3}, {"id": 15, "bbox": [486.42, 49.94, 268.19, 131.41], "category_id": 1}, {"id": 16, "bbox": [808.95, 155.94, 148.12, 47.31], "category_id": 2}], "caption": "Scheme 2. Transformation of (S)-1,3,4-Oxadiazin-6-ones into (S)-\u03b1-Amino Acid Ester ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 811, 784, 841], "ImageBB": [421, 858, 859, 1127]}, "reactions": [{"reactants": [1, 15], "conditions": [8, 16], "products": [2]}, {"reactants": [2], "conditions": [9], "products": [11]}, {"reactants": [11], "conditions": [0, 10], "products": [13]}], "diagram_type": "tree"}, {"id": 455, "width": 1356, "height": 668, "file_name": "op200052z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1317.1, 80.0, 36.9, 60.9], "category_id": 3}, {"id": 1, "bbox": [423.0, 12.0, 272.0, 120.0], "category_id": 2}, {"id": 2, "bbox": [3.0, 2.0, 408.0, 219.0], "category_id": 1}, {"id": 3, "bbox": [492.0, 188.1, 132.0, 56.81], "category_id": 2}, {"id": 4, "bbox": [736.5, 3.1, 485.2, 219.8], "category_id": 1}, {"id": 5, "bbox": [935.07, 236.07, 61.7, 58.9], "category_id": 3}, {"id": 6, "bbox": [7.0, 364.0, 1339.0, 300.0], "category_id": 4}, {"id": 7, "bbox": [140.0, 235.0, 62.0, 56.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [1, 3], "products": [4, 0]}], "corefs": [[2, 7], [4, 5]], "caption": "Table 3. Thermal stability study of 6a", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 438, 647, 459], "ImageBB": [436, 469, 775, 636]}, "diagram_type": "single"}, {"id": 1175, "width": 1344, "height": 680, "file_name": "ol202381m-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [24.88, 12.11, 236.66, 172.23], "category_id": 1}, {"id": 1, "bbox": [301.21, 0.0, 345.58, 123.79], "category_id": 2}, {"id": 2, "bbox": [365.75, 410.39, 179.51, 78.04], "category_id": 2}, {"id": 3, "bbox": [803.44, 308.8, 256.83, 82.75], "category_id": 2}, {"id": 4, "bbox": [301.21, 140.61, 239.35, 76.69], "category_id": 2}, {"id": 5, "bbox": [728.14, 220.0, 58.49, 43.05], "category_id": 3}, {"id": 6, "bbox": [567.45, 532.16, 289.78, 96.21], "category_id": 3}, {"id": 7, "bbox": [89.42, 530.82, 52.44, 46.42], "category_id": 3}, {"id": 8, "bbox": [602.41, 280.54, 187.58, 240.86], "category_id": 1}, {"id": 9, "bbox": [1122.8, 528.12, 55.13, 51.81], "category_id": 3}, {"id": 10, "bbox": [665.61, 12.78, 207.75, 200.49], "category_id": 1}, {"id": 11, "bbox": [362.39, 314.86, 247.42, 82.75], "category_id": 2}, {"id": 12, "bbox": [806.8, 406.35, 159.35, 71.99], "category_id": 2}, {"id": 13, "bbox": [1056.91, 280.54, 262.21, 251.62], "category_id": 1}, {"id": 14, "bbox": [908.33, 148.01, 233.97, 75.35], "category_id": 2}, {"id": 15, "bbox": [24.2, 279.87, 342.22, 275.84], "category_id": 1}, {"id": 16, "bbox": [89.42, 219.32, 59.84, 43.73], "category_id": 3}, {"id": 17, "bbox": [909.17, 16.21, 35.47, 47.63], "category_id": 2}, {"id": 18, "bbox": [928.42, 74.99, 184.47, 38.52], "category_id": 2}, {"id": 19, "bbox": [949.9, 16.15, 310.73, 48.44], "category_id": 1}], "caption": "Scheme 2. 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Comparative study of Pd-PEPPSI-IPr (2) and Pd- PEPPSI-IPent (1) in aryl aminations with electron-de\ufb01cient anilines ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 94, 784, 139], "ImageBB": [448, 146, 787, 424]}, "diagram_type": "single"}, {"id": 1192, "width": 1356, "height": 1276, "file_name": "ol500444z-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [300.0, 553.68, 647.64, 52.42], "category_id": 2}, {"id": 1, "bbox": [374.44, 1059.19, 645.1, 150.63], "category_id": 2}, {"id": 2, "bbox": [974.77, 656.82, 94.97, 43.43], "category_id": 3}, {"id": 3, "bbox": [1069.74, 1155.54, 223.85, 54.28], "category_id": 2}, {"id": 4, "bbox": [1203.37, 656.82, 44.77, 43.43], "category_id": 3}, {"id": 5, "bbox": [1010.73, 6.11, 189.93, 273.45], "category_id": 1}, {"id": 6, "bbox": [362.23, 209.67, 644.43, 52.92], "category_id": 2}, {"id": 7, "bbox": [1069.74, 264.63, 59.02, 41.39], "category_id": 3}, {"id": 8, "bbox": [974.77, 701.6, 99.04, 48.18], "category_id": 2}, {"id": 9, "bbox": [1172.17, 700.25, 103.79, 53.6], "category_id": 2}, {"id": 10, "bbox": [88.7, 961.9, 228.3, 142.4], "category_id": 1}, {"id": 11, "bbox": [85.8, 452.3, 229.63, 154.31], "category_id": 1}, {"id": 12, "bbox": [148.6, 1102.61, 56.94, 45.59], "category_id": 3}, {"id": 13, "bbox": [112.7, 111.8, 229.5, 152.15], "category_id": 1}, {"id": 14, "bbox": [317.4, 352.2, 214.2, 174.1], "category_id": 1}, {"id": 15, "bbox": [1167.6, 1110.08, 35.77, 42.75], "category_id": 3}, {"id": 16, "bbox": [163.2, 264.63, 60.65, 46.27], "category_id": 3}, {"id": 17, "bbox": [942.4, 388.5, 179.2, 268.1], "category_id": 1}, {"id": 18, "bbox": [133.63, 604.57, 61.05, 48.83], "category_id": 3}, {"id": 19, "bbox": [529.38, 980.34, 568.3, 47.49], "category_id": 2}, {"id": 20, "bbox": [1039.47, 309.41, 116.42, 52.08], "category_id": 2}, {"id": 21, "bbox": [42.26, 972.68, 50.55, 52.09], "category_id": 2}, {"id": 22, "bbox": [1103.81, 847.08, 185.35, 263.47], "category_id": 1}, {"id": 23, "bbox": [316.5, 851.67, 209.81, 174.63], "category_id": 1}, {"id": 24, "bbox": [1129.85, 390.6, 186.88, 268.06], "category_id": 1}, {"id": 25, "bbox": [529.38, 484.04, 433.5, 47.48], "category_id": 2}, {"id": 26, "bbox": [36.13, 490.16, 55.15, 49.02], "category_id": 2}, {"id": 27, "bbox": [52.98, 134.78, 58.21, 49.02], "category_id": 2}, {"id": 28, "bbox": [550.82, 136.32, 456.48, 44.42], "category_id": 2}, {"id": 29, "bbox": [342.5, 6.11, 211.39, 173.1], "category_id": 1}], "caption": "Scheme 2. Optimization of Conditions for the Synthesis of Tetrahydroquinoxaline 4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 471, 782, 501], "ImageBB": [448, 507, 787, 826]}, "reactions": [{"reactants": [13, 29], "conditions": [28, 6], "products": [5]}, {"reactants": [11, 14], "conditions": [25, 0], "products": [17, 24]}, {"reactants": [10, 23], "conditions": [19, 1], "products": [22]}], "diagram_type": "multiple"}, {"id": 456, "width": 1344, "height": 620, "file_name": "op200052z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [749.0, 50.4, 473.9, 227.6], "category_id": 1}, {"id": 1, "bbox": [974.0, 327.1, 44.9, 46.9], "category_id": 3}, {"id": 2, "bbox": [180.01, 328.97, 44.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [1285.89, 153.04, 32.1, 51.0], "category_id": 3}, {"id": 4, "bbox": [23.2, 64.4, 401.8, 236.6], "category_id": 1}, {"id": 5, "bbox": [9.0, 460.0, 1335.0, 160.0], "category_id": 4}, {"id": 6, "bbox": [452.0, 206.0, 235.0, 121.0], "category_id": 2}, {"id": 7, "bbox": [438.0, 3.0, 273.0, 176.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [7, 6], "products": [0, 3]}], "corefs": [[4, 2], [0, 1]], "caption": "Table 2. Results of di\ufb02uoromethylation of 5", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 444, 317, 459], "ImageBB": [71, 469, 407, 624]}, "diagram_type": "single"}, {"id": 1105, "width": 1348, "height": 1392, "file_name": "jo980058k-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [616.2, 717.93, 33.42, 46.66], "category_id": 2}, {"id": 1, "bbox": [739.21, 1318.4, 110.29, 48.46], "category_id": 2}, {"id": 2, "bbox": [709.13, 1320.07, 26.74, 48.46], "category_id": 2}, {"id": 3, "bbox": [272.98, 1340.12, 347.58, 46.79], "category_id": 3}, {"id": 4, "bbox": [272.98, 1296.68, 275.73, 43.44], "category_id": 3}, {"id": 5, "bbox": [272.98, 1248.22, 466.23, 51.8], "category_id": 3}, {"id": 6, "bbox": [161.02, 1323.41, 36.76, 43.45], "category_id": 2}, {"id": 7, "bbox": [161.02, 1269.94, 35.09, 46.79], "category_id": 2}, {"id": 8, "bbox": [832.79, 543.03, 35.09, 45.11], "category_id": 2}, {"id": 9, "bbox": [600.51, 780.32, 90.24, 46.79], "category_id": 2}, {"id": 10, "bbox": [949.76, 564.75, 193.85, 43.45], "category_id": 3}, {"id": 11, "bbox": [45.26, 781.3, 84.25, 48.75], "category_id": 2}, {"id": 12, "bbox": [45.26, 1059.84, 84.25, 52.92], "category_id": 2}, {"id": 13, "bbox": [45.26, 418.51, 89.82, 51.53], "category_id": 2}, {"id": 14, "bbox": [184.51, 890.63, 290.35, 104.45], "category_id": 3}, {"id": 15, "bbox": [192.17, 0.0, 416.37, 176.87], "category_id": 1}, {"id": 16, "bbox": [45.26, 178.27, 51.52, 45.95], "category_id": 3}, {"id": 17, "bbox": [0.0, 6.27, 132.29, 149.71], "category_id": 1}, {"id": 18, "bbox": [45.26, 419.9, 87.03, 50.14], "category_id": 2}, {"id": 19, "bbox": [884.27, 274.36, 346.74, 231.19], "category_id": 1}, {"id": 20, "bbox": [297.31, 176.18, 57.09, 46.65], "category_id": 3}, {"id": 21, "bbox": [45.26, 725.59, 54.31, 41.09], "category_id": 2}, {"id": 22, "bbox": [799.32, 4.18, 487.4, 155.28], "category_id": 1}, {"id": 23, "bbox": [646.14, 108.63, 84.95, 45.96], "category_id": 2}, {"id": 24, "bbox": [731.09, 354.44, 42.47, 39.0], "category_id": 2}, {"id": 25, "bbox": [232.56, 1002.05, 453.97, 231.88], "category_id": 1}, {"id": 26, "bbox": [184.51, 654.57, 294.53, 229.1], "category_id": 1}, {"id": 27, "bbox": [570.95, 522.26, 251.05, 101.67], "category_id": 2}, {"id": 28, "bbox": [949.72, 513.21, 325.28, 52.69], "category_id": 3}, {"id": 29, "bbox": [27.15, 1174.74, 164.55, 207.26], "category_id": 2}, {"id": 30, "bbox": [731.09, 1126.69, 80.07, 49.44], "category_id": 2}, {"id": 31, "bbox": [984.53, 1249.94, 61.97, 48.75], "category_id": 3}, {"id": 32, "bbox": [948.33, 169.91, 61.27, 48.05], "category_id": 3}, {"id": 33, "bbox": [848.76, 995.08, 492.27, 231.89], "category_id": 1}, {"id": 34, "bbox": [763.12, 647.6, 584.88, 234.67], "category_id": 1}, {"id": 35, "bbox": [276.42, 535.49, 60.58, 52.23], "category_id": 3}, {"id": 36, "bbox": [59.88, 355.83, 43.17, 48.05], "category_id": 2}, {"id": 37, "bbox": [735.27, 1073.07, 48.04, 36.91], "category_id": 2}, {"id": 38, "bbox": [194.26, 284.81, 478.34, 231.88], "category_id": 1}, {"id": 39, "bbox": [966.43, 894.81, 58.49, 50.13], "category_id": 3}, {"id": 40, "bbox": [646.84, 48.74, 53.61, 37.61], "category_id": 2}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 183, 275, 197], "ImageBB": [74, 204, 411, 552]}, "reactions": [{"reactants": [17, 15], "conditions": [40, 23], "products": [22]}, {"reactants": [22], "conditions": [36, 18], "products": [38]}, {"reactants": [38], "conditions": [24], "products": [19]}, {"reactants": [19], "conditions": [21, 11], "products": [26]}, {"reactants": [26], "conditions": [0, 9], "products": [34]}, {"reactants": [34], "conditions": [12], "products": [25]}, {"reactants": [25], "conditions": [37, 30], "products": [33]}], "diagram_type": "multiple"}, {"id": 536, "width": 996, "height": 1456, "file_name": "jo000585f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [169.6, 1140.0, 340.8, 225.1], "category_id": 1}, {"id": 1, "bbox": [656.0, 328.0, 296.0, 64.9], "category_id": 3}, {"id": 2, "bbox": [172.0, 323.2, 283.0, 76.2], "category_id": 3}, {"id": 3, "bbox": [223.32, 1392.56, 160.6, 59.17], "category_id": 3}, {"id": 4, "bbox": [219.09, 893.84, 133.14, 61.28], "category_id": 3}, {"id": 5, "bbox": [277.0, 487.0, 111.8, 52.2], "category_id": 2}, {"id": 6, "bbox": [163.0, 79.0, 335.2, 234.0], "category_id": 1}, {"id": 7, "bbox": [158.6, 639.5, 347.5, 222.7], "category_id": 1}, {"id": 8, "bbox": [648.0, 75.0, 345.0, 236.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [], "products": [8]}, {"reactants": [6], "conditions": [5], "products": [7]}, {"reactants": [7], "conditions": [], "products": [0]}], "corefs": [[6, 2], [8, 1], [7, 4], [0, 3]], "caption": "  Table 1. Phosphoramidate-Aminophosphonate Rearrangement of (R)-[1-2H1]6c Induced by s-BuLi or               LDA in Et2O or THF ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [453, 440, 761, 478], "ImageBB": [424, 63, 673, 427]}, "diagram_type": "tree"}, {"id": 1016, "width": 1324, "height": 1040, "file_name": "ja992608h-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [312.62, 617.33, 55.64, 49.02], "category_id": 3}, {"id": 1, "bbox": [0.0, 708.74, 517.94, 289.46], "category_id": 1}, {"id": 2, "bbox": [947.8, 608.72, 56.96, 49.68], "category_id": 3}, {"id": 3, "bbox": [312.62, 982.96, 63.58, 49.02], "category_id": 3}, {"id": 4, "bbox": [0.0, 347.08, 532.51, 286.81], "category_id": 1}, {"id": 5, "bbox": [448.4, 82.13, 84.11, 51.01], "category_id": 2}, {"id": 6, "bbox": [1037.87, 989.59, 54.98, 47.69], "category_id": 3}, {"id": 7, "bbox": [1123.31, 82.13, 125.18, 52.33], "category_id": 2}, {"id": 8, "bbox": [186.78, 262.96, 43.71, 47.69], "category_id": 3}, {"id": 9, "bbox": [647.1, 333.17, 529.86, 284.16], "category_id": 1}, {"id": 10, "bbox": [735.85, 723.31, 514.63, 286.81], "category_id": 1}, {"id": 11, "bbox": [592.12, 2.65, 510.0, 281.51], "category_id": 1}, {"id": 12, "bbox": [553.05, 445.78, 70.87, 57.63], "category_id": 2}, {"id": 13, "bbox": [610.67, 838.57, 30.47, 43.71], "category_id": 2}, {"id": 14, "bbox": [902.76, 270.91, 43.71, 44.38], "category_id": 3}, {"id": 15, "bbox": [15.9, 21.86, 394.08, 207.32], "category_id": 1}, {"id": 16, "bbox": [1235.91, 443.13, 43.71, 49.68], "category_id": 2}], "caption": "Scheme 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 63, 135, 78], "ImageBB": [76, 84, 407, 344]}, "reactions": [{"reactants": [15], "conditions": [5], "products": [11]}, {"reactants": [11], "conditions": [7], "products": [4]}, {"reactants": [4], "conditions": [12], "products": [9]}, {"reactants": [9], "conditions": [16], "products": [1]}, {"reactants": [1], "conditions": [13], "products": [10]}], "diagram_type": "multiple"}, {"id": 572, "width": 1348, "height": 1064, "file_name": "acs.orglett.5b00805-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [501.09, 253.91, 54.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [957.2, 3.0, 316.3, 238.2], "category_id": 1}, {"id": 2, "bbox": [133.3, 35.1, 219.9, 207.6], "category_id": 1}, {"id": 3, "bbox": [461.4, 391.3, 299.5, 305.7], "category_id": 1}, {"id": 4, "bbox": [906.3, 366.5, 432.7, 334.5], "category_id": 1}, {"id": 5, "bbox": [16.4, 388.1, 247.6, 306.9], "category_id": 1}, {"id": 6, "bbox": [620.0, 91.0, 339.0, 49.0], "category_id": 2}, {"id": 7, "bbox": [420.82, 69.5, 166.78, 109.64], "category_id": 1}, {"id": 8, "bbox": [616.0, 159.0, 237.3, 42.8], "category_id": 2}, {"id": 9, "bbox": [1048.0, 245.0, 61.0, 55.0], "category_id": 3}, {"id": 10, "bbox": [32.0, 988.0, 1314.0, 76.0], "category_id": 4}, {"id": 11, "bbox": [23.0, 701.0, 323.0, 90.0], "category_id": 3}, {"id": 12, "bbox": [50.0, 237.0, 397.0, 135.0], "category_id": 3}, {"id": 13, "bbox": [1101.0, 701.0, 212.0, 84.0], "category_id": 3}, {"id": 14, "bbox": [429.0, 695.0, 514.0, 275.0], "category_id": 3}], "reactions": [{"reactants": [2, 7], "conditions": [6, 8], "products": [1]}], "corefs": [[2, 12], [7, 0], [1, 9], [5, 11], [3, 14], [4, 13]], "caption": "Table 1. Enantioselective Addition of Cumene Hydroperoxide 2a to Ketimines 1a\u2212c Derived from Isatins Using Various Chiral Organocatalysts 3,4a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 174, 414, 219], "ImageBB": [82, 226, 419, 492]}, "diagram_type": "single"}, {"id": 927, "width": 1416, "height": 1020, "file_name": "acs.oprd.5b00144-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1289.2, 286.95, 126.8, 126.82], "category_id": 2}, {"id": 1, "bbox": [451.93, 0.0, 401.64, 165.79], "category_id": 1}, {"id": 2, "bbox": [784.86, 252.94, 494.43, 291.9], "category_id": 1}, {"id": 3, "bbox": [1367.12, 181.38, 40.38, 46.05], "category_id": 3}, {"id": 4, "bbox": [1117.07, 662.46, 298.93, 230.97], "category_id": 1}, {"id": 5, "bbox": [885.44, 0.0, 223.84, 57.39], "category_id": 2}, {"id": 6, "bbox": [495.85, 446.36, 256.42, 118.32], "category_id": 2}, {"id": 7, "bbox": [981.78, 569.64, 55.25, 53.85], "category_id": 3}, {"id": 8, "bbox": [927.24, 730.47, 134.58, 60.94], "category_id": 2}, {"id": 9, "bbox": [534.1, 339.38, 201.88, 77.22], "category_id": 1}, {"id": 10, "bbox": [625.48, 926.73, 46.75, 49.6], "category_id": 3}, {"id": 11, "bbox": [448.39, 667.42, 461.85, 226.01], "category_id": 1}, {"id": 12, "bbox": [1126.99, 0.0, 289.01, 165.79], "category_id": 1}, {"id": 13, "bbox": [1291.33, 930.27, 46.75, 48.18], "category_id": 3}], "caption": "Scheme 1. Initial Synthesis of 1, Lorcaserin", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 322, 110], "ImageBB": [82, 129, 436, 384]}, "reactions": [{"reactants": [1], "conditions": [5], "products": [12]}, {"reactants": [], "conditions": [9, 6], "products": [2]}, {"reactants": [11], "conditions": [8], "products": [4]}], "diagram_type": "multiple"}, {"id": 144, "width": 1352, "height": 1560, "file_name": "op700274v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [240.2, 19.0, 278.8, 251.3], "category_id": 1}, {"id": 1, "bbox": [528.0, 117.0, 257.0, 72.8], "category_id": 2}, {"id": 2, "bbox": [841.8, 19.0, 271.2, 202.9], "category_id": 1}, {"id": 3, "bbox": [512.0, 2.0, 273.0, 87.0], "category_id": 2}, {"id": 4, "bbox": [937.0, 227.0, 64.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [5.0, 301.0, 1347.0, 1241.0], "category_id": 4}, {"id": 6, "bbox": [345.0, 230.0, 54.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 1], "products": [2]}], "corefs": [[0, 6], [2, 4]], "caption": "Table 1. N-Detosylationa of N-tosyl-7-azaindole (1a)", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 45, 343, 59], "ImageBB": [58, 60, 396, 450]}, "diagram_type": "single"}, {"id": 362, "width": 1344, "height": 1348, "file_name": "ol1030487-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [391.6, 365.2, 106.4, 95.99], "category_id": 1}, {"id": 1, "bbox": [538.0, 385.0, 267.0, 154.0], "category_id": 1}, {"id": 2, "bbox": [1032.0, 411.0, 256.0, 164.0], "category_id": 1}, {"id": 3, "bbox": [1258.0, 185.0, 43.0, 34.0], "category_id": 3}, {"id": 4, "bbox": [549.05, 298.06, 108.42, 43.37], "category_id": 2}, {"id": 5, "bbox": [101.0, 22.0, 240.5, 200.2], "category_id": 1}, {"id": 6, "bbox": [79.0, 361.0, 39.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [213.0, 579.0, 41.0, 35.0], "category_id": 3}, {"id": 8, "bbox": [658.0, 549.0, 41.0, 34.0], "category_id": 3}, {"id": 9, "bbox": [1213.0, 553.0, 40.0, 34.0], "category_id": 3}, {"id": 10, "bbox": [404.0, 473.0, 79.0, 46.0], "category_id": 2}, {"id": 11, "bbox": [130.0, 192.0, 33.0, 27.0], "category_id": 3}, {"id": 12, "bbox": [857.0, 481.0, 84.0, 34.0], "category_id": 2}, {"id": 13, "bbox": [738.0, 231.0, 23.0, 36.0], "category_id": 3}, {"id": 14, "bbox": [729.0, 79.0, 39.0, 32.0], "category_id": 3}, {"id": 15, "bbox": [220.0, 293.0, 107.0, 70.0], "category_id": 2}, {"id": 16, "bbox": [578.0, 181.0, 201.0, 47.0], "category_id": 1}, {"id": 17, "bbox": [1229.0, 354.0, 46.0, 38.0], "category_id": 3}, {"id": 18, "bbox": [1148.0, 299.5, 195.0, 57.9], "category_id": 1}, {"id": 19, "bbox": [3.6, 300.6, 188.4, 62.4], "category_id": 1}, {"id": 20, "bbox": [707.5, 984.9, 324.9, 357.7], "category_id": 1}, {"id": 21, "bbox": [843.0, 373.0, 103.0, 91.0], "category_id": 1}, {"id": 22, "bbox": [1029.19, 20.4, 281.0, 196.8], "category_id": 1}, {"id": 23, "bbox": [80.0, 395.2, 258.5, 162.6], "category_id": 1}, {"id": 24, "bbox": [1022.0, 302.39, 111.0, 74.0], "category_id": 2}, {"id": 25, "bbox": [576.0, 21.7, 186.7, 62.3], "category_id": 1}, {"id": 26, "bbox": [307.7, 932.7, 372.1, 399.7], "category_id": 1}], "reactions": [{"reactants": [25, 16], "conditions": [4], "products": [1]}, {"reactants": [1], "conditions": [0, 10], "products": [23]}, {"reactants": [23], "conditions": [19, 15], "products": [5]}, {"reactants": [1], "conditions": [21, 12], "products": [2]}, {"reactants": [2], "conditions": [24, 18], "products": [22]}], "corefs": [[25, 14], [16, 13], [1, 8], [23, 7], [19, 6], [5, 11], [22, 3], [18, 17], [2, 9]], "caption": "Figure 1. Stereo plots of the X-ray crystal structures of (\u00fe)-9: C, gray; N, blue; O, red. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 994, 405, 1021], "ImageBB": [71, 644, 407, 981]}, "diagram_type": "tree"}, {"id": 147, "width": 1352, "height": 3428, "file_name": "op700249f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [936.44, 215.89, 131.36, 51.95], "category_id": 3}, {"id": 1, "bbox": [97.82, 216.63, 83.86, 51.21], "category_id": 3}, {"id": 2, "bbox": [0.0, 3253.22, 1351.28, 151.64], "category_id": 2}, {"id": 3, "bbox": [382.06, 17.0, 318.38, 86.83], "category_id": 2}, {"id": 4, "bbox": [4.89, 266.35, 1346.39, 2973.05], "category_id": 4}, {"id": 5, "bbox": [5.05, 3.64, 302.05, 206.32], "category_id": 1}, {"id": 6, "bbox": [811.76, 5.12, 428.96, 249.36], "category_id": 1}, {"id": 7, "bbox": [316.75, 147.62, 466.81, 101.67], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [3, 7], "products": [6]}], "corefs": [[5, 1], [6, 0]], "caption": "Table 1. Scope of CuAAC to prepare N-triazole-linked glycosidic amino acids and peptides ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 361, 73], "ImageBB": [58, 81, 396, 938]}, "diagram_type": "single"}, {"id": 902, "width": 1316, "height": 820, "file_name": "acs.joc.5b02382-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [541.0, 360.0, 258.0, 99.0], "category_id": 3}, {"id": 1, "bbox": [483.5, 203.0, 403.7, 147.7], "category_id": 1}, {"id": 2, "bbox": [7.0, 244.2, 443.9, 114.5], "category_id": 1}, {"id": 3, "bbox": [865.8, 465.4, 405.7, 105.5], "category_id": 1}, {"id": 4, "bbox": [479.9, 465.1, 381.7, 105.0], "category_id": 1}, {"id": 5, "bbox": [608.0, 34.3, 255.2, 54.6], "category_id": 2}, {"id": 6, "bbox": [907.9, 212.5, 399.8, 144.5], "category_id": 1}, {"id": 7, "bbox": [878.0, 29.5, 338.4, 124.5], "category_id": 1}, {"id": 8, "bbox": [281.3, 0.0, 304.7, 150.5], "category_id": 1}, {"id": 9, "bbox": [38.9, 10.6, 196.1, 141.1], "category_id": 1}, {"id": 10, "bbox": [876.3, 639.0, 346.8, 124.2], "category_id": 1}, {"id": 11, "bbox": [434.5, 638.4, 320.2, 122.6], "category_id": 1}, {"id": 12, "bbox": [74.0, 375.0, 281.0, 356.5], "category_id": 3}, {"id": 13, "bbox": [1002.0, 588.0, 119.0, 50.0], "category_id": 3}, {"id": 14, "bbox": [542.0, 768.0, 151.0, 46.0], "category_id": 3}, {"id": 15, "bbox": [981.0, 138.0, 35.0, 29.0], "category_id": 3}, {"id": 16, "bbox": [408.0, 127.0, 52.0, 42.0], "category_id": 3}, {"id": 17, "bbox": [111.0, 127.0, 36.0, 35.0], "category_id": 3}, {"id": 18, "bbox": [539.0, 582.0, 140.0, 48.0], "category_id": 3}, {"id": 19, "bbox": [989.0, 374.0, 147.0, 54.0], "category_id": 3}, {"id": 20, "bbox": [1002.0, 771.0, 130.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [9, 8], "conditions": [5], "products": [7]}], "corefs": [[9, 17], [8, 16], [7, 15], [2, 12], [1, 0], [4, 18], [11, 14], [6, 19], [3, 13], [10, 20]], "caption": "Table 2. Substrate Scope of the Propargylic Amidesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 274, 748, 295], "ImageBB": [453, 300, 782, 505]}, "diagram_type": "single"}, {"id": 1054, "width": 1356, "height": 944, "file_name": "jo2001534-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [971.38, 53.59, 284.9, 170.26], "category_id": 1}, {"id": 1, "bbox": [27.13, 309.32, 281.51, 42.73], "category_id": 3}, {"id": 2, "bbox": [147.88, 590.15, 276.08, 139.06], "category_id": 1}, {"id": 3, "bbox": [165.51, 769.23, 210.97, 51.55], "category_id": 3}, {"id": 4, "bbox": [203.5, 836.38, 124.82, 107.62], "category_id": 2}, {"id": 5, "bbox": [1001.23, 305.93, 246.91, 46.8], "category_id": 3}, {"id": 6, "bbox": [1082.63, 553.52, 269.3, 175.69], "category_id": 1}, {"id": 7, "bbox": [30.53, 4.07, 242.16, 299.82], "category_id": 1}, {"id": 8, "bbox": [1050.07, 373.08, 120.07, 109.21], "category_id": 2}, {"id": 9, "bbox": [1143.68, 835.02, 128.21, 108.98], "category_id": 2}, {"id": 10, "bbox": [567.77, 369.01, 126.85, 113.28], "category_id": 2}, {"id": 11, "bbox": [710.86, 836.31, 103.13, 105.39], "category_id": 2}, {"id": 12, "bbox": [693.94, 767.87, 123.46, 48.16], "category_id": 3}, {"id": 13, "bbox": [495.87, 314.75, 267.26, 47.48], "category_id": 3}, {"id": 14, "bbox": [100.39, 369.01, 119.39, 113.28], "category_id": 2}, {"id": 15, "bbox": [1176.24, 769.23, 71.9, 46.8], "category_id": 3}, {"id": 16, "bbox": [617.29, 592.86, 277.44, 139.06], "category_id": 1}, {"id": 17, "bbox": [466.02, 10.85, 287.61, 221.82], "category_id": 1}], "caption": "Scheme 5. Computational Simulation of the 7-Endo-Trig Cyclization of the Anion 1a- To Give Anion 7a- as a Model Reaction for the Formation of Type 6 Compounds for the Gas Phase and SCRF-CPCM(UAKS) Solution-Phase Simulations (THF) (Relative Energies: SCS-MP2/6-311\u00feG(d,p)// B3LYP/6-31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 310, 771, 431], "ImageBB": [436, 442, 775, 678]}, "reactions": [{"reactants": [7], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [7]}, {"reactants": [17], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [17]}, {"reactants": [0], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [0]}, {"reactants": [2], "conditions": [], "products": [16]}, {"reactants": [16], "conditions": [], "products": [2]}, {"reactants": [16], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [16]}], "diagram_type": "multiple"}, {"id": 149, "width": 1356, "height": 816, "file_name": "op7001886-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [268.0, 144.0, 192.0, 93.0], "category_id": 2}, {"id": 1, "bbox": [308.0, 66.0, 113.0, 52.0], "category_id": 2}, {"id": 2, "bbox": [41.41, 275.34, 55.69, 44.46], "category_id": 3}, {"id": 3, "bbox": [7.0, 326.8, 1342.0, 476.2], "category_id": 4}, {"id": 4, "bbox": [1242.4, 276.0, 57.2, 41.9], "category_id": 3}, {"id": 5, "bbox": [2.0, 23.0, 255.4, 212.7], "category_id": 1}, {"id": 6, "bbox": [950.75, 275.62, 58.4, 41.57], "category_id": 3}, {"id": 7, "bbox": [1070.62, 1.25, 280.0, 264.0], "category_id": 1}, {"id": 8, "bbox": [771.16, 1.53, 286.0, 271.0], "category_id": 1}, {"id": 9, "bbox": [480.38, 2.72, 300.0, 269.0], "category_id": 1}, {"id": 10, "bbox": [554.75, 277.09, 65.7, 40.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [1, 0], "products": [9, 8, 7]}], "corefs": [[5, 2], [9, 10], [8, 6], [7, 4]], "caption": "Table 1", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 441, 471, 455], "ImageBB": [424, 456, 763, 660]}, "diagram_type": "single"}, {"id": 746, "width": 1344, "height": 544, "file_name": "jo991283k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [251.3, 59.1, 173.6, 137.9], "category_id": 1}, {"id": 1, "bbox": [844.4, 60.0, 179.3, 135.8], "category_id": 1}, {"id": 2, "bbox": [787.0, 4.0, 311.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [3.0, 254.0, 1340.0, 290.0], "category_id": 4}, {"id": 4, "bbox": [546.0, 66.0, 152.0, 52.0], "category_id": 2}, {"id": 5, "bbox": [501.0, 134.0, 254.0, 84.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [4, 5], "products": [1]}], "corefs": [], "caption": "Table 2. Effect of Bulkiness of the Group Adjacent to    the Carbonyl Moiety on Stereoselectivity in the           Reduction by the APG4 Systema ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [84, 342, 399, 379], "ImageBB": [74, 385, 410, 521]}, "diagram_type": "single"}, {"id": 305, "width": 1344, "height": 1400, "file_name": "ol303154k-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [286.0, 232.0, 154.0, 49.0], "category_id": 2}, {"id": 1, "bbox": [919.8, 1050.8, 332.0, 224.6], "category_id": 1}, {"id": 2, "bbox": [579.4, 92.2, 273.6, 205.0], "category_id": 1}, {"id": 3, "bbox": [586.0, 343.8, 301.6, 202.6], "category_id": 1}, {"id": 4, "bbox": [343.0, 575.8, 136.0, 145.2], "category_id": 1}, {"id": 5, "bbox": [26.4, 261.6, 168.0, 163.2], "category_id": 1}, {"id": 6, "bbox": [224.2, 102.6, 262.2, 122.6], "category_id": 1}, {"id": 7, "bbox": [1254.2, 189.0, 57.8, 66.0], "category_id": 3}, {"id": 8, "bbox": [901.6, 399.0, 372.4, 112.0], "category_id": 2}, {"id": 9, "bbox": [893.0, 175.6, 330.2, 109.8], "category_id": 2}, {"id": 10, "bbox": [174.0, 0.0, 162.3, 46.0], "category_id": 2}, {"id": 11, "bbox": [547.0, 1338.0, 410.0, 62.0], "category_id": 2}, {"id": 12, "bbox": [995.0, 1341.0, 233.0, 56.0], "category_id": 2}, {"id": 13, "bbox": [115.0, 1338.0, 353.0, 62.0], "category_id": 2}, {"id": 14, "bbox": [1008.0, 1272.0, 187.0, 58.0], "category_id": 2}, {"id": 15, "bbox": [534.0, 573.0, 441.0, 87.0], "category_id": 2}, {"id": 16, "bbox": [515.4, 1054.6, 397.6, 263.4], "category_id": 1}, {"id": 17, "bbox": [296.0, 355.0, 159.0, 54.0], "category_id": 2}, {"id": 18, "bbox": [1266.0, 422.0, 67.0, 54.0], "category_id": 3}, {"id": 19, "bbox": [233.0, 427.0, 307.0, 125.0], "category_id": 1}, {"id": 20, "bbox": [95.0, 939.0, 381.0, 394.0], "category_id": 1}, {"id": 21, "bbox": [338.25, 3.58, 124.48, 37.89], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [6, 0], "products": [2]}, {"reactants": [5], "conditions": [19, 17], "products": [3]}], "corefs": [[20, 13], [16, 11], [1, 12]], "caption": "Figure 1. Bioactive spiro-tetrahydroquinolines.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 492, 321, 505], "ImageBB": [71, 130, 407, 480]}, "diagram_type": "tree"}, {"id": 600, "width": 1356, "height": 416, "file_name": "acs.oprd.6b00095-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1064.0, 38.0, 205.0, 306.0], "category_id": 1}, {"id": 1, "bbox": [361.3, 39.5, 209.7, 311.5], "category_id": 1}, {"id": 2, "bbox": [4.0, 42.0, 213.0, 308.0], "category_id": 1}, {"id": 3, "bbox": [706.0, 51.0, 207.0, 308.0], "category_id": 1}, {"id": 4, "bbox": [46.0, 368.0, 136.0, 43.7], "category_id": 2}, {"id": 5, "bbox": [1142.0, 363.0, 214.0, 51.0], "category_id": 2}, {"id": 6, "bbox": [778.0, 362.0, 238.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [403.0, 353.0, 222.0, 48.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}], "corefs": [[2, 4], [1, 7], [3, 6], [0, 5]], "caption": "Figure 1. Catalytic oxidation of glucose to glucaric acid.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 612, 715, 626], "ImageBB": [448, 499, 787, 603]}, "diagram_type": "single"}, {"id": 474, "width": 1896, "height": 396, "file_name": "op100108j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [910.81, 342.44, 54.34, 53.56], "category_id": 3}, {"id": 1, "bbox": [1617.17, 341.01, 51.47, 51.48], "category_id": 3}, {"id": 2, "bbox": [241.64, 339.58, 47.18, 52.91], "category_id": 3}, {"id": 3, "bbox": [653.4, 9.0, 565.3, 361.3], "category_id": 1}, {"id": 4, "bbox": [1333.3, 2.0, 560.1, 362.5], "category_id": 1}, {"id": 5, "bbox": [2.6, 35.9, 541.9, 328.6], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [], "products": [3, 4]}], "corefs": [[5, 2], [3, 0], [4, 1]], "caption": "Figure 1. Structures of (+)-catechin (1) and its B-ring fission lactone products, 2 and 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 148, 540, 162], "ImageBB": [173, 46, 647, 145]}, "diagram_type": "single"}, {"id": 1340, "width": 1352, "height": 936, "file_name": "op700009t-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [812.96, 890.59, 45.31, 43.28], "category_id": 3}, {"id": 1, "bbox": [421.36, 173.11, 39.9, 40.58], "category_id": 3}, {"id": 2, "bbox": [587.74, 526.78, 327.35, 367.19], "category_id": 1}, {"id": 3, "bbox": [1043.59, 175.82, 39.23, 41.25], "category_id": 3}, {"id": 4, "bbox": [986.78, 526.78, 365.22, 367.87], "category_id": 1}, {"id": 5, "bbox": [654.7, 132.54, 116.33, 43.28], "category_id": 2}, {"id": 6, "bbox": [0.0, 664.73, 39.9, 48.69], "category_id": 3}, {"id": 7, "bbox": [650.64, 61.54, 132.56, 45.98], "category_id": 2}, {"id": 8, "bbox": [342.9, 615.37, 127.83, 56.12], "category_id": 2}, {"id": 9, "bbox": [365.9, 253.58, 311.79, 219.78], "category_id": 1}, {"id": 10, "bbox": [705.42, 378.01, 132.56, 50.72], "category_id": 2}, {"id": 11, "bbox": [185.99, 181.23, 48.02, 44.63], "category_id": 3}, {"id": 12, "bbox": [83.87, 570.73, 201.54, 198.81], "category_id": 1}, {"id": 13, "bbox": [456.53, 461.86, 38.55, 40.58], "category_id": 3}, {"id": 14, "bbox": [1140.98, 894.65, 34.5, 40.57], "category_id": 3}, {"id": 15, "bbox": [305.03, 697.19, 229.95, 92.64], "category_id": 2}, {"id": 16, "bbox": [119.71, 279.96, 166.38, 51.39], "category_id": 2}, {"id": 17, "bbox": [73.04, 2.7, 241.46, 208.96], "category_id": 1}, {"id": 18, "bbox": [1030.06, 446.99, 34.5, 40.57], "category_id": 3}, {"id": 19, "bbox": [332.76, 29.08, 264.45, 154.85], "category_id": 1}, {"id": 20, "bbox": [926.58, 244.12, 313.15, 218.42], "category_id": 1}, {"id": 21, "bbox": [140.0, 357.72, 118.36, 44.63], "category_id": 2}, {"id": 22, "bbox": [202.9, 776.31, 45.32, 43.95], "category_id": 3}, {"id": 23, "bbox": [860.3, 10.82, 374.02, 217.07], "category_id": 1}, {"id": 24, "bbox": [707.45, 304.98, 131.89, 52.74], "category_id": 2}], "caption": "Scheme 1. Original synthetic route for 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 460, 672, 474], "ImageBB": [439, 479, 777, 713]}, "reactions": [{"reactants": [17, 19], "conditions": [7, 5], "products": [23]}, {"reactants": [23], "conditions": [16, 21], "products": [9]}, {"reactants": [9], "conditions": [24, 10], "products": [20]}, {"reactants": [6, 12], "conditions": [8, 15], "products": [2]}], "diagram_type": "multiple"}, {"id": 1278, "width": 1356, "height": 856, "file_name": "op100197g-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [112.6, 369.23, 48.84, 50.9], "category_id": 3}, {"id": 1, "bbox": [649.17, 465.61, 265.91, 104.52], "category_id": 2}, {"id": 2, "bbox": [977.49, 420.13, 378.51, 294.57], "category_id": 1}, {"id": 3, "bbox": [55.62, 316.97, 165.52, 50.9], "category_id": 2}, {"id": 4, "bbox": [468.37, 673.07, 210.66, 45.21], "category_id": 2}, {"id": 5, "bbox": [259.13, 735.74, 362.91, 48.87], "category_id": 2}, {"id": 6, "bbox": [643.74, 595.92, 301.19, 50.23], "category_id": 2}, {"id": 7, "bbox": [1107.05, 799.54, 50.87, 56.33], "category_id": 3}, {"id": 8, "bbox": [319.5, 22.4, 202.14, 95.7], "category_id": 2}, {"id": 9, "bbox": [360.2, 800.22, 50.87, 55.65], "category_id": 3}, {"id": 10, "bbox": [4.07, 6.11, 316.11, 289.81], "category_id": 1}, {"id": 11, "bbox": [257.77, 417.42, 316.1, 299.99], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 210, 486, 224], "ImageBB": [424, 228, 763, 442]}, "reactions": [{"reactants": [10], "conditions": [8], "products": [11]}, {"reactants": [11], "conditions": [1, 6], "products": [2]}], "diagram_type": "multiple"}, {"id": 838, "width": 2820, "height": 1636, "file_name": "jo202571h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [938.0, 69.0, 335.0, 75.0], "category_id": 2}, {"id": 1, "bbox": [758.0, 305.0, 24.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [2077.0, 301.0, 41.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [1786.0, 1578.0, 296.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [1548.0, 303.0, 48.0, 56.0], "category_id": 3}, {"id": 5, "bbox": [481.0, 1269.0, 195.0, 101.0], "category_id": 3}, {"id": 6, "bbox": [1935.0, 426.2, 330.3, 283.8], "category_id": 1}, {"id": 7, "bbox": [1554.6, 429.4, 335.4, 278.6], "category_id": 1}, {"id": 8, "bbox": [1690.0, 643.0, 74.0, 46.0], "category_id": 3}, {"id": 9, "bbox": [977.0, 171.0, 255.0, 55.0], "category_id": 2}, {"id": 10, "bbox": [1309.0, 990.0, 80.0, 48.0], "category_id": 3}, {"id": 11, "bbox": [1540.0, 710.0, 345.0, 345.0], "category_id": 1}, {"id": 12, "bbox": [1020.0, 1419.0, 101.0, 115.0], "category_id": 3}, {"id": 13, "bbox": [1892.0, 1450.0, 142.0, 92.0], "category_id": 3}, {"id": 14, "bbox": [4.0, 1077.0, 2721.0, 72.0], "category_id": 2}, {"id": 15, "bbox": [902.0, 643.0, 72.0, 55.0], "category_id": 3}, {"id": 16, "bbox": [630.0, 650.0, 70.0, 41.0], "category_id": 3}, {"id": 17, "bbox": [1314.0, 643.0, 77.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [1186.0, 715.0, 321.0, 349.0], "category_id": 1}, {"id": 19, "bbox": [700.0, 732.0, 130.0, 70.0], "category_id": 2}, {"id": 20, "bbox": [1682.0, 990.0, 75.0, 46.0], "category_id": 3}, {"id": 21, "bbox": [2061.0, 990.0, 62.0, 48.0], "category_id": 3}, {"id": 22, "bbox": [1928.0, 715.0, 340.0, 335.0], "category_id": 1}, {"id": 23, "bbox": [1983.0, 1196.6, 345.3, 316.4], "category_id": 1}, {"id": 24, "bbox": [1598.2, 1195.8, 307.8, 314.2], "category_id": 1}, {"id": 25, "bbox": [495.0, 430.9, 289.0, 279.1], "category_id": 1}, {"id": 26, "bbox": [1825.5, 7.0, 497.4, 280.6], "category_id": 1}, {"id": 27, "bbox": [1295.8, 4.0, 464.6, 289.1], "category_id": 1}, {"id": 28, "bbox": [468.0, 7.0, 423.5, 281.9], "category_id": 1}, {"id": 29, "bbox": [779.0, 432.0, 258.3, 277.0], "category_id": 1}, {"id": 30, "bbox": [1181.5, 430.0, 329.5, 280.0], "category_id": 1}, {"id": 31, "bbox": [2075.0, 643.0, 70.0, 60.0], "category_id": 3}, {"id": 32, "bbox": [839.0, 1587.0, 306.0, 49.0], "category_id": 2}, {"id": 33, "bbox": [1107.5, 1213.6, 303.3, 327.7], "category_id": 1}, {"id": 34, "bbox": [624.2, 1216.0, 342.8, 323.0], "category_id": 1}], "reactions": [{"reactants": [28], "conditions": [0, 9], "products": [27, 26]}], "corefs": [[28, 1], [27, 4], [26, 2], [25, 16], [29, 15], [30, 17], [7, 8], [6, 31], [18, 10], [11, 20], [22, 21]], "caption": "Figure 1. Mutual orientation of the neighboring aromatic rings in S-alkylated thiacalix[4]arenes and the assignment of the stereochemistry of S-alkyl groups. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 535, 784, 563], "ImageBB": [82, 116, 787, 525]}, "diagram_type": "single"}, {"id": 38, "width": 1352, "height": 1820, "file_name": "ja5080739-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.1, 319.71, 1347.62, 1469.75], "category_id": 4}, {"id": 1, "bbox": [577.8, 2.68, 380.09, 157.0], "category_id": 1}, {"id": 2, "bbox": [845.52, 16.77, 112.38, 60.71], "category_id": 1}, {"id": 3, "bbox": [608.33, 178.81, 321.38, 124.12], "category_id": 2}, {"id": 4, "bbox": [799.21, 138.58, 173.99, 40.7], "category_id": 2}, {"id": 5, "bbox": [284.25, 115.4, 297.9, 164.04], "category_id": 1}, {"id": 6, "bbox": [21.23, 82.53, 208.66, 114.72], "category_id": 1}, {"id": 7, "bbox": [1083.85, 222.43, 26.94, 33.82], "category_id": 3}, {"id": 8, "bbox": [624.63, 120.52, 46.72, 34.25], "category_id": 3}, {"id": 9, "bbox": [80.71, 220.71, 22.2, 35.54], "category_id": 3}, {"id": 10, "bbox": [1009.9, 82.53, 257.98, 114.72], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [1, 2, 3], "products": [10]}], "corefs": [[6, 9], [1, 8], [10, 7]], "caption": "Table 2. Scope of the Racemic Reactiona,b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 166, 325, 187], "ImageBB": [82, 193, 420, 648]}, "diagram_type": "single"}, {"id": 575, "width": 1172, "height": 940, "file_name": "acs.orglett.5b00663-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [799.91, 2.36, 102.0, 39.0], "category_id": 2}, {"id": 1, "bbox": [402.0, 64.0, 266.5, 44.2], "category_id": 2}, {"id": 2, "bbox": [181.0, 849.5, 285.0, 85.5], "category_id": 1}, {"id": 3, "bbox": [187.0, 730.0, 185.9, 98.5], "category_id": 1}, {"id": 4, "bbox": [584.0, 743.0, 120.0, 71.9], "category_id": 1}, {"id": 5, "bbox": [579.6, 880.4, 147.2, 38.2], "category_id": 1}, {"id": 6, "bbox": [190.0, 95.27, 33.0, 36.0], "category_id": 3}, {"id": 7, "bbox": [706.0, 771.0, 51.0, 68.0], "category_id": 3}, {"id": 8, "bbox": [578.0, 620.0, 111.0, 88.0], "category_id": 1}, {"id": 9, "bbox": [581.0, 523.0, 131.0, 58.0], "category_id": 1}, {"id": 10, "bbox": [570.0, 433.0, 162.0, 57.0], "category_id": 1}, {"id": 11, "bbox": [573.0, 331.0, 154.0, 57.0], "category_id": 1}, {"id": 12, "bbox": [571.0, 243.0, 161.0, 53.0], "category_id": 1}, {"id": 13, "bbox": [184.0, 617.0, 139.0, 88.0], "category_id": 1}, {"id": 14, "bbox": [183.0, 515.0, 206.0, 71.0], "category_id": 1}, {"id": 15, "bbox": [189.0, 416.0, 222.0, 77.0], "category_id": 1}, {"id": 16, "bbox": [192.0, 321.0, 222.0, 78.0], "category_id": 1}, {"id": 17, "bbox": [183.0, 219.0, 240.0, 80.0], "category_id": 1}, {"id": 18, "bbox": [468.0, 892.0, 49.0, 48.0], "category_id": 3}, {"id": 19, "bbox": [371.0, 790.0, 52.0, 54.0], "category_id": 3}, {"id": 20, "bbox": [320.0, 666.0, 52.0, 51.0], "category_id": 3}, {"id": 21, "bbox": [391.0, 554.0, 48.0, 58.0], "category_id": 3}, {"id": 22, "bbox": [414.0, 456.0, 42.0, 44.0], "category_id": 3}, {"id": 23, "bbox": [411.0, 358.0, 48.0, 44.0], "category_id": 3}, {"id": 24, "bbox": [416.0, 263.0, 46.0, 45.0], "category_id": 3}, {"id": 25, "bbox": [721.0, 876.0, 57.0, 47.0], "category_id": 3}, {"id": 26, "bbox": [689.0, 663.0, 43.0, 50.0], "category_id": 3}, {"id": 27, "bbox": [713.0, 538.0, 53.0, 57.0], "category_id": 3}, {"id": 28, "bbox": [724.0, 442.0, 53.0, 64.0], "category_id": 3}, {"id": 29, "bbox": [730.0, 348.0, 44.0, 53.0], "category_id": 3}, {"id": 30, "bbox": [727.0, 250.0, 43.0, 46.0], "category_id": 3}, {"id": 31, "bbox": [10.0, 154.0, 1154.0, 786.0], "category_id": 4}, {"id": 32, "bbox": [321.0, 0.0, 426.0, 52.0], "category_id": 2}, {"id": 33, "bbox": [990.0, 84.0, 33.0, 39.0], "category_id": 3}, {"id": 34, "bbox": [132.0, 13.0, 155.0, 58.0], "category_id": 1}, {"id": 35, "bbox": [965.24, 24.56, 85.95, 42.29], "category_id": 2}], "reactions": [{"reactants": [34], "conditions": [32, 1, 0], "products": [35]}], "corefs": [[34, 6], [35, 33], [17, 24], [12, 30], [16, 23], [11, 29], [15, 22], [10, 28], [14, 21], [9, 27], [13, 20], [8, 26], [3, 19], [4, 7], [2, 18], [5, 25]], "caption": "Table 4. Substrate Scope for the Debenzylation Reactiona", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 403, 109], "ImageBB": [104, 116, 397, 351]}, "diagram_type": "single"}, {"id": 823, "width": 1912, "height": 2060, "file_name": "jo400755q-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [104.0, 1435.0, 254.0, 58.0], "category_id": 3}, {"id": 1, "bbox": [1409.0, 915.0, 274.0, 71.0], "category_id": 3}, {"id": 2, "bbox": [943.0, 913.0, 253.0, 67.0], "category_id": 3}, {"id": 3, "bbox": [531.0, 915.0, 248.0, 61.0], "category_id": 3}, {"id": 4, "bbox": [112.0, 911.0, 242.0, 60.0], "category_id": 3}, {"id": 5, "bbox": [276.0, 10.0, 340.0, 310.0], "category_id": 1}, {"id": 6, "bbox": [924.0, 6.0, 336.0, 302.0], "category_id": 1}, {"id": 7, "bbox": [1081.0, 300.0, 73.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [299.0, 292.0, 183.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [596.0, 43.0, 295.0, 84.0], "category_id": 2}, {"id": 10, "bbox": [1308.0, 77.0, 319.0, 52.0], "category_id": 2}, {"id": 11, "bbox": [1565.0, 1433.0, 77.0, 52.0], "category_id": 3}, {"id": 12, "bbox": [559.0, 1433.0, 265.0, 65.0], "category_id": 3}, {"id": 13, "bbox": [600.0, 144.0, 313.0, 98.0], "category_id": 2}, {"id": 14, "bbox": [112.2, 1505.0, 312.0, 440.8], "category_id": 1}, {"id": 15, "bbox": [1262.3, 1585.5, 478.2, 321.7], "category_id": 1}, {"id": 16, "bbox": [1207.22, 1433.1, 289.95, 60.75], "category_id": 2}, {"id": 17, "bbox": [863.0, 995.0, 408.7, 419.0], "category_id": 1}, {"id": 18, "bbox": [675.4, 1512.5, 341.4, 440.0], "category_id": 1}, {"id": 19, "bbox": [464.2, 977.3, 403.0, 442.7], "category_id": 1}, {"id": 20, "bbox": [1323.0, 1004.0, 411.1, 407.2], "category_id": 1}, {"id": 21, "bbox": [672.0, 1947.0, 254.4, 69.0], "category_id": 3}, {"id": 22, "bbox": [443.5, 447.6, 391.5, 421.4], "category_id": 1}, {"id": 23, "bbox": [110.1, 423.8, 306.2, 364.2], "category_id": 1}, {"id": 24, "bbox": [17.8, 995.8, 400.5, 410.0], "category_id": 1}, {"id": 25, "bbox": [1269.0, 449.0, 476.7, 454.5], "category_id": 1}, {"id": 26, "bbox": [887.0, 447.0, 373.0, 418.0], "category_id": 1}, {"id": 27, "bbox": [1258.0, 1947.0, 250.0, 72.5], "category_id": 3}, {"id": 28, "bbox": [1118.48, 1419.48, 54.2, 69.5], "category_id": 3}, {"id": 29, "bbox": [117.0, 1953.24, 248.0, 58.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [9, 13], "products": [6]}], "corefs": [[5, 8], [6, 7], [23, 4], [22, 3], [26, 2], [25, 1], [24, 0], [19, 12], [17, 28], [20, 11], [14, 29], [18, 21], [15, 27]], "caption": "Table 3. Ortho-Chlorination of N-Aryl Ring of N,1-Diaryl-1H-tetrazol-5-aminea", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 530, 111], "ImageBB": [195, 116, 673, 631]}, "diagram_type": "single"}, {"id": 1233, "width": 1340, "height": 1052, "file_name": "op0155211-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [923.72, 732.2, 357.29, 230.62], "category_id": 1}, {"id": 1, "bbox": [346.56, 450.25, 87.15, 58.96], "category_id": 2}, {"id": 2, "bbox": [1181.13, 144.05, 85.13, 55.62], "category_id": 2}, {"id": 3, "bbox": [967.29, 322.28, 180.99, 149.92], "category_id": 1}, {"id": 4, "bbox": [451.0, 733.67, 142.5, 151.53], "category_id": 1}, {"id": 5, "bbox": [1262.91, 817.42, 77.09, 58.96], "category_id": 2}, {"id": 6, "bbox": [968.02, 492.53, 181.85, 47.99], "category_id": 2}, {"id": 7, "bbox": [91.17, 377.22, 258.07, 161.47], "category_id": 1}, {"id": 8, "bbox": [1053.1, 994.98, 65.02, 54.27], "category_id": 3}, {"id": 9, "bbox": [701.84, 416.75, 89.83, 44.22], "category_id": 2}, {"id": 10, "bbox": [450.22, 895.4, 164.18, 50.52], "category_id": 2}, {"id": 11, "bbox": [700.5, 489.11, 95.86, 49.58], "category_id": 2}, {"id": 12, "bbox": [700.5, 788.61, 91.17, 43.55], "category_id": 2}, {"id": 13, "bbox": [700.5, 116.58, 89.15, 49.58], "category_id": 2}, {"id": 14, "bbox": [0.0, 720.27, 286.23, 231.16], "category_id": 1}, {"id": 15, "bbox": [700.5, 182.24, 98.54, 44.9], "category_id": 2}, {"id": 16, "bbox": [698.49, 862.31, 100.55, 48.24], "category_id": 2}, {"id": 17, "bbox": [242.66, 557.45, 59.66, 50.93], "category_id": 3}, {"id": 18, "bbox": [1054.44, 558.12, 59.66, 50.26], "category_id": 3}, {"id": 19, "bbox": [162.22, 994.98, 61.67, 54.27], "category_id": 3}, {"id": 20, "bbox": [904.95, 85.76, 251.38, 151.43], "category_id": 1}, {"id": 21, "bbox": [1054.44, 237.19, 58.99, 52.93], "category_id": 3}, {"id": 22, "bbox": [10.06, 96.48, 175.62, 142.72], "category_id": 1}, {"id": 23, "bbox": [373.38, 87.77, 136.07, 151.43], "category_id": 1}, {"id": 24, "bbox": [500.07, 999.0, 58.32, 50.25], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 553, 501, 567], "ImageBB": [441, 571, 776, 834]}, "reactions": [{"reactants": [22, 23], "conditions": [13, 15], "products": [20, 2]}, {"reactants": [7, 1], "conditions": [9, 11], "products": [3, 6]}, {"reactants": [14, 4], "conditions": [12, 16], "products": [0, 5]}], "diagram_type": "multiple"}, {"id": 80, "width": 1348, "height": 1980, "file_name": "ja075824w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [819.65, 328.36, 153.56, 38.23], "category_id": 2}, {"id": 1, "bbox": [564.09, 148.83, 316.56, 40.54], "category_id": 2}, {"id": 2, "bbox": [192.34, 367.65, 593.82, 171.09], "category_id": 2}, {"id": 3, "bbox": [196.07, 283.1, 193.47, 39.3], "category_id": 2}, {"id": 4, "bbox": [528.03, 5.84, 389.92, 92.77], "category_id": 2}, {"id": 5, "bbox": [175.9, 105.6, 96.6, 37.6], "category_id": 2}, {"id": 6, "bbox": [1035.34, 328.78, 185.62, 36.97], "category_id": 2}, {"id": 7, "bbox": [332.07, 106.85, 144.4, 36.14], "category_id": 2}, {"id": 8, "bbox": [37.92, 604.8, 1276.8, 1341.6], "category_id": 4}, {"id": 9, "bbox": [318.72, 168.0, 184.8, 45.6], "category_id": 2}], "reactions": [{"reactants": [5, 7], "conditions": [4, 1, 3, 2], "products": [0, 6]}], "corefs": [], "caption": "Table 2. DMAP-Catalyzed Esterification of Alcohols and Carboxylic Acids under Base- and Solvent-Free Conditions ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 735, 88], "ImageBB": [439, 88, 776, 583]}, "diagram_type": "multiple"}, {"id": 658, "width": 1344, "height": 632, "file_name": "ol402981z-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [866.85, 300.0, 113.0, 60.8], "category_id": 2}, {"id": 1, "bbox": [1017.0, 230.0, 308.0, 248.6], "category_id": 1}, {"id": 2, "bbox": [490.8, 212.7, 336.0, 267.4], "category_id": 1}, {"id": 3, "bbox": [26.3, 291.9, 263.0, 157.7], "category_id": 1}, {"id": 4, "bbox": [845.86, 169.15, 105.0, 86.0], "category_id": 2}, {"id": 5, "bbox": [874.28, 387.0, 96.1, 50.0], "category_id": 2}, {"id": 6, "bbox": [247.0, 521.0, 596.0, 105.0], "category_id": 2}, {"id": 7, "bbox": [300.0, 288.0, 133.0, 69.0], "category_id": 2}, {"id": 8, "bbox": [315.0, 396.0, 101.0, 87.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [7, 8], "products": [2]}, {"reactants": [2], "conditions": [0, 5], "products": [1]}], "corefs": [], "caption": "Figure 1. Concept behind enantioselective halonium ion-initiated Wagner Meerwein transposition of allylic alcohols. Hal = F, Cl, Br, or I. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 568, 405, 612], "ImageBB": [71, 400, 407, 558]}, "diagram_type": "single"}, {"id": 921, "width": 1356, "height": 396, "file_name": "acs.joc.5b02237-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1315.3, 133.73, 36.63, 48.2], "category_id": 3}, {"id": 1, "bbox": [671.56, 8.82, 285.58, 286.47], "category_id": 1}, {"id": 2, "bbox": [974.1, 47.52, 324.92, 97.07], "category_id": 2}, {"id": 3, "bbox": [455.84, 93.68, 213.0, 58.38], "category_id": 2}, {"id": 4, "bbox": [166.19, 4.07, 287.62, 263.39], "category_id": 1}, {"id": 5, "bbox": [68.51, 95.72, 67.84, 42.08], "category_id": 2}, {"id": 6, "bbox": [789.59, 306.15, 57.66, 46.84], "category_id": 3}, {"id": 7, "bbox": [287.62, 306.15, 50.87, 43.45], "category_id": 3}, {"id": 8, "bbox": [4.07, 133.73, 34.6, 46.16], "category_id": 3}], "caption": "Scheme 7. Proposed Mechanism of the Photorearrangement", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 563, 784, 578], "ImageBB": [448, 584, 787, 683]}, "reactions": [{"reactants": [8], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [2], "products": [0]}], "diagram_type": "single"}, {"id": 1283, "width": 2808, "height": 652, "file_name": "op2000089-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1098.48, 56.1, 60.4, 57.5], "category_id": 2}, {"id": 1, "bbox": [1331.66, 274.89, 106.76, 99.58], "category_id": 1}, {"id": 2, "bbox": [434.05, 552.59, 623.69, 54.69], "category_id": 2}, {"id": 3, "bbox": [1702.5, 0.0, 247.23, 124.82], "category_id": 2}, {"id": 4, "bbox": [974.86, 148.67, 318.87, 58.9], "category_id": 2}, {"id": 5, "bbox": [1772.73, 329.59, 105.36, 65.92], "category_id": 2}, {"id": 6, "bbox": [656.0, 284.71, 276.72, 232.81], "category_id": 1}, {"id": 7, "bbox": [2129.53, 287.51, 243.01, 230.01], "category_id": 1}, {"id": 8, "bbox": [1097.07, 335.2, 68.83, 60.31], "category_id": 2}, {"id": 9, "bbox": [686.9, 64.52, 248.63, 131.83], "category_id": 1}, {"id": 10, "bbox": [2005.91, 14.03, 370.85, 234.21], "category_id": 1}, {"id": 11, "bbox": [1009.98, 424.96, 243.01, 96.77], "category_id": 2}, {"id": 12, "bbox": [434.05, 199.16, 181.21, 123.42], "category_id": 1}, {"id": 13, "bbox": [1349.3, 67.32, 298.42, 129.68], "category_id": 1}, {"id": 14, "bbox": [1372.39, 298.73, 279.54, 234.22], "category_id": 1}], "caption": "Scheme 2. Competitive reactions for the in situ borylation with 1 through a magnesium-halide exchange", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 257, 655, 272], "ImageBB": [71, 282, 773, 445]}, "reactions": [{"reactants": [12, 9], "conditions": [0, 4], "products": [13]}, {"reactants": [13], "conditions": [3], "products": [10]}, {"reactants": [12, 6], "conditions": [8, 11], "products": [1, 14]}, {"reactants": [14], "conditions": [5], "products": [7]}], "diagram_type": "multiple"}, {"id": 609, "width": 2820, "height": 920, "file_name": "acs.oprd.5b00339-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2011.0, 424.0, 235.0, 68.0], "category_id": 2}, {"id": 1, "bbox": [1225.9, 426.7, 352.3, 137.4], "category_id": 1}, {"id": 2, "bbox": [367.8, 0.0, 929.3, 238.0], "category_id": 1}, {"id": 3, "bbox": [798.62, 271.62, 68.0, 81.0], "category_id": 3}, {"id": 4, "bbox": [797.75, 826.87, 51.4, 48.5], "category_id": 3}, {"id": 5, "bbox": [1977.0, 826.0, 58.6, 58.3], "category_id": 3}, {"id": 6, "bbox": [1967.24, 272.49, 65.0, 81.0], "category_id": 3}, {"id": 7, "bbox": [370.3, 390.9, 857.7, 416.1], "category_id": 1}, {"id": 8, "bbox": [1560.0, 517.4, 902.9, 290.3], "category_id": 1}, {"id": 9, "bbox": [1518.0, 0.0, 961.0, 247.0], "category_id": 1}, {"id": 10, "bbox": [1384.43, 563.1, 48.92, 51.05], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [1], "products": [7]}], "corefs": [[2, 3], [9, 6], [8, 5], [1, 10], [7, 4]], "caption": "Table 1. Asymmetric Hydrogenation of Ketone 4 with Optimizing Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 346, 581, 367], "ImageBB": [82, 116, 787, 346]}, "diagram_type": "tree"}, {"id": 321, "width": 1344, "height": 1704, "file_name": "ol301863j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [957.8, 32.6, 341.7, 188.6], "category_id": 1}, {"id": 1, "bbox": [726.0, 238.0, 204.6, 92.0], "category_id": 2}, {"id": 2, "bbox": [42.0, 464.6, 1293.0, 1236.4], "category_id": 4}, {"id": 3, "bbox": [26.2, 2.0, 365.6, 249.6], "category_id": 1}, {"id": 4, "bbox": [1008.3, 291.87, 252.3, 51.93], "category_id": 3}, {"id": 5, "bbox": [1004.0, 227.0, 318.6, 55.8], "category_id": 3}, {"id": 6, "bbox": [580.0, 47.0, 140.0, 66.0], "category_id": 2}, {"id": 7, "bbox": [463.0, 124.0, 437.0, 109.0], "category_id": 2}, {"id": 8, "bbox": [159.0, 219.0, 76.0, 77.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [6, 7], "products": [0]}, {"reactants": [5], "conditions": [1], "products": [4]}], "corefs": [[3, 8], [0, 5], [0, 4]], "caption": "Table 2. Efficient Preparation of Glycosyloxyamines", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 351, 100], "ImageBB": [71, 112, 407, 538]}, "diagram_type": "tree"}, {"id": 106, "width": 1340, "height": 816, "file_name": "ja001164i-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [648.68, 384.33, 92.15, 37.12], "category_id": 2}, {"id": 1, "bbox": [498.83, 483.84, 360.24, 253.71], "category_id": 1}, {"id": 2, "bbox": [963.61, 97.5, 330.97, 253.71], "category_id": 1}, {"id": 3, "bbox": [489.46, 97.5, 359.08, 253.71], "category_id": 1}, {"id": 4, "bbox": [599.51, 769.5, 34.78, 28.93], "category_id": 3}, {"id": 5, "bbox": [236.58, 627.84, 203.37, 69.91], "category_id": 2}, {"id": 6, "bbox": [240.1, 241.5, 202.19, 69.9], "category_id": 2}, {"id": 7, "bbox": [600.68, 384.33, 40.64, 30.1], "category_id": 3}, {"id": 8, "bbox": [11.8, 596.23, 179.96, 35.96], "category_id": 2}, {"id": 9, "bbox": [248.29, 167.75, 42.01, 37.12], "category_id": 3}, {"id": 10, "bbox": [14.15, 209.89, 181.12, 38.3], "category_id": 2}, {"id": 11, "bbox": [294.11, 555.04, 139.46, 40.42], "category_id": 2}, {"id": 12, "bbox": [297.14, 167.99, 139.46, 38.4], "category_id": 2}, {"id": 13, "bbox": [245.95, 555.26, 42.85, 39.46], "category_id": 3}, {"id": 14, "bbox": [648.68, 769.5, 109.71, 35.95], "category_id": 2}, {"id": 15, "bbox": [1086.54, 383.16, 90.97, 37.12], "category_id": 2}], "reactions": [{"reactants": [10], "conditions": [9, 12, 6], "products": [3, 2]}, {"reactants": [8], "conditions": [13, 11, 5], "products": [1]}], "corefs": [[3, 7], [1, 4]], "caption": "Table 8. Comparison of the Reactivities of LBAs in the Protonation of 3a to 4aa ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 298, 721, 323], "ImageBB": [439, 82, 775, 286]}, "diagram_type": "multiple"}, {"id": 391, "width": 1352, "height": 868, "file_name": "op500224x-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [885.0, 153.0, 84.0, 50.0], "category_id": 2}, {"id": 1, "bbox": [547.0, 514.0, 276.0, 282.0], "category_id": 1}, {"id": 2, "bbox": [104.0, 595.0, 37.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [637.0, 814.0, 56.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [1163.0, 815.0, 47.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [1169.0, 344.0, 46.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [653.0, 347.0, 38.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [207.0, 690.0, 313.0, 54.0], "category_id": 2}, {"id": 8, "bbox": [312.0, 233.0, 154.0, 52.0], "category_id": 2}, {"id": 9, "bbox": [361.0, 153.0, 59.0, 59.0], "category_id": 2}, {"id": 10, "bbox": [1053.0, 514.9, 293.3, 287.1], "category_id": 1}, {"id": 11, "bbox": [555.29, 44.98, 272.71, 281.12], "category_id": 1}, {"id": 12, "bbox": [1061.8, 47.6, 290.2, 280.4], "category_id": 1}, {"id": 13, "bbox": [0.0, 301.0, 267.3, 281.5], "category_id": 1}, {"id": 14, "bbox": [880.0, 622.0, 80.7, 51.9], "category_id": 2}, {"id": 15, "bbox": [360.0, 625.0, 57.8, 46.2], "category_id": 2}], "reactions": [{"reactants": [13], "conditions": [9, 8], "products": [11]}, {"reactants": [11], "conditions": [0], "products": [12]}, {"reactants": [13], "conditions": [15, 7], "products": [1]}, {"reactants": [1], "conditions": [14], "products": [10]}], "corefs": [[13, 2], [11, 6], [12, 5], [1, 3], [10, 4]], "caption": "Figure 3. Piperidines generated via kinetic and thermodynamic iminiums. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 984, 417, 1012], "ImageBB": [82, 758, 420, 975]}, "diagram_type": "tree"}, {"id": 50, "width": 1348, "height": 372, "file_name": "ja408031s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.13, 297.36, 1333.76, 72.18], "category_id": 4}, {"id": 1, "bbox": [188.28, 218.4, 72.58, 42.46], "category_id": 3}, {"id": 2, "bbox": [46.25, 131.46, 358.36, 63.98], "category_id": 1}, {"id": 3, "bbox": [1004.31, 227.87, 28.68, 40.74], "category_id": 3}, {"id": 4, "bbox": [453.4, 3.21, 231.83, 134.56], "category_id": 2}, {"id": 5, "bbox": [770.17, 80.68, 531.39, 112.18], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [4], "products": [5]}], "corefs": [[2, 1], [5, 3]], "caption": "Table 1. Optimization of Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 343, 110], "ImageBB": [82, 116, 419, 209]}, "diagram_type": "single"}, {"id": 1014, "width": 1032, "height": 2176, "file_name": "ja983111v-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [409.42, 1609.96, 25.04, 33.74], "category_id": 2}, {"id": 1, "bbox": [754.59, 124.09, 277.41, 342.9], "category_id": 1}, {"id": 2, "bbox": [323.4, 2136.81, 35.93, 39.19], "category_id": 3}, {"id": 3, "bbox": [52.27, 4.35, 614.12, 446.31], "category_id": 1}, {"id": 4, "bbox": [82.75, 587.81, 700.15, 396.23], "category_id": 1}, {"id": 5, "bbox": [827.55, 485.49, 54.44, 42.45], "category_id": 3}, {"id": 6, "bbox": [0.0, 1702.48, 844.97, 473.52], "category_id": 1}, {"id": 7, "bbox": [319.04, 402.76, 33.76, 38.1], "category_id": 3}, {"id": 8, "bbox": [359.33, 1510.9, 29.4, 40.28], "category_id": 3}, {"id": 9, "bbox": [359.33, 490.93, 32.67, 33.75], "category_id": 2}, {"id": 10, "bbox": [388.73, 1028.67, 30.49, 41.37], "category_id": 2}, {"id": 11, "bbox": [245.0, 1137.53, 547.7, 385.34], "category_id": 1}, {"id": 12, "bbox": [803.59, 719.53, 196.0, 183.96], "category_id": 1}], "caption": "Scheme 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 63, 133, 78], "ImageBB": [113, 84, 371, 628]}, "reactions": [{"reactants": [3, 1], "conditions": [9], "products": [4]}, {"reactants": [4, 12], "conditions": [10], "products": [11]}, {"reactants": [11], "conditions": [0], "products": [6]}], "diagram_type": "tree"}, {"id": 943, "width": 1356, "height": 652, "file_name": "acs.orglett.5b01872-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [65.8, 0.0, 291.01, 152.61], "category_id": 2}, {"id": 1, "bbox": [274.73, 77.7, 414.77, 213.28], "category_id": 1}, {"id": 2, "bbox": [917.79, 38.66, 419.89, 249.61], "category_id": 1}, {"id": 3, "bbox": [525.71, 220.44, 51.56, 46.8], "category_id": 3}, {"id": 4, "bbox": [381.9, 352.7, 254.38, 141.09], "category_id": 1}, {"id": 5, "bbox": [1170.14, 221.12, 48.84, 46.12], "category_id": 3}, {"id": 6, "bbox": [507.4, 478.19, 40.7, 40.69], "category_id": 3}, {"id": 7, "bbox": [733.28, 181.1, 182.48, 151.26], "category_id": 2}, {"id": 8, "bbox": [960.53, 322.86, 220.46, 90.21], "category_id": 2}, {"id": 9, "bbox": [246.92, 475.47, 59.01, 48.16], "category_id": 3}, {"id": 10, "bbox": [1170.14, 493.79, 44.77, 45.44], "category_id": 3}, {"id": 11, "bbox": [0.0, 545.33, 870.99, 61.05], "category_id": 2}, {"id": 12, "bbox": [79.37, 341.17, 272.01, 169.57], "category_id": 1}, {"id": 13, "bbox": [150.59, 178.39, 116.68, 122.09], "category_id": 2}, {"id": 14, "bbox": [1203.37, 290.98, 144.49, 156.68], "category_id": 2}, {"id": 15, "bbox": [10.85, 140.4, 52.24, 47.48], "category_id": 3}, {"id": 16, "bbox": [733.28, 6.1, 189.94, 56.3], "category_id": 1}, {"id": 17, "bbox": [695.35, 74.92, 266.9, 70.56], "category_id": 2}], "caption": "Scheme 3. Synthesis of the Divinyl Intermediate", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 722, 110], "ImageBB": [448, 116, 787, 279]}, "reactions": [{"reactants": [15], "conditions": [0, 13], "products": [1]}, {"reactants": [1], "conditions": [16, 17, 7], "products": [2]}, {"reactants": [2], "conditions": [8, 14], "products": [10]}], "diagram_type": "tree"}, {"id": 1128, "width": 1696, "height": 800, "file_name": "jo991524o-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1426.2, 68.7, 269.8, 240.02], "category_id": 1}, {"id": 1, "bbox": [1153.01, 232.38, 273.19, 55.98], "category_id": 2}, {"id": 2, "bbox": [207.86, 598.77, 126.42, 59.37], "category_id": 2}, {"id": 3, "bbox": [869.63, 78.88, 267.26, 232.38], "category_id": 1}, {"id": 4, "bbox": [987.57, 323.98, 58.54, 49.19], "category_id": 3}, {"id": 5, "bbox": [48.36, 340.1, 60.24, 46.64], "category_id": 3}, {"id": 6, "bbox": [207.86, 686.98, 132.36, 50.88], "category_id": 2}, {"id": 7, "bbox": [156.11, 251.04, 204.47, 50.04], "category_id": 2}, {"id": 8, "bbox": [0.0, 102.62, 137.44, 232.39], "category_id": 1}, {"id": 9, "bbox": [242.65, 186.59, 62.78, 43.25], "category_id": 3}, {"id": 10, "bbox": [1034.23, 739.56, 63.63, 50.89], "category_id": 3}, {"id": 11, "bbox": [377.55, 426.6, 111.14, 55.98], "category_id": 2}, {"id": 12, "bbox": [15.27, 540.25, 183.26, 195.92], "category_id": 1}, {"id": 13, "bbox": [48.36, 753.13, 77.21, 45.8], "category_id": 3}, {"id": 14, "bbox": [474.27, 334.16, 61.09, 44.1], "category_id": 3}, {"id": 15, "bbox": [544.69, 424.06, 195.14, 61.06], "category_id": 2}, {"id": 16, "bbox": [188.35, 0.0, 156.96, 175.56], "category_id": 1}, {"id": 17, "bbox": [644.8, 238.32, 182.41, 56.83], "category_id": 2}, {"id": 18, "bbox": [649.04, 589.44, 219.75, 65.31], "category_id": 2}, {"id": 19, "bbox": [647.35, 142.48, 219.74, 59.37], "category_id": 2}, {"id": 20, "bbox": [1153.01, 137.4, 223.13, 64.45], "category_id": 2}, {"id": 21, "bbox": [1543.28, 317.2, 65.33, 48.34], "category_id": 3}, {"id": 22, "bbox": [853.51, 537.71, 429.31, 223.9], "category_id": 1}, {"id": 23, "bbox": [367.37, 90.75, 267.25, 224.75], "category_id": 1}, {"id": 24, "bbox": [414.88, 550.43, 202.77, 185.74], "category_id": 1}, {"id": 25, "bbox": [491.24, 744.65, 63.63, 47.49], "category_id": 3}], "caption": "Scheme 6", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 64, 453, 78], "ImageBB": [213, 85, 637, 285]}, "reactions": [{"reactants": [8, 16], "conditions": [7], "products": [23]}, {"reactants": [23], "conditions": [19, 17], "products": [3]}, {"reactants": [3], "conditions": [20, 1], "products": [0]}, {"reactants": [23], "conditions": [15], "products": [24]}, {"reactants": [24], "conditions": [11], "products": [23]}, {"reactants": [12], "conditions": [2, 6], "products": [24]}, {"reactants": [24], "conditions": [18], "products": [22]}], "diagram_type": "tree"}, {"id": 817, "width": 1348, "height": 404, "file_name": "jo4014707-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [637.0, 4.0, 262.0, 108.0], "category_id": 2}, {"id": 1, "bbox": [1034.0, 13.0, 186.0, 202.0], "category_id": 1}, {"id": 2, "bbox": [134.3, 13.0, 110.3, 187.0], "category_id": 1}, {"id": 3, "bbox": [179.0, 213.0, 29.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [1060.0, 217.0, 102.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [370.0, 211.0, 52.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [25.0, 289.0, 1311.0, 111.0], "category_id": 4}, {"id": 7, "bbox": [316.0, 92.0, 182.0, 60.0], "category_id": 2}, {"id": 8, "bbox": [644.0, 134.0, 251.0, 96.0], "category_id": 2}], "reactions": [{"reactants": [2, 7], "conditions": [0, 8], "products": [1]}], "corefs": [[2, 3], [7, 5], [1, 4]], "caption": "Table 2. Asymmetric 1,4-Addition at Low Temperaturea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 640, 400, 661], "ImageBB": [82, 667, 419, 768]}, "diagram_type": "single"}, {"id": 516, "width": 1348, "height": 572, "file_name": "jo025690z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [985.5, 5.0, 225.5, 199.6], "category_id": 1}, {"id": 1, "bbox": [1070.56, 217.0, 35.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [413.0, 282.0, 677.0, 290.0], "category_id": 4}, {"id": 3, "bbox": [526.0, 32.0, 375.0, 49.0], "category_id": 2}, {"id": 4, "bbox": [71.0, 220.0, 23.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [338.0, 221.0, 43.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [274.0, 75.0, 140.0, 56.0], "category_id": 1}, {"id": 7, "bbox": [0.0, 32.0, 234.0, 141.0], "category_id": 1}, {"id": 8, "bbox": [586.0, 121.0, 251.0, 45.0], "category_id": 2}], "reactions": [{"reactants": [7, 6], "conditions": [3, 8], "products": [0]}], "corefs": [[7, 4], [6, 5], [0, 1]], "caption": "Table 3.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 620, 124, 634], "ImageBB": [75, 648, 412, 791]}, "diagram_type": "single"}, {"id": 605, "width": 1348, "height": 788, "file_name": "acs.oprd.5b00379-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [526.71, 647.43, 30.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [67.6, 0.0, 923.4, 621.0], "category_id": 1}, {"id": 2, "bbox": [1249.57, 286.0, 37.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [5.0, 717.0, 1336.0, 71.0], "category_id": 4}, {"id": 4, "bbox": [747.0, 310.0, 281.0, 51.0], "category_id": 2}, {"id": 5, "bbox": [747.0, 231.0, 406.0, 60.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [5, 4], "products": [2]}], "corefs": [[1, 0]], "caption": "Table 3. Optimization of the C18 Puri\ufb01cation Procedure", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 579, 403, 594], "ImageBB": [82, 601, 419, 798]}, "diagram_type": "single"}, {"id": 733, "width": 1344, "height": 884, "file_name": "ol016212y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [108.0, 273.0, 334.0, 67.0], "category_id": 2}, {"id": 1, "bbox": [3.0, 365.0, 1341.0, 519.0], "category_id": 4}, {"id": 2, "bbox": [919.0, 275.0, 330.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [437.38, 164.71, 382.75, 98.36], "category_id": 2}, {"id": 4, "bbox": [911.9, 3.6, 317.8, 237.0], "category_id": 1}, {"id": 5, "bbox": [398.48, 95.56, 470.1, 55.7], "category_id": 2}, {"id": 6, "bbox": [100.0, 0.0, 266.0, 233.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 3], "products": [4]}], "corefs": [], "caption": "Table 1. Comparison of the Fiber-Supported Titanium TADDOLate Derived from P1 with P1B and 4 in the Addition of Et2Zn to PhCHO ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 180, 399, 224], "ImageBB": [74, 226, 410, 447]}, "diagram_type": "single"}, {"id": 709, "width": 1348, "height": 1100, "file_name": "ol0349920-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [620.94, 356.85, 191.69, 87.0], "category_id": 1}, {"id": 1, "bbox": [113.0, 159.0, 316.0, 244.0], "category_id": 1}, {"id": 2, "bbox": [440.99, 22.38, 114.95, 44.7], "category_id": 2}, {"id": 3, "bbox": [600.64, 440.67, 122.93, 49.49], "category_id": 2}, {"id": 4, "bbox": [520.81, 373.61, 100.58, 57.48], "category_id": 2}, {"id": 5, "bbox": [527.0, 313.0, 265.8, 47.5], "category_id": 2}, {"id": 6, "bbox": [442.0, 7.0, 439.0, 298.0], "category_id": 1}, {"id": 7, "bbox": [896.0, 200.0, 339.0, 206.0], "category_id": 1}, {"id": 8, "bbox": [837.0, 249.0, 36.0, 51.0], "category_id": 3}, {"id": 9, "bbox": [5.0, 516.0, 1343.0, 583.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [6, 5, 4, 0, 3], "products": [7]}], "corefs": [[6, 8]], "caption": "Table 1. Enantioselective Deuteride Reduction of Various Aldimines or Their Equivalents Derived from p-Phenylbenzaldehydea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 747, 120], "ImageBB": [439, 125, 776, 400]}, "diagram_type": "single"}, {"id": 846, "width": 1196, "height": 900, "file_name": "jo201478d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.2, 313.2, 1195.8, 586.8], "category_id": 4}, {"id": 1, "bbox": [584.0, 14.0, 176.0, 100.0], "category_id": 2}, {"id": 2, "bbox": [23.0, 700.0, 143.0, 134.0], "category_id": 1}, {"id": 3, "bbox": [438.0, 834.0, 55.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [1003.0, 171.0, 33.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [0.0, 436.0, 172.0, 127.0], "category_id": 1}, {"id": 6, "bbox": [831.0, 1.0, 365.0, 218.0], "category_id": 1}, {"id": 7, "bbox": [440.0, 567.0, 52.0, 39.0], "category_id": 3}, {"id": 8, "bbox": [87.0, 835.0, 53.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [373.0, 52.0, 197.0, 130.0], "category_id": 1}, {"id": 10, "bbox": [445.0, 171.0, 31.0, 39.0], "category_id": 3}, {"id": 11, "bbox": [2.0, 24.0, 357.0, 183.0], "category_id": 1}, {"id": 12, "bbox": [87.0, 567.0, 55.0, 39.0], "category_id": 3}, {"id": 13, "bbox": [309.0, 408.0, 351.0, 152.0], "category_id": 1}, {"id": 14, "bbox": [622.0, 126.0, 152.0, 98.0], "category_id": 2}, {"id": 15, "bbox": [152.0, 173.0, 54.0, 39.0], "category_id": 3}, {"id": 16, "bbox": [309.0, 686.0, 314.0, 197.0], "category_id": 1}], "reactions": [{"reactants": [11, 9], "conditions": [1, 14], "products": [6]}], "corefs": [[11, 15], [9, 10], [6, 4], [5, 12], [13, 7], [2, 8], [16, 3]], "caption": "Table 2. Epoxide Rearrangement Followed by Addition and ISMS Using the Unprotected \u03b4-Hydroxyalkenylsilanes ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 770, 123], "ImageBB": [455, 133, 754, 358]}, "diagram_type": "single"}, {"id": 1018, "width": 1356, "height": 552, "file_name": "jacs.5b05596-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [47.48, 21.01, 355.45, 135.58], "category_id": 1}, {"id": 1, "bbox": [41.38, 246.75, 368.34, 199.98], "category_id": 1}, {"id": 2, "bbox": [206.22, 455.54, 40.7, 48.81], "category_id": 3}, {"id": 3, "bbox": [915.76, 205.4, 54.94, 35.25], "category_id": 2}, {"id": 4, "bbox": [1225.76, 427.75, 70.55, 49.48], "category_id": 3}, {"id": 5, "bbox": [777.38, 429.78, 52.91, 50.84], "category_id": 3}, {"id": 6, "bbox": [528.43, 4.07, 321.53, 499.6], "category_id": 1}, {"id": 7, "bbox": [206.22, 170.15, 40.7, 44.74], "category_id": 3}, {"id": 8, "bbox": [993.09, 2.03, 324.24, 496.89], "category_id": 1}], "caption": "Scheme 7. Catenation of Two Cyclopentane-1,3-diyls", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 736, 749, 751], "ImageBB": [448, 757, 787, 895]}, "reactions": [{"reactants": [0, 1], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [3], "products": [8]}, {"reactants": [8], "conditions": [], "products": [6]}], "diagram_type": "single"}, {"id": 1017, "width": 1352, "height": 1096, "file_name": "jacs.5b00936-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [651.31, 140.63, 81.16, 32.45], "category_id": 2}, {"id": 1, "bbox": [110.24, 283.28, 294.89, 276.52], "category_id": 1}, {"id": 2, "bbox": [1087.55, 726.79, 188.02, 118.99], "category_id": 1}, {"id": 3, "bbox": [61.55, 101.41, 318.55, 53.41], "category_id": 1}, {"id": 4, "bbox": [94.69, 174.43, 241.45, 37.19], "category_id": 3}, {"id": 5, "bbox": [674.31, 782.91, 194.78, 54.76], "category_id": 2}, {"id": 6, "bbox": [418.65, 84.51, 116.33, 36.51], "category_id": 2}, {"id": 7, "bbox": [828.51, 85.86, 126.48, 36.51], "category_id": 2}, {"id": 8, "bbox": [443.0, 171.05, 72.37, 30.42], "category_id": 2}, {"id": 9, "bbox": [1101.75, 856.6, 165.71, 41.92], "category_id": 3}, {"id": 10, "bbox": [808.9, 278.55, 503.87, 325.87], "category_id": 1}, {"id": 11, "bbox": [484.93, 283.28, 302.33, 258.27], "category_id": 1}, {"id": 12, "bbox": [333.43, 835.64, 157.59, 52.06], "category_id": 2}, {"id": 13, "bbox": [690.51, 710.51, 157.89, 48.69], "category_id": 2}, {"id": 14, "bbox": [858.27, 171.05, 73.72, 30.42], "category_id": 2}, {"id": 15, "bbox": [1003.01, 58.14, 279.33, 91.95], "category_id": 1}, {"id": 16, "bbox": [630.35, 519.91, 41.25, 41.24], "category_id": 3}, {"id": 17, "bbox": [73.72, 718.0, 140.48, 103.45], "category_id": 1}, {"id": 18, "bbox": [1000.98, 167.67, 258.36, 39.21], "category_id": 3}, {"id": 19, "bbox": [564.07, 38.54, 242.13, 60.56], "category_id": 1}, {"id": 20, "bbox": [72.37, 839.7, 153.53, 48.0], "category_id": 2}, {"id": 21, "bbox": [628.99, 79.78, 122.42, 35.83], "category_id": 2}, {"id": 22, "bbox": [952.28, 957.34, 366.58, 134.54], "category_id": 1}, {"id": 23, "bbox": [244.83, 523.29, 35.17, 38.54], "category_id": 3}, {"id": 24, "bbox": [828.51, 128.46, 133.92, 28.39], "category_id": 2}, {"id": 25, "bbox": [417.98, 125.75, 135.26, 30.43], "category_id": 2}, {"id": 26, "bbox": [550.54, 955.31, 320.58, 126.43], "category_id": 1}, {"id": 27, "bbox": [10.15, 957.34, 412.56, 122.37], "category_id": 1}, {"id": 28, "bbox": [356.32, 747.35, 110.52, 46.05], "category_id": 2}], "caption": "Scheme 1. Hydroboration of 1-Octyne with 1 and 2 along with Solid State Structure of 2 at 30% Probability Ellipsoids ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 405]}, "reactions": [{"reactants": [19, 0], "conditions": [6, 25], "products": [3]}, {"reactants": [19, 0], "conditions": [7, 24], "products": [15]}, {"reactants": [17, 28], "conditions": [13, 5], "products": [2]}], "diagram_type": "multiple"}, {"id": 673, "width": 1344, "height": 1892, "file_name": "ol401812h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [161.19, 25.63, 311.71, 147.97], "category_id": 1}, {"id": 1, "bbox": [264.0, 216.0, 193.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [6.0, 701.0, 1331.0, 1160.0], "category_id": 4}, {"id": 3, "bbox": [875.2, 6.3, 308.3, 172.0], "category_id": 1}, {"id": 4, "bbox": [502.0, 0.0, 302.5, 87.0], "category_id": 1}, {"id": 5, "bbox": [1020.0, 216.1, 56.0, 58.9], "category_id": 3}, {"id": 6, "bbox": [503.74, 104.69, 333.66, 146.01], "category_id": 1}, {"id": 7, "bbox": [795.4, 398.1, 180.7, 238.3], "category_id": 3}, {"id": 8, "bbox": [373.0, 320.8, 404.1, 316.2], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4, 6], "products": [3]}], "corefs": [[0, 1], [3, 5]], "caption": "Table 1. Screening of Reaction Conditions", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 298, 100], "ImageBB": [71, 112, 407, 585]}, "diagram_type": "single"}, {"id": 832, "width": 1348, "height": 400, "file_name": "jo4004426-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [546.0, 207.0, 375.0, 51.0], "category_id": 2}, {"id": 1, "bbox": [291.0, 32.0, 181.8, 268.0], "category_id": 1}, {"id": 2, "bbox": [49.0, 36.0, 128.0, 265.0], "category_id": 1}, {"id": 3, "bbox": [169.0, 238.0, 30.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [460.0, 238.0, 32.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [959.0, 6.0, 336.0, 291.0], "category_id": 1}, {"id": 6, "bbox": [1129.0, 234.0, 31.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [541.0, 44.0, 384.0, 107.9], "category_id": 2}], "reactions": [{"reactants": [2, 1], "conditions": [7, 0], "products": [5]}], "corefs": [[2, 3], [1, 4], [5, 6]], "caption": "Table 1. Optimization Studies with a Homogeneous Metal Source ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 412, 125], "ImageBB": [82, 131, 419, 231]}, "diagram_type": "single"}, {"id": 917, "width": 2820, "height": 676, "file_name": "acs.joc.5b01547-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [643.28, 229.62, 57.84, 53.53], "category_id": 3}, {"id": 1, "bbox": [1965.11, 5.63, 320.23, 190.17], "category_id": 1}, {"id": 2, "bbox": [2122.4, 239.21, 91.45, 72.31], "category_id": 1}, {"id": 3, "bbox": [1697.08, 38.03, 122.73, 61.99], "category_id": 2}, {"id": 4, "bbox": [1654.76, 494.45, 128.37, 54.94], "category_id": 2}, {"id": 5, "bbox": [529.01, 8.45, 344.22, 188.77], "category_id": 1}, {"id": 6, "bbox": [884.51, 50.71, 349.86, 59.17], "category_id": 2}, {"id": 7, "bbox": [1423.4, 228.21, 62.07, 49.3], "category_id": 3}, {"id": 8, "bbox": [1697.08, 126.78, 134.02, 56.35], "category_id": 2}, {"id": 9, "bbox": [1323.24, 12.68, 324.46, 184.54], "category_id": 1}, {"id": 10, "bbox": [1262.58, 580.38, 153.77, 52.12], "category_id": 3}, {"id": 11, "bbox": [891.57, 125.37, 299.07, 111.29], "category_id": 2}, {"id": 12, "bbox": [1602.56, 259.2, 335.75, 211.3], "category_id": 1}, {"id": 13, "bbox": [1086.24, 349.35, 438.73, 219.76], "category_id": 1}, {"id": 14, "bbox": [1965.11, 397.25, 313.18, 184.54], "category_id": 1}], "caption": "Scheme 2. Formation of 4 with Excess Sodium Trichloroacetate", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 442, 110], "ImageBB": [82, 116, 787, 285]}, "reactions": [{"reactants": [5], "conditions": [6, 11], "products": [9]}, {"reactants": [9], "conditions": [3, 8], "products": [1]}, {"reactants": [1], "conditions": [2], "products": [14]}, {"reactants": [14], "conditions": [12, 4], "products": [13]}], "diagram_type": "tree"}, {"id": 916, "width": 1356, "height": 920, "file_name": "acs.joc.5b01204-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 584.31, 966.63, 284.34], "category_id": 1}, {"id": 1, "bbox": [276.76, 523.91, 60.37, 37.32], "category_id": 3}, {"id": 2, "bbox": [213.0, 232.77, 31.2, 36.65], "category_id": 3}, {"id": 3, "bbox": [820.11, 407.86, 363.59, 41.4], "category_id": 2}, {"id": 4, "bbox": [893.37, 186.62, 311.36, 111.98], "category_id": 2}, {"id": 5, "bbox": [39.34, 2.71, 341.89, 269.42], "category_id": 1}, {"id": 6, "bbox": [560.99, 4.07, 341.88, 268.06], "category_id": 1}, {"id": 7, "bbox": [963.92, 724.1, 282.19, 76.01], "category_id": 2}, {"id": 8, "bbox": [1283.42, 695.6, 48.16, 38.01], "category_id": 3}, {"id": 9, "bbox": [99.04, 295.89, 770.59, 266.02], "category_id": 1}, {"id": 10, "bbox": [362.23, 179.84, 149.92, 40.04], "category_id": 2}, {"id": 11, "bbox": [1042.61, 655.56, 127.53, 46.83], "category_id": 2}, {"id": 12, "bbox": [172.3, 838.79, 63.76, 39.36], "category_id": 3}, {"id": 13, "bbox": [330.35, 101.8, 211.64, 45.46], "category_id": 2}, {"id": 14, "bbox": [733.28, 232.77, 47.49, 39.36], "category_id": 3}, {"id": 15, "bbox": [816.04, 475.05, 341.88, 75.32], "category_id": 2}, {"id": 16, "bbox": [895.41, 77.36, 352.73, 80.08], "category_id": 2}], "caption": "Scheme 3. Synthesis of Probe 5b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 477, 636, 492], "ImageBB": [448, 498, 787, 728]}, "reactions": [{"reactants": [5], "conditions": [13, 10], "products": [6]}, {"reactants": [6], "conditions": [16, 4], "products": [9]}, {"reactants": [9], "conditions": [3, 15], "products": [0]}, {"reactants": [0], "conditions": [11, 7], "products": [8]}], "diagram_type": "multiple"}, {"id": 398, "width": 1352, "height": 468, "file_name": "op500102h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [49.0, 326.0, 55.0, 47.9], "category_id": 3}, {"id": 1, "bbox": [1062.0, 114.4, 287.0, 208.6], "category_id": 1}, {"id": 2, "bbox": [1.0, 166.3, 228.0, 130.5], "category_id": 1}, {"id": 3, "bbox": [494.2, 146.2, 214.8, 183.8], "category_id": 1}, {"id": 4, "bbox": [770.41, 4.98, 265.39, 115.92], "category_id": 1}, {"id": 5, "bbox": [268.0, 158.1, 164.0, 56.9], "category_id": 2}, {"id": 6, "bbox": [248.0, 231.0, 187.9, 49.8], "category_id": 2}, {"id": 7, "bbox": [5.0, 391.0, 1339.0, 77.0], "category_id": 4}, {"id": 8, "bbox": [747.0, 130.0, 297.0, 90.0], "category_id": 2}, {"id": 9, "bbox": [760.0, 240.0, 275.0, 89.0], "category_id": 2}, {"id": 10, "bbox": [552.0, 326.0, 52.0, 39.0], "category_id": 3}, {"id": 11, "bbox": [1188.0, 325.0, 35.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5, 6], "products": [3]}, {"reactants": [3], "conditions": [4, 8, 9], "products": [1]}], "corefs": [[2, 0], [3, 10], [1, 11]], "caption": "Table 1. Reaction of activated TFEDMA with \u03b2-keto esters and hydrazines ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 367, 783, 401], "ImageBB": [448, 407, 786, 524]}, "diagram_type": "single"}, {"id": 115, "width": 1328, "height": 1268, "file_name": "op9802071-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [584.0, 84.0, 339.0, 208.0], "category_id": 1}, {"id": 1, "bbox": [15.0, 343.0, 47.0, 59.0], "category_id": 3}, {"id": 2, "bbox": [1125.0, 337.0, 86.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [716.0, 328.0, 80.0, 62.0], "category_id": 3}, {"id": 4, "bbox": [132.0, 290.0, 364.0, 77.0], "category_id": 2}, {"id": 5, "bbox": [719.0, 703.0, 81.0, 60.0], "category_id": 3}, {"id": 6, "bbox": [705.0, 891.0, 415.0, 235.0], "category_id": 1}, {"id": 7, "bbox": [828.0, 1154.0, 261.0, 114.0], "category_id": 3}, {"id": 8, "bbox": [1003.1, 79.3, 321.6, 220.0], "category_id": 1}, {"id": 9, "bbox": [234.27, 996.73, 42.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [1125.0, 711.0, 93.4, 56.8], "category_id": 3}, {"id": 11, "bbox": [332.0, 953.9, 330.0, 61.1], "category_id": 2}, {"id": 12, "bbox": [999.8, 457.0, 326.2, 222.7], "category_id": 1}, {"id": 13, "bbox": [584.0, 454.2, 337.4, 211.8], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [4], "products": [0, 8, 13, 12]}, {"reactants": [9], "conditions": [11], "products": [6]}], "corefs": [[0, 3], [8, 2], [13, 5], [12, 10], [6, 7]], "caption": "Table 1. Reduction of 3 with borohydrides", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 382, 310, 396], "ImageBB": [74, 52, 406, 369]}, "diagram_type": "multiple"}, {"id": 871, "width": 1352, "height": 620, "file_name": "ol7019636-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [860.0, 0.0, 261.0, 140.0], "category_id": 1}, {"id": 1, "bbox": [656.0, 31.0, 68.0, 43.0], "category_id": 2}, {"id": 2, "bbox": [0.0, 172.0, 1352.0, 444.0], "category_id": 4}, {"id": 3, "bbox": [241.0, 0.0, 265.0, 142.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1], "products": [0]}], "corefs": [], "caption": "Table 3. Preparation of Some Diazeniumdiolate Prodrug Forms ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 373, 104], "ImageBB": [73, 108, 411, 263]}, "diagram_type": "single"}, {"id": 405, "width": 1352, "height": 1228, "file_name": "op400278d-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [52.9, 43.0, 172.1, 202.0], "category_id": 1}, {"id": 1, "bbox": [555.0, 866.0, 243.0, 116.0], "category_id": 2}, {"id": 2, "bbox": [44.0, 1088.0, 462.0, 108.0], "category_id": 2}, {"id": 3, "bbox": [149.0, 595.0, 254.0, 110.0], "category_id": 2}, {"id": 4, "bbox": [973.0, 610.0, 243.0, 112.0], "category_id": 2}, {"id": 5, "bbox": [524.0, 211.0, 344.0, 100.0], "category_id": 2}, {"id": 6, "bbox": [285.0, 250.0, 194.0, 64.0], "category_id": 2}, {"id": 7, "bbox": [27.0, 259.0, 205.0, 59.0], "category_id": 2}, {"id": 8, "bbox": [491.0, 2.0, 423.0, 205.0], "category_id": 2}, {"id": 9, "bbox": [1055.0, 1079.0, 71.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [241.0, 1027.0, 66.0, 53.0], "category_id": 3}, {"id": 11, "bbox": [642.0, 817.0, 66.0, 45.0], "category_id": 3}, {"id": 12, "bbox": [239.0, 544.0, 74.0, 51.0], "category_id": 3}, {"id": 13, "bbox": [1055.0, 558.0, 71.0, 47.0], "category_id": 3}, {"id": 14, "bbox": [110.0, 792.0, 329.0, 217.0], "category_id": 1}, {"id": 15, "bbox": [934.0, 723.0, 316.0, 329.0], "category_id": 1}, {"id": 16, "bbox": [449.0, 564.0, 480.0, 278.0], "category_id": 1}, {"id": 17, "bbox": [43.0, 357.0, 497.0, 188.0], "category_id": 1}, {"id": 18, "bbox": [888.0, 347.0, 464.0, 253.0], "category_id": 1}, {"id": 19, "bbox": [919.0, 78.0, 433.0, 190.0], "category_id": 1}, {"id": 20, "bbox": [305.0, 57.0, 174.0, 199.0], "category_id": 1}], "reactions": [{"reactants": [0, 20], "conditions": [8, 5], "products": [19]}], "corefs": [[17, 12], [18, 13], [16, 11], [14, 10], [15, 9]], "caption": "Table 6. Comparative study of Pd-PEPPSI-IPent (1) and Pd- PEPPSI-IPentCl (84) in aryl aminations with electron- de\ufb01cient anilines and electron-rich aryl chlorides ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 141, 417, 186], "ImageBB": [82, 193, 420, 500]}, "diagram_type": "single"}, {"id": 720, "width": 1348, "height": 904, "file_name": "ol026156g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [407.5, 2.4, 326.7, 295.0], "category_id": 1}, {"id": 1, "bbox": [1132.0, 356.0, 61.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [1139.29, 308.97, 48.47, 47.26], "category_id": 2}, {"id": 3, "bbox": [55.5, 86.0, 274.8, 131.5], "category_id": 1}, {"id": 4, "bbox": [517.3, 354.6, 88.7, 46.4], "category_id": 3}, {"id": 5, "bbox": [825.2, 167.0, 92.8, 95.5], "category_id": 2}, {"id": 6, "bbox": [0.0, 439.3, 1344.0, 464.7], "category_id": 4}, {"id": 7, "bbox": [837.0, 81.8, 61.6, 59.2], "category_id": 2}, {"id": 8, "bbox": [1018.9, 9.7, 284.1, 282.3], "category_id": 1}, {"id": 9, "bbox": [490.98, 308.97, 155.11, 50.89], "category_id": 2}], "reactions": [{"reactants": [3, 0], "conditions": [7, 5], "products": [8]}], "corefs": [[0, 4], [8, 1]], "caption": "Table 1. Effects of R-Amino Acids in 2 on Catalytic Asymmetric Coupling of 2-Naphthol in CCl4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 478, 721, 510], "ImageBB": [439, 520, 776, 746]}, "diagram_type": "single"}, {"id": 311, "width": 1356, "height": 1976, "file_name": "ol302400p-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [583.0, 135.0, 215.0, 90.0], "category_id": 2}, {"id": 1, "bbox": [996.0, 167.0, 93.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [563.0, 35.0, 267.0, 84.0], "category_id": 2}, {"id": 3, "bbox": [81.0, 3.0, 250.0, 148.0], "category_id": 1}, {"id": 4, "bbox": [853.0, 26.0, 433.0, 139.0], "category_id": 1}, {"id": 5, "bbox": [272.0, 59.0, 275.0, 123.0], "category_id": 1}, {"id": 6, "bbox": [15.0, 279.0, 1341.0, 1697.0], "category_id": 4}], "reactions": [{"reactants": [3, 5], "conditions": [2, 0], "products": [4]}], "corefs": [[4, 1]], "caption": "Table 3. Pd-Catalyzed Dehydrogenative Olefination of Terminal Alkynes with Allyl Phenyl Ethersa,b ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 439, 728, 466], "ImageBB": [436, 477, 775, 971]}, "diagram_type": "single"}, {"id": 214, "width": 884, "height": 800, "file_name": "op034064g-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [258.5, 398.0, 300.8, 45.6], "category_id": 2}, {"id": 1, "bbox": [258.1, 360.0, 609.9, 45.0], "category_id": 2}, {"id": 2, "bbox": [394.1, 6.0, 484.9, 149.4], "category_id": 1}, {"id": 3, "bbox": [138.78, 154.0, 53.0, 51.0], "category_id": 3}, {"id": 4, "bbox": [62.22, 486.86, 51.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [472.0, 202.0, 388.0, 53.6], "category_id": 2}, {"id": 6, "bbox": [0.0, 570.1, 573.7, 192.9], "category_id": 1}, {"id": 7, "bbox": [1.0, 331.1, 196.8, 142.8], "category_id": 1}, {"id": 8, "bbox": [212.0, 752.0, 62.2, 48.0], "category_id": 3}, {"id": 9, "bbox": [0.0, 15.4, 302.1, 145.9], "category_id": 1}, {"id": 10, "bbox": [78.0, 204.0, 148.8, 46.3], "category_id": 2}], "reactions": [{"reactants": [9, 2], "conditions": [7, 1, 0], "products": [6]}], "corefs": [[9, 3], [7, 4], [6, 8]], "caption": "Table 4. Alkylation of resorcinol monobenzoate", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 294, 702, 308], "ImageBB": [424, 81, 645, 281]}, "diagram_type": "tree"}, {"id": 954, "width": 1352, "height": 2036, "file_name": "acs.orglett.6b00661-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.07, 16.3, 351.46, 422.68], "category_id": 1}, {"id": 1, "bbox": [120.21, 1329.15, 460.45, 67.23], "category_id": 3}, {"id": 2, "bbox": [535.84, 503.14, 236.34, 104.91], "category_id": 2}, {"id": 3, "bbox": [1016.67, 736.38, 77.43, 61.11], "category_id": 3}, {"id": 4, "bbox": [875.07, 845.36, 178.28, 158.89], "category_id": 2}, {"id": 5, "bbox": [116.13, 1849.61, 462.5, 70.28], "category_id": 3}, {"id": 6, "bbox": [122.25, 1048.05, 576.59, 428.79], "category_id": 1}, {"id": 7, "bbox": [122.25, 1564.43, 578.62, 437.96], "category_id": 1}, {"id": 8, "bbox": [162.99, 1455.45, 228.19, 112.04], "category_id": 2}, {"id": 9, "bbox": [309.69, 92.68, 142.62, 100.84], "category_id": 2}, {"id": 10, "bbox": [911.75, 226.11, 302.55, 152.78], "category_id": 2}, {"id": 11, "bbox": [613.26, 886.1, 188.47, 106.95], "category_id": 2}, {"id": 12, "bbox": [775.24, 435.92, 575.57, 445.09], "category_id": 1}, {"id": 13, "bbox": [1013.62, 143.61, 77.42, 63.15], "category_id": 3}, {"id": 14, "bbox": [239.4, 736.38, 92.7, 61.11], "category_id": 3}, {"id": 15, "bbox": [562.33, 647.77, 190.5, 204.72], "category_id": 2}, {"id": 16, "bbox": [911.75, 1329.15, 302.55, 71.3], "category_id": 3}, {"id": 17, "bbox": [613.26, 287.22, 81.5, 71.3], "category_id": 3}, {"id": 18, "bbox": [775.24, 1048.05, 572.51, 365.64], "category_id": 1}, {"id": 19, "bbox": [0.0, 456.29, 590.85, 424.72], "category_id": 1}, {"id": 20, "bbox": [309.69, 228.15, 157.9, 157.87], "category_id": 2}, {"id": 21, "bbox": [538.9, 16.3, 340.25, 423.7], "category_id": 1}, {"id": 22, "bbox": [1066.59, 886.1, 190.5, 115.09], "category_id": 2}, {"id": 23, "bbox": [871.0, 0.0, 405.44, 208.79], "category_id": 1}, {"id": 24, "bbox": [83.53, 282.13, 82.52, 81.48], "category_id": 3}], "caption": "Scheme 5. Synthesis of Gardnerine (1), Hydroxygardnerine (2), and Hydroxygardnutine (3) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 640]}, "reactions": [{"reactants": [0], "conditions": [9, 20], "products": [21]}, {"reactants": [21], "conditions": [23, 10], "products": [19]}, {"reactants": [19], "conditions": [2, 15], "products": [12]}, {"reactants": [12], "conditions": [4, 11], "products": [6]}, {"reactants": [6], "conditions": [8], "products": [7]}, {"reactants": [12], "conditions": [4, 22], "products": [18]}], "diagram_type": "tree"}, {"id": 592, "width": 1356, "height": 348, "file_name": "acs.oprd.6b00180-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [94.0, 249.0, 139.0, 38.7], "category_id": 2}, {"id": 1, "bbox": [528.0, 285.0, 633.0, 62.0], "category_id": 2}, {"id": 2, "bbox": [98.0, 217.0, 131.0, 33.0], "category_id": 2}, {"id": 3, "bbox": [1038.0, 38.4, 314.9, 204.8], "category_id": 1}, {"id": 4, "bbox": [7.0, 65.6, 253.0, 137.4], "category_id": 1}, {"id": 5, "bbox": [327.2, 65.3, 301.8, 123.5], "category_id": 1}, {"id": 6, "bbox": [650.0, 35.0, 348.7, 89.2], "category_id": 2}, {"id": 7, "bbox": [719.5, 146.2, 190.8, 124.1], "category_id": 2}, {"id": 8, "bbox": [397.0, 209.0, 148.6, 43.8], "category_id": 2}, {"id": 9, "bbox": [1217.91, 229.75, 84.88, 46.01], "category_id": 2}], "reactions": [{"reactants": [4, 5], "conditions": [6, 7], "products": [3]}], "corefs": [], "caption": "Figure 3. Suzuki reaction of 4-bromoanisole with 3-aminophenylbor- onic acid using Pd(OAc)2/K3PO4/H2O in the absence of added ligand. ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 746, 784, 788], "ImageBB": [448, 650, 787, 737]}, "diagram_type": "single"}, {"id": 60, "width": 1352, "height": 948, "file_name": "ja402810t-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1119.49, 849.23, 73.55, 29.87], "category_id": 2}, {"id": 1, "bbox": [746.48, 589.9, 218.02, 194.7], "category_id": 1}, {"id": 2, "bbox": [7.56, 139.43, 563.91, 308.49], "category_id": 1}, {"id": 3, "bbox": [682.33, 137.05, 562.72, 307.31], "category_id": 1}, {"id": 4, "bbox": [12.31, 507.7, 588.86, 308.49], "category_id": 1}, {"id": 5, "bbox": [1033.31, 528.63, 310.26, 304.51], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1, 5]}], "corefs": [], "caption": "Figure 2. Fragmentation patterns observed following CID of singly protonated PRAGS-derivatized (a) and FRAGS-derivatized (c) maltoheptaose and CID spectra of singly protonated PRAGS- derivatized (b) and FRAGS-derivatized (d) maltoheptaose. The parent ion refers to the protonated molecular ion. The possible fragmentation of the reducing terminus glycan subunit is not observed because of the low mass cuto\ufb00. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 614, 417, 711], "ImageBB": [82, 716, 420, 953]}, "diagram_type": "multiple"}, {"id": 875, "width": 1352, "height": 680, "file_name": "ol701624y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [267.0, 278.0, 78.0, 35.0], "category_id": 3}, {"id": 1, "bbox": [604.0, 218.0, 86.0, 33.0], "category_id": 2}, {"id": 2, "bbox": [106.0, 44.0, 365.0, 212.0], "category_id": 1}, {"id": 3, "bbox": [883.0, 3.0, 364.0, 279.0], "category_id": 1}, {"id": 4, "bbox": [529.0, 20.0, 262.0, 101.0], "category_id": 2}, {"id": 5, "bbox": [582.0, 155.0, 165.0, 42.0], "category_id": 2}, {"id": 6, "bbox": [8.0, 344.0, 1333.0, 322.0], "category_id": 4}, {"id": 7, "bbox": [907.0, 281.0, 73.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4, 5, 1], "products": [3]}], "corefs": [[2, 0], [3, 7]], "caption": "Table 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 486, 89], "ImageBB": [439, 93, 777, 263]}, "diagram_type": "single"}, {"id": 1321, "width": 1356, "height": 940, "file_name": "op3003097-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [259.8, 176.38, 335.78, 60.37], "category_id": 2}, {"id": 1, "bbox": [392.76, 543.38, 295.75, 59.02], "category_id": 2}, {"id": 2, "bbox": [144.49, 850.01, 159.41, 46.81], "category_id": 3}, {"id": 3, "bbox": [1025.65, 171.63, 50.87, 49.52], "category_id": 3}, {"id": 4, "bbox": [31.2, 128.89, 217.75, 209.62], "category_id": 1}, {"id": 5, "bbox": [690.55, 404.99, 38.66, 46.13], "category_id": 3}, {"id": 6, "bbox": [16.28, 459.26, 388.01, 371.08], "category_id": 1}, {"id": 7, "bbox": [594.9, 113.97, 261.16, 278.81], "category_id": 1}, {"id": 8, "bbox": [404.29, 635.64, 238.78, 107.19], "category_id": 2}, {"id": 9, "bbox": [128.88, 400.24, 42.74, 44.78], "category_id": 3}, {"id": 10, "bbox": [690.55, 455.87, 388.69, 374.47], "category_id": 1}, {"id": 11, "bbox": [894.05, 852.05, 29.17, 43.41], "category_id": 3}, {"id": 12, "bbox": [896.76, 269.32, 335.1, 134.32], "category_id": 2}, {"id": 13, "bbox": [875.74, 8.82, 392.75, 131.6], "category_id": 1}, {"id": 14, "bbox": [277.44, 267.28, 277.44, 152.64], "category_id": 2}], "caption": "Scheme 4. Process for the preparation of puri\ufb01ed 8", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 741, 110], "ImageBB": [448, 116, 787, 351]}, "reactions": [{"reactants": [4], "conditions": [0, 14], "products": [7]}, {"reactants": [7, 13], "conditions": [12], "products": [6]}, {"reactants": [6], "conditions": [1, 8], "products": [10]}], "diagram_type": "multiple"}, {"id": 155, "width": 2816, "height": 1752, "file_name": "op700160a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [14.0, 340.0, 2798.0, 895.0], "category_id": 4}, {"id": 1, "bbox": [24.0, 1235.0, 2792.0, 127.0], "category_id": 2}, {"id": 2, "bbox": [379.9, 1370.4, 322.1, 304.8], "category_id": 1}, {"id": 3, "bbox": [911.0, 258.3, 61.3, 54.4], "category_id": 3}, {"id": 4, "bbox": [635.0, 259.0, 46.4, 51.0], "category_id": 3}, {"id": 5, "bbox": [1871.39, 1510.0, 176.51, 57.0], "category_id": 2}, {"id": 6, "bbox": [772.3, 24.1, 317.7, 180.8], "category_id": 1}, {"id": 7, "bbox": [165.0, 1486.0, 190.6, 60.0], "category_id": 2}, {"id": 8, "bbox": [1468.8, 1402.2, 368.9, 249.1], "category_id": 1}, {"id": 9, "bbox": [1303.0, 1499.0, 154.3, 63.0], "category_id": 2}, {"id": 10, "bbox": [2094.1, 1392.1, 393.5, 266.0], "category_id": 1}, {"id": 11, "bbox": [738.0, 1497.0, 187.5, 59.0], "category_id": 2}, {"id": 12, "bbox": [950.2, 1388.8, 307.5, 273.8], "category_id": 1}, {"id": 13, "bbox": [1969.4, 0.0, 238.5, 232.6], "category_id": 1}, {"id": 14, "bbox": [1258.1, 42.8, 189.6, 51.2], "category_id": 2}, {"id": 15, "bbox": [2037.36, 258.35, 105.68, 63.41], "category_id": 3}, {"id": 16, "bbox": [1139.0, 128.0, 437.0, 63.3], "category_id": 2}, {"id": 17, "bbox": [1727.35, 258.35, 96.29, 61.06], "category_id": 3}, {"id": 18, "bbox": [607.1, 46.8, 116.2, 135.1], "category_id": 1}, {"id": 19, "bbox": [1660.3, 3.0, 238.2, 231.8], "category_id": 1}], "reactions": [{"reactants": [18, 6], "conditions": [14, 16], "products": [19, 13]}], "corefs": [[18, 4], [6, 3], [19, 17], [13, 15]], "caption": "Table 2. Chiral lanthanide camphorate catalysts in bisfuran alcohol formationa", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 45, 493, 59], "ImageBB": [58, 74, 762, 512]}, "diagram_type": "single"}, {"id": 486, "width": 1344, "height": 1060, "file_name": "ol0610183-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [35.0, 2.2, 243.3, 305.8], "category_id": 1}, {"id": 1, "bbox": [511.6, 15.0, 246.4, 299.0], "category_id": 1}, {"id": 2, "bbox": [1182.58, 343.74, 34.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [1071.58, 35.0, 240.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [627.0, 341.0, 27.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [2.0, 423.0, 1342.0, 637.0], "category_id": 4}, {"id": 6, "bbox": [339.0, 135.0, 89.0, 42.0], "category_id": 2}, {"id": 7, "bbox": [312.0, 204.0, 162.0, 62.0], "category_id": 2}, {"id": 8, "bbox": [856.0, 137.0, 86.0, 38.0], "category_id": 2}, {"id": 9, "bbox": [820.0, 204.0, 158.0, 51.0], "category_id": 2}, {"id": 10, "bbox": [141.0, 339.0, 36.0, 35.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [6, 7], "products": [1]}, {"reactants": [1], "conditions": [8, 9], "products": [3]}], "corefs": [[0, 10], [1, 4], [3, 2]], "caption": "Table 1. Substitution of 1 with Aromatic Compounds", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 624, 359, 637], "ImageBB": [74, 642, 410, 907]}, "diagram_type": "single"}, {"id": 289, "width": 1344, "height": 1288, "file_name": "ol702044z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [170.0, 0.0, 282.0, 243.0], "category_id": 1}, {"id": 1, "bbox": [1025.0, 250.0, 43.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [485.0, 173.0, 342.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [510.0, 108.0, 291.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [886.0, 30.0, 286.0, 212.0], "category_id": 1}, {"id": 5, "bbox": [8.0, 354.0, 1336.0, 934.0], "category_id": 4}, {"id": 6, "bbox": [242.0, 247.0, 50.0, 55.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 2], "products": [4]}], "corefs": [[0, 6], [4, 1]], "caption": "Table 1. Reaction Development for the Conversion 1 f 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 298, 387, 314], "ImageBB": [74, 317, 410, 639]}, "diagram_type": "single"}, {"id": 852, "width": 1344, "height": 1168, "file_name": "jo2008675-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [416.0, 224.0, 32.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [92.0, 211.0, 97.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [334.0, 82.0, 233.0, 117.0], "category_id": 1}, {"id": 3, "bbox": [973.0, 37.0, 368.0, 177.0], "category_id": 1}, {"id": 4, "bbox": [3.0, 2.0, 241.0, 204.0], "category_id": 1}, {"id": 5, "bbox": [5.0, 336.0, 1339.0, 832.0], "category_id": 4}, {"id": 6, "bbox": [615.0, 159.0, 291.0, 47.0], "category_id": 2}, {"id": 7, "bbox": [610.0, 97.0, 273.0, 49.0], "category_id": 2}, {"id": 8, "bbox": [1142.0, 216.0, 102.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [4, 2], "conditions": [7, 6], "products": [3]}], "corefs": [[4, 1], [2, 0], [3, 8]], "caption": "Table 3. Synthesis of Di\ufb00erently Substituted 2, 3-Dihydrobenzofuransa ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 698, 122], "ImageBB": [437, 133, 773, 425]}, "diagram_type": "single"}, {"id": 76, "width": 2808, "height": 3076, "file_name": "ja200818w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [880.17, 204.77, 174.32, 44.69], "category_id": 2}, {"id": 1, "bbox": [1105.28, 150.43, 745.63, 138.57], "category_id": 2}, {"id": 2, "bbox": [488.68, 426.6, 1828.42, 2501.25], "category_id": 4}, {"id": 3, "bbox": [568.79, 58.12, 222.28, 146.19], "category_id": 1}, {"id": 4, "bbox": [885.2, 118.2, 158.2, 44.5], "category_id": 1}, {"id": 5, "bbox": [590.63, 210.98, 170.45, 45.47], "category_id": 2}, {"id": 6, "bbox": [1109.16, 42.53, 510.43, 92.05], "category_id": 2}, {"id": 7, "bbox": [1872.2, 7.6, 367.61, 200.72], "category_id": 1}], "reactions": [{"reactants": [3, 4], "conditions": [6, 1], "products": [7]}], "corefs": [[3, 5], [4, 0]], "caption": "Table 1. Palladium-Catalyzed Carbonylations Using 25 and *25a", "pdf": {"Page": 8, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 428, 108], "ImageBB": [71, 117, 773, 886]}, "diagram_type": "single"}, {"id": 791, "width": 1204, "height": 988, "file_name": "jo501785d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [363.0, 168.0, 56.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [7.0, 233.0, 1174.0, 749.0], "category_id": 4}, {"id": 2, "bbox": [579.0, 104.0, 271.0, 113.0], "category_id": 2}, {"id": 3, "bbox": [119.0, 164.0, 37.0, 49.0], "category_id": 3}, {"id": 4, "bbox": [168.0, 844.0, 155.0, 137.0], "category_id": 1}, {"id": 5, "bbox": [600.0, 1.0, 221.0, 96.0], "category_id": 2}, {"id": 6, "bbox": [944.0, 165.6, 38.7, 49.4], "category_id": 3}, {"id": 7, "bbox": [17.9, 22.9, 226.8, 170.8], "category_id": 1}, {"id": 8, "bbox": [867.3, 3.0, 322.7, 206.7], "category_id": 1}, {"id": 9, "bbox": [281.6, 28.2, 274.8, 124.6], "category_id": 1}], "reactions": [{"reactants": [7, 9], "conditions": [5, 2], "products": [8]}], "corefs": [[7, 3], [9, 0], [8, 6]], "caption": "Table 2. Scope with Respect to Triazole 1a,b", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 336, 110], "ImageBB": [100, 116, 401, 363]}, "diagram_type": "single"}, {"id": 698, "width": 1368, "height": 2072, "file_name": "ol047761h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [860.0, 0.0, 274.0, 213.0], "category_id": 1}, {"id": 1, "bbox": [32.0, 228.1, 1308.1, 1843.9], "category_id": 4}, {"id": 2, "bbox": [218.0, 24.0, 229.0, 131.0], "category_id": 1}, {"id": 3, "bbox": [469.0, 24.0, 320.0, 67.0], "category_id": 2}, {"id": 4, "bbox": [730.0, 283.0, 268.0, 201.0], "category_id": 1}, {"id": 5, "bbox": [1045.0, 171.0, 92.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [330.0, 171.0, 37.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [827.0, 478.0, 73.0, 62.0], "category_id": 3}, {"id": 8, "bbox": [1164.0, 476.0, 71.0, 64.0], "category_id": 3}, {"id": 9, "bbox": [471.0, 114.0, 320.0, 56.0], "category_id": 2}, {"id": 10, "bbox": [1065.0, 287.0, 268.0, 187.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [3, 9], "products": [0]}], "corefs": [[2, 6], [0, 5], [4, 7], [10, 8]], "caption": "Table 2. Ring Opening of Bn2N-R-Me-Ser-\u03b2-Lactone with Various Grignard-Derived Organocuprates ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 421, 385, 449], "ImageBB": [73, 450, 415, 968]}, "diagram_type": "single"}, {"id": 352, "width": 1348, "height": 1832, "file_name": "ol201201a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [309.0, 66.3, 255.6, 196.7], "category_id": 1}, {"id": 1, "bbox": [624.0, 175.09, 256.0, 47.0], "category_id": 2}, {"id": 2, "bbox": [1100.0, 260.0, 83.0, 50.1], "category_id": 3}, {"id": 3, "bbox": [423.0, 260.0, 45.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [622.0, 106.0, 265.0, 57.0], "category_id": 2}, {"id": 5, "bbox": [2.0, 7.0, 187.0, 241.0], "category_id": 1}, {"id": 6, "bbox": [951.0, 11.0, 382.0, 256.0], "category_id": 1}, {"id": 7, "bbox": [47.0, 265.0, 59.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [10.0, 365.0, 1338.0, 1467.0], "category_id": 4}], "reactions": [{"reactants": [5, 0], "conditions": [4, 1], "products": [6]}], "corefs": [[5, 7], [0, 3], [6, 2]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 185, 688, 201], "ImageBB": [436, 211, 773, 669]}, "diagram_type": "single"}, {"id": 1097, "width": 1040, "height": 564, "file_name": "jo961365y-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [382.39, 214.32, 113.42, 56.18], "category_id": 3}, {"id": 1, "bbox": [331.41, 329.8, 226.83, 165.94], "category_id": 1}, {"id": 2, "bbox": [816.81, 214.32, 112.37, 55.14], "category_id": 3}, {"id": 3, "bbox": [775.19, 4.68, 264.81, 245.01], "category_id": 1}, {"id": 4, "bbox": [835.02, 507.7, 104.57, 53.58], "category_id": 3}, {"id": 5, "bbox": [338.69, 36.41, 222.67, 159.7], "category_id": 1}, {"id": 6, "bbox": [382.39, 507.18, 111.34, 54.1], "category_id": 3}, {"id": 7, "bbox": [774.67, 290.78, 265.33, 247.61], "category_id": 1}, {"id": 8, "bbox": [0.0, 380.78, 132.67, 58.26], "category_id": 3}, {"id": 9, "bbox": [0.0, 380.78, 132.67, 58.26], "category_id": 3}, {"id": 10, "bbox": [0.0, 110.8, 132.67, 60.86], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [206, 49, 269, 63], "ImageBB": [111, 68, 371, 209]}, "reactions": [{"reactants": [10], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [3]}, {"reactants": [9], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [7]}], "diagram_type": "multiple"}, {"id": 296, "width": 1344, "height": 1196, "file_name": "ol400025a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [686.0, 106.0, 186.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [418.0, 251.0, 54.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [1.0, 317.0, 1343.0, 879.0], "category_id": 4}, {"id": 3, "bbox": [1004.0, 248.0, 67.5, 45.9], "category_id": 3}, {"id": 4, "bbox": [352.1, 48.0, 299.4, 182.3], "category_id": 1}, {"id": 5, "bbox": [924.8, 1.5, 299.1, 241.4], "category_id": 1}, {"id": 6, "bbox": [663.6, 173.2, 241.8, 44.2], "category_id": 2}, {"id": 7, "bbox": [181.0, 246.6, 59.0, 50.4], "category_id": 3}, {"id": 8, "bbox": [126.3, 104.3, 205.2, 126.9], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [0, 6], "products": [5]}], "corefs": [[8, 7], [4, 1], [5, 3]], "caption": "Table 2. Screening of Squaramide Catalytsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 544, 303, 560], "ImageBB": [71, 571, 407, 870]}, "diagram_type": "single"}, {"id": 37, "width": 1348, "height": 1676, "file_name": "ja5080739-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [389.55, 50.69, 140.17, 38.61], "category_id": 2}, {"id": 1, "bbox": [107.07, 106.48, 43.91, 34.27], "category_id": 3}, {"id": 2, "bbox": [1023.27, 5.47, 270.66, 108.04], "category_id": 1}, {"id": 3, "bbox": [594.93, 32.72, 265.63, 33.01], "category_id": 2}, {"id": 4, "bbox": [1123.86, 106.48, 46.43, 35.11], "category_id": 3}, {"id": 5, "bbox": [594.09, 70.02, 320.95, 74.93], "category_id": 2}, {"id": 6, "bbox": [0.0, 168.74, 1344.96, 1504.99], "category_id": 4}, {"id": 7, "bbox": [51.31, 6.55, 218.26, 106.25], "category_id": 1}], "reactions": [{"reactants": [7, 0], "conditions": [3, 5], "products": [2]}], "corefs": [[7, 1], [2, 4]], "caption": "Table 3. Optimization of the Asymmetric Varianta", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 734, 110], "ImageBB": [449, 116, 786, 535]}, "diagram_type": "single"}, {"id": 844, "width": 1352, "height": 3144, "file_name": "jo201489z-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [827.0, 603.0, 441.0, 408.0], "category_id": 1}, {"id": 1, "bbox": [280.0, 220.0, 184.0, 106.0], "category_id": 2}, {"id": 2, "bbox": [135.0, 1822.0, 151.0, 66.0], "category_id": 2}, {"id": 3, "bbox": [775.0, 524.0, 127.0, 61.0], "category_id": 2}, {"id": 4, "bbox": [736.0, 477.0, 66.0, 31.0], "category_id": 3}, {"id": 5, "bbox": [734.0, 942.0, 59.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [1128.0, 1501.0, 71.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [586.0, 1487.0, 95.0, 65.0], "category_id": 3}, {"id": 8, "bbox": [72.0, 1851.0, 47.0, 68.0], "category_id": 3}, {"id": 9, "bbox": [608.0, 2037.0, 82.0, 51.0], "category_id": 3}, {"id": 10, "bbox": [1130.0, 2021.0, 83.0, 59.0], "category_id": 3}, {"id": 11, "bbox": [543.0, 85.0, 442.0, 399.0], "category_id": 1}, {"id": 12, "bbox": [316.0, 599.0, 445.0, 406.0], "category_id": 1}, {"id": 13, "bbox": [293.0, 1163.0, 438.0, 385.0], "category_id": 1}, {"id": 14, "bbox": [807.0, 1156.0, 435.0, 402.0], "category_id": 1}, {"id": 15, "bbox": [817.0, 1677.0, 418.0, 402.0], "category_id": 1}, {"id": 16, "bbox": [300.0, 1670.0, 421.0, 416.0], "category_id": 1}, {"id": 17, "bbox": [145.0, 2267.0, 540.0, 550.0], "category_id": 1}, {"id": 18, "bbox": [636.0, 2231.0, 566.0, 570.0], "category_id": 1}, {"id": 19, "bbox": [277.0, 2811.0, 388.0, 319.0], "category_id": 1}, {"id": 20, "bbox": [748.0, 2794.0, 401.0, 333.0], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [3], "products": [12, 0]}, {"reactants": [12], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [16]}, {"reactants": [0], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [], "products": [15]}, {"reactants": [16], "conditions": [2], "products": [8]}], "corefs": [[11, 4], [12, 5], [0, 5], [13, 7], [14, 6], [16, 9], [15, 10]], "caption": "Figure 2. DFT calculated structures IIB (left) and IIIA (right), shown above the expansions of the key bipyrrolic fragments. ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 875, 405, 903], "ImageBB": [69, 81, 407, 867]}, "diagram_type": "tree"}, {"id": 206, "width": 1348, "height": 924, "file_name": "op034181b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 442.0, 1342.0, 458.0], "category_id": 4}, {"id": 1, "bbox": [655.14, 116.09, 154.1, 54.31], "category_id": 2}, {"id": 2, "bbox": [1140.9, 234.12, 47.07, 54.49], "category_id": 3}, {"id": 3, "bbox": [285.02, 262.6, 45.83, 56.98], "category_id": 3}, {"id": 4, "bbox": [141.0, 108.0, 334.0, 161.9], "category_id": 1}, {"id": 5, "bbox": [536.0, 224.0, 377.0, 42.0], "category_id": 2}, {"id": 6, "bbox": [876.0, 0.0, 335.0, 413.0], "category_id": 1}, {"id": 7, "bbox": [527.0, 43.0, 327.0, 156.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [7, 1, 5], "products": [6]}], "corefs": [[4, 3], [6, 2]], "caption": "Table 1. Nucleophilic aromatic substitution of 4-fluoro-3-nitroaniline with phenethylamine ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 697, 81], "ImageBB": [439, 84, 776, 315]}, "diagram_type": "single"}, {"id": 33, "width": 1348, "height": 796, "file_name": "ja511913h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [353.78, 651.64, 160.62, 36.6], "category_id": 2}, {"id": 1, "bbox": [122.0, 653.68, 150.46, 34.56], "category_id": 2}, {"id": 2, "bbox": [929.82, 506.46, 314.24, 98.54], "category_id": 1}, {"id": 3, "bbox": [318.7, 534.19, 232.07, 60.54], "category_id": 1}, {"id": 4, "bbox": [95.82, 513.64, 197.15, 97.52], "category_id": 1}, {"id": 5, "bbox": [584.72, 605.06, 290.61, 82.11], "category_id": 2}, {"id": 6, "bbox": [582.67, 487.97, 293.69, 82.11], "category_id": 2}, {"id": 7, "bbox": [725.86, 49.82, 370.03, 382.24], "category_id": 1}, {"id": 8, "bbox": [7.13, 722.81, 1333.77, 73.19], "category_id": 4}, {"id": 9, "bbox": [980.0, 651.64, 216.54, 36.6], "category_id": 2}], "reactions": [{"reactants": [4, 3], "conditions": [6, 5], "products": [2]}], "corefs": [[4, 1], [3, 0], [2, 9]], "caption": "Table 1. Optimization of the Decarboxylative Ole\ufb01nationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 773, 111], "ImageBB": [449, 116, 786, 315]}, "diagram_type": "single"}, {"id": 421, "width": 2820, "height": 2272, "file_name": "op300341n-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [750.2, 79.1, 199.6, 128.7], "category_id": 1}, {"id": 1, "bbox": [976.4, 96.1, 855.0, 269.7], "category_id": 1}, {"id": 2, "bbox": [240.4, 1481.6, 1216.6, 790.4], "category_id": 4}, {"id": 3, "bbox": [1507.5, 1414.2, 981.8, 845.2], "category_id": 4}, {"id": 4, "bbox": [246.5, 540.2, 1156.5, 756.5], "category_id": 4}, {"id": 5, "bbox": [2296.4, 293.1, 148.4, 202.8], "category_id": 1}, {"id": 6, "bbox": [2097.6, 0.0, 713.3, 191.2], "category_id": 1}, {"id": 7, "bbox": [1401.3, 542.6, 1167.7, 760.2], "category_id": 4}, {"id": 8, "bbox": [14.2, 120.0, 750.8, 205.7], "category_id": 1}, {"id": 9, "bbox": [1461.0, 377.0, 67.0, 52.0], "category_id": 3}, {"id": 10, "bbox": [2461.0, 431.0, 62.0, 48.0], "category_id": 3}, {"id": 11, "bbox": [364.0, 364.0, 63.0, 81.0], "category_id": 3}, {"id": 12, "bbox": [2540.0, 128.0, 44.0, 64.0], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [0], "products": [1]}, {"reactants": [1], "conditions": [], "products": [6, 5]}], "corefs": [[8, 11], [1, 9], [6, 12], [5, 10]], "caption": "Figure 2. Distillation phase diagrams for chloroacetonitrile, TFA, and 2-butanol.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 693, 471, 707], "ImageBB": [82, 116, 787, 684]}, "diagram_type": "single"}, {"id": 58, "width": 1352, "height": 1404, "file_name": "ja406383h-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [552.62, 434.38, 186.73, 190.26], "category_id": 1}, {"id": 1, "bbox": [427.9, 740.04, 108.06, 49.14], "category_id": 2}, {"id": 2, "bbox": [198.98, 763.4, 169.14, 107.56], "category_id": 1}, {"id": 3, "bbox": [556.14, 1025.54, 199.05, 177.94], "category_id": 1}, {"id": 4, "bbox": [126.84, 444.94, 158.59, 63.58], "category_id": 1}, {"id": 5, "bbox": [288.45, 1075.89, 184.66, 35.88], "category_id": 2}, {"id": 6, "bbox": [854.59, 1075.4, 129.67, 35.88], "category_id": 2}, {"id": 7, "bbox": [303.18, 641.84, 167.97, 78.1], "category_id": 2}, {"id": 8, "bbox": [906.26, 237.33, 170.9, 123.4], "category_id": 1}, {"id": 9, "bbox": [198.98, 233.81, 169.14, 123.4], "category_id": 1}, {"id": 10, "bbox": [1004.78, 1030.82, 250.08, 190.26], "category_id": 1}, {"id": 11, "bbox": [930.9, 759.87, 167.37, 109.33], "category_id": 1}, {"id": 12, "bbox": [123.48, 555.57, 172.49, 52.13], "category_id": 1}, {"id": 13, "bbox": [56.47, 1020.27, 200.81, 184.97], "category_id": 1}, {"id": 14, "bbox": [817.28, 640.36, 260.76, 72.71], "category_id": 2}, {"id": 15, "bbox": [806.47, 734.64, 60.44, 30.97], "category_id": 2}, {"id": 16, "bbox": [677.34, 276.03, 220.01, 77.13], "category_id": 2}, {"id": 17, "bbox": [329.21, 449.36, 126.72, 72.7], "category_id": 2}, {"id": 18, "bbox": [414.64, 278.49, 85.48, 73.21], "category_id": 2}], "reactions": [{"reactants": [9], "conditions": [18], "products": [0]}, {"reactants": [8], "conditions": [16], "products": [0]}, {"reactants": [4, 12], "conditions": [17], "products": [0]}, {"reactants": [2], "conditions": [7, 1], "products": [0]}, {"reactants": [11], "conditions": [14, 15], "products": [0]}, {"reactants": [13], "conditions": [5], "products": [3]}, {"reactants": [3], "conditions": [6], "products": [10]}], "corefs": [], "caption": "Figure 2. Some examples of natural and pharmaceutical products containing an enamide group. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 267, 417, 295], "ImageBB": [82, 298, 420, 649]}, "diagram_type": "tree"}, {"id": 651, "width": 1348, "height": 964, "file_name": "ol5000692-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [230.1, 5.5, 282.9, 189.8], "category_id": 1}, {"id": 1, "bbox": [294.2, 196.0, 110.8, 56.5], "category_id": 3}, {"id": 2, "bbox": [540.5, 34.7, 202.5, 55.3], "category_id": 2}, {"id": 3, "bbox": [945.7, 200.5, 114.6, 53.3], "category_id": 3}, {"id": 4, "bbox": [541.0, 105.0, 216.8, 105.8], "category_id": 2}, {"id": 5, "bbox": [784.0, 0.0, 363.0, 188.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 280.0, 1339.0, 684.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [2, 4], "products": [5]}], "corefs": [[0, 1], [5, 3]], "caption": "Table 2. Cyclization of 2 to 3 Catalyzed by 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 737, 345, 758], "ImageBB": [82, 764, 419, 1005]}, "diagram_type": "single"}, {"id": 1156, "width": 1356, "height": 812, "file_name": "ol0513995-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 58.35, 259.13, 115.35], "category_id": 1}, {"id": 1, "bbox": [1043.96, 264.63, 279.48, 50.89], "category_id": 2}, {"id": 2, "bbox": [845.89, 0.0, 263.87, 175.06], "category_id": 1}, {"id": 3, "bbox": [1010.05, 183.88, 40.02, 52.93], "category_id": 3}, {"id": 4, "bbox": [366.3, 558.43, 442.28, 54.96], "category_id": 2}, {"id": 5, "bbox": [1043.96, 312.8, 307.97, 139.78], "category_id": 2}, {"id": 6, "bbox": [124.81, 481.08, 192.65, 215.77], "category_id": 1}, {"id": 7, "bbox": [284.9, 16.28, 523.68, 93.64], "category_id": 2}, {"id": 8, "bbox": [214.36, 707.03, 42.05, 46.82], "category_id": 3}, {"id": 9, "bbox": [845.21, 479.04, 266.59, 219.17], "category_id": 1}, {"id": 10, "bbox": [113.96, 187.27, 31.88, 43.43], "category_id": 3}, {"id": 11, "bbox": [1010.05, 705.67, 40.02, 48.18], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 547, 265, 560], "ImageBB": [73, 565, 412, 768]}, "reactions": [{"reactants": [0], "conditions": [7], "products": [2]}, {"reactants": [2], "conditions": [1, 5], "products": [9]}, {"reactants": [9], "conditions": [4], "products": [6]}], "diagram_type": "tree"}, {"id": 1290, "width": 2040, "height": 1424, "file_name": "op200112g-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 1112.94, 667.41, 262.41], "category_id": 1}, {"id": 1, "bbox": [253.09, 255.26, 312.27, 215.44], "category_id": 1}, {"id": 2, "bbox": [811.31, 0.0, 319.42, 215.44], "category_id": 1}, {"id": 3, "bbox": [1374.63, 621.82, 665.37, 226.67], "category_id": 1}, {"id": 4, "bbox": [271.46, 0.0, 302.07, 217.48], "category_id": 1}, {"id": 5, "bbox": [632.72, 1122.13, 651.08, 250.15], "category_id": 1}, {"id": 6, "bbox": [676.6, 38.8, 60.21, 50.03], "category_id": 2}, {"id": 7, "bbox": [527.6, 689.2, 56.13, 53.1], "category_id": 2}, {"id": 8, "bbox": [1257.27, 205.23, 59.19, 51.05], "category_id": 2}, {"id": 9, "bbox": [1709.35, 459.47, 51.03, 47.99], "category_id": 2}, {"id": 10, "bbox": [628.63, 606.5, 642.93, 283.85], "category_id": 1}, {"id": 11, "bbox": [194.92, 992.45, 54.08, 51.06], "category_id": 2}, {"id": 12, "bbox": [1308.29, 700.44, 47.97, 52.07], "category_id": 2}, {"id": 13, "bbox": [956.22, 1378.41, 31.63, 40.84], "category_id": 3}, {"id": 14, "bbox": [676.6, 332.86, 46.94, 46.97], "category_id": 2}, {"id": 15, "bbox": [812.33, 265.47, 379.63, 219.53], "category_id": 1}, {"id": 16, "bbox": [554.14, 1171.14, 45.92, 52.07], "category_id": 2}, {"id": 17, "bbox": [1374.63, 138.86, 665.37, 222.59], "category_id": 1}, {"id": 18, "bbox": [0.0, 613.65, 563.32, 266.49], "category_id": 1}], "caption": "Scheme 4. Previous1 biomimetic route to the key iso\ufb02av-3-ene intermediate 8a", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 508, 108], "ImageBB": [167, 116, 677, 472]}, "reactions": [{"reactants": [4], "conditions": [6], "products": [2]}, {"reactants": [1], "conditions": [14], "products": [15]}, {"reactants": [2, 15], "conditions": [8], "products": [17]}, {"reactants": [17], "conditions": [9], "products": [3]}, {"reactants": [3], "conditions": [12], "products": [10]}, {"reactants": [10], "conditions": [7], "products": [18]}, {"reactants": [18], "conditions": [11], "products": [0]}, {"reactants": [0], "conditions": [16], "products": [5]}], "diagram_type": "tree"}, {"id": 872, "width": 1352, "height": 632, "file_name": "ol701624y-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 347.0, 1346.0, 284.0], "category_id": 4}, {"id": 1, "bbox": [925.0, 222.0, 82.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [575.18, 31.0, 197.0, 111.0], "category_id": 2}, {"id": 3, "bbox": [852.0, 0.0, 354.0, 251.2], "category_id": 1}, {"id": 4, "bbox": [154.0, 219.0, 82.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [150.8, 2.0, 366.2, 326.0], "category_id": 1}, {"id": 6, "bbox": [575.18, 185.55, 210.0, 100.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [2, 6], "products": [3]}], "corefs": [[5, 4], [3, 1]], "caption": "Table 6.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 260, 486, 273], "ImageBB": [439, 276, 777, 434]}, "diagram_type": "single"}, {"id": 634, "width": 1348, "height": 1044, "file_name": "ol501165h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [231.4, 33.63, 39.02, 56.51], "category_id": 3}, {"id": 1, "bbox": [924.0, 553.1, 353.3, 359.6], "category_id": 1}, {"id": 2, "bbox": [976.0, 27.0, 180.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [562.0, 1.0, 362.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [847.0, 452.0, 247.0, 81.0], "category_id": 3}, {"id": 5, "bbox": [64.0, 815.0, 312.0, 127.0], "category_id": 3}, {"id": 6, "bbox": [502.0, 848.0, 276.0, 96.0], "category_id": 3}, {"id": 7, "bbox": [21.0, 971.0, 1319.0, 66.0], "category_id": 4}, {"id": 8, "bbox": [220.0, 550.0, 265.0, 360.0], "category_id": 1}, {"id": 9, "bbox": [940.0, 793.0, 103.0, 57.0], "category_id": 3}, {"id": 10, "bbox": [302.2, 34.0, 196.8, 56.0], "category_id": 1}, {"id": 11, "bbox": [519.69, 63.0, 452.0, 89.0], "category_id": 2}, {"id": 12, "bbox": [558.0, 428.69, 88.0, 50.0], "category_id": 3}, {"id": 13, "bbox": [162.0, 442.69, 228.0, 91.0], "category_id": 3}, {"id": 14, "bbox": [218.0, 237.1, 286.7, 236.9], "category_id": 1}, {"id": 15, "bbox": [553.0, 230.1, 280.0, 243.9], "category_id": 1}, {"id": 16, "bbox": [874.9, 207.4, 330.4, 296.0], "category_id": 1}, {"id": 17, "bbox": [546.8, 550.0, 300.2, 313.0], "category_id": 1}], "reactions": [{"reactants": [0, 10], "conditions": [3, 11], "products": [2]}], "corefs": [[14, 13], [15, 12], [16, 4], [8, 5], [17, 6], [1, 9]], "caption": "Table 2. Cyclocarbopalladation/Suzuki\u2212Miyaura Coupling", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 411, 110], "ImageBB": [82, 116, 419, 377]}, "diagram_type": "single"}, {"id": 495, "width": 1348, "height": 1244, "file_name": "ol0600584-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [786.0, 15.0, 220.3, 135.0], "category_id": 1}, {"id": 1, "bbox": [568.7, 1.0, 201.3, 98.3], "category_id": 2}, {"id": 2, "bbox": [345.0, 16.0, 208.0, 133.0], "category_id": 1}, {"id": 3, "bbox": [10.0, 195.0, 1338.0, 1049.0], "category_id": 4}, {"id": 4, "bbox": [608.0, 109.0, 136.0, 42.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [1, 4], "products": [0]}], "corefs": [], "caption": "Table 1. Enantioselective Borane Reduction of Acetophenonea", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 500, 770, 514], "ImageBB": [439, 523, 776, 834]}, "diagram_type": "single"}, {"id": 94, "width": 1348, "height": 620, "file_name": "ja053368a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1105.08, 5.53, 228.7, 168.72], "category_id": 1}, {"id": 1, "bbox": [7.16, 205.8, 1336.74, 407.6], "category_id": 4}, {"id": 2, "bbox": [438.19, 113.29, 553.0, 39.61], "category_id": 2}, {"id": 3, "bbox": [15.29, 47.21, 93.5, 93.5], "category_id": 1}, {"id": 4, "bbox": [148.46, 42.13, 163.64, 97.56], "category_id": 1}, {"id": 5, "bbox": [337.55, 36.03, 754.28, 40.63], "category_id": 2}], "reactions": [{"reactants": [3, 4], "conditions": [5, 2], "products": [0]}], "corefs": [], "caption": "Table 1. DA Reaction of Cyclopentadiene with Methacroleina", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 470, 747, 483], "ImageBB": [439, 488, 776, 643]}, "diagram_type": "single"}, {"id": 577, "width": 1148, "height": 1892, "file_name": "acs.orglett.5b00663-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [251.6, 140.9, 26.9, 36.6], "category_id": 3}, {"id": 1, "bbox": [493.0, 103.0, 157.0, 40.0], "category_id": 2}, {"id": 2, "bbox": [878.0, 142.0, 28.0, 31.0], "category_id": 3}, {"id": 3, "bbox": [375.0, 10.0, 418.0, 78.0], "category_id": 2}, {"id": 4, "bbox": [0.0, 203.0, 1143.0, 1685.0], "category_id": 4}, {"id": 5, "bbox": [835.0, 17.0, 120.0, 103.0], "category_id": 1}, {"id": 6, "bbox": [185.0, 8.0, 154.0, 108.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 1], "products": [5]}], "corefs": [[6, 0], [5, 2]], "caption": "Table 2. Substrate Scope Screeninga", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 652, 109], "ImageBB": [474, 116, 761, 589]}, "diagram_type": "single"}, {"id": 1179, "width": 2808, "height": 1700, "file_name": "ol301852m-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1293.73, 886.38, 212.11, 74.46], "category_id": 2}, {"id": 1, "bbox": [1057.74, 171.38, 209.3, 74.45], "category_id": 2}, {"id": 2, "bbox": [1894.94, 1223.52, 119.4, 43.55], "category_id": 2}, {"id": 3, "bbox": [1893.54, 890.6, 136.25, 85.69], "category_id": 2}, {"id": 4, "bbox": [920.08, 1116.76, 417.2, 314.66], "category_id": 1}, {"id": 5, "bbox": [1354.13, 1223.52, 92.71, 43.55], "category_id": 2}, {"id": 6, "bbox": [793.66, 1272.69, 154.51, 78.66], "category_id": 2}, {"id": 7, "bbox": [823.16, 1224.92, 80.06, 42.15], "category_id": 2}, {"id": 8, "bbox": [622.28, 0.0, 501.48, 309.04], "category_id": 1}, {"id": 9, "bbox": [823.16, 629.32, 43.54, 40.74], "category_id": 3}, {"id": 10, "bbox": [1063.36, 502.89, 75.85, 42.15], "category_id": 2}, {"id": 11, "bbox": [1163.09, 365.23, 431.25, 304.83], "category_id": 1}, {"id": 12, "bbox": [1293.73, 1275.49, 214.92, 82.88], "category_id": 2}, {"id": 13, "bbox": [823.16, 840.03, 81.47, 43.54], "category_id": 2}, {"id": 14, "bbox": [1472.13, 726.25, 428.43, 309.04], "category_id": 1}, {"id": 15, "bbox": [823.16, 629.32, 43.54, 40.74], "category_id": 3}, {"id": 16, "bbox": [2201.17, 1168.74, 51.97, 46.35], "category_id": 3}, {"id": 17, "bbox": [1942.7, 632.13, 39.34, 47.76], "category_id": 3}, {"id": 18, "bbox": [1569.05, 557.68, 200.87, 75.85], "category_id": 2}, {"id": 19, "bbox": [581.55, 758.55, 42.14, 40.74], "category_id": 3}, {"id": 20, "bbox": [1678.62, 1397.71, 46.35, 49.16], "category_id": 3}, {"id": 21, "bbox": [920.08, 722.03, 412.98, 311.85], "category_id": 1}, {"id": 22, "bbox": [1764.31, 0.0, 373.65, 278.14], "category_id": 1}, {"id": 23, "bbox": [1472.13, 1125.19, 431.24, 313.25], "category_id": 1}, {"id": 24, "bbox": [1354.13, 838.62, 87.09, 44.95], "category_id": 2}, {"id": 25, "bbox": [1670.19, 995.95, 43.55, 46.36], "category_id": 3}, {"id": 26, "bbox": [1894.94, 844.24, 118.0, 39.33], "category_id": 2}, {"id": 27, "bbox": [2036.82, 932.74, 377.86, 273.92], "category_id": 1}, {"id": 28, "bbox": [1106.91, 1393.49, 53.37, 44.95], "category_id": 3}, {"id": 29, "bbox": [1894.94, 1272.69, 141.88, 84.28], "category_id": 2}, {"id": 30, "bbox": [481.81, 439.68, 184.02, 96.93], "category_id": 1}, {"id": 31, "bbox": [656.0, 380.68, 369.43, 272.52], "category_id": 1}, {"id": 32, "bbox": [1472.13, 726.25, 428.43, 311.85], "category_id": 1}, {"id": 33, "bbox": [1216.47, 0.0, 502.89, 311.85], "category_id": 1}, {"id": 34, "bbox": [1102.69, 986.12, 59.0, 47.76], "category_id": 3}, {"id": 35, "bbox": [577.33, 1165.93, 54.79, 49.16], "category_id": 3}, {"id": 36, "bbox": [793.66, 886.38, 154.51, 74.46], "category_id": 2}, {"id": 37, "bbox": [398.19, 61.27, 273.17, 93.18], "category_id": 1}, {"id": 38, "bbox": [1745.01, 374.68, 421.41, 292.24], "category_id": 1}, {"id": 39, "bbox": [1831.84, 321.74, 116.47, 38.12], "category_id": 2}, {"id": 40, "bbox": [1967.36, 323.86, 192.71, 33.88], "category_id": 2}, {"id": 41, "bbox": [1035.6, 563.15, 139.76, 63.53], "category_id": 2}, {"id": 42, "bbox": [1626.42, 508.09, 72.0, 33.89], "category_id": 2}, {"id": 43, "bbox": [1440.07, 247.62, 33.88, 44.47], "category_id": 3}, {"id": 44, "bbox": [1116.07, 116.33, 78.35, 42.35], "category_id": 2}, {"id": 45, "bbox": [1358.4, 631.4, 56.8, 42.2], "category_id": 3}, {"id": 46, "bbox": [842.2, 248.64, 54.7, 43.56], "category_id": 3}, {"id": 47, "bbox": [622.28, 838.62, 130.64, 76.08], "category_id": 2}, {"id": 48, "bbox": [419.4, 802.1, 186.03, 94.12], "category_id": 1}, {"id": 49, "bbox": [419.4, 925.72, 367.23, 272.51], "category_id": 1}, {"id": 50, "bbox": [481.81, 171.38, 144.69, 73.22], "category_id": 2}, {"id": 51, "bbox": [404.55, 330.11, 23.15, 47.09], "category_id": 3}, {"id": 52, "bbox": [1942.7, 245.83, 39.34, 44.95], "category_id": 3}, {"id": 53, "bbox": [481.81, 557.68, 144.69, 71.64], "category_id": 2}], "caption": "Scheme 2. Synthetic Routes of Butterfly-Shaped Fused Heteroacenes 1 6", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 463, 102], "ImageBB": [71, 113, 773, 538]}, "reactions": [{"reactants": [51, 37], "conditions": [50], "products": [8]}, {"reactants": [8], "conditions": [44, 1], "products": [33]}, {"reactants": [51, 30], "conditions": [53], "products": [31]}, {"reactants": [31], "conditions": [10, 41], "products": [11]}, {"reactants": [11], "conditions": [42, 18], "products": [38]}, {"reactants": [38], "conditions": [39, 40], "products": [22]}, {"reactants": [19, 48], "conditions": [47], "products": [49]}, {"reactants": [49], "conditions": [13, 36], "products": [21]}, {"reactants": [21], "conditions": [24, 0], "products": [32]}, {"reactants": [32], "conditions": [26, 3], "products": [27]}, {"reactants": [49], "conditions": [6, 7], "products": [4]}, {"reactants": [4], "conditions": [5, 12], "products": [23]}, {"reactants": [23], "conditions": [2, 29], "products": [27]}], "diagram_type": "graph"}, {"id": 1213, "width": 1352, "height": 1012, "file_name": "ol802297h-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [984.75, 795.87, 44.64, 53.42], "category_id": 3}, {"id": 1, "bbox": [331.41, 903.39, 41.93, 48.01], "category_id": 3}, {"id": 2, "bbox": [283.39, 250.19, 31.78, 43.28], "category_id": 3}, {"id": 3, "bbox": [820.4, 0.0, 436.91, 246.13], "category_id": 1}, {"id": 4, "bbox": [769.67, 499.7, 489.0, 303.61], "category_id": 1}, {"id": 5, "bbox": [331.41, 606.54, 44.63, 45.98], "category_id": 3}, {"id": 6, "bbox": [89.28, 0.0, 440.29, 254.92], "category_id": 1}, {"id": 7, "bbox": [186.67, 456.43, 236.04, 144.02], "category_id": 1}, {"id": 8, "bbox": [161.64, 692.42, 409.19, 216.38], "category_id": 1}, {"id": 9, "bbox": [988.13, 248.16, 38.55, 48.69], "category_id": 3}], "caption": "Scheme 1. 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Substrate with blocked s-trans configuration.", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 542, 728, 555], "ImageBB": [437, 112, 773, 529]}, "diagram_type": "tree"}, {"id": 1228, "width": 1008, "height": 636, "file_name": "op010073i-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [137.16, 204.24, 35.8, 42.86], "category_id": 3}, {"id": 1, "bbox": [777.56, 592.03, 32.77, 39.84], "category_id": 3}, {"id": 2, "bbox": [631.83, 232.48, 40.34, 42.36], "category_id": 3}, {"id": 3, "bbox": [0.0, 2.02, 304.57, 167.92], "category_id": 1}, {"id": 4, "bbox": [618.21, 327.28, 313.65, 232.98], "category_id": 1}, {"id": 5, "bbox": [196.66, 546.65, 34.79, 40.34], "category_id": 3}, {"id": 6, "bbox": [62.53, 400.91, 327.26, 89.26], "category_id": 1}, {"id": 7, "bbox": [518.37, 4.54, 324.74, 221.38], "category_id": 1}], "caption": "Scheme 2. 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Processes lovering reactivity of ethylmagnesium chloride 8 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 405, 81], "ImageBB": [112, 86, 372, 198]}, "reactions": [{"reactants": [1, 2], "conditions": [], "products": [0, 3]}, {"reactants": [6], "conditions": [], "products": [7]}, {"reactants": [6], "conditions": [], "products": [4, 8]}, {"reactants": [4], "conditions": [], "products": [5]}], "diagram_type": "tree"}, {"id": 525, "width": 1352, "height": 708, "file_name": "jo0109321-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [579.0, 4.0, 165.0, 107.0], "category_id": 2}, {"id": 1, "bbox": [7.0, 230.0, 1345.0, 478.0], "category_id": 4}, {"id": 2, "bbox": [1002.0, 17.0, 247.0, 42.0], "category_id": 2}, {"id": 3, "bbox": [1000.0, 82.8, 352.0, 49.2], "category_id": 2}, {"id": 4, "bbox": [5.1, 76.4, 526.9, 78.6], "category_id": 1}, {"id": 5, "bbox": [572.0, 136.0, 219.0, 36.0], "category_id": 2}, {"id": 6, "bbox": [993.0, 167.0, 332.0, 49.9], "category_id": 2}, {"id": 7, "bbox": [897.7, 56.0, 62.3, 46.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [0, 5, 7], "products": [2, 3, 6]}], "corefs": [], "caption": "Table 2. Effect of Catalyst on the Hydroboration of          1-Octene with BH3-THF in THFa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [455, 296, 758, 322], "ImageBB": [439, 330, 777, 507]}, "diagram_type": "single"}, {"id": 300, "width": 2808, "height": 1024, "file_name": "ol303482k-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1795.0, 523.0, 203.0, 107.0], "category_id": 2}, {"id": 1, "bbox": [1845.0, 432.0, 53.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [1688.0, 679.0, 691.0, 264.0], "category_id": 1}, {"id": 3, "bbox": [2123.0, 265.0, 268.0, 141.0], "category_id": 1}, {"id": 4, "bbox": [16.0, 162.0, 1310.0, 806.0], "category_id": 1}, {"id": 5, "bbox": [2082.0, 544.0, 560.0, 60.0], "category_id": 2}, {"id": 6, "bbox": [2235.0, 408.0, 51.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [2068.0, 824.0, 175.0, 98.0], "category_id": 3}, {"id": 8, "bbox": [1462.5, 114.0, 1072.5, 67.0], "category_id": 2}, {"id": 9, "bbox": [1625.0, 212.6, 462.0, 260.4], "category_id": 1}, {"id": 10, "bbox": [2088.4, 965.0, 441.6, 57.0], "category_id": 2}], "reactions": [{"reactants": [9, 3], "conditions": [0, 5], "products": [2]}], "corefs": [[9, 1], [3, 6], [2, 7]], "caption": "Figure 2. X-ray crystal structure of imide 15d.", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 314, 315, 327], "ImageBB": [71, 59, 773, 315]}, "diagram_type": "tree"}, {"id": 55, "width": 1176, "height": 1372, "file_name": "ja406383h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [909.29, 183.74, 24.35, 34.67], "category_id": 3}, {"id": 1, "bbox": [305.81, 180.3, 153.3, 41.55], "category_id": 2}, {"id": 2, "bbox": [87.46, 27.28, 177.37, 122.36], "category_id": 1}, {"id": 3, "bbox": [3.21, 262.83, 1165.97, 1107.51], "category_id": 4}, {"id": 4, "bbox": [328.16, 35.88, 129.23, 117.19], "category_id": 1}, {"id": 5, "bbox": [835.35, 30.72, 251.3, 158.46], "category_id": 1}, {"id": 6, "bbox": [493.21, 4.93, 294.28, 84.53], "category_id": 2}, {"id": 7, "bbox": [534.5, 113.25, 237.5, 125.75], "category_id": 2}, {"id": 8, "bbox": [145.92, 183.74, 26.07, 31.23], "category_id": 3}], "reactions": [{"reactants": [2, 4], "conditions": [6, 7], "products": [5]}], "corefs": [[2, 8], [5, 0]], "caption": "Table 3. Direct C\u2212H Amidation of Other Chelate Group- Containing Substratesa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 172, 410, 202], "ImageBB": [104, 208, 398, 551]}, "diagram_type": "single"}, {"id": 46, "width": 1232, "height": 560, "file_name": "ja410533y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [299.94, 197.65, 140.44, 131.14], "category_id": 1}, {"id": 1, "bbox": [49.08, 197.65, 145.08, 120.92], "category_id": 1}, {"id": 2, "bbox": [49.08, 4.39, 145.08, 121.86], "category_id": 1}, {"id": 3, "bbox": [325.03, 342.59, 41.95, 32.66], "category_id": 3}, {"id": 4, "bbox": [264.64, 384.4, 163.66, 37.3], "category_id": 2}, {"id": 5, "bbox": [1001.42, 341.66, 39.16, 32.66], "category_id": 3}, {"id": 6, "bbox": [515.5, 152.12, 285.37, 79.12], "category_id": 2}, {"id": 7, "bbox": [487.62, 258.04, 339.27, 206.4], "category_id": 2}, {"id": 8, "bbox": [21.21, 138.18, 201.76, 37.31], "category_id": 3}, {"id": 9, "bbox": [24.92, 325.86, 195.26, 36.38], "category_id": 3}, {"id": 10, "bbox": [3.56, 515.4, 237.99, 37.31], "category_id": 3}, {"id": 11, "bbox": [815.6, 384.4, 408.02, 122.78], "category_id": 2}, {"id": 12, "bbox": [909.44, 161.41, 198.97, 132.08], "category_id": 1}, {"id": 13, "bbox": [61.16, 386.26, 123.71, 119.99], "category_id": 1}], "reactions": [{"reactants": [2, 0], "conditions": [6, 7], "products": [12]}, {"reactants": [1, 0], "conditions": [6, 7], "products": [12]}, {"reactants": [13, 0], "conditions": [6, 7], "products": [12]}], "corefs": [[2, 8], [1, 9], [13, 10], [0, 3], [12, 5]], "caption": "Table 3. Redox Level-Independent Formation of Lactone 3fa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 417, 110], "ImageBB": [97, 116, 405, 256]}, "diagram_type": "single"}, {"id": 281, "width": 1344, "height": 872, "file_name": "ol800288b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [432.0, 0.0, 212.0, 48.0], "category_id": 2}, {"id": 1, "bbox": [330.0, 129.0, 453.0, 45.0], "category_id": 2}, {"id": 2, "bbox": [71.0, 20.0, 249.0, 67.0], "category_id": 1}, {"id": 3, "bbox": [809.0, 1.0, 464.0, 92.0], "category_id": 1}, {"id": 4, "bbox": [366.0, 68.0, 390.0, 52.0], "category_id": 2}, {"id": 5, "bbox": [12.0, 225.0, 1332.0, 647.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [0, 4, 1], "products": [3]}], "corefs": [], "caption": "Table 2. Aziridination of 1-Hexene Catalyzed by Various Copper-carbene Complexesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 426, 379, 454], "ImageBB": [74, 459, 410, 677]}, "diagram_type": "single"}, {"id": 650, "width": 1352, "height": 696, "file_name": "ol500121z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [903.0, 477.0, 74.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [195.0, 350.0, 55.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [495.0, 163.0, 186.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [808.0, 344.0, 456.0, 107.0], "category_id": 1}, {"id": 4, "bbox": [811.0, 5.0, 386.0, 183.0], "category_id": 1}, {"id": 5, "bbox": [896.0, 191.0, 71.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [84.0, 176.0, 287.0, 110.0], "category_id": 1}, {"id": 7, "bbox": [2.0, 541.0, 1350.0, 155.0], "category_id": 4}, {"id": 8, "bbox": [412.0, 235.0, 351.1, 139.5], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [2, 8], "products": [4, 3]}], "corefs": [[6, 1], [4, 5], [3, 0]], "caption": "Table 1. Palladium Catalysts for the Alkylation of 1a with 2aa ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 533, 775, 563], "ImageBB": [449, 569, 787, 743]}, "diagram_type": "single"}, {"id": 1178, "width": 1344, "height": 732, "file_name": "ol301114z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [20.84, 14.79, 266.25, 233.31], "category_id": 1}, {"id": 1, "bbox": [406.09, 88.75, 155.31, 111.61], "category_id": 1}, {"id": 2, "bbox": [115.64, 455.85, 424.25, 226.58], "category_id": 1}, {"id": 3, "bbox": [984.97, 39.67, 322.72, 223.22], "category_id": 1}, {"id": 4, "bbox": [726.8, 164.05, 78.66, 49.08], "category_id": 2}, {"id": 5, "bbox": [896.22, 455.18, 423.58, 226.58], "category_id": 1}, {"id": 6, "bbox": [327.43, 299.19, 161.36, 93.46], "category_id": 2}, {"id": 7, "bbox": [936.56, 303.23, 155.99, 92.11], "category_id": 2}, {"id": 8, "bbox": [679.73, 0.0, 151.28, 135.81], "category_id": 1}], "caption": "Scheme 1. Proposed Annulation of 2,3-Disubstituted Indole with MVK Catalyzed by Chiral Primary Amine ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 756, 116], "ImageBB": [437, 127, 773, 310]}, "reactions": [{"reactants": [0, 1], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [], "products": [5]}, {"reactants": [0, 1, 8], "conditions": [4], "products": [3]}, {"reactants": [5], "conditions": [7], "products": [3]}], "diagram_type": "graph"}, {"id": 310, "width": 1252, "height": 1592, "file_name": "ol302668y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [609.9, 190.0, 325.1, 92.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 106.3, 272.0, 108.7], "category_id": 1}, {"id": 2, "bbox": [306.2, 107.4, 317.8, 110.6], "category_id": 1}, {"id": 3, "bbox": [383.91, 217.53, 184.64, 53.34], "category_id": 2}, {"id": 4, "bbox": [19.0, 430.0, 1233.0, 1162.0], "category_id": 4}, {"id": 5, "bbox": [1025.0, 253.0, 58.0, 64.0], "category_id": 3}, {"id": 6, "bbox": [443.1, 280.7, 63.2, 46.9], "category_id": 3}, {"id": 7, "bbox": [607.7, 0.0, 327.3, 167.3], "category_id": 2}, {"id": 8, "bbox": [83.0, 218.0, 72.0, 55.0], "category_id": 3}, {"id": 9, "bbox": [941.0, 34.0, 311.0, 277.0], "category_id": 1}], "reactions": [{"reactants": [1, 2], "conditions": [7, 0], "products": [9]}], "corefs": [[1, 8], [2, 6], [9, 5]], "caption": "Table 1. Synthesis of the Various 5-Substituents of 2-(4-Cyanopheyl)-1,3a,6a-triazapentalenes ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 549, 340, 576], "ImageBB": [83, 587, 396, 985]}, "diagram_type": "single"}, {"id": 972, "width": 1192, "height": 912, "file_name": "ja040054z-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [683.95, 513.95, 475.85, 329.12], "category_id": 1}, {"id": 1, "bbox": [496.72, 199.14, 125.22, 50.68], "category_id": 2}, {"id": 2, "bbox": [648.18, 0.0, 516.39, 334.48], "category_id": 1}, {"id": 3, "bbox": [0.0, 0.0, 500.29, 335.68], "category_id": 1}, {"id": 4, "bbox": [104.35, 418.55, 136.75, 55.45], "category_id": 2}, {"id": 5, "bbox": [277.45, 423.72, 91.97, 48.18], "category_id": 2}, {"id": 6, "bbox": [778.89, 427.01, 93.06, 49.26], "category_id": 2}, {"id": 7, "bbox": [32.2, 518.2, 468.09, 327.85], "category_id": 1}, {"id": 8, "bbox": [521.16, 606.96, 115.09, 55.45], "category_id": 2}, {"id": 9, "bbox": [239.12, 350.58, 45.31, 50.68], "category_id": 3}, {"id": 10, "bbox": [229.57, 857.97, 51.88, 54.03], "category_id": 3}, {"id": 11, "bbox": [872.38, 347.0, 71.56, 50.68], "category_id": 3}, {"id": 12, "bbox": [921.88, 425.3, 258.12, 52.1], "category_id": 2}], "caption": "Scheme 6", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 125, 76], "ImageBB": [93, 80, 391, 308]}, "reactions": [{"reactants": [3], "conditions": [1], "products": [2]}, {"reactants": [3], "conditions": [4, 5], "products": [7]}, {"reactants": [7], "conditions": [8], "products": [0]}, {"reactants": [0], "conditions": [6, 12], "products": [2]}], "diagram_type": "graph"}, {"id": 370, "width": 1348, "height": 1220, "file_name": "ol102738b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [665.83, 63.84, 178.25, 44.15], "category_id": 2}, {"id": 1, "bbox": [7.0, 273.0, 1341.0, 947.0], "category_id": 4}, {"id": 2, "bbox": [178.64, 180.73, 65.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [396.3, 21.9, 255.1, 124.6], "category_id": 1}, {"id": 4, "bbox": [142.3, 19.5, 207.7, 157.2], "category_id": 1}, {"id": 5, "bbox": [485.63, 170.0, 72.0, 51.0], "category_id": 3}, {"id": 6, "bbox": [667.46, 119.44, 168.45, 44.16], "category_id": 2}, {"id": 7, "bbox": [871.0, 0.0, 339.0, 232.0], "category_id": 1}, {"id": 8, "bbox": [911.0, 178.0, 68.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [4, 3], "conditions": [0, 6], "products": [7]}], "corefs": [[4, 2], [3, 5], [7, 8]], "caption": "Table 1. Optimization of Conditions on the Model Reactiona", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 762, 101], "ImageBB": [436, 112, 773, 417]}, "diagram_type": "single"}, {"id": 233, "width": 2508, "height": 1716, "file_name": "op000111i-Figure-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [794.5, 612.5, 288.5, 272.8], "category_id": 1}, {"id": 1, "bbox": [314.0, 932.1, 755.8, 103.9], "category_id": 2}, {"id": 2, "bbox": [290.1, 637.9, 261.6, 245.2], "category_id": 1}, {"id": 3, "bbox": [1176.6, 659.4, 642.2, 723.8], "category_id": 1}, {"id": 4, "bbox": [226.0, 1092.0, 535.1, 247.1], "category_id": 2}, {"id": 5, "bbox": [571.0, 671.3, 215.9, 75.7], "category_id": 2}, {"id": 6, "bbox": [524.0, 385.0, 636.0, 177.0], "category_id": 2}, {"id": 7, "bbox": [892.0, 1636.0, 893.0, 80.0], "category_id": 2}, {"id": 8, "bbox": [1309.38, 1134.46, 68.55, 84.04], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5], "products": [0]}], "corefs": [[3, 8]], "caption": "Figure 10. Continuous reduction of tetralone, applying polysiloxane-bound oxazaborolidine as catalyst.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 495, 642, 509], "ImageBB": [112, 55, 739, 484]}, "diagram_type": "single"}, {"id": 304, "width": 1344, "height": 1608, "file_name": "ol303154k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [372.0, 279.0, 49.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [332.0, 598.0, 53.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [25.2, 350.3, 226.5, 217.6], "category_id": 1}, {"id": 3, "bbox": [909.0, 273.5, 417.7, 349.5], "category_id": 1}, {"id": 4, "bbox": [459.2, 357.7, 183.7, 172.0], "category_id": 1}, {"id": 5, "bbox": [296.4, 0.0, 334.5, 281.9], "category_id": 1}, {"id": 6, "bbox": [302.2, 344.1, 124.7, 235.8], "category_id": 1}, {"id": 7, "bbox": [504.0, 598.0, 54.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [1101.0, 605.0, 95.0, 50.0], "category_id": 3}, {"id": 9, "bbox": [702.0, 420.0, 186.0, 56.0], "category_id": 2}, {"id": 10, "bbox": [642.0, 490.0, 321.0, 65.0], "category_id": 2}, {"id": 11, "bbox": [0.0, 672.0, 1344.0, 936.0], "category_id": 4}, {"id": 12, "bbox": [132.0, 602.0, 52.0, 44.0], "category_id": 3}, {"id": 13, "bbox": [649.0, 64.0, 391.0, 231.8], "category_id": 3}], "reactions": [{"reactants": [2, 6, 4], "conditions": [9, 10], "products": [3]}], "corefs": [[5, 0], [5, 13], [2, 12], [6, 1], [4, 7], [3, 8]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 322, 101], "ImageBB": [71, 112, 407, 514]}, "diagram_type": "single"}, {"id": 1157, "width": 1352, "height": 552, "file_name": "ol0514606-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [20.97, 0.0, 431.5, 154.95], "category_id": 1}, {"id": 1, "bbox": [93.33, 304.49, 433.54, 153.6], "category_id": 1}, {"id": 2, "bbox": [915.76, 157.66, 29.08, 38.57], "category_id": 3}, {"id": 3, "bbox": [1034.8, 438.46, 27.73, 36.54], "category_id": 3}, {"id": 4, "bbox": [280.68, 454.03, 29.08, 37.89], "category_id": 3}, {"id": 5, "bbox": [785.9, 252.39, 448.42, 182.69], "category_id": 1}, {"id": 6, "bbox": [538.37, 418.84, 232.66, 51.42], "category_id": 2}, {"id": 7, "bbox": [657.4, 8.8, 432.18, 124.5], "category_id": 1}, {"id": 8, "bbox": [1104.46, 98.79, 211.02, 46.69], "category_id": 2}, {"id": 9, "bbox": [1104.46, 10.83, 220.49, 49.39], "category_id": 2}, {"id": 10, "bbox": [438.27, 54.81, 190.72, 46.69], "category_id": 2}, {"id": 11, "bbox": [253.63, 163.07, 54.1, 41.95], "category_id": 3}, {"id": 12, "bbox": [539.72, 331.55, 204.25, 52.78], "category_id": 2}, {"id": 13, "bbox": [434.21, 142.77, 189.37, 85.26], "category_id": 2}], "caption": "Scheme 5", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 712, 631, 725], "ImageBB": [439, 730, 777, 868]}, "reactions": [{"reactants": [0], "conditions": [10, 13], "products": [7]}, {"reactants": [7], "conditions": [9, 8], "products": [1]}, {"reactants": [1], "conditions": [12, 6], "products": [5]}], "diagram_type": "multiple"}, {"id": 1101, "width": 1324, "height": 1256, "file_name": "jo9708497-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 0.0, 388.79, 218.49], "category_id": 1}, {"id": 1, "bbox": [87.43, 1021.6, 443.1, 115.21], "category_id": 2}, {"id": 2, "bbox": [42.39, 472.73, 105.97, 53.63], "category_id": 2}, {"id": 3, "bbox": [774.93, 1205.0, 62.26, 50.32], "category_id": 3}, {"id": 4, "bbox": [170.88, 236.37, 41.73, 48.99], "category_id": 3}, {"id": 5, "bbox": [1074.3, 843.5, 249.7, 98.65], "category_id": 3}, {"id": 6, "bbox": [201.35, 843.5, 208.63, 99.98], "category_id": 3}, {"id": 7, "bbox": [466.28, 664.74, 456.35, 109.9], "category_id": 2}, {"id": 8, "bbox": [184.79, 346.93, 443.1, 213.86], "category_id": 1}, {"id": 9, "bbox": [11.92, 409.83, 141.08, 49.0], "category_id": 2}, {"id": 10, "bbox": [779.56, 8.61, 439.13, 218.49], "category_id": 1}, {"id": 11, "bbox": [586.16, 973.27, 392.77, 227.1], "category_id": 1}, {"id": 12, "bbox": [923.95, 612.43, 400.05, 225.77], "category_id": 1}, {"id": 13, "bbox": [747.77, 385.34, 416.61, 113.21], "category_id": 2}, {"id": 14, "bbox": [408.66, 554.17, 48.35, 50.98], "category_id": 3}, {"id": 15, "bbox": [530.53, 172.14, 92.72, 52.97], "category_id": 2}, {"id": 16, "bbox": [466.94, 30.46, 272.22, 115.2], "category_id": 2}, {"id": 17, "bbox": [1015.35, 241.0, 49.02, 50.32], "category_id": 3}, {"id": 18, "bbox": [0.0, 619.72, 441.77, 219.15], "category_id": 1}], "caption": "Scheme 1. Synthesis of Azido Triflate 14", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [470, 49, 741, 63], "ImageBB": [442, 69, 773, 383]}, "reactions": [{"reactants": [0], "conditions": [16, 15], "products": [10]}, {"reactants": [10], "conditions": [9, 2], "products": [8]}, {"reactants": [8], "conditions": [13], "products": [18]}, {"reactants": [18], "conditions": [7], "products": [12]}, {"reactants": [12], "conditions": [1], "products": [11]}], "diagram_type": "multiple"}, {"id": 290, "width": 1348, "height": 1000, "file_name": "ol401042b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.0, 191.6, 156.4, 70.6], "category_id": 1}, {"id": 1, "bbox": [95.0, 330.0, 191.3, 47.8], "category_id": 2}, {"id": 2, "bbox": [640.0, 176.9, 261.0, 56.1], "category_id": 2}, {"id": 3, "bbox": [907.0, 74.6, 417.7, 215.1], "category_id": 1}, {"id": 4, "bbox": [675.4, 250.2, 143.7, 54.4], "category_id": 2}, {"id": 5, "bbox": [27.1, 1.0, 329.8, 309.2], "category_id": 1}, {"id": 6, "bbox": [480.0, 282.0, 77.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [3.0, 417.0, 1345.0, 581.0], "category_id": 4}, {"id": 8, "bbox": [1076.0, 276.0, 86.0, 51.0], "category_id": 3}, {"id": 9, "bbox": [158.0, 279.0, 65.0, 46.0], "category_id": 3}, {"id": 10, "bbox": [461.0, 333.0, 123.0, 48.0], "category_id": 2}], "reactions": [{"reactants": [5, 0], "conditions": [2, 4], "products": [3]}], "corefs": [[5, 9], [0, 6], [3, 8]], "caption": "Table 2. Scope of Aldehydes for Organocatalytic Annulationa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 579, 766, 595], "ImageBB": [436, 606, 773, 856]}, "diagram_type": "single"}, {"id": 756, "width": 1348, "height": 1044, "file_name": "jo990528q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [212.0, 2.0, 237.2, 144.0], "category_id": 1}, {"id": 1, "bbox": [810.0, 362.2, 354.0, 190.2], "category_id": 1}, {"id": 2, "bbox": [293.6, 136.4, 26.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [914.4, 532.0, 102.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [493.2, 344.0, 244.8, 109.8], "category_id": 1}, {"id": 5, "bbox": [212.8, 390.2, 180.2, 145.2], "category_id": 1}, {"id": 6, "bbox": [568.0, 483.0, 119.0, 56.0], "category_id": 2}, {"id": 7, "bbox": [696.0, 351.0, 89.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [282.0, 537.0, 37.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [319.0, 200.0, 203.0, 144.0], "category_id": 2}, {"id": 10, "bbox": [21.0, 620.0, 1327.0, 419.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [4, 6], "products": [1]}], "corefs": [[0, 2], [5, 8], [4, 7], [1, 3]], "caption": "Table 1. Reaction of 2 with r,\u03b2-Unsaturated thioester                         3a-e ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [449, 353, 765, 380], "ImageBB": [439, 390, 776, 651]}, "diagram_type": "tree"}, {"id": 721, "width": 1324, "height": 1152, "file_name": "ol0173127-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [9.0, 506.0, 1315.0, 646.0], "category_id": 4}, {"id": 1, "bbox": [383.0, 47.0, 294.0, 98.0], "category_id": 1}, {"id": 2, "bbox": [806.0, 199.0, 469.0, 293.0], "category_id": 1}, {"id": 3, "bbox": [361.0, 152.0, 370.0, 198.0], "category_id": 2}, {"id": 4, "bbox": [47.0, 1.0, 240.0, 198.0], "category_id": 1}, {"id": 5, "bbox": [368.0, 364.0, 376.0, 105.0], "category_id": 2}], "reactions": [{"reactants": [4, 1], "conditions": [3, 5], "products": [2]}], "corefs": [], "caption": "Table 3. Friedel-Crafts Alkylation of Indol Derivatives in a CO2/1a System ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 395, 104], "ImageBB": [77, 111, 408, 399]}, "diagram_type": "multiple"}, {"id": 222, "width": 1184, "height": 3316, "file_name": "op0255478-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.0, 79.0, 274.0, 121.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 275.5, 1175.0, 3040.5], "category_id": 4}, {"id": 2, "bbox": [715.0, 151.0, 76.0, 57.0], "category_id": 2}, {"id": 3, "bbox": [300.6, 130.0, 155.4, 43.6], "category_id": 1}, {"id": 4, "bbox": [651.0, 94.0, 239.0, 55.0], "category_id": 2}, {"id": 5, "bbox": [886.0, 13.0, 295.0, 240.0], "category_id": 1}, {"id": 6, "bbox": [482.0, 79.0, 197.0, 132.0], "category_id": 1}], "reactions": [{"reactants": [0, 3, 6], "conditions": [4, 2], "products": [5]}], "corefs": [], "caption": "Table 1. Synthesis of dihydropyrimidinones without any solvent and catalyst ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 383, 81], "ImageBB": [95, 88, 391, 917]}, "diagram_type": "single"}, {"id": 862, "width": 1356, "height": 2208, "file_name": "jo2003264-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1218.0, 179.0, 42.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [77.0, 175.0, 38.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [461.0, 140.0, 287.0, 98.5], "category_id": 2}, {"id": 3, "bbox": [385.0, 0.0, 761.0, 120.1], "category_id": 2}, {"id": 4, "bbox": [248.0, 108.0, 159.0, 58.0], "category_id": 2}, {"id": 5, "bbox": [1158.2, 48.0, 197.8, 131.0], "category_id": 1}, {"id": 6, "bbox": [290.0, 179.0, 47.0, 51.0], "category_id": 3}, {"id": 7, "bbox": [30.0, 291.0, 1326.0, 1917.0], "category_id": 4}, {"id": 8, "bbox": [7.0, 97.59, 201.0, 65.8], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [3, 2], "products": [5]}], "corefs": [[8, 1], [4, 6], [5, 0]], "caption": "Table 3. Oxidative Methyl Esteri\ufb01cation of Primary Alcohols (1) with 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 122], "ImageBB": [69, 133, 408, 685]}, "diagram_type": "single"}, {"id": 1065, "width": 1356, "height": 808, "file_name": "jo300771f-Scheme-c12.png", "license": 0, "bboxes": [{"id": 0, "bbox": [562.41, 1.6, 195.32, 46.02], "category_id": 1}, {"id": 1, "bbox": [214.71, 343.15, 160.56, 45.0], "category_id": 1}, {"id": 2, "bbox": [665.69, 720.5, 201.46, 38.86], "category_id": 3}, {"id": 3, "bbox": [185.86, 553.73, 223.86, 54.97], "category_id": 2}, {"id": 4, "bbox": [666.13, 668.41, 233.37, 46.89], "category_id": 3}, {"id": 5, "bbox": [531.82, 59.3, 253.7, 89.99], "category_id": 2}, {"id": 6, "bbox": [163.48, 394.5, 264.55, 142.27], "category_id": 2}, {"id": 7, "bbox": [434.14, 667.06, 138.38, 98.39], "category_id": 2}, {"id": 8, "bbox": [609.83, 169.65, 101.75, 54.29], "category_id": 2}, {"id": 9, "bbox": [286.26, 251.08, 59.69, 46.82], "category_id": 3}, {"id": 10, "bbox": [1015.47, 249.04, 63.77, 49.54], "category_id": 3}, {"id": 11, "bbox": [879.81, 34.61, 337.81, 202.22], "category_id": 1}, {"id": 12, "bbox": [530.46, 352.87, 284.23, 293.15], "category_id": 1}, {"id": 13, "bbox": [246.92, 48.86, 187.22, 177.79], "category_id": 1}], "caption": "Scheme 12. Preparation of 12b", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 415, 625, 430], "ImageBB": [448, 436, 787, 638]}, "reactions": [{"reactants": [13], "conditions": [0, 5, 8], "products": [11]}, {"reactants": [11], "conditions": [1, 6, 3], "products": [12]}, {"reactants": [4], "conditions": [7], "products": [2]}], "diagram_type": "multiple"}, {"id": 122, "width": 1220, "height": 1384, "file_name": "op970113b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [783.0, 97.0, 333.0, 114.0], "category_id": 2}, {"id": 1, "bbox": [812.0, 648.0, 324.4, 79.7], "category_id": 2}, {"id": 2, "bbox": [0.0, 0.0, 647.1, 287.3], "category_id": 1}, {"id": 3, "bbox": [0.0, 435.1, 584.4, 312.6], "category_id": 1}, {"id": 4, "bbox": [16.1, 957.5, 588.7, 300.8], "category_id": 1}, {"id": 5, "bbox": [187.0, 765.0, 170.0, 80.7], "category_id": 2}, {"id": 6, "bbox": [174.0, 1314.0, 168.0, 70.0], "category_id": 2}, {"id": 7, "bbox": [818.0, 547.0, 179.0, 77.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [7, 1], "products": [4]}], "corefs": [], "caption": "Table 1. Scale-up of benzoyl migration method and comparison to original Sharpless methoda,b ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 427, 361, 455], "ImageBB": [112, 69, 417, 415]}, "diagram_type": "multiple"}, {"id": 1057, "width": 1344, "height": 1140, "file_name": "jo200666z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [459.88, 500.74, 284.4, 86.71], "category_id": 2}, {"id": 1, "bbox": [512.32, 807.91, 130.43, 49.07], "category_id": 2}, {"id": 2, "bbox": [976.23, 284.32, 177.5, 49.73], "category_id": 2}, {"id": 3, "bbox": [941.27, 1047.19, 140.52, 47.73], "category_id": 3}, {"id": 4, "bbox": [924.46, 288.35, 41.01, 41.0], "category_id": 3}, {"id": 5, "bbox": [732.85, 667.43, 535.85, 379.09], "category_id": 1}, {"id": 6, "bbox": [83.37, 343.46, 290.45, 270.2], "category_id": 1}, {"id": 7, "bbox": [168.76, 591.48, 55.8, 44.36], "category_id": 3}, {"id": 8, "bbox": [839.75, 373.71, 307.93, 229.2], "category_id": 1}, {"id": 9, "bbox": [810.84, 34.28, 379.2, 210.38], "category_id": 1}, {"id": 10, "bbox": [508.96, 431.51, 141.19, 50.41], "category_id": 2}, {"id": 11, "bbox": [169.43, 290.36, 43.03, 42.35], "category_id": 3}, {"id": 12, "bbox": [459.88, 196.26, 245.4, 51.76], "category_id": 2}, {"id": 13, "bbox": [87.4, 674.16, 385.25, 352.2], "category_id": 1}, {"id": 14, "bbox": [459.88, 868.4, 289.1, 46.38], "category_id": 2}, {"id": 15, "bbox": [459.88, 83.35, 287.09, 93.42], "category_id": 2}, {"id": 16, "bbox": [171.45, 1004.18, 50.42, 47.05], "category_id": 3}, {"id": 17, "bbox": [83.37, 4.03, 328.1, 345.48], "category_id": 1}, {"id": 18, "bbox": [923.12, 600.89, 224.56, 47.05], "category_id": 3}], "caption": "Scheme 1. Removing the Directing Group", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 308, 107], "ImageBB": [71, 117, 407, 402]}, "reactions": [{"reactants": [17], "conditions": [15, 12], "products": [9]}, {"reactants": [6], "conditions": [10, 0], "products": [8]}, {"reactants": [13], "conditions": [1, 14], "products": [5]}], "diagram_type": "multiple"}, {"id": 935, "width": 1356, "height": 616, "file_name": "acs.orglett.5b00663-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1104.4, 276.79, 92.03, 29.65], "category_id": 2}, {"id": 1, "bbox": [341.88, 410.09, 162.02, 50.84], "category_id": 1}, {"id": 2, "bbox": [508.21, 423.02, 94.08, 35.79], "category_id": 2}, {"id": 3, "bbox": [613.54, 208.27, 261.79, 128.85], "category_id": 1}, {"id": 4, "bbox": [589.48, 14.91, 266.58, 130.83], "category_id": 1}, {"id": 5, "bbox": [904.9, 205.38, 169.59, 133.54], "category_id": 1}, {"id": 6, "bbox": [980.2, 338.24, 33.24, 33.21], "category_id": 3}, {"id": 7, "bbox": [1096.2, 84.05, 99.03, 40.67], "category_id": 2}, {"id": 8, "bbox": [157.37, 530.75, 39.35, 31.18], "category_id": 3}, {"id": 9, "bbox": [1120.62, 328.75, 65.12, 36.6], "category_id": 2}, {"id": 10, "bbox": [652.56, 336.89, 104.47, 38.63], "category_id": 3}, {"id": 11, "bbox": [341.88, 290.11, 240.81, 73.21], "category_id": 2}, {"id": 12, "bbox": [77.33, 437.21, 235.38, 84.72], "category_id": 1}, {"id": 13, "bbox": [890.66, 68.46, 167.55, 56.26], "category_id": 1}, {"id": 14, "bbox": [674.95, 140.31, 45.45, 31.18], "category_id": 3}, {"id": 15, "bbox": [636.28, 399.25, 259.13, 128.11], "category_id": 1}, {"id": 16, "bbox": [674.95, 530.07, 99.71, 32.53], "category_id": 3}, {"id": 17, "bbox": [379.19, 199.96, 139.74, 84.05], "category_id": 1}, {"id": 18, "bbox": [951.71, 414.84, 200.79, 98.28], "category_id": 1}, {"id": 19, "bbox": [1040.57, 534.14, 66.48, 35.24], "category_id": 2}, {"id": 20, "bbox": [324.92, 471.1, 308.65, 71.17], "category_id": 2}, {"id": 21, "bbox": [341.88, 4.07, 198.08, 93.54], "category_id": 1}, {"id": 22, "bbox": [324.92, 102.35, 239.46, 67.79], "category_id": 2}, {"id": 23, "bbox": [75.97, 47.45, 236.74, 86.76], "category_id": 1}, {"id": 24, "bbox": [75.97, 240.63, 236.07, 86.77], "category_id": 1}, {"id": 25, "bbox": [157.37, 335.53, 40.71, 31.86], "category_id": 3}, {"id": 26, "bbox": [157.37, 137.6, 38.67, 31.86], "category_id": 3}], "caption": "Scheme 2. Investigations of the Role of Ester", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 699, 110], "ImageBB": [448, 116, 787, 270]}, "reactions": [{"reactants": [23], "conditions": [21, 22], "products": [4, 13, 7]}, {"reactants": [24], "conditions": [17, 11], "products": [3, 5, 0]}, {"reactants": [12], "conditions": [1, 2, 20], "products": [15, 18]}], "diagram_type": "multiple"}, {"id": 640, "width": 1332, "height": 2248, "file_name": "ol501019y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [224.0, 127.0, 42.8, 41.9], "category_id": 3}, {"id": 1, "bbox": [783.4, 0.0, 377.6, 120.1], "category_id": 1}, {"id": 2, "bbox": [171.7, 2.9, 182.3, 124.1], "category_id": 1}, {"id": 3, "bbox": [411.0, 77.0, 290.0, 91.0], "category_id": 2}, {"id": 4, "bbox": [375.0, 15.0, 368.0, 50.0], "category_id": 2}, {"id": 5, "bbox": [3.0, 189.0, 1329.0, 2059.0], "category_id": 4}, {"id": 6, "bbox": [950.0, 117.0, 48.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4, 3], "products": [1]}], "corefs": [[2, 0], [1, 6]], "caption": "Table 2. Palladium-Catalyzed Homocoupling of 2- Substituted Furansa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 248, 366, 278], "ImageBB": [84, 285, 417, 847]}, "diagram_type": "single"}, {"id": 874, "width": 1344, "height": 608, "file_name": "ol701624y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [845.0, 46.0, 400.0, 201.9], "category_id": 1}, {"id": 1, "bbox": [212.71, 171.85, 104.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [4.0, 313.0, 1340.0, 295.0], "category_id": 4}, {"id": 3, "bbox": [1039.0, 254.0, 94.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [503.0, 0.0, 275.0, 105.0], "category_id": 2}, {"id": 5, "bbox": [506.0, 126.9, 291.0, 119.9], "category_id": 2}, {"id": 6, "bbox": [102.3, 37.6, 363.2, 124.3], "category_id": 1}, {"id": 7, "bbox": [845.37, 192.42, 140.75, 55.79], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [4, 5], "products": [0]}], "corefs": [[6, 1], [0, 3]], "caption": "Table 4.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 362, 120, 375], "ImageBB": [74, 378, 410, 530]}, "diagram_type": "single"}, {"id": 1204, "width": 1352, "height": 756, "file_name": "ol7019636-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [813.63, 186.76, 271.22, 250.37], "category_id": 1}, {"id": 1, "bbox": [516.05, 81.2, 225.22, 87.97], "category_id": 2}, {"id": 2, "bbox": [514.02, 0.0, 214.4, 55.49], "category_id": 2}, {"id": 3, "bbox": [261.74, 426.31, 165.03, 47.37], "category_id": 2}, {"id": 4, "bbox": [276.62, 241.57, 237.4, 149.55], "category_id": 1}, {"id": 5, "bbox": [541.75, 523.75, 120.39, 45.34], "category_id": 2}, {"id": 6, "bbox": [813.63, 442.55, 190.73, 43.98], "category_id": 2}, {"id": 7, "bbox": [511.99, 653.67, 92.66, 46.02], "category_id": 2}], "caption": "Scheme 1. PROLI/NO, a Nitric Oxide Donor", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [484, 811, 730, 824], "ImageBB": [439, 828, 777, 1017]}, "reactions": [{"reactants": [4], "conditions": [2, 1], "products": [0]}, {"reactants": [0], "conditions": [6, 5], "products": [3, 4, 7]}], "diagram_type": "graph"}, {"id": 1305, "width": 1356, "height": 816, "file_name": "op300059b-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [246.24, 211.68, 168.9, 160.12], "category_id": 1}, {"id": 1, "bbox": [177.05, 609.27, 121.42, 46.14], "category_id": 2}, {"id": 2, "bbox": [32.56, 459.33, 37.31, 40.71], "category_id": 3}, {"id": 3, "bbox": [362.91, 6.11, 143.13, 48.85], "category_id": 2}, {"id": 4, "bbox": [391.4, 113.98, 134.99, 50.21], "category_id": 2}, {"id": 5, "bbox": [158.73, 6.78, 151.95, 43.43], "category_id": 2}, {"id": 6, "bbox": [423.96, 323.63, 33.92, 44.1], "category_id": 3}, {"id": 7, "bbox": [1187.09, 696.79, 34.6, 40.03], "category_id": 3}, {"id": 8, "bbox": [4.07, 324.99, 172.98, 126.2], "category_id": 1}, {"id": 9, "bbox": [1122.65, 176.4, 233.35, 150.62], "category_id": 1}, {"id": 10, "bbox": [417.25, 529.98, 229.24, 177.71], "category_id": 1}, {"id": 11, "bbox": [747.53, 464.08, 37.99, 42.06], "category_id": 3}, {"id": 12, "bbox": [1126.72, 533.28, 223.17, 171.65], "category_id": 1}, {"id": 13, "bbox": [1183.7, 328.38, 34.6, 41.39], "category_id": 3}, {"id": 14, "bbox": [518.25, 731.39, 33.92, 40.71], "category_id": 3}, {"id": 15, "bbox": [569.13, 274.78, 337.13, 180.48], "category_id": 1}], "caption": "Scheme 2. Reaction mechanism for the formation of 2 and 8", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 689, 784, 704], "ImageBB": [448, 710, 787, 914]}, "reactions": [{"reactants": [5, 3], "conditions": [], "products": [4, 0]}, {"reactants": [8, 0], "conditions": [6], "products": [15]}, {"reactants": [15], "conditions": [], "products": [9]}, {"reactants": [15], "conditions": [], "products": [12]}, {"reactants": [8, 1], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [12]}], "diagram_type": "graph"}, {"id": 278, "width": 1348, "height": 1008, "file_name": "ol800527p-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [997.0, 144.0, 333.0, 238.0], "category_id": 1}, {"id": 1, "bbox": [412.0, 213.0, 141.0, 41.0], "category_id": 2}, {"id": 2, "bbox": [372.0, 294.0, 219.0, 91.0], "category_id": 2}, {"id": 3, "bbox": [765.0, 316.0, 54.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [159.0, 321.0, 51.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [14.0, 145.0, 335.0, 162.3], "category_id": 1}, {"id": 6, "bbox": [503.85, 140.27, 58.46, 54.56], "category_id": 3}, {"id": 7, "bbox": [0.0, 419.0, 1348.0, 531.0], "category_id": 4}, {"id": 8, "bbox": [1073.0, 311.0, 54.0, 47.0], "category_id": 3}, {"id": 9, "bbox": [312.0, 3.0, 338.0, 203.0], "category_id": 1}, {"id": 10, "bbox": [625.0, 92.0, 330.0, 216.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [9, 1, 2], "products": [10, 0]}], "corefs": [[5, 4], [9, 6], [10, 3], [0, 8]], "caption": "Table 1. Regioselectivity of the Introduction of a Cyanomethyl Group ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 345, 752, 372], "ImageBB": [425, 381, 762, 633]}, "diagram_type": "single"}, {"id": 465, "width": 1344, "height": 968, "file_name": "op100335q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [986.0, 599.0, 176.0, 271.0], "category_id": 1}, {"id": 1, "bbox": [559.0, 578.0, 262.0, 276.0], "category_id": 1}, {"id": 2, "bbox": [90.0, 573.0, 200.0, 311.0], "category_id": 1}, {"id": 3, "bbox": [71.0, 191.0, 337.0, 302.0], "category_id": 1}, {"id": 4, "bbox": [370.0, 245.0, 238.0, 94.0], "category_id": 1}, {"id": 5, "bbox": [622.0, 187.0, 345.0, 289.0], "category_id": 1}, {"id": 6, "bbox": [1040.0, 231.0, 233.0, 92.0], "category_id": 1}, {"id": 7, "bbox": [1142.0, 286.0, 61.0, 60.0], "category_id": 3}, {"id": 8, "bbox": [1043.0, 792.0, 57.0, 59.0], "category_id": 3}, {"id": 9, "bbox": [125.0, 860.0, 52.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [476.0, 304.0, 65.0, 42.0], "category_id": 3}, {"id": 11, "bbox": [806.0, 458.0, 52.0, 41.0], "category_id": 3}, {"id": 12, "bbox": [260.0, 458.0, 56.0, 53.0], "category_id": 3}, {"id": 13, "bbox": [829.0, 0.0, 48.0, 44.0], "category_id": 3}, {"id": 14, "bbox": [878.48, 132.03, 59.0, 46.37], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [14], "products": [13]}, {"reactants": [5], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [0]}], "corefs": [[3, 12], [4, 10], [5, 11], [6, 7], [2, 9], [0, 8]], "caption": "Table 1. E\ufb00ect of acid on the formation of imidazoles 14 and 20a ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 401, 405, 431], "ImageBB": [71, 133, 407, 375]}, "diagram_type": "tree"}, {"id": 1115, "width": 2448, "height": 792, "file_name": "jo9816515-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1911.62, 176.45, 227.78, 58.82], "category_id": 2}, {"id": 1, "bbox": [608.63, 188.71, 153.08, 52.69], "category_id": 2}, {"id": 2, "bbox": [1009.08, 357.81, 58.78, 62.49], "category_id": 3}, {"id": 3, "bbox": [852.33, 19.61, 401.67, 284.28], "category_id": 1}, {"id": 4, "bbox": [121.24, 366.38, 133.48, 62.5], "category_id": 3}, {"id": 5, "bbox": [2187.16, 19.61, 260.84, 267.13], "category_id": 1}, {"id": 6, "bbox": [420.04, 69.85, 169.0, 186.25], "category_id": 1}, {"id": 7, "bbox": [612.31, 112.73, 145.73, 61.27], "category_id": 2}, {"id": 8, "bbox": [1418.1, 3.68, 437.19, 286.73], "category_id": 1}, {"id": 9, "bbox": [0.0, 85.78, 377.18, 151.94], "category_id": 1}, {"id": 10, "bbox": [1592.0, 355.36, 67.35, 64.94], "category_id": 3}, {"id": 11, "bbox": [1939.79, 105.38, 154.3, 55.14], "category_id": 2}, {"id": 12, "bbox": [2204.3, 354.13, 243.7, 73.52], "category_id": 3}, {"id": 13, "bbox": [467.8, 355.36, 89.4, 68.62], "category_id": 3}, {"id": 14, "bbox": [0.0, 442.36, 1225.4, 349.64], "category_id": 4}], "caption": "Scheme 7", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 701, 453, 715], "ImageBB": [119, 720, 731, 918]}, "reactions": [{"reactants": [9, 6], "conditions": [7, 1], "products": [3]}, {"reactants": [3], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [11, 0], "products": [5]}], "diagram_type": "single"}, {"id": 729, "width": 2816, "height": 1212, "file_name": "ol016466j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [401.42, 394.63, 42.48, 46.72], "category_id": 3}, {"id": 1, "bbox": [852.0, 342.0, 239.0, 56.0], "category_id": 2}, {"id": 2, "bbox": [361.07, 687.69, 197.5, 53.1], "category_id": 3}, {"id": 3, "bbox": [363.2, 747.16, 178.39, 44.6], "category_id": 3}, {"id": 4, "bbox": [126.0, 777.0, 1044.0, 429.0], "category_id": 1}, {"id": 5, "bbox": [672.0, 873.0, 470.0, 56.0], "category_id": 2}, {"id": 6, "bbox": [807.0, 207.0, 312.0, 54.0], "category_id": 2}, {"id": 7, "bbox": [140.0, 449.0, 869.0, 258.0], "category_id": 1}, {"id": 8, "bbox": [1513.0, 140.0, 1218.0, 1039.0], "category_id": 4}, {"id": 9, "bbox": [669.0, 772.0, 484.0, 47.0], "category_id": 2}, {"id": 10, "bbox": [391.0, 831.0, 241.0, 61.0], "category_id": 2}, {"id": 11, "bbox": [933.0, 261.0, 45.0, 47.0], "category_id": 3}, {"id": 12, "bbox": [666.0, 814.0, 585.0, 64.0], "category_id": 2}, {"id": 13, "bbox": [141.75, 694.26, 174.25, 67.84], "category_id": 2}, {"id": 14, "bbox": [109.0, 174.0, 692.0, 257.1], "category_id": 1}], "reactions": [{"reactants": [14], "conditions": [6, 1], "products": [7]}, {"reactants": [2], "conditions": [13], "products": [3]}, {"reactants": [7], "conditions": [9, 12, 5], "products": [4]}], "corefs": [[14, 2], [6, 11], [7, 2], [7, 3]], "caption": "Figure 1. Partial one-dimensional transient NOE spectra of 2 mM polymer-bound trisaccharide 5 and 5 with Verotoxin-1 (200/1) in D2O: (a) 1H NMR spectra of 5 in D2O; (b) 1D NOESY spectra of 5 and VT-1 in D2O; (c) 1D NOESY spectra of 5 in D2O. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 354, 775, 410], "ImageBB": [73, 52, 777, 355]}, "diagram_type": "tree"}], "roles": [{"id": 1, "name": "reactants"}, {"id": 2, "name": "conditions"}, {"id": 3, "name": "products"}]}