test0.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 66, "width": 1352, "height": 428, "file_name": "ja3066978-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [829.38, 21.2, 204.02, 163.45], "category_id": 1}, {"id": 1, "bbox": [1079.75, 26.38, 204.02, 132.37], "category_id": 1}, {"id": 2, "bbox": [466.77, 5.66, 284.32, 178.12], "category_id": 1}, {"id": 3, "bbox": [7.14, 275.7, 1333.64, 150.9], "category_id": 4}, {"id": 4, "bbox": [1210.98, 203.37, 27.9, 34.8], "category_id": 3}, {"id": 5, "bbox": [60.14, 12.57, 285.17, 146.18], "category_id": 1}, {"id": 6, "bbox": [229.35, 203.37, 22.72, 35.67], "category_id": 3}, {"id": 7, "bbox": [640.31, 200.78, 27.9, 35.67], "category_id": 3}, {"id": 8, "bbox": [964.06, 210.27, 25.31, 34.81], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [], "products": [2, 0, 1]}], "corefs": [[5, 6], [2, 7], [0, 8], [1, 4]], "caption": "Table 1. Hydrogenation of 6-Chloroquinoline to 6-Chloro- 1,2,3,4-tetrahydroquinoline under Various Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 782, 125], "ImageBB": [449, 131, 787, 238]}, "diagram_type": "single"}, {"id": 511, "width": 1344, "height": 1964, "file_name": "ol051488h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [106.0, 262.0, 167.0, 59.0], "category_id": 2}, {"id": 1, "bbox": [267.0, 764.0, 455.0, 247.0], "category_id": 3}, {"id": 2, "bbox": [579.0, 97.0, 169.0, 63.4], "category_id": 2}, {"id": 3, "bbox": [49.0, 0.0, 195.0, 224.0], "category_id": 1}, {"id": 4, "bbox": [540.0, 17.0, 242.0, 57.6], "category_id": 3}, {"id": 5, "bbox": [260.0, 1.0, 220.6, 168.7], "category_id": 1}, {"id": 6, "bbox": [870.0, 0.0, 410.0, 225.0], "category_id": 1}, {"id": 7, "bbox": [849.0, 291.0, 454.0, 168.0], "category_id": 1}, {"id": 8, "bbox": [58.0, 519.0, 122.0, 172.0], "category_id": 1}, {"id": 9, "bbox": [269.0, 496.0, 284.0, 273.0], "category_id": 1}, {"id": 10, "bbox": [617.0, 504.0, 285.0, 191.0], "category_id": 1}, {"id": 11, "bbox": [948.0, 511.0, 292.0, 224.0], "category_id": 1}, {"id": 12, "bbox": [143.0, 210.0, 59.0, 58.0], "category_id": 3}, {"id": 13, "bbox": [328.0, 209.0, 76.0, 56.0], "category_id": 3}, {"id": 14, "bbox": [1053.0, 206.0, 63.0, 63.0], "category_id": 3}, {"id": 15, "bbox": [664.0, 696.0, 64.0, 59.0], "category_id": 3}, {"id": 16, "bbox": [998.0, 696.0, 68.0, 61.0], "category_id": 3}, {"id": 17, "bbox": [104.0, 701.0, 68.0, 57.0], "category_id": 3}, {"id": 18, "bbox": [0.0, 1026.0, 1344.0, 938.0], "category_id": 4}, {"id": 19, "bbox": [1064.0, 446.0, 37.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [3, 5], "conditions": [4, 2], "products": [6, 7]}], "corefs": [[3, 12], [5, 13], [6, 14], [7, 19], [8, 17], [9, 1], [10, 15], [11, 16]], "caption": "Table 1. Asymmetric Conjugate Addition of Isovaleraldehyde 3a to Vinyl Sulfones 1-2 Catalyzed by Various Amines 4a-g ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 410, 401, 438], "ImageBB": [74, 443, 410, 934]}, "diagram_type": "single"}, {"id": 1061, "width": 1352, "height": 2008, "file_name": "jo201996w-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [882.48, 611.74, 366.45, 434.95], "category_id": 1}, {"id": 1, "bbox": [12.05, 33.15, 219.87, 202.91], "category_id": 1}, {"id": 2, "bbox": [93.37, 1239.56, 506.0, 551.47], "category_id": 1}, {"id": 3, "bbox": [275.09, 1004.5, 63.25, 47.21], "category_id": 3}, {"id": 4, "bbox": [326.29, 1222.48, 126.5, 55.25], "category_id": 3}, {"id": 5, "bbox": [271.07, 1821.16, 365.44, 150.68], "category_id": 3}, {"id": 6, "bbox": [1133.47, 466.09, 65.26, 53.24], "category_id": 3}, {"id": 7, "bbox": [949.75, 307.38, 60.24, 47.21], "category_id": 3}, {"id": 8, "bbox": [619.45, 190.86, 94.37, 47.21], "category_id": 2}, {"id": 9, "bbox": [674.66, 811.64, 107.43, 54.24], "category_id": 2}, {"id": 10, "bbox": [1066.21, 1000.48, 68.27, 60.27], "category_id": 3}, {"id": 11, "bbox": [985.89, 533.39, 355.4, 57.26], "category_id": 2}, {"id": 12, "bbox": [256.01, 82.37, 247.98, 163.73], "category_id": 1}, {"id": 13, "bbox": [49.19, 314.41, 65.26, 51.23], "category_id": 3}, {"id": 14, "bbox": [871.44, 422.9, 89.35, 51.23], "category_id": 2}, {"id": 15, "bbox": [515.03, 79.36, 279.1, 91.41], "category_id": 2}, {"id": 16, "bbox": [420.66, 310.39, 71.28, 53.24], "category_id": 3}, {"id": 17, "bbox": [995.93, 358.61, 209.83, 150.67], "category_id": 1}, {"id": 18, "bbox": [9.04, 1105.96, 290.14, 102.46], "category_id": 2}, {"id": 19, "bbox": [326.29, 1073.81, 209.83, 159.72], "category_id": 1}, {"id": 20, "bbox": [93.37, 629.82, 425.68, 385.73], "category_id": 1}, {"id": 21, "bbox": [675.67, 871.91, 102.4, 50.22], "category_id": 2}, {"id": 22, "bbox": [882.48, 19.09, 397.57, 212.95], "category_id": 1}], "caption": "Scheme 5. Synthesis of Nonsymmetric 2,2\u2034-Disubstitued Tris-ortho-azobenzenes ", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 81, 405, 112], "ImageBB": [69, 119, 407, 621]}, "reactions": [{"reactants": [1, 12], "conditions": [15, 8], "products": [22]}, {"reactants": [22], "conditions": [14, 17, 11], "products": [0]}, {"reactants": [0], "conditions": [9, 21], "products": [20]}, {"reactants": [20], "conditions": [18, 19], "products": [2]}], "diagram_type": "tree"}, {"id": 369, "width": 1344, "height": 1860, "file_name": "ol102738b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [627.0, 192.0, 36.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [315.0, 155.4, 257.0, 80.6], "category_id": 2}, {"id": 2, "bbox": [924.0, 190.0, 40.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [566.0, 21.0, 309.0, 217.0], "category_id": 1}, {"id": 4, "bbox": [655.0, 238.0, 255.0, 116.0], "category_id": 1}, {"id": 5, "bbox": [888.0, 7.5, 316.0, 239.5], "category_id": 1}, {"id": 6, "bbox": [317.0, 12.5, 252.1, 112.6], "category_id": 1}, {"id": 7, "bbox": [139.4, 44.5, 185.6, 153.5], "category_id": 1}, {"id": 8, "bbox": [450.0, 106.0, 55.0, 45.0], "category_id": 3}, {"id": 9, "bbox": [180.0, 196.0, 32.0, 38.0], "category_id": 3}, {"id": 10, "bbox": [140.0, 260.0, 517.0, 73.0], "category_id": 2}, {"id": 11, "bbox": [916.0, 241.0, 272.0, 113.0], "category_id": 1}, {"id": 12, "bbox": [11.0, 397.0, 1333.0, 1463.0], "category_id": 4}], "reactions": [{"reactants": [7], "conditions": [6, 1], "products": [3, 5]}], "corefs": [[7, 9], [6, 8], [3, 0], [5, 2]], "caption": "Table 2. PBu3-Catalyzed Cascade [3 \u00fe 2] Cyclization-Allylic Alkylation and [2 \u00fe 2 \u00fe 1] Annulation of 1 and 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 397, 117], "ImageBB": [71, 126, 407, 591]}, "diagram_type": "single"}, {"id": 913, "width": 1352, "height": 1100, "file_name": "acs.joc.5b00632-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [144.06, 470.53, 332.08, 130.48], "category_id": 1}, {"id": 1, "bbox": [894.12, 254.87, 297.59, 187.27], "category_id": 2}, {"id": 2, "bbox": [920.5, 709.85, 220.48, 100.06], "category_id": 2}, {"id": 3, "bbox": [231.98, 181.18, 53.43, 54.76], "category_id": 3}, {"id": 4, "bbox": [543.78, 156.17, 97.39, 52.05], "category_id": 2}, {"id": 5, "bbox": [896.15, 624.67, 41.25, 50.03], "category_id": 3}, {"id": 6, "bbox": [315.85, 1007.32, 46.67, 49.35], "category_id": 3}, {"id": 7, "bbox": [995.57, 991.09, 41.26, 48.0], "category_id": 3}, {"id": 8, "bbox": [847.45, 185.24, 44.64, 54.76], "category_id": 3}, {"id": 9, "bbox": [679.72, 859.94, 40.58, 44.62], "category_id": 3}, {"id": 10, "bbox": [562.71, 675.38, 230.63, 199.43], "category_id": 1}, {"id": 11, "bbox": [122.42, 799.77, 426.09, 200.79], "category_id": 1}, {"id": 12, "bbox": [165.03, 47.32, 248.89, 118.31], "category_id": 1}, {"id": 13, "bbox": [761.56, 482.7, 297.59, 123.72], "category_id": 1}, {"id": 14, "bbox": [563.39, 989.74, 242.81, 58.82], "category_id": 2}, {"id": 15, "bbox": [563.39, 908.61, 273.92, 54.76], "category_id": 2}, {"id": 16, "bbox": [859.63, 853.18, 371.31, 124.39], "category_id": 1}, {"id": 17, "bbox": [775.08, 43.27, 237.4, 125.74], "category_id": 1}, {"id": 18, "bbox": [307.06, 617.91, 43.28, 48.68], "category_id": 3}, {"id": 19, "bbox": [467.35, 4.06, 240.78, 102.76], "category_id": 2}], "caption": "Scheme 3. Preparation of 2", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 202, 238, 217], "ImageBB": [82, 223, 420, 498]}, "reactions": [{"reactants": [12], "conditions": [19, 4], "products": [17]}, {"reactants": [17], "conditions": [1], "products": [13]}, {"reactants": [0], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [0]}, {"reactants": [13], "conditions": [2], "products": [16]}, {"reactants": [16], "conditions": [10, 15, 14], "products": [11]}], "diagram_type": "tree"}, {"id": 1038, "width": 1336, "height": 1200, "file_name": "jo001700p-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [199.16, 812.9, 828.07, 383.05], "category_id": 1}, {"id": 1, "bbox": [731.45, 504.27, 462.43, 56.04], "category_id": 3}, {"id": 2, "bbox": [731.45, 406.17, 413.45, 56.18], "category_id": 3}, {"id": 3, "bbox": [0.0, 0.0, 617.54, 266.06], "category_id": 1}, {"id": 4, "bbox": [779.95, 8.69, 493.89, 264.73], "category_id": 1}, {"id": 5, "bbox": [273.35, 304.17, 50.12, 59.5], "category_id": 3}, {"id": 6, "bbox": [648.28, 88.24, 51.47, 47.47], "category_id": 2}, {"id": 7, "bbox": [509.94, 650.46, 76.86, 62.17], "category_id": 2}, {"id": 8, "bbox": [535.34, 1143.81, 72.84, 56.19], "category_id": 3}, {"id": 9, "bbox": [1283.87, 341.61, 43.53, 56.82], "category_id": 2}, {"id": 10, "bbox": [732.49, 316.87, 385.61, 56.93], "category_id": 3}, {"id": 11, "bbox": [733.4, 591.63, 437.52, 63.17], "category_id": 3}, {"id": 12, "bbox": [1283.87, 554.86, 52.13, 59.74], "category_id": 2}, {"id": 13, "bbox": [1283.87, 458.59, 47.83, 49.47], "category_id": 2}], "caption": "Scheme 5", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 349, 270, 363], "ImageBB": [75, 369, 409, 669]}, "reactions": [{"reactants": [3], "conditions": [6], "products": [4]}, {"reactants": [10], "conditions": [9], "products": [2]}, {"reactants": [2], "conditions": [13], "products": [1]}, {"reactants": [1], "conditions": [12], "products": [11]}, {"reactants": [1, 11], "conditions": [7], "products": [0]}], "diagram_type": "tree"}, {"id": 1075, "width": 2820, "height": 1656, "file_name": "jo402763m-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1516.5, 647.33, 238.42, 207.32], "category_id": 1}, {"id": 1, "bbox": [1238.6, 417.45, 231.35, 214.37], "category_id": 1}, {"id": 2, "bbox": [224.3, 992.86, 334.34, 363.86], "category_id": 1}, {"id": 3, "bbox": [1743.63, 456.94, 55.02, 50.77], "category_id": 3}, {"id": 4, "bbox": [1410.71, 1265.05, 265.21, 220.01], "category_id": 1}, {"id": 5, "bbox": [753.32, 228.47, 43.73, 49.36], "category_id": 3}, {"id": 6, "bbox": [2039.88, 447.07, 372.43, 276.42], "category_id": 1}, {"id": 7, "bbox": [964.92, 334.24, 105.81, 66.29], "category_id": 2}, {"id": 8, "bbox": [1438.92, 851.83, 411.93, 59.23], "category_id": 3}, {"id": 9, "bbox": [0.0, 1552.76, 713.82, 77.56], "category_id": 2}, {"id": 10, "bbox": [1045.33, 1314.41, 57.84, 55.01], "category_id": 3}, {"id": 11, "bbox": [1728.11, 980.17, 242.65, 204.49], "category_id": 1}, {"id": 12, "bbox": [2007.43, 724.9, 524.79, 62.06], "category_id": 3}, {"id": 13, "bbox": [212.7, 139.62, 286.69, 306.04], "category_id": 1}, {"id": 14, "bbox": [359.73, 386.43, 47.96, 55.0], "category_id": 3}, {"id": 15, "bbox": [53.61, 1074.66, 40.91, 47.95], "category_id": 3}, {"id": 16, "bbox": [1508.04, 1476.6, 47.97, 47.95], "category_id": 3}, {"id": 17, "bbox": [2561.84, 449.89, 258.16, 241.16], "category_id": 1}, {"id": 18, "bbox": [2353.8, 427.33, 79.1, 66.28], "category_id": 2}, {"id": 19, "bbox": [306.12, 1314.41, 55.02, 56.42], "category_id": 3}, {"id": 20, "bbox": [1038.28, 847.6, 69.12, 55.0], "category_id": 3}, {"id": 21, "bbox": [72.26, 595.22, 301.99, 299.86], "category_id": 1}, {"id": 22, "bbox": [622.12, 0.0, 308.95, 242.57], "category_id": 1}, {"id": 23, "bbox": [966.33, 975.94, 320.23, 365.27], "category_id": 1}, {"id": 24, "bbox": [1338.76, 634.64, 71.95, 56.41], "category_id": 3}, {"id": 25, "bbox": [1653.35, 241.16, 286.37, 220.01], "category_id": 1}, {"id": 26, "bbox": [51.0, 476.12, 85.06, 51.08], "category_id": 2}, {"id": 27, "bbox": [0.0, 937.4, 147.5, 139.9], "category_id": 1}, {"id": 28, "bbox": [1190.64, 104.36, 255.66, 215.78], "category_id": 1}, {"id": 29, "bbox": [2441.4, 427.21, 97.83, 65.93], "category_id": 2}, {"id": 30, "bbox": [67.1, 823.62, 54.22, 66.29], "category_id": 3}, {"id": 31, "bbox": [1696.9, 1186.07, 307.71, 60.65], "category_id": 3}, {"id": 32, "bbox": [977.0, 631.82, 268.65, 236.93], "category_id": 1}, {"id": 33, "bbox": [2619.68, 720.67, 162.23, 59.23], "category_id": 3}, {"id": 34, "bbox": [1392.1, 267.96, 124.41, 55.0], "category_id": 3}], "caption": "Scheme 6. Plausible Catalytic Cycle Reaction Mechanism for the Formation of Chromenes 5 and the Carbonyl Compounds 10a", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 784, 110], "ImageBB": [82, 116, 787, 530]}, "reactions": [{"reactants": [2], "conditions": [], "products": [21, 27]}, {"reactants": [21], "conditions": [], "products": [26, 13]}, {"reactants": [13], "conditions": [], "products": [22, 7]}, {"reactants": [23], "conditions": [], "products": [2, 7]}, {"reactants": [28, 7], "conditions": [], "products": [25]}, {"reactants": [32], "conditions": [], "products": [1, 7]}, {"reactants": [11, 4], "conditions": [], "products": [23]}, {"reactants": [0], "conditions": [], "products": [32]}, {"reactants": [25], "conditions": [], "products": [0]}, {"reactants": [25], "conditions": [], "products": [6]}, {"reactants": [25], "conditions": [], "products": [11]}, {"reactants": [6], "conditions": [], "products": [17, 18, 29]}], "diagram_type": "graph"}, {"id": 1326, 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Direct synthesis of (\u2013)-1 utilizing chiral ligands and catalysts", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 441, 60], "ImageBB": [58, 74, 762, 427]}, "diagram_type": "single"}, {"id": 221, "width": 1316, "height": 1420, "file_name": "op025610t-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [189.0, 1377.0, 68.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [1052.0, 398.0, 91.0, 78.0], "category_id": 2}, {"id": 2, "bbox": [872.0, 414.0, 116.0, 64.0], "category_id": 2}, {"id": 3, "bbox": [283.0, 355.0, 121.0, 78.0], "category_id": 2}, {"id": 4, "bbox": [1049.0, 696.0, 267.0, 59.0], "category_id": 2}, {"id": 5, "bbox": [343.66, 611.34, 59.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [72.83, 614.83, 56.0, 50.5], "category_id": 3}, {"id": 7, "bbox": [469.0, 220.0, 40.5, 54.7], "category_id": 3}, {"id": 8, "bbox": [461.0, 860.9, 320.2, 47.1], "category_id": 2}, {"id": 9, "bbox": [4.0, 555.1, 215.0, 54.9], "category_id": 2}, {"id": 10, "bbox": [302.0, 554.6, 197.0, 52.4], "category_id": 2}, {"id": 11, "bbox": [835.6, 5.0, 350.7, 275.2], "category_id": 1}, {"id": 12, "bbox": [1152.0, 215.7, 51.8, 58.3], "category_id": 3}, {"id": 13, "bbox": [830.3, 831.0, 360.8, 255.5], "category_id": 1}, {"id": 14, "bbox": [28.0, 849.7, 348.6, 171.1], "category_id": 1}, {"id": 15, "bbox": [40.1, 1193.7, 345.4, 164.7], "category_id": 1}, {"id": 16, "bbox": [818.0, 559.0, 462.0, 59.0], "category_id": 2}, {"id": 17, "bbox": [558.0, 527.0, 215.0, 40.0], "category_id": 2}, {"id": 18, "bbox": [273.0, 139.0, 310.0, 73.0], "category_id": 2}, {"id": 19, "bbox": [536.0, 930.0, 110.0, 54.0], "category_id": 2}, {"id": 20, "bbox": [232.0, 1083.0, 283.0, 43.0], "category_id": 2}, {"id": 21, "bbox": [985.0, 1118.0, 70.0, 54.0], "category_id": 3}, {"id": 22, "bbox": [934.88, 616.88, 43.9, 47.8], "category_id": 3}, {"id": 23, "bbox": [136.4, 1033.97, 43.92, 43.91], "category_id": 3}], "reactions": [{"reactants": [9, 10], "conditions": [17], "products": [16]}, {"reactants": [10], "conditions": [3], "products": [18]}, {"reactants": [16], "conditions": [2, 1], "products": [11]}, {"reactants": [16], "conditions": [4], "products": [13]}, {"reactants": [13], "conditions": [8, 19], "products": [14]}, {"reactants": [14], "conditions": [20], "products": [15]}], "corefs": [[18, 7], [11, 12], [9, 6], [10, 5], [16, 22], [14, 23], [13, 21], [15, 0]], "caption": "Table 1. Proportional composition (%)a of the reaction mixture under different pressure and atmospheric conditions ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 454, 408, 482], "ImageBB": [78, 87, 407, 442]}, "diagram_type": "tree"}, {"id": 121, "width": 1344, "height": 1020, "file_name": "op9701245-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [513.0, 11.0, 239.0, 159.9], "category_id": 2}, {"id": 1, "bbox": [210.0, 496.5, 951.0, 404.5], "category_id": 4}, {"id": 2, "bbox": [895.0, 7.0, 239.0, 332.0], "category_id": 1}, {"id": 3, "bbox": [519.0, 235.0, 356.0, 219.0], "category_id": 2}, {"id": 4, "bbox": [214.0, 86.0, 293.0, 257.0], "category_id": 1}, {"id": 5, "bbox": [46.0, 923.0, 495.0, 68.0], "category_id": 2}, {"id": 6, "bbox": [952.0, 377.0, 71.0, 67.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [0, 3], "products": [2]}], "corefs": [[2, 6]], "caption": "Table 1. Furfuryl alcohol rearrangement", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 327, 304, 341], "ImageBB": [74, 349, 410, 604]}, "diagram_type": "single"}, {"id": 215, "width": 2808, "height": 1068, "file_name": "op030202q-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1715.3, 8.0, 237.3, 283.0], "category_id": 1}, {"id": 1, "bbox": [784.0, 80.03, 129.0, 45.0], "category_id": 2}, {"id": 2, "bbox": [521.3, 7.4, 227.5, 291.6], "category_id": 1}, {"id": 3, "bbox": [1277.0, 162.0, 328.0, 60.4], "category_id": 2}, {"id": 4, "bbox": [966.0, 5.0, 304.1, 294.8], "category_id": 1}, {"id": 5, "bbox": [1277.0, 67.0, 370.0, 62.4], "category_id": 2}, {"id": 6, "bbox": [989.0, 363.0, 207.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [1796.0, 299.0, 132.0, 59.0], "category_id": 3}, {"id": 8, "bbox": [0.0, 487.0, 2808.0, 581.0], "category_id": 4}, {"id": 9, "bbox": [602.0, 316.0, 87.0, 61.0], "category_id": 3}, {"id": 10, "bbox": [795.0, 167.0, 149.0, 48.0], "category_id": 2}, {"id": 11, "bbox": [2070.0, 117.0, 227.0, 109.0], "category_id": 2}, {"id": 12, "bbox": [972.0, 313.0, 219.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [1, 10], "products": [4]}, {"reactants": [4], "conditions": [5, 3], "products": [0, 11]}], "corefs": [[2, 9], [4, 12], [4, 6], [0, 7]], "caption": "Table 4. Resolution of racemic PLA by diastereomeric salt formation: optimization", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 460, 533, 474], "ImageBB": [74, 479, 776, 746]}, "diagram_type": "single"}, {"id": 900, "width": 1348, "height": 568, "file_name": "acs.joc.6b00116-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [597.0, 6.9, 242.0, 125.1], "category_id": 2}, {"id": 1, "bbox": [968.0, 272.0, 330.0, 125.1], "category_id": 1}, {"id": 2, "bbox": [3.0, 492.9, 1345.0, 75.1], "category_id": 4}, {"id": 3, "bbox": [48.9, 47.0, 274.1, 149.0], "category_id": 1}, {"id": 4, "bbox": [92.0, 218.0, 198.4, 106.0], "category_id": 3}, {"id": 5, "bbox": [521.0, 255.0, 417.3, 172.4], "category_id": 1}, {"id": 6, "bbox": [704.0, 432.0, 28.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [387.0, 109.0, 200.0, 55.0], "category_id": 2}, {"id": 8, "bbox": [1120.0, 432.0, 25.0, 35.0], "category_id": 3}], "reactions": [{"reactants": [3, 7], "conditions": [0], "products": [5, 1]}], "corefs": [[3, 4], [5, 6], [1, 8]], "caption": "Table 1. TpRh(C2H4)2/P(2-furyl)3-Catalyzed Reaction of Terminal Alkynes with Hydrazinesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 403, 125], "ImageBB": [82, 131, 419, 273]}, "diagram_type": "multiple"}, {"id": 829, "width": 1348, "height": 296, "file_name": "jo400501k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [781.0, 5.0, 244.0, 186.8], "category_id": 1}, {"id": 1, "bbox": [351.0, 150.0, 80.0, 50.0], "category_id": 3}, {"id": 2, "bbox": [334.3, 26.2, 245.7, 166.7], "category_id": 1}, {"id": 3, "bbox": [593.0, 27.1, 173.0, 57.9], "category_id": 2}, {"id": 4, "bbox": [7.0, 223.0, 1334.0, 73.0], "category_id": 4}, {"id": 5, "bbox": [648.4, 102.0, 95.5, 69.0], "category_id": 2}, {"id": 6, "bbox": [805.0, 145.0, 82.0, 53.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [3, 5], "products": [0]}], "corefs": [[2, 1], [0, 6]], "caption": "Table 1. Optimization of Conditions for the Synthesis of Diaminesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 404, 125], "ImageBB": [82, 131, 419, 205]}, "diagram_type": "single"}, {"id": 1100, "width": 2784, "height": 1908, "file_name": "jo970671o-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [459.59, 0.0, 476.3, 214.37], "category_id": 2}, {"id": 1, "bbox": [545.94, 425.96, 1137.83, 293.72], "category_id": 1}, {"id": 2, "bbox": [1753.4, 296.5, 988.82, 302.07], "category_id": 2}, {"id": 3, "bbox": [1806.33, 1586.92, 282.71, 75.17], "category_id": 2}, {"id": 4, "bbox": [1767.33, 828.26, 646.21, 178.18], "category_id": 2}, {"id": 5, "bbox": [2190.71, 1560.47, 593.29, 178.18], "category_id": 3}, {"id": 6, "bbox": [0.0, 778.15, 1675.41, 530.36], "category_id": 1}, {"id": 7, "bbox": [745.09, 1106.67, 523.66, 58.46], "category_id": 3}, {"id": 8, "bbox": [973.49, 0.0, 710.28, 286.76], "category_id": 1}, {"id": 9, "bbox": [1316.1, 289.54, 296.64, 62.64], "category_id": 2}, {"id": 10, "bbox": [200.55, 164.26, 221.44, 100.23], "category_id": 1}, {"id": 11, "bbox": [417.81, 1266.75, 1279.89, 641.25], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [389, 49, 452, 63], "ImageBB": [77, 70, 773, 547]}, "reactions": [{"reactants": [10], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [9], "products": [1]}, {"reactants": [1], "conditions": [2], "products": [6]}, {"reactants": [6], "conditions": [4], "products": [11]}, {"reactants": [11], "conditions": [3], "products": [5]}], "diagram_type": "tree"}, {"id": 52, "width": 1348, "height": 408, "file_name": "ja407179c-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1056.81, 267.38, 91.53, 35.57], "category_id": 3}, {"id": 1, "bbox": [333.75, 211.43, 98.41, 39.88], "category_id": 2}, {"id": 2, "bbox": [652.24, 163.23, 119.93, 38.15], "category_id": 2}, {"id": 3, "bbox": [591.13, 51.32, 270.56, 89.8], "category_id": 2}, {"id": 4, "bbox": [7.13, 331.62, 1334.78, 73.2], "category_id": 4}, {"id": 5, "bbox": [966.43, 46.16, 336.85, 209.45], "category_id": 1}, {"id": 6, "bbox": [235.62, 84.03, 303.28, 110.46], "category_id": 1}, {"id": 7, "bbox": [44.52, 4.84, 150.92, 249.05], "category_id": 1}, {"id": 8, "bbox": [68.63, 267.38, 41.59, 33.85], "category_id": 3}], "reactions": [{"reactants": [7, 6], "conditions": [3, 2], "products": [5]}], "corefs": [[7, 8], [5, 0]], "caption": "Table 2. 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"category_id": 2}, {"id": 33, "bbox": [25.05, 692.92, 347.71, 96.47], "category_id": 3}, {"id": 34, "bbox": [82.51, 145.06, 57.46, 43.45], "category_id": 3}, {"id": 35, "bbox": [1021.76, 760.67, 262.99, 153.9], "category_id": 1}, {"id": 36, "bbox": [836.12, 952.86, 297.62, 134.76], "category_id": 2}, {"id": 37, "bbox": [327.82, 37.55, 135.55, 110.46], "category_id": 1}, {"id": 38, "bbox": [406.64, 1233.42, 292.46, 96.46], "category_id": 2}, {"id": 39, "bbox": [1021.76, 430.78, 262.99, 151.69], "category_id": 1}, {"id": 40, "bbox": [1081.43, 29.45, 144.39, 110.46], "category_id": 1}, {"id": 41, "bbox": [25.05, 29.45, 265.2, 113.41], "category_id": 1}, {"id": 42, "bbox": [385.28, 145.06, 47.15, 46.4], "category_id": 3}, {"id": 43, "bbox": [483.26, 314.43, 285.09, 92.05], "category_id": 2}, {"id": 44, "bbox": [1081.43, 574.37, 64.09, 43.44], "category_id": 3}, {"id": 45, "bbox": [777.92, 574.37, 61.88, 44.18], "category_id": 3}, {"id": 46, "bbox": [724.15, 428.57, 260.04, 148.01], "category_id": 1}, {"id": 47, "bbox": [777.92, 906.47, 61.88, 46.39], "category_id": 3}, {"id": 48, "bbox": [777.92, 574.37, 61.88, 44.18], "category_id": 3}, {"id": 49, "bbox": [724.15, 760.67, 260.04, 149.48], "category_id": 1}, {"id": 50, "bbox": [777.92, 1290.85, 61.88, 44.19], "category_id": 3}], "caption": "Scheme 3. Comparison between Asymmetric Permanganate Oxidation and Sharpless ADa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 235, 417, 265], "ImageBB": [87, 272, 414, 640]}, "reactions": [{"reactants": [41, 37], "conditions": [9, 27], "products": [16, 40]}, {"reactants": [15, 21], "conditions": [24, 43], "products": [31, 20]}, {"reactants": [0], "conditions": [18, 23], "products": [46, 39]}, {"reactants": [0], "conditions": [28, 30], "products": [49, 35]}, {"reactants": [6], "conditions": [4, 38], "products": [26, 14]}], "diagram_type": "multiple"}, {"id": 232, "width": 2640, "height": 1760, "file_name": "op000111i-Figure-c11.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1424.0, 494.0, 559.0, 93.0], "category_id": 2}, {"id": 1, "bbox": [927.0, 1093.0, 140.0, 152.0], "category_id": 2}, {"id": 2, "bbox": [731.0, 617.0, 205.0, 69.0], "category_id": 2}, {"id": 3, "bbox": [1700.95, 1229.2, 61.24, 81.64], "category_id": 3}, {"id": 4, "bbox": [936.0, 1260.0, 357.0, 155.0], "category_id": 2}, {"id": 5, "bbox": [1459.0, 701.0, 728.0, 757.0], "category_id": 1}, {"id": 6, "bbox": [1027.1, 517.7, 304.3, 289.8], "category_id": 1}, {"id": 7, "bbox": [345.4, 517.0, 306.4, 292.7], "category_id": 1}, {"id": 8, "bbox": [351.0, 1262.0, 222.0, 141.0], "category_id": 2}, {"id": 9, "bbox": [340.0, 1099.0, 403.0, 149.0], "category_id": 2}, {"id": 10, "bbox": [676.0, 973.0, 318.0, 64.0], "category_id": 2}, {"id": 11, "bbox": [445.0, 888.0, 783.0, 73.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [2], "products": [6]}], "corefs": [[5, 3]], "caption": "Figure 11. Continuous reduction of tetralone, applying polystyrene-bound oxazaborolidine as catalyst.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 1013, 638, 1027], "ImageBB": [97, 564, 757, 1004]}, "diagram_type": "single"}, {"id": 587, "width": 1356, "height": 720, "file_name": "acs.oprd.6b00180-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [361.0, 72.6, 250.0, 133.4], "category_id": 1}, {"id": 1, "bbox": [1017.0, 1.0, 332.0, 222.0], "category_id": 1}, {"id": 2, "bbox": [656.0, 77.0, 291.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [714.0, 147.0, 149.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [135.0, 206.0, 36.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [1228.0, 208.0, 36.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [16.0, 278.0, 1339.0, 442.0], "category_id": 4}, {"id": 7, "bbox": [3.0, 57.0, 266.0, 159.0], "category_id": 1}], "reactions": [{"reactants": [7, 0], "conditions": [2, 3], "products": [1]}], "corefs": [[7, 4], [1, 5]], "caption": "Table 6. Temperature E\ufb00ects on the 100 mL Scale Suzuki Reaction of 4-Bromoaniline (2) with PhB(OH)2 in H2O with No Added Liganda ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 553, 777, 599], "ImageBB": [448, 605, 787, 785]}, "diagram_type": "single"}, {"id": 1172, "width": 1344, "height": 1204, "file_name": "ol200717n-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [135.81, 28.91, 467.95, 322.09], "category_id": 1}, {"id": 1, "bbox": [879.42, 940.71, 163.37, 96.83], "category_id": 3}, {"id": 2, "bbox": [615.19, 66.57, 143.21, 103.55], "category_id": 2}, {"id": 3, "bbox": [974.22, 489.52, 233.97, 143.23], "category_id": 2}, {"id": 4, "bbox": [343.56, 714.11, 60.51, 50.43], "category_id": 3}, {"id": 5, "bbox": [766.46, 0.0, 393.32, 373.86], "category_id": 1}, {"id": 6, "bbox": [293.14, 1064.44, 160.69, 94.14], "category_id": 3}, {"id": 7, "bbox": [878.74, 375.88, 162.04, 94.81], "category_id": 3}, {"id": 8, "bbox": [175.48, 481.45, 389.28, 280.4], "category_id": 1}, {"id": 9, "bbox": [143.21, 834.47, 454.5, 223.92], "category_id": 1}, {"id": 10, "bbox": [642.08, 204.42, 92.11, 98.17], "category_id": 2}, {"id": 11, "bbox": [260.19, 377.23, 226.58, 53.12], "category_id": 3}, {"id": 12, "bbox": [613.84, 826.4, 138.5, 97.5], "category_id": 2}, {"id": 13, "bbox": [763.77, 663.68, 391.98, 275.69], "category_id": 1}, {"id": 14, "bbox": [598.38, 675.11, 171.44, 110.27], "category_id": 2}], "caption": "Scheme 4. Elaboration of Triol 11", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 430, 253, 443], "ImageBB": [71, 455, 407, 756]}, "reactions": [{"reactants": [0], "conditions": [2, 10], "products": [5]}, {"reactants": [5], "conditions": [3], "products": [13]}, {"reactants": [13], "conditions": [14, 12], "products": [8, 9]}], "diagram_type": "tree"}, {"id": 707, "width": 1344, "height": 1084, "file_name": "ol035127i-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [743.0, 0.0, 315.0, 294.0], "category_id": 1}, {"id": 1, "bbox": [12.0, 32.0, 410.0, 257.0], "category_id": 1}, {"id": 2, "bbox": [1063.0, 0.0, 267.0, 311.0], "category_id": 1}, {"id": 3, "bbox": [1171.0, 289.0, 72.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [422.0, 159.0, 284.0, 116.0], "category_id": 2}, {"id": 5, "bbox": [413.0, 59.0, 288.0, 59.0], "category_id": 2}, {"id": 6, "bbox": [164.0, 297.0, 61.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [981.0, 296.0, 70.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [0.0, 399.0, 1344.0, 685.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [5, 4], "products": [0, 2]}], "corefs": [[1, 6], [0, 7], [2, 3]], "caption": "Table 1. Optimization of the Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 147, 339, 160], "ImageBB": [74, 171, 410, 442]}, "diagram_type": "single"}, {"id": 775, "width": 1348, "height": 868, "file_name": "jo951899j-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 390.0, 1342.0, 478.0], "category_id": 4}, {"id": 1, "bbox": [596.0, 4.0, 157.0, 188.0], "category_id": 2}, {"id": 2, "bbox": [319.0, 291.0, 96.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [971.0, 283.0, 97.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [134.0, 51.0, 421.0, 209.0], "category_id": 1}, {"id": 5, "bbox": [819.0, 52.0, 395.0, 209.0], "category_id": 1}, {"id": 6, "bbox": [588.0, 225.0, 147.0, 40.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [1, 6], "products": [5]}], "corefs": [[4, 2], [5, 3]], "caption": "Table 6. Removal of the MEE Ester Protecting Group       from \u03b2-Glycosidic Conjugates with Papain ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [438, 277, 755, 302], "ImageBB": [429, 311, 766, 528]}, "diagram_type": "single"}, {"id": 1164, "width": 1352, "height": 908, "file_name": "ol060868f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [32.46, 546.63, 351.7, 250.99], "category_id": 1}, {"id": 1, "bbox": [806.2, 4.06, 506.57, 286.17], "category_id": 1}, {"id": 2, "bbox": [165.03, 796.94, 43.96, 50.74], "category_id": 3}, {"id": 3, "bbox": [32.46, 54.8, 258.37, 225.28], "category_id": 1}, {"id": 4, "bbox": [394.98, 535.13, 385.51, 149.51], "category_id": 2}, {"id": 5, "bbox": [903.59, 361.26, 420.0, 101.48], "category_id": 2}, {"id": 6, "bbox": [963.78, 290.23, 38.55, 52.09], "category_id": 3}, {"id": 7, "bbox": [165.03, 286.17, 43.28, 54.12], "category_id": 3}, {"id": 8, "bbox": [442.33, 197.54, 136.62, 57.51], "category_id": 2}, {"id": 9, "bbox": [540.39, 710.35, 101.45, 52.76], "category_id": 2}, {"id": 10, "bbox": [806.2, 508.74, 503.19, 290.91], "category_id": 1}, {"id": 11, "bbox": [423.39, 69.68, 178.55, 103.51], "category_id": 2}, {"id": 12, "bbox": [769.0, 380.88, 98.07, 54.8], "category_id": 2}, {"id": 13, "bbox": [963.78, 798.29, 44.64, 52.77], "category_id": 3}], "caption": "Scheme 1. Enantioselective Preparation of 6", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [121, 262, 362, 275], "ImageBB": [73, 279, 411, 506]}, "reactions": [{"reactants": [3], "conditions": [11, 8], "products": [1]}, {"reactants": [1], "conditions": [12, 5], "products": [10]}, {"reactants": [10], "conditions": [4, 9], "products": [0]}], "diagram_type": "tree"}, {"id": 449, "width": 2808, "height": 980, "file_name": "op2001047-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1041.0, 40.0, 218.0, 93.0], "category_id": 2}, {"id": 1, "bbox": [2124.0, 219.0, 48.0, 34.0], "category_id": 3}, {"id": 2, "bbox": [1632.0, 215.0, 48.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [823.0, 218.0, 50.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [1831.0, 0.0, 438.0, 227.0], "category_id": 1}, {"id": 5, "bbox": [1316.0, 0.0, 446.0, 230.0], "category_id": 1}, {"id": 6, "bbox": [1050.0, 174.0, 194.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [524.0, 0.0, 455.0, 229.0], "category_id": 1}, {"id": 8, "bbox": [7.0, 296.0, 2796.0, 684.0], "category_id": 4}], "reactions": [{"reactants": [7], "conditions": [0, 6], "products": [5, 4]}], "corefs": [[7, 3], [5, 2], [4, 1]], "caption": "Table 6. In\ufb02uence of catalyst, temperature, and \ufb02ow rate on the \ufb02ow hydrogenation of 4-aryl-3-buten-2-ones 1ba", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 300, 694, 322], "ImageBB": [71, 330, 773, 575]}, "diagram_type": "single"}, {"id": 613, "width": 3396, "height": 2004, "file_name": "acs.oprd.5b00312-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1136.4, 387.5, 397.8, 243.7], "category_id": 1}, {"id": 1, "bbox": [1755.0, 421.2, 389.5, 155.5], "category_id": 1}, {"id": 2, "bbox": [1941.35, 800.27, 288.95, 194.93], "category_id": 1}, {"id": 3, "bbox": [1569.06, 400.24, 61.79, 45.67], "category_id": 2}, {"id": 4, "bbox": [2184.23, 400.24, 64.47, 42.98], "category_id": 2}, {"id": 5, "bbox": [1580.0, 534.0, 151.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [1149.0, 644.0, 434.0, 85.9], "category_id": 2}, {"id": 7, "bbox": [1763.0, 645.9, 454.0, 88.8], "category_id": 2}, {"id": 8, "bbox": [1909.0, 1004.0, 349.0, 74.6], "category_id": 2}, {"id": 9, "bbox": [1837.0, 311.0, 300.0, 62.0], "category_id": 3}, {"id": 10, "bbox": [1222.0, 304.0, 271.0, 66.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [5], "products": [1]}], "corefs": [[0, 10], [1, 9], [0, 6], [1, 7], [2, 8]], "caption": "Figure 1. (A\u2212C) UHPLC/UV chromatograms at 254 nm for (A) unreacted compound 3, (B) the HCl control, and (C) the TiCl3/HCl-treated sample. (D, E) High-resolution mass spectra of (D) compound 3 and (E) reduced quinoxaline compound 3a. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 537, 784, 565], "ImageBB": [10, 22, 859, 523]}, "diagram_type": "single"}, {"id": 1224, "width": 1332, "height": 652, "file_name": "op010068e-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [346.2, 314.08, 661.3, 254.72], "category_id": 1}, {"id": 1, "bbox": [549.06, 132.7, 33.98, 46.01], "category_id": 3}, {"id": 2, "bbox": [0.0, 48.01, 516.41, 177.49], "category_id": 1}, {"id": 3, "bbox": [707.65, 598.15, 55.97, 40.01], "category_id": 3}, {"id": 4, "bbox": [1072.13, 248.73, 54.64, 44.68], "category_id": 3}, {"id": 5, "bbox": [258.54, 208.05, 58.63, 43.35], "category_id": 3}, {"id": 6, "bbox": [669.0, 2.67, 663.0, 255.39], "category_id": 1}], "caption": "Scheme 9", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [441, 72, 774, 235]}, "reactions": [{"reactants": [2, 1], "conditions": [], "products": [6]}], "diagram_type": "single"}, {"id": 57, "width": 2820, "height": 1784, "file_name": "ja406383h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1346.2, 183.12, 30.46, 33.08], "category_id": 3}, {"id": 1, "bbox": [562.19, 205.12, 88.68, 38.22], "category_id": 3}, {"id": 2, "bbox": [1525.21, 185.35, 27.08, 30.84], "category_id": 3}, {"id": 3, "bbox": [1719.53, 185.1, 27.08, 31.34], "category_id": 3}, {"id": 4, "bbox": [1931.91, 185.35, 25.82, 31.09], "category_id": 3}, {"id": 5, "bbox": [2080.59, 177.33, 200.34, 37.6], "category_id": 3}, {"id": 6, "bbox": [2320.16, 176.7, 230.6, 38.55], "category_id": 3}, {"id": 7, "bbox": [272.39, 207.71, 44.7, 35.63], "category_id": 3}, {"id": 8, "bbox": [718.73, 139.14, 166.31, 80.96], "category_id": 2}, {"id": 9, "bbox": [735.55, 30.46, 117.15, 77.04], "category_id": 2}, {"id": 10, "bbox": [2348.38, 35.45, 110.76, 114.22], "category_id": 1}, {"id": 11, "bbox": [2111.38, 35.02, 132.85, 114.21], "category_id": 1}, {"id": 12, "bbox": [1643.02, 28.95, 159.71, 122.88], "category_id": 1}, {"id": 13, "bbox": [1860.52, 53.21, 151.48, 98.62], "category_id": 1}, {"id": 14, "bbox": [1461.48, 33.72, 144.54, 130.68], "category_id": 1}, {"id": 15, "bbox": [1297.7, 87.44, 115.52, 34.93], "category_id": 1}, {"id": 16, "bbox": [957.15, 4.69, 261.96, 227.3], "category_id": 1}, {"id": 17, "bbox": [546.84, 70.54, 112.92, 102.96], "category_id": 1}, {"id": 18, "bbox": [232.14, 7.02, 261.33, 180.85], "category_id": 1}, {"id": 19, "bbox": [0.0, 264.11, 2812.14, 1515.5], "category_id": 4}], "reactions": [{"reactants": [18, 17], "conditions": [9, 8], "products": [16]}], "corefs": [[18, 7], [17, 1], [15, 0], [14, 2], [12, 3], [13, 4], [11, 5], [10, 6]], "caption": "Table 1. Optimization of Direct C\u2212H Amidation of Benzamidea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 446, 110], "ImageBB": [82, 116, 787, 562]}, "diagram_type": "single"}, {"id": 397, "width": 1352, "height": 1136, "file_name": "op500102h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [588.0, 45.0, 195.0, 52.0], "category_id": 2}, {"id": 1, "bbox": [2.0, 282.0, 1319.0, 823.0], "category_id": 4}, {"id": 2, "bbox": [557.0, 123.0, 256.0, 57.0], "category_id": 2}, {"id": 3, "bbox": [986.0, 221.0, 98.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [277.0, 223.0, 93.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [873.0, 2.0, 330.0, 211.0], "category_id": 1}, {"id": 6, "bbox": [163.0, 0.0, 319.5, 210.4], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [0, 2], "products": [5]}], "corefs": [[6, 4], [5, 3]], "caption": "Table 2. Saponi\ufb01cation of 3,5-bis(\ufb02uoroalkyl)pyrazoles 4", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 403, 110], "ImageBB": [82, 116, 420, 400]}, "diagram_type": "single"}, {"id": 1238, "width": 1000, "height": 528, "file_name": "op025501e-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [429.21, 413.6, 203.11, 46.01], "category_id": 2}, {"id": 1, "bbox": [67.53, 246.06, 36.02, 45.01], "category_id": 3}, {"id": 2, "bbox": [663.33, 328.08, 277.64, 128.53], "category_id": 1}, {"id": 3, "bbox": [356.68, 59.01, 248.12, 52.02], "category_id": 2}, {"id": 4, "bbox": [242.62, 480.62, 38.02, 45.01], "category_id": 3}, {"id": 5, "bbox": [723.36, 206.05, 42.02, 45.51], "category_id": 3}, {"id": 6, "bbox": [6.5, 347.59, 143.58, 56.51], "category_id": 2}, {"id": 7, "bbox": [665.33, 45.51, 331.67, 124.53], "category_id": 1}, {"id": 8, "bbox": [429.21, 130.03, 105.56, 44.51], "category_id": 2}, {"id": 9, "bbox": [429.21, 341.09, 195.6, 54.51], "category_id": 2}, {"id": 10, "bbox": [174.09, 331.08, 248.12, 126.53], "category_id": 1}, {"id": 11, "bbox": [6.5, 2.0, 337.67, 223.06], "category_id": 1}, {"id": 12, "bbox": [725.36, 481.12, 43.52, 40.01], "category_id": 3}], "caption": "Scheme 1. Chemical synthesis of 4", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 240, 639, 254], "ImageBB": [483, 259, 733, 391]}, "reactions": [{"reactants": [11], "conditions": [3, 8], "products": [7]}, {"reactants": [7], "conditions": [6], "products": [10]}, {"reactants": [10], "conditions": [9, 0], "products": [2]}], "diagram_type": "multiple"}, {"id": 126, "width": 1352, "height": 1452, "file_name": "op9002533-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [311.6, 79.0, 298.4, 59.5], "category_id": 2}, {"id": 1, "bbox": [309.0, 0.0, 371.0, 54.4], "category_id": 2}, {"id": 2, "bbox": [0.0, 6.0, 299.0, 139.6], "category_id": 1}, {"id": 3, "bbox": [449.0, 213.5, 301.0, 142.5], "category_id": 1}, {"id": 4, "bbox": [1058.5, 206.0, 293.5, 150.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 410.4, 1352.0, 1041.6], "category_id": 4}, {"id": 6, "bbox": [601.0, 377.0, 40.5, 31.1], "category_id": 3}, {"id": 7, "bbox": [756.0, 298.0, 170.0, 52.0], "category_id": 2}, {"id": 8, "bbox": [1194.0, 371.0, 43.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [112.0, 182.0, 26.0, 35.0], "category_id": 3}, {"id": 10, "bbox": [753.0, 182.0, 307.0, 98.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [1, 0], "products": [3]}, {"reactants": [3], "conditions": [10, 7], "products": [4]}], "corefs": [[2, 9], [3, 6], [4, 8]], "caption": "Table 1. Scope of cyclization using Eaton\u2019s reagent", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 341, 60], "ImageBB": [58, 74, 396, 437]}, "diagram_type": "multiple"}, {"id": 847, "width": 1344, "height": 1004, "file_name": "jo201478d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [101.0, 27.0, 297.0, 177.0], "category_id": 1}, {"id": 1, "bbox": [649.0, 7.0, 217.0, 83.0], "category_id": 2}, {"id": 2, "bbox": [702.0, 112.0, 132.0, 89.0], "category_id": 2}, {"id": 3, "bbox": [210.0, 187.0, 49.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [531.0, 187.0, 51.0, 37.0], "category_id": 3}, {"id": 5, "bbox": [1029.0, 187.0, 52.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [873.0, 31.0, 373.0, 151.0], "category_id": 1}, {"id": 7, "bbox": [427.0, 27.0, 211.0, 132.0], "category_id": 1}, {"id": 8, "bbox": [4.0, 277.0, 1334.0, 716.0], "category_id": 4}], "reactions": [{"reactants": [0, 7], "conditions": [1, 2], "products": [6]}], "corefs": [[0, 3], [7, 4], [6, 5]], "caption": "Table 1. Comparison of Catalyst Loading on Tandem Reac- tion of (Z)-\u03b4-Hydroxyalkenylsilane 1a and Phenylacetaldehyde ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 137], "ImageBB": [71, 148, 407, 399]}, "diagram_type": "single"}, {"id": 963, "width": 1136, "height": 1064, "file_name": "ja016495p-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [750.14, 2.27, 313.69, 343.68], "category_id": 1}, {"id": 1, "bbox": [732.52, 781.09, 237.54, 260.17], "category_id": 1}, {"id": 2, "bbox": [505.77, 605.56, 107.41, 46.01], "category_id": 2}, {"id": 3, "bbox": [0.0, 390.26, 313.69, 226.66], "category_id": 1}, {"id": 4, "bbox": [251.75, 600.44, 38.07, 47.15], "category_id": 3}, {"id": 5, "bbox": [521.68, 170.99, 126.16, 71.57], "category_id": 2}, {"id": 6, "bbox": [988.25, 702.13, 59.67, 51.12], "category_id": 3}, {"id": 7, "bbox": [1024.05, 208.48, 111.95, 47.15], "category_id": 2}, {"id": 8, "bbox": [505.77, 965.14, 114.8, 47.72], "category_id": 2}, {"id": 9, "bbox": [930.85, 360.15, 56.83, 48.29], "category_id": 3}, {"id": 10, "bbox": [971.2, 1012.86, 58.53, 49.42], "category_id": 3}, {"id": 11, "bbox": [731.95, 545.91, 329.6, 139.74], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 65, 130, 79], "ImageBB": [143, 107, 427, 373]}, "reactions": [{"reactants": [3], "conditions": [5], "products": [0]}, {"reactants": [3], "conditions": [2], "products": [11]}, {"reactants": [3], "conditions": [8], "products": [1]}], "diagram_type": "tree"}, {"id": 678, "width": 1344, "height": 2088, "file_name": "ol401571r-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [437.0, 107.8, 182.0, 97.2], "category_id": 2}, {"id": 1, "bbox": [930.5, 4.3, 341.1, 246.7], "category_id": 1}, {"id": 2, "bbox": [74.4, 0.0, 362.6, 218.3], "category_id": 1}, {"id": 3, "bbox": [638.1, 5.0, 252.9, 120.0], "category_id": 2}, {"id": 4, "bbox": [41.0, 331.0, 1210.0, 1703.0], "category_id": 4}, {"id": 5, "bbox": [1086.0, 251.0, 57.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [226.0, 251.0, 36.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [642.0, 148.0, 254.0, 103.0], "category_id": 2}], "reactions": [{"reactants": [2, 0], "conditions": [3, 7], "products": [1]}], "corefs": [[2, 6], [1, 5]], "caption": "Table 2. CO2 Incorporation with C C Bond Formation through Intramolecular Rearrangement with Various o-Alkynylaniline Derivatives ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 370, 128], "ImageBB": [71, 139, 407, 661]}, "diagram_type": "single"}, {"id": 125, "width": 948, "height": 1028, "file_name": "op9600419-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [196.0, 981.0, 35.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [513.0, 348.0, 35.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [591.0, 608.0, 357.0, 337.0], "category_id": 1}, {"id": 3, "bbox": [126.0, 0.0, 688.0, 341.0], "category_id": 1}, {"id": 4, "bbox": [2.0, 604.0, 454.0, 356.0], "category_id": 1}, {"id": 5, "bbox": [801.0, 960.0, 36.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [], "products": [4, 2]}], "corefs": [[3, 1], [4, 0], [2, 5]], "caption": "Figure 1. Retrosynthetic analysis.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 312, 264, 326], "ImageBB": [123, 52, 360, 309]}, "diagram_type": "tree"}, {"id": 555, "width": 1348, "height": 440, "file_name": "acs.orglett.5b02279-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [298.0, 88.6, 341.0, 182.4], "category_id": 1}, {"id": 1, "bbox": [1160.0, 288.05, 36.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [10.1, 40.3, 253.9, 271.7], "category_id": 1}, {"id": 3, "bbox": [637.0, 99.0, 276.0, 87.0], "category_id": 2}, {"id": 4, "bbox": [385.0, 289.0, 37.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [8.0, 369.0, 1340.0, 71.0], "category_id": 4}, {"id": 6, "bbox": [90.0, 298.0, 48.0, 43.0], "category_id": 3}, {"id": 7, "bbox": [915.0, 1.0, 431.0, 319.0], "category_id": 1}, {"id": 8, "bbox": [643.0, 212.0, 235.0, 93.0], "category_id": 2}], "reactions": [{"reactants": [2, 0], "conditions": [3, 8], "products": [7]}], "corefs": [[2, 6], [0, 4], [7, 1]], "caption": "Table 2. Scope of 2-(Chloromethyl)phenyl-carbamates 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 406, 110], "ImageBB": [82, 116, 419, 226]}, "diagram_type": "single"}, {"id": 1006, "width": 1252, "height": 1516, "file_name": "ja9612413-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [585.4, 1178.52, 459.52, 337.48], "category_id": 1}, {"id": 1, "bbox": [532.32, 4.55, 434.5, 336.72], "category_id": 1}, {"id": 2, "bbox": [368.53, 995.75, 309.38, 56.88], "category_id": 2}, {"id": 3, "bbox": [0.0, 1102.68, 294.97, 76.6], "category_id": 1}, {"id": 4, "bbox": [734.78, 339.75, 301.04, 78.88], "category_id": 1}, {"id": 5, "bbox": [89.48, 714.39, 217.63, 194.15], "category_id": 1}, {"id": 6, "bbox": [919.8, 991.96, 288.91, 53.09], "category_id": 2}, {"id": 7, "bbox": [997.15, 464.13, 185.02, 59.15], "category_id": 2}, {"id": 8, "bbox": [532.32, 550.58, 507.29, 336.72], "category_id": 1}, {"id": 9, "bbox": [764.35, 467.92, 207.78, 62.95], "category_id": 2}], "caption": "Scheme 1. Proposed Mechanism for Organolanthanide-Catalyzed Aminoolefin Hydroamination/Cyclization ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 50, 298, 92], "ImageBB": [85, 97, 398, 476]}, "reactions": [{"reactants": [1, 4], "conditions": [], "products": [8, 9]}, {"reactants": [8], "conditions": [6], "products": [0]}, {"reactants": [0, 3], "conditions": [2], "products": [5, 8]}], "diagram_type": "graph"}, {"id": 244, "width": 1308, "height": 1820, "file_name": "ol901684h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 72.0, 218.0, 149.0], "category_id": 1}, {"id": 1, "bbox": [532.0, 155.0, 339.0, 38.0], "category_id": 2}, {"id": 2, "bbox": [530.0, 2.0, 341.0, 132.0], "category_id": 2}, {"id": 3, "bbox": [902.0, 82.0, 400.0, 136.0], "category_id": 1}, {"id": 4, "bbox": [265.0, 124.0, 240.0, 45.0], "category_id": 1}, {"id": 5, "bbox": [1123.0, 220.0, 30.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 293.0, 1308.0, 1527.0], "category_id": 4}, {"id": 7, "bbox": [101.0, 218.0, 27.0, 42.0], "category_id": 3}, {"id": 8, "bbox": [376.0, 220.0, 32.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [0, 4], "conditions": [2, 1], "products": [3]}], "corefs": [[0, 7], [4, 8], [3, 5]], "caption": "Table 2. Nickel-Catalyzed Direct Alkynylation of Benzoxazole (1) with Various Alkynyl Bromides 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 752, 102], "ImageBB": [430, 111, 757, 566]}, "diagram_type": "single"}, {"id": 1062, "width": 1352, "height": 756, "file_name": "jo2020856-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [89.28, 16.24, 430.82, 275.41], "category_id": 1}, {"id": 1, "bbox": [587.74, 4.06, 315.85, 272.7], "category_id": 1}, {"id": 2, "bbox": [477.49, 393.83, 196.82, 242.93], "category_id": 1}, {"id": 3, "bbox": [685.81, 272.03, 62.9, 48.04], "category_id": 3}, {"id": 4, "bbox": [708.8, 359.32, 194.79, 155.63], "category_id": 1}, {"id": 5, "bbox": [380.1, 521.04, 74.4, 41.96], "category_id": 2}, {"id": 6, "bbox": [1061.17, 278.79, 54.79, 43.99], "category_id": 3}, {"id": 7, "bbox": [913.06, 154.96, 57.49, 39.92], "category_id": 2}, {"id": 8, "bbox": [537.69, 662.47, 56.13, 51.43], "category_id": 3}, {"id": 9, "bbox": [914.41, 383.68, 351.02, 274.05], "category_id": 1}, {"id": 10, "bbox": [87.92, 403.3, 237.4, 194.88], "category_id": 1}, {"id": 11, "bbox": [1137.6, 316.69, 83.87, 44.66], "category_id": 2}, {"id": 12, "bbox": [976.63, 8.8, 288.12, 273.38], "category_id": 1}, {"id": 13, "bbox": [1061.85, 660.44, 59.52, 47.37], "category_id": 3}], "caption": "Scheme 5. Plausible Reaction Mechanism for the Formation of Dihydroquinazolinone ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [448, 96, 783, 126], "ImageBB": [448, 132, 786, 321]}, "reactions": [{"reactants": [0], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [7], "products": [12]}, {"reactants": [12], "conditions": [11], "products": [9]}, {"reactants": [9], "conditions": [4], "products": [2]}, {"reactants": [2], "conditions": [5], "products": [10]}], "diagram_type": "tree"}, {"id": 579, "width": 1328, "height": 1588, "file_name": "acs.orglett.5b00312-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.0, 28.0, 228.0, 143.0], "category_id": 1}, {"id": 1, "bbox": [512.0, 188.0, 27.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [44.0, 14.0, 104.0, 164.0], "category_id": 1}, {"id": 3, "bbox": [283.0, 189.0, 68.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [65.0, 194.0, 50.0, 37.0], "category_id": 3}, {"id": 5, "bbox": [931.0, 8.0, 358.0, 185.0], "category_id": 1}, {"id": 6, "bbox": [3.0, 246.0, 1325.0, 1342.0], "category_id": 4}, {"id": 7, "bbox": [619.0, 1.0, 272.0, 80.0], "category_id": 2}, {"id": 8, "bbox": [704.0, 111.0, 113.0, 48.0], "category_id": 2}, {"id": 9, "bbox": [1074.0, 193.0, 90.0, 33.0], "category_id": 3}, {"id": 10, "bbox": [484.39, 20.7, 85.0, 155.4], "category_id": 1}], "reactions": [{"reactants": [2, 0, 10], "conditions": [7, 8], "products": [5]}], "corefs": [[2, 4], [0, 3], [10, 1], [5, 9]], "caption": "Table 3. Reaction of 2-Cyclohexenol with Phenylacetylenes", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 416, 111], "ImageBB": [85, 116, 417, 513]}, "diagram_type": "single"}, {"id": 926, "width": 3396, "height": 1036, "file_name": "acs.oprd.5b00027-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2296.84, 711.21, 73.05, 54.31], "category_id": 3}, {"id": 1, "bbox": [1885.72, 286.86, 319.39, 62.8], "category_id": 3}, {"id": 2, "bbox": [2307.56, 373.17, 99.88, 51.22], "category_id": 2}, {"id": 3, "bbox": [852.82, 476.97, 490.97, 224.05], "category_id": 1}, {"id": 4, "bbox": [1731.13, 502.43, 142.7, 69.59], "category_id": 2}, {"id": 5, "bbox": [1128.04, 98.45, 44.17, 52.62], "category_id": 3}, {"id": 6, "bbox": [2004.64, 432.4, 550.43, 268.62], "category_id": 1}, {"id": 7, "bbox": [927.57, 290.25, 71.35, 54.32], "category_id": 3}, {"id": 8, "bbox": [1211.28, 22.07, 458.69, 247.82], "category_id": 1}, {"id": 9, "bbox": [1505.18, 290.25, 66.26, 50.93], "category_id": 3}, {"id": 10, "bbox": [1561.24, 556.75, 64.56, 57.71], "category_id": 3}, {"id": 11, "bbox": [2002.94, 0.0, 552.13, 268.19], "category_id": 1}, {"id": 12, "bbox": [1087.26, 168.04, 149.5, 52.62], "category_id": 2}, {"id": 13, "bbox": [2288.3, 290.25, 52.71, 50.93], "category_id": 3}, {"id": 14, "bbox": [1731.13, 164.65, 142.7, 59.41], "category_id": 2}, {"id": 15, "bbox": [1406.65, 509.22, 105.33, 67.89], "category_id": 2}, {"id": 16, "bbox": [840.93, 42.43, 253.13, 218.97], "category_id": 1}, {"id": 17, "bbox": [1088.96, 714.6, 57.76, 50.92], "category_id": 3}, {"id": 18, "bbox": [1673.37, 45.83, 314.28, 100.15], "category_id": 2}], "caption": "Scheme 2. Improved synthetic route for 4-(1-piperazinyl)benzo[b]thiophene dihydrochloride (18)", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 836, 634, 851], "ImageBB": [10, 868, 859, 1127]}, "reactions": [{"reactants": [16], "conditions": [5, 12], "products": [8]}, {"reactants": [8], "conditions": [18, 14], "products": [11]}, {"reactants": [11], "conditions": [2], "products": [6]}, {"reactants": [8], "conditions": [1], "products": [6]}, {"reactants": [6], "conditions": [4], "products": [10]}, {"reactants": [10], "conditions": [15], "products": [3]}], "diagram_type": "graph"}, {"id": 49, "width": 1356, "height": 1484, "file_name": "ja408733f-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [853.09, 79.02, 117.22, 39.37], "category_id": 2}, {"id": 1, "bbox": [308.77, 142.55, 102.89, 38.74], "category_id": 2}, {"id": 2, "bbox": [995.09, 6.16, 333.33, 263.57], "category_id": 1}, {"id": 3, "bbox": [463.22, 6.16, 334.58, 263.57], "category_id": 1}, {"id": 4, "bbox": [23.53, 4.91, 265.44, 404.95], "category_id": 1}, {"id": 5, "bbox": [158.24, 805.8, 1037.9, 670.95], "category_id": 1}, {"id": 6, "bbox": [299.43, 72.8, 114.73, 38.12], "category_id": 2}, {"id": 7, "bbox": [461.98, 470.76, 332.7, 259.21], "category_id": 1}, {"id": 8, "bbox": [622.04, 340.6, 290.97, 79.22], "category_id": 2}, {"id": 9, "bbox": [433.33, 341.22, 141.51, 76.73], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [6], "products": [3]}, {"reactants": [3], "conditions": [1], "products": [4]}, {"reactants": [2], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [8], "products": [7]}, {"reactants": [7], "conditions": [9], "products": [3]}], "corefs": [], "caption": "Figure 1. Molecular structure of [\u03ba4-Tptm]ZnF.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 733, 679, 749], "ImageBB": [448, 355, 787, 726]}, "diagram_type": "tree"}, {"id": 179, "width": 1288, "height": 1132, "file_name": "op0602270-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [419.0, 28.0, 431.0, 59.0], "category_id": 2}, {"id": 1, "bbox": [367.0, 142.0, 552.0, 66.0], "category_id": 2}, {"id": 2, "bbox": [1087.0, 232.0, 50.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [66.0, 234.0, 229.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 0.0, 343.0, 230.0], "category_id": 1}, {"id": 5, "bbox": [30.2, 329.8, 1198.8, 796.6], "category_id": 1}, {"id": 6, "bbox": [937.7, 2.0, 350.3, 230.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0, 1], "products": [6]}], "corefs": [[4, 3], [6, 2]], "caption": "Figure 5. Dependency of the optical purity of ligand 6a on product selectivity. Reactions were carried out at 10 \u00b0C for 24 h with 0.0024 mmol [Rh(cod)2]BF4, 0.005 mmol ligand 6a and 0.24 mmol substrate in 2.0 mL of methanol. Conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 347, 775, 430], "ImageBB": [447, 53, 769, 336]}, "diagram_type": "single"}, {"id": 133, "width": 1000, "height": 1388, "file_name": "op900008a-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [632.0, 954.0, 29.0, 33.0], "category_id": 2}, {"id": 1, "bbox": [258.0, 969.0, 21.0, 21.0], "category_id": 2}, {"id": 2, "bbox": [410.0, 739.0, 26.0, 32.0], "category_id": 2}, {"id": 3, "bbox": [0.0, 973.0, 226.0, 152.0], "category_id": 1}, {"id": 4, "bbox": [531.0, 742.0, 428.0, 118.0], "category_id": 1}, {"id": 5, "bbox": [516.0, 1350.0, 43.0, 30.0], "category_id": 3}, {"id": 6, "bbox": [638.0, 1165.0, 33.0, 33.0], "category_id": 2}, {"id": 7, "bbox": [0.0, 731.0, 322.0, 122.8], "category_id": 1}, {"id": 8, "bbox": [117.0, 1100.0, 44.0, 34.0], "category_id": 3}, {"id": 9, "bbox": [688.0, 975.0, 304.0, 149.0], "category_id": 1}, {"id": 10, "bbox": [811.0, 893.0, 27.0, 35.0], "category_id": 2}, {"id": 11, "bbox": [512.0, 1109.0, 43.0, 35.0], "category_id": 3}, {"id": 12, "bbox": [321.0, 1214.0, 311.0, 150.0], "category_id": 1}, {"id": 13, "bbox": [0.0, 0.0, 995.0, 530.0], "category_id": 1}, {"id": 14, "bbox": [322.0, 968.0, 304.0, 155.3], "category_id": 1}, {"id": 15, "bbox": [798.0, 240.0, 33.0, 35.0], "category_id": 3}, {"id": 16, "bbox": [875.0, 1099.0, 40.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2], "products": [4]}, {"reactants": [4], "conditions": [10], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [14]}, {"reactants": [3], "conditions": [1], "products": [14]}, {"reactants": [9], "conditions": [6], "products": [12]}], "corefs": [[13, 15], [3, 8], [14, 11], [9, 16], [12, 5]], "caption": "Figure 2", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 183, 109, 197], "ImageBB": [108, 47, 358, 394]}, "diagram_type": "tree"}, {"id": 8, "width": 1352, "height": 1088, "file_name": "jacs.5b05415-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [528.0, 875.46, 243.47, 82.02], "category_id": 2}, {"id": 1, "bbox": [105.44, 270.39, 52.54, 44.12], "category_id": 3}, {"id": 2, "bbox": [532.21, 975.13, 233.64, 48.33], "category_id": 2}, {"id": 3, "bbox": [352.52, 684.53, 282.77, 84.83], "category_id": 2}, {"id": 4, "bbox": [732.97, 531.51, 155.02, 46.92], "category_id": 3}, {"id": 5, "bbox": [243.02, 1042.52, 66.57, 41.28], "category_id": 3}, {"id": 6, "bbox": [380.59, 621.36, 225.22, 45.52], "category_id": 2}, {"id": 7, "bbox": [353.92, 437.45, 281.37, 86.23], "category_id": 2}, {"id": 8, "bbox": [380.59, 375.68, 225.22, 45.52], "category_id": 2}, {"id": 9, "bbox": [359.54, 186.16, 267.33, 86.23], "category_id": 2}, {"id": 10, "bbox": [382.0, 128.6, 222.41, 44.12], "category_id": 2}, {"id": 11, "bbox": [160.19, 865.63, 232.23, 213.99], "category_id": 1}, {"id": 12, "bbox": [745.6, 344.8, 232.24, 213.98], "category_id": 1}, {"id": 13, "bbox": [1082.53, 96.31, 230.83, 166.25], "category_id": 1}, {"id": 14, "bbox": [745.6, 96.31, 233.64, 167.66], "category_id": 1}, {"id": 15, "bbox": [11.38, 611.53, 239.25, 166.26], "category_id": 1}, {"id": 16, "bbox": [11.38, 365.85, 240.66, 166.26], "category_id": 1}, {"id": 17, "bbox": [11.38, 114.56, 239.25, 128.35], "category_id": 1}, {"id": 18, "bbox": [101.22, 781.4, 58.16, 42.71], "category_id": 3}, {"id": 19, "bbox": [101.22, 531.51, 56.78, 44.12], "category_id": 3}, {"id": 20, "bbox": [1114.82, 268.99, 164.85, 44.11], "category_id": 3}, {"id": 21, "bbox": [716.12, 268.99, 289.79, 44.11], "category_id": 3}, {"id": 22, "bbox": [747.24, 644.9, 415.42, 75.17], "category_id": 2}, {"id": 23, "bbox": [854.06, 941.63, 340.25, 46.16], "category_id": 2}], "reactions": [{"reactants": [17], "conditions": [10, 9], "products": [14, 13]}, {"reactants": [16], "conditions": [8, 7], "products": [12]}, {"reactants": [15], "conditions": [6, 3], "products": [22]}, {"reactants": [11], "conditions": [0, 2], "products": [23]}], "corefs": [[17, 1], [14, 21], [13, 20], [16, 19], [12, 4], [15, 18], [11, 5]], "caption": "Figure 5. Challenges in gold-catalyzed cyclization.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1046, 321, 1060], "ImageBB": [82, 754, 420, 1026]}, "diagram_type": "multiple"}, {"id": 190, "width": 1016, "height": 772, "file_name": "op0601316-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [720.0, 462.3, 38.8, 58.4], "category_id": 1}, {"id": 1, "bbox": [837.3, 442.1, 125.2, 99.5], "category_id": 1}, {"id": 2, "bbox": [610.7, 442.0, 84.1, 96.7], "category_id": 1}, {"id": 3, "bbox": [693.1, 249.0, 66.5, 112.0], "category_id": 1}, {"id": 4, "bbox": [839.1, 115.4, 139.9, 156.3], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [2, 0], "conditions": [], "products": [1]}], "corefs": [], "caption": "Figure 5. Rate of HPP and benzoin formation as a function of benzaldehyde concentration. ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 250, 409, 278], "ImageBB": [115, 54, 369, 247]}, "diagram_type": "tree"}, {"id": 771, "width": 1224, "height": 1332, "file_name": "jo9602433-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 1033.43, 37.86, 75.0], "category_id": 3}, {"id": 1, "bbox": [566.0, 203.1, 432.2, 319.9], "category_id": 1}, {"id": 2, "bbox": [646.0, 1000.0, 467.0, 275.0], "category_id": 1}, {"id": 3, "bbox": [172.0, 986.0, 309.0, 68.0], "category_id": 2}, {"id": 4, "bbox": [242.0, 1083.0, 144.0, 63.0], "category_id": 2}, {"id": 5, "bbox": [862.0, 1288.0, 56.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [782.0, 540.0, 61.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [794.0, 803.0, 44.0, 54.0], "category_id": 3}, {"id": 8, "bbox": [413.0, 905.0, 277.0, 56.0], "category_id": 3}, {"id": 9, "bbox": [36.0, 781.0, 48.0, 63.0], "category_id": 3}, {"id": 10, "bbox": [21.0, 316.0, 53.0, 56.0], "category_id": 3}, {"id": 11, "bbox": [218.0, 1156.0, 229.0, 71.0], "category_id": 2}, {"id": 12, "bbox": [257.0, 1232.0, 163.0, 70.0], "category_id": 2}, {"id": 13, "bbox": [252.0, 238.0, 88.0, 59.0], "category_id": 2}], "reactions": [{"reactants": [10], "conditions": [13], "products": [1]}, {"reactants": [1], "conditions": [], "products": [10]}, {"reactants": [1], "conditions": [], "products": [9]}, {"reactants": [0], "conditions": [3, 4, 11, 12], "products": [2]}], "corefs": [[1, 6], [2, 5]], "caption": "Table 1. Treatment of (E)-3 with BTMABr3 or Br2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [451, 372, 743, 385], "ImageBB": [459, 26, 765, 359]}, "diagram_type": "tree"}, {"id": 1358, "width": 1068, "height": 1536, "file_name": "op9001824-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [496.3, 674.64, 44.56, 54.56], "category_id": 2}, {"id": 1, "bbox": [137.52, 487.16, 58.39, 53.78], "category_id": 2}, {"id": 2, "bbox": [33.6, 920.52, 396.5, 375.98], "category_id": 1}, {"id": 3, "bbox": [199.75, 381.89, 59.15, 45.33], "category_id": 3}, {"id": 4, "bbox": [808.98, 1428.43, 68.37, 49.17], "category_id": 3}, {"id": 5, "bbox": [496.3, 1240.17, 49.93, 56.09], "category_id": 2}, {"id": 6, "bbox": [199.75, 841.38, 59.15, 48.41], "category_id": 3}, {"id": 7, "bbox": [625.36, 0.0, 442.64, 380.35], "category_id": 1}, {"id": 8, "bbox": [625.36, 1045.77, 439.45, 379.58], "category_id": 1}, {"id": 9, "bbox": [808.98, 840.61, 59.16, 49.18], "category_id": 3}, {"id": 10, "bbox": [496.3, 216.68, 49.93, 52.25], "category_id": 2}, {"id": 11, "bbox": [770.57, 936.66, 61.46, 56.09], "category_id": 2}, {"id": 12, "bbox": [4.61, 0.0, 451.74, 378.05], "category_id": 1}, {"id": 13, "bbox": [198.98, 1493.74, 59.92, 42.26], "category_id": 3}, {"id": 14, "bbox": [806.67, 379.58, 70.68, 54.56], "category_id": 3}, {"id": 15, "bbox": [620.76, 456.42, 447.24, 381.12], "category_id": 1}, {"id": 16, "bbox": [6.91, 455.65, 449.44, 381.89], "category_id": 1}, {"id": 17, "bbox": [3.44, 1296.57, 459.22, 182.1], "category_id": 1}], "caption": "Scheme 6 a", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 492, 60], "ImageBB": [460, 69, 727, 453]}, "reactions": [{"reactants": [7], "conditions": [10], "products": [12]}, {"reactants": [12], "conditions": [1], "products": [16]}, {"reactants": [16], "conditions": [0], "products": [15]}, {"reactants": [15], "conditions": [11], "products": [8]}, {"reactants": [8], "conditions": [5], "products": [2, 17]}], "diagram_type": "tree"}, {"id": 1292, "width": 1356, "height": 900, "file_name": "op200112g-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [954.6, 340.37, 98.32, 42.14], "category_id": 2}, {"id": 1, "bbox": [0.0, 206.15, 384.62, 210.23], "category_id": 1}, {"id": 2, "bbox": [412.43, 540.47, 364.95, 314.66], "category_id": 1}, {"id": 3, "bbox": [89.54, 25.09, 267.27, 147.16], "category_id": 1}, {"id": 4, "bbox": [514.86, 0.0, 264.14, 187.9], "category_id": 1}, {"id": 5, "bbox": [982.8, 89.51, 367.09, 342.49], "category_id": 1}, {"id": 6, "bbox": [966.63, 541.83, 371.05, 307.87], "category_id": 1}, {"id": 7, "bbox": [537.55, 193.43, 332.77, 235.54], "category_id": 1}], "caption": "Scheme 6. Mechanism of the isoprenylation reaction utilized to form the \ufb01nal chromene ring system within GLY I ", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 123], "ImageBB": [71, 133, 410, 358]}, "reactions": [{"reactants": [3, 1], "conditions": [], "products": [4, 7]}, {"reactants": [4, 7], "conditions": [], "products": [3, 1]}, {"reactants": [4, 7], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [2]}], "diagram_type": "tree"}, {"id": 193, "width": 1356, "height": 1932, "file_name": "op060114g-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [591.0, 68.0, 281.0, 431.0], "category_id": 1}, {"id": 1, "bbox": [445.0, 1638.0, 376.0, 62.0], "category_id": 2}, {"id": 2, "bbox": [61.0, 376.0, 47.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [908.0, 701.0, 221.0, 55.0], "category_id": 2}, {"id": 4, "bbox": [6.0, 429.0, 169.0, 39.0], "category_id": 2}, {"id": 5, "bbox": [110.0, 1336.0, 272.0, 45.0], "category_id": 2}, {"id": 6, "bbox": [451.0, 920.0, 455.0, 106.0], "category_id": 2}, {"id": 7, "bbox": [433.0, 1069.0, 271.0, 63.0], "category_id": 2}, {"id": 8, "bbox": [449.0, 1534.0, 294.0, 64.0], "category_id": 2}, {"id": 9, "bbox": [806.0, 599.0, 325.0, 94.0], "category_id": 2}, {"id": 10, "bbox": [320.0, 282.0, 243.0, 58.0], "category_id": 2}, {"id": 11, "bbox": [316.0, 186.0, 235.0, 64.0], "category_id": 2}, {"id": 12, "bbox": [39.0, 793.0, 273.0, 423.0], "category_id": 1}, {"id": 13, "bbox": [1077.0, 775.0, 276.0, 426.0], "category_id": 1}, {"id": 14, "bbox": [1042.0, 78.0, 277.0, 413.0], "category_id": 1}, {"id": 15, "bbox": [34.0, 113.0, 264.0, 232.0], "category_id": 1}, {"id": 16, "bbox": [4.0, 1881.0, 200.0, 51.0], "category_id": 3}, {"id": 17, "bbox": [910.0, 1867.0, 294.0, 61.0], "category_id": 3}, {"id": 18, "bbox": [12.0, 1205.0, 166.0, 56.0], "category_id": 3}, {"id": 19, "bbox": [965.4, 1451.0, 283.6, 412.0], "category_id": 1}, {"id": 20, "bbox": [1000.0, 487.0, 202.0, 61.0], "category_id": 3}, {"id": 21, "bbox": [41.0, 1449.0, 273.2, 415.8], "category_id": 1}, {"id": 22, "bbox": [569.0, 491.0, 164.0, 53.0], "category_id": 3}, {"id": 23, "bbox": [1070.0, 1197.0, 165.0, 58.0], "category_id": 3}], "reactions": [{"reactants": [15], "conditions": [11, 10], "products": [0, 14]}, {"reactants": [0], "conditions": [9, 3], "products": [13]}, {"reactants": [13], "conditions": [6, 7], "products": [12]}, {"reactants": [12], "conditions": [5], "products": [21]}, {"reactants": [21], "conditions": [8, 1], "products": [19]}], "corefs": [[15, 2], [0, 22], [14, 20], [13, 23], [12, 18], [21, 16], [19, 17]], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 332, 129, 346], "ImageBB": [73, 356, 412, 839]}, "diagram_type": "tree"}, {"id": 429, "width": 1352, "height": 1104, "file_name": "op300205j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [950.0, 0.0, 180.7, 157.3], "category_id": 1}, {"id": 1, "bbox": [588.9, 0.0, 187.1, 164.2], "category_id": 1}, {"id": 2, "bbox": [205.0, 3.0, 213.0, 159.2], "category_id": 1}, {"id": 3, "bbox": [423.0, 8.0, 110.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [770.0, 12.0, 140.0, 54.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [4], "products": [0]}], "corefs": [], "caption": "Figure 1. (1) Reaction of 2-bromopyridine with n-BuLi followed by trapping with MeOH using the \ufb02ow microreactor system with the in- line mixer. (2) Reaction of 2-bromopyridine with n-BuLi followed by trapping with MeOH using the \ufb02ow microreactor system without the in-line mixer. (3) Reaction of 2-bromopyridine with n-BuLi followed by trapping with MeOH using a conventional macro batch system. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 431, 417, 514], "ImageBB": [82, 146, 420, 422]}, "diagram_type": "single"}, {"id": 401, "width": 3396, "height": 1640, "file_name": "op400292m-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2115.2, 945.2, 181.0, 238.2], "category_id": 1}, {"id": 1, "bbox": [1253.0, 1316.0, 279.0, 68.0], "category_id": 2}, {"id": 2, "bbox": [896.0, 1137.0, 300.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [1978.25, 328.24, 110.25, 191.96], "category_id": 1}, {"id": 4, "bbox": [1295.0, 983.0, 88.3, 55.8], "category_id": 2}, {"id": 5, "bbox": [1474.1, 990.3, 290.9, 160.3], "category_id": 1}, {"id": 6, "bbox": [835.1, 915.9, 400.1, 176.2], "category_id": 1}, {"id": 7, "bbox": [826.2, 1451.56, 98.4, 126.1], "category_id": 1}, {"id": 8, "bbox": [2103.0, 538.32, 283.0, 58.0], "category_id": 2}, {"id": 9, "bbox": [2205.0, 719.0, 283.0, 83.0], "category_id": 2}, {"id": 10, "bbox": [2230.0, 1206.0, 299.0, 71.0], "category_id": 2}, {"id": 11, "bbox": [1735.0, 1516.0, 277.9, 62.5], "category_id": 2}, {"id": 12, "bbox": [2186.0, 282.24, 183.1, 148.36], "category_id": 1}, {"id": 13, "bbox": [2117.0, 1454.8, 194.0, 185.2], "category_id": 1}, {"id": 14, "bbox": [1082.71, 1298.07, 188.09, 143.73], "category_id": 1}, {"id": 15, "bbox": [2422.0, 1077.0, 148.3, 41.0], "category_id": 2}, {"id": 16, "bbox": [998.0, 1503.0, 173.0, 56.5], "category_id": 2}, {"id": 17, "bbox": [1969.6, 1344.6, 98.7, 156.6], "category_id": 1}, {"id": 18, "bbox": [1803.0, 1110.2, 245.0, 54.8], "category_id": 2}, {"id": 19, "bbox": [1766.7, 481.6, 185.0, 283.5], "category_id": 1}, {"id": 20, "bbox": [1039.0, 730.12, 294.0, 71.0], "category_id": 2}, {"id": 21, "bbox": [1781.0, 838.0, 264.0, 93.0], "category_id": 2}, {"id": 22, "bbox": [958.2, 294.2, 139.1, 143.4], "category_id": 1}, {"id": 23, "bbox": [1785.0, 1239.0, 197.0, 54.0], "category_id": 2}, {"id": 24, "bbox": [1162.4, 525.0, 261.0, 223.1], "category_id": 1}, {"id": 25, "bbox": [1440.0, 722.0, 234.0, 91.0], "category_id": 2}, {"id": 26, "bbox": [1105.7, 289.0, 219.4, 216.4], "category_id": 1}, {"id": 27, "bbox": [2323.0, 1027.0, 80.0, 44.0], "category_id": 2}, {"id": 28, "bbox": [1801.0, 1027.0, 242.0, 58.0], "category_id": 2}], "reactions": [{"reactants": [22], "conditions": [26], "products": [24]}, {"reactants": [24], "conditions": [25], "products": [5]}, {"reactants": [12], "conditions": [3, 8], "products": [19]}, {"reactants": [19], "conditions": [21], "products": [5]}, {"reactants": [6], "conditions": [4], "products": [5]}, {"reactants": [15], "conditions": [27], "products": [0]}, {"reactants": [0], "conditions": [28, 18], "products": [5]}, {"reactants": [7], "conditions": [16], "products": [14]}, {"reactants": [14], "conditions": [], "products": [5]}, {"reactants": [13], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [23], "products": [5]}], "corefs": [], "caption": "Figure 2. Various approaches available to obtain the C2-symmetric diamines 1 or 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 442, 489, 457], "ImageBB": [10, 22, 859, 432]}, "diagram_type": "tree"}, {"id": 563, "width": 1352, "height": 828, "file_name": "acs.orglett.5b01754-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [53.2, 306.0, 1278.8, 522.0], "category_id": 4}, {"id": 1, "bbox": [492.0, 167.0, 393.0, 110.0], "category_id": 2}, {"id": 2, "bbox": [525.0, 6.0, 292.0, 103.0], "category_id": 2}, {"id": 3, "bbox": [69.0, 16.0, 329.0, 266.0], "category_id": 1}, {"id": 4, "bbox": [1210.0, 222.0, 69.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [948.0, 5.0, 336.0, 269.0], "category_id": 1}, {"id": 6, "bbox": [312.0, 219.0, 78.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [2, 1], "products": [5]}], "corefs": [[3, 6], [5, 4]], "caption": "Table 1. Proposed Direct Interconversion of BINOL and H8-BINOL-Based Chiral Br\u00f8nsted Acids ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 759, 404, 789], "ImageBB": [82, 796, 420, 1003]}, "diagram_type": "single"}, {"id": 99, "width": 1356, "height": 1412, "file_name": "ja0289088-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.5, 249.01, 360.3, 82.92], "category_id": 2}, {"id": 1, "bbox": [575.34, 164.79, 163.86, 119.25], "category_id": 1}, {"id": 2, "bbox": [273.12, 16.15, 200.18, 157.24], "category_id": 1}, {"id": 3, "bbox": [15.49, 173.04, 163.81, 117.61], "category_id": 1}, {"id": 4, "bbox": [1128.58, 173.04, 165.49, 115.95], "category_id": 1}, {"id": 5, "bbox": [5.55, 442.6, 1342.95, 962.19], "category_id": 4}, {"id": 6, "bbox": [885.81, 120.2, 59.81, 43.28], "category_id": 1}, {"id": 7, "bbox": [377.16, 131.76, 102.74, 54.84], "category_id": 1}, {"id": 8, "bbox": [785.07, 7.9, 200.18, 157.23], "category_id": 1}, {"id": 9, "bbox": [273.12, 189.56, 125.86, 39.98], "category_id": 2}, {"id": 10, "bbox": [241.63, 116.35, 23.96, 30.8], "category_id": 3}, {"id": 11, "bbox": [811.5, 191.21, 203.48, 36.68], "category_id": 2}, {"id": 12, "bbox": [743.79, 237.5, 390.09, 127.46], "category_id": 2}, {"id": 13, "bbox": [963.43, 125.15, 142.38, 35.05], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [2, 7, 9, 0], "products": [3]}, {"reactants": [1], "conditions": [8, 6, 13, 11, 12], "products": [4]}], "corefs": [[2, 10]], "caption": "Table 2. Epoxidation Reaction with Peroxymonosulfate Ammonium 6b (Method A) or Using the Corresponding Hydrochloride in Catalytic Amount (Method B) and Epoxidation Reaction at -10 \u00b0C (Method C) ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 388, 113], "ImageBB": [73, 112, 412, 465]}, "diagram_type": "single"}, {"id": 188, "width": 1344, "height": 380, "file_name": "op060155c-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [567.0, 139.0, 170.0, 87.0], "category_id": 2}, {"id": 1, "bbox": [570.0, 281.0, 173.0, 90.0], "category_id": 2}, {"id": 2, "bbox": [357.1, 126.0, 162.9, 193.8], "category_id": 1}, {"id": 3, "bbox": [773.0, 124.1, 215.9, 199.9], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 1], "products": [3]}], "corefs": [], "caption": "Figure 2. Lithium exchange in MeTHF.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 338, 299, 352], "ImageBB": [74, 238, 410, 333]}, "diagram_type": "single"}, {"id": 669, "width": 1348, "height": 1540, "file_name": "ol401909z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [979.0, 250.0, 49.0, 62.0], "category_id": 3}, {"id": 1, "bbox": [805.9, 2.0, 510.2, 342.1], "category_id": 1}, {"id": 2, "bbox": [616.0, 82.0, 177.0, 49.0], "category_id": 2}, {"id": 3, "bbox": [30.9, 5.0, 249.2, 246.1], "category_id": 1}, {"id": 4, "bbox": [313.0, 0.0, 331.8, 246.2], "category_id": 1}, {"id": 5, "bbox": [491.0, 204.0, 52.1, 53.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 376.9, 1342.0, 1163.1], "category_id": 4}], "reactions": [{"reactants": [3, 4], "conditions": [2], "products": [1]}], "corefs": [[4, 5], [1, 0]], "caption": "Table 1. Screening of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 688, 101], "ImageBB": [436, 112, 773, 497]}, "diagram_type": "single"}, {"id": 830, "width": 1260, "height": 1896, "file_name": "jo4004426-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [798.0, 943.0, 401.1, 307.0], "category_id": 1}, {"id": 1, "bbox": [830.6, 631.0, 376.7, 293.0], "category_id": 1}, {"id": 2, "bbox": [95.2, 298.0, 347.8, 303.7], "category_id": 1}, {"id": 3, "bbox": [556.6, 324.8, 266.4, 281.9], "category_id": 1}, {"id": 4, "bbox": [848.0, 321.0, 374.0, 285.4], "category_id": 1}, {"id": 5, "bbox": [946.0, 8.0, 314.0, 277.4], "category_id": 1}, {"id": 6, "bbox": [228.0, 5.0, 185.3, 276.5], "category_id": 1}, {"id": 7, "bbox": [0.0, 22.0, 164.5, 192.1], "category_id": 1}, {"id": 8, "bbox": [84.2, 1259.0, 366.8, 304.0], "category_id": 1}, {"id": 9, "bbox": [116.0, 1591.0, 324.0, 299.0], "category_id": 1}, {"id": 10, "bbox": [460.0, 1284.0, 366.4, 279.0], "category_id": 1}, {"id": 11, "bbox": [52.0, 865.0, 290.0, 59.0], "category_id": 3}, {"id": 12, "bbox": [60.0, 1845.0, 171.0, 51.0], "category_id": 3}, {"id": 13, "bbox": [435.0, 1845.0, 181.0, 51.0], "category_id": 3}, {"id": 14, "bbox": [823.0, 1837.0, 151.0, 59.0], "category_id": 3}, {"id": 15, "bbox": [826.0, 1502.0, 276.0, 61.0], "category_id": 3}, {"id": 16, "bbox": [74.0, 1507.0, 151.0, 67.0], "category_id": 3}, {"id": 17, "bbox": [451.0, 1513.0, 160.0, 59.0], "category_id": 3}, {"id": 18, "bbox": [809.0, 1197.0, 156.0, 53.0], "category_id": 3}, {"id": 19, "bbox": [440.0, 1181.0, 176.0, 67.0], "category_id": 3}, {"id": 20, "bbox": [55.0, 1192.0, 181.0, 61.0], "category_id": 3}, {"id": 21, "bbox": [823.0, 871.0, 170.0, 44.0], "category_id": 3}, {"id": 22, "bbox": [451.0, 868.0, 162.0, 59.0], "category_id": 3}, {"id": 23, "bbox": [94.0, 622.0, 349.0, 299.0], "category_id": 1}, {"id": 24, "bbox": [513.0, 617.0, 310.0, 304.0], "category_id": 1}, {"id": 25, "bbox": [476.0, 941.0, 355.0, 312.0], "category_id": 1}, {"id": 26, "bbox": [778.0, 1262.0, 433.0, 301.0], "category_id": 1}, {"id": 27, "bbox": [837.0, 1569.0, 377.0, 318.0], "category_id": 1}, {"id": 28, "bbox": [443.0, 1586.0, 391.0, 304.0], "category_id": 1}, {"id": 29, "bbox": [496.0, 16.0, 413.0, 112.0], "category_id": 2}, {"id": 30, "bbox": [435.0, 175.0, 508.0, 112.0], "category_id": 2}, {"id": 31, "bbox": [393.0, 220.0, 30.0, 39.0], "category_id": 3}, {"id": 32, "bbox": [1046.0, 226.0, 92.0, 47.0], "category_id": 3}, {"id": 33, "bbox": [72.0, 544.0, 296.0, 70.0], "category_id": 3}, {"id": 34, "bbox": [460.0, 541.0, 282.0, 62.0], "category_id": 3}, {"id": 35, "bbox": [828.0, 552.0, 171.0, 56.0], "category_id": 3}, {"id": 36, "bbox": [88.0, 943.0, 366.5, 299.0], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [29, 30], "products": [5]}], "corefs": [[6, 31], [5, 32], [2, 33], [3, 34], [4, 35], [23, 11], [24, 22], [1, 21], [36, 20], [25, 19], [0, 18], [8, 16], [10, 17], [26, 15], [9, 12], [28, 13], [27, 14]], "caption": "Table 3. Scope of the Reaction", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 625, 110], "ImageBB": [460, 116, 775, 590]}, "diagram_type": "single"}, {"id": 1264, "width": 736, "height": 608, "file_name": "op050182n-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [554.49, 232.36, 168.99, 154.29], "category_id": 1}, {"id": 1, "bbox": [121.13, 103.84, 34.24, 41.25], "category_id": 3}, {"id": 2, "bbox": [331.0, 562.67, 47.86, 45.33], "category_id": 3}, {"id": 3, "bbox": [61.85, 48.61, 160.53, 51.55], "category_id": 1}, {"id": 4, "bbox": [270.62, 440.0, 169.36, 150.8], "category_id": 1}, {"id": 5, "bbox": [571.42, 0.0, 164.58, 124.8], "category_id": 1}, {"id": 6, "bbox": [331.0, 321.11, 96.83, 49.34], "category_id": 2}, {"id": 7, "bbox": [331.0, 160.19, 92.78, 48.6], "category_id": 2}, {"id": 8, "bbox": [652.42, 121.52, 50.44, 41.98], "category_id": 3}, {"id": 9, "bbox": [57.07, 372.29, 42.34, 45.66], "category_id": 3}, {"id": 10, "bbox": [0.0, 268.45, 185.2, 131.46], "category_id": 1}, {"id": 11, "bbox": [607.5, 369.72, 51.18, 47.13], "category_id": 3}], "caption": "Scheme 3. New synthetic strategy for conversion of nitriles to chiral amines ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 445, 406, 473], "ImageBB": [150, 477, 334, 629]}, "reactions": [{"reactants": [3], "conditions": [], "products": [5]}, {"reactants": [3], "conditions": [], "products": [10]}, {"reactants": [0], "conditions": [], "products": [5, 7]}, {"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [10, 6], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [0]}], "diagram_type": "graph"}, {"id": 633, "width": 1348, "height": 388, "file_name": "ol5012407-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [921.0, 28.0, 293.0, 215.0], "category_id": 1}, {"id": 1, "bbox": [39.0, 313.0, 1284.0, 63.0], "category_id": 4}, {"id": 2, "bbox": [520.0, 216.0, 127.0, 42.0], "category_id": 2}, {"id": 3, "bbox": [260.0, 246.0, 47.0, 40.0], "category_id": 3}, {"id": 4, "bbox": [140.0, 5.0, 293.0, 227.0], "category_id": 1}, {"id": 5, "bbox": [1038.0, 246.0, 56.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [515.0, 52.0, 227.0, 130.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [6, 2], "products": [0]}], "corefs": [[4, 3], [0, 5]], "caption": "Table 1. 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Conversion of Aldehyde 5 to Tri\ufb02ate 4", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 732, 110], "ImageBB": [448, 116, 787, 486]}, "reactions": [{"reactants": [10, 12], "conditions": [5], "products": [7]}, {"reactants": [7], "conditions": [3], "products": [22, 17]}, {"reactants": [22], "conditions": [0], "products": [17]}, {"reactants": [17], "conditions": [1, 13], "products": [19]}, {"reactants": [19], "conditions": [8, 9], "products": [18]}, {"reactants": [18], "conditions": [4, 2], "products": [15]}], "diagram_type": "multiple"}, {"id": 48, "width": 1352, "height": 1820, "file_name": "ja408733f-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [364.33, 441.71, 98.0, 35.95], "category_id": 2}, {"id": 1, "bbox": [523.35, 309.95, 305.23, 242.6], "category_id": 1}, {"id": 2, "bbox": [856.55, 377.53, 113.92, 35.95], "category_id": 2}, {"id": 3, "bbox": [572.78, 216.29, 58.22, 34.88], "category_id": 2}, {"id": 4, "bbox": [672.5, 216.82, 83.15, 34.88], "category_id": 2}, {"id": 5, "bbox": [388.72, 367.98, 73.08, 36.48], "category_id": 2}, {"id": 6, "bbox": [522.59, 689.56, 344.18, 377.03], "category_id": 1}, {"id": 7, "bbox": [690.63, 565.06, 167.74, 118.86], "category_id": 1}, {"id": 8, "bbox": [460.72, 565.06, 167.75, 118.86], "category_id": 1}, {"id": 9, "bbox": [25.36, 225.93, 305.23, 327.38], "category_id": 1}, {"id": 10, "bbox": [1015.24, 206.07, 305.23, 346.48], "category_id": 1}, {"id": 11, "bbox": [391.22, 2.9, 519.85, 152.47], "category_id": 1}, {"id": 12, "bbox": [29.53, 1144.91, 1292.75, 668.44], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2], "products": [10]}, {"reactants": [1], "conditions": [5], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [1]}, {"reactants": [1], "conditions": [3], "products": [11]}, {"reactants": [11], "conditions": [4], "products": [1]}, {"reactants": [1], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [7], "products": [1]}], "corefs": [], "caption": "Figure 2. Molecular structure of [\u03ba4-Tptm]ZnF\u00b7H2O.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 578, 338, 595], "ImageBB": [82, 116, 420, 571]}, "diagram_type": "tree"}, {"id": 1046, "width": 2148, "height": 980, "file_name": "jo0108865-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [583.4, 302.6, 361.4, 58.3], "category_id": 3}, {"id": 1, "bbox": [1527.99, 29.02, 260.04, 66.64], "category_id": 2}, {"id": 2, "bbox": [0.0, 64.49, 274.01, 232.16], "category_id": 1}, {"id": 3, "bbox": [593.14, 54.82, 256.82, 230.01], "category_id": 1}, {"id": 4, "bbox": [1527.99, 133.28, 247.15, 146.18], "category_id": 1}, {"id": 5, "bbox": [322.36, 868.46, 287.98, 109.64], "category_id": 3}, {"id": 6, "bbox": [1212.08, 29.02, 213.83, 226.79], "category_id": 1}, {"id": 7, "bbox": [1016.51, 54.82, 103.16, 59.11], "category_id": 2}, {"id": 8, "bbox": [1867.55, 326.75, 280.45, 112.86], "category_id": 3}, {"id": 9, "bbox": [1896.56, 3.22, 251.44, 271.94], "category_id": 1}, {"id": 10, "bbox": [1244.31, 349.32, 68.77, 61.27], "category_id": 3}, {"id": 11, "bbox": [112.83, 705.09, 46.2, 59.11], "category_id": 3}, {"id": 12, "bbox": [12.89, 310.63, 266.49, 65.56], "category_id": 3}, {"id": 13, "bbox": [294.42, 75.24, 206.31, 76.31], "category_id": 2}, {"id": 14, "bbox": [1290.52, 241.84, 177.3, 60.19], "category_id": 2}, {"id": 15, "bbox": [325.58, 601.9, 208.47, 265.49], "category_id": 1}, {"id": 16, "bbox": [583.1, 378.99, 187.91, 51.84], "category_id": 3}, {"id": 17, "bbox": [581.48, 453.51, 507.03, 55.07], "category_id": 3}, {"id": 18, "bbox": [385.47, 351.45, 129.59, 48.6], "category_id": 2}, {"id": 19, "bbox": [398.43, 434.07, 115.01, 56.69], "category_id": 2}], "caption": "Scheme 6", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 163, 453, 177], "ImageBB": [156, 186, 693, 431]}, "reactions": [{"reactants": [2], "conditions": [13], "products": [3]}, {"reactants": [3], "conditions": [7], "products": [6]}, {"reactants": [6], "conditions": [1, 4], "products": [9]}, {"reactants": [0], "conditions": [18], "products": [16]}, {"reactants": [16], "conditions": [19], "products": [17]}, {"reactants": [9], "conditions": [11], "products": [15]}], "diagram_type": "multiple"}, {"id": 484, "width": 1352, "height": 1260, "file_name": "ol061289d-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [222.0, 188.0, 442.0, 264.0], "category_id": 1}, {"id": 1, "bbox": [400.0, 514.0, 51.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [888.0, 519.0, 67.0, 55.0], "category_id": 3}, {"id": 3, "bbox": [551.0, 957.0, 62.0, 59.0], "category_id": 3}, {"id": 4, "bbox": [443.0, 674.0, 47.0, 46.0], "category_id": 3}, {"id": 5, "bbox": [844.0, 634.0, 266.0, 71.0], "category_id": 2}, {"id": 6, "bbox": [840.0, 926.0, 228.0, 47.0], "category_id": 2}, {"id": 7, "bbox": [686.0, 140.9, 442.0, 358.1], "category_id": 1}, {"id": 8, "bbox": [275.71, 592.91, 839.44, 665.47], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [], "products": [7]}], "corefs": [[0, 1], [7, 2]], "caption": "Figure 3. HPLC chromatographs for the reaction of 7 with methyl bromoacetate. HPLC conditions: Kromasil C18, 15-45% B in A over 25 min, A ) H2O + 0.1% TFA, B ) CH3CN + 0.08% TFA ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 379, 775, 421], "ImageBB": [439, 52, 777, 367]}, "diagram_type": "single"}, {"id": 343, "width": 1348, "height": 884, "file_name": "ol202395s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1007.0, 308.0, 261.2, 115.0], "category_id": 3}, {"id": 1, "bbox": [67.0, 304.0, 250.6, 110.1], "category_id": 3}, {"id": 2, "bbox": [8.0, 547.0, 1339.0, 337.0], "category_id": 4}, {"id": 3, "bbox": [679.0, 154.7, 271.0, 121.3], "category_id": 2}, {"id": 4, "bbox": [388.9, 31.0, 298.1, 210.1], "category_id": 1}, {"id": 5, "bbox": [747.0, 71.0, 110.0, 65.0], "category_id": 2}, {"id": 6, "bbox": [955.4, 3.0, 376.6, 297.0], "category_id": 1}, {"id": 7, "bbox": [16.0, 3.0, 347.0, 254.0], "category_id": 1}, {"id": 8, "bbox": [482.0, 312.3, 73.4, 62.7], "category_id": 3}], "reactions": [{"reactants": [7, 4], "conditions": [5, 3], "products": [6]}], "corefs": [[7, 1], [4, 8], [6, 0]], "caption": "Table 2. Reaction of P-Alkynyl-\u03bb5-phosphazenes 4 and P- Alkynylphosphane Sulphide 5 with in-situ Generated Benzynea ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 771, 115], "ImageBB": [436, 126, 773, 347]}, "diagram_type": "single"}, {"id": 15, "width": 1348, "height": 616, "file_name": "ja9612413-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [864.78, 7.22, 157.82, 115.52], "category_id": 1}, {"id": 1, "bbox": [6.65, 168.74, 1337.05, 441.36], "category_id": 4}, {"id": 2, "bbox": [312.23, 23.26, 382.47, 82.06], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [0]}], "corefs": [], "caption": "Table 3. Metal Size and Ancillary Ligation Effects on the Turnover Frequencies for Primary Aminoalkyne Hydroamination/ Cyclization ", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 259, 758, 297], "ImageBB": [438, 305, 775, 458]}, "diagram_type": "single"}, {"id": 68, "width": 1356, "height": 1044, "file_name": "ja300396h-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [965.36, 83.13, 220.19, 105.57], "category_id": 1}, {"id": 1, "bbox": [607.84, 64.72, 69.82, 35.13], "category_id": 2}, {"id": 2, "bbox": [426.45, 79.97, 127.13, 59.84], "category_id": 1}, {"id": 3, "bbox": [808.31, 225.19, 25.31, 24.04], "category_id": 3}, {"id": 4, "bbox": [1061.4, 220.13, 54.42, 37.96], "category_id": 3}, {"id": 5, "bbox": [210.36, 79.97, 122.93, 59.84], "category_id": 1}, {"id": 6, "bbox": [749.27, 43.17, 146.06, 147.63], "category_id": 1}], "reactions": [{"reactants": [5, 2], "conditions": [1], "products": [6, 0]}], "corefs": [[6, 3], [0, 4]], "caption": "Figure 4. Catalytic activity and regioselectivity outcome in hydro- thiolation of phenylacetylene with thiophenol for catalysts 2 (blue circles), 4 (green crosses), and 2 + 10 equiv of pyridine (red triangles). ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 737, 784, 779], "ImageBB": [448, 467, 787, 728]}, "diagram_type": "single"}, {"id": 772, "width": 1308, "height": 1808, "file_name": "jo9521209-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1109.0, 1208.0, 65.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [1098.0, 1251.0, 60.0, 55.0], "category_id": 3}, {"id": 2, "bbox": [558.0, 1260.0, 66.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [636.0, 1258.0, 440.0, 47.0], "category_id": 2}, {"id": 4, "bbox": [635.0, 1195.0, 444.0, 56.0], "category_id": 2}, {"id": 5, "bbox": [564.0, 1201.4, 56.4, 52.6], "category_id": 3}, {"id": 6, "bbox": [0.0, 1122.0, 501.6, 116.5], "category_id": 3}, {"id": 7, "bbox": [493.73, 559.15, 326.0, 56.0], "category_id": 3}, {"id": 8, "bbox": [724.0, 1362.6, 268.0, 97.4], "category_id": 2}, {"id": 9, "bbox": [923.0, 556.0, 299.0, 54.0], "category_id": 3}, {"id": 10, "bbox": [675.0, 637.0, 353.0, 116.0], "category_id": 2}, {"id": 11, "bbox": [538.0, 1133.0, 284.0, 54.0], "category_id": 2}, {"id": 12, "bbox": [1062.0, 1763.0, 57.0, 45.0], "category_id": 3}, {"id": 13, "bbox": [518.1, 1476.4, 301.9, 262.3], "category_id": 1}, {"id": 14, "bbox": [934.7, 1486.0, 302.6, 277.4], "category_id": 1}, {"id": 15, "bbox": [469.0, 679.0, 147.0, 37.0], "category_id": 2}, {"id": 16, "bbox": [955.0, 1133.0, 269.0, 49.0], "category_id": 2}, {"id": 17, "bbox": [606.0, 1749.0, 69.0, 49.0], "category_id": 3}, {"id": 18, "bbox": [315.0, 1000.0, 181.0, 67.0], "category_id": 2}, {"id": 19, "bbox": [505.8, 195.7, 295.1, 343.8], "category_id": 1}, {"id": 20, "bbox": [914.8, 202.7, 311.8, 338.6], "category_id": 1}, {"id": 21, "bbox": [1104.0, 674.0, 162.0, 64.0], "category_id": 2}, {"id": 22, "bbox": [8.46, 784.69, 289.24, 309.31], "category_id": 1}, {"id": 23, "bbox": [346.0, 833.3, 120.0, 111.0], "category_id": 1}, {"id": 24, "bbox": [535.6, 766.8, 294.2, 349.2], "category_id": 1}, {"id": 25, "bbox": [945.0, 765.0, 306.0, 353.7], "category_id": 1}], "reactions": [{"reactants": [22], "conditions": [23, 18], "products": [24, 25]}, {"reactants": [24], "conditions": [15, 10], "products": [19]}, {"reactants": [25], "conditions": [21, 10], "products": [20]}, {"reactants": [24], "conditions": [8], "products": [13]}, {"reactants": [25], "conditions": [8], "products": [14]}], "corefs": [[22, 6], [19, 7], [20, 9], [24, 5], [24, 2], [25, 0], [25, 1], [13, 17], [14, 12]], "caption": "Table 1. Diels-Alder reactions of 6 and 7 with               cyclopentadiene ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [459, 490, 735, 515], "ImageBB": [440, 26, 767, 478]}, "diagram_type": "tree"}, {"id": 890, "width": 1348, "height": 384, "file_name": "acs.oprd.5b00144-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [119.0, 27.4, 478.0, 187.6], "category_id": 1}, {"id": 1, "bbox": [1048.0, 242.0, 35.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [682.0, 56.0, 101.0, 56.0], "category_id": 2}, {"id": 3, "bbox": [886.0, 1.0, 350.0, 210.0], "category_id": 1}, {"id": 4, "bbox": [371.0, 241.0, 52.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [3.0, 309.0, 1345.0, 75.0], "category_id": 4}, {"id": 6, "bbox": [486.96, 8.04, 74.21, 41.68], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [6, 2], "products": [3]}], "corefs": [[0, 4], [3, 1]], "caption": "Table 1. Reaction Condition Optimization of Friedel\u2212Crafts Alkylation in the Synthesis of Racemic Lorcaserin ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 529, 417, 559], "ImageBB": [82, 566, 419, 662]}, "diagram_type": "single"}, {"id": 988, "width": 2824, "height": 2448, "file_name": "ja204366b-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1271.07, 332.13, 390.86, 235.1], "category_id": 1}, {"id": 1, "bbox": [4.46, 323.31, 452.57, 235.11], "category_id": 1}, {"id": 2, "bbox": [680.92, 964.48, 572.15, 242.88], "category_id": 1}, {"id": 3, "bbox": [954.99, 1334.45, 214.73, 57.9], "category_id": 2}, {"id": 4, "bbox": [1641.56, 1156.52, 66.4, 52.25], "category_id": 3}, {"id": 5, "bbox": [1425.42, 1208.77, 422.4, 55.08], "category_id": 3}, {"id": 6, "bbox": [1742.4, 797.85, 168.99, 69.19], "category_id": 2}, {"id": 7, "bbox": [464.5, 1269.49, 484.84, 248.54], "category_id": 1}, {"id": 8, "bbox": [2136.27, 1214.65, 402.13, 46.25], 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Synthesis of the First-Generation Self-Assembling Dendrons and of the Corresponding Dendronized PBI (3,4,5)12G1-m-PBI with m = 0, 1, 2, 3, 4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 714, 123], "ImageBB": [71, 133, 777, 745]}, "reactions": [{"reactants": [17], "conditions": [72, 71], "products": [11]}, {"reactants": [1], "conditions": [24], "products": [23]}, {"reactants": [23], "conditions": [53], "products": [0]}, {"reactants": [0], "conditions": [25, 54], "products": [76]}, {"reactants": [76], "conditions": [74, 55], "products": [73]}, {"reactants": [23], "conditions": [56], "products": [9]}, {"reactants": [9], "conditions": [57, 44], "products": [26]}, {"reactants": [26], "conditions": [21, 6], "products": [42]}, {"reactants": [19], "conditions": [39, 27], "products": [2]}, {"reactants": [2], "conditions": [69], "products": [29]}, {"reactants": [29], "conditions": [58, 15], "products": [43]}, {"reactants": [13], "conditions": [22, 61], "products": [7]}, {"reactants": [7], "conditions": [3, 62], "products": [50]}, {"reactants": [13], "conditions": [14, 46], "products": [33]}, {"reactants": [33], "conditions": [47, 65], "products": [36]}, {"reactants": [18, 70], "conditions": [49, 64], "products": [20]}], "diagram_type": "tree"}, {"id": 914, "width": 1356, "height": 940, "file_name": "acs.joc.5b00632-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1014.12, 209.62, 55.62, 46.13], "category_id": 3}, {"id": 1, "bbox": [590.16, 58.34, 156.69, 49.52], "category_id": 2}, {"id": 2, "bbox": [354.09, 274.74, 167.55, 94.3], "category_id": 2}, {"id": 3, "bbox": [145.84, 2.71, 415.15, 193.34], "category_id": 1}, {"id": 4, "bbox": [1014.12, 598.33, 52.91, 45.45], "category_id": 3}, {"id": 5, "bbox": [619.32, 686.52, 358.17, 176.38], "category_id": 1}, {"id": 6, "bbox": [277.44, 202.84, 42.74, 46.13], "category_id": 3}, {"id": 7, "bbox": [799.08, 8.82, 410.4, 217.76], "category_id": 1}, {"id": 8, "bbox": [591.51, 398.89, 183.15, 94.97], "category_id": 2}, {"id": 9, "bbox": [187.9, 415.17, 359.52, 196.05], "category_id": 1}, {"id": 10, "bbox": [196.04, 633.61, 330.35, 131.6], "category_id": 2}, {"id": 11, "bbox": [805.87, 394.82, 402.25, 196.73], "category_id": 1}], "caption": "Scheme 4. 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Optimization of the Pd-Catalyzed Cyclization of Propargylic Carbonate 1aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 569, 379, 597], "ImageBB": [74, 599, 410, 713]}, "diagram_type": "single"}, {"id": 1001, "width": 2756, "height": 820, "file_name": "ja801487v-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1167.75, 303.01, 187.5, 139.12], "category_id": 1}, {"id": 1, "bbox": [1983.93, 685.91, 115.81, 112.95], "category_id": 2}, {"id": 2, "bbox": [1666.88, 315.48, 184.98, 58.2], "category_id": 2}, {"id": 3, "bbox": [413.61, 323.67, 68.93, 49.59], "category_id": 2}, {"id": 4, "bbox": [2159.03, 5.51, 539.07, 104.29], "category_id": 2}, {"id": 5, "bbox": [2160.41, 709.7, 590.08, 108.44], "category_id": 2}, {"id": 6, "bbox": [1651.67, 696.93, 231.62, 57.85], "category_id": 2}, {"id": 7, "bbox": [2176.95, 331.94, 533.55, 111.56], "category_id": 2}, {"id": 8, "bbox": [1647.53, 0.0, 228.87, 55.09], "category_id": 2}, {"id": 9, "bbox": [1198.08, 462.79, 63.42, 49.58], "category_id": 3}, {"id": 10, "bbox": [107.54, 472.43, 195.77, 49.58], "category_id": 3}, {"id": 11, "bbox": [991.28, 327.81, 117.19, 50.96], "category_id": 2}, {"id": 12, "bbox": [1983.93, 30.3, 107.54, 48.21], "category_id": 3}, {"id": 13, "bbox": [0.0, 309.9, 359.84, 137.74], "category_id": 1}, {"id": 14, "bbox": [1948.09, 285.11, 150.28, 191.45], "category_id": 3}, {"id": 15, "bbox": [1422.81, 318.17, 140.62, 103.3], "category_id": 1}, {"id": 16, "bbox": [1483.47, 460.03, 62.04, 52.34], "category_id": 3}, {"id": 17, "bbox": [552.85, 311.28, 358.46, 137.73], "category_id": 1}], "caption": "Scheme 1. 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Plan for the Dichotomous Synthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 621, 320, 634], "ImageBB": [71, 644, 407, 981]}, "reactions": [{"reactants": [6, 4], "conditions": [16], "products": [19]}, {"reactants": [7, 26], "conditions": [23], "products": [27]}, {"reactants": [27, 13], "conditions": [8], "products": [6]}, {"reactants": [27, 15], "conditions": [2], "products": [14]}, {"reactants": [14, 9], "conditions": [10], "products": [21]}], "diagram_type": "tree"}, {"id": 1351, "width": 1356, "height": 680, "file_name": "op800033c-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [659.35, 240.98, 442.27, 174.45], "category_id": 1}, {"id": 1, "bbox": [333.74, 2.72, 318.14, 52.26], "category_id": 2}, {"id": 2, "bbox": [1125.36, 76.03, 103.79, 46.84], "category_id": 2}, {"id": 3, "bbox": [438.89, 255.91, 211.64, 45.48], "category_id": 2}, {"id": 4, "bbox": [177.05, 456.84, 527.74, 171.06], "category_id": 1}, {"id": 5, "bbox": [1112.48, 320.4, 215.03, 49.55], "category_id": 2}, {"id": 6, "bbox": [689.19, 0.0, 400.9, 171.74], "category_id": 1}, {"id": 7, "bbox": [381.23, 77.38, 207.57, 123.55], "category_id": 1}, {"id": 8, "bbox": [552.17, 185.99, 51.55, 40.73], "category_id": 3}, {"id": 9, "bbox": [1048.71, 504.36, 189.26, 42.04], "category_id": 3}, {"id": 10, "bbox": [2.71, 230.8, 433.46, 172.41], "category_id": 1}, {"id": 11, "bbox": [59.02, 2.72, 262.51, 169.02], "category_id": 1}, {"id": 12, "bbox": [465.34, 323.79, 146.52, 48.2], "category_id": 2}, {"id": 13, "bbox": [404.29, 639.44, 67.16, 38.69], "category_id": 3}, {"id": 14, "bbox": [347.31, 110.65, 40.02, 43.44], "category_id": 2}, {"id": 15, "bbox": [857.42, 150.7, 47.48, 37.33], "category_id": 3}, {"id": 16, "bbox": [177.05, 187.35, 42.73, 34.62], "category_id": 3}, {"id": 17, "bbox": [209.61, 381.49, 46.12, 35.3], "category_id": 3}, {"id": 18, "bbox": [792.3, 531.51, 188.58, 50.91], "category_id": 2}, {"id": 19, "bbox": [877.77, 395.07, 43.41, 35.3], "category_id": 3}], "caption": "Scheme 9", "pdf": {"Page": 8, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 486, 60], "ImageBB": [424, 65, 763, 235]}, "reactions": [{"reactants": [11, 7], "conditions": [1], "products": [6]}, {"reactants": [6], "conditions": [2], "products": [10]}, {"reactants": [10], "conditions": [3, 12], "products": [0]}, {"reactants": [0], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [18], "products": [9]}], "diagram_type": "multiple"}, {"id": 739, "width": 1348, "height": 1112, "file_name": "ol0157003-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [960.18, 0.0, 310.05, 217.56], "category_id": 1}, {"id": 1, "bbox": [645.66, 0.0, 304.09, 217.56], "category_id": 1}, {"id": 2, "bbox": [179.1, 262.3, 973.4, 265.3], "category_id": 4}, {"id": 3, "bbox": [1088.38, 225.01, 59.62, 49.19], "category_id": 3}, {"id": 4, "bbox": [77.74, 4.4, 378.62, 211.67], "category_id": 1}, {"id": 5, "bbox": [775.35, 225.01, 55.15, 47.7], "category_id": 3}, {"id": 6, "bbox": [3.21, 557.42, 1341.55, 551.53], "category_id": 4}, {"id": 7, "bbox": [487.66, 86.38, 140.12, 52.18], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [7], "products": [1, 0]}], "corefs": [[1, 5], [0, 3]], "caption": "Table 1. Rearrangements of Syn Acetals 6s-10sa", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 246, 705, 260], "ImageBB": [439, 264, 776, 542]}, "diagram_type": "single"}, {"id": 1308, "width": 1704, "height": 1740, "file_name": "op300162d-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [788.0, 486.57, 164.56, 52.23], "category_id": 3}, {"id": 1, "bbox": [568.58, 819.95, 148.02, 48.74], "category_id": 2}, {"id": 2, "bbox": [1137.15, 268.96, 241.19, 60.93], "category_id": 2}, {"id": 3, "bbox": [62.69, 0.0, 508.5, 518.78], "category_id": 1}, {"id": 4, "bbox": [565.09, 263.74, 195.92, 58.32], "category_id": 2}, {"id": 5, "bbox": [727.05, 637.16, 440.58, 525.74], "category_id": 1}, {"id": 6, "bbox": [626.04, 20.89, 461.48, 517.91], "category_id": 1}, {"id": 7, "bbox": [568.58, 195.85, 202.0, 56.58], "category_id": 2}, {"id": 8, "bbox": [847.21, 1150.72, 166.3, 46.13], "category_id": 3}, {"id": 9, "bbox": [175.01, 502.24, 171.53, 47.0], "category_id": 3}, {"id": 10, "bbox": [151.5, 1171.61, 204.62, 48.74], "category_id": 3}, {"id": 11, "bbox": [70.53, 631.94, 443.19, 518.78], "category_id": 1}, {"id": 12, "bbox": [1136.28, 194.98, 207.23, 64.41], "category_id": 2}], "caption": "Scheme 1. Schematic Conversion of HBIW to HNIW", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 671, 751, 686], "ImageBB": [433, 692, 859, 1127]}, "reactions": [{"reactants": [3], "conditions": [7, 4], "products": [6]}, {"reactants": [6], "conditions": [12, 2], "products": [11]}, {"reactants": [11], "conditions": [1], "products": [5]}], "diagram_type": "multiple"}, {"id": 342, "width": 1344, "height": 540, "file_name": "ol202499g-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [512.2, 278.1, 167.5, 156.8], "category_id": 1}, {"id": 1, "bbox": [570.0, 196.9, 67.2, 49.1], "category_id": 2}, {"id": 2, "bbox": [1227.43, 421.54, 37.5, 44.59], "category_id": 3}, {"id": 3, "bbox": [769.1, 412.0, 183.9, 120.0], "category_id": 1}, {"id": 4, "bbox": [27.0, 289.0, 86.0, 120.0], "category_id": 1}, {"id": 5, "bbox": [174.0, 316.0, 120.0, 56.0], "category_id": 2}, {"id": 6, "bbox": [578.0, 448.0, 16.0, 31.0], "category_id": 3}, {"id": 7, "bbox": [1034.1, 283.3, 257.6, 176.6], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [1], "products": [0]}, {"reactants": [0, 3], "conditions": [1], "products": [7]}], "corefs": [[0, 6], [7, 2]], "caption": "Figure 1. Strategy of tandem cyanation allylic alkylation reaction. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 328, 405, 355], "ImageBB": [71, 180, 407, 315]}, "diagram_type": "tree"}, {"id": 187, "width": 888, "height": 200, "file_name": "op060155c-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [414.3, 0.0, 243.0, 92.0], "category_id": 2}, {"id": 1, "bbox": [4.0, 17.1, 200.3, 156.9], "category_id": 1}, {"id": 2, "bbox": [241.7, 87.4, 168.3, 51.2], "category_id": 2}, {"id": 3, "bbox": [421.7, 148.3, 180.9, 49.7], "category_id": 2}, {"id": 4, "bbox": [675.0, 15.0, 207.0, 161.0], "category_id": 1}], "reactions": [{"reactants": [1, 2], "conditions": [0, 3], "products": [4]}], "corefs": [], "caption": "Figure 3. Nickel cross-coupling.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 106, 621, 120], "ImageBB": [497, 53, 719, 103]}, "diagram_type": "single"}, {"id": 1135, "width": 1000, "height": 756, "file_name": "ol006614q-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [744.15, 274.12, 30.86, 41.75], "category_id": 2}, {"id": 1, "bbox": [27.01, 381.6, 316.16, 186.04], "category_id": 1}, {"id": 2, "bbox": [411.08, 67.2, 26.31, 39.03], "category_id": 2}, {"id": 3, "bbox": [552.78, 556.64, 390.19, 195.05], "category_id": 3}, {"id": 4, "bbox": [471.24, 0.0, 528.76, 210.05], "category_id": 1}, {"id": 5, "bbox": [402.2, 415.1, 47.52, 44.51], "category_id": 2}, {"id": 6, "bbox": [27.01, 38.01, 369.69, 136.03], "category_id": 1}, {"id": 7, "bbox": [471.24, 366.09, 528.76, 208.55], "category_id": 1}, {"id": 8, "bbox": [195.1, 220.06, 42.02, 52.01], "category_id": 3}, {"id": 9, "bbox": [726.0, 221.56, 33.1, 43.24], "category_id": 3}, {"id": 10, "bbox": [0.0, 558.14, 386.69, 193.55], "category_id": 3}], "caption": "Scheme 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 531, 269, 545], "ImageBB": [117, 550, 367, 739]}, "reactions": [{"reactants": [6], "conditions": [2], "products": [4]}, {"reactants": [4], "conditions": [0], "products": [7]}, {"reactants": [7], "conditions": [5], "products": [1]}], "diagram_type": "tree"}, {"id": 236, "width": 1300, "height": 472, "file_name": "op000070q-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [636.7, 106.15, 331.5, 91.25], "category_id": 2}, {"id": 1, "bbox": [675.6, 14.0, 197.5, 44.7], "category_id": 2}, {"id": 2, "bbox": [393.36, 29.24, 192.54, 115.06], "category_id": 1}, {"id": 3, "bbox": [1039.09, 2.36, 255.11, 170.84], "category_id": 1}, {"id": 4, "bbox": [507.9, 322.6, 147.6, 147.7], "category_id": 1}, {"id": 5, "bbox": [5.49, 4.85, 238.21, 150.75], "category_id": 1}, {"id": 6, "bbox": [400.98, 237.69, 151.92, 53.11], "category_id": 2}], "reactions": [{"reactants": [5, 2], "conditions": [1, 0], "products": [3]}], "corefs": [], "caption": "Table 3. Analysis of N-BOC amino acid resins", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 202, 696, 216], "ImageBB": [446, 73, 771, 191]}, "diagram_type": "single"}, {"id": 1147, "width": 1328, "height": 856, "file_name": "ol0361507-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [992.51, 2.66, 335.49, 370.13], "category_id": 1}, {"id": 1, "bbox": [1044.99, 528.95, 29.24, 44.52], "category_id": 2}, {"id": 2, "bbox": [924.09, 202.01, 35.87, 45.19], "category_id": 2}, {"id": 3, "bbox": [1167.23, 554.86, 28.57, 42.53], "category_id": 3}, {"id": 4, "bbox": [592.58, 528.95, 35.21, 37.87], "category_id": 2}, {"id": 5, "bbox": [533.46, 2.66, 335.49, 371.46], "category_id": 1}, {"id": 6, "bbox": [445.1, 210.65, 32.55, 36.55], "category_id": 2}, {"id": 7, "bbox": [227.87, 418.64, 261.08, 373.45], "category_id": 1}, {"id": 8, "bbox": [642.41, 386.74, 31.89, 40.54], "category_id": 3}, {"id": 9, "bbox": [690.91, 418.64, 261.08, 371.46], "category_id": 1}, {"id": 10, "bbox": [800.52, 806.71, 51.15, 45.18], "category_id": 3}, {"id": 11, "bbox": [116.92, 521.64, 32.55, 44.52], "category_id": 2}, {"id": 12, "bbox": [337.48, 808.04, 52.48, 46.51], "category_id": 3}, {"id": 13, "bbox": [0.0, 2.66, 390.63, 370.79], "category_id": 1}, {"id": 14, "bbox": [115.59, 386.74, 36.54, 38.54], "category_id": 3}, {"id": 15, "bbox": [1006.46, 392.06, 277.03, 97.68], "category_id": 3}], "caption": "Scheme 3 a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 196, 637, 210], "ImageBB": [442, 215, 774, 429]}, "reactions": [{"reactants": [13], "conditions": [6], "products": [5]}, {"reactants": [5], "conditions": [2], "products": [0]}, {"reactants": [0], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [4], "products": [9]}, {"reactants": [9], "conditions": [1], "products": [3]}], "diagram_type": "multiple"}, {"id": 143, "width": 1352, "height": 2136, "file_name": "op7002826-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [872.0, 135.0, 155.0, 33.0], "category_id": 2}, {"id": 1, "bbox": [1155.0, 249.0, 81.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [608.0, 245.0, 89.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [38.0, 234.0, 79.0, 51.0], "category_id": 3}, {"id": 4, "bbox": [860.0, 168.0, 170.0, 47.0], "category_id": 2}, {"id": 5, "bbox": [227.0, 218.0, 144.0, 57.0], "category_id": 2}, {"id": 6, "bbox": [212.0, 181.0, 168.0, 41.0], "category_id": 2}, {"id": 7, "bbox": [197.0, 145.0, 170.0, 38.0], "category_id": 2}, {"id": 8, "bbox": [864.0, 38.0, 161.0, 63.0], "category_id": 2}, {"id": 9, "bbox": [195.0, 5.0, 253.0, 107.0], "category_id": 1}, {"id": 10, "bbox": [2.0, 1889.0, 1350.0, 247.0], "category_id": 2}, {"id": 11, "bbox": [2.0, 339.0, 1350.0, 1550.0], "category_id": 4}, {"id": 12, "bbox": [1110.0, 11.0, 242.0, 219.3], "category_id": 1}, {"id": 13, "bbox": [536.5, 52.0, 232.5, 153.0], "category_id": 1}, {"id": 14, "bbox": [0.0, 91.0, 150.0, 57.0], "category_id": 1}], "reactions": [{"reactants": [14], "conditions": [9, 7, 6, 5], "products": [13]}, {"reactants": [13], "conditions": [8, 0, 4], "products": [12]}], "corefs": [[14, 3], [13, 2], [12, 1]], "caption": "Table 1. Substrate scope of one-pot pyrrole synthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 351, 60], "ImageBB": [58, 74, 396, 608]}, "diagram_type": "single"}, {"id": 21, "width": 1352, "height": 572, "file_name": "ja905415r-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [349.36, 105.72, 158.26, 46.03], "category_id": 2}, {"id": 1, "bbox": [4.02, 321.56, 1341.88, 247.19], "category_id": 4}, {"id": 2, "bbox": [303.6, 173.93, 230.79, 90.06], "category_id": 2}, {"id": 3, "bbox": [750.81, 25.43, 360.29, 178.99], "category_id": 1}, {"id": 4, "bbox": [536.7, 11.62, 261.87, 254.09], "category_id": 1}, {"id": 5, "bbox": [50.64, 4.71, 306.76, 237.69], "category_id": 1}, {"id": 6, "bbox": [1084.06, 270.62, 52.94, 39.98], "category_id": 3}, {"id": 7, "bbox": [882.04, 212.78, 55.53, 41.71], "category_id": 3}, {"id": 8, "bbox": [706.78, 250.76, 58.12, 42.58], "category_id": 3}, {"id": 9, "bbox": [211.22, 250.76, 52.94, 42.58], "category_id": 3}, {"id": 10, "bbox": [992.55, 105.72, 301.58, 199.71], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [0, 2], "products": [4, 3, 10]}], "corefs": [[5, 9], [4, 8], [3, 7], [10, 6]], "caption": "Table 6. Gold-Catalyzed Cycloadditions of 1c in the Presence of MeOHa ", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 565, 382, 589], "ImageBB": [58, 597, 396, 740]}, "diagram_type": "single"}, {"id": 34, "width": 1344, "height": 2524, "file_name": "ja511335v-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [386.0, 25.39, 494.68, 129.99], "category_id": 2}, {"id": 1, "bbox": [407.04, 168.72, 453.04, 136.13], "category_id": 2}, {"id": 2, "bbox": [67.57, 1.13, 220.2, 295.11], "category_id": 1}, {"id": 3, "bbox": [1112.3, 313.81, 65.12, 34.87], "category_id": 3}, {"id": 4, "bbox": [63.4, 314.25, 215.9, 40.57], "category_id": 3}, {"id": 5, "bbox": [984.75, 19.7, 291.29, 264.55], "category_id": 1}, {"id": 6, "bbox": [0.0, 378.92, 1340.52, 2138.44], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [0, 1], "products": [5]}], "corefs": [[2, 4], [5, 3]], "caption": "Table 3. Diastereoselective (3 + 1 + 2) Cycloadditions Using a Cationic Rh(I)-System ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [83, 131, 419, 762]}, "diagram_type": "single"}, {"id": 1071, "width": 1352, "height": 896, "file_name": "jo401608v-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [77.1, 0.0, 302.33, 293.67], "category_id": 1}, {"id": 1, "bbox": [411.89, 140.07, 123.09, 65.63], "category_id": 2}, {"id": 2, "bbox": [562.71, 250.36, 284.74, 64.28], "category_id": 2}, {"id": 3, "bbox": [1169.39, 566.36, 52.08, 55.48], "category_id": 3}, {"id": 4, "bbox": [633.73, 183.37, 157.59, 66.31], "category_id": 2}, {"id": 5, "bbox": [167.73, 585.3, 62.22, 56.84], "category_id": 3}, {"id": 6, "bbox": [577.59, 581.24, 273.24, 274.05], "category_id": 1}, {"id": 7, "bbox": [663.49, 778.83, 54.78, 57.51], "category_id": 3}, {"id": 8, "bbox": [186.67, 757.85, 248.22, 66.99], "category_id": 1}, {"id": 9, "bbox": [97.39, 232.09, 100.1, 60.22], "category_id": 3}, {"id": 10, "bbox": [124.45, 337.65, 329.37, 303.82], "category_id": 1}, {"id": 11, "bbox": [1142.34, 150.22, 102.12, 63.6], "category_id": 3}, {"id": 12, "bbox": [124.45, 761.91, 54.78, 62.93], "category_id": 3}, {"id": 13, "bbox": [533.63, 110.29, 133.24, 69.02], "category_id": 2}, {"id": 14, "bbox": [973.25, 337.65, 298.94, 241.56], "category_id": 1}, {"id": 15, "bbox": [996.92, 0.0, 275.27, 211.79], "category_id": 1}], "caption": "Scheme 8. Plausible Mechanism", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 683, 263, 698], "ImageBB": [82, 705, 420, 929]}, "reactions": [{"reactants": [10], "conditions": [], "products": [0]}, {"reactants": [10, 1], "conditions": [], "products": [13, 4]}, {"reactants": [4, 15], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [], "products": [6]}, {"reactants": [6, 8], "conditions": [], "products": [10]}], "diagram_type": "graph"}, {"id": 910, "width": 1352, "height": 420, "file_name": "acs.joc.5b00302-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [920.7, 4.0, 431.3, 327.0], "category_id": 1}, {"id": 1, "bbox": [697.9, 122.7, 205.1, 47.3], "category_id": 2}, {"id": 2, "bbox": [498.0, 276.0, 53.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [2.0, 80.0, 374.0, 170.0], "category_id": 1}, {"id": 4, "bbox": [431.0, 24.0, 245.0, 264.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 346.0, 1345.0, 74.0], "category_id": 4}, {"id": 6, "bbox": [711.0, 192.0, 173.0, 38.0], "category_id": 2}, {"id": 7, "bbox": [995.0, 274.0, 54.0, 45.0], "category_id": 3}, {"id": 8, "bbox": [159.0, 273.0, 53.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [3, 4], "conditions": [1, 6], "products": [0]}], "corefs": [[3, 8], [4, 2], [0, 7]], "caption": "Table 2. Reaction with Low Catalyst Loadinga", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 712, 110], "ImageBB": [448, 116, 786, 221]}, "diagram_type": "single"}, {"id": 238, "width": 1344, "height": 672, "file_name": "ol991356m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [152.0, 11.1, 351.0, 107.0], "category_id": 1}, {"id": 1, "bbox": [781.1, 9.9, 419.8, 110.2], "category_id": 1}, {"id": 2, "bbox": [0.0, 142.0, 1344.0, 530.0], "category_id": 4}, {"id": 3, "bbox": [529.0, 0.0, 194.0, 39.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [3], "products": [1]}], "corefs": [], "caption": "Table 1. Efficiency of Various Pd Catalysts on the Formation of 4-Nitrobiphenyl in THF-MeOHa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 378, 401, 406], "ImageBB": [74, 410, 410, 578]}, "diagram_type": "single"}, {"id": 576, "width": 1196, "height": 816, "file_name": "acs.orglett.5b00663-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [136.0, 110.0, 33.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [7.0, 173.0, 1189.0, 643.0], "category_id": 4}, {"id": 2, "bbox": [493.0, 15.0, 428.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [571.0, 83.0, 274.0, 57.0], "category_id": 2}, {"id": 4, "bbox": [1015.0, 105.0, 34.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [71.0, 23.0, 167.0, 62.0], "category_id": 1}, {"id": 6, "bbox": [966.7, 3.6, 152.3, 102.9], "category_id": 1}, {"id": 7, "bbox": [306.0, 4.7, 150.4, 106.3], "category_id": 1}], "reactions": [{"reactants": [5, 7], "conditions": [2, 3], "products": [6]}], "corefs": [[5, 0], [6, 4]], "caption": "Table 3. Transesteri\ufb01cation with Di\ufb00erent Estersa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 661, 727, 679], "ImageBB": [468, 685, 767, 889]}, "diagram_type": "single"}, {"id": 970, "width": 1344, "height": 1716, "file_name": "ja030261j-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [994.09, 144.22, 349.91, 231.77], "category_id": 1}, {"id": 1, "bbox": [584.61, 166.54, 305.6, 229.2], "category_id": 1}, {"id": 2, "bbox": [562.29, 24.89, 242.94, 53.23], "category_id": 2}, {"id": 3, "bbox": [607.78, 101.29, 170.84, 51.51], "category_id": 2}, {"id": 4, "bbox": [802.65, 925.39, 499.62, 257.53], "category_id": 1}, {"id": 5, "bbox": [899.66, 97.86, 323.63, 51.51], "category_id": 2}, {"id": 6, "bbox": [119.32, 674.73, 131.35, 54.93], "category_id": 3}, {"id": 7, "bbox": [721.96, 1421.56, 557.99, 236.93], "category_id": 1}, {"id": 8, "bbox": [845.58, 660.13, 127.9, 54.94], "category_id": 3}, {"id": 9, "bbox": [1045.59, 660.13, 133.06, 55.8], "category_id": 3}, {"id": 10, "bbox": [769.17, 426.64, 506.49, 206.02], "category_id": 1}, {"id": 11, "bbox": [20.6, 1406.97, 349.39, 272.98], "category_id": 1}, {"id": 12, "bbox": [84.99, 892.77, 310.76, 283.28], "category_id": 1}, {"id": 13, "bbox": [937.43, 1662.78, 125.33, 49.79], "category_id": 3}, {"id": 14, "bbox": [937.43, 1199.23, 125.33, 50.64], "category_id": 3}, {"id": 15, "bbox": [0.0, 428.36, 504.77, 212.03], "category_id": 1}], "caption": "Scheme 2. Derivation of the Pyrimidine Unit of Thiamin from Pyridoxine ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 573, 380, 597], "ImageBB": [74, 601, 410, 1030]}, "reactions": [{"reactants": [2, 3], "conditions": [1], "products": [10]}, {"reactants": [2, 5], "conditions": [0], "products": [10]}, {"reactants": [2], "conditions": [], "products": [15]}, {"reactants": [12], "conditions": [], "products": [4]}, {"reactants": [11], "conditions": [], "products": [7]}], "diagram_type": "tree"}, {"id": 1267, "width": 1356, "height": 1532, "file_name": "op060099f-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [30.65, 563.29, 471.27, 411.55], "category_id": 1}, {"id": 1, "bbox": [233.0, 1394.05, 69.89, 45.98], "category_id": 3}, {"id": 2, "bbox": [157.09, 331.08, 50.58, 47.51], "category_id": 3}, {"id": 3, "bbox": [441.38, 105.76, 271.27, 101.93], "category_id": 2}, {"id": 4, "bbox": [820.7, 36.79, 460.54, 367.09], "category_id": 1}, {"id": 5, "bbox": [589.28, 661.39, 237.55, 75.87], "category_id": 2}, {"id": 6, "bbox": [1074.34, 470.56, 147.13, 67.44], "category_id": 2}, {"id": 7, "bbox": [919.55, 343.34, 73.57, 48.28], "category_id": 3}, {"id": 8, "bbox": [182.38, 1177.93, 351.73, 354.07], "category_id": 1}, {"id": 9, "bbox": [258.24, 1031.55, 78.93, 78.17], "category_id": 2}, {"id": 10, "bbox": [66.67, 134.12, 399.24, 242.94], "category_id": 1}, {"id": 11, "bbox": [887.37, 842.26, 75.09, 49.04], "category_id": 3}, {"id": 12, "bbox": [95.02, 853.75, 75.1, 55.18], "category_id": 3}, {"id": 13, "bbox": [820.7, 554.1, 475.87, 410.01], "category_id": 1}, {"id": 14, "bbox": [865.15, 925.79, 194.63, 40.62], "category_id": 2}], "caption": "Scheme 6. Reaction scheme as applied in pilot plant", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 574, 370, 588], "ImageBB": [73, 593, 412, 976]}, "reactions": [{"reactants": [10], "conditions": [3], "products": [4]}, {"reactants": [4], "conditions": [6], "products": [13]}, {"reactants": [13], "conditions": [5], "products": [0]}, {"reactants": [0], "conditions": [9], "products": [8]}], "diagram_type": "tree"}, {"id": 1079, "width": 1352, "height": 2184, "file_name": "jo501014e-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [937.62, 1755.72, 186.87, 55.72], "category_id": 3}, {"id": 1, "bbox": [220.75, 1413.75, 161.73, 131.11], "category_id": 1}, {"id": 2, "bbox": [787.9, 0.0, 444.78, 276.41], "category_id": 1}, {"id": 3, "bbox": [528.0, 469.79, 223.85, 192.29], "category_id": 1}, {"id": 4, "bbox": [829.9, 1220.37, 408.24, 196.66], "category_id": 1}, {"id": 5, "bbox": [62.1, 0.0, 72.31, 61.18], "category_id": 2}, {"id": 6, "bbox": [926.5, 874.04, 313.83, 193.38], "category_id": 1}, {"id": 7, "bbox": [56.8, 1804.89, 77.61, 66.64], "category_id": 2}, {"id": 8, "bbox": [220.75, 871.85, 159.54, 135.48], "category_id": 1}, {"id": 9, "bbox": [924.99, 1900.84, 380.17, 194.02], "category_id": 1}, {"id": 10, "bbox": [841.09, 285.78, 388.03, 194.02], "category_id": 1}, {"id": 11, "bbox": [901.39, 429.98, 188.77, 62.92], "category_id": 3}, {"id": 12, "bbox": [59.78, 1166.72, 68.17, 70.79], "category_id": 2}, {"id": 13, "bbox": [454.6, 258.93, 295.06, 147.5], "category_id": 1}, {"id": 14, "bbox": [896.09, 209.77, 165.02, 54.63], "category_id": 3}, {"id": 15, "bbox": [814.13, 1595.12, 420.73, 216.32], "category_id": 1}, {"id": 16, "bbox": [896.09, 1071.79, 336.59, 109.25], "category_id": 3}, {"id": 17, "bbox": [520.17, 884.96, 68.85, 56.81], "category_id": 3}, {"id": 18, "bbox": [896.09, 1413.75, 336.59, 160.61], "category_id": 3}, {"id": 19, "bbox": [40.43, 355.08, 334.4, 83.03], "category_id": 1}, {"id": 20, "bbox": [896.09, 209.77, 166.11, 54.63], "category_id": 3}, {"id": 21, "bbox": [520.17, 1299.04, 68.85, 53.53], "category_id": 3}, {"id": 22, "bbox": [896.09, 1413.75, 336.59, 160.61], "category_id": 3}, {"id": 23, "bbox": [938.71, 739.65, 184.69, 55.72], "category_id": 3}, {"id": 24, "bbox": [181.4, 1884.64, 236.05, 174.81], "category_id": 1}, {"id": 25, "bbox": [896.09, 1413.75, 336.59, 160.61], "category_id": 3}, {"id": 26, "bbox": [937.62, 2081.3, 184.68, 59.0], "category_id": 3}, {"id": 27, "bbox": [896.09, 209.77, 166.11, 54.63], "category_id": 3}, {"id": 28, "bbox": [868.77, 516.77, 307.08, 216.33], "category_id": 1}, {"id": 29, "bbox": [401.06, 46.98, 348.6, 150.77], "category_id": 1}, {"id": 30, "bbox": [452.42, 1805.98, 224.02, 151.86], "category_id": 1}, {"id": 31, "bbox": [418.54, 1167.93, 307.08, 150.77], "category_id": 1}, {"id": 32, "bbox": [454.6, 740.75, 232.77, 148.58], "category_id": 1}, {"id": 33, "bbox": [364.99, 1531.75, 395.6, 166.07], "category_id": 1}], "caption": "Scheme 5. 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Optimizing formic acida", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 767, 271, 788], "ImageBB": [82, 408, 420, 767]}, "diagram_type": "tree"}, {"id": 1318, "width": 1132, "height": 1496, "file_name": "op300235t-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [352.37, 210.29, 40.39, 39.67], "category_id": 2}, {"id": 1, "bbox": [943.38, 881.58, 45.64, 47.9], "category_id": 3}, {"id": 2, "bbox": [846.87, 56.13, 248.38, 196.07], "category_id": 1}, {"id": 3, "bbox": [614.96, 458.01, 517.04, 510.39], "category_id": 1}, {"id": 4, "bbox": [451.87, 983.36, 672.56, 505.9], "category_id": 1}, {"id": 5, "bbox": [662.09, 392.9, 33.66, 41.16], "category_id": 3}, {"id": 6, "bbox": [785.53, 1447.36, 45.63, 48.64], "category_id": 3}, {"id": 7, "bbox": [1024.93, 178.11, 38.15, 48.65], "category_id": 3}, {"id": 8, "bbox": [970.89, 287.28, 34.7, 44.34], "category_id": 2}, {"id": 9, "bbox": [0.0, 0.0, 309.72, 390.65], "category_id": 1}, {"id": 10, "bbox": [0.0, 485.69, 494.51, 460.25], "category_id": 1}, {"id": 11, "bbox": [130.92, 392.15, 36.66, 41.91], "category_id": 3}, {"id": 12, "bbox": [36.66, 1081.4, 300.74, 174.37], "category_id": 1}, {"id": 13, "bbox": [321.69, 900.29, 38.16, 45.65], "category_id": 3}, {"id": 14, "bbox": [76.38, 1087.33, 55.9, 50.13], "category_id": 3}, {"id": 15, "bbox": [469.07, 0.0, 379.3, 386.91], "category_id": 1}, {"id": 16, "bbox": [166.08, 1306.66, 40.4, 41.16], "category_id": 2}, {"id": 17, "bbox": [556.6, 687.01, 72.57, 52.38], "category_id": 2}], "caption": "Scheme 1. Medicinal chemistry route to the PI3K\u03b4 inhibitor 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [109, 131, 392, 505]}, "reactions": [{"reactants": [9], "conditions": [0], "products": [15]}, {"reactants": [15, 2], "conditions": [8], "products": [10]}, {"reactants": [10], "conditions": [17], "products": [3]}, {"reactants": [3, 12], "conditions": [16], "products": [4]}], "diagram_type": "multiple"}, {"id": 273, "width": 1348, "height": 836, "file_name": "ol8006259-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 424.0, 1347.0, 412.0], "category_id": 4}, {"id": 1, "bbox": [884.0, 340.0, 353.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [876.0, 143.0, 452.0, 58.0], "category_id": 3}, {"id": 3, "bbox": [465.0, 0.0, 526.7, 386.0], "category_id": 1}, {"id": 4, "bbox": [27.15, 203.85, 62.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [939.0, 217.0, 285.0, 93.3], "category_id": 2}, {"id": 6, "bbox": [101.0, 108.0, 349.0, 110.8], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [6], "products": [3]}, {"reactants": [2], "conditions": [5], "products": [1]}], "corefs": [[3, 2], [3, 1]], "caption": "Table 2. Synthesis of R-(N-Glycosyltriazolyl)-\u03b2-lactam Hybrids 15-18 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 731, 755, 761], "ImageBB": [425, 770, 762, 979]}, "diagram_type": "tree"}, {"id": 1089, "width": 1096, "height": 768, "file_name": "jo960838y-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [14.8, 0.0, 234.66, 138.72], "category_id": 1}, {"id": 1, "bbox": [386.61, 532.93, 38.73, 44.25], "category_id": 2}, {"id": 2, "bbox": [455.76, 47.97, 60.85, 60.85], "category_id": 1}, {"id": 3, "bbox": [424.91, 258.26, 138.89, 128.85], "category_id": 1}, {"id": 4, "bbox": [3.29, 475.94, 474.81, 228.1], "category_id": 1}, {"id": 5, "bbox": [885.46, 529.67, 185.32, 195.75], "category_id": 1}, {"id": 6, "bbox": [156.81, 721.04, 53.73, 39.48], "category_id": 3}, {"id": 7, "bbox": [731.95, 106.92, 86.62, 55.38], "category_id": 2}, {"id": 8, "bbox": [516.47, 398.08, 56.48, 44.96], "category_id": 3}, {"id": 9, "bbox": [762.65, 543.93, 63.6, 52.09], "category_id": 2}, {"id": 10, "bbox": [609.13, 723.23, 53.73, 40.03], "category_id": 3}, {"id": 11, "bbox": [112.4, 336.67, 139.26, 53.18], "category_id": 2}, {"id": 12, "bbox": [1045.01, 722.13, 47.7, 40.03], "category_id": 3}, {"id": 13, "bbox": [547.73, 527.48, 169.96, 150.24], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 49, 635, 63], "ImageBB": [470, 69, 744, 261]}, "reactions": [{"reactants": [0, 2], "conditions": [], "products": [3, 11]}, {"reactants": [3], "conditions": [], "products": [2, 7]}, {"reactants": [4], "conditions": [1], "products": [13]}, {"reactants": [13], "conditions": [9], "products": [5]}], "diagram_type": "graph"}, {"id": 1354, "width": 1696, "height": 748, "file_name": "op800189g-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1597.58, 660.81, 98.42, 55.14], "category_id": 2}, {"id": 1, "bbox": [1566.19, 701.53, 33.09, 43.26], "category_id": 2}, {"id": 2, "bbox": [634.62, 391.06, 229.92, 189.17], "category_id": 1}, {"id": 3, "bbox": [1078.35, 87.37, 97.57, 55.14], "category_id": 2}, {"id": 4, "bbox": [332.58, 257.88, 67.88, 73.8], "category_id": 2}, {"id": 5, "bbox": [1242.09, 638.76, 308.83, 80.59], "category_id": 1}, {"id": 6, "bbox": [1253.12, 392.76, 341.07, 145.05], "category_id": 1}, {"id": 7, "bbox": [933.27, 663.36, 92.47, 52.59], "category_id": 2}, {"id": 8, "bbox": [623.59, 274.84, 78.91, 50.9], "category_id": 2}, {"id": 9, "bbox": [900.45, 700.15, 31.97, 42.21], "category_id": 2}, {"id": 10, "bbox": [0.0, 638.76, 335.98, 82.28], "category_id": 1}, {"id": 11, "bbox": [570.99, 634.52, 310.52, 86.52], "category_id": 1}, {"id": 12, "bbox": [1141.13, 239.22, 100.96, 73.8], "category_id": 2}, {"id": 13, "bbox": [1038.47, 134.88, 38.18, 47.5], "category_id": 2}, {"id": 14, "bbox": [468.33, 11.03, 535.36, 184.92], "category_id": 1}, {"id": 15, "bbox": [82.3, 389.36, 226.53, 187.47], "category_id": 1}], "caption": "Scheme 3. Reversible and irreversible decomposition of PTTCa under various conditions", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 384, 551, 398], "ImageBB": [198, 403, 622, 590]}, "reactions": [{"reactants": [14], "conditions": [4], "products": [15, 10]}, {"reactants": [14], "conditions": [8], "products": [2, 11]}, {"reactants": [2, 11], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [12], "products": [6, 5]}], "diagram_type": "tree"}, {"id": 1184, "width": 1344, "height": 772, "file_name": "ol401443a-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [99.51, 319.9, 313.3, 176.75], "category_id": 1}, {"id": 1, "bbox": [888.83, 79.3, 200.35, 78.63], "category_id": 1}, {"id": 2, "bbox": [913.7, 338.04, 197.67, 76.62], "category_id": 1}, {"id": 3, "bbox": [1128.85, 106.86, 112.28, 103.49], "category_id": 3}, {"id": 4, "bbox": [1128.85, 381.73, 103.54, 96.1], "category_id": 3}, {"id": 5, "bbox": [416.18, 347.45, 146.57, 68.55], "category_id": 2}, {"id": 6, "bbox": [600.4, 73.25, 242.04, 201.62], "category_id": 1}, {"id": 7, "bbox": [761.76, 471.78, 58.49, 63.18], "category_id": 3}, {"id": 8, "bbox": [169.43, 228.5, 88.75, 59.14], "category_id": 3}, {"id": 9, "bbox": [601.07, 318.55, 271.62, 180.79], "category_id": 1}, {"id": 10, "bbox": [221.2, 473.13, 51.1, 61.16], "category_id": 3}, {"id": 11, "bbox": [320.03, 99.46, 201.7, 65.19], "category_id": 2}, {"id": 12, "bbox": [135.14, 2.02, 299.86, 224.46], "category_id": 1}, {"id": 13, "bbox": [769.82, 204.31, 61.19, 67.87], "category_id": 3}], "caption": "Scheme 3. Proposed Mechanism", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 307, 244, 320], "ImageBB": [71, 330, 407, 523]}, "reactions": [{"reactants": [12], "conditions": [11], "products": [6]}, {"reactants": [6], "conditions": [1], "products": [3]}, {"reactants": [0], "conditions": [5], "products": [9]}, {"reactants": [9], "conditions": [2], "products": [4]}], "diagram_type": "multiple"}, {"id": 100, "width": 1344, "height": 1056, "file_name": "ja0289088-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [466.15, 66.17, 414.1, 191.39], "category_id": 2}, {"id": 1, "bbox": [252.53, 22.24, 174.72, 127.75], "category_id": 1}, {"id": 2, "bbox": [266.7, 472.18, 22.44, 34.7], "category_id": 3}, {"id": 3, "bbox": [595.09, 484.44, 27.88, 34.71], "category_id": 3}, {"id": 4, "bbox": [984.78, 481.72, 26.53, 34.7], "category_id": 3}, {"id": 5, "bbox": [922.11, 278.69, 221.37, 158.7], "category_id": 1}, {"id": 6, "bbox": [929.76, 23.75, 176.23, 126.24], "category_id": 1}, {"id": 7, "bbox": [551.48, 284.15, 225.47, 157.33], "category_id": 1}, {"id": 8, "bbox": [198.58, 285.51, 218.65, 158.69], "category_id": 1}, {"id": 9, "bbox": [2.36, 533.5, 1338.69, 517.1], "category_id": 4}, {"id": 10, "bbox": [549.48, 7.1, 215.62, 39.86], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [10, 0], "products": [6]}], "corefs": [[8, 2], [7, 3], [5, 4]], "caption": "Table 1. Asymmetric Epoxidation of 1-Phenylcyclohexene Using Chiral Amines as Catalyst ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 398, 88], "ImageBB": [74, 96, 410, 360]}, "diagram_type": "single"}, {"id": 1243, "width": 1112, "height": 612, "file_name": "op025619v-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [721.49, 295.23, 159.1, 57.27], "category_id": 2}, {"id": 1, "bbox": [497.87, 261.87, 189.69, 244.09], "category_id": 1}, {"id": 2, "bbox": [429.45, 5.0, 222.51, 172.36], "category_id": 1}, {"id": 3, "bbox": [1007.42, 563.78, 44.5, 45.04], "category_id": 3}, {"id": 4, "bbox": [0.0, 50.6, 225.29, 128.99], "category_id": 1}, {"id": 5, "bbox": [259.78, 115.09, 129.61, 132.88], "category_id": 2}, {"id": 6, "bbox": [262.01, 23.91, 117.37, 56.15], "category_id": 2}, {"id": 7, "bbox": [881.14, 246.31, 230.86, 272.99], "category_id": 1}, {"id": 8, "bbox": [707.03, 111.76, 112.92, 48.92], "category_id": 2}, {"id": 9, "bbox": [683.67, 23.91, 160.2, 59.49], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 216, 501, 230], "ImageBB": [469, 235, 747, 388]}, "reactions": [{"reactants": [4], "conditions": [6, 5], "products": [2]}, {"reactants": [2], "conditions": [9, 8], "products": [1]}, {"reactants": [1], "conditions": [0], "products": [7]}], "diagram_type": "multiple"}, {"id": 717, "width": 1352, "height": 1016, "file_name": "ol027494k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1095.0, 321.0, 36.7, 42.8], "category_id": 3}, {"id": 1, "bbox": [131.0, 193.0, 36.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [0.0, 389.0, 1352.0, 627.0], "category_id": 4}, {"id": 3, "bbox": [284.0, 129.0, 288.0, 101.0], "category_id": 2}, {"id": 4, "bbox": [284.0, 8.0, 298.0, 96.0], "category_id": 2}, {"id": 5, "bbox": [784.6, 320.9, 33.4, 43.1], "category_id": 3}, {"id": 6, "bbox": [72.0, 15.4, 209.3, 187.9], "category_id": 1}, {"id": 7, "bbox": [620.2, 10.0, 351.5, 277.8], "category_id": 1}, {"id": 8, "bbox": [959.0, 8.0, 321.6, 274.2], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 3], "products": [7, 8]}], "corefs": [[6, 1], [7, 5], [8, 0]], "caption": "Table 2. Alkenylation Reaction of Various Enolates with Alkenylselenonium Salt 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 574, 377, 602], "ImageBB": [73, 605, 411, 859]}, "diagram_type": "single"}, {"id": 355, "width": 1348, "height": 1032, "file_name": "ol200703g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1013.0, 27.0, 273.0, 202.9], "category_id": 1}, {"id": 1, "bbox": [541.0, 1.0, 456.0, 139.0], "category_id": 2}, {"id": 2, "bbox": [687.0, 160.0, 180.0, 100.0], "category_id": 2}, {"id": 3, "bbox": [7.0, 352.0, 1341.0, 680.0], "category_id": 4}, {"id": 4, "bbox": [197.0, 249.0, 33.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [382.0, 121.0, 130.0, 55.0], "category_id": 2}, {"id": 6, "bbox": [66.0, 18.0, 348.0, 209.0], "category_id": 1}, {"id": 7, "bbox": [1126.0, 244.0, 97.0, 55.0], "category_id": 3}], "reactions": [{"reactants": [6, 5], "conditions": [1, 2], "products": [0]}], "corefs": [[6, 4], [0, 7]], "caption": "Table 1. Copper-Catalyzed Enantioselective Propargylic Ami- nation of Propargylic Pentafluorobenzoates (1) with Anilinesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 171, 767, 198], "ImageBB": [436, 209, 773, 467]}, "diagram_type": "single"}, {"id": 1289, "width": 2808, "height": 868, "file_name": "op200112g-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1689.86, 511.38, 592.78, 227.59], "category_id": 1}, {"id": 1, "bbox": [1022.62, 22.48, 545.03, 250.07], "category_id": 1}, {"id": 2, "bbox": [1864.04, 764.26, 259.87, 57.6], "category_id": 3}, {"id": 3, "bbox": [529.57, 591.46, 363.82, 161.56], "category_id": 1}, {"id": 4, "bbox": [1864.04, 290.81, 276.73, 53.39], "category_id": 3}, {"id": 5, "bbox": [1028.24, 502.95, 549.24, 250.07], "category_id": 1}, {"id": 6, "bbox": [1216.47, 292.22, 302.01, 56.19], "category_id": 3}, {"id": 7, "bbox": [1682.83, 0.0, 592.79, 280.98], "category_id": 1}, {"id": 8, "bbox": [587.17, 764.26, 313.24, 53.38], "category_id": 3}, {"id": 9, "bbox": [522.55, 321.72, 375.05, 214.94], "category_id": 1}, {"id": 10, "bbox": [1223.5, 764.26, 282.34, 56.19], "category_id": 3}], "caption": "Scheme 2. Retrosynthetic approaches to the key iso\ufb02av-3-ene intermediate 8", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 497, 107], "ImageBB": [71, 117, 773, 334]}, "reactions": [{"reactants": [1], "conditions": [], "products": [7]}, {"reactants": [1], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [3, 9]}, {"reactants": [5], "conditions": [], "products": [0]}], "diagram_type": "tree"}, {"id": 132, "width": 1356, "height": 712, "file_name": "op900056s-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.2, 625.5, 272.8, 86.5], "category_id": 3}, {"id": 1, "bbox": [9.4, 3.0, 341.2, 173.1], "category_id": 1}, {"id": 2, "bbox": [3.0, 214.0, 419.5, 89.0], "category_id": 3}, {"id": 3, "bbox": [432.5, 310.9, 414.9, 292.8], "category_id": 1}, {"id": 4, "bbox": [542.6, 116.4, 146.6, 50.8], "category_id": 2}, {"id": 5, "bbox": [800.1, 1.2, 345.9, 174.5], "category_id": 1}, {"id": 6, "bbox": [534.0, 32.0, 148.0, 60.0], "category_id": 2}, {"id": 7, "bbox": [774.5, 206.0, 581.5, 98.0], "category_id": 3}, {"id": 8, "bbox": [398.17, 76.12, 59.64, 55.97], "category_id": 1}], "reactions": [{"reactants": [1, 8], "conditions": [6, 4], "products": [5]}], "corefs": [[1, 2], [5, 7], [3, 0]], "caption": "Figure 1. DMI hydrogenation catalysed by Ru-BINAP.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 229, 728, 243], "ImageBB": [424, 47, 763, 225]}, "diagram_type": "single"}, {"id": 1362, "width": 2404, "height": 664, "file_name": "op900242x-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [612.12, 600.4, 42.1, 51.73], "category_id": 3}, {"id": 1, "bbox": [2055.25, 601.6, 48.1, 50.53], "category_id": 3}, {"id": 2, "bbox": [1967.46, 160.03, 381.22, 411.49], "category_id": 1}, {"id": 3, "bbox": [1277.16, 597.99, 46.9, 50.53], "category_id": 3}, {"id": 4, "bbox": [2212.79, 386.23, 191.21, 73.39], "category_id": 2}, {"id": 5, "bbox": [529.14, 121.52, 383.63, 407.89], "category_id": 1}, {"id": 6, "bbox": [1118.42, 131.15, 381.22, 411.49], "category_id": 1}, {"id": 7, "bbox": [0.0, 123.93, 377.62, 409.09], "category_id": 1}, {"id": 8, "bbox": [794.92, 298.39, 176.78, 46.93], "category_id": 2}, {"id": 9, "bbox": [92.6, 604.01, 44.5, 48.12], "category_id": 3}, {"id": 10, "bbox": [1680.03, 425.93, 268.18, 42.11], "category_id": 2}, {"id": 11, "bbox": [322.3, 298.39, 175.58, 46.93], "category_id": 2}, {"id": 12, "bbox": [1738.96, 332.08, 120.26, 44.52], "category_id": 2}], "caption": "Scheme 1. Some details of the commercial route for the fluoroaryl-amine mesylate 1", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 525, 60], "ImageBB": [109, 65, 710, 231]}, "reactions": [{"reactants": [7], "conditions": [11], "products": [5]}, {"reactants": [5], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [12, 10], "products": [2, 4]}], "diagram_type": "single"}, {"id": 873, "width": 1352, "height": 676, "file_name": "ol701624y-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [879.0, 4.0, 368.0, 277.0], "category_id": 1}, {"id": 1, "bbox": [108.0, 47.0, 365.0, 203.0], "category_id": 1}, {"id": 2, "bbox": [539.0, 79.0, 257.0, 37.0], "category_id": 2}, {"id": 3, "bbox": [586.0, 154.0, 166.0, 42.0], "category_id": 2}, {"id": 4, "bbox": [621.0, 217.0, 95.0, 38.0], "category_id": 2}, {"id": 5, "bbox": [905.0, 282.0, 84.0, 32.0], "category_id": 3}, {"id": 6, "bbox": [270.0, 279.0, 89.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [7.0, 337.0, 1345.0, 339.0], "category_id": 4}, {"id": 8, "bbox": [539.0, 24.0, 258.0, 39.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [8, 2, 3, 4], "products": [0]}], "corefs": [[1, 6], [0, 5]], "caption": "Table 5.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 740, 120, 753], "ImageBB": [73, 756, 411, 925]}, "diagram_type": "single"}, {"id": 107, "width": 1344, "height": 504, "file_name": "ja001164i-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [445.34, 8.06, 331.66, 121.69], "category_id": 2}, {"id": 1, "bbox": [474.75, 167.31, 270.8, 74.02], "category_id": 2}, {"id": 2, "bbox": [805.43, 84.13, 135.89, 33.45], "category_id": 2}, {"id": 3, "bbox": [99.45, 76.02, 301.23, 161.25], "category_id": 1}, {"id": 4, "bbox": [1025.54, 76.02, 222.11, 160.23], "category_id": 1}, {"id": 5, "bbox": [4.04, 375.11, 1333.87, 127.71], "category_id": 4}, {"id": 6, "bbox": [123.65, 296.05, 256.43, 45.62], "category_id": 2}, {"id": 7, "bbox": [230.3, 260.63, 45.61, 33.44], "category_id": 3}, {"id": 8, "bbox": [1052.93, 259.61, 170.38, 41.56], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0, 1, 2], "products": [4]}], "corefs": [[3, 7], [4, 8]], "caption": "Table 6. Chiral LBA-catalyzed Enantioselective Protonation of 5aa", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 408, 78], "ImageBB": [74, 86, 410, 212]}, "diagram_type": "single"}, {"id": 990, "width": 1356, "height": 396, "file_name": "ja211778j-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [594.9, 287.15, 89.54, 58.38], "category_id": 2}, {"id": 1, "bbox": [849.96, 112.01, 70.55, 50.23], "category_id": 2}, {"id": 2, "bbox": [472.8, 0.0, 371.05, 54.99], "category_id": 2}, {"id": 3, "bbox": [49.52, 76.03, 382.58, 103.86], "category_id": 2}, {"id": 4, "bbox": [27.13, 238.95, 426.68, 113.36], "category_id": 2}, {"id": 5, "bbox": [636.28, 50.23, 42.06, 45.49], "category_id": 3}, {"id": 6, "bbox": [592.87, 195.5, 139.06, 51.6], "category_id": 2}, {"id": 7, "bbox": [883.2, 245.06, 441.6, 105.9], "category_id": 2}], "caption": "Scheme 1. Proposed Catalytic Cycle for Hydrogen Ev olution Catalyzed by [H2]+ ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 753, 125], "ImageBB": [448, 131, 787, 230]}, "reactions": [{"reactants": [4], "conditions": [3], "products": [2]}, {"reactants": [2], "conditions": [1], "products": [7]}, {"reactants": [7], "conditions": [6, 0], "products": [4]}], "diagram_type": "graph"}, {"id": 784, "width": 1352, "height": 1008, "file_name": "jo5026145-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [343.27, 192.39, 235.34, 96.83], "category_id": 2}, {"id": 1, "bbox": [738.0, 322.0, 89.4, 52.9], "category_id": 3}, {"id": 2, "bbox": [355.6, 105.1, 186.1, 48.6], "category_id": 2}, {"id": 3, "bbox": [1152.54, 319.3, 84.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 23.9, 307.2, 288.0], "category_id": 1}, {"id": 5, "bbox": [591.0, 21.2, 334.5, 296.8], "category_id": 1}, {"id": 6, "bbox": [1062.3, 1.0, 282.7, 286.7], "category_id": 1}, {"id": 7, "bbox": [103.0, 318.0, 71.2, 55.6], "category_id": 3}, {"id": 8, "bbox": [11.0, 396.0, 1341.0, 592.0], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [2, 0], "products": [5, 6]}], "corefs": [[4, 7], [5, 1], [6, 3]], "caption": "Table 1. Optimization of Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 250, 343, 265], "ImageBB": [82, 271, 420, 523]}, "diagram_type": "single"}, {"id": 1284, "width": 1344, "height": 972, "file_name": "op200019k-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [498.87, 441.07, 267.59, 63.88], "category_id": 2}, {"id": 1, "bbox": [706.63, 820.96, 346.25, 86.74], "category_id": 2}, {"id": 2, "bbox": [230.61, 396.7, 155.31, 174.81], "category_id": 1}, {"id": 3, "bbox": [276.33, 210.45, 41.01, 43.03], "category_id": 3}, {"id": 4, "bbox": [847.82, 393.33, 220.52, 213.15], "category_id": 1}, {"id": 5, "bbox": [932.53, 0.0, 209.77, 200.37], "category_id": 1}, {"id": 6, "bbox": [318.69, 277.02, 139.84, 94.13], "category_id": 2}, {"id": 7, "bbox": [769.82, 275.0, 218.51, 89.42], "category_id": 2}, {"id": 8, "bbox": [706.63, 699.26, 287.08, 88.75], "category_id": 2}, {"id": 9, "bbox": [587.62, 882.82, 52.44, 43.7], "category_id": 3}, {"id": 10, "bbox": [989.01, 212.47, 38.32, 43.03], "category_id": 3}, {"id": 11, "bbox": [528.46, 146.58, 250.11, 94.13], "category_id": 2}, {"id": 12, "bbox": [227.92, 30.93, 178.17, 172.8], "category_id": 1}, {"id": 13, "bbox": [485.43, 691.87, 188.25, 208.43], "category_id": 1}, {"id": 14, "bbox": [276.33, 582.27, 53.79, 44.38], "category_id": 3}, {"id": 15, "bbox": [1026.66, 272.31, 147.24, 93.46], "category_id": 2}, {"id": 16, "bbox": [180.19, 275.0, 96.14, 98.84], "category_id": 2}, {"id": 17, "bbox": [986.99, 584.96, 40.34, 45.72], "category_id": 3}, {"id": 18, "bbox": [444.41, 527.81, 378.53, 53.79], "category_id": 2}, {"id": 19, "bbox": [495.51, 66.56, 289.78, 61.19], "category_id": 2}, {"id": 20, "bbox": [194.98, 750.36, 287.76, 92.12], "category_id": 2}], "caption": "Scheme 4. Wittig route to \ufb02uoromethyl butenolide 13", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 371, 372, 391], "ImageBB": [71, 400, 407, 643]}, "reactions": [{"reactants": [12], "conditions": [19, 11], "products": [5]}, {"reactants": [5], "conditions": [7, 15], "products": [4]}, {"reactants": [2], "conditions": [16, 6], "products": [12]}, {"reactants": [2], "conditions": [0, 18], "products": [4]}, {"reactants": [4], "conditions": [8, 1], "products": [13]}], "diagram_type": "graph"}, {"id": 368, "width": 1348, "height": 816, "file_name": "ol102738b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [868.3, 4.2, 336.9, 185.3], "category_id": 1}, {"id": 1, "bbox": [525.6, 159.0, 52.4, 47.0], "category_id": 3}, {"id": 2, "bbox": [141.4, 9.9, 258.6, 156.1], "category_id": 1}, {"id": 3, "bbox": [413.3, 30.6, 266.9, 121.8], "category_id": 1}, {"id": 4, "bbox": [689.0, 9.0, 178.6, 88.6], "category_id": 2}, {"id": 5, "bbox": [690.0, 108.2, 155.8, 48.7], "category_id": 2}, {"id": 6, "bbox": [208.2, 156.1, 43.8, 49.9], "category_id": 3}, {"id": 7, "bbox": [1006.0, 148.0, 46.0, 48.0], "category_id": 3}, {"id": 8, "bbox": [10.0, 289.0, 1338.0, 527.0], "category_id": 4}], "reactions": [{"reactants": [2, 3], "conditions": [4, 5], "products": [0]}], "corefs": [[2, 6], [3, 1], [0, 7]], "caption": "Table 3. PBu3-Catalyzed [3 \u00fe 2] Cyclization of 1 and 2a", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 325, 732, 343], "ImageBB": [436, 353, 773, 557]}, "diagram_type": "single"}, {"id": 589, "width": 1352, "height": 508, "file_name": "acs.oprd.6b00180-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [652.3, 38.0, 300.7, 90.0], "category_id": 2}, {"id": 1, "bbox": [4.0, 271.0, 1341.0, 237.0], "category_id": 4}, {"id": 2, "bbox": [1211.0, 200.0, 44.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [682.0, 143.0, 233.0, 95.0], "category_id": 2}, {"id": 4, "bbox": [993.0, 1.9, 359.0, 218.1], "category_id": 1}, {"id": 5, "bbox": [381.3, 74.7, 246.7, 134.3], "category_id": 1}, {"id": 6, "bbox": [161.28, 196.04, 33.62, 47.16], "category_id": 3}, {"id": 7, "bbox": [1.0, 59.7, 287.9, 152.7], "category_id": 1}], "reactions": [{"reactants": [7, 5], "conditions": [0, 3], "products": [4]}], "corefs": [[7, 6], [4, 2]], "caption": "Table 4. E\ufb00ect of the Amount of Aryl Bromide on the Heterogeneous Pd(OAc)2 Catalyzed Suzuki Reaction of 4- Bromoanisole (1) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 233, 411, 278], "ImageBB": [82, 285, 420, 412]}, "diagram_type": "single"}, {"id": 660, "width": 1476, "height": 2912, "file_name": "ol4025293-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [145.7, 1079.4, 482.2, 453.7], "category_id": 1}, {"id": 1, "bbox": [316.0, 267.0, 145.3, 269.0], "category_id": 1}, {"id": 2, "bbox": [915.0, 1586.2, 407.7, 467.0], "category_id": 1}, {"id": 3, "bbox": [282.1, 1583.7, 330.4, 458.9], "category_id": 1}, {"id": 4, "bbox": [721.9, 1080.0, 435.0, 449.0], "category_id": 1}, {"id": 5, "bbox": [645.3, 649.7, 333.5, 374.3], "category_id": 1}, {"id": 6, "bbox": [970.5, 689.5, 373.0, 147.1], "category_id": 1}, {"id": 7, "bbox": [226.7, 650.0, 346.0, 373.1], "category_id": 1}, {"id": 8, "bbox": [947.0, 840.0, 422.2, 47.1], "category_id": 2}, {"id": 9, "bbox": [505.0, 269.3, 223.3, 117.7], "category_id": 1}, {"id": 10, "bbox": [380.0, 590.0, 33.0, 39.0], "category_id": 3}, {"id": 11, "bbox": [603.0, 1308.0, 241.0, 32.0], "category_id": 2}, {"id": 12, "bbox": [698.0, 1265.0, 59.0, 29.0], "category_id": 2}, {"id": 13, "bbox": [1153.0, 1310.0, 288.0, 36.0], "category_id": 2}, {"id": 14, "bbox": [1174.0, 1258.0, 252.0, 36.0], "category_id": 2}, {"id": 15, "bbox": [689.0, 1758.0, 93.0, 68.0], "category_id": 2}, {"id": 16, "bbox": [1025.0, 2061.0, 150.0, 54.0], "category_id": 3}, {"id": 17, "bbox": [406.0, 2068.0, 33.0, 47.0], "category_id": 3}, {"id": 18, "bbox": [378.0, 1545.0, 24.0, 24.0], "category_id": 3}, {"id": 19, "bbox": [919.0, 1536.0, 44.0, 38.0], "category_id": 3}, {"id": 20, "bbox": [426.0, 1034.0, 41.0, 31.0], "category_id": 3}, {"id": 21, "bbox": [859.0, 1036.0, 41.0, 26.0], "category_id": 3}, {"id": 22, "bbox": [831.0, 595.0, 37.0, 56.0], "category_id": 3}, {"id": 23, "bbox": [593.0, 806.0, 145.0, 31.0], "category_id": 2}, {"id": 24, "bbox": [537.0, 841.0, 248.0, 44.0], "category_id": 2}, {"id": 25, "bbox": [1021.0, 402.0, 254.0, 32.0], "category_id": 2}, {"id": 26, "bbox": [1053.0, 364.0, 189.0, 32.0], "category_id": 2}, {"id": 27, "bbox": [503.0, 407.0, 231.0, 32.0], "category_id": 2}, {"id": 28, "bbox": [682.0, 206.0, 329.0, 387.0], "category_id": 1}, {"id": 29, "bbox": [147.0, 109.0, 1326.0, 71.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [9, 27], "products": [28]}, {"reactants": [28], "conditions": [26, 25], "products": [7]}, {"reactants": [7], "conditions": [23, 24], "products": [5]}, {"reactants": [5], "conditions": [6, 8], "products": [0]}, {"reactants": [0], "conditions": [12, 11], "products": [4]}, {"reactants": [4], "conditions": [14, 13], "products": [3]}, {"reactants": [3], "conditions": [15], "products": [2]}], "corefs": [[1, 10], [28, 22], [7, 20], [5, 21], [0, 18], [4, 19], [3, 17], [2, 16]], "caption": "Figure 1. Fluorescence spectra of probe 1 (5 \u03bcM, \u03bbex = 440 nm) in the presence of various metal ions (Li\u00fe, Zn2\u00fe, Ba2\u00fe, Mn2\u00fe, Hg2\u00fe, K\u00fe, Na\u00fe, Ca2\u00fe, Sr2\u00fe, Mg2\u00fe, Fe2\u00fe, Fe3\u00fe, and Cu2\u00fe) (A), and different concentrations of Cu2\u00fe ions (0 2500 \u03bcM) (B) in HEPES buffer (10 mM, pH 7.4). ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 797, 771, 869], "ImageBB": [404, 59, 773, 787]}, "diagram_type": "multiple"}, {"id": 960, "width": 1020, "height": 400, "file_name": "ja012253d-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [783.24, 4.59, 230.64, 168.81], "category_id": 1}, {"id": 1, "bbox": [113.28, 194.82, 279.11, 199.92], "category_id": 1}, {"id": 2, "bbox": [26.53, 285.09, 56.64, 48.45], "category_id": 2}, {"id": 3, "bbox": [394.94, 3.06, 237.27, 203.49], "category_id": 1}, {"id": 4, "bbox": [0.0, 4.59, 239.31, 165.75], "category_id": 1}, {"id": 5, "bbox": [520.97, 206.55, 234.21, 182.58], "category_id": 1}, {"id": 6, "bbox": [270.44, 9.69, 73.98, 59.67], "category_id": 2}], "caption": "Scheme 7", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 145, 125, 157], "ImageBB": [115, 157, 370, 257]}, "reactions": [{"reactants": [4], "conditions": [6], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [1, 2]}], "diagram_type": "tree"}, {"id": 749, "width": 1348, "height": 716, "file_name": "jo990938e-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [729.0, 195.0, 119.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [243.0, 195.0, 89.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [1010.0, 196.0, 122.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [483.88, 58.22, 52.99, 41.57], "category_id": 2}, {"id": 4, "bbox": [152.0, 14.0, 297.0, 171.0], "category_id": 1}, {"id": 5, "bbox": [662.0, 19.0, 262.0, 173.0], "category_id": 1}, {"id": 6, "bbox": [12.0, 272.0, 1336.0, 444.0], "category_id": 4}, {"id": 7, "bbox": [449.0, 133.0, 207.0, 99.0], "category_id": 2}, {"id": 8, "bbox": [937.0, 14.0, 263.0, 182.0], "category_id": 1}, {"id": 9, "bbox": [515.3, 2.0, 118.2, 114.9], "category_id": 1}, {"id": 10, "bbox": [587.6, 49.92, 38.63, 40.67], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [3, 9, 7], "products": [5, 8]}], "corefs": [[4, 1], [9, 10], [5, 0], [8, 2]], "caption": " Table 7. Additions of Transient Chiral Allenylindium Reagents from Mesylate ent-1 to Representative Achiral                       Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [444, 64, 770, 101], "ImageBB": [439, 110, 776, 289]}, "diagram_type": "single"}, {"id": 937, "width": 1352, "height": 500, "file_name": "acs.orglett.5b01044-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [85.89, 61.54, 190.73, 136.62], "category_id": 1}, {"id": 1, "bbox": [733.15, 4.06, 199.52, 256.32], "category_id": 1}, {"id": 2, "bbox": [498.46, 236.71, 309.76, 217.09], "category_id": 1}, {"id": 3, "bbox": [1064.56, 29.08, 202.9, 204.92], "category_id": 1}, {"id": 4, "bbox": [420.68, 2.71, 190.73, 256.99], "category_id": 1}, {"id": 5, "bbox": [1036.83, 297.57, 215.75, 86.57], "category_id": 2}, {"id": 6, "bbox": [811.61, 300.28, 190.72, 41.25], "category_id": 2}, {"id": 7, "bbox": [653.34, 399.02, 211.7, 47.34], "category_id": 3}], "caption": "Scheme 1. Reported Fu\u2019s Original Synthesis of Planar-Chiral Ferrocene-Fused 4-Dialkylaminopyridines 1 ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 787, 417, 817], "ImageBB": [82, 823, 420, 948]}, "reactions": [{"reactants": [0], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [6], "products": [5]}], "diagram_type": "multiple"}, {"id": 1012, "width": 980, "height": 1856, "file_name": "ja980022+-Scheme-c15.png", "license": 0, "bboxes": [{"id": 0, "bbox": [293.33, 105.84, 148.52, 91.92], "category_id": 2}, {"id": 1, "bbox": [0.0, 356.53, 365.74, 244.19], "category_id": 1}, {"id": 2, "bbox": [261.77, 908.97, 63.12, 43.63], "category_id": 3}, {"id": 3, "bbox": [384.3, 1705.59, 62.19, 52.92], "category_id": 3}, {"id": 4, "bbox": [512.4, 1674.95, 94.68, 49.21], "category_id": 2}, {"id": 5, "bbox": [452.2, 0.0, 406.44, 340.75], "category_id": 1}, {"id": 6, "bbox": [418.8, 988.81, 416.64, 253.48], "category_id": 1}, {"id": 7, "bbox": [419.9, 1330.49, 409.97, 248.83], "category_id": 1}, {"id": 8, "bbox": [496.68, 630.59, 160.42, 57.93], "category_id": 3}, {"id": 9, "bbox": [61.27, 1378.77, 76.11, 54.78], "category_id": 3}, {"id": 10, "bbox": [161.52, 241.4, 124.38, 55.71], "category_id": 3}, {"id": 11, "bbox": [261.77, 1236.71, 146.67, 91.92], "category_id": 2}, {"id": 12, "bbox": [698.05, 1702.8, 69.62, 55.71], "category_id": 3}, {"id": 13, "bbox": [512.4, 1233.93, 152.24, 57.56], "category_id": 3}, {"id": 14, "bbox": [293.33, 1364.84, 82.62, 51.07], "category_id": 2}, {"id": 15, "bbox": [817.8, 256.26, 161.52, 170.83], "category_id": 2}, {"id": 16, "bbox": [447.42, 384.38, 408.44, 310.11], "category_id": 1}, {"id": 17, "bbox": [192.15, 1658.24, 123.46, 57.56], "category_id": 2}, {"id": 18, "bbox": [25.06, 1000.88, 182.87, 251.62], "category_id": 1}, {"id": 19, "bbox": [61.27, 1706.52, 64.97, 53.85], "category_id": 3}, {"id": 20, "bbox": [161.52, 606.29, 62.19, 47.35], "category_id": 3}, {"id": 21, "bbox": [447.42, 384.38, 408.44, 310.11], "category_id": 1}, {"id": 22, "bbox": [512.4, 1577.46, 155.02, 54.78], "category_id": 3}, {"id": 23, "bbox": [0.0, 22.28, 328.6, 249.76], "category_id": 1}, {"id": 24, "bbox": [449.28, 277.61, 187.51, 58.49], "category_id": 3}, {"id": 25, "bbox": [25.06, 655.5, 375.02, 295.25], "category_id": 1}, {"id": 26, "bbox": [325.82, 234.9, 82.62, 47.35], "category_id": 2}, {"id": 27, "bbox": [192.15, 1746.44, 114.18, 51.07], "category_id": 2}, {"id": 28, "bbox": [25.06, 1247.86, 129.03, 58.49], "category_id": 3}], "caption": "Scheme 15", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 65, 503, 79], "ImageBB": [486, 84, 731, 548]}, "reactions": [{"reactants": [23, 1], "conditions": [0, 26], "products": [5, 21]}, {"reactants": [5], "conditions": [15], "products": [21]}, {"reactants": [18, 9], "conditions": [11, 14], "products": [6, 7]}, {"reactants": [19], "conditions": [17], "products": [3]}, {"reactants": [3], "conditions": [27], "products": [19]}, {"reactants": [3], "conditions": [4], "products": [12]}], "diagram_type": "tree"}, {"id": 56, "width": 2820, "height": 2588, "file_name": "ja406383h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1773.33, 4.81, 302.85, 200.76], "category_id": 1}, {"id": 1, "bbox": [279.5, 267.17, 2252.71, 2207.33], "category_id": 4}, {"id": 2, "bbox": [1165.11, 38.48, 119.3, 117.13], "category_id": 1}, {"id": 3, "bbox": [4.68, 2493.86, 2603.68, 62.74], "category_id": 2}, {"id": 4, "bbox": [1914.52, 207.92, 22.64, 32.41], "category_id": 3}, {"id": 5, "bbox": [1130.35, 203.57, 194.24, 42.19], "category_id": 3}, {"id": 6, "bbox": [1388.84, 8.07, 312.63, 83.46], "category_id": 2}, {"id": 7, "bbox": [920.73, 206.83, 20.46, 33.5], "category_id": 3}, {"id": 8, "bbox": [1436.63, 116.68, 194.24, 75.86], "category_id": 2}, {"id": 9, "bbox": [736.09, 3.73, 301.77, 166.0], "category_id": 1}], "reactions": [{"reactants": [9, 2], "conditions": [6, 8], "products": [0]}], "corefs": [[9, 7], [2, 5], [0, 4]], "caption": "Table 2. Substrate Scope of the Ir-Catalyzed C\u2212H Amidation of Benzamidesa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 522, 110], "ImageBB": [82, 116, 787, 763]}, "diagram_type": "single"}, {"id": 1033, "width": 2060, "height": 816, "file_name": "jo0014820-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [566.78, 540.01, 389.54, 225.7], "category_id": 1}, {"id": 1, "bbox": [0.0, 507.04, 389.53, 308.13], "category_id": 1}, {"id": 2, "bbox": [1478.79, 77.29, 111.3, 51.53], "category_id": 2}, {"id": 3, "bbox": [1700.35, 537.95, 359.65, 234.97], "category_id": 1}, {"id": 4, "bbox": [1549.89, 594.63, 116.45, 55.65], "category_id": 2}, {"id": 5, "bbox": [533.81, 9.28, 364.8, 228.78], "category_id": 1}, {"id": 6, "bbox": [420.45, 596.69, 138.09, 56.69], "category_id": 2}, {"id": 7, "bbox": [1129.44, 529.71, 364.81, 246.3], "category_id": 1}, {"id": 8, "bbox": [1070.71, 0.0, 392.62, 267.95], "category_id": 1}, {"id": 9, "bbox": [922.31, 77.29, 117.48, 51.53], "category_id": 2}, {"id": 10, "bbox": [991.36, 594.63, 120.57, 55.65], "category_id": 2}, {"id": 11, "bbox": [41.22, 6.18, 346.25, 203.02], "category_id": 1}, {"id": 12, "bbox": [1845.65, 750.25, 62.86, 56.68], "category_id": 3}, {"id": 13, "bbox": [160.76, 226.72, 71.11, 55.65], "category_id": 3}, {"id": 14, "bbox": [1675.62, 16.49, 353.46, 265.88], "category_id": 1}, {"id": 15, "bbox": [124.69, 748.19, 82.44, 64.92], "category_id": 3}, {"id": 16, "bbox": [1723.02, 390.58, 132.94, 47.41], "category_id": 2}], "caption": "Scheme 2", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 64, 453, 78], "ImageBB": [168, 84, 683, 288]}, "reactions": [{"reactants": [5], "conditions": [9], "products": [8]}, {"reactants": [8], "conditions": [2], "products": [14]}, {"reactants": [14], "conditions": [16], "products": [3]}, {"reactants": [3], "conditions": [4], "products": [7]}, {"reactants": [7], "conditions": [10], "products": [0]}, {"reactants": [0], "conditions": [6], "products": [1]}], "diagram_type": "tree"}, {"id": 629, "width": 1264, "height": 1000, "file_name": "ol501422k-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [330.3, 245.2, 216.1, 251.9], "category_id": 4}, {"id": 1, "bbox": [490.0, 0.0, 223.0, 76.0], "category_id": 2}, {"id": 2, "bbox": [123.0, 184.0, 53.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [365.0, 194.0, 93.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [82.0, 954.0, 129.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [750.5, 13.3, 370.6, 167.3], "category_id": 1}, {"id": 6, "bbox": [480.13, 687.71, 122.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [485.0, 949.7, 118.0, 43.3], "category_id": 3}, {"id": 8, "bbox": [87.0, 693.42, 119.0, 36.0], "category_id": 3}, {"id": 9, "bbox": [828.85, 185.71, 152.0, 39.0], "category_id": 3}, {"id": 10, "bbox": [502.0, 90.0, 202.7, 43.7], "category_id": 2}, {"id": 11, "bbox": [38.0, 37.9, 231.6, 110.4], "category_id": 1}, {"id": 12, "bbox": [873.71, 682.87, 131.0, 41.0], "category_id": 3}, {"id": 13, "bbox": [326.2, 13.6, 173.5, 161.1], "category_id": 1}, {"id": 14, "bbox": [401.0, 784.6, 403.6, 172.4], "category_id": 1}, {"id": 15, "bbox": [3.9, 785.2, 326.8, 157.9], "category_id": 1}, {"id": 16, "bbox": [3.9, 523.6, 381.1, 165.2], "category_id": 1}, {"id": 17, "bbox": [403.0, 523.2, 376.5, 163.2], "category_id": 1}, {"id": 18, "bbox": [796.6, 517.2, 462.2, 173.9], "category_id": 1}], "reactions": [{"reactants": [11, 13], "conditions": [1, 10], "products": [5]}], "corefs": [[11, 2], [13, 3], [5, 9], [16, 8], [17, 6], [18, 12], [15, 4], [14, 7]], "caption": "Table 3. E\ufb00ect of Substituents on the Nitroso Moietya", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 383, 110], "ImageBB": [93, 116, 409, 366]}, "diagram_type": "single"}, {"id": 797, "width": 1352, "height": 1232, "file_name": "jo501014e-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [485.0, 930.0, 357.0, 289.0], "category_id": 1}, {"id": 1, "bbox": [145.0, 28.0, 943.0, 61.0], "category_id": 2}, {"id": 2, "bbox": [223.0, 538.0, 213.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [761.0, 91.0, 350.0, 447.0], "category_id": 1}, {"id": 4, "bbox": [890.0, 728.0, 319.0, 220.0], "category_id": 1}, {"id": 5, "bbox": [147.0, 755.0, 327.0, 174.0], "category_id": 1}, {"id": 6, "bbox": [514.0, 530.0, 236.0, 103.0], "category_id": 2}, {"id": 7, "bbox": [826.0, 534.0, 211.0, 95.0], "category_id": 2}, {"id": 8, "bbox": [147.0, 673.0, 669.0, 75.0], "category_id": 2}, {"id": 9, "bbox": [137.0, 154.0, 377.0, 384.0], "category_id": 1}, {"id": 10, "bbox": [521.0, 146.0, 225.0, 390.0], "category_id": 1}, {"id": 11, "bbox": [482.0, 775.0, 340.0, 60.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [11], "products": [4]}, {"reactants": [5], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [4]}], "corefs": [[9, 2], [10, 6], [3, 7]], "caption": "Figure 1. (a) Bioactive 2H-indazoles. (b) A typical Davis\u2212Beirut reaction proceeding through the proposed nitrosoimine intermediate.6 ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 881, 417, 909], "ImageBB": [82, 563, 420, 871]}, "diagram_type": "graph"}, {"id": 909, "width": 1352, "height": 600, "file_name": "acs.joc.5b00632-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [883.0, 549.1, 203.7, 48.0], "category_id": 3}, {"id": 1, "bbox": [205.0, 251.0, 269.5, 54.8], "category_id": 3}, {"id": 2, "bbox": [836.0, 37.1, 373.0, 203.9], "category_id": 1}, {"id": 3, "bbox": [800.2, 416.4, 362.4, 133.6], "category_id": 1}, {"id": 4, "bbox": [272.0, 544.2, 196.0, 50.8], "category_id": 3}, {"id": 5, "bbox": [840.0, 256.0, 402.0, 134.0], "category_id": 3}, {"id": 6, "bbox": [125.7, 41.6, 359.0, 206.4], "category_id": 1}, {"id": 7, "bbox": [118.6, 294.8, 469.2, 247.5], "category_id": 1}, {"id": 8, "bbox": [552.0, 174.0, 225.0, 55.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [8], "products": [2]}], "corefs": [[6, 1], [2, 5], [7, 4], [3, 0]], "caption": "Figure 1. Thiophenopyridine antiplatelet agents.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 804, 318, 818], "ImageBB": [82, 645, 420, 795]}, "diagram_type": "single"}, {"id": 857, "width": 1356, "height": 856, "file_name": "jo200480h-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [600.0, 147.0, 361.0, 355.0], "category_id": 1}, {"id": 1, "bbox": [4.6, 19.3, 241.4, 147.7], "category_id": 1}, {"id": 2, "bbox": [401.9, 152.4, 125.5, 46.6], "category_id": 3}, {"id": 3, "bbox": [630.0, 505.0, 193.1, 47.9], "category_id": 3}, {"id": 4, "bbox": [39.0, 502.0, 191.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [271.0, 41.0, 443.9, 107.0], "category_id": 1}, {"id": 6, "bbox": [17.0, 205.0, 417.0, 295.0], "category_id": 1}, {"id": 7, "bbox": [728.0, 3.0, 596.0, 94.0], "category_id": 2}, {"id": 8, "bbox": [881.0, 107.0, 320.0, 46.0], "category_id": 2}, {"id": 9, "bbox": [3.0, 617.0, 1346.0, 239.0], "category_id": 4}, {"id": 10, "bbox": [47.0, 161.0, 39.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [1, 5], "conditions": [7, 8], "products": [6, 0]}], "corefs": [[1, 10], [5, 2], [6, 4], [0, 3]], "caption": "Table 4. Heteroannulation Reaction between 4-Acetamido- 3-iodopyridine (1) and Unsymmetrical Diarylacetylenes 24 27 ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 427, 767, 472], "ImageBB": [436, 483, 775, 697]}, "diagram_type": "multiple"}, {"id": 596, "width": 1352, "height": 372, "file_name": "acs.oprd.6b00126-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1122.1, 10.0, 229.9, 189.0], "category_id": 1}, {"id": 1, "bbox": [784.2, 11.0, 252.8, 191.0], "category_id": 1}, {"id": 2, "bbox": [4.0, 5.1, 317.8, 194.9], "category_id": 1}, {"id": 3, "bbox": [0.0, 295.0, 1342.0, 77.0], "category_id": 4}, {"id": 4, "bbox": [116.0, 213.0, 29.0, 39.0], "category_id": 3}, {"id": 5, "bbox": [1237.0, 213.0, 29.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [899.0, 211.0, 35.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [372.0, 223.0, 343.0, 53.0], "category_id": 2}, {"id": 8, "bbox": [449.0, 186.0, 196.0, 40.0], "category_id": 2}, {"id": 9, "bbox": [391.0, 138.0, 305.0, 42.0], "category_id": 2}, {"id": 10, "bbox": [370.0, 47.0, 345.0, 43.0], "category_id": 2}, {"id": 11, "bbox": [401.0, 8.0, 278.0, 33.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [11, 10, 9, 8, 7], "products": [1, 0]}], "corefs": [[2, 4], [1, 6], [0, 5]], "caption": "Table 1. Reevaluation of Previously Reported Reaction Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 217, 392, 247], "ImageBB": [82, 253, 420, 346]}, "diagram_type": "single"}, {"id": 623, "width": 1352, "height": 516, "file_name": "ol502423k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [397.0, 42.0, 181.0, 55.0], "category_id": 2}, {"id": 1, "bbox": [1024.32, 241.27, 312.08, 51.0], "category_id": 3}, {"id": 2, "bbox": [623.59, 245.14, 250.91, 47.16], "category_id": 3}, {"id": 3, "bbox": [389.0, 109.0, 195.0, 47.0], "category_id": 2}, {"id": 4, "bbox": [0.0, 317.0, 1352.0, 199.0], "category_id": 4}, {"id": 5, "bbox": [614.36, 5.32, 290.04, 211.68], "category_id": 1}, {"id": 6, "bbox": [1022.45, 3.86, 315.55, 213.14], "category_id": 1}, {"id": 7, "bbox": [248.55, 247.27, 98.0, 41.0], "category_id": 3}, {"id": 8, "bbox": [253.0, 42.1, 102.8, 165.6], "category_id": 1}, {"id": 9, "bbox": [76.32, 245.27, 93.0, 43.0], "category_id": 3}, {"id": 10, "bbox": [10.9, 26.0, 212.1, 209.0], "category_id": 1}], "reactions": [{"reactants": [10, 8], "conditions": [0, 3], "products": [5]}, {"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [5]}], "corefs": [[10, 9], [8, 7], [5, 2], [6, 1]], "caption": "Table 1. Preparation of 2-Aminoindoles 4a", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 466, 692, 487], "ImageBB": [449, 493, 787, 622]}, "diagram_type": "single"}, {"id": 365, "width": 1208, "height": 1988, "file_name": "ol102784c-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [812.0, 31.0, 356.0, 121.0], "category_id": 1}, {"id": 1, "bbox": [0.0, 214.0, 1175.0, 1774.0], "category_id": 4}, {"id": 2, "bbox": [447.0, 4.0, 267.0, 42.0], "category_id": 2}, {"id": 3, "bbox": [381.0, 51.0, 392.0, 48.0], "category_id": 2}, {"id": 4, "bbox": [459.0, 107.0, 216.0, 44.0], "category_id": 2}, {"id": 5, "bbox": [251.0, 72.0, 110.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [40.0, 30.0, 211.1, 121.0], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [2, 3, 4], "products": [0]}], "corefs": [], "caption": "Table 3. Copper-Catalyzed C-S Coupling of Different Aryl Bromides with Potassium Thiocyanatea ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 275, 371, 302], "ImageBB": [76, 311, 378, 808]}, "diagram_type": "single"}, {"id": 1235, "width": 2192, "height": 456, "file_name": "op020098x-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 26.35, 404.63, 201.98], "category_id": 1}, {"id": 1, "bbox": [460.55, 379.82, 372.83, 76.18], "category_id": 2}, {"id": 2, "bbox": [527.44, 47.2, 637.09, 210.77], "category_id": 1}, {"id": 3, "bbox": [1303.8, 0.0, 888.2, 245.9], "category_id": 1}], "caption": "Scheme 3. Oligonucleotide synthesis using I-linker solid support", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 534, 434, 548], "ImageBB": [151, 552, 699, 666]}, "reactions": [{"reactants": [0], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [3]}], "diagram_type": "multiple"}, {"id": 627, "width": 1752, "height": 1960, "file_name": "ol501424f-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1118.0, 1551.0, 35.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [950.0, 1594.0, 439.0, 96.0], "category_id": 2}, {"id": 2, "bbox": [192.0, 1590.0, 409.0, 100.0], "category_id": 2}, {"id": 3, "bbox": [549.0, 1401.0, 374.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [601.0, 1466.0, 197.0, 58.0], "category_id": 2}, {"id": 5, "bbox": [763.0, 936.0, 263.0, 91.0], "category_id": 2}, {"id": 6, "bbox": [307.0, 1103.0, 47.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [607.0, 1097.0, 66.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [1151.0, 1111.0, 51.0, 41.0], "category_id": 3}, {"id": 9, "bbox": [303.0, 1534.0, 33.0, 37.0], "category_id": 3}, {"id": 10, "bbox": [890.0, 1220.0, 267.0, 62.0], "category_id": 2}, {"id": 11, "bbox": [89.0, 61.0, 1404.0, 579.6], "category_id": 2}, {"id": 12, "bbox": [187.1, 960.8, 259.4, 129.1], "category_id": 1}, {"id": 13, "bbox": [489.1, 931.6, 269.0, 135.7], "category_id": 1}, {"id": 14, "bbox": [1018.1, 883.1, 315.2, 213.4], "category_id": 1}, {"id": 15, "bbox": [941.6, 1341.6, 393.9, 210.8], "category_id": 1}, {"id": 16, "bbox": [188.5, 1354.1, 298.3, 184.3], "category_id": 1}, {"id": 17, "bbox": [810.0, 1039.0, 148.0, 48.4], "category_id": 2}, {"id": 18, "bbox": [108.0, 689.9, 1361.0, 140.1], "category_id": 2}], "reactions": [{"reactants": [12, 13], "conditions": [5, 17], "products": [14]}, {"reactants": [14], "conditions": [10], "products": [15]}, {"reactants": [15], "conditions": [3, 4], "products": [16]}], "corefs": [[12, 6], [13, 7], [14, 8], [15, 0], [16, 9]], "caption": "Figure 3. (Top) Blown-up orbital interactions of diene and dienophile in the inverse demand Diels\u2212Alder. (Bottom) HOMO\u2212LUMO interaction diagram of the reactants. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 592, 784, 634], "ImageBB": [421, 637, 859, 1127]}, "diagram_type": "tree"}, {"id": 582, "width": 1356, "height": 1192, "file_name": "acs.orglett.5b00081-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [989.0, 419.0, 285.0, 267.4], "category_id": 1}, {"id": 1, "bbox": [87.0, 358.0, 212.4, 175.8], "category_id": 1}, {"id": 2, "bbox": [603.0, 39.0, 325.0, 266.9], "category_id": 1}, {"id": 3, "bbox": [985.08, 39.73, 286.12, 263.07], "category_id": 1}, {"id": 4, "bbox": [83.0, 62.0, 124.1, 117.8], "category_id": 1}, {"id": 5, "bbox": [681.0, 690.0, 182.0, 38.0], "category_id": 2}, {"id": 6, "bbox": [681.0, 317.0, 218.0, 36.0], "category_id": 2}, {"id": 7, "bbox": [1059.0, 311.0, 157.0, 36.0], "category_id": 2}, {"id": 8, "bbox": [87.98, 181.57, 115.91, 107.27], "category_id": 1}, {"id": 9, "bbox": [299.04, 416.86, 254.32, 257.78], "category_id": 1}, {"id": 10, "bbox": [266.0, 62.0, 290.0, 257.0], "category_id": 1}, {"id": 11, "bbox": [910.0, 129.0, 55.0, 55.0], "category_id": 1}, {"id": 12, "bbox": [632.0, 424.0, 286.0, 258.0], "category_id": 1}, {"id": 13, "bbox": [504.0, 734.0, 280.0, 389.0], "category_id": 1}, {"id": 14, "bbox": [965.0, 742.0, 287.0, 382.0], "category_id": 1}, {"id": 15, "bbox": [113.0, 735.0, 327.0, 383.0], "category_id": 1}, {"id": 16, "bbox": [191.0, 1148.0, 126.0, 39.0], "category_id": 2}, {"id": 17, "bbox": [528.0, 1147.0, 251.0, 43.0], "category_id": 2}, {"id": 18, "bbox": [1044.0, 1152.0, 145.0, 33.0], "category_id": 2}, {"id": 19, "bbox": [1092.0, 690.0, 117.0, 35.0], "category_id": 2}, {"id": 20, "bbox": [323.0, 308.0, 157.0, 38.0], "category_id": 2}, {"id": 21, "bbox": [376.0, 689.0, 149.0, 38.0], "category_id": 2}], "reactions": [{"reactants": [4, 8], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [11], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [9]}, {"reactants": [9, 1], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}], "corefs": [[10, 20], [2, 6], [3, 7], [0, 19], [12, 5], [9, 21], [15, 16], [13, 17], [14, 18]], "caption": "Figure 4. Plausible biosynthetic route for duclauxins.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 882, 706, 896], "ImageBB": [448, 575, 787, 873]}, "diagram_type": "tree"}, {"id": 942, "width": 1352, "height": 944, "file_name": "acs.orglett.5b01872-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [58.17, 625.43, 277.97, 171.07], "category_id": 1}, {"id": 1, "bbox": [874.51, 208.93, 57.48, 45.98], "category_id": 3}, {"id": 2, "bbox": [550.54, 772.16, 56.14, 45.3], "category_id": 3}, {"id": 3, "bbox": [26.38, 354.3, 424.74, 220.42], "category_id": 1}, {"id": 4, "bbox": [26.38, 58.15, 259.71, 143.34], "category_id": 1}, {"id": 5, "bbox": [528.63, 295.75, 177.92, 55.53], "category_id": 1}, {"id": 6, "bbox": [1091.61, 150.1, 200.87, 116.3], "category_id": 2}, {"id": 7, "bbox": [1183.59, 752.55, 83.19, 75.05], "category_id": 3}, {"id": 8, "bbox": [530.93, 469.92, 169.76, 76.4], "category_id": 2}, {"id": 9, "bbox": [296.91, 73.02, 87.25, 46.66], "category_id": 2}, {"id": 10, "bbox": [280.68, 502.38, 55.46, 45.97], "category_id": 3}, {"id": 11, "bbox": [779.82, 61.53, 265.8, 143.34], "category_id": 1}, {"id": 12, "bbox": [746.0, 601.77, 445.71, 204.19], "category_id": 1}, {"id": 13, "bbox": [779.82, 323.87, 411.89, 249.5], "category_id": 1}, {"id": 14, "bbox": [0.0, 835.71, 1211.32, 64.91], "category_id": 2}, {"id": 15, "bbox": [227.93, 152.13, 228.6, 121.71], "category_id": 2}, {"id": 16, "bbox": [211.02, 770.8, 58.16, 46.66], "category_id": 3}, {"id": 17, "bbox": [1200.5, 482.77, 49.37, 43.95], "category_id": 3}, {"id": 18, "bbox": [1057.79, 2.3, 275.95, 122.11], "category_id": 2}, {"id": 19, "bbox": [477.49, 351.5, 278.66, 77.18], "category_id": 2}, {"id": 20, "bbox": [121.74, 208.93, 45.99, 45.98], "category_id": 3}, {"id": 21, "bbox": [499.14, 37.19, 277.3, 87.22], "category_id": 2}, {"id": 22, "bbox": [448.41, 116.97, 39.23, 43.95], "category_id": 3}, {"id": 23, "bbox": [570.83, 151.46, 142.71, 114.94], "category_id": 2}, {"id": 24, "bbox": [1124.75, 519.96, 196.14, 48.68], "category_id": 2}, {"id": 25, "bbox": [334.79, 614.62, 355.75, 175.12], "category_id": 1}], "caption": "Scheme 2. An Attempt to Prepare the Divinyl Intermediate", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 504, 417, 519], "ImageBB": [82, 525, 420, 761]}, "reactions": [{"reactants": [4], "conditions": [9, 15], "products": [22]}, {"reactants": [22], "conditions": [21, 23], "products": [11]}, {"reactants": [11], "conditions": [18, 6], "products": [3]}, {"reactants": [3], "conditions": [5, 19, 8], "products": [13, 12]}], "diagram_type": "multiple"}, {"id": 962, "width": 1304, "height": 1964, "file_name": "ja0161958-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [991.39, 1088.6, 47.16, 49.12], "category_id": 2}, {"id": 1, "bbox": [293.72, 1089.22, 42.44, 49.52], "category_id": 2}, {"id": 2, "bbox": [295.5, 1296.89, 51.1, 52.07], "category_id": 2}, {"id": 3, "bbox": [925.56, 1900.14, 162.12, 57.97], "category_id": 3}, {"id": 4, "bbox": [0.0, 1395.14, 631.78, 498.12], "category_id": 1}, {"id": 5, "bbox": [239.74, 336.99, 62.88, 47.16], "category_id": 3}, {"id": 6, "bbox": [925.56, 1197.66, 62.88, 49.12], "category_id": 3}, {"id": 7, "bbox": [239.74, 1191.76, 60.92, 53.06], "category_id": 3}, {"id": 8, "bbox": [925.56, 336.99, 62.88, 50.11], "category_id": 3}, {"id": 9, "bbox": [303.61, 485.35, 45.19, 47.16], "category_id": 2}, {"id": 10, "bbox": [65.83, 0.0, 455.9, 310.47], "category_id": 1}, {"id": 11, "bbox": [239.74, 992.32, 63.87, 51.09], "category_id": 3}, {"id": 12, "bbox": [930.47, 990.35, 59.93, 50.11], "category_id": 3}, {"id": 13, "bbox": [743.79, 0.0, 458.84, 307.52], "category_id": 1}, {"id": 14, "bbox": [660.27, 1398.09, 639.63, 483.38], "category_id": 1}, {"id": 15, "bbox": [474.57, 1407.91, 94.32, 63.86], "category_id": 2}, {"id": 16, "bbox": [995.32, 1306.71, 48.14, 47.16], "category_id": 2}, {"id": 17, "bbox": [611.14, 73.69, 33.41, 49.12], "category_id": 2}, {"id": 18, "bbox": [65.83, 468.65, 460.81, 500.09], "category_id": 1}, {"id": 19, "bbox": [207.32, 1910.95, 169.98, 53.05], "category_id": 3}, {"id": 20, "bbox": [1167.26, 1394.16, 98.26, 65.82], "category_id": 2}, {"id": 21, "bbox": [739.86, 465.7, 458.84, 498.12], "category_id": 1}, {"id": 22, "bbox": [995.32, 479.46, 42.25, 48.14], "category_id": 2}, {"id": 23, "bbox": [0.0, 1960.07, 0.98, 3.93], "category_id": 3}], "caption": "Scheme 1. Synthesis of the Biomimetic Supramolecular Calix[6]arene-Based Cuprous Systems Presenting Two Different Cavitiesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 761, 100], "ImageBB": [446, 100, 772, 591]}, "reactions": [{"reactants": [10], "conditions": [17], "products": [13]}, {"reactants": [10], "conditions": [9], "products": [18]}, {"reactants": [13], "conditions": [22], "products": [21]}, {"reactants": [18], "conditions": [1], "products": [7]}, {"reactants": [7], "conditions": [2], "products": [4, 15]}, {"reactants": [21], "conditions": [0], "products": [6]}, {"reactants": [6], "conditions": [16], "products": [14, 20]}], "diagram_type": "tree"}, {"id": 208, "width": 1120, "height": 728, "file_name": "op0340964-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [13.0, 605.5, 188.0, 117.5], "category_id": 3}, {"id": 1, "bbox": [832.0, 606.5, 187.0, 117.5], "category_id": 3}, {"id": 2, "bbox": [851.6, 332.7, 268.4, 222.7], "category_id": 1}, {"id": 3, "bbox": [371.5, 162.7, 286.8, 61.5], "category_id": 2}, {"id": 4, "bbox": [4.9, 210.9, 247.2, 171.5], "category_id": 1}, {"id": 5, "bbox": [366.0, 345.0, 160.2, 97.3], "category_id": 2}, {"id": 6, "bbox": [849.9, 0.0, 264.1, 227.6], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 5], "products": [6, 2]}], "corefs": [[4, 0], [2, 1]], "caption": "Figure 2. Enzymatic and uncatalyzed hydrocyanation of benzaldehyde and 2-chlorobenzaldehyde. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 436, 409, 464], "ImageBB": [102, 251, 382, 433]}, "diagram_type": "tree"}, {"id": 854, "width": 1344, "height": 712, "file_name": "jo2008675-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [784.0, 114.0, 86.0, 44.0], "category_id": 2}, {"id": 1, "bbox": [105.0, 231.0, 48.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [1120.0, 234.0, 55.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [7.1, 19.1, 296.9, 209.9], "category_id": 1}, {"id": 4, "bbox": [367.3, 73.4, 319.7, 128.5], "category_id": 1}, {"id": 5, "bbox": [493.0, 219.0, 40.9, 50.9], "category_id": 3}, {"id": 6, "bbox": [4.0, 350.1, 1340.0, 361.9], "category_id": 4}, {"id": 7, "bbox": [991.4, 2.9, 346.5, 229.1], "category_id": 1}, {"id": 8, "bbox": [691.0, 164.0, 243.9, 49.9], "category_id": 2}], "reactions": [{"reactants": [3, 4], "conditions": [0, 8], "products": [7]}], "corefs": [[3, 1], [4, 5], [7, 2]], "caption": "Table 1. Reaction of 2-Hydroxyaryl-r,\u03b2-unsaturated Ketone 2a and Diethyl R-Bromomalonate 5 under Di\ufb00erent Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 245, 771, 290], "ImageBB": [437, 300, 773, 478]}, "diagram_type": "single"}, {"id": 1199, "width": 1356, "height": 552, "file_name": "ol502842f-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [109.89, 433.17, 58.34, 37.96], "category_id": 3}, {"id": 1, "bbox": [941.53, 385.04, 69.87, 36.61], "category_id": 2}, {"id": 2, "bbox": [36.63, 260.31, 206.22, 228.45], "category_id": 1}, {"id": 3, "bbox": [110.57, 179.64, 59.01, 38.64], "category_id": 3}, {"id": 4, "bbox": [834.36, 31.18, 281.51, 82.7], "category_id": 2}, {"id": 5, "bbox": [1117.9, 6.1, 192.65, 215.57], "category_id": 1}, {"id": 6, "bbox": [1105.01, 260.99, 214.36, 223.02], "category_id": 1}, {"id": 7, "bbox": [590.83, 140.32, 215.04, 213.54], "category_id": 1}, {"id": 8, "bbox": [250.31, 305.05, 317.46, 74.57], "category_id": 2}, {"id": 9, "bbox": [36.63, 2.71, 210.29, 225.74], "category_id": 1}, {"id": 10, "bbox": [307.97, 21.01, 253.69, 111.18], "category_id": 2}, {"id": 11, "bbox": [1169.46, 460.28, 52.23, 33.22], "category_id": 3}, {"id": 12, "bbox": [1176.24, 203.37, 58.34, 37.28], "category_id": 3}, {"id": 13, "bbox": [378.51, 140.32, 69.19, 35.93], "category_id": 2}, {"id": 14, "bbox": [851.32, 284.03, 252.34, 77.96], "category_id": 2}, {"id": 15, "bbox": [250.31, 228.45, 261.16, 73.45], "category_id": 2}, {"id": 16, "bbox": [280.83, 396.56, 257.77, 43.39], "category_id": 2}, {"id": 17, "bbox": [941.53, 134.22, 69.2, 35.93], "category_id": 2}, {"id": 18, "bbox": [678.34, 340.3, 46.8, 37.96], "category_id": 3}], "caption": "Scheme 6. Synthesis of Useful Synthetic Intermediates", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 750, 110], "ImageBB": [448, 116, 787, 254]}, "reactions": [{"reactants": [7], "conditions": [10, 13], "products": [9]}, {"reactants": [7], "conditions": [4, 17], "products": [5]}, {"reactants": [7], "conditions": [14, 1], "products": [6]}, {"reactants": [7], "conditions": [15, 8, 16], "products": [2]}], "diagram_type": "tree"}, {"id": 98, "width": 1348, "height": 884, "file_name": "ja0289088-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [522.13, 7.34, 218.09, 169.49], "category_id": 1}, {"id": 1, "bbox": [255.38, 187.24, 177.76, 128.14], "category_id": 1}, {"id": 2, "bbox": [511.8, 254.45, 314.23, 187.07], "category_id": 2}, {"id": 3, "bbox": [553.14, 203.78, 217.06, 39.23], "category_id": 2}, {"id": 4, "bbox": [7.04, 458.85, 1335.42, 416.06], "category_id": 4}, {"id": 5, "bbox": [725.81, 142.78, 146.75, 33.02], "category_id": 2}, {"id": 6, "bbox": [631.72, 127.27, 64.08, 48.53], "category_id": 1}, {"id": 7, "bbox": [916.05, 186.21, 177.77, 128.14], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [0, 6, 5, 3, 2], "products": [7]}], "corefs": [], "caption": "Table 3. Variation of the Amount of Water", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 654, 76], "ImageBB": [439, 84, 776, 305]}, "diagram_type": "single"}, {"id": 888, "width": 1348, "height": 560, "file_name": "ol5029892-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [173.06, 131.92, 35.29, 44.76], "category_id": 3}, {"id": 1, "bbox": [1060.54, 129.33, 43.9, 47.35], "category_id": 3}, {"id": 2, "bbox": [13.0, 473.0, 1335.0, 87.0], "category_id": 4}, {"id": 3, "bbox": [965.0, 364.0, 383.0, 52.5], "category_id": 3}, {"id": 4, "bbox": [405.0, 357.0, 192.0, 60.1], "category_id": 3}, {"id": 5, "bbox": [649.0, 368.0, 297.0, 51.4], "category_id": 3}, {"id": 6, "bbox": [119.9, 67.9, 145.8, 59.7], "category_id": 1}, {"id": 7, "bbox": [365.0, 249.0, 272.5, 68.4], "category_id": 1}, {"id": 8, "bbox": [14.12, 408.92, 309.72, 50.16], "category_id": 2}, {"id": 9, "bbox": [331.0, 109.4, 490.1, 50.5], "category_id": 2}, {"id": 10, "bbox": [989.5, 4.0, 185.5, 124.8], "category_id": 1}, {"id": 11, "bbox": [115.0, 368.7, 105.5, 38.3], "category_id": 3}, {"id": 12, "bbox": [1021.2, 207.3, 251.7, 148.7], "category_id": 1}, {"id": 13, "bbox": [673.4, 228.1, 246.3, 105.6], "category_id": 1}, {"id": 14, "bbox": [9.7, 186.5, 319.5, 191.7], "category_id": 1}, {"id": 15, "bbox": [325.0, 4.0, 596.0, 90.3], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [15, 9], "products": [10]}], "corefs": [[6, 0], [10, 1], [14, 11], [7, 4], [13, 5], [12, 3]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 268, 110], "ImageBB": [82, 116, 419, 256]}, "diagram_type": "single"}, {"id": 545, "width": 956, "height": 1096, "file_name": "acs.orglett.5b03589-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [364.7, 138.0, 202.4, 113.8], "category_id": 1}, {"id": 1, "bbox": [368.26, 249.75, 256.1, 47.72], "category_id": 2}, {"id": 2, "bbox": [55.0, 56.0, 241.0, 127.0], "category_id": 1}, {"id": 3, "bbox": [632.0, 34.0, 275.0, 150.0], "category_id": 1}, {"id": 4, "bbox": [14.0, 408.2, 942.0, 687.8], "category_id": 4}, {"id": 5, "bbox": [78.0, 191.0, 214.0, 55.0], "category_id": 3}, {"id": 6, "bbox": [707.0, 199.0, 40.0, 36.0], "category_id": 3}, {"id": 7, "bbox": [323.0, 297.0, 358.0, 80.0], "category_id": 2}, {"id": 8, "bbox": [325.0, 0.0, 271.0, 115.0], "category_id": 2}, {"id": 9, "bbox": [320.85, 174.82, 44.08, 48.48], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [8, 9, 0, 1, 7], "products": [3]}], "corefs": [[2, 5], [3, 6]], "caption": "Table 4. Scope of the Tandem Coupling/Cyclization Reaction with Functionalized 2-Pyridylhydrazines ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 572, 417, 602], "ImageBB": [131, 609, 370, 883]}, "diagram_type": "single"}, {"id": 1298, "width": 1352, "height": 864, "file_name": "op2003216-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 85.88, 201.55, 284.69], "category_id": 1}, {"id": 1, "bbox": [536.34, 443.6, 246.86, 100.09], "category_id": 2}, {"id": 2, "bbox": [524.16, 83.85, 273.24, 334.73], "category_id": 1}, {"id": 3, "bbox": [1011.13, 449.01, 206.28, 235.33], "category_id": 1}, {"id": 4, "bbox": [964.46, 366.51, 48.69, 48.69], "category_id": 3}, {"id": 5, "bbox": [79.81, 371.92, 44.64, 48.69], "category_id": 3}, {"id": 6, "bbox": [1220.11, 365.16, 47.35, 50.04], "category_id": 3}, {"id": 7, "bbox": [1143.01, 83.85, 208.99, 275.23], "category_id": 1}, {"id": 8, "bbox": [836.63, 154.86, 43.96, 48.68], "category_id": 2}, {"id": 9, "bbox": [254.98, 646.47, 115.65, 104.82], "category_id": 1}, {"id": 10, "bbox": [0.0, 577.5, 202.23, 241.41], "category_id": 1}, {"id": 11, "bbox": [888.71, 85.88, 237.39, 269.14], "category_id": 1}, {"id": 12, "bbox": [222.52, 4.06, 234.01, 132.54], "category_id": 1}, {"id": 13, "bbox": [984.07, 693.81, 260.39, 52.07], "category_id": 2}, {"id": 14, "bbox": [219.81, 137.27, 261.07, 56.13], "category_id": 2}], "caption": "Scheme 3. Postulated reaction mechanism for the bromoacetylation of 2 ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 363, 125], "ImageBB": [82, 131, 420, 347]}, "reactions": [{"reactants": [0, 12], "conditions": [14], "products": [2]}, {"reactants": [2], "conditions": [8], "products": [11, 7]}], "diagram_type": "tree"}, {"id": 1173, "width": 1356, "height": 1136, "file_name": "ol202027k-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1071.78, 305.86, 130.24, 56.29], "category_id": 2}, {"id": 1, "bbox": [502.65, 539.15, 270.66, 141.06], "category_id": 1}, {"id": 2, "bbox": [972.74, 879.59, 383.26, 215.66], "category_id": 1}, {"id": 3, "bbox": [326.28, 176.33, 266.59, 330.95], "category_id": 1}, {"id": 4, "bbox": [866.24, 427.25, 58.34, 54.93], "category_id": 3}, {"id": 5, "bbox": [830.29, 260.42, 250.98, 143.09], "category_id": 1}, {"id": 6, "bbox": [609.83, 16.95, 115.31, 60.36], "category_id": 2}, {"id": 7, "bbox": [349.34, 547.97, 117.36, 208.87], "category_id": 1}, {"id": 8, "bbox": [1136.9, 707.34, 58.33, 61.71], "category_id": 3}, {"id": 9, "bbox": [797.73, 0.0, 126.85, 208.88], "category_id": 1}, {"id": 10, "bbox": [681.05, 927.74, 143.13, 65.11], "category_id": 2}, {"id": 11, "bbox": [996.48, 45.44, 119.39, 58.32], "category_id": 2}, {"id": 12, "bbox": [253.02, 897.23, 125.49, 53.57], "category_id": 2}, {"id": 13, "bbox": [400.22, 875.53, 294.4, 215.66], "category_id": 1}, {"id": 14, "bbox": [1235.8, 766.4, 113.19, 58.64], "category_id": 2}, {"id": 15, "bbox": [0.0, 918.93, 61.73, 63.75], "category_id": 3}, {"id": 16, "bbox": [126.85, 925.71, 117.35, 57.65], "category_id": 2}, {"id": 17, "bbox": [553.52, 704.63, 63.77, 57.64], "category_id": 3}, {"id": 18, "bbox": [439.56, 6.1, 121.43, 145.81], "category_id": 1}, {"id": 19, "bbox": [972.06, 566.28, 383.94, 209.92], "category_id": 1}], "caption": "Scheme 2. Plausible Reaction Mechanism for the Copper-Cat- alyzed Soft Enolization Perkin Acyl-Mannich Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 402, 116], "ImageBB": [71, 127, 410, 411]}, "reactions": [{"reactants": [18], "conditions": [6], "products": [9, 11]}, {"reactants": [3], "conditions": [], "products": [5, 0]}, {"reactants": [5, 0], "conditions": [], "products": [3]}, {"reactants": [7, 1], "conditions": [], "products": [19]}, {"reactants": [19, 14], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [19, 14]}, {"reactants": [2], "conditions": [], "products": [13, 10]}, {"reactants": [13, 10], "conditions": [], "products": [2]}, {"reactants": [13], "conditions": [12], "products": [15, 16]}], "diagram_type": "tree"}, {"id": 764, "width": 1156, "height": 1316, "file_name": "jo961365y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [711.0, 1253.0, 66.0, 57.0], "category_id": 3}, {"id": 1, "bbox": [355.0, 190.0, 205.0, 92.0], "category_id": 1}, {"id": 2, "bbox": [155.0, 1264.0, 68.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [692.0, 727.0, 116.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [170.0, 726.0, 116.0, 57.0], "category_id": 3}, {"id": 5, "bbox": [461.0, 287.0, 26.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [721.0, 922.0, 251.0, 58.0], "category_id": 2}, {"id": 7, "bbox": [726.0, 868.0, 229.0, 57.0], "category_id": 2}, {"id": 8, "bbox": [10.0, 922.0, 238.0, 56.0], "category_id": 2}, {"id": 9, "bbox": [7.0, 867.0, 227.0, 54.0], "category_id": 2}, {"id": 10, "bbox": [0.0, 434.0, 241.0, 63.0], "category_id": 2}, {"id": 11, "bbox": [683.0, 432.0, 300.0, 69.0], "category_id": 2}, {"id": 12, "bbox": [356.0, 357.0, 258.0, 59.0], "category_id": 2}, {"id": 13, "bbox": [590.0, 539.0, 305.0, 183.0], "category_id": 1}, {"id": 14, "bbox": [42.6, 1076.0, 377.4, 186.0], "category_id": 1}, {"id": 15, "bbox": [86.3, 554.9, 305.7, 165.1], "category_id": 1}, {"id": 16, "bbox": [549.0, 1079.0, 395.0, 183.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [12, 10], "products": [15]}, {"reactants": [1], "conditions": [12, 11], "products": [13]}, {"reactants": [15], "conditions": [9, 8], "products": [14]}, {"reactants": [13], "conditions": [7, 6], "products": [16]}], "corefs": [[1, 5], [15, 4], [13, 3], [14, 2], [16, 0]], "caption": "Table 1. Comparison of the % of Enantiomeric Excess of    (R)- and (S)-6 in Asymmetric Dihydroxylation of 5 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 361, 772, 386], "ImageBB": [486, 20, 775, 349]}, "diagram_type": "tree"}, {"id": 203, "width": 1316, "height": 1416, "file_name": "op034198u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [706.5, 83.0, 593.0, 360.0], "category_id": 1}, {"id": 1, "bbox": [32.2, 1056.0, 590.6, 350.0], "category_id": 1}, {"id": 2, "bbox": [1119.0, 705.0, 192.0, 61.6], "category_id": 2}, {"id": 3, "bbox": [56.0, 651.0, 375.0, 119.0], "category_id": 2}, {"id": 4, "bbox": [744.0, 941.0, 59.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [17.0, 79.0, 363.0, 361.0], "category_id": 1}, {"id": 6, "bbox": [963.0, 400.0, 38.0, 57.0], "category_id": 3}, {"id": 7, "bbox": [191.0, 402.0, 42.0, 54.0], "category_id": 3}, {"id": 8, "bbox": [467.0, 472.0, 614.0, 468.0], "category_id": 1}, {"id": 9, "bbox": [494.0, 300.0, 113.0, 70.0], "category_id": 2}, {"id": 10, "bbox": [398.0, 159.0, 280.0, 113.0], "category_id": 2}, {"id": 11, "bbox": [282.0, 1370.0, 46.0, 44.0], "category_id": 3}, {"id": 12, "bbox": [1168.0, 806.0, 99.0, 54.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [10, 9], "products": [0]}, {"reactants": [0], "conditions": [3], "products": [8]}, {"reactants": [8], "conditions": [2, 12], "products": [1]}], "corefs": [[5, 7], [0, 6], [8, 4], [1, 11]], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 128, 129, 142], "ImageBB": [74, 152, 403, 506]}, "diagram_type": "multiple"}, {"id": 814, "width": 1352, "height": 416, "file_name": "jo401608v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [85.0, 225.0, 60.0, 49.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 26.0, 272.0, 203.0], "category_id": 1}, {"id": 2, "bbox": [317.0, 106.0, 266.0, 66.0], "category_id": 1}, {"id": 3, "bbox": [1047.0, 1.0, 305.0, 274.0], "category_id": 1}, {"id": 4, "bbox": [591.0, 75.0, 452.0, 50.7], "category_id": 2}, {"id": 5, "bbox": [1108.0, 225.0, 56.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [16.0, 308.0, 1315.0, 108.0], "category_id": 4}, {"id": 7, "bbox": [432.0, 224.0, 49.0, 55.0], "category_id": 3}, {"id": 8, "bbox": [648.47, 144.78, 339.53, 99.93], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [4, 8], "products": [3]}], "corefs": [[1, 0], [2, 7], [3, 5]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 268, 110], "ImageBB": [82, 116, 420, 220]}, "diagram_type": "single"}, {"id": 750, "width": 1344, "height": 712, "file_name": "jo990938e-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [520.97, 49.86, 34.46, 40.54], "category_id": 3}, {"id": 1, "bbox": [665.0, 187.0, 92.0, 33.0], "category_id": 3}, {"id": 2, "bbox": [1011.0, 189.0, 93.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [5.0, 268.0, 1339.0, 444.0], "category_id": 4}, {"id": 4, "bbox": [148.0, 18.0, 248.0, 161.0], "category_id": 1}, {"id": 5, "bbox": [445.0, 5.0, 120.0, 113.0], "category_id": 1}, {"id": 6, "bbox": [601.0, 22.0, 249.0, 161.0], "category_id": 1}, {"id": 7, "bbox": [940.0, 21.0, 251.0, 161.0], "category_id": 1}, {"id": 8, "bbox": [238.0, 190.0, 27.0, 34.0], "category_id": 3}, {"id": 9, "bbox": [420.0, 62.0, 41.0, 32.0], "category_id": 2}, {"id": 10, "bbox": [387.0, 135.0, 199.0, 84.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [9, 5, 10], "products": [6, 7]}], "corefs": [[4, 8], [5, 0], [6, 1], [7, 2]], "caption": "Table 6. Additions of Transient Chiral Allenylindium  Reagents from Mesylate 7 to Representative Achiral                      Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [83, 64, 398, 101], "ImageBB": [74, 110, 410, 288]}, "diagram_type": "single"}, {"id": 532, "width": 1344, "height": 1988, "file_name": "jo000745n-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [662.0, 23.0, 408.0, 204.0], "category_id": 1}, {"id": 1, "bbox": [808.0, 232.0, 110.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [19.0, 293.0, 1325.0, 1695.0], "category_id": 4}, {"id": 3, "bbox": [409.0, 29.0, 172.0, 60.0], "category_id": 2}, {"id": 4, "bbox": [235.0, 84.0, 126.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [3], "products": [0]}], "corefs": [[0, 1]], "caption": "Table 3. Preparation of Protected Thioureas 28-41 by            Protection of Thioureas 17-27 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [81, 64, 402, 89], "ImageBB": [74, 90, 410, 587]}, "diagram_type": "single"}, {"id": 616, "width": 1352, "height": 744, "file_name": "acs.oprd.5b00278-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [721.04, 39.26, 70.95, 58.49], "category_id": 2}, {"id": 1, "bbox": [545.0, 40.0, 114.9, 58.0], "category_id": 2}, {"id": 2, "bbox": [450.0, 689.0, 179.0, 51.0], "category_id": 2}, {"id": 3, "bbox": [608.0, 600.0, 131.0, 58.0], "category_id": 2}, {"id": 4, "bbox": [620.0, 130.0, 115.0, 56.0], "category_id": 2}, {"id": 5, "bbox": [9.0, 281.0, 286.0, 237.0], "category_id": 1}, {"id": 6, "bbox": [877.0, 268.0, 128.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [312.0, 258.0, 200.0, 100.0], "category_id": 2}, {"id": 8, "bbox": [337.0, 382.0, 154.0, 84.0], "category_id": 2}, {"id": 9, "bbox": [1044.0, 274.0, 294.0, 244.0], "category_id": 1}, {"id": 10, "bbox": [520.0, 277.0, 291.0, 246.0], "category_id": 1}, {"id": 11, "bbox": [734.0, 691.0, 126.0, 47.0], "category_id": 2}, {"id": 12, "bbox": [843.0, 317.0, 190.0, 46.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [7], "products": [10]}, {"reactants": [10], "conditions": [8], "products": [5]}, {"reactants": [10], "conditions": [6, 12], "products": [9]}, {"reactants": [9, 0], "conditions": [4], "products": [5, 1]}, {"reactants": [5, 2], "conditions": [3], "products": [9, 11]}], "corefs": [], "caption": "Figure 2. Catalytic cycle of GOase including the reduction to the semioxidized inactive form. The active site is simpli\ufb01ed to only shown the copper-Tyr272 coordination. Adapted with permission from ref 8. Copyright 2003 American Chemical Society. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 785, 417, 840], "ImageBB": [82, 589, 420, 775]}, "diagram_type": "graph"}, {"id": 1227, "width": 1152, "height": 864, "file_name": "op010073i-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [684.05, 12.68, 156.75, 162.47], "category_id": 1}, {"id": 1, "bbox": [31.12, 629.15, 305.43, 165.93], "category_id": 1}, {"id": 2, "bbox": [96.82, 171.69, 40.91, 42.64], "category_id": 3}, {"id": 3, "bbox": [432.79, 640.1, 291.03, 62.22], "category_id": 2}, {"id": 4, "bbox": [306.01, 520.83, 42.07, 45.52], "category_id": 3}, {"id": 5, "bbox": [199.4, 372.19, 282.95, 131.36], "category_id": 1}, {"id": 6, "bbox": [560.15, 303.63, 406.86, 131.93], "category_id": 2}, {"id": 7, "bbox": [908.23, 137.12, 217.26, 53.01], "category_id": 2}, {"id": 8, "bbox": [147.53, 816.4, 42.65, 46.09], "category_id": 3}, {"id": 9, "bbox": [723.82, 195.89, 38.03, 42.63], "category_id": 3}, {"id": 10, "bbox": [945.69, 815.82, 38.03, 44.94], "category_id": 3}, {"id": 11, "bbox": [0.0, 17.86, 264.52, 131.94], "category_id": 1}, {"id": 12, "bbox": [303.7, 0.0, 312.35, 85.27], "category_id": 2}, {"id": 13, "bbox": [807.38, 614.75, 306.01, 169.38], "category_id": 1}, {"id": 14, "bbox": [907.08, 52.43, 218.41, 51.85], "category_id": 2}, {"id": 15, "bbox": [466.79, 750.14, 220.15, 57.61], "category_id": 2}], "caption": "Scheme 1. Literature synthesis of 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 417, 644, 431], "ImageBB": [464, 438, 752, 654]}, "reactions": [{"reactants": [11], "conditions": [12], "products": [0]}, {"reactants": [0], "conditions": [14, 7], "products": [5]}, {"reactants": [5], "conditions": [6], "products": [1]}, {"reactants": [1], "conditions": [3, 15], "products": [13]}], "diagram_type": "multiple"}, {"id": 298, "width": 1344, "height": 788, "file_name": "ol400025a-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [734.0, 514.1, 486.0, 238.9], "category_id": 1}, {"id": 1, "bbox": [126.1, 509.1, 248.9, 205.9], "category_id": 1}, {"id": 2, "bbox": [485.0, 166.1, 332.0, 241.9], "category_id": 1}, {"id": 3, "bbox": [123.0, 166.0, 339.9, 236.8], "category_id": 1}, {"id": 4, "bbox": [863.0, 206.1, 237.0, 153.8], "category_id": 1}, {"id": 5, "bbox": [421.0, 508.0, 296.0, 218.0], "category_id": 1}, {"id": 6, "bbox": [964.0, 752.0, 24.0, 27.0], "category_id": 3}, {"id": 7, "bbox": [556.0, 746.0, 35.0, 30.0], "category_id": 3}, {"id": 8, "bbox": [176.6, 415.97, 258.4, 60.5], "category_id": 3}, {"id": 9, "bbox": [515.4, 417.0, 261.6, 59.5], "category_id": 3}, {"id": 10, "bbox": [128.2, 723.0, 280.8, 58.5], "category_id": 3}, {"id": 11, "bbox": [861.4, 411.0, 252.6, 60.5], "category_id": 3}], "reactions": [], "corefs": [[3, 8], [2, 9], [4, 11], [1, 10], [5, 7], [0, 6]], "caption": "Figure 1. Squaramide catalysts.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 269, 604, 282], "ImageBB": [437, 59, 773, 256]}, "diagram_type": "multiple"}, {"id": 655, "width": 1348, "height": 328, "file_name": "ol403122a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [9.0, 251.0, 1318.0, 77.0], "category_id": 4}, {"id": 1, "bbox": [251.39, 143.36, 206.59, 49.07], "category_id": 2}, {"id": 2, "bbox": [287.1, 84.7, 139.8, 43.6], "category_id": 2}, {"id": 3, "bbox": [503.2, 75.4, 249.3, 121.5], "category_id": 1}, {"id": 4, "bbox": [788.6, 7.2, 216.1, 120.8], "category_id": 1}, {"id": 5, "bbox": [1001.9, 60.6, 292.1, 133.1], "category_id": 1}, {"id": 6, "bbox": [794.0, 139.0, 187.0, 76.4], "category_id": 2}, {"id": 7, "bbox": [53.0, 98.0, 158.0, 62.7], "category_id": 2}, {"id": 8, "bbox": [1121.53, 184.28, 54.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2, 1], "products": [3]}, {"reactants": [3], "conditions": [4, 6], "products": [5]}], "corefs": [[5, 8]], "caption": "Table 1. Initial Screening and Optimization of Conditions for S-Alkylation of DABSO-Generated Magnesium Sul\ufb01natesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 411, 140], "ImageBB": [82, 146, 419, 228]}, "diagram_type": "single"}, {"id": 1286, "width": 1412, "height": 956, "file_name": "op200086t-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [96.06, 808.34, 99.6, 59.3], "category_id": 3}, {"id": 1, "bbox": [1106.15, 195.55, 233.8, 61.42], "category_id": 3}, {"id": 2, "bbox": [16.95, 8.47, 261.35, 166.61], "category_id": 1}, {"id": 3, "bbox": [1123.81, 9.18, 215.44, 169.43], "category_id": 1}, {"id": 4, "bbox": [577.8, 808.34, 223.2, 89.66], "category_id": 3}, {"id": 5, "bbox": [562.26, 617.02, 268.41, 171.55], "category_id": 1}, {"id": 6, "bbox": [578.5, 0.0, 244.4, 170.14], "category_id": 1}, {"id": 7, "bbox": [0.0, 619.14, 290.31, 171.55], "category_id": 1}, {"id": 8, "bbox": [28.86, 392.55, 235.27, 49.35], "category_id": 3}, {"id": 9, "bbox": [497.1, 301.89, 389.06, 80.31], "category_id": 3}, {"id": 10, "bbox": [497.1, 397.14, 401.68, 80.34], "category_id": 3}, {"id": 11, "bbox": [300.2, 36.1, 204.84, 39.7], "category_id": 2}, {"id": 12, "bbox": [497.4, 202.6, 366.6, 81.7], "category_id": 3}, {"id": 13, "bbox": [29.9, 290.9, 229.2, 53.7], "category_id": 3}, {"id": 14, "bbox": [1109.68, 292.27, 245.81, 60.01], "category_id": 3}, {"id": 15, "bbox": [1111.9, 385.9, 244.0, 58.1], "category_id": 3}, {"id": 16, "bbox": [29.6, 195.55, 224.69, 60.01], "category_id": 3}, {"id": 17, "bbox": [868.11, 38.4, 208.37, 35.1], "category_id": 2}, {"id": 18, "bbox": [309.4, 645.5, 204.12, 45.2], "category_id": 2}], "caption": "Scheme 1. Substrates and products of bioreductions", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 572, 362, 587], "ImageBB": [71, 597, 424, 836]}, "reactions": [{"reactants": [2], "conditions": [11], "products": [6]}, {"reactants": [3], "conditions": [17], "products": [6]}, {"reactants": [7], "conditions": [18], "products": [5]}], "diagram_type": "multiple"}, {"id": 2, "width": 1356, "height": 688, "file_name": "jacs.5b12989-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.65, 262.6, 1338.95, 417.44], "category_id": 4}, {"id": 1, "bbox": [965.41, 10.46, 176.88, 169.79], "category_id": 1}, {"id": 2, "bbox": [624.51, 10.46, 176.0, 169.79], "category_id": 1}, {"id": 3, "bbox": [209.94, 14.9, 176.88, 165.3], "category_id": 1}, {"id": 4, "bbox": [399.03, 42.42, 119.18, 58.82], "category_id": 2}, {"id": 5, "bbox": [399.03, 122.3, 172.44, 62.38], "category_id": 2}, {"id": 6, "bbox": [815.38, 103.68, 134.27, 33.07], "category_id": 2}, {"id": 7, "bbox": [288.95, 206.65, 23.3, 29.52], "category_id": 3}, {"id": 8, "bbox": [707.96, 206.65, 25.97, 29.52], "category_id": 3}, {"id": 9, "bbox": [1051.52, 206.65, 49.94, 29.52], "category_id": 3}, {"id": 10, "bbox": [815.38, 35.32, 100.54, 59.7], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4, 5], "products": [2]}, {"reactants": [2], "conditions": [10, 6], "products": [1]}], "corefs": [[3, 7], [2, 8], [1, 9]], "caption": "Table 3. Mechanistic Insight from O-Alkyl Group Variance of the Oxyboration Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 784, 125], "ImageBB": [448, 131, 787, 303]}, "diagram_type": "single"}, {"id": 667, "width": 1276, "height": 2064, "file_name": "ol401909z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [58.0, 8.0, 254.4, 244.7], "category_id": 1}, {"id": 1, "bbox": [370.3, 70.0, 153.7, 116.1], "category_id": 1}, {"id": 2, "bbox": [7.0, 266.6, 1269.0, 1797.4], "category_id": 4}, {"id": 3, "bbox": [828.6, 2.7, 383.1, 249.3], "category_id": 1}, {"id": 4, "bbox": [410.0, 189.0, 41.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [534.0, 136.0, 274.0, 53.0], "category_id": 2}, {"id": 6, "bbox": [574.0, 78.0, 175.0, 58.0], "category_id": 2}, {"id": 7, "bbox": [1064.0, 194.0, 53.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [0, 1], "conditions": [6, 5], "products": [3]}], "corefs": [[1, 4], [3, 7]], "caption": "Table 3. Cu-Catalyzed Synthesis of Fullerooxazole from C60 and Amidea ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 303, 758, 330], "ImageBB": [445, 341, 764, 857]}, "diagram_type": "single"}, {"id": 383, "width": 1352, "height": 1680, "file_name": "op500224x-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1011.0, 698.0, 171.0, 91.0], "category_id": 3}, {"id": 1, "bbox": [123.0, 1165.0, 197.0, 99.0], "category_id": 3}, {"id": 2, "bbox": [548.0, 1170.0, 174.0, 90.0], "category_id": 3}, {"id": 3, "bbox": [234.0, 1591.0, 174.0, 89.0], "category_id": 3}, {"id": 4, "bbox": [972.0, 1173.0, 168.0, 86.0], "category_id": 3}, {"id": 5, "bbox": [543.0, 704.0, 191.0, 81.0], "category_id": 3}, {"id": 6, "bbox": [869.0, 1593.0, 175.0, 87.0], "category_id": 3}, {"id": 7, "bbox": [140.0, 703.0, 167.0, 82.0], "category_id": 3}, {"id": 8, "bbox": [895.0, 105.0, 83.0, 38.0], "category_id": 2}, {"id": 9, "bbox": [642.0, 306.0, 91.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [1166.0, 302.0, 80.0, 64.0], "category_id": 3}, {"id": 11, "bbox": [109.0, 306.0, 60.0, 60.0], "category_id": 3}, {"id": 12, "bbox": [9.0, 1277.0, 613.0, 302.0], "category_id": 1}, {"id": 13, "bbox": [661.0, 1275.0, 649.0, 302.0], "category_id": 1}, {"id": 14, "bbox": [1050.0, 7.0, 302.0, 295.0], "category_id": 1}, {"id": 15, "bbox": [5.0, 860.0, 463.0, 292.0], "category_id": 1}, {"id": 16, "bbox": [402.0, 848.0, 454.0, 313.0], "category_id": 1}, {"id": 17, "bbox": [459.0, 386.0, 369.0, 318.0], "category_id": 1}, {"id": 18, "bbox": [264.0, 93.0, 222.0, 58.0], "category_id": 2}, {"id": 19, "bbox": [864.0, 390.0, 473.0, 302.0], "category_id": 1}, {"id": 20, "bbox": [817.0, 801.0, 528.0, 398.0], "category_id": 1}, {"id": 21, "bbox": [537.0, 3.0, 306.0, 302.0], "category_id": 1}, {"id": 22, "bbox": [0.0, 6.0, 269.0, 295.0], "category_id": 1}, {"id": 23, "bbox": [828.0, 176.0, 219.0, 45.0], "category_id": 2}, {"id": 24, "bbox": [324.0, 175.0, 103.0, 94.0], "category_id": 2}, {"id": 25, "bbox": [34.0, 382.0, 405.0, 318.0], "category_id": 1}], "reactions": [{"reactants": [22], "conditions": [18, 24], "products": [21]}, {"reactants": [21], "conditions": [8, 23], "products": [14]}], "corefs": [[22, 11], [21, 9], [14, 10], [25, 7], [17, 5], [19, 0], [15, 1], [16, 2], [20, 4], [12, 3], [13, 6]], "caption": "Table 7. Thermodynamic protonation with carbon nucleophile addition products ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 734, 125], "ImageBB": [448, 131, 786, 551]}, "diagram_type": "single"}, {"id": 732, "width": 1348, "height": 800, "file_name": "ol016212y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [916.9, 2.1, 313.0, 241.7], "category_id": 1}, {"id": 1, "bbox": [13.0, 342.0, 1323.0, 458.0], "category_id": 4}, {"id": 2, "bbox": [516.0, 174.0, 239.9, 49.6], "category_id": 2}, {"id": 3, "bbox": [96.4, 7.3, 265.2, 236.5], "category_id": 1}, {"id": 4, "bbox": [428.0, 101.0, 428.0, 54.0], "category_id": 2}, {"id": 5, "bbox": [107.0, 261.0, 333.0, 56.0], "category_id": 2}, {"id": 6, "bbox": [924.0, 260.0, 339.0, 53.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4, 2], "products": [0]}], "corefs": [], "caption": "Table 2. Comparison of the Fiber-Supported Amino Alcohol P3 with 3 and 5 as Catalysts in the Addition of Et2Zn to PhCHO ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 276, 761, 320], "ImageBB": [439, 322, 776, 522]}, "diagram_type": "single"}, {"id": 1248, "width": 1064, "height": 568, "file_name": "op0340661-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [51.63, 470.26, 112.84, 44.15], "category_id": 2}, {"id": 1, "bbox": [661.07, 5.32, 240.06, 40.96], "category_id": 2}, {"id": 2, "bbox": [545.04, 195.23, 121.89, 41.5], "category_id": 2}, {"id": 3, "bbox": [220.89, 514.41, 36.73, 44.16], "category_id": 3}, {"id": 4, "bbox": [339.59, 155.33, 133.59, 48.95], "category_id": 2}, {"id": 5, "bbox": [446.04, 258.0, 116.03, 46.29], "category_id": 2}, {"id": 6, "bbox": [463.6, 48.41, 121.36, 47.34], "category_id": 2}, {"id": 7, "bbox": [714.83, 260.66, 316.17, 43.63], "category_id": 2}, {"id": 8, "bbox": [37.26, 244.17, 30.87, 40.96], "category_id": 3}, {"id": 9, "bbox": [661.07, 317.59, 217.17, 45.21], "category_id": 2}, {"id": 10, "bbox": [51.63, 397.91, 150.1, 47.35], "category_id": 2}, {"id": 11, "bbox": [6.92, 110.12, 297.0, 153.2], "category_id": 1}, {"id": 12, "bbox": [204.39, 335.67, 324.15, 226.62], "category_id": 1}, {"id": 13, "bbox": [690.35, 114.37, 370.46, 150.02], "category_id": 1}], "caption": "Scheme 7. pH dependence of ureide formation", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 664, 339, 678], "ImageBB": [109, 686, 375, 828]}, "reactions": [{"reactants": [11, 4], "conditions": [2], "products": [13]}, {"reactants": [13], "conditions": [10, 0], "products": [12]}], "diagram_type": "tree"}, {"id": 617, "width": 1356, "height": 432, "file_name": "acs.oprd.5b00251-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1156.0, 102.0, 86.0, 56.0], "category_id": 2}, {"id": 1, "bbox": [493.0, 60.0, 353.0, 53.0], "category_id": 2}, {"id": 2, "bbox": [113.0, 104.0, 100.0, 56.0], "category_id": 2}, {"id": 3, "bbox": [295.5, 51.91, 162.6, 125.78], "category_id": 1}, {"id": 4, "bbox": [875.0, 40.0, 214.0, 133.8], "category_id": 1}, {"id": 5, "bbox": [185.3, 229.0, 98.6, 177.9], "category_id": 1}, {"id": 6, "bbox": [1014.0, 234.1, 170.0, 149.9], "category_id": 1}, {"id": 7, "bbox": [805.1, 219.0, 133.9, 213.0], "category_id": 1}, {"id": 8, "bbox": [362.0, 236.5, 210.9, 131.1], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [1], "products": [4, 0]}, {"reactants": [5, 8], "conditions": [], "products": [7, 6]}], "corefs": [], "caption": "Figure 2. Reaction scheme for in situ epoxidation with peracetic acid.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 946, 784, 960], "ImageBB": [448, 829, 787, 937]}, "diagram_type": "multiple"}, {"id": 969, "width": 1904, "height": 1748, "file_name": "ja029499i-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1096.3, 1263.71, 62.86, 84.76], "category_id": 2}, {"id": 1, "bbox": [1026.77, 5.71, 279.07, 233.32], "category_id": 1}, {"id": 2, "bbox": [1249.65, 1132.29, 252.41, 63.81], "category_id": 2}, {"id": 3, "bbox": [1522.88, 522.55, 146.89, 58.76], "category_id": 2}, {"id": 4, "bbox": [1045.82, 554.24, 274.31, 120.95], "category_id": 1}, {"id": 5, "bbox": [1533.37, 1561.28, 107.02, 52.46], "category_id": 2}, {"id": 6, "bbox": [0.0, 1276.09, 284.79, 286.65], "category_id": 1}, {"id": 7, "bbox": [1621.11, 1289.42, 271.46, 218.08], "category_id": 1}, {"id": 8, "bbox": [454.33, 647.57, 278.12, 281.88], "category_id": 1}, {"id": 9, "bbox": [486.72, 999.92, 94.29, 60.0], "category_id": 2}, {"id": 10, "bbox": [1358.23, 1021.83, 96.2, 63.8], "category_id": 2}, {"id": 11, "bbox": [1250.6, 925.64, 289.55, 63.81], "category_id": 2}, {"id": 12, "bbox": [1621.11, 697.09, 282.89, 235.22], "category_id": 1}, {"id": 13, "bbox": [1235.36, 361.88, 86.68, 52.37], "category_id": 2}, {"id": 14, "bbox": [806.75, 392.35, 160.01, 99.99], "category_id": 2}, {"id": 15, "bbox": [928.66, 1034.21, 219.07, 63.8], "category_id": 2}, {"id": 16, "bbox": [1249.65, 787.56, 62.86, 50.47], "category_id": 2}, {"id": 17, "bbox": [1045.82, 1501.79, 280.98, 243.79], "category_id": 1}, {"id": 18, "bbox": [456.24, 1122.77, 282.88, 285.69], "category_id": 1}, {"id": 19, "bbox": [365.75, 1382.75, 120.01, 57.14], "category_id": 2}, {"id": 20, "bbox": [1248.1, 1382.4, 139.4, 62.4], "category_id": 2}], "caption": "Scheme 1. Proposed Reaction Topology for the Simultaneous Interconnected Unicyclic Rh and Bimetallic Rh-Mn CBER Hydroformylation Reactions ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 764, 88], "ImageBB": [187, 88, 663, 525]}, "reactions": [{"reactants": [1], "conditions": [13], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [8], "conditions": [], "products": [14, 4]}, {"reactants": [4, 3], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [4]}, {"reactants": [12], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [12]}, {"reactants": [7], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [7]}, {"reactants": [17], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [17]}, {"reactants": [18], "conditions": [9], "products": [8]}, {"reactants": [8], "conditions": [], 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Synthesis of [\u03ba4-Tptm]ZnF", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 332, 661, 349], "ImageBB": [453, 355, 782, 539]}, "reactions": [{"reactants": [1], "conditions": [3], "products": [6]}, {"reactants": [6], "conditions": [2], "products": [1]}, {"reactants": [4], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [5], "products": [0]}, {"reactants": [0], "conditions": [7], "products": [6]}], "diagram_type": "tree"}, {"id": 761, "width": 1348, "height": 492, "file_name": "jo971595s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [55.0, 266.0, 1231.0, 226.0], "category_id": 4}, {"id": 1, "bbox": [132.0, 180.0, 60.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [669.0, 8.0, 318.0, 145.0], "category_id": 1}, {"id": 3, "bbox": [1028.0, 9.0, 289.0, 153.0], "category_id": 1}, {"id": 4, "bbox": [31.0, 4.0, 333.0, 144.0], "category_id": 1}, {"id": 5, "bbox": [765.0, 183.0, 63.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [1138.0, 187.0, 62.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [457.0, 39.0, 50.0, 38.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [7], "products": [2, 3]}], "corefs": [[4, 1], [2, 5], [3, 6]], "caption": "Table 2. Synperiplanar versus Antiperiplanar Attack in                the Radical Reductiona ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [441, 49, 772, 74], "ImageBB": [438, 79, 775, 202]}, "diagram_type": "single"}, {"id": 1364, "width": 1356, "height": 780, "file_name": "op900265h-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [832.32, 737.13, 145.17, 42.05], "category_id": 3}, {"id": 1, "bbox": [963.92, 2.71, 388.01, 289.57], "category_id": 1}, {"id": 2, "bbox": [0.0, 2.71, 482.3, 291.6], "category_id": 1}, {"id": 3, "bbox": [548.1, 368.91, 771.27, 388.57], "category_id": 1}, {"id": 4, "bbox": [490.44, 2.71, 454.49, 291.6], "category_id": 1}, {"id": 5, "bbox": [668.84, 309.91, 34.6, 35.26], "category_id": 3}, {"id": 6, "bbox": [1145.71, 308.55, 37.31, 38.66], "category_id": 3}, {"id": 7, "bbox": [202.15, 308.55, 32.56, 37.3], "category_id": 3}], "caption": "Scheme 1. Synthetic route to S-0139 4 from oleanolic acid 1", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 315, 759, 329], "ImageBB": [424, 334, 763, 529]}, "reactions": [{"reactants": [2], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}], "diagram_type": "multiple"}, {"id": 435, "width": 1348, "height": 440, "file_name": "op300031r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [423.8, 90.0, 170.2, 51.9], "category_id": 2}, {"id": 1, "bbox": [77.0, 4.0, 274.0, 290.0], "category_id": 1}, {"id": 2, "bbox": [1.0, 365.0, 1347.0, 75.0], "category_id": 4}, {"id": 3, "bbox": [653.0, 8.0, 300.0, 279.0], "category_id": 1}, {"id": 4, "bbox": [666.0, 293.0, 269.0, 48.0], "category_id": 2}, {"id": 5, "bbox": [990.0, 291.0, 268.0, 42.0], "category_id": 2}, {"id": 6, "bbox": [972.0, 9.0, 305.0, 281.0], "category_id": 1}, {"id": 7, "bbox": [394.45, 157.99, 240.93, 51.84], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [0, 7], "products": [3, 6]}], "corefs": [], "caption": "Table 1. Screening of MeMgBr Addition to Cyclobutanone Substrates ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 782, 125], "ImageBB": [449, 131, 786, 241]}, "diagram_type": "single"}, {"id": 966, "width": 968, "height": 1116, "file_name": "ja0176346-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 1113.77, 7.26, 2.23], "category_id": 3}, {"id": 1, "bbox": [24.01, 474.54, 252.39, 178.65], "category_id": 1}, {"id": 2, "bbox": [785.65, 1056.26, 53.6, 44.11], "category_id": 3}, {"id": 3, "bbox": [0.0, 832.39, 284.78, 231.69], "category_id": 1}, {"id": 4, "bbox": [341.17, 2.23, 237.32, 187.58], "category_id": 1}, {"id": 5, "bbox": [454.53, 419.27, 52.48, 40.19], "category_id": 3}, {"id": 6, "bbox": [687.93, 525.34, 245.69, 121.15], "category_id": 1}, {"id": 7, "bbox": [357.37, 473.42, 242.9, 305.38], "category_id": 1}, {"id": 8, "bbox": [773.92, 184.23, 78.74, 44.11], "category_id": 3}, {"id": 9, "bbox": [357.37, 244.53, 242.9, 173.06], "category_id": 1}, {"id": 10, "bbox": [63.66, 85.97, 142.94, 47.46], "category_id": 2}, {"id": 11, "bbox": [118.94, 648.16, 53.6, 37.97], "category_id": 3}, {"id": 12, "bbox": [128.99, 133.43, 50.25, 41.31], "category_id": 3}, {"id": 13, "bbox": [668.83, 242.53, 28.14, 32.15], "category_id": 2}, {"id": 14, "bbox": [0.0, 1113.77, 7.26, 2.23], "category_id": 3}, {"id": 15, "bbox": [441.68, 186.47, 73.15, 41.87], "category_id": 3}, {"id": 16, "bbox": [786.21, 646.49, 35.73, 39.64], "category_id": 3}, {"id": 17, "bbox": [262.44, 60.85, 34.06, 32.94], "category_id": 2}, {"id": 18, "bbox": [339.5, 423.73, 32.94, 42.99], "category_id": 3}, {"id": 19, "bbox": [623.72, 63.64, 34.06, 42.43], "category_id": 2}, {"id": 20, "bbox": [496.96, 899.39, 96.05, 104.95], "category_id": 1}, {"id": 21, "bbox": [686.26, 844.12, 246.8, 152.97], "category_id": 1}, {"id": 22, "bbox": [454.53, 783.82, 46.34, 35.73], "category_id": 3}, {"id": 23, "bbox": [0.0, 1113.77, 968.0, 2.23], "category_id": 2}, {"id": 24, "bbox": [127.87, 1069.1, 54.16, 43.55], "category_id": 3}, {"id": 25, "bbox": [579.05, 434.9, 30.71, 34.61], "category_id": 3}, {"id": 26, "bbox": [668.95, 0.0, 242.34, 184.23], "category_id": 1}, {"id": 27, "bbox": [357.37, 894.36, 117.82, 172.51], "category_id": 1}], "caption": "Scheme 3 a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 338, 132, 351], "ImageBB": [122, 351, 364, 630]}, "reactions": [{"reactants": [10], "conditions": [17], "products": [4]}, {"reactants": [4], "conditions": [19], "products": [26]}, {"reactants": [26], "conditions": [13], "products": [9]}, {"reactants": [9], "conditions": [18], "products": [1, 7]}, {"reactants": [9], "conditions": [25], "products": [6]}, {"reactants": [3], "conditions": [], "products": [1]}, {"reactants": [27], "conditions": [], "products": [3]}, {"reactants": [20], "conditions": [], "products": [21]}], "diagram_type": "graph"}, {"id": 907, "width": 1352, "height": 420, "file_name": "acs.joc.5b00685-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [993.3, 239.0, 229.7, 33.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 0.0, 437.7, 218.0], "category_id": 1}, {"id": 2, "bbox": [39.8, 239.0, 358.2, 34.2], "category_id": 3}, {"id": 3, "bbox": [478.0, 129.0, 139.0, 42.0], "category_id": 2}, {"id": 4, "bbox": [479.0, 84.0, 95.0, 33.0], "category_id": 2}, {"id": 5, "bbox": [467.0, 17.0, 128.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [860.0, 2.0, 492.0, 243.0], "category_id": 1}, {"id": 7, "bbox": [606.0, 1.0, 215.0, 86.5], "category_id": 1}, {"id": 8, "bbox": [9.0, 301.0, 1343.0, 118.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [5, 7, 4, 3], "products": [6]}], "corefs": [[1, 2], [6, 0]], "caption": "Table 2. Optimization of the Rapid Conversion of Thiamine to Fursultiamine by Disul\ufb01de Formation ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 416, 784, 446], "ImageBB": [448, 453, 786, 558]}, "diagram_type": "single"}, {"id": 329, "width": 1344, "height": 696, "file_name": "ol300842d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [107.0, 39.2, 430.2, 201.0], "category_id": 1}, {"id": 1, "bbox": [579.0, 66.5, 263.0, 43.2], "category_id": 2}, {"id": 2, "bbox": [616.0, 175.0, 210.0, 50.0], "category_id": 2}, {"id": 3, "bbox": [213.0, 228.0, 54.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [1014.0, 228.0, 52.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [671.0, 123.0, 93.0, 45.0], "category_id": 2}, {"id": 6, "bbox": [6.0, 287.0, 1338.0, 409.0], "category_id": 4}, {"id": 7, "bbox": [911.0, 3.0, 334.0, 237.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 5, 2], "products": [7]}], "corefs": [[0, 3], [7, 4]], "caption": "Table 1. Optimization of Reaction Condition", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 312, 100], "ImageBB": [71, 112, 407, 286]}, "diagram_type": "single"}, {"id": 44, "width": 1320, "height": 696, "file_name": "ja410533y-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [669.97, 22.52, 289.73, 80.68], "category_id": 2}, {"id": 1, "bbox": [1094.04, 3.6, 190.15, 172.23], "category_id": 1}, {"id": 2, "bbox": [372.33, 51.38, 196.11, 136.39], "category_id": 1}, {"id": 3, "bbox": [90.61, 45.41, 138.38, 130.42], "category_id": 1}, {"id": 4, "bbox": [396.22, 256.45, 165.25, 37.84], "category_id": 2}, {"id": 5, "bbox": [462.91, 212.65, 32.86, 32.86], "category_id": 3}, {"id": 6, "bbox": [1104.0, 212.65, 176.21, 39.83], "category_id": 3}, {"id": 7, "bbox": [78.66, 212.65, 178.2, 39.83], "category_id": 3}, {"id": 8, "bbox": [83.64, 255.46, 168.24, 38.83], "category_id": 2}, {"id": 9, "bbox": [8.98, 303.24, 1302.12, 386.25], "category_id": 4}, {"id": 10, "bbox": [642.1, 131.02, 342.45, 121.46], "category_id": 2}], "reactions": [{"reactants": [3, 2], "conditions": [0, 10], "products": [1]}], "corefs": [[3, 7], [2, 5], [1, 6]], "caption": "Table 5. Hydrohydroxyalkylation of Hydroxyl-Substituted Methacrylate 2i with Diols 1b, 1f, 1j, and 1l to Form \u03b1-exo- Methylene-\u03b3-butyrolactones 5b, 5f, 5j, and 5la ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 536, 784, 581], "ImageBB": [452, 588, 782, 762]}, "diagram_type": "single"}, {"id": 565, "width": 1348, "height": 376, "file_name": "acs.orglett.5b01385-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [13.0, 304.0, 1335.0, 66.0], "category_id": 4}, {"id": 1, "bbox": [1063.0, 212.0, 62.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [564.0, 162.0, 307.0, 87.0], "category_id": 2}, {"id": 3, "bbox": [115.0, 219.0, 166.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [343.0, 220.0, 156.0, 56.0], "category_id": 2}, {"id": 5, "bbox": [129.5, 70.3, 135.4, 115.5], "category_id": 1}, {"id": 6, "bbox": [537.2, 2.93, 355.78, 126.0], "category_id": 2}, {"id": 7, "bbox": [369.2, 55.0, 96.7, 158.0], "category_id": 1}, {"id": 8, "bbox": [969.3, 50.1, 254.5, 159.9], "category_id": 1}], "reactions": [{"reactants": [5, 7], "conditions": [6, 2], "products": [8]}], "corefs": [[8, 1]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 738, 110], "ImageBB": [449, 116, 786, 210]}, "diagram_type": "single"}, {"id": 992, "width": 1352, "height": 1116, "file_name": "ja3058138-Scheme-c11.png", "license": 0, "bboxes": [{"id": 0, "bbox": [625.61, 330.82, 229.28, 89.98], "category_id": 2}, {"id": 1, "bbox": [4.73, 1015.56, 755.74, 61.62], "category_id": 2}, {"id": 2, "bbox": [144.74, 939.03, 50.72, 41.94], "category_id": 3}, {"id": 3, "bbox": [1011.13, 564.23, 50.04, 37.88], "category_id": 3}, {"id": 4, "bbox": [735.18, 692.09, 252.95, 95.39], "category_id": 2}, {"id": 5, "bbox": [1100.4, 181.31, 45.99, 35.86], "category_id": 3}, {"id": 6, "bbox": [580.3, 2.71, 300.29, 86.59], "category_id": 2}, {"id": 7, "bbox": [238.75, 31.12, 299.62, 112.98], "category_id": 1}, {"id": 8, "bbox": [1166.01, 932.26, 52.08, 44.65], "category_id": 3}, {"id": 9, "bbox": [96.04, 443.81, 253.63, 132.6], "category_id": 2}, {"id": 10, "bbox": [646.58, 767.86, 50.72, 48.72], "category_id": 3}, {"id": 11, "bbox": [588.41, 113.66, 283.39, 135.98], "category_id": 2}, {"id": 12, "bbox": [497.11, 566.26, 49.37, 35.85], "category_id": 3}, {"id": 13, "bbox": [263.1, 697.51, 334.11, 92.0], "category_id": 2}, {"id": 14, "bbox": [10.15, 650.82, 219.8, 321.36], "category_id": 1}, {"id": 15, "bbox": [373.34, 274.0, 219.13, 301.05], "category_id": 1}, {"id": 16, "bbox": [10.82, 406.6, 52.08, 48.03], "category_id": 3}, {"id": 17, "bbox": [263.1, 803.72, 274.59, 91.33], "category_id": 2}, {"id": 18, "bbox": [645.23, 443.81, 202.22, 131.24], "category_id": 2}, {"id": 19, "bbox": [746.68, 804.4, 235.36, 54.12], "category_id": 2}, {"id": 20, "bbox": [877.21, 274.0, 221.84, 303.08], "category_id": 1}, {"id": 21, "bbox": [941.46, 10.15, 388.22, 180.63], "category_id": 1}, {"id": 22, "bbox": [1038.18, 640.68, 300.97, 286.85], "category_id": 1}, {"id": 23, "bbox": [1132.87, 328.79, 144.73, 92.01], "category_id": 2}, {"id": 24, "bbox": [96.04, 330.82, 256.33, 89.98], "category_id": 2}, {"id": 25, "bbox": [10.82, 24.36, 172.47, 165.75], "category_id": 1}, {"id": 26, "bbox": [353.72, 163.04, 48.02, 39.24], "category_id": 3}, {"id": 27, "bbox": [1132.87, 442.45, 159.61, 101.48], "category_id": 2}], "caption": "Scheme 11. Synthesis of Key Aminoalcohol 11a", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 303, 352, 324], "ImageBB": [82, 330, 420, 609]}, "reactions": [{"reactants": [25, 7], "conditions": [6, 11], "products": [21]}, {"reactants": [16], "conditions": [24, 9], "products": [15]}, {"reactants": [15], "conditions": [0, 18], "products": [20]}, {"reactants": [20], "conditions": [23, 27], "products": [14]}, {"reactants": [14], "conditions": [13, 17], "products": [10]}, {"reactants": [10], "conditions": [4, 19], "products": [22]}], "diagram_type": "multiple"}, {"id": 1214, "width": 1348, "height": 888, "file_name": "ol802669r-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [56.64, 462.3, 294.02, 330.83], "category_id": 1}, {"id": 1, "bbox": [1098.5, 711.52, 39.11, 43.17], "category_id": 3}, {"id": 2, "bbox": [463.94, 496.38, 333.13, 333.84], "category_id": 1}, {"id": 3, "bbox": [574.54, 678.47, 37.76, 46.54], "category_id": 3}, {"id": 4, "bbox": [191.51, 772.22, 33.72, 43.16], "category_id": 3}, {"id": 5, "bbox": [596.11, 32.37, 353.36, 101.84], "category_id": 2}, {"id": 6, "bbox": [621.74, 156.47, 302.78, 92.39], "category_id": 2}, {"id": 7, "bbox": [364.82, 254.26, 42.48, 42.49], "category_id": 3}, {"id": 8, "bbox": [956.88, 468.73, 334.48, 335.19], "category_id": 1}, {"id": 9, "bbox": [975.09, 0.0, 293.34, 306.86], "category_id": 1}, {"id": 10, "bbox": [159.82, 20.91, 422.13, 246.84], "category_id": 1}, {"id": 11, "bbox": [1080.29, 223.24, 37.76, 49.9], "category_id": 3}], "caption": "Scheme 3. Reaction with Diaminoacetal 5", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [483, 74, 702, 89], "ImageBB": [425, 96, 762, 318]}, "reactions": [{"reactants": [10], "conditions": [5, 6], "products": [9]}, {"reactants": [10], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [2]}, {"reactants": [8], "conditions": [], "products": [9]}], "diagram_type": "graph"}, {"id": 420, "width": 2820, "height": 2032, "file_name": "op300363s-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2154.0, 260.0, 71.0, 52.0], "category_id": 3}, {"id": 1, "bbox": [1771.0, 263.0, 67.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [1400.0, 260.0, 52.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [1757.0, 873.1, 603.8, 476.5], "category_id": 1}, {"id": 4, "bbox": [518.72, 262.72, 59.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [947.17, 261.45, 75.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [2054.0, 29.0, 330.0, 275.1], "category_id": 1}, {"id": 7, "bbox": [1637.9, 7.0, 312.2, 302.6], "category_id": 1}, {"id": 8, "bbox": [1248.1, 0.0, 303.9, 304.1], "category_id": 1}, {"id": 9, "bbox": [862.2, 15.4, 298.4, 228.3], "category_id": 1}, {"id": 10, "bbox": [439.3, 38.5, 268.3, 202.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [], "products": [7]}, {"reactants": [8], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10]}, {"reactants": [7], "conditions": [], "products": [6]}], "corefs": [[10, 4], [9, 5], [8, 2], [7, 1], [6, 0]], "caption": "Figure 5. 1H NMR analysis of a sample containing dienylimine 9a after extraction of the reaction mixture with sat. NaHCO3/EtOAc. Conditions: 1 mmol 2-ethylphenylhydrazine hydrochloride 1a, 1 equiv DHF, 1.5 mL MeOH/H2O 2:1; 20% H2SO4; 5 min reaction temperature at 130 \u00b0C. ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 631, 784, 662], "ImageBB": [82, 116, 787, 624]}, "diagram_type": "single"}, {"id": 518, "width": 1252, "height": 928, "file_name": "jo011082s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [364.0, 788.0, 104.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [842.0, 404.0, 44.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [482.0, 513.0, 45.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [106.0, 387.0, 49.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [308.0, 867.0, 703.0, 61.0], "category_id": 2}, {"id": 5, "bbox": [823.0, 777.0, 182.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [388.2, 315.3, 274.1, 183.0], "category_id": 1}, {"id": 7, "bbox": [2.0, 224.5, 356.9, 194.9], "category_id": 1}, {"id": 8, "bbox": [740.3, 572.0, 274.9, 199.0], "category_id": 1}, {"id": 9, "bbox": [686.4, 201.4, 339.5, 173.8], "category_id": 1}, {"id": 10, "bbox": [259.2, 582.7, 321.8, 193.2], "category_id": 1}, {"id": 11, "bbox": [375.0, 238.0, 145.0, 57.0], "category_id": 2}, {"id": 12, "bbox": [367.0, 349.0, 50.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [11, 12, 6], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10, 8]}], "corefs": [[7, 3], [6, 2], [9, 1], [10, 0], [8, 5]], "caption": "Table 2. 1,3-Dienes 10 and 11", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [520, 279, 695, 291], "ImageBB": [464, 35, 777, 267]}, "diagram_type": "multiple"}, {"id": 801, "width": 1352, "height": 912, "file_name": "jo501006u-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [455.0, 39.8, 352.4, 54.1], "category_id": 2}, {"id": 1, "bbox": [569.0, 180.3, 270.0, 50.6], "category_id": 2}, {"id": 2, "bbox": [235.0, 135.0, 204.0, 75.0], "category_id": 1}, {"id": 3, "bbox": [3.0, 237.0, 1349.0, 675.0], "category_id": 4}, {"id": 4, "bbox": [454.72, 107.52, 249.39, 52.57], "category_id": 1}, {"id": 5, "bbox": [1206.57, 150.31, 140.59, 45.24], "category_id": 2}, {"id": 6, "bbox": [701.67, 106.3, 256.73, 57.46], "category_id": 2}, {"id": 7, "bbox": [9.0, 135.0, 172.0, 73.0], "category_id": 1}, {"id": 8, "bbox": [938.0, 151.0, 230.6, 45.0], "category_id": 1}], "reactions": [{"reactants": [7, 2], "conditions": [0, 4, 6, 1], "products": [8, 5]}], "corefs": [], "caption": "Figure 3. Plots of the yields of the cross-coupling product (\u25a0, left axis) and nonane (\u25c6, right axis) against the amount of phenylpropyne used at 3 h reaction time. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 749, 417, 793], "ImageBB": [82, 514, 420, 742]}, "diagram_type": "single"}, {"id": 858, "width": 1356, "height": 1020, "file_name": "jo200480h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.88, 128.53, 138.1, 46.48], "category_id": 3}, {"id": 1, "bbox": [274.7, 31.0, 537.6, 110.9], "category_id": 1}, {"id": 2, "bbox": [50.4, 366.0, 177.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [427.0, 278.0, 338.8, 58.2], "category_id": 2}, {"id": 4, "bbox": [4.7, 140.6, 302.5, 213.9], "category_id": 1}, {"id": 5, "bbox": [859.0, 3.0, 497.0, 370.0], "category_id": 1}, {"id": 6, "bbox": [266.0, 164.0, 591.0, 112.0], "category_id": 2}, {"id": 7, "bbox": [960.0, 372.0, 153.0, 39.0], "category_id": 3}, {"id": 8, "bbox": [4.0, 494.0, 1352.0, 526.0], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [1, 6, 3], "products": [5]}], "corefs": [[4, 2], [1, 0], [5, 7]], "caption": "Table 3. Heteroannulation Reaction between 4-Acetamido- 3-iodopyridines 1, 4, and 6 and Symmetrical Diarylacetylenes 16 18 ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 771, 137], "ImageBB": [436, 148, 775, 403]}, "diagram_type": "single"}, {"id": 499, "width": 1356, "height": 2660, "file_name": "ol053021c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [889.0, 1.0, 346.0, 265.0], "category_id": 1}, {"id": 1, "bbox": [468.0, 80.4, 363.0, 49.6], "category_id": 2}, {"id": 2, "bbox": [15.0, 285.0, 1334.0, 2375.0], "category_id": 4}, {"id": 3, "bbox": [477.0, 174.0, 364.0, 92.0], "category_id": 2}, {"id": 4, "bbox": [617.28, 25.02, 74.88, 57.06], "category_id": 3}, {"id": 5, "bbox": [84.0, 0.0, 359.0, 267.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [4, 1, 3], "products": [0]}], "corefs": [], "caption": "Table 1. Substrate Scope of the Reactiona,b", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 242, 305, 256], "ImageBB": [73, 256, 412, 921]}, "diagram_type": "single"}, {"id": 986, "width": 1356, "height": 980, "file_name": "ja2031294-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [629.5, 206.3, 69.87, 49.53], "category_id": 2}, {"id": 1, "bbox": [12.89, 447.2, 61.05, 68.54], "category_id": 3}, {"id": 2, "bbox": [9.41, 2.35, 65.69, 59.15], "category_id": 3}, {"id": 3, "bbox": [1183.02, 118.76, 172.98, 244.97], "category_id": 1}, {"id": 4, "bbox": [643.74, 669.1, 113.29, 51.58], "category_id": 2}, {"id": 5, "bbox": [629.5, 745.79, 160.09, 58.36], "category_id": 2}, {"id": 6, "bbox": [455.84, 698.28, 100.4, 63.11], "category_id": 2}, {"id": 7, "bbox": [422.61, 223.26, 145.16, 69.22], "category_id": 2}, {"id": 8, "bbox": [1176.92, 582.24, 168.9, 239.55], "category_id": 1}, {"id": 9, "bbox": [757.03, 156.76, 371.73, 203.58], "category_id": 1}, {"id": 10, "bbox": [841.82, 619.57, 292.36, 201.54], "category_id": 1}, {"id": 11, "bbox": [0.0, 456.02, 356.81, 386.81], "category_id": 1}, {"id": 12, "bbox": [0.0, 0.0, 362.23, 389.52], "category_id": 1}], "caption": "Scheme 1. UP-Catalyzed (A) Phosphorolysis and (B) Arsenolysis of Uridine ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 369, 122], "ImageBB": [71, 133, 410, 378]}, "reactions": [{"reactants": [12, 7], "conditions": [0], "products": [9, 3]}, {"reactants": [9, 3], "conditions": [], "products": [7, 12]}, {"reactants": [11, 6], "conditions": [4, 5], "products": [10, 8]}], "diagram_type": "multiple"}, {"id": 561, "width": 1352, "height": 776, "file_name": "acs.orglett.5b01754-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1192.0, 218.0, 77.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [339.0, 210.0, 74.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [6.0, 293.0, 1346.0, 483.0], "category_id": 4}, {"id": 3, "bbox": [476.0, 99.0, 391.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [479.0, 174.0, 391.0, 57.7], "category_id": 2}, {"id": 5, "bbox": [943.7, 6.6, 318.5, 262.9], "category_id": 1}, {"id": 6, "bbox": [85.3, 3.9, 322.8, 263.5], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 4], "products": [5]}], "corefs": [[6, 1], [5, 0]], "caption": "Table 3. Proposed Direct Interconversion of BINOL and H8-BINOL-Based Chiral Br\u00f8nsted Acid ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 387, 771, 417], "ImageBB": [448, 424, 786, 618]}, "diagram_type": "single"}, {"id": 91, "width": 1344, "height": 1248, "file_name": "ja053650h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [880.34, 53.93, 312.11, 201.68], "category_id": 1}, {"id": 1, "bbox": [541.49, 144.7, 225.88, 36.8], "category_id": 2}, {"id": 2, "bbox": [558.12, 76.62, 186.56, 36.78], "category_id": 2}, {"id": 3, "bbox": [149.69, 7.04, 289.42, 204.7], "category_id": 1}, {"id": 4, "bbox": [2.95, 276.3, 1336.23, 964.1], "category_id": 4}], "reactions": [{"reactants": [3], "conditions": [2, 1], "products": [0]}], "corefs": [], "caption": "Table 1. Intramolecular Carbonylation of 2-(2-Iodophenoxy)aniline (3, R1 ) R2 ) H, X ) I) with G1-Pd under Different Reaction Conditionsa ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 406, 100], "ImageBB": [74, 102, 410, 414]}, "diagram_type": "single"}, {"id": 75, "width": 1356, "height": 1136, "file_name": "ja2014746-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [269.68, 430.42, 20.43, 28.16], "category_id": 3}, {"id": 1, "bbox": [37.04, 5.39, 527.1, 139.56], "category_id": 1}, {"id": 2, "bbox": [6.0, 631.97, 640.29, 481.94], "category_id": 1}, {"id": 3, "bbox": [668.32, 622.33, 680.23, 506.73], "category_id": 1}, {"id": 4, "bbox": [650.89, 32.01, 86.31, 37.5], "category_id": 2}, {"id": 5, "bbox": [603.56, 88.22, 176.54, 62.64], "category_id": 2}, {"id": 6, "bbox": [631.67, 287.91, 86.31, 36.02], "category_id": 2}, {"id": 7, "bbox": [22.25, 240.57, 518.23, 160.27], "category_id": 1}, {"id": 8, "bbox": [821.0, 5.39, 501.96, 135.12], "category_id": 1}, {"id": 9, "bbox": [806.21, 234.66, 504.91, 163.23], "category_id": 1}, {"id": 10, "bbox": [584.33, 344.11, 175.06, 62.65], "category_id": 2}, {"id": 11, "bbox": [288.5, 148.86, 16.79, 30.11], "category_id": 3}, {"id": 12, "bbox": [1047.81, 429.83, 20.43, 26.37], "category_id": 3}, {"id": 13, "bbox": [1066.24, 151.03, 20.43, 27.56], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [8]}, {"reactants": [7], "conditions": [6, 10], "products": [9]}], "corefs": [[1, 11], [8, 13], [7, 0], [9, 12]], "caption": "Figure 1. (Left) ORTEP drawing of 2 (50% probability level). One of the tert-butyl groups on Si3 is disordered, and the minor contribution (occupancy factor 0.299) and hydrogen atoms are omitted for clarity. # indicates the following symmetry transformation:  x,  y \u00fe 1,  z. Selected bond lengths (\u00c5) and angles (deg): Si1 Si2 = 2.3675(6), Si1 Si3 = 2.3737(6), Si1 C1 = 1.8174(14), C1 C2 = 1.423(2), C1 C3# = 1.422(2), C2 C3 = 1.3700(19). Si2 Si1 Si3 = 122.86(2), Si2 Si1 C1 = 117.52(5), Si3 Si1 C1 = 119.58(5), Si1 C1 C2 = 120.66(11), Si1 C1 C3# = 124.39(11), C2 C1 C3# = 114.94(12), C1 C2 C3 = 122.78(13), C2 C3 C1# = 122.29(13). (Right) ORTEP drawing of 4 (50% probability level). Hydrogen atoms are omitted for clarity. # indicates the following symmetry transformation:  x \u00fe 1/2,  y \u00fe 1/2, z. Selected bond lengths (\u00c5) and angles (deg): Si1 Si2 = 2.3554(14), Si1 Si3 = 2.3524(14), Si1 C2 = 1.9108(19), C1 C2 = 1.387(3), C1 C2# = 1.387(3), C2 C3 = 1.395(5), C3 C4 = 1.386(4), C4 C3# = 1.386(4). Si2 Si1 Si3 = 122.21(5), Si2 Si1 C2 = 117.15(5), Si3 Si1 C2 = 119.29(5), C2 C1 C2# = 123.2(4), Si1 C2 C1 = 120.8(3), Si1 C2 C3 = 121.73(17), C1 C2 C3 = 117.5(2), C2 C3 C4 = 121.0(3), C3 C4 C3# = 119.7(4). ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 430, 405, 707], "ImageBB": [71, 133, 410, 417]}, "diagram_type": "multiple"}, {"id": 1007, "width": 1252, "height": 1476, "file_name": "ja9612413-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [602.35, 2.95, 458.41, 335.96], "category_id": 1}, {"id": 1, "bbox": [0.0, 1097.22, 343.25, 59.07], "category_id": 1}, {"id": 2, "bbox": [808.3, 342.6, 347.68, 53.17], "category_id": 2}, {"id": 3, "bbox": [583.9, 523.5, 437.0, 353.68], "category_id": 1}, {"id": 4, "bbox": [844.47, 461.48, 225.88, 63.5], "category_id": 2}, {"id": 5, "bbox": [577.25, 1138.57, 494.58, 337.43], "category_id": 1}, {"id": 6, "bbox": [367.61, 965.79, 284.2, 51.68], "category_id": 2}, {"id": 7, "bbox": [86.37, 377.31, 293.79, 152.84], "category_id": 1}, {"id": 8, "bbox": [71.6, 657.15, 293.8, 190.5], "category_id": 1}, {"id": 9, "bbox": [916.81, 965.79, 311.51, 51.68], "category_id": 2}], "caption": "Scheme 2. Simplified Catalytic Cycle for the Hydroamination/Cyclization of Aminoalkynes ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 50, 690, 78], "ImageBB": [451, 84, 764, 453]}, "reactions": [{"reactants": [0, 2], "conditions": [], "products": [3, 4]}, {"reactants": [3], "conditions": [9], "products": [5]}, {"reactants": [5, 1], "conditions": [6], "products": [3, 8]}, {"reactants": [8], "conditions": [], "products": [7]}], "diagram_type": "graph"}, {"id": 666, "width": 1344, "height": 976, "file_name": "ol402047d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [848.0, 277.0, 32.0, 35.0], "category_id": 3}, {"id": 1, "bbox": [273.0, 96.0, 159.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [186.0, 148.0, 306.0, 51.0], "category_id": 2}, {"id": 3, "bbox": [2.0, 396.0, 1342.0, 580.0], "category_id": 4}, {"id": 4, "bbox": [1100.0, 129.0, 159.0, 80.0], "category_id": 2}, {"id": 5, "bbox": [987.0, 306.0, 28.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [958.0, 6.0, 99.0, 305.0], "category_id": 1}, {"id": 7, "bbox": [685.0, 78.0, 31.0, 33.0], "category_id": 3}, {"id": 8, "bbox": [535.0, 150.0, 242.0, 168.0], "category_id": 2}, {"id": 9, "bbox": [90.0, 125.0, 78.0, 47.0], "category_id": 2}, {"id": 10, "bbox": [594.7, 108.0, 163.1, 42.0], "category_id": 2}, {"id": 11, "bbox": [560.0, 24.1, 207.5, 77.9], "category_id": 1}, {"id": 12, "bbox": [820.0, 12.0, 93.7, 259.7], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [1, 2, 11, 10, 8], "products": [12, 6, 4]}], "corefs": [[11, 7], [12, 0], [6, 5]], "caption": "Table 1. Optimization of CCR Employing PSTAa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 336, 101], "ImageBB": [71, 112, 407, 356]}, "diagram_type": "single"}, {"id": 11, "width": 1356, "height": 704, "file_name": "jacs.5b05415-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1045.69, 250.49, 264.53, 168.23], "category_id": 1}, {"id": 1, "bbox": [18.31, 496.66, 277.24, 167.33], "category_id": 1}, {"id": 2, "bbox": [1020.26, 496.66, 311.76, 167.33], "category_id": 1}, {"id": 3, "bbox": [243.59, 293.18, 271.79, 42.88], "category_id": 2}, {"id": 4, "bbox": [279.01, 357.68, 184.59, 43.78], "category_id": 2}, {"id": 5, "bbox": [784.98, 286.83, 179.14, 42.87], "category_id": 2}, {"id": 6, "bbox": [779.53, 125.13, 217.29, 44.7], "category_id": 2}, {"id": 7, "bbox": [757.73, 352.23, 229.1, 83.75], "category_id": 2}, {"id": 8, "bbox": [293.55, 555.71, 249.08, 43.78], "category_id": 2}, {"id": 9, "bbox": [267.2, 620.2, 274.52, 70.13], "category_id": 2}, {"id": 10, "bbox": [804.97, 552.07, 141.89, 37.43], "category_id": 2}, {"id": 11, "bbox": [758.64, 609.3, 236.36, 44.7], "category_id": 2}, {"id": 12, "bbox": [124.59, 411.27, 46.51, 38.34], "category_id": 3}, {"id": 13, "bbox": [618.75, 425.81, 49.24, 37.42], "category_id": 3}, {"id": 14, "bbox": [1150.16, 214.15, 53.77, 38.34], "category_id": 3}, {"id": 15, "bbox": [1151.97, 422.17, 50.15, 40.16], "category_id": 3}, {"id": 16, "bbox": [120.95, 659.26, 49.24, 36.52], "category_id": 3}, {"id": 17, "bbox": [1151.06, 659.26, 51.97, 38.34], "category_id": 3}, {"id": 18, "bbox": [789.53, 67.0, 199.12, 42.87], "category_id": 2}, {"id": 19, "bbox": [553.35, 271.38, 166.41, 156.43], "category_id": 1}, {"id": 20, "bbox": [17.4, 271.38, 225.46, 126.45], "category_id": 1}, {"id": 21, "bbox": [1056.59, 44.29, 243.63, 168.23], "category_id": 1}], "reactions": [{"reactants": [20], "conditions": [3, 4], "products": [19]}, {"reactants": [19], "conditions": [18, 6], "products": [21]}, {"reactants": [19], "conditions": [5, 7], "products": [0]}, {"reactants": [19], "conditions": [8, 9], "products": [1]}, {"reactants": [19], "conditions": [10, 11], "products": [2]}], "corefs": [[20, 12], [19, 13], [21, 14], [0, 15], [2, 17], [1, 16]], "caption": "Figure 1. Gold catalysis and radical reaction relay.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 825, 688, 839], "ImageBB": [448, 640, 787, 816]}, "diagram_type": "tree"}, {"id": 387, "width": 1704, "height": 1952, "file_name": "op500224x-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [168.0, 310.0, 67.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [700.0, 308.0, 73.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [1238.0, 310.0, 74.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [341.0, 67.0, 170.0, 70.0], "category_id": 2}, {"id": 4, "bbox": [351.0, 173.0, 158.0, 91.0], "category_id": 2}, {"id": 5, "bbox": [940.0, 98.0, 93.0, 45.0], "category_id": 2}, {"id": 6, "bbox": [726.0, 805.0, 491.0, 291.0], "category_id": 1}, {"id": 7, "bbox": [910.0, 405.0, 480.0, 302.0], "category_id": 1}, {"id": 8, "bbox": [68.0, 403.0, 398.0, 304.0], "category_id": 1}, {"id": 9, "bbox": [44.0, 0.0, 292.0, 301.0], "category_id": 1}, {"id": 10, "bbox": [496.0, 401.0, 375.0, 306.0], "category_id": 1}, {"id": 11, "bbox": [274.0, 1107.0, 170.0, 89.0], "category_id": 3}, {"id": 12, "bbox": [966.0, 1522.0, 169.0, 89.0], "category_id": 3}, {"id": 13, "bbox": [247.0, 712.0, 184.0, 86.0], "category_id": 3}, {"id": 14, "bbox": [587.0, 708.0, 199.0, 95.0], "category_id": 3}, {"id": 15, "bbox": [1061.0, 708.0, 188.0, 95.0], "category_id": 3}, {"id": 16, "bbox": [899.0, 1105.0, 173.0, 87.0], "category_id": 3}, {"id": 17, "bbox": [291.0, 1529.0, 171.0, 84.0], "category_id": 3}, {"id": 18, "bbox": [111.2, 835.0, 501.8, 285.0], "category_id": 1}, {"id": 19, "bbox": [76.7, 1209.0, 582.3, 306.3], "category_id": 1}, {"id": 20, "bbox": [584.7, 0.0, 286.3, 306.7], "category_id": 1}, {"id": 21, "bbox": [1107.0, 0.0, 305.0, 305.8], "category_id": 1}, {"id": 22, "bbox": [891.9, 165.0, 212.1, 65.7], "category_id": 2}, {"id": 23, "bbox": [777.5, 1198.0, 545.5, 326.0], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [3, 4], "products": [20]}, {"reactants": [20], "conditions": [5, 22], "products": [21]}], "corefs": [[9, 0], [20, 1], [21, 2], [8, 13], [10, 14], [7, 15], [18, 11], [6, 16], [19, 17], [23, 12]], "caption": "Table 3. Kinetic protonation and carbon nucleophile addition products ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 603, 747, 633], "ImageBB": [433, 639, 859, 1127]}, "diagram_type": "single"}, {"id": 1051, "width": 1796, "height": 956, "file_name": "jo0157425-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [376.45, 893.39, 47.62, 50.28], "category_id": 3}, {"id": 1, "bbox": [0.0, 118.52, 35.94, 52.08], "category_id": 3}, {"id": 2, "bbox": [1466.27, 587.21, 329.73, 304.38], "category_id": 1}, {"id": 3, "bbox": [1199.43, 296.3, 38.63, 46.69], "category_id": 3}, {"id": 4, "bbox": [1224.59, 907.75, 40.43, 45.8], "category_id": 3}, {"id": 5, "bbox": [274.93, 5.39, 334.22, 305.28], "category_id": 1}, {"id": 6, "bbox": [451.92, 297.2, 47.62, 50.28], "category_id": 3}, {"id": 7, "bbox": [824.78, 897.88, 44.92, 52.97], "category_id": 3}, {"id": 8, "bbox": [1064.66, 628.51, 309.07, 213.7], "category_id": 1}, {"id": 9, "bbox": [1640.57, 907.75, 36.83, 45.8], "category_id": 3}, {"id": 10, "bbox": [780.75, 591.7, 113.21, 187.66], "category_id": 1}, {"id": 11, "bbox": [933.49, 62.85, 530.98, 179.58], "category_id": 1}, {"id": 12, "bbox": [207.54, 527.05, 335.12, 275.65], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 64, 453, 78], "ImageBB": [201, 83, 650, 322]}, "reactions": [{"reactants": [1], "conditions": [], "products": [5, 11]}, {"reactants": [5], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [10, 8]}], "diagram_type": "tree"}, {"id": 949, "width": 1352, "height": 788, "file_name": "acs.orglett.5b02709-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [672.96, 89.27, 343.58, 231.28], "category_id": 1}, {"id": 1, "bbox": [1043.59, 236.02, 235.37, 48.01], "category_id": 2}, {"id": 2, "bbox": [1092.29, 672.89, 162.32, 61.54], "category_id": 1}, {"id": 3, "bbox": [503.2, 524.11, 177.2, 87.24], "category_id": 2}, {"id": 4, "bbox": [4.06, 511.26, 371.98, 223.17], "category_id": 1}, {"id": 5, "bbox": [1137.6, 502.47, 154.88, 147.43], "category_id": 1}, {"id": 6, "bbox": [309.76, 607.97, 163.68, 123.08], "category_id": 1}, {"id": 7, "bbox": [709.48, 504.5, 156.23, 235.34], "category_id": 1}, {"id": 8, "bbox": [25.7, 0.0, 564.07, 461.89], "category_id": 1}, {"id": 9, "bbox": [1015.18, 359.1, 318.56, 47.34], "category_id": 2}, {"id": 10, "bbox": [1044.27, 110.23, 233.33, 89.95], "category_id": 2}, {"id": 11, "bbox": [879.24, 273.89, 39.23, 48.02], "category_id": 3}, {"id": 12, "bbox": [193.43, 695.89, 38.55, 39.22], "category_id": 3}, {"id": 13, "bbox": [1123.4, 600.53, 40.58, 45.99], "category_id": 3}, {"id": 14, "bbox": [902.24, 518.7, 180.58, 85.89], "category_id": 2}, {"id": 15, "bbox": [838.66, 701.3, 33.82, 41.25], "category_id": 3}, {"id": 16, "bbox": [329.38, 403.74, 205.6, 45.98], "category_id": 3}], "caption": "Scheme 1. Retrosynthetic Analysis", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 276, 110], "ImageBB": [82, 116, 420, 313]}, "reactions": [{"reactants": [8], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [10, 1], "products": [9]}, {"reactants": [4, 6], "conditions": [3], "products": [7]}, {"reactants": [7], "conditions": [14], "products": [5, 2]}], "diagram_type": "multiple"}, {"id": 1055, "width": 2808, "height": 824, "file_name": "jo2001534-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [313.25, 626.76, 318.87, 57.62], "category_id": 3}, {"id": 1, "bbox": [1210.85, 26.7, 325.89, 309.17], "category_id": 1}, {"id": 2, "bbox": [2211.0, 22.48, 328.7, 316.2], "category_id": 1}, {"id": 3, "bbox": [2338.83, 625.36, 84.28, 54.8], "category_id": 3}, {"id": 4, "bbox": [1806.42, 622.66, 137.65, 61.41], "category_id": 3}, {"id": 5, "bbox": [351.6, 482.89, 120.71, 120.71], "category_id": 2}, {"id": 6, "bbox": [266.89, 43.56, 325.89, 451.1], "category_id": 1}, {"id": 7, "bbox": [1695.48, 22.48, 328.7, 316.2], "category_id": 1}, {"id": 8, "bbox": [1807.2, 477.8, 114.3, 126.1], "category_id": 2}, {"id": 9, "bbox": [1250.19, 622.55, 257.06, 61.83], "category_id": 3}, {"id": 10, "bbox": [796.47, 622.55, 297.79, 59.02], "category_id": 3}, {"id": 11, "bbox": [0.0, 727.3, 1471.8, 87.77], "category_id": 2}, {"id": 12, "bbox": [1288.11, 477.8, 120.69, 127.1], "category_id": 2}, {"id": 13, "bbox": [733.25, 33.73, 334.32, 363.97], "category_id": 1}, {"id": 14, "bbox": [845.0, 479.9, 120.7, 125.0], "category_id": 2}, {"id": 15, "bbox": [2306.52, 477.8, 162.95, 126.1], "category_id": 2}], "caption": "Scheme 8. Calculated 6-Exo-Trig Cyclization of 1d- as Model for the Formation of Type 8 Compounds from 5d-h for the Gas Phase and SCRF-CPCM(UAKS) Solution-Phase Simulations (THF) (Relative Energies: SCS-MP2/6-311\u00feG(d,p)//B3LYP/6- 31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 770, 138], "ImageBB": [71, 148, 773, 354]}, "reactions": [{"reactants": [6], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [6]}, {"reactants": [13], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [13]}, {"reactants": [1], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [2]}], "diagram_type": "single"}, {"id": 113, "width": 1188, "height": 1476, "file_name": "op990099y-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [147.0, 222.0, 357.0, 80.0], "category_id": 2}, {"id": 1, "bbox": [838.0, 230.0, 350.0, 72.0], "category_id": 2}, {"id": 2, "bbox": [819.0, 1388.0, 250.1, 73.6], "category_id": 2}, {"id": 3, "bbox": [272.3, 1017.6, 574.5, 458.4], "category_id": 1}, {"id": 4, "bbox": [41.0, 593.0, 1023.0, 220.9], "category_id": 1}, {"id": 5, "bbox": [654.0, 409.7, 201.0, 92.5], "category_id": 2}, {"id": 6, "bbox": [729.0, 867.0, 251.4, 71.2], "category_id": 2}, {"id": 7, "bbox": [9.0, 0.0, 567.0, 197.2], "category_id": 1}, {"id": 8, "bbox": [753.0, 2.0, 435.0, 188.9], "category_id": 1}], "reactions": [{"reactants": [7, 8], "conditions": [5], "products": [4, 3]}], "corefs": [[7, 0], [8, 1], [4, 6], [3, 2]], "caption": "Figure 1. Reaction scheme for the reaction between diphenyl oxide with benzyl chloride over sulphated zirconia catalyst. 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Single-crystal X-ray structure of 9a. Hydrogen atoms are omitted for clarity except polar N-H bonds. Selected bond lengths (A\u030a): C5-O1 1.224(3), C12-O2 1.200(3), N1-C1 1.368(3), N1-C4 1.340(3). 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Model for Stereoselection in the Anti Diol Series", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [262, 75, 586, 88], "ImageBB": [73, 94, 777, 271]}, "reactions": [{"reactants": [17], "conditions": [1], "products": [11]}, {"reactants": [11], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [], "products": [17]}, {"reactants": [11], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [11]}, {"reactants": [15], "conditions": [21], "products": [12]}, {"reactants": [10], "conditions": [8, 9], "products": [20]}, {"reactants": [2], "conditions": [24], "products": [18]}, {"reactants": [25], "conditions": [14, 22], "products": [13]}], "diagram_type": "graph"}, {"id": 1191, "width": 1352, "height": 1016, "file_name": "ol500248h-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [89.7, 2.7, 182.19, 114.27], "category_id": 1}, {"id": 1, "bbox": [656.05, 438.82, 71.01, 37.19], "category_id": 2}, {"id": 2, "bbox": [325.32, 124.41, 179.9, 40.57], "category_id": 3}, {"id": 3, "bbox": [918.47, 42.6, 171.11, 38.54], "category_id": 2}, {"id": 4, "bbox": [987.45, 440.17, 31.79, 35.84], "category_id": 3}, {"id": 5, "bbox": [100.1, 438.82, 158.26, 40.57], "category_id": 3}, {"id": 6, "bbox": [877.21, 253.56, 253.63, 185.26], "category_id": 1}, {"id": 7, "bbox": [520.1, 71.67, 345.61, 41.92], "category_id": 2}, {"id": 8, "bbox": [384.16, 869.53, 44.64, 41.24], "category_id": 3}, {"id": 9, "bbox": [325.32, 438.15, 177.88, 42.59], "category_id": 3}, {"id": 10, "bbox": [81.16, 541.6, 198.84, 115.62], "category_id": 1}, {"id": 11, "bbox": [535.77, 131.68, 454.94, 98.8], "category_id": 2}, {"id": 12, "bbox": [349.67, 6.76, 134.59, 81.14], "category_id": 1}, {"id": 13, "bbox": [100.1, 665.33, 158.26, 37.87], "category_id": 3}, {"id": 14, "bbox": [574.89, 334.69, 238.74, 33.81], "category_id": 2}, {"id": 15, "bbox": [543.1, 392.17, 301.65, 39.21], "category_id": 2}, {"id": 16, "bbox": [520.1, 605.83, 345.61, 86.55], "category_id": 2}, {"id": 17, "bbox": [543.1, 10.14, 337.49, 40.57], "category_id": 2}, {"id": 18, "bbox": [345.61, 663.3, 146.09, 41.25], "category_id": 3}, {"id": 19, "bbox": [574.89, 541.6, 238.74, 39.89], "category_id": 2}, {"id": 20, "bbox": [100.77, 124.41, 150.83, 40.57], "category_id": 3}, {"id": 21, "bbox": [918.47, 572.7, 171.11, 38.54], "category_id": 2}, {"id": 22, "bbox": [465.32, 892.52, 479.52, 70.99], "category_id": 2}, {"id": 23, "bbox": [349.67, 530.78, 133.24, 113.59], "category_id": 1}, {"id": 24, "bbox": [574.89, 798.53, 231.31, 33.14], "category_id": 2}, {"id": 25, "bbox": [877.21, 678.18, 253.63, 190.67], "category_id": 1}, {"id": 26, "bbox": [81.16, 261.67, 198.84, 154.16], "category_id": 1}, {"id": 27, "bbox": [100.1, 438.15, 158.26, 41.24], "category_id": 3}, {"id": 28, "bbox": [998.95, 874.94, 63.58, 36.51], "category_id": 3}, {"id": 29, "bbox": [349.67, 321.17, 131.21, 85.2], "category_id": 1}, {"id": 30, "bbox": [100.1, 730.92, 255.65, 211.63], "category_id": 1}], "caption": "Scheme 3. Investigation of the Reaction Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 324, 376, 339], "ImageBB": [82, 346, 420, 600]}, "reactions": [{"reactants": [26, 29], "conditions": [14, 15, 1], "products": [6]}, {"reactants": [30], "conditions": [24, 22], "products": [25]}], "diagram_type": "multiple"}, {"id": 984, "width": 1356, "height": 864, "file_name": "ja200818w-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [542.67, 0.0, 177.73, 114.01], "category_id": 1}, {"id": 1, "bbox": [0.0, 0.0, 2.71, 4.07], "category_id": 2}, {"id": 2, "bbox": [0.0, 0.0, 2.71, 6.79], "category_id": 2}, {"id": 3, "bbox": [0.0, 0.0, 2.71, 8.82], "category_id": 2}, {"id": 4, "bbox": [530.71, 764.39, 69.49, 46.67], "category_id": 2}, {"id": 5, "bbox": [0.0, 319.63, 263.87, 177.12], "category_id": 1}, {"id": 6, "bbox": [633.2, 762.76, 108.9, 53.61], "category_id": 1}, {"id": 7, "bbox": [971.38, 354.24, 380.55, 160.83], "category_id": 1}, {"id": 8, "bbox": [138.38, 517.1, 33.24, 44.79], "category_id": 3}, {"id": 9, "bbox": [377.16, 487.92, 510.11, 133.01], "category_id": 2}, {"id": 10, "bbox": [1103.66, 548.32, 42.05, 47.5], "category_id": 3}, {"id": 11, "bbox": [307.97, 280.95, 588.12, 71.93], "category_id": 2}], "caption": "Scheme 1. Formation of 2 by Two Di\ufb00erent Pathways", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 373, 107], "ImageBB": [71, 117, 410, 333]}, "reactions": [{"reactants": [5], "conditions": [11], "products": [0, 7]}, {"reactants": [5], "conditions": [9], "products": [4, 6, 7]}], "diagram_type": "graph"}, {"id": 9, "width": 1352, "height": 668, "file_name": "jacs.5b05415-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [401.16, 160.63, 343.02, 141.0], "category_id": 2}, {"id": 1, "bbox": [404.61, 52.71, 341.3, 89.2], "category_id": 2}, {"id": 2, "bbox": [1208.39, 416.18, 53.8, 40.85], "category_id": 3}, {"id": 3, "bbox": [956.29, 416.18, 52.08, 40.85], "category_id": 3}, {"id": 4, "bbox": [1148.82, 231.42, 51.21, 39.13], "category_id": 3}, {"id": 5, "bbox": [889.81, 231.42, 52.08, 39.13], "category_id": 3}, {"id": 6, "bbox": [1191.12, 482.66, 84.02, 44.3], "category_id": 2}, {"id": 7, "bbox": [1190.26, 588.85, 84.88, 43.44], "category_id": 2}, {"id": 8, "bbox": [1125.51, 278.05, 108.19, 39.12], "category_id": 2}, {"id": 9, "bbox": [81.72, 307.4, 98.7, 40.85], "category_id": 2}, {"id": 10, "bbox": [163.74, 213.29, 49.48, 37.4], "category_id": 3}, {"id": 11, "bbox": [1061.62, 48.4, 226.47, 176.39], "category_id": 1}, {"id": 12, "bbox": [833.7, 46.67, 163.44, 161.72], "category_id": 1}, {"id": 13, "bbox": [61.0, 420.5, 300.72, 180.71], "category_id": 1}, {"id": 14, "bbox": [77.4, 76.02, 228.2, 125.46], "category_id": 1}, {"id": 15, "bbox": [200.0, 278.05, 141.86, 85.74], "category_id": 2}, {"id": 16, "bbox": [872.54, 276.32, 85.75, 39.99], "category_id": 2}, {"id": 17, "bbox": [394.25, 573.31, 505.33, 89.2], "category_id": 2}, {"id": 18, "bbox": [467.64, 400.64, 356.83, 36.53], "category_id": 2}, {"id": 19, "bbox": [161.15, 606.98, 52.94, 40.85], "category_id": 3}, {"id": 20, "bbox": [390.8, 459.35, 504.47, 89.2], "category_id": 2}], "reactions": [{"reactants": [14], "conditions": [1, 0], "products": [12, 11]}, {"reactants": [14], "conditions": [9, 15], "products": [13]}, {"reactants": [13], "conditions": [18, 20, 17], "products": [3, 2]}], "corefs": [[14, 10], [12, 5], [11, 4], [13, 19]], "caption": "Figure 4. Mechanistic investigation.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 414, 254, 428], "ImageBB": [82, 237, 420, 404]}, "diagram_type": "tree"}, {"id": 1353, "width": 1352, "height": 1164, "file_name": "op800136f-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [892.77, 0.0, 43.28, 47.33], "category_id": 3}, {"id": 1, "bbox": [921.85, 104.12, 232.66, 54.77], "category_id": 2}, {"id": 2, "bbox": [708.8, 700.47, 507.26, 448.27], "category_id": 1}, {"id": 3, "bbox": [681.75, 97.36, 118.36, 57.47], "category_id": 2}, {"id": 4, "bbox": [1263.4, 288.03, 88.6, 61.53], "category_id": 2}, {"id": 5, "bbox": [663.49, 214.33, 512.66, 243.41], "category_id": 1}, {"id": 6, "bbox": [0.0, 537.52, 371.99, 164.98], "category_id": 1}, {"id": 7, "bbox": [164.35, 442.19, 237.39, 57.47], "category_id": 2}, {"id": 8, "bbox": [424.74, 266.39, 121.74, 54.09], "category_id": 2}, {"id": 9, "bbox": [131.21, 699.12, 71.02, 52.06], "category_id": 3}, {"id": 10, "bbox": [870.45, 466.53, 99.42, 50.03], "category_id": 3}, {"id": 11, "bbox": [922.53, 1108.17, 71.69, 55.83], "category_id": 3}, {"id": 12, "bbox": [309.76, 290.73, 45.32, 59.5], "category_id": 3}, {"id": 13, "bbox": [992.86, 617.98, 115.66, 54.77], "category_id": 2}, {"id": 14, "bbox": [923.2, 546.31, 43.29, 50.03], "category_id": 3}, {"id": 15, "bbox": [131.21, 289.38, 73.72, 58.83], "category_id": 3}], "caption": "Scheme 6", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 486, 119, 500], "ImageBB": [58, 505, 396, 796]}, "reactions": [{"reactants": [5, 4], "conditions": [1], "products": [3, 9]}, {"reactants": [5, 4], "conditions": [], "products": [15, 12]}, {"reactants": [15, 12], "conditions": [8], "products": [5]}, {"reactants": [15], "conditions": [7], "products": [6]}, {"reactants": [5, 4], "conditions": [14], "products": [13, 2]}, {"reactants": [2], "conditions": [], "products": [5]}], "diagram_type": "tree"}, {"id": 848, "width": 1344, "height": 912, "file_name": "jo201478d-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [317.0, 220.0, 213.0, 83.4], "category_id": 2}, {"id": 1, "bbox": [612.0, 259.8, 223.0, 191.0], "category_id": 1}, {"id": 2, "bbox": [975.14, 432.84, 87.36, 38.39], "category_id": 3}, {"id": 3, "bbox": [457.0, 187.0, 36.2, 39.1], "category_id": 3}, {"id": 4, "bbox": [922.6, 291.7, 222.8, 156.5], "category_id": 1}, {"id": 5, "bbox": [644.3, 0.0, 251.1, 200.4], "category_id": 1}, {"id": 6, "bbox": [1019.0, 474.0, 62.0, 49.0], "category_id": 2}, {"id": 7, "bbox": [261.0, 188.0, 37.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [504.0, 667.0, 340.0, 245.0], "category_id": 1}, {"id": 9, "bbox": [200.1, 7.9, 152.7, 175.7], "category_id": 1}, {"id": 10, "bbox": [390.8, 23.4, 143.2, 141.9], "category_id": 1}, {"id": 11, "bbox": [743.0, 210.1, 43.9, 44.3], "category_id": 3}], "reactions": [{"reactants": [9, 10], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4, 6]}], "corefs": [[9, 7], [10, 3], [5, 11], [4, 2]], "caption": "Figure 1. Proposed steric hindrance limiting the transformation of trans-stilbene oxide to the desired DHP product. 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Investigation of two potential process routes for the synthesis of rif S.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 558, 471, 572], "ImageBB": [82, 343, 787, 549]}, "diagram_type": "graph"}, {"id": 160, "width": 876, "height": 240, "file_name": "op700060e-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [351.0, 86.0, 172.0, 61.0], "category_id": 2}, {"id": 1, "bbox": [378.0, 16.0, 113.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [552.6, 5.0, 323.4, 188.0], "category_id": 1}, {"id": 3, "bbox": [6.0, 0.0, 323.0, 156.0], "category_id": 1}, {"id": 4, "bbox": [187.0, 141.0, 30.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [645.0, 196.0, 114.3, 35.4], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [2]}], "corefs": [[3, 4], [2, 5]], "caption": "Figure 2. Oxidation of 2 with concentrated sodium hypochlorite.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 109, 394, 123], "ImageBB": [117, 46, 336, 106]}, "diagram_type": "single"}, {"id": 463, "width": 1344, "height": 1176, "file_name": "op200005e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 872.0, 1342.0, 301.0], "category_id": 4}, {"id": 1, "bbox": [1028.0, 690.0, 59.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [49.0, 611.0, 187.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [433.0, 367.0, 153.0, 42.0], "category_id": 2}, {"id": 4, "bbox": [919.0, 258.0, 59.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [113.0, 308.0, 35.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [628.0, 364.0, 705.0, 328.0], "category_id": 1}, {"id": 7, "bbox": [34.0, 433.0, 205.0, 153.0], "category_id": 1}, {"id": 8, "bbox": [19.0, 69.0, 338.0, 244.0], "category_id": 1}, {"id": 9, "bbox": [732.0, 0.0, 456.0, 246.0], "category_id": 1}, {"id": 10, "bbox": [424.0, 271.0, 115.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [8, 7], "conditions": [10, 3], "products": [9, 6]}], "corefs": [[8, 5], [7, 2], [9, 4], [6, 1]], "caption": "Table 1. Formation of Amide 13 from 8 and Homopiperazine", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 446, 405, 461], "ImageBB": [71, 471, 407, 765]}, "diagram_type": "single"}, {"id": 514, "width": 1352, "height": 1056, "file_name": "ol051342i-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [548.0, 91.0, 210.0, 54.0], "category_id": 2}, {"id": 1, "bbox": [39.0, 0.0, 402.0, 221.0], "category_id": 1}, {"id": 2, "bbox": [469.0, 3.0, 381.0, 80.0], "category_id": 2}, {"id": 3, "bbox": [22.0, 306.0, 1311.0, 741.0], "category_id": 4}, {"id": 4, "bbox": [186.0, 230.0, 58.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [1056.0, 232.0, 47.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [919.0, 1.0, 402.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2, 0], "products": [6]}], "corefs": [[1, 4], [6, 5]], "caption": "Table 1. Pictet-Spengler Reaction of Thioortho Esters with N-Tosyltryptamines ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 460, 758, 488], "ImageBB": [439, 496, 777, 760]}, "diagram_type": "single"}, {"id": 835, "width": 1348, "height": 2672, "file_name": "jo302142v-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [17.0, 201.0, 359.0, 258.0], "category_id": 1}, {"id": 1, "bbox": [394.0, 183.0, 227.0, 258.0], "category_id": 1}, {"id": 2, "bbox": [861.0, 498.0, 89.0, 69.0], "category_id": 3}, {"id": 3, "bbox": [177.0, 411.0, 50.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 838.0, 1348.0, 1834.0], "category_id": 4}, {"id": 5, "bbox": [445.0, 443.0, 153.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [42.0, 73.0, 325.0, 96.0], "category_id": 2}, {"id": 7, "bbox": [854.0, 226.0, 103.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [735.0, 0.0, 590.0, 283.0], "category_id": 1}, {"id": 9, "bbox": [25.86, 558.82, 1296.6, 243.56], "category_id": 4}, {"id": 10, "bbox": [717.0, 272.0, 626.0, 286.0], "category_id": 1}], "reactions": [{"reactants": [0, 1], "conditions": [], "products": [8, 10]}], "corefs": [[0, 3], [1, 5], [8, 7], [10, 2]], "caption": "Table 2. Aldol Reactions of the Ti(IV) \u201cate\u201d Enolate of 1a (R = MOM, Et3Si) with (\u00b1)-5a ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 184, 417, 220], "ImageBB": [82, 224, 419, 892]}, "diagram_type": "tree"}, {"id": 1294, "width": 1344, "height": 684, "file_name": "op200176f-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [230.61, 579.9, 39.67, 43.72], "category_id": 3}, {"id": 1, "bbox": [71.27, 8.07, 329.44, 170.2], "category_id": 1}, {"id": 2, "bbox": [248.76, 182.31, 59.84, 48.44], "category_id": 3}, {"id": 3, "bbox": [471.98, 0.0, 403.4, 133.87], "category_id": 1}, {"id": 4, "bbox": [696.54, 371.35, 80.68, 47.09], "category_id": 2}, {"id": 5, "bbox": [68.58, 347.8, 635.36, 219.99], "category_id": 1}, {"id": 6, "bbox": [974.89, 409.7, 57.15, 49.1], "category_id": 3}, {"id": 7, "bbox": [646.79, 198.46, 628.63, 205.85], "category_id": 1}], "caption": "Scheme 4. Preparation of Intermediate 9 from Dinitroaniline ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 229, 331, 259], "ImageBB": [71, 270, 407, 441]}, "reactions": [{"reactants": [1, 3], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [4], "products": [5]}], "diagram_type": "tree"}, {"id": 172, "width": 1352, "height": 1452, "file_name": "op500224x-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [410.0, 803.0, 392.0, 303.0], "category_id": 1}, {"id": 1, "bbox": [4.0, 1167.0, 392.0, 285.0], "category_id": 1}, {"id": 2, "bbox": [989.0, 1083.0, 163.0, 70.0], "category_id": 3}, {"id": 3, "bbox": [572.0, 1095.6, 174.0, 85.4], "category_id": 3}, {"id": 4, "bbox": [225.0, 1086.0, 162.0, 84.5], "category_id": 3}, {"id": 5, "bbox": [45.0, 824.0, 417.0, 271.0], "category_id": 1}, {"id": 6, "bbox": [739.0, 779.0, 582.0, 361.0], "category_id": 1}, {"id": 7, "bbox": [338.0, 1179.0, 396.0, 273.0], "category_id": 1}, {"id": 8, "bbox": [696.0, 1181.0, 319.0, 271.0], "category_id": 1}, {"id": 9, "bbox": [944.0, 1203.0, 408.0, 249.0], "category_id": 1}, {"id": 10, "bbox": [969.0, 347.0, 102.0, 61.0], "category_id": 3}, {"id": 11, "bbox": [710.0, 350.0, 85.0, 56.0], "category_id": 3}, {"id": 12, "bbox": [114.0, 356.0, 61.0, 43.0], "category_id": 3}, {"id": 13, "bbox": [112.0, 722.0, 88.0, 61.0], "category_id": 3}, {"id": 14, "bbox": [1118.0, 727.0, 101.0, 63.0], "category_id": 3}, {"id": 15, "bbox": [613.0, 727.0, 88.0, 65.0], "category_id": 3}, {"id": 16, "bbox": [207.0, 0.0, 76.0, 56.0], "category_id": 3}, {"id": 17, "bbox": [1068.0, 108.0, 224.0, 72.0], "category_id": 2}, {"id": 18, "bbox": [1059.0, 200.0, 219.0, 91.0], "category_id": 2}, {"id": 19, "bbox": [315.0, 124.0, 214.0, 70.0], "category_id": 2}, {"id": 20, "bbox": [304.0, 216.0, 234.0, 100.0], "category_id": 2}, {"id": 21, "bbox": [486.0, 681.0, 327.0, 50.0], "category_id": 2}, {"id": 22, "bbox": [22.0, 0.0, 279.0, 169.0], "category_id": 1}, {"id": 23, "bbox": [1.0, 94.0, 273.0, 256.0], "category_id": 1}, {"id": 24, "bbox": [597.0, 33.0, 313.0, 314.0], "category_id": 1}, {"id": 25, "bbox": [969.0, 60.0, 81.0, 274.0], "category_id": 1}, {"id": 26, "bbox": [26.0, 406.0, 289.0, 303.0], "category_id": 1}, {"id": 27, "bbox": [335.0, 566.0, 124.0, 59.0], "category_id": 1}, {"id": 28, "bbox": [500.0, 429.0, 309.0, 264.0], "category_id": 1}, {"id": 29, "bbox": [983.0, 426.0, 349.0, 312.0], "category_id": 1}], "reactions": [{"reactants": [22, 23], "conditions": [19, 20], "products": [24]}, {"reactants": [24, 25], "conditions": [17, 18], "products": [29]}, {"reactants": [26], "conditions": [27], "products": [28]}], "corefs": [[22, 16], [23, 12], [24, 11], [25, 10], [26, 13], [28, 15], [29, 14], [5, 4], [0, 3], [6, 2]], "caption": "Table 9. Tropane synthesis via azomethine ylides", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 727, 110], "ImageBB": [448, 116, 786, 479]}, "diagram_type": "multiple"}, {"id": 901, "width": 1352, "height": 1536, "file_name": "acs.joc.6b00020-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1042.0, 1008.0, 137.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [640.0, 1011.0, 133.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [0.0, 1072.0, 408.0, 307.0], "category_id": 1}, {"id": 3, "bbox": [406.0, 1071.0, 399.0, 300.0], "category_id": 1}, {"id": 4, "bbox": [887.0, 0.0, 394.0, 286.0], "category_id": 1}, {"id": 5, "bbox": [136.5, 589.2, 152.1, 64.5], "category_id": 3}, {"id": 6, "bbox": [872.0, 696.0, 410.0, 290.0], "category_id": 1}, {"id": 7, "bbox": [408.0, 692.0, 410.0, 303.0], "category_id": 1}, {"id": 8, "bbox": [4.0, 686.0, 391.0, 325.0], "category_id": 1}, {"id": 9, "bbox": [877.0, 313.0, 470.0, 298.0], "category_id": 1}, {"id": 10, "bbox": [410.0, 305.0, 482.0, 317.0], "category_id": 1}, {"id": 11, "bbox": [4.0, 310.0, 374.0, 250.0], "category_id": 1}, {"id": 12, "bbox": [159.0, 260.0, 44.0, 43.0], "category_id": 3}, {"id": 13, "bbox": [1083.0, 265.0, 35.0, 38.0], "category_id": 3}, {"id": 14, "bbox": [550.0, 30.0, 183.0, 52.0], "category_id": 1}, {"id": 15, "bbox": [475.0, 74.0, 343.0, 72.0], "category_id": 2}, {"id": 16, "bbox": [458.0, 174.0, 389.0, 110.0], "category_id": 2}, {"id": 17, "bbox": [19.69, 36.0, 362.0, 217.0], "category_id": 1}, {"id": 18, "bbox": [149.0, 1013.0, 126.0, 45.0], "category_id": 3}, {"id": 19, "bbox": [143.0, 1429.0, 133.0, 51.0], "category_id": 3}, {"id": 20, "bbox": [1065.0, 1427.0, 134.0, 55.0], "category_id": 3}, {"id": 21, "bbox": [545.0, 1414.0, 343.0, 120.0], "category_id": 3}, {"id": 22, "bbox": [631.0, 624.0, 153.0, 60.0], "category_id": 3}, {"id": 23, "bbox": [1024.0, 621.0, 160.0, 61.8], "category_id": 3}, {"id": 24, "bbox": [868.0, 1070.9, 469.0, 346.1], "category_id": 1}], "reactions": [{"reactants": [17], "conditions": [14, 15, 16], "products": [4]}], "corefs": [[17, 12], [4, 13], [11, 5], [10, 22], [9, 23], [8, 18], [7, 1], [6, 0], [2, 19], [3, 21], [24, 20]], "caption": "Table 1. [Co]-Catalyzed [2 + 2 + 2]-Cyclotrimerization Reaction of Diynes 2/2\u2032 with Various Alkynesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 233, 396, 263], "ImageBB": [82, 269, 420, 653]}, "diagram_type": "single"}, {"id": 396, "width": 1704, "height": 1296, "file_name": "op500102h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [495.0, 227.0, 105.9, 47.0], "category_id": 3}, {"id": 1, "bbox": [288.36, 306.0, 1319.0, 737.0], "category_id": 4}, {"id": 2, "bbox": [1248.2, 12.0, 289.1, 210.0], "category_id": 1}, {"id": 3, "bbox": [378.8, 4.0, 319.3, 212.7], "category_id": 1}, {"id": 4, "bbox": [1361.0, 230.0, 94.2, 45.4], "category_id": 3}, {"id": 5, "bbox": [757.0, 9.0, 449.2, 92.2], "category_id": 2}, {"id": 6, "bbox": [756.43, 126.85, 330.08, 105.97], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [5, 6], "products": [2]}], "corefs": [[3, 0], [2, 4]], "caption": "Table 3. Decarboxylation of 3,5-bis(\ufb02uoroalkyl)pyrazoles 5", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 781, 414, 796], "ImageBB": [10, 803, 436, 1127]}, "diagram_type": "single"}, {"id": 836, "width": 1348, "height": 996, "file_name": "jo302142v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [33.0, 568.0, 1284.0, 240.0], "category_id": 4}, {"id": 1, "bbox": [731.0, 0.0, 582.3, 268.0], "category_id": 1}, {"id": 2, "bbox": [734.0, 279.0, 577.0, 269.7], "category_id": 1}, {"id": 3, "bbox": [24.0, 189.0, 352.0, 258.3], "category_id": 1}, {"id": 4, "bbox": [408.0, 187.0, 212.0, 244.3], "category_id": 1}, {"id": 5, "bbox": [8.0, 832.0, 1340.0, 164.0], "category_id": 4}, {"id": 6, "bbox": [43.0, 85.0, 320.0, 73.0], "category_id": 2}, {"id": 7, "bbox": [862.0, 500.0, 91.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [856.0, 231.0, 95.0, 47.0], "category_id": 3}, {"id": 9, "bbox": [439.0, 442.0, 159.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [170.0, 409.0, 65.0, 47.7], "category_id": 3}], "reactions": [{"reactants": [3, 4], "conditions": [], "products": [1, 2]}], "corefs": [[3, 10], [4, 9], [1, 8], [2, 7]], "caption": "Table 1. Aldol Reactions of the (c-Hex)2B Enolate of 1a (R = MOM, Et3Si) with (\u00b1)-5a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 127], "ImageBB": [82, 131, 419, 380]}, "diagram_type": "tree"}, {"id": 375, "width": 1220, "height": 2488, "file_name": "ol101839m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [98.0, 0.0, 152.0, 124.0], "category_id": 1}, {"id": 1, "bbox": [896.7, 5.0, 144.3, 121.0], "category_id": 1}, {"id": 2, "bbox": [119.34, 143.0, 100.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [9.0, 522.0, 1211.0, 1966.0], "category_id": 4}, {"id": 4, "bbox": [926.0, 150.0, 89.7, 46.3], "category_id": 3}, {"id": 5, "bbox": [288.0, 13.0, 491.6, 50.0], "category_id": 2}, {"id": 6, "bbox": [95.0, 207.0, 1033.0, 280.0], "category_id": 4}, {"id": 7, "bbox": [293.26, 76.81, 336.85, 50.03], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [3, 7], "products": [1]}], "corefs": [[0, 2], [1, 4]], "caption": "Table 1. The Oxidation of a Variety of Secondary Alcohols with Hydrogen Peroxide Promoted by 3a ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 156, 369, 183], "ImageBB": [74, 192, 379, 814]}, "diagram_type": "single"}, {"id": 979, "width": 1352, "height": 828, "file_name": "ja064212t-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1094.99, 71.05, 234.01, 213.14], "category_id": 1}, {"id": 1, "bbox": [454.5, 758.51, 62.22, 55.49], "category_id": 3}, {"id": 2, "bbox": [734.5, 525.07, 230.63, 215.85], "category_id": 1}, {"id": 3, "bbox": [960.1, 441.2, 95.5, 60.8], "category_id": 2}, {"id": 4, "bbox": [966.6, 18.3, 94.1, 59.4], "category_id": 2}, {"id": 5, "bbox": [251.3, 16.3, 100.0, 62.5], "category_id": 2}, {"id": 6, "bbox": [389.57, 495.98, 223.87, 242.91], "category_id": 1}, {"id": 7, "bbox": [454.5, 333.58, 60.87, 54.81], "category_id": 3}, {"id": 8, "bbox": [252.3, 445.0, 97.3, 56.4], "category_id": 2}, {"id": 9, "bbox": [1094.99, 495.3, 232.66, 209.76], "category_id": 1}, {"id": 10, "bbox": [1193.06, 332.91, 58.84, 54.8], "category_id": 3}, {"id": 11, "bbox": [100.1, 757.84, 59.52, 56.16], "category_id": 3}, {"id": 12, "bbox": [1164.65, 758.51, 61.55, 55.49], "category_id": 3}, {"id": 13, "bbox": [100.1, 334.94, 58.16, 52.77], "category_id": 3}, {"id": 14, "bbox": [31.11, 495.3, 222.52, 243.59], "category_id": 1}, {"id": 15, "bbox": [734.5, 117.74, 231.99, 197.57], "category_id": 1}, {"id": 16, "bbox": [31.11, 71.72, 228.6, 244.95], "category_id": 1}, {"id": 17, "bbox": [389.57, 71.72, 231.98, 245.62], "category_id": 1}, {"id": 18, "bbox": [835.28, 334.94, 59.52, 52.1], "category_id": 3}, {"id": 19, "bbox": [805.52, 757.16, 65.6, 58.19], "category_id": 3}], "caption": "Scheme 2. Schematic Description of the (R) and (\u03b2) Conformers in Phospha(III)guanidines (X ) Lone Pair, Chalcogen) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 765, 88], "ImageBB": [439, 92, 777, 299]}, "reactions": [{"reactants": [16], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [16]}, {"reactants": [15], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [15]}, {"reactants": [14], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [14]}, {"reactants": [2], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [2]}], "diagram_type": "graph"}, {"id": 974, "width": 888, "height": 520, "file_name": "ja052327b-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [727.64, 4.0, 100.83, 148.29], "category_id": 1}, {"id": 1, "bbox": [710.76, 429.33, 33.31, 42.18], "category_id": 3}, {"id": 2, "bbox": [741.41, 407.58, 137.26, 80.36], "category_id": 1}, {"id": 3, "bbox": [375.81, 388.04, 255.43, 129.2], "category_id": 1}, {"id": 4, "bbox": [490.87, 179.81, 185.24, 96.35], "category_id": 1}, {"id": 5, "bbox": [782.72, 143.41, 105.28, 151.84], "category_id": 1}, {"id": 6, "bbox": [213.67, 150.96, 189.24, 139.41], "category_id": 1}, {"id": 7, "bbox": [2.67, 426.67, 227.44, 84.36], "category_id": 1}, {"id": 8, "bbox": [681.06, 275.04, 30.14, 37.5], "category_id": 2}], "caption": "Scheme 4. Postulated Mechanisms for the Formation of Methylcyclopentane and Methylenecyclopentane ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 257, 358, 281], "ImageBB": [131, 285, 353, 415]}, "reactions": [{"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [3]}, {"reactants": [7], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [4], "products": [0, 5]}, {"reactants": [3], "conditions": [8], "products": [2]}], "diagram_type": "graph"}, {"id": 177, "width": 1272, "height": 700, "file_name": "op0602270-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [436.0, 369.0, 400.0, 54.0], "category_id": 2}, {"id": 1, "bbox": [420.0, 29.0, 400.0, 50.0], "category_id": 2}, {"id": 2, "bbox": [956.0, 352.0, 311.0, 215.0], "category_id": 1}, {"id": 3, "bbox": [941.0, 7.0, 310.0, 217.0], "category_id": 1}, {"id": 4, "bbox": [3.0, 9.0, 312.0, 218.0], "category_id": 1}, {"id": 5, "bbox": [13.0, 349.0, 230.0, 310.0], "category_id": 1}, {"id": 6, "bbox": [368.0, 491.0, 569.0, 52.0], "category_id": 2}, {"id": 7, "bbox": [379.0, 147.0, 518.0, 48.0], "category_id": 2}, {"id": 8, "bbox": [998.0, 246.0, 260.0, 90.0], "category_id": 3}, {"id": 9, "bbox": [287.0, 602.0, 216.0, 88.0], "category_id": 3}, {"id": 10, "bbox": [995.0, 606.0, 261.0, 89.0], "category_id": 3}, {"id": 11, "bbox": [95.0, 248.0, 218.0, 83.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1, 7], "products": [3]}, {"reactants": [5], "conditions": [0, 6], "products": [2]}], "corefs": [[4, 11], [3, 8], [5, 9], [2, 10]], "caption": "Table 2. Influence of ester group on conversion and enantioselectivity ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 726, 81], "ImageBB": [449, 89, 767, 264]}, "diagram_type": "multiple"}, {"id": 315, "width": 1352, "height": 1832, "file_name": "ol3023903-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [863.0, 215.8, 134.6, 131.2], "category_id": 1}, {"id": 1, "bbox": [625.0, 396.7, 326.9, 204.3], "category_id": 1}, {"id": 2, "bbox": [1028.4, 443.4, 280.2, 233.6], "category_id": 1}, {"id": 3, "bbox": [0.0, 1094.7, 515.0, 279.3], "category_id": 1}, {"id": 4, "bbox": [27.6, 452.8, 546.8, 229.3], "category_id": 1}, {"id": 5, "bbox": [375.1, 156.7, 187.5, 191.2], "category_id": 1}, {"id": 6, "bbox": [521.0, 681.8, 454.0, 301.1], "category_id": 1}, {"id": 7, "bbox": [22.0, 760.9, 466.0, 225.1], "category_id": 1}, {"id": 8, "bbox": [973.0, 801.4, 365.6, 255.6], "category_id": 1}, {"id": 9, "bbox": [912.1, 1148.0, 351.9, 211.0], "category_id": 1}, {"id": 10, "bbox": [588.0, 1257.2, 268.6, 217.8], "category_id": 1}, {"id": 11, "bbox": [586.0, 289.1, 219.0, 67.9], "category_id": 2}, {"id": 12, "bbox": [1033.0, 1058.0, 241.0, 40.0], "category_id": 3}, {"id": 13, "bbox": [123.0, 1298.0, 148.0, 79.0], "category_id": 3}, {"id": 14, "bbox": [1032.0, 687.0, 283.0, 39.0], "category_id": 3}, {"id": 15, "bbox": [238.0, 663.0, 278.0, 42.0], "category_id": 3}, {"id": 16, "bbox": [664.0, 904.0, 118.0, 83.0], "category_id": 3}, {"id": 17, "bbox": [88.0, 984.0, 310.0, 45.0], "category_id": 3}, {"id": 18, "bbox": [971.0, 1313.0, 154.0, 68.0], "category_id": 3}, {"id": 19, "bbox": [731.0, 1434.0, 123.0, 76.0], "category_id": 3}, {"id": 20, "bbox": [477.0, 1137.0, 132.0, 76.0], "category_id": 3}, {"id": 21, "bbox": [721.0, 554.0, 146.0, 79.0], "category_id": 3}, {"id": 22, "bbox": [907.0, 351.0, 37.0, 31.0], "category_id": 3}, {"id": 23, "bbox": [607.0, 172.0, 166.0, 92.0], "category_id": 1}, {"id": 24, "bbox": [6.0, 1505.0, 1346.0, 327.0], "category_id": 2}, {"id": 25, "bbox": [451.0, 1003.0, 395.0, 225.0], "category_id": 1}, {"id": 26, "bbox": [401.0, 353.0, 27.0, 26.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [23, 11], "products": [0]}], "corefs": [[5, 26], [0, 22], [4, 15], [1, 21], [2, 14], [7, 17], [6, 16], [8, 12], [3, 13], [25, 20], [10, 19], [9, 18]], "caption": "Figure 3. 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Stereocontrolled Preparation of Clopidogrel Metabolite Thioacetate Intermediates", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 562, 613, 577], "ImageBB": [10, 594, 859, 1127]}, "reactions": [{"reactants": [39], "conditions": [8], "products": [10]}, {"reactants": [10], "conditions": [7, 54], "products": [6]}, {"reactants": [10], "conditions": [5, 24], "products": [49]}, {"reactants": [10], "conditions": [5, 56], "products": [11]}, {"reactants": [6], "conditions": [33], "products": [49]}, {"reactants": [11], "conditions": [40, 46], "products": [48]}, {"reactants": [49], "conditions": [1, 53], "products": [51]}, {"reactants": [48], "conditions": [19, 38], "products": [20]}, {"reactants": [51], "conditions": [52, 17], "products": [27]}, {"reactants": [20], "conditions": [35], "products": [45, 9]}, {"reactants": [27], "conditions": [21], "products": [50]}, {"reactants": [45], "conditions": [23, 31], "products": [26]}, {"reactants": [45, 9], "conditions": [3], "products": [25]}, {"reactants": [50], "conditions": [22, 0], "products": [44]}], "diagram_type": "tree"}, {"id": 983, "width": 900, "height": 1220, "file_name": "ja107927b-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [728.97, 373.51, 130.65, 62.86], "category_id": 2}, {"id": 1, "bbox": [653.88, 234.97, 93.41, 46.38], "category_id": 3}, {"id": 2, "bbox": [700.89, 812.93, 153.24, 115.34], "category_id": 2}, {"id": 3, "bbox": [507.96, 0.0, 379.14, 264.87], "category_id": 1}, {"id": 4, "bbox": [434.09, 346.04, 150.19, 63.47], "category_id": 2}, {"id": 5, "bbox": [357.16, 595.05, 122.11, 53.09], "category_id": 2}, {"id": 6, "bbox": [699.06, 1176.06, 35.41, 43.94], "category_id": 3}, {"id": 7, "bbox": [354.11, 388.15, 75.7, 59.2], "category_id": 2}, {"id": 8, "bbox": [187.43, 327.73, 103.79, 115.35], "category_id": 1}, {"id": 9, "bbox": [353.5, 683.54, 141.64, 55.54], "category_id": 2}, {"id": 10, "bbox": [158.13, 734.2, 40.9, 45.77], "category_id": 3}, {"id": 11, "bbox": [533.6, 498.01, 366.32, 268.53], "category_id": 1}, {"id": 12, "bbox": [185.6, 234.36, 39.69, 49.43], "category_id": 3}, {"id": 13, "bbox": [97.68, 350.93, 71.44, 58.58], "category_id": 2}, {"id": 14, "bbox": [686.23, 729.92, 45.18, 48.83], "category_id": 3}, {"id": 15, "bbox": [34.8, 7.93, 280.84, 261.21], "category_id": 1}, {"id": 16, "bbox": [536.66, 936.82, 320.52, 261.21], "category_id": 1}, {"id": 17, "bbox": [4.27, 500.45, 294.89, 264.26], "category_id": 1}], "caption": "Scheme 2. Reactions of 1 with Acetonitrile", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 282, 637, 294], "ImageBB": [481, 297, 706, 602]}, "reactions": [{"reactants": [15], "conditions": [13, 8], "products": [17]}, {"reactants": [17], "conditions": [5, 9], "products": [11]}, {"reactants": [11], "conditions": [2], "products": [16]}, {"reactants": [15], "conditions": [4, 7], "products": [11]}, {"reactants": [11], "conditions": [0], "products": [3]}], "diagram_type": "graph"}, {"id": 557, "width": 1352, "height": 2396, "file_name": "acs.orglett.5b02003-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [858.0, 2043.0, 323.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [521.0, 2339.0, 361.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [1114.0, 633.0, 31.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [464.0, 631.0, 64.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [191.0, 631.0, 39.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [27.0, 1093.0, 356.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [514.0, 1732.0, 361.0, 56.0], "category_id": 3}, {"id": 7, "bbox": [27.0, 1727.0, 348.0, 62.0], "category_id": 3}, {"id": 8, "bbox": [29.0, 2339.0, 342.0, 49.0], "category_id": 3}, {"id": 9, "bbox": [622.0, 511.0, 308.0, 44.0], "category_id": 3}, {"id": 10, "bbox": [519.0, 1090.0, 346.0, 58.0], "category_id": 3}, {"id": 11, "bbox": [974.0, 1088.0, 356.0, 60.0], "category_id": 3}, {"id": 12, "bbox": [712.0, 565.0, 128.0, 48.0], "category_id": 3}, {"id": 13, "bbox": [175.0, 1402.0, 346.0, 54.0], "category_id": 3}, {"id": 14, "bbox": [179.0, 2043.0, 315.0, 65.0], "category_id": 3}, {"id": 15, "bbox": [983.0, 2337.0, 353.0, 55.0], "category_id": 3}, {"id": 16, "bbox": [849.0, 1413.0, 349.0, 49.0], "category_id": 3}, {"id": 17, "bbox": [995.0, 1730.0, 337.0, 57.0], "category_id": 3}, {"id": 18, "bbox": [385.0, 481.0, 233.0, 159.1], "category_id": 1}, {"id": 19, "bbox": [925.0, 449.0, 353.0, 226.1], "category_id": 1}, {"id": 20, "bbox": [121.0, 1792.0, 433.0, 264.0], "category_id": 1}, {"id": 21, "bbox": [29.0, 437.0, 344.0, 210.2], "category_id": 1}, {"id": 22, "bbox": [930.0, 804.0, 411.0, 268.0], "category_id": 1}, {"id": 23, "bbox": [775.0, 1787.0, 441.0, 247.0], "category_id": 1}, {"id": 24, "bbox": [7.0, 2081.0, 441.0, 272.0], "category_id": 1}, {"id": 25, "bbox": [903.0, 2096.0, 448.0, 257.0], "category_id": 1}, {"id": 26, "bbox": [11.0, 1457.0, 420.0, 268.0], "category_id": 1}, {"id": 27, "bbox": [468.0, 1460.0, 418.0, 260.0], "category_id": 1}, {"id": 28, "bbox": [912.0, 1460.0, 420.0, 262.0], "category_id": 1}, {"id": 29, "bbox": [501.0, 327.0, 77.0, 44.0], "category_id": 2}, {"id": 30, "bbox": [498.0, 277.0, 75.0, 44.0], "category_id": 2}, {"id": 31, "bbox": [516.0, 136.0, 78.0, 43.0], "category_id": 2}, {"id": 32, "bbox": [522.0, 85.0, 66.0, 43.0], "category_id": 2}, {"id": 33, "bbox": [465.0, 2106.0, 427.0, 237.0], "category_id": 1}, {"id": 34, "bbox": [8.0, 772.0, 349.0, 312.0], "category_id": 1}, {"id": 35, "bbox": [472.0, 804.0, 395.0, 263.0], "category_id": 1}, {"id": 36, "bbox": [958.0, 255.0, 365.0, 182.0], "category_id": 1}, {"id": 37, "bbox": [1017.0, 24.0, 308.0, 194.0], "category_id": 1}, {"id": 38, "bbox": [17.0, 7.0, 223.0, 180.0], "category_id": 1}, {"id": 39, "bbox": [20.0, 236.0, 272.0, 155.0], "category_id": 1}, {"id": 40, "bbox": [327.0, 235.0, 153.0, 170.0], "category_id": 1}, {"id": 41, "bbox": [317.0, 41.0, 149.0, 176.0], "category_id": 1}, {"id": 42, "bbox": [588.0, 240.0, 360.0, 209.0], "category_id": 1}, {"id": 43, "bbox": [759.0, 1143.0, 466.0, 268.0], "category_id": 1}, {"id": 44, "bbox": [110.0, 1152.0, 448.0, 255.0], "category_id": 1}, {"id": 45, "bbox": [671.0, 9.0, 291.0, 240.0], "category_id": 1}], "reactions": [{"reactants": [38, 41], "conditions": [32, 31], "products": [45, 37]}, {"reactants": [39, 40], "conditions": [30, 29], "products": [42, 36]}, {"reactants": [21, 18], "conditions": [9, 12], "products": [19]}], "corefs": [[21, 4], [18, 3], [19, 2], [34, 5], [35, 10], [22, 11], [44, 13], [43, 16], [26, 7], [27, 6], [28, 17], [20, 14], [23, 0], [24, 8], [33, 1], [25, 15]], "caption": "Table 3. Scope of Phthalazinium Dicyanomethanidesa,b", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 396, 110], "ImageBB": [82, 116, 420, 715]}, "diagram_type": "multiple"}, {"id": 1041, "width": 1340, "height": 1472, "file_name": "jo010170+-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [151.01, 956.5, 189.49, 83.99], "category_id": 3}, {"id": 1, "bbox": [67.04, 1136.22, 396.31, 195.87], "category_id": 1}, {"id": 2, "bbox": [1015.1, 939.61, 53.04, 39.02], "category_id": 3}, {"id": 3, "bbox": [873.67, 1130.33, 344.01, 195.13], "category_id": 1}, {"id": 4, "bbox": [278.45, 282.77, 48.62, 36.08], "category_id": 2}, {"id": 5, "bbox": [0.0, 0.0, 508.29, 236.37], "category_id": 1}, {"id": 6, "bbox": [0.0, 360.08, 529.65, 194.41], "category_id": 1}, {"id": 7, "bbox": [1015.1, 554.49, 53.04, 40.5], "category_id": 3}, {"id": 8, "bbox": [102.39, 1341.66, 292.45, 130.34], "category_id": 3}, {"id": 9, "bbox": [771.27, 315.9, 535.55, 260.68], "category_id": 1}, {"id": 10, "bbox": [230.57, 207.66, 50.83, 42.71], "category_id": 3}, {"id": 11, "bbox": [1015.1, 1343.87, 53.04, 39.77], "category_id": 3}, {"id": 12, "bbox": [232.04, 560.38, 50.83, 36.81], "category_id": 3}, {"id": 13, "bbox": [36.1, 686.3, 453.04, 251.83], "category_id": 1}, {"id": 14, "bbox": [819.89, 672.3, 446.41, 248.9], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 318, 270, 332], "ImageBB": [75, 337, 410, 705]}, "reactions": [{"reactants": [5], "conditions": [4], "products": [6]}, {"reactants": [6], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [], "products": [1]}, {"reactants": [14], "conditions": [], "products": [3]}], "diagram_type": "tree"}, {"id": 414, "width": 2820, "height": 1632, "file_name": "op400269b-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1780.0, 1342.0, 264.0, 77.0], "category_id": 2}, {"id": 1, "bbox": [1853.0, 1268.0, 119.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [1538.0, 441.0, 820.0, 551.0], "category_id": 1}, {"id": 3, "bbox": [552.0, 520.0, 753.0, 407.0], "category_id": 1}, {"id": 4, "bbox": [463.0, 988.0, 869.0, 336.0], "category_id": 1}, {"id": 5, "bbox": [1466.0, 964.0, 855.0, 360.0], "category_id": 1}, {"id": 6, "bbox": [2335.44, 118.02, 122.51, 61.48], "category_id": 3}, {"id": 7, "bbox": [1106.0, 1351.0, 445.0, 277.0], "category_id": 1}, {"id": 8, "bbox": [1248.0, 63.0, 303.0, 70.0], "category_id": 2}, {"id": 9, "bbox": [1284.0, 162.0, 195.0, 51.0], "category_id": 2}, {"id": 10, "bbox": [1934.0, 340.0, 135.0, 41.0], "category_id": 3}, {"id": 11, "bbox": [1010.0, 337.0, 48.0, 50.0], "category_id": 3}, {"id": 12, "bbox": [495.0, 337.0, 108.0, 47.0], "category_id": 3}, {"id": 13, "bbox": [1286.0, 1589.0, 55.0, 32.0], "category_id": 3}, {"id": 14, "bbox": [882.0, 1269.0, 46.0, 46.0], "category_id": 3}, {"id": 15, "bbox": [881.0, 870.0, 49.0, 40.0], "category_id": 3}, {"id": 16, "bbox": [1870.0, 870.0, 54.0, 58.0], "category_id": 3}, {"id": 17, "bbox": [1534.0, 3.0, 772.0, 286.9], "category_id": 1}, {"id": 18, "bbox": [769.75, 17.38, 511.25, 254.72], "category_id": 1}, {"id": 19, "bbox": [361.0, 7.3, 366.0, 269.7], "category_id": 1}], "reactions": [{"reactants": [19, 18], "conditions": [8, 9], "products": [17, 6]}], "corefs": [[19, 12], [18, 11], [17, 10], [3, 15], [2, 16], [4, 14], [5, 1], [7, 13]], "caption": "Figure 2. Impurities derived from CDMT-mediated coupling of 2 and 4.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 533, 437, 547], "ImageBB": [82, 116, 787, 524]}, "diagram_type": "single"}, {"id": 184, "width": 1356, "height": 812, "file_name": "op060175e-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [120.0, 599.0, 205.8, 92.3], "category_id": 2}, {"id": 1, "bbox": [864.0, 287.0, 435.6, 91.2], "category_id": 2}, {"id": 2, "bbox": [3.0, 183.0, 472.0, 344.0], "category_id": 1}, {"id": 3, "bbox": [531.0, 146.0, 190.0, 66.0], "category_id": 2}, {"id": 4, "bbox": [534.0, 551.0, 208.0, 72.0], "category_id": 2}, {"id": 5, "bbox": [962.0, 201.0, 143.0, 51.0], "category_id": 2}, {"id": 6, "bbox": [1001.0, 615.0, 163.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [921.0, 718.0, 432.0, 94.0], "category_id": 2}, {"id": 8, "bbox": [600.0, 0.0, 481.0, 345.0], "category_id": 1}, {"id": 9, "bbox": [670.0, 428.0, 479.0, 354.0], "category_id": 1}, {"id": 10, "bbox": [192.0, 527.0, 87.0, 54.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [3], "products": [8, 5]}, {"reactants": [2], "conditions": [4], "products": [9, 6]}], "corefs": [[2, 10]], "caption": "Figure 2. Resolution of 1a and 4 with both antipodes of DPTTA. a: Yields were calculated relative to the theoretical amount, which is half of the starting racemate. 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Synthesis of Borylated Isocoumarins and 2-Pyrones via the Oxyboration Reactiona,b ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 413, 125], "ImageBB": [84, 131, 417, 436]}, "diagram_type": "single"}, {"id": 1096, "width": 1352, "height": 1584, "file_name": "jo961323+-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [690.03, 992.87, 68.13, 47.55], "category_id": 3}, {"id": 1, "bbox": [690.03, 1500.8, 71.3, 46.75], "category_id": 3}, {"id": 2, "bbox": [128.34, 1058.64, 342.25, 462.76], "category_id": 1}, {"id": 3, "bbox": [6.62, 1.86, 287.18, 568.57], "category_id": 1}, {"id": 4, "bbox": [965.0, 3.77, 374.61, 433.55], "category_id": 1}, {"id": 5, "bbox": [42.75, 564.73, 346.08, 437.35], "category_id": 1}, {"id": 6, "bbox": [476.3, 570.43, 346.09, 433.56], "category_id": 1}, {"id": 7, "bbox": [995.43, 566.63, 336.58, 454.47], "category_id": 1}, {"id": 8, "bbox": [1014.45, 1068.64, 273.82, 418.34], "category_id": 1}, {"id": 9, "bbox": [272.84, 298.51, 81.76, 53.24], "category_id": 2}, {"id": 10, "bbox": [761.54, 279.49, 83.67, 49.44], "category_id": 2}, {"id": 11, "bbox": [883.24, 726.36, 51.34, 51.34], "category_id": 2}, {"id": 12, "bbox": [21.83, 1241.68, 43.74, 47.54], "category_id": 2}, {"id": 13, "bbox": [61.76, 435.42, 72.26, 53.24], "category_id": 3}, {"id": 14, "bbox": [668.36, 433.52, 66.56, 53.24], "category_id": 3}, {"id": 15, "bbox": [1157.06, 431.62, 79.87, 53.24], "category_id": 3}, {"id": 16, "bbox": [250.02, 990.68, 74.16, 51.34], "category_id": 3}, {"id": 17, "bbox": [1132.34, 992.58, 76.06, 47.54], "category_id": 3}, {"id": 18, "bbox": [217.69, 1502.2, 79.87, 55.14], "category_id": 3}, {"id": 19, "bbox": [1065.79, 1500.29, 163.53, 55.15], "category_id": 3}, {"id": 20, "bbox": [417.36, 230.05, 45.63, 49.44], "category_id": 2}, {"id": 21, "bbox": [480.88, 7.13, 379.48, 438.2], "category_id": 1}, {"id": 22, "bbox": [826.3, 1242.48, 119.62, 46.75], "category_id": 2}, {"id": 23, "bbox": [463.46, 1244.85, 45.94, 44.38], "category_id": 2}, {"id": 24, "bbox": [885.71, 236.13, 35.65, 45.17], "category_id": 2}, {"id": 25, "bbox": [535.55, 1058.64, 282.03, 382.73], "category_id": 1}, {"id": 26, "bbox": [463.46, 425.52, 43.57, 45.16], "category_id": 2}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [206, 49, 275, 63], "ImageBB": [73, 70, 411, 466]}, "reactions": [{"reactants": [3], "conditions": [20], "products": [21]}, {"reactants": [21], "conditions": [24], "products": [4]}, {"reactants": [21], "conditions": [26], "products": [6]}, {"reactants": [6], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [12], "products": [2]}, {"reactants": [2], "conditions": [23], "products": [25]}, {"reactants": [25], "conditions": [22], "products": [8]}], "diagram_type": "tree"}, {"id": 270, "width": 1352, "height": 932, "file_name": "ol801035c-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [77.0, 541.0, 227.0, 178.0], "category_id": 1}, {"id": 1, "bbox": [909.0, 706.0, 309.0, 177.0], "category_id": 1}, {"id": 2, "bbox": [399.0, 596.0, 201.0, 46.0], "category_id": 2}, {"id": 3, "bbox": [318.0, 667.0, 387.0, 123.0], "category_id": 2}, {"id": 4, "bbox": [247.0, 742.0, 33.0, 37.0], "category_id": 3}, {"id": 5, "bbox": [827.0, 742.0, 29.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [1225.0, 744.0, 26.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [1139.0, 863.0, 35.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [1052.0, 541.0, 219.0, 178.0], "category_id": 1}, {"id": 9, "bbox": [679.0, 541.0, 294.0, 176.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [9, 8, 1]}], "corefs": [[0, 4], [9, 5], [8, 6], [1, 7]], "caption": "Figure 1. 4-Thiazolylcarboxylic esters are units of the heterocyclic core in the d series of thiopeptide antibiotics exemplified by sulfomycinamte and micrococcinate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 285, 394, 327], "ImageBB": [425, 132, 763, 365]}, "diagram_type": "single"}, {"id": 134, "width": 1352, "height": 1008, "file_name": "op800270e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [816.0, 218.0, 71.0, 71.0], "category_id": 3}, {"id": 1, "bbox": [213.0, 218.0, 57.0, 60.0], "category_id": 3}, {"id": 2, "bbox": [15.0, 326.0, 1328.0, 670.0], "category_id": 4}, {"id": 3, "bbox": [1284.0, 222.0, 68.0, 63.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 4.0, 356.0, 317.9], "category_id": 1}, {"id": 5, "bbox": [598.8, 6.0, 355.2, 314.7], "category_id": 1}, {"id": 6, "bbox": [928.0, 3.0, 399.3, 311.0], "category_id": 1}, {"id": 7, "bbox": [367.0, 26.5, 216.7, 91.5], "category_id": 2}, {"id": 8, "bbox": [396.0, 124.0, 154.0, 54.5], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [7, 8], "products": [5, 6]}], "corefs": [[4, 1], [5, 0], [6, 3]], "caption": "Table 1. Effect of base and solvent on enolization selectivity of 9 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 388, 73], "ImageBB": [58, 88, 396, 340]}, "diagram_type": "single"}, {"id": 548, "width": 1348, "height": 360, "file_name": "acs.orglett.5b03589-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [708.57, 202.92, 29.49, 39.65], "category_id": 3}, {"id": 1, "bbox": [1115.21, 211.05, 46.76, 41.68], "category_id": 3}, {"id": 2, "bbox": [554.0, 72.1, 245.0, 146.5], "category_id": 1}, {"id": 3, "bbox": [198.25, 62.12, 31.51, 36.6], "category_id": 3}, {"id": 4, "bbox": [144.37, 145.48, 210.43, 114.88], "category_id": 1}, {"id": 5, "bbox": [339.5, 109.0, 153.5, 36.0], "category_id": 2}, {"id": 6, "bbox": [816.4, 107.9, 182.6, 37.1], "category_id": 2}, {"id": 7, "bbox": [252.12, 174.96, 32.53, 36.6], "category_id": 3}, {"id": 8, "bbox": [141.0, 6.0, 205.9, 117.7], "category_id": 1}, {"id": 9, "bbox": [1020.1, 58.1, 187.9, 147.2], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [5], "products": [2]}, {"reactants": [2], "conditions": [6], "products": [9]}], "corefs": [[8, 3], [4, 7], [2, 0], [9, 1]], "caption": "Table 1. 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Conditions Optimization", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 617, 100], "ImageBB": [436, 112, 773, 375]}, "diagram_type": "single"}, {"id": 1231, "width": 1324, "height": 900, "file_name": "op0101106-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [504.7, 847.23, 52.32, 50.35], "category_id": 3}, {"id": 1, "bbox": [28.48, 577.63, 239.76, 72.2], "category_id": 2}, {"id": 2, "bbox": [1036.55, 370.29, 49.01, 53.66], "category_id": 3}, {"id": 3, "bbox": [28.48, 688.25, 225.86, 66.91], "category_id": 2}, {"id": 4, "bbox": [88.75, 370.29, 48.35, 55.64], "category_id": 3}, {"id": 5, "bbox": [742.47, 2.65, 127.17, 88.76], "category_id": 2}, {"id": 6, "bbox": [947.8, 2.65, 376.2, 372.28], "category_id": 1}, {"id": 7, "bbox": [0.0, 15.9, 236.45, 311.33], "category_id": 1}, {"id": 8, "bbox": [291.43, 231.18, 150.34, 62.93], "category_id": 2}, {"id": 9, "bbox": [429.85, 24.51, 419.26, 373.6], "category_id": 1}, {"id": 10, "bbox": [520.59, 385.53, 48.35, 49.02], "category_id": 3}, {"id": 11, "bbox": [423.89, 473.63, 641.8, 366.98], "category_id": 1}], "caption": "Scheme 1. 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Periodate-coupled chromogenic assay principle for esterase/lipase activity. C2-CLIPS-O (2-hydroxy-4-(p-nitrophe- noxy)butylacetate (1)), C3-CLIPS-O (2-hydroxy-4-(p-nitrophe- noxy)butylpropionate (2)), C10-CLIPS-O (2-hydroxy-4-(p- nitrophenoxy)butyldecanoate (3)) and C16-CLIPS-O 2-hydroxy- 4-(p-nitrophenoxy)butylpalmitate (4)). 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Tetrahydropyridines generated via kinetic iminiums from carbon electrophile addition and subsequent reduction ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 800]}, "diagram_type": "single"}, {"id": 32, "width": 1176, "height": 1376, "file_name": "ja511913h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.06, 29.9, 199.07, 101.43], "category_id": 1}, {"id": 1, "bbox": [275.28, 3.27, 158.24, 156.47], "category_id": 1}, {"id": 2, "bbox": [518.52, 122.23, 275.42, 74.79], "category_id": 2}, {"id": 3, "bbox": [41.0, 170.09, 150.11, 31.71], "category_id": 2}, {"id": 4, "bbox": [274.5, 168.43, 158.45, 31.69], "category_id": 2}, {"id": 5, "bbox": [901.62, 166.76, 253.52, 40.03], "category_id": 2}, {"id": 6, "bbox": [506.09, 6.82, 298.5, 85.45], "category_id": 2}, {"id": 7, "bbox": [910.9, 3.27, 232.81, 154.69], "category_id": 1}, {"id": 8, "bbox": [1.85, 232.31, 1168.49, 1136.53], "category_id": 4}], "reactions": [{"reactants": [0, 1], "conditions": [6, 2], "products": [7]}], "corefs": [[0, 3], [1, 4], [7, 5]], "caption": "Table 2. Decarboxylative Ole\ufb01nation: Vinyl Halide Scopea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 407, 111], "ImageBB": [104, 116, 398, 460]}, "diagram_type": "single"}, {"id": 347, "width": 2712, "height": 2348, "file_name": "ol2017998-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1383.0, 150.0, 280.0, 77.4], "category_id": 2}, {"id": 1, "bbox": [551.7, 21.6, 350.7, 238.3], "category_id": 1}, {"id": 2, "bbox": [978.0, 46.6, 250.1, 162.7], "category_id": 1}, {"id": 3, "bbox": [1007.0, 257.0, 202.0, 54.7], "category_id": 2}, {"id": 4, "bbox": [644.1, 205.0, 154.9, 52.0], "category_id": 3}, {"id": 5, "bbox": [1828.3, 2.0, 336.9, 209.0], "category_id": 1}, {"id": 6, "bbox": [19.0, 370.6, 2693.0, 1977.4], "category_id": 4}, {"id": 7, "bbox": [1238.0, 2.0, 578.0, 116.0], "category_id": 2}, {"id": 8, "bbox": [1987.0, 208.0, 54.0, 52.0], "category_id": 3}, {"id": 9, "bbox": [1077.0, 213.0, 63.0, 44.0], "category_id": 3}, {"id": 10, "bbox": [614.0, 251.0, 217.0, 58.0], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [7, 0], "products": [5]}], "corefs": [[1, 4], [2, 9], [5, 8]], "caption": "Table 3. Preparative Palladium-Catalyzed Allylations of Substituted Aromatic Bromides Using (Z)-1b and 3a", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 651, 101], "ImageBB": [83, 112, 761, 699]}, "diagram_type": "single"}, {"id": 668, "width": 1352, "height": 2176, "file_name": "ol401909z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1028.0, 223.0, 61.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [609.0, 68.0, 189.0, 52.0], "category_id": 2}, {"id": 2, "bbox": [35.0, 305.0, 1317.0, 1871.0], "category_id": 4}, {"id": 3, "bbox": [479.0, 166.0, 29.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [864.6, 0.0, 403.0, 248.0], "category_id": 1}, {"id": 5, "bbox": [87.0, 4.0, 248.8, 244.0], "category_id": 1}, {"id": 6, "bbox": [399.8, 52.0, 168.2, 114.8], "category_id": 1}, {"id": 7, "bbox": [565.0, 130.6, 274.0, 46.6], "category_id": 2}], "reactions": [{"reactants": [5, 6], "conditions": [1, 7], "products": [4]}], "corefs": [[6, 3], [4, 0]], "caption": "Table 2. Substrate Scope of Cu-Catalyzed Synthesis of Fulleroimidazole from C60 and Amidinesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 361, 116], "ImageBB": [71, 126, 409, 670]}, "diagram_type": "single"}, {"id": 1211, "width": 1352, "height": 864, "file_name": "ol801034x-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1038.18, 299.57, 52.75, 56.12], "category_id": 3}, {"id": 1, "bbox": [1100.4, 744.52, 46.67, 55.45], "category_id": 3}, {"id": 2, "bbox": [1205.91, 342.17, 131.89, 68.98], "category_id": 2}, {"id": 3, "bbox": [32.46, 54.77, 303.68, 221.13], "category_id": 1}, {"id": 4, "bbox": [144.06, 744.52, 45.99, 55.45], "category_id": 3}, {"id": 5, "bbox": [915.76, 2.7, 351.7, 280.64], "category_id": 1}, {"id": 6, "bbox": [4.06, 502.44, 353.72, 164.32], "category_id": 1}, {"id": 7, "bbox": [105.51, 290.1, 41.93, 52.07], "category_id": 3}, {"id": 8, "bbox": [504.55, 290.1, 47.34, 59.51], "category_id": 3}, {"id": 9, "bbox": [657.4, 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"category_id": 1}], "reactions": [{"reactants": [1], "conditions": [3, 2], "products": [5]}], "corefs": [[1, 0], [5, 4]], "caption": "Figure 1 shows the 1H and 13C NMR spectra of germanium", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [438, 993, 760, 1008], "ImageBB": [450, 922, 737, 983]}, "diagram_type": "single"}, {"id": 981, "width": 1356, "height": 492, "file_name": "ja076333e-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [379.87, 42.7, 192.65, 46.1], "category_id": 2}, {"id": 1, "bbox": [417.18, 105.75, 107.18, 43.38], "category_id": 2}, {"id": 2, "bbox": [69.87, 156.58, 153.98, 44.07], "category_id": 3}, {"id": 3, "bbox": [627.46, 2.71, 437.53, 181.67], "category_id": 1}, {"id": 4, "bbox": [513.5, 385.02, 141.78, 46.77], "category_id": 2}, {"id": 5, "bbox": [0.0, 4.07, 338.49, 157.26], "category_id": 1}, {"id": 6, "bbox": [497.22, 258.94, 146.52, 96.93], "category_id": 1}, {"id": 7, "bbox": [721.07, 252.84, 634.93, 185.05], 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Synthesis of Lys-NTA-SH", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 274, 76], "ImageBB": [73, 80, 412, 203]}, "reactions": [{"reactants": [5], "conditions": [0, 1], "products": [3]}, {"reactants": [3], "conditions": [10, 12], "products": [8]}, {"reactants": [8], "conditions": [6, 4], "products": [7]}], "diagram_type": "multiple"}, {"id": 763, "width": 1384, "height": 1620, "file_name": "jo961824v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1081.0, 1516.0, 27.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [88.0, 308.0, 285.0, 214.0], "category_id": 1}, {"id": 2, "bbox": [852.0, 498.0, 132.0, 46.0], "category_id": 2}, {"id": 3, "bbox": [856.0, 417.0, 528.0, 48.0], "category_id": 2}, {"id": 4, "bbox": [573.0, 244.0, 232.0, 427.0], "category_id": 1}, {"id": 5, "bbox": [94.0, 892.0, 470.0, 552.0], "category_id": 1}, {"id": 6, "bbox": [878.0, 895.0, 469.0, 555.0], "category_id": 1}, {"id": 7, "bbox": [668.0, 1202.0, 91.0, 42.0], "category_id": 2}, {"id": 8, "bbox": [681.0, 1112.0, 65.0, 54.0], "category_id": 2}, {"id": 9, "bbox": [610.0, 694.0, 436.0, 149.0], "category_id": 3}, {"id": 10, "bbox": [128.0, 723.0, 417.9, 93.7], "category_id": 3}, {"id": 11, "bbox": [219.0, 1476.3, 396.3, 141.7], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [3, 2], "products": [5]}, {"reactants": [5], "conditions": [8, 7], "products": [6]}], "corefs": [[1, 10], [4, 9], [5, 11], [6, 0]], "caption": " Table 1. BF3-Promoted Addition Reaction of 1,2-Naphthoquinones with 1,1-Diarylethylenesa ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [469, 437, 743, 462], "ImageBB": [424, 20, 770, 425]}, "diagram_type": "multiple"}, {"id": 22, "width": 1352, "height": 1080, "file_name": "ja905415r-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [431.53, 84.4, 251.45, 105.12], "category_id": 2}, {"id": 1, "bbox": [990.35, 31.45, 279.31, 258.41], "category_id": 1}, {"id": 2, "bbox": [710.24, 4.97, 254.23, 291.86], "category_id": 1}, {"id": 3, "bbox": [76.18, 59.32, 336.45, 234.72], "category_id": 1}, {"id": 4, "bbox": [2.32, 321.3, 1343.99, 753.13], "category_id": 4}, {"id": 5, "bbox": [1178.47, 265.56, 56.35, 42.41], "category_id": 3}, {"id": 6, "bbox": [306.11, 266.96, 54.96, 41.01], "category_id": 3}, {"id": 7, "bbox": [431.53, 204.25, 248.66, 49.38], "category_id": 2}, {"id": 8, "bbox": [863.53, 271.14, 53.56, 42.41], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0, 7], "products": [2, 1]}], "corefs": [[3, 6], [2, 8], [1, 5]], "caption": "Table 5. Comparison of the enantioselectivities of 2a and 3a, isolated from the reaction of 1a using different Au catalysts.a ", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 365, 81], "ImageBB": [58, 89, 396, 359]}, "diagram_type": "single"}, {"id": 402, "width": 1704, "height": 1124, "file_name": "op400278d-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [65.1, 18.1, 217.7, 175.9], "category_id": 1}, {"id": 1, "bbox": [611.0, 121.0, 333.0, 101.0], "category_id": 2}, {"id": 2, "bbox": [609.0, 0.0, 345.0, 96.0], "category_id": 2}, {"id": 3, "bbox": [981.0, 0.0, 427.0, 221.0], "category_id": 1}, {"id": 4, "bbox": [603.0, 764.0, 298.0, 76.0], "category_id": 3}, {"id": 5, "bbox": [180.0, 762.0, 265.0, 82.0], "category_id": 3}, {"id": 6, "bbox": [83.0, 199.0, 197.0, 92.0], "category_id": 3}, {"id": 7, "bbox": [332.0, 203.0, 189.0, 90.0], "category_id": 3}, {"id": 8, "bbox": [1176.0, 203.0, 68.0, 47.0], "category_id": 3}, {"id": 9, "bbox": [532.45, 311.04, 429.55, 413.96], "category_id": 1}, {"id": 10, "bbox": [82.5, 308.5, 429.5, 432.0], "category_id": 1}, {"id": 11, "bbox": [1113.97, 760.0, 161.0, 59.0], "category_id": 3}, {"id": 12, "bbox": [979.47, 313.07, 430.93, 407.43], "category_id": 1}, {"id": 13, "bbox": [309.51, 12.09, 248.61, 191.35], "category_id": 1}], "reactions": [{"reactants": [0, 13], "conditions": [2, 1], "products": [3]}], "corefs": [[0, 6], [13, 7], [3, 8], [10, 5], [9, 4], [12, 11]], "caption": "Table 9. Pyridine optimization of the IPentCl-Pd-based pre- catalysts in room temperature aryl aminations ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 797, 782, 830], "ImageBB": [433, 846, 859, 1127]}, "diagram_type": "single"}, {"id": 911, "width": 2820, "height": 3452, "file_name": "acs.joc.5b00301-Figure-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [210.0, 1965.0, 2365.7, 1487.0], "category_id": 4}, {"id": 1, "bbox": [345.6, 1049.1, 177.4, 133.6], "category_id": 1}, {"id": 2, "bbox": [1953.0, 1196.0, 136.0, 62.0], "category_id": 2}, {"id": 3, "bbox": [2143.0, 1182.0, 111.0, 88.0], "category_id": 2}, {"id": 4, "bbox": [417.0, 1626.0, 128.0, 83.0], "category_id": 2}, {"id": 5, "bbox": [896.0, 1626.0, 136.0, 85.0], "category_id": 2}, {"id": 6, "bbox": [762.0, 1173.0, 120.0, 88.0], "category_id": 2}, {"id": 7, "bbox": [1811.7, 110.4, 163.5, 127.7], "category_id": 1}, {"id": 8, "bbox": [1966.4, 343.1, 273.3, 272.7], "category_id": 1}, {"id": 9, "bbox": [1240.4, 0.0, 319.8, 183.1], "category_id": 1}, {"id": 10, "bbox": [563.0, 1176.0, 134.0, 80.0], "category_id": 2}, {"id": 11, "bbox": [1818.0, 1632.0, 120.0, 73.5], "category_id": 2}, {"id": 12, "bbox": [2271.0, 1636.8, 131.2, 69.2], "category_id": 2}, {"id": 13, "bbox": [583.4, 347.0, 268.8, 263.1], "category_id": 1}, {"id": 14, "bbox": [254.42, 1769.15, 247.65, 181.21], "category_id": 1}, {"id": 15, "bbox": [932.96, 1769.15, 235.57, 183.23], "category_id": 1}, {"id": 16, "bbox": [1647.74, 1767.14, 237.59, 185.24], "category_id": 1}, {"id": 17, "bbox": [2328.29, 1767.14, 221.48, 183.22], "category_id": 1}, {"id": 18, "bbox": [579.4, 783.0, 278.5, 272.3], "category_id": 1}, {"id": 19, "bbox": [932.0, 1048.0, 161.9, 133.2], "category_id": 1}, {"id": 20, "bbox": [1969.2, 785.0, 266.5, 269.5], "category_id": 1}, {"id": 21, "bbox": [2320.8, 1054.2, 153.8, 129.8], "category_id": 1}, {"id": 22, "bbox": [1726.4, 1056.0, 174.8, 123.5], "category_id": 1}, {"id": 23, "bbox": [893.22, 1308.92, 331.28, 266.3], "category_id": 1}, {"id": 24, "bbox": [215.0, 1305.5, 335.9, 271.2], "category_id": 1}, {"id": 25, "bbox": [1597.8, 1308.1, 328.0, 267.8], "category_id": 1}, {"id": 26, "bbox": [2274.7, 1310.7, 323.9, 267.5], "category_id": 1}, {"id": 27, "bbox": [847.2, 111.0, 178.5, 129.5], "category_id": 1}], "reactions": [{"reactants": [14], "conditions": [], "products": [24]}, {"reactants": [24], "conditions": [], "products": [14]}, {"reactants": [15], "conditions": [], "products": [23]}, {"reactants": [23], "conditions": [], "products": [15]}, {"reactants": [24], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [1], "products": [24]}, {"reactants": [23], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [19], "products": [23]}, {"reactants": [18], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [18]}, {"reactants": [13], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [27], "products": [13]}, {"reactants": [9], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [7], "products": [9]}, {"reactants": [8], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [], "products": [8]}, {"reactants": [20], "conditions": [22], "products": [25]}, {"reactants": [25], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [21], "products": [26]}, {"reactants": [26], "conditions": [], "products": [20]}, {"reactants": [25], "conditions": [], "products": [16]}, {"reactants": [16], "conditions": [], "products": [25]}, {"reactants": [26], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [26]}], "corefs": [], "caption": "Figure 8. Overlaid benzoin reaction coordinates: pyrrolidinone-based triazolium (I\u2032).", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 988, 487, 1002], "ImageBB": [82, 116, 787, 979]}, "diagram_type": "tree"}, {"id": 887, "width": 1356, "height": 796, "file_name": "ol5029892-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1142.03, 249.92, 66.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [731.2, 56.0, 289.8, 100.7], "category_id": 2}, {"id": 2, "bbox": [159.0, 245.0, 64.9, 51.9], "category_id": 3}, {"id": 3, "bbox": [404.3, 109.0, 233.8, 107.9], "category_id": 1}, {"id": 4, "bbox": [765.0, 323.0, 217.0, 50.0], "category_id": 2}, {"id": 5, "bbox": [1105.1, 5.1, 145.7, 227.9], "category_id": 1}, {"id": 6, "bbox": [494.0, 248.9, 57.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [105.2, 104.4, 171.8, 126.4], "category_id": 1}, {"id": 8, "bbox": [726.2, 181.0, 287.8, 137.9], "category_id": 1}, {"id": 9, "bbox": [34.0, 396.0, 1288.0, 379.0], "category_id": 4}], "reactions": [{"reactants": [7, 3], "conditions": [1, 8], "products": [5]}], "corefs": [[7, 2], [3, 6], [5, 0]], "caption": "Table 3. Reactivity of Benzylic Grignard Reagent with O- Benzoyl-N-hydroxypiperidine ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 773, 125], "ImageBB": [448, 131, 787, 330]}, "diagram_type": "single"}, {"id": 1020, "width": 2820, "height": 1624, "file_name": "jacs.5b07904-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [983.26, 761.44, 237.0, 249.58], "category_id": 1}, {"id": 1, "bbox": [2420.77, 954.62, 196.09, 188.95], "category_id": 1}, {"id": 2, "bbox": [538.89, 342.65, 173.52, 181.9], "category_id": 1}, {"id": 3, "bbox": [313.18, 349.7, 166.46, 149.47], "category_id": 1}, {"id": 4, "bbox": [766.01, 851.69, 136.84, 60.63], "category_id": 2}, {"id": 5, "bbox": [403.46, 1198.56, 253.93, 256.64], "category_id": 1}, {"id": 6, "bbox": [909.9, 1294.45, 162.24, 142.42], "category_id": 1}, {"id": 7, "bbox": [1083.42, 38.07, 179.16, 194.59], "category_id": 1}, {"id": 8, "bbox": [1763.38, 650.04, 258.16, 249.59], "category_id": 1}, {"id": 9, "bbox": [2413.72, 305.99, 203.14, 197.41], "category_id": 1}, {"id": 10, "bbox": [2018.72, 1238.05, 232.77, 249.58], "category_id": 1}, {"id": 11, "bbox": [1596.92, 153.7, 93.11, 47.94], "category_id": 2}, {"id": 12, "bbox": [1591.28, 1403.02, 102.98, 43.72], "category_id": 2}, {"id": 13, "bbox": [2011.67, 259.45, 239.82, 93.07], "category_id": 2}, {"id": 14, "bbox": [2413.72, 1173.18, 229.94, 56.41], "category_id": 2}, {"id": 15, "bbox": [1763.38, 0.0, 239.82, 252.4], "category_id": 1}, {"id": 16, "bbox": [2011.67, 0.0, 244.05, 252.4], "category_id": 1}, {"id": 17, "bbox": [2011.67, 0.0, 245.46, 249.58], "category_id": 1}, {"id": 18, "bbox": [1297.24, 45.25, 180.77, 185.03], "category_id": 1}, {"id": 19, "bbox": [2028.8, 655.62, 244.59, 240.31], "category_id": 1}, {"id": 20, "bbox": [1994.8, 1493.53, 233.93, 89.33], "category_id": 2}, {"id": 21, "bbox": [730.75, 917.96, 213.01, 43.71], "category_id": 2}, {"id": 22, "bbox": [1340.8, 1280.35, 179.94, 188.95], "category_id": 1}, {"id": 23, "bbox": [1113.2, 1491.86, 206.1, 94.47], "category_id": 2}, {"id": 24, "bbox": [2011.7, 450.1, 166.43, 130.85], "category_id": 2}, {"id": 25, "bbox": [1733.76, 1496.09, 234.94, 90.24], "category_id": 2}, {"id": 26, "bbox": [2412.31, 542.88, 236.99, 52.17], "category_id": 2}, {"id": 27, "bbox": [1231.5, 1128.4, 112.9, 115.29], "category_id": 2}, {"id": 28, "bbox": [876.59, 57.4, 156.11, 139.3], "category_id": 1}, {"id": 29, "bbox": [2011.67, 1039.23, 170.93, 137.97], "category_id": 2}, {"id": 30, "bbox": [1223.08, 1011.02, 242.64, 87.43], "category_id": 2}, {"id": 31, "bbox": [1733.76, 259.45, 258.16, 93.07], "category_id": 2}, {"id": 32, "bbox": [952.23, 1012.43, 244.05, 81.79], "category_id": 2}, {"id": 33, "bbox": [1125.8, 1278.94, 181.92, 190.36], "category_id": 1}, {"id": 34, "bbox": [517.0, 573.5, 115.0, 120.26], "category_id": 2}, {"id": 35, "bbox": [536.07, 139.6, 124.14, 111.39], "category_id": 2}, {"id": 36, "bbox": [1248.47, 760.03, 231.36, 250.99], "category_id": 1}, {"id": 37, "bbox": [1591.28, 1338.16, 114.26, 53.58], "category_id": 2}, {"id": 38, "bbox": [399.23, 764.26, 248.28, 256.63], "category_id": 1}, {"id": 39, "bbox": [1760.56, 1233.82, 237.0, 253.81], "category_id": 1}, {"id": 40, "bbox": [1338.76, 1490.45, 204.55, 91.65], "category_id": 2}, {"id": 41, "bbox": [1578.58, 84.6, 126.96, 60.64], "category_id": 2}, {"id": 42, "bbox": [580.54, 196.25, 131.86, 99.95], "category_id": 2}], "caption": "Scheme 2. Enantioselectively Competing Reaction Pathways Involving Kinetic Resolution ((S)-Pathway) and Chiral Catalysis ((R)-Pathway) for the (S)-Pr-Mediated Asymmetric Hydrogenation of IP on Supported Pd Catalyst ", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 784, 125], "ImageBB": [82, 131, 787, 537]}, "reactions": [{"reactants": [3, 2], "conditions": [35, 42], "products": [28, 7, 18]}, {"reactants": [28, 7, 18], "conditions": [41], "products": [15, 17]}, {"reactants": [15, 17], "conditions": [11], "products": [28, 7, 18]}, {"reactants": [15, 17], "conditions": [24], "products": [8, 19]}, {"reactants": [38], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [38]}, {"reactants": [38], "conditions": [], "products": [3, 2]}, {"reactants": [3, 2], "conditions": [34], "products": [38]}, {"reactants": [38], "conditions": [4, 21], "products": [0, 36]}, {"reactants": [0, 36], "conditions": [27], "products": [6, 33, 32]}, {"reactants": [6, 33, 32], "conditions": [], "products": [0, 36]}, {"reactants": [6, 33, 32], "conditions": [37], "products": [39, 10]}, {"reactants": [39, 10], "conditions": [12], "products": [6, 33, 32]}, {"reactants": [39, 10], "conditions": [29], "products": [8, 19]}], "diagram_type": "graph"}, {"id": 730, "width": 1348, "height": 644, "file_name": "ol016212y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [930.0, 281.0, 321.0, 43.0], "category_id": 2}, {"id": 1, "bbox": [1.0, 352.0, 1347.0, 292.0], "category_id": 4}, {"id": 2, "bbox": [406.0, 92.0, 377.0, 51.0], "category_id": 2}, {"id": 3, "bbox": [442.0, 169.0, 357.0, 94.0], "category_id": 2}, {"id": 4, "bbox": [101.2, 5.0, 266.6, 230.8], "category_id": 1}, {"id": 5, "bbox": [920.0, 6.0, 313.8, 237.0], "category_id": 1}, {"id": 6, "bbox": [107.5, 277.0, 340.5, 55.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [2, 3], "products": [5]}], "corefs": [], "caption": "Table 4. Titanium-Mediated Addition of Et2Zn to PhCHO Using P2 and 2 ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 748, 104], "ImageBB": [439, 107, 776, 268]}, "diagram_type": "single"}, {"id": 358, "width": 1348, "height": 3576, "file_name": "ol200038n-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [298.0, 688.0, 279.5, 101.0], "category_id": 2}, {"id": 1, "bbox": [300.0, 549.0, 352.8, 96.0], "category_id": 2}, {"id": 2, "bbox": [463.0, 420.0, 330.0, 77.0], "category_id": 1}, {"id": 3, "bbox": [298.0, 805.0, 290.5, 58.0], "category_id": 2}, {"id": 4, "bbox": [623.0, 1633.0, 146.4, 40.0], "category_id": 3}, {"id": 5, "bbox": [2.0, 2136.0, 1346.0, 614.0], "category_id": 2}, {"id": 6, "bbox": [760.0, 1683.0, 407.0, 281.0], "category_id": 1}, {"id": 7, "bbox": [81.0, 1690.0, 628.0, 292.0], "category_id": 1}, {"id": 8, "bbox": [886.0, 1332.0, 411.0, 278.0], "category_id": 1}, {"id": 9, "bbox": [482.0, 1328.0, 399.0, 275.0], "category_id": 1}, {"id": 10, "bbox": [49.0, 1256.0, 430.0, 420.0], "category_id": 1}, {"id": 11, "bbox": [699.0, 964.0, 412.0, 275.0], "category_id": 1}, {"id": 12, "bbox": [211.0, 962.0, 412.0, 282.0], "category_id": 1}, {"id": 13, "bbox": [827.0, 900.0, 35.0, 35.0], "category_id": 3}, {"id": 14, "bbox": [607.0, 637.0, 393.0, 263.0], "category_id": 1}, {"id": 15, "bbox": [800.0, 420.0, 51.0, 56.0], "category_id": 3}, {"id": 16, "bbox": [1070.0, 642.0, 35.0, 50.0], "category_id": 3}, {"id": 17, "bbox": [882.0, 344.0, 372.0, 322.0], "category_id": 1}, {"id": 18, "bbox": [291.0, 427.0, 231.0, 94.0], "category_id": 2}, {"id": 19, "bbox": [293.0, 329.0, 449.0, 93.0], "category_id": 2}, {"id": 20, "bbox": [2.0, 113.0, 1282.0, 175.0], "category_id": 2}, {"id": 21, "bbox": [940.0, 1967.0, 147.8, 51.0], "category_id": 3}, {"id": 22, "bbox": [1034.79, 1633.59, 143.6, 40.0], "category_id": 3}, {"id": 23, "bbox": [276.0, 2962.0, 802.0, 608.0], "category_id": 1}, {"id": 24, "bbox": [89.0, 514.0, 182.0, 51.0], "category_id": 2}, {"id": 25, "bbox": [845.0, 1254.0, 151.6, 44.0], "category_id": 3}, {"id": 26, "bbox": [274.0, 1632.0, 144.2, 40.0], "category_id": 3}, {"id": 27, "bbox": [489.0, 1964.0, 139.9, 55.0], "category_id": 3}, {"id": 28, "bbox": [419.0, 1256.0, 148.6, 44.0], "category_id": 3}], "reactions": [{"reactants": [24], "conditions": [19, 18, 2, 1], "products": [17]}, {"reactants": [17], "conditions": [0, 3], "products": [14]}], "corefs": [[2, 15], [17, 16], [14, 13], [12, 28], [11, 25], [10, 26], [9, 4], [8, 22], [7, 27], [6, 21]], "caption": "Figure 1. Single-crystal X-ray structure of 2a. Hydrogen atoms are omitted for clarity except polar N-H bonds. Selected bond lengths (A\u030a): N1-C1 1.390(2), N1-C6 1.363(2), N2-N3 1.350(2), N2-C4 1.372(2), N3-C5 1.327(2), N4-N2 1.438(2). ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 966, 771, 1021], "ImageBB": [436, 59, 773, 953]}, "diagram_type": "multiple"}, {"id": 1245, "width": 1248, "height": 1400, "file_name": "op0300488-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [972.31, 619.81, 130.3, 70.74], "category_id": 2}, {"id": 1, "bbox": [695.61, 49.72, 526.08, 314.46], "category_id": 1}, {"id": 2, "bbox": [491.06, 82.64, 125.39, 62.33], "category_id": 2}, {"id": 3, "bbox": [63.75, 586.19, 198.24, 84.05], "category_id": 1}, {"id": 4, "bbox": [179.33, 301.15, 45.53, 46.92], "category_id": 3}, {"id": 5, "bbox": [941.49, 1354.48, 56.74, 45.52], "category_id": 3}, {"id": 6, "bbox": [727.13, 1071.54, 481.25, 284.34], "category_id": 1}, {"id": 7, "bbox": [305.42, 552.58, 562.51, 310.95], "category_id": 1}, {"id": 8, "bbox": [0.0, 11.21, 442.02, 233.21], "category_id": 1}, {"id": 9, "bbox": [32.22, 1055.43, 535.9, 233.21], "category_id": 1}, {"id": 10, "bbox": [253.59, 1310.36, 65.14, 47.62], "category_id": 3}], "caption": "Scheme 1. Allylation of \u03b2-D-glucose pentaacetate 2 using ZnCl2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 284, 392, 313], "ImageBB": [86, 316, 398, 666]}, "reactions": [{"reactants": [8], "conditions": [2], "products": [1]}, {"reactants": [1], "conditions": [3], "products": [7]}, {"reactants": [7], "conditions": [0], "products": [9, 6]}], "diagram_type": "multiple"}, {"id": 1158, "width": 1352, "height": 416, "file_name": "ol052113z-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [746.68, 296.7, 195.82, 62.9], "category_id": 2}, {"id": 1, "bbox": [144.78, 101.45, 81.57, 54.04], "category_id": 2}, {"id": 2, "bbox": [261.02, 96.35, 174.35, 60.16], "category_id": 2}, {"id": 3, "bbox": [524.08, 100.43, 267.14, 67.3], "category_id": 2}, {"id": 4, "bbox": [89.73, 4.59, 137.64, 57.1], "category_id": 2}, {"id": 5, "bbox": [268.16, 7.65, 101.96, 55.06], "category_id": 2}, {"id": 6, "bbox": [450.67, 3.57, 186.58, 65.25], "category_id": 2}, {"id": 7, "bbox": [684.16, 10.71, 151.92, 59.13], "category_id": 2}, {"id": 8, "bbox": [932.94, 7.65, 214.12, 64.23], "category_id": 2}, {"id": 9, "bbox": [1190.9, 15.8, 79.53, 47.93], "category_id": 2}, {"id": 10, "bbox": [384.39, 1.53, 54.04, 30.59], "category_id": 2}, {"id": 11, "bbox": [666.82, 190.16, 53.02, 29.57], "category_id": 2}, {"id": 12, "bbox": [1087.92, 192.2, 139.69, 60.15], "category_id": 2}, {"id": 13, "bbox": [968.63, 194.24, 76.47, 59.13], "category_id": 2}, {"id": 14, "bbox": [736.16, 193.22, 188.62, 59.13], "category_id": 2}, {"id": 15, "bbox": [425.18, 190.16, 219.21, 67.29], "category_id": 2}, {"id": 16, "bbox": [981.88, 305.37, 91.77, 50.98], "category_id": 2}, {"id": 17, "bbox": [480.24, 299.25, 172.31, 58.12], "category_id": 2}, {"id": 18, "bbox": [865.71, 96.08, 355.76, 69.69], "category_id": 2}, {"id": 19, "bbox": [140.0, 187.42, 248.0, 71.04], "category_id": 2}, {"id": 20, "bbox": [327.35, 306.2, 107.75, 57.81], "category_id": 2}], "caption": "Scheme 5. Possible Single-Electron-Transfer Pathway", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [462, 75, 751, 88], "ImageBB": [439, 93, 777, 197]}, "reactions": [{"reactants": [4, 5], "conditions": [10], "products": [6, 7]}, {"reactants": [6, 7], "conditions": [], "products": [4, 5]}, {"reactants": [6, 7], "conditions": [], "products": [8, 9]}, {"reactants": [8, 9], "conditions": [], "products": [6, 7]}, {"reactants": [1, 2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [1, 2]}, {"reactants": [3], "conditions": [], "products": [18]}, {"reactants": [19, 15], "conditions": [11], "products": [14, 13, 12]}, {"reactants": [20, 17], "conditions": [], "products": [0, 16]}], "diagram_type": "multiple"}, {"id": 712, "width": 1348, "height": 1088, "file_name": "ol034469l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [592.0, 147.0, 326.0, 71.0], "category_id": 2}, {"id": 1, "bbox": [932.0, 18.0, 228.0, 189.0], "category_id": 1}, {"id": 2, "bbox": [193.0, 63.0, 378.0, 143.0], "category_id": 1}, {"id": 3, "bbox": [1018.0, 201.0, 75.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [346.0, 201.0, 72.0, 60.0], "category_id": 3}, {"id": 5, "bbox": [633.0, 0.0, 249.0, 144.0], "category_id": 2}, {"id": 6, "bbox": [2.0, 280.0, 1342.0, 808.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [5, 0], "products": [1]}], "corefs": [[2, 4], [1, 3]], "caption": "Table 1. Screen of Solvents and Br\u00f8nsted Acids", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 314, 698, 327], "ImageBB": [439, 331, 776, 603]}, "diagram_type": "single"}, {"id": 176, "width": 1336, "height": 880, "file_name": "op0602270-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 232.0, 559.0, 181.7], "category_id": 3}, {"id": 1, "bbox": [734.0, 225.72, 602.0, 189.18], "category_id": 3}, {"id": 2, "bbox": [826.0, 778.0, 455.0, 88.0], "category_id": 3}, {"id": 3, "bbox": [31.0, 785.0, 403.0, 88.6], "category_id": 3}, {"id": 4, "bbox": [412.0, 502.0, 393.0, 60.0], "category_id": 2}, {"id": 5, "bbox": [307.0, 607.0, 543.0, 60.0], "category_id": 2}, {"id": 6, "bbox": [394.0, 16.0, 399.0, 64.0], "category_id": 2}, {"id": 7, "bbox": [362.0, 122.0, 495.0, 62.0], "category_id": 2}, {"id": 8, "bbox": [13.0, 481.0, 249.0, 300.0], "category_id": 1}, {"id": 9, "bbox": [869.0, 488.0, 337.0, 218.0], "category_id": 1}, {"id": 10, "bbox": [4.0, 1.0, 340.0, 216.0], "category_id": 1}, {"id": 11, "bbox": [863.0, 0.0, 355.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [6, 7], "products": [11]}, {"reactants": [8], "conditions": [4, 5], "products": [9]}], "corefs": [[10, 0], [11, 1], [8, 3], [9, 2]], "caption": "Table 3. Influence of \u03b23-substitution on conversion and enantioselectivity ", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 377, 81], "ImageBB": [75, 89, 409, 309]}, "diagram_type": "multiple"}, {"id": 1138, "width": 1352, "height": 668, "file_name": "ol010283f-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [630.35, 469.78, 179.9, 46.64], "category_id": 2}, {"id": 1, "bbox": [630.35, 537.37, 171.11, 44.61], "category_id": 2}, {"id": 2, "bbox": [71.69, 10.82, 250.25, 250.77], "category_id": 1}, {"id": 3, "bbox": [1094.99, 138.57, 166.38, 40.55], "category_id": 2}, {"id": 4, "bbox": [375.37, 65.57, 257.01, 65.56], "category_id": 2}, {"id": 5, "bbox": [142.71, 406.24, 399.04, 199.4], "category_id": 1}, {"id": 6, "bbox": [1095.67, 54.75, 162.32, 79.76], "category_id": 2}, {"id": 7, "bbox": [462.62, 156.82, 79.13, 44.61], "category_id": 2}, {"id": 8, "bbox": [872.48, 458.29, 333.43, 146.68], "category_id": 1}, {"id": 9, "bbox": [698.66, 0.0, 274.59, 273.76], "category_id": 1}], "caption": "Scheme 2. Proposed Mechanism", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [517, 75, 698, 88], "ImageBB": [439, 94, 777, 261]}, "reactions": [{"reactants": [2], "conditions": [4, 7], "products": [9]}, {"reactants": [9], "conditions": [6, 3], "products": [5]}, {"reactants": [5], "conditions": [0, 1], "products": [8]}], "diagram_type": "multiple"}, {"id": 1069, "width": 1356, "height": 520, "file_name": "jo400501k-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [408.36, 0.0, 217.07, 166.25], "category_id": 1}, {"id": 1, "bbox": [1136.22, 289.07, 215.71, 188.65], "category_id": 1}, {"id": 2, "bbox": [1160.64, 2.71, 187.22, 171.01], "category_id": 1}, {"id": 3, "bbox": [4.07, 21.04, 230.64, 143.85], "category_id": 1}, {"id": 4, "bbox": [1138.25, 189.32, 80.73, 69.9], "category_id": 2}, {"id": 5, "bbox": [790.94, 0.0, 191.97, 181.86], "category_id": 1}, {"id": 6, "bbox": [255.06, 43.43, 122.1, 52.25], "category_id": 2}, {"id": 7, "bbox": [1010.05, 100.43, 105.82, 47.5], "category_id": 2}, {"id": 8, "bbox": [996.48, 32.57, 122.78, 50.22], "category_id": 2}, {"id": 9, "bbox": [619.32, 32.57, 135.67, 55.65], "category_id": 2}], "caption": "Scheme 6. Mechanism of the Diamine Synthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 636, 721, 651], "ImageBB": [448, 657, 787, 787]}, "reactions": [{"reactants": [3], "conditions": [6], "products": [0]}, {"reactants": [0], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [8, 7], "products": [2]}, {"reactants": [2], "conditions": [4], "products": [1]}], "diagram_type": "tree"}], "roles": [{"id": 1, "name": "reactants"}, {"id": 2, "name": "conditions"}, {"id": 3, "name": "products"}]}