dev4.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 686, "width": 1476, "height": 2472, "file_name": "ol4012794-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [111.0, 2226.0, 1365.0, 169.0], "category_id": 2}, {"id": 1, "bbox": [1097.0, 12.0, 330.0, 214.0], "category_id": 1}, {"id": 2, "bbox": [701.0, 114.0, 311.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [1200.0, 234.0, 38.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [244.0, 232.0, 43.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [111.0, 1896.0, 1365.0, 271.0], "category_id": 2}, {"id": 6, "bbox": [666.13, 0.0, 397.5, 84.0], "category_id": 2}, {"id": 7, "bbox": [534.0, 175.6, 45.2, 41.4], "category_id": 3}, {"id": 8, "bbox": [456.2, 70.0, 202.8, 77.6], "category_id": 1}, {"id": 9, "bbox": [174.0, 22.3, 218.7, 205.7], "category_id": 1}, {"id": 10, "bbox": [119.0, 375.7, 1357.0, 1478.3], "category_id": 4}], "reactions": [{"reactants": [9, 8], "conditions": [6, 2], "products": [1]}], "corefs": [[9, 4], [8, 7], [1, 3]], "caption": "Table 2. Reaction of Phenylphosphine Oxides 4 with Acrylates 5a", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 417, 771, 433], "ImageBB": [404, 444, 773, 1062]}, "diagram_type": "single"}, {"id": 1120, "width": 1348, "height": 2096, "file_name": "jo9906328-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1235.58, 1820.24, 53.5, 47.18], "category_id": 3}, {"id": 1, "bbox": [740.51, 163.57, 47.2, 39.84], "category_id": 2}, {"id": 2, "bbox": [95.45, 1756.28, 38.81, 46.13], "category_id": 2}, {"id": 3, "bbox": [168.87, 1498.34, 44.05, 44.04], "category_id": 3}, {"id": 4, "bbox": [281.1, 1711.19, 578.98, 321.9], "category_id": 1}, {"id": 5, "bbox": [170.97, 633.31, 61.88, 52.42], "category_id": 3}, {"id": 6, "bbox": [353.47, 868.18, 433.19, 204.46], "category_id": 1}, {"id": 7, "bbox": [0.0, 430.94, 437.38, 204.47], "category_id": 1}, {"id": 8, "bbox": [0.0, 1297.02, 442.63, 197.13], "category_id": 1}, {"id": 9, "bbox": [699.6, 0.0, 167.2, 117.43], "category_id": 1}, {"id": 10, "bbox": [554.8, 1230.97, 217.18, 169.03], "category_id": 1}, {"id": 11, "bbox": [775.12, 436.19, 420.6, 197.12], "category_id": 1}, {"id": 12, "bbox": [526.54, 1050.62, 45.1, 47.18], "category_id": 3}, {"id": 13, "bbox": [120.43, 883.09, 32.71, 52.84], "category_id": 2}, {"id": 14, "bbox": [226.11, 893.16, 37.74, 37.74], "category_id": 2}, {"id": 15, "bbox": [505.41, 1338.53, 37.74, 40.26], "category_id": 2}, {"id": 16, "bbox": [671.48, 1237.88, 35.23, 42.77], "category_id": 3}, {"id": 17, "bbox": [860.08, 45.09, 47.2, 52.42], "category_id": 3}, {"id": 18, "bbox": [860.08, 877.61, 40.91, 52.43], "category_id": 2}, {"id": 19, "bbox": [1055.17, 1808.7, 53.93, 55.58], "category_id": 3}, {"id": 20, "bbox": [504.51, 699.37, 96.5, 61.86], "category_id": 2}, {"id": 21, "bbox": [217.12, 22.02, 354.52, 195.02], "category_id": 1}, {"id": 22, "bbox": [483.53, 2045.67, 110.14, 46.14], "category_id": 3}, {"id": 23, "bbox": [1006.93, 630.16, 70.27, 51.38], "category_id": 3}, {"id": 24, "bbox": [773.03, 1249.84, 571.64, 282.05], "category_id": 1}, {"id": 25, "bbox": [906.23, 1756.28, 26.23, 44.04], "category_id": 2}, {"id": 26, "bbox": [1126.5, 1488.9, 102.79, 52.43], "category_id": 3}, {"id": 27, "bbox": [403.82, 372.23, 454.17, 56.62], "category_id": 2}, {"id": 28, "bbox": [350.33, 223.34, 39.85, 45.08], "category_id": 3}], "caption": "Scheme 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 63, 276, 77], "ImageBB": [74, 84, 411, 608]}, "reactions": [{"reactants": [21, 9], "conditions": [], "products": [7, 11]}, {"reactants": [11], "conditions": [20], "products": [7]}, {"reactants": [11], "conditions": [18], "products": [6]}, {"reactants": [6], "conditions": [14], "products": [7]}, {"reactants": [7], "conditions": [13], "products": [8]}, {"reactants": [8, 10], "conditions": [15], "products": [24]}, {"reactants": [24], "conditions": [2], "products": [4]}, {"reactants": [4], "conditions": [25], "products": [19, 0]}], "diagram_type": "graph"}, {"id": 422, "width": 1352, "height": 1340, "file_name": "op300331b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1088.0, 654.0, 59.0, 58.0], "category_id": 3}, {"id": 1, "bbox": [44.0, 0.0, 412.0, 244.0], "category_id": 1}, {"id": 2, "bbox": [53.0, 367.0, 513.0, 241.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 734.0, 1349.0, 569.0], "category_id": 4}, {"id": 4, "bbox": [377.0, 146.0, 558.0, 138.0], "category_id": 2}, {"id": 5, "bbox": [456.0, 48.0, 363.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [679.0, 657.0, 64.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [517.0, 376.0, 482.0, 241.0], "category_id": 1}, {"id": 8, "bbox": [966.0, 367.0, 336.0, 244.0], "category_id": 1}, {"id": 9, "bbox": [157.0, 272.0, 55.0, 55.0], "category_id": 3}, {"id": 10, "bbox": [215.0, 657.0, 61.0, 50.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [5, 4], "products": [2, 7, 8]}], "corefs": [[1, 9], [2, 10], [7, 6], [8, 0]], "caption": "Table 2. Screening of reaction conditions for carbonylation of 17 ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 589, 417, 619], "ImageBB": [82, 626, 420, 961]}, "diagram_type": "multiple"}, {"id": 953, "width": 1352, "height": 1392, "file_name": "acs.orglett.6b00661-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [469.92, 497.89, 390.68, 55.31], "category_id": 3}, {"id": 1, "bbox": [63.35, 1085.61, 286.13, 70.33], "category_id": 2}, {"id": 2, "bbox": [970.48, 471.43, 349.49, 428.95], "category_id": 1}, {"id": 3, "bbox": [472.01, 395.53, 388.47, 98.18], "category_id": 1}, {"id": 4, "bbox": [735.87, 16.71, 191.45, 293.16], "category_id": 1}, {"id": 5, "bbox": [36.9, 15.32, 216.51, 296.64], "category_id": 1}, {"id": 6, "bbox": [103.04, 306.39, 77.97, 63.37], "category_id": 3}, {"id": 7, "bbox": [299.36, 184.53, 327.21, 107.94], "category_id": 2}, {"id": 8, "bbox": [991.37, 79.38, 249.93, 64.76], "category_id": 2}, {"id": 9, "bbox": [470.5, 554.72, 394.37, 51.81], "category_id": 3}, {"id": 10, "bbox": [1017.13, 181.05, 199.1, 107.24], "category_id": 2}, {"id": 11, "bbox": [749.57, 1224.82, 304.13, 50.13], "category_id": 3}, {"id": 12, "bbox": [921.69, 892.28, 299.12, 48.46], "category_id": 2}, {"id": 13, "bbox": [886.6, 825.44, 317.5, 45.11], "category_id": 3}, {"id": 14, "bbox": [886.6, 776.97, 262.35, 46.79], "category_id": 3}, {"id": 15, "bbox": [405.18, 926.14, 460.87, 425.47], "category_id": 1}, {"id": 16, "bbox": [297.27, 0.0, 344.61, 148.32], "category_id": 2}, {"id": 17, "bbox": [806.18, 308.48, 66.14, 57.1], "category_id": 3}, {"id": 18, "bbox": [36.9, 497.19, 344.61, 251.38], "category_id": 1}, {"id": 19, "bbox": [103.04, 1185.18, 206.07, 68.94], "category_id": 2}, {"id": 20, "bbox": [747.7, 1183.1, 373.0, 43.6], "category_id": 3}, {"id": 21, "bbox": [530.5, 732.69, 312.4, 95.01], "category_id": 2}, {"id": 22, "bbox": [886.9, 729.2, 308.0, 48.9], "category_id": 3}, {"id": 23, "bbox": [472.01, 644.12, 394.04, 48.18], "category_id": 2}, {"id": 24, "bbox": [108.1, 775.0, 213.3, 45.2], "category_id": 3}, {"id": 25, "bbox": [351.57, 770.86, 148.99, 153.19], "category_id": 2}, {"id": 26, "bbox": [134.62, 822.09, 168.77, 48.46], "category_id": 3}], "caption": "Scheme 2. Synthesis of Alkynyl Silyl Enol Ethers 10 and 19", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 470, 417, 485], "ImageBB": [82, 491, 420, 839]}, "reactions": [{"reactants": [5], "conditions": [16, 7], "products": [4]}, {"reactants": [4], "conditions": [8, 10], "products": [18]}, {"reactants": [18], "conditions": [3, 23], "products": [2]}, {"reactants": [2], "conditions": [1, 19], "products": [15]}, {"reactants": [24], "conditions": [25], "products": [26]}, {"reactants": [22], "conditions": [21], "products": [14]}], "diagram_type": "multiple"}, {"id": 802, "width": 3396, "height": 1248, "file_name": "jo501006u-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1061.0, 382.0, 302.0, 85.0], "category_id": 1}, {"id": 1, "bbox": [2422.0, 376.88, 247.0, 85.0], "category_id": 1}, {"id": 2, "bbox": [2011.0, 377.12, 316.0, 91.0], "category_id": 1}, {"id": 3, "bbox": [732.0, 385.0, 262.0, 82.0], "category_id": 1}, {"id": 4, "bbox": [1594.68, 442.32, 228.0, 64.0], "category_id": 2}, {"id": 5, "bbox": [1382.61, 280.2, 533.0, 142.07], "category_id": 2}], "reactions": [{"reactants": [3, 0], "conditions": [5, 4], "products": [2, 1]}], "corefs": [], "caption": "Figure 2. Time-courses of coupling product (a) and reduced product (b) in the reaction of n-NonBr with n-BuMgCl with 25 mol ppm of CuCl2 and 100 mol % (\u25c6), 50 mol % (\u25a0), 25 mol % (\u25b2), 5 mol % (\u25cf), or 0 mol % (\u25c7) of phenylpropyne. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 343, 784, 371], "ImageBB": [10, 22, 859, 334]}, "diagram_type": "single"}, {"id": 1201, "width": 1356, "height": 856, "file_name": "ol502998n-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [280.83, 382.12, 96.33, 38.01], "category_id": 2}, {"id": 1, "bbox": [1121.93, 615.52, 25.69, 28.78], "category_id": 3}, {"id": 2, "bbox": [445.76, 651.49, 77.07, 30.83], "category_id": 2}, {"id": 3, "bbox": [493.83, 260.63, 221.82, 42.08], "category_id": 2}, {"id": 4, "bbox": [238.1, 447.28, 200.11, 253.17], "category_id": 1}, {"id": 5, "bbox": [976.01, 734.73, 77.07, 29.8], "category_id": 2}, {"id": 6, "bbox": [531.82, 6.11, 210.96, 168.19], "category_id": 1}, {"id": 7, "bbox": [1017.51, 241.95, 50.2, 43.44], "category_id": 3}, {"id": 8, "bbox": [954.42, 126.24, 219.79, 155.36], "category_id": 1}, {"id": 9, "bbox": [665.45, 145.93, 43.41, 42.08], "category_id": 3}, {"id": 10, "bbox": [1164.03, 221.94, 45.45, 161.54], "category_id": 1}, {"id": 11, "bbox": [510.11, 528.73, 280.16, 42.08], "category_id": 2}, {"id": 12, "bbox": [390.72, 373.3, 157.38, 89.59], "category_id": 1}, {"id": 13, "bbox": [799.08, 772.39, 229.96, 34.62], "category_id": 2}, {"id": 14, "bbox": [849.96, 92.31, 76.65, 44.11], "category_id": 2}, {"id": 15, "bbox": [187.9, 96.38, 225.89, 138.46], "category_id": 1}, {"id": 16, "bbox": [531.82, 600.67, 244.2, 211.77], "category_id": 1}, {"id": 17, "bbox": [905.58, 373.3, 215.71, 40.04], "category_id": 2}, {"id": 18, "bbox": [252.34, 226.69, 48.84, 40.73], "category_id": 3}, {"id": 19, "bbox": [970.7, 488.0, 221.82, 196.16], "category_id": 1}, {"id": 20, "bbox": [579.3, 769.68, 33.92, 39.36], "category_id": 3}, {"id": 21, "bbox": [144.49, 397.06, 122.78, 37.33], "category_id": 2}, {"id": 22, "bbox": [390.72, 251.13, 88.19, 38.69], "category_id": 2}], "caption": "Scheme 5. Proposed Catalytic Cycle for the Indole Synthesis", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 187, 784, 202], "ImageBB": [448, 208, 787, 422]}, "reactions": [{"reactants": [21], "conditions": [0], "products": [12]}, {"reactants": [12, 15], "conditions": [22, 3], "products": [6]}, {"reactants": [6], "conditions": [14], "products": [8]}, {"reactants": [8, 10], "conditions": [17], "products": [19]}, {"reactants": [19, 5], "conditions": [13], "products": [16]}, {"reactants": [16, 2], "conditions": [11], "products": [4, 12]}], "diagram_type": "graph"}, {"id": 1295, "width": 1688, "height": 1280, "file_name": "op2001832-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [270.22, 807.96, 28.71, 32.08], "category_id": 2}, {"id": 1, "bbox": [220.39, 653.46, 53.2, 43.05], "category_id": 3}, {"id": 2, "bbox": [671.32, 415.38, 366.47, 197.55], "category_id": 1}, {"id": 3, "bbox": [1296.19, 0.0, 237.28, 174.76], "category_id": 1}, {"id": 4, "bbox": [433.19, 969.21, 411.23, 233.86], "category_id": 1}, {"id": 5, "bbox": [653.58, 29.55, 38.85, 38.84], "category_id": 2}, {"id": 6, "bbox": [1485.34, 271.01, 28.71, 43.05], "category_id": 2}, {"id": 7, "bbox": [1465.07, 655.15, 52.36, 43.05], "category_id": 3}, {"id": 8, "bbox": [226.31, 42.21, 343.67, 130.86], "category_id": 1}, {"id": 9, "bbox": [1324.9, 1206.45, 35.46, 43.05], "category_id": 3}, {"id": 10, "bbox": [1242.15, 415.38, 445.85, 206.84], "category_id": 1}, {"id": 11, "bbox": [558.16, 429.73, 40.54, 44.74], "category_id": 2}, {"id": 12, "bbox": [83.6, 431.42, 359.72, 192.49], "category_id": 1}, {"id": 13, "bbox": [804.73, 35.46, 363.11, 130.86], "category_id": 1}, {"id": 14, "bbox": [831.76, 653.46, 52.35, 43.05], "category_id": 3}, {"id": 15, "bbox": [365.63, 1230.93, 55.74, 45.59], "category_id": 3}, {"id": 16, "bbox": [937.31, 995.38, 40.53, 50.66], "category_id": 2}, {"id": 17, "bbox": [1134.9, 962.46, 403.64, 231.32], "category_id": 1}, {"id": 18, "bbox": [1134.9, 429.73, 37.16, 39.68], "category_id": 2}, {"id": 19, "bbox": [0.0, 974.28, 408.7, 236.39], "category_id": 1}], "caption": "Scheme 4. Mandelic acid resolution route to (3S,5R)-3-(aminomethyl)-5-methyloctanoic acida", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 644, 595, 665], "ImageBB": [211, 675, 633, 995]}, "reactions": [{"reactants": [8], "conditions": [5], "products": [13]}, {"reactants": [13, 3], "conditions": [6], "products": [10]}, {"reactants": [10], "conditions": [18], "products": [2]}, {"reactants": [2], "conditions": [11], "products": [12]}, {"reactants": [12], "conditions": [0], "products": [19]}, {"reactants": [19, 4], "conditions": [16], "products": [17]}], "diagram_type": "tree"}, {"id": 755, "width": 1344, "height": 748, "file_name": "jo990938e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [572.0, 178.0, 327.0, 177.9], "category_id": 1}, {"id": 1, "bbox": [1.0, 443.0, 1342.0, 301.0], "category_id": 4}, {"id": 2, "bbox": [128.0, 170.0, 215.9, 82.9], "category_id": 2}, {"id": 3, "bbox": [387.0, 7.0, 351.0, 52.0], "category_id": 2}, {"id": 4, "bbox": [157.2, 285.0, 132.8, 80.0], "category_id": 2}, {"id": 5, "bbox": [657.01, 370.92, 134.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [1035.2, 373.0, 59.7, 37.0], "category_id": 3}, {"id": 7, "bbox": [775.1, 6.0, 373.7, 130.0], "category_id": 1}, {"id": 8, "bbox": [836.1, 129.0, 384.9, 233.1], "category_id": 1}, {"id": 9, "bbox": [138.4, 0.0, 242.6, 142.9], "category_id": 1}, {"id": 10, "bbox": [300.4, 181.0, 324.5, 174.0], "category_id": 1}, {"id": 11, "bbox": [394.0, 95.0, 304.0, 59.0], "category_id": 2}, {"id": 12, "bbox": [357.0, 369.0, 150.0, 51.0], "category_id": 3}, {"id": 13, "bbox": [196.0, 101.0, 38.0, 39.0], "category_id": 3}, {"id": 14, "bbox": [938.0, 108.0, 42.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [9], "conditions": [3, 11], "products": [7]}, {"reactants": [7], "conditions": [2, 4], "products": [10, 0, 8]}], "corefs": [[9, 13], [7, 14], [10, 12], [0, 5], [8, 6]], "caption": "Table 1. Addition of Allenylmetal Reagents Prepared         from Allenylstannane 2 to Aldehyde 3a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [84, 64, 399, 89], "ImageBB": [74, 99, 410, 286]}, "diagram_type": "multiple"}, {"id": 183, "width": 1336, "height": 2728, "file_name": "op0602270-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1070.41, 288.94, 149.93, 58.51], "category_id": 3}, {"id": 1, "bbox": [394.0, 65.0, 460.0, 66.0], "category_id": 2}, {"id": 2, "bbox": [474.0, 191.0, 289.0, 66.0], "category_id": 2}, {"id": 3, "bbox": [526.0, 1419.0, 292.0, 62.0], "category_id": 2}, {"id": 4, "bbox": [977.0, 1269.0, 357.0, 243.0], "category_id": 1}, {"id": 5, "bbox": [69.0, 1271.0, 370.0, 241.0], "category_id": 1}, {"id": 6, "bbox": [903.6, 34.0, 379.4, 249.9], "category_id": 1}, {"id": 7, "bbox": [452.0, 1296.0, 459.8, 56.0], "category_id": 2}, {"id": 8, "bbox": [286.0, 291.0, 77.0, 49.0], "category_id": 3}, {"id": 9, "bbox": [33.0, 1590.0, 1280.0, 1138.0], "category_id": 4}, {"id": 10, "bbox": [250.96, 338.64, 963.7, 854.8], "category_id": 4}, {"id": 11, "bbox": [0.0, 0.0, 249.0, 331.0], "category_id": 1}, {"id": 12, "bbox": [1135.0, 1522.0, 122.0, 46.0], "category_id": 3}, {"id": 13, "bbox": [221.0, 1525.0, 75.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [11], "conditions": [1, 2], "products": [6]}, {"reactants": [5], "conditions": [7, 3], "products": [4]}], "corefs": [[11, 8], [6, 0], [5, 13], [4, 12]], "caption": "Figure 1. Solvent and pressure variation. Reactions were carried out at 10 \u00b0C for 24 h with 0.0024 mmol [Rh(cod)2]BF4, 0.005 mmol ligand 6a and 0.24 mmol substrate in 2.0 mL of solvent. Conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). The absolute configuration was determined by comparison with reported data.3l ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 738, 409, 835], "ImageBB": [75, 53, 409, 735]}, "diagram_type": "multiple"}, {"id": 25, "width": 1348, "height": 800, "file_name": "ja905415r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [230.23, 295.26, 51.55, 41.23], "category_id": 3}, {"id": 1, "bbox": [3.14, 345.84, 1340.83, 450.0], "category_id": 4}, {"id": 2, "bbox": [64.04, 32.04, 346.77, 242.52], "category_id": 1}, {"id": 3, "bbox": [656.55, 41.33, 306.52, 247.68], "category_id": 1}, {"id": 4, "bbox": [1019.91, 2.1, 260.06, 291.04], "category_id": 1}, {"id": 5, "bbox": [421.2, 123.91, 187.81, 46.39], "category_id": 2}, {"id": 6, "bbox": [425.33, 194.1, 175.37, 51.55], "category_id": 2}, {"id": 7, "bbox": [838.23, 295.26, 56.71, 41.23], "category_id": 3}, {"id": 8, "bbox": [1192.3, 295.26, 52.58, 41.23], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5, 6], "products": [3, 4]}], "corefs": [[2, 0], [3, 7], [4, 8]], "caption": "Table 1. Au-Catalyzed [4C+2C] vs [4C+3C] Cycloaddition of 1aa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 462, 752, 476], "ImageBB": [425, 485, 762, 685]}, "diagram_type": "single"}, {"id": 423, "width": 1352, "height": 896, "file_name": "op3002883-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [229.0, 200.0, 51.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [505.0, 137.0, 281.0, 127.0], "category_id": 2}, {"id": 2, "bbox": [501.0, 0.0, 295.0, 131.0], "category_id": 2}, {"id": 3, "bbox": [792.0, 1.0, 560.0, 203.0], "category_id": 1}, {"id": 4, "bbox": [985.0, 217.0, 49.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [2.0, 50.0, 488.0, 141.0], "category_id": 1}, {"id": 6, "bbox": [10.0, 290.8, 1332.0, 578.2], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [2, 1], "products": [3]}], "corefs": [[5, 0], [3, 4]], "caption": "Table 1. Ligand and Solvent Optimization", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 324, 321, 339], "ImageBB": [82, 346, 420, 570]}, "diagram_type": "single"}, {"id": 903, "width": 1352, "height": 1828, "file_name": "acs.joc.5b02057-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [567.0, 33.0, 463.0, 102.0], "category_id": 2}, {"id": 1, "bbox": [988.0, 1456.0, 316.0, 262.0], "category_id": 1}, {"id": 2, "bbox": [679.0, 1458.0, 285.0, 283.0], "category_id": 1}, {"id": 3, "bbox": [378.0, 1452.0, 281.0, 293.0], "category_id": 1}, {"id": 4, "bbox": [4.0, 1469.0, 330.0, 267.0], "category_id": 1}, {"id": 5, "bbox": [1024.0, 1070.0, 271.0, 317.0], "category_id": 1}, {"id": 6, "bbox": [685.0, 1064.0, 281.0, 325.0], "category_id": 1}, {"id": 7, "bbox": [360.0, 1059.0, 303.0, 328.0], "category_id": 1}, {"id": 8, "bbox": [15.0, 1064.0, 316.0, 320.0], "category_id": 1}, {"id": 9, "bbox": [1024.0, 654.0, 280.0, 316.0], "category_id": 1}, {"id": 10, "bbox": [690.0, 659.0, 296.0, 305.0], "category_id": 1}, {"id": 11, "bbox": [376.0, 654.0, 283.0, 321.0], "category_id": 1}, {"id": 12, "bbox": [6.0, 650.0, 290.0, 305.0], "category_id": 1}, {"id": 13, "bbox": [1028.0, 302.0, 260.0, 294.0], "category_id": 1}, {"id": 14, "bbox": [674.0, 291.0, 301.0, 290.0], "category_id": 1}, {"id": 15, "bbox": [369.0, 400.0, 274.0, 190.0], "category_id": 1}, {"id": 16, "bbox": [13.0, 398.0, 285.0, 192.0], "category_id": 1}, {"id": 17, "bbox": [1030.0, 0.0, 319.0, 207.0], "category_id": 1}, {"id": 18, "bbox": [340.0, 66.0, 236.0, 141.0], "category_id": 1}, {"id": 19, "bbox": [0.0, 69.0, 289.0, 120.0], "category_id": 1}, {"id": 20, "bbox": [1150.0, 218.0, 61.0, 40.0], "category_id": 3}, {"id": 21, "bbox": [409.0, 215.0, 76.0, 47.0], "category_id": 3}, {"id": 22, "bbox": [78.0, 211.0, 71.0, 53.0], "category_id": 3}, {"id": 23, "bbox": [1064.0, 1743.0, 187.0, 44.0], "category_id": 3}, {"id": 24, "bbox": [716.0, 1741.0, 196.0, 53.0], "category_id": 3}, {"id": 25, "bbox": [391.0, 1747.0, 210.0, 49.0], "category_id": 3}, {"id": 26, "bbox": [42.0, 1750.0, 185.0, 40.0], "category_id": 3}, {"id": 27, "bbox": [1055.0, 1391.0, 209.0, 51.0], "category_id": 3}, {"id": 28, "bbox": [710.0, 1398.0, 213.0, 42.0], "category_id": 3}, {"id": 29, "bbox": [398.0, 1393.0, 234.0, 38.0], "category_id": 3}, {"id": 30, "bbox": [49.0, 1391.0, 187.0, 45.0], "category_id": 3}, {"id": 31, "bbox": [1057.0, 970.0, 203.0, 56.0], "category_id": 3}, {"id": 32, "bbox": [716.0, 977.0, 203.0, 53.0], "category_id": 3}, {"id": 33, "bbox": [407.0, 984.0, 196.0, 46.0], "category_id": 3}, {"id": 34, "bbox": [46.0, 981.0, 174.0, 45.0], "category_id": 3}, {"id": 35, "bbox": [1070.0, 594.0, 178.0, 47.0], "category_id": 3}, {"id": 36, "bbox": [721.0, 587.0, 191.0, 56.0], "category_id": 3}, {"id": 37, "bbox": [398.0, 592.0, 200.0, 49.0], "category_id": 3}, {"id": 38, "bbox": [33.0, 598.0, 220.0, 45.0], "category_id": 3}, {"id": 39, "bbox": [688.0, 160.0, 233.0, 100.0], "category_id": 2}], "reactions": [{"reactants": [19, 18], "conditions": [0, 39], "products": [17]}], "corefs": [[19, 22], [18, 21], [17, 20], [16, 38], [15, 37], [14, 36], [13, 35], [12, 34], [11, 33], [10, 32], [9, 31], [8, 30], [7, 29], [6, 28], [5, 27], [4, 26], [3, 25], [2, 24], [1, 24]], "caption": "Table 2. Reaction Scope of Ynamides 1 with Vinyl Azide 2ba", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 380, 417, 401], "ImageBB": [82, 407, 420, 864]}, "diagram_type": "single"}, {"id": 181, "width": 1344, "height": 1192, "file_name": "op0602270-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [419.0, 32.0, 470.0, 63.0], "category_id": 2}, {"id": 1, "bbox": [8.0, 11.0, 367.0, 229.8], "category_id": 1}, {"id": 2, "bbox": [42.6, 336.0, 1262.4, 853.5], "category_id": 1}, {"id": 3, "bbox": [983.2, 7.0, 360.8, 232.6], "category_id": 1}, {"id": 4, "bbox": [73.0, 243.4, 227.3, 50.5], "category_id": 3}, {"id": 5, "bbox": [382.0, 149.0, 570.0, 68.6], "category_id": 2}, {"id": 6, "bbox": [1127.4, 240.0, 67.6, 59.8], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [0, 5], "products": [3]}], "corefs": [[1, 4], [3, 6]], "caption": "Figure 3. Dependency of enantioselectivity versus E/Z ratio. Reactions were carried out at 10 \u00b0C for 24 h with 0.0024 mmol [Rh(cod)2]BF4, 0.005 mmol ligand 6a and 0.24 mmol substrate in 2.0 mL of ethanol. Conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 757, 775, 840], "ImageBB": [440, 456, 776, 754]}, "diagram_type": "single"}, {"id": 831, "width": 1348, "height": 408, "file_name": "jo4004426-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [549.0, 204.0, 383.9, 59.7], "category_id": 2}, {"id": 1, "bbox": [285.4, 28.0, 179.8, 279.0], "category_id": 1}, {"id": 2, "bbox": [963.0, 3.0, 352.9, 301.9], "category_id": 1}, {"id": 3, "bbox": [32.1, 16.0, 132.2, 296.0], "category_id": 1}, {"id": 4, "bbox": [545.0, 42.0, 401.0, 113.0], "category_id": 2}, {"id": 5, "bbox": [451.0, 236.0, 34.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [1124.0, 229.0, 45.0, 63.0], "category_id": 3}, {"id": 7, "bbox": [2.0, 324.0, 1346.0, 83.0], "category_id": 4}, {"id": 8, "bbox": [149.0, 239.0, 42.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [3, 1], "conditions": [4, 0], "products": [2]}], "corefs": [[3, 8], [1, 5], [2, 6]], "caption": "Table 2. Optimization Studies with Heterogeneous Copper Catalysts ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 205, 415, 235], "ImageBB": [82, 242, 419, 344]}, "diagram_type": "single"}, {"id": 820, "width": 1352, "height": 1656, "file_name": "jo401195c-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [844.0, 294.0, 149.0, 49.0], "category_id": 3}, {"id": 1, "bbox": [1060.0, 286.0, 252.0, 59.4], "category_id": 3}, {"id": 2, "bbox": [387.0, 3.0, 279.0, 48.0], "category_id": 2}, {"id": 3, "bbox": [1084.0, 20.0, 265.0, 255.0], "category_id": 1}, {"id": 4, "bbox": [58.0, 292.0, 116.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [319.0, 219.0, 311.0, 51.0], "category_id": 2}, {"id": 6, "bbox": [264.0, 89.0, 179.0, 77.0], "category_id": 2}, {"id": 7, "bbox": [451.0, 58.0, 200.0, 125.0], "category_id": 1}, {"id": 8, "bbox": [793.0, 119.0, 208.0, 159.0], "category_id": 1}, {"id": 9, "bbox": [0.0, 121.0, 224.0, 153.0], "category_id": 1}, {"id": 10, "bbox": [8.0, 369.0, 1340.0, 1287.0], "category_id": 4}], "reactions": [{"reactants": [9], "conditions": [2, 6, 7, 5], "products": [8, 3]}], "corefs": [[9, 4], [8, 0], [3, 1]], "caption": "Table 7. KR of trans-Diol (\u00b1)-1 with Peptide Catalyst 12b Using Various Acyl Donors ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 403, 781, 437], "ImageBB": [448, 444, 786, 858]}, "diagram_type": "single"}, {"id": 166, "width": 1352, "height": 1088, "file_name": "op500334b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1117.0, 1041.0, 40.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [7.0, 309.0, 1344.0, 424.0], "category_id": 4}, {"id": 2, "bbox": [811.0, 4.0, 510.0, 290.0], "category_id": 1}, {"id": 3, "bbox": [1.0, 736.0, 489.0, 315.0], "category_id": 1}, {"id": 4, "bbox": [98.0, 243.0, 47.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [921.0, 228.0, 45.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [198.0, 1036.0, 43.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [661.0, 1043.0, 51.0, 42.0], "category_id": 3}, {"id": 8, "bbox": [433.0, 27.0, 377.0, 120.2], "category_id": 2}, {"id": 9, "bbox": [34.5, 0.0, 349.5, 285.4], "category_id": 1}, {"id": 10, "bbox": [550.0, 736.0, 367.0, 305.2], "category_id": 1}, {"id": 11, "bbox": [1012.0, 743.3, 335.0, 297.7], "category_id": 1}, {"id": 12, "bbox": [501.0, 194.3, 230.0, 54.7], "category_id": 2}], "reactions": [{"reactants": [9], "conditions": [8, 12], "products": [2]}], "corefs": [[9, 4], [2, 5], [3, 6], [10, 7], [11, 0]], "caption": "Table 2. Optimization of the copper catalyst and main impurities ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 463, 757, 493], "ImageBB": [448, 499, 786, 771]}, "diagram_type": "single"}, {"id": 886, "width": 1348, "height": 344, "file_name": "ol502998n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [445.0, 204.0, 36.0, 32.0], "category_id": 3}, {"id": 1, "bbox": [543.0, 74.0, 395.0, 38.0], "category_id": 2}, {"id": 2, "bbox": [121.0, 32.0, 214.0, 132.0], "category_id": 1}, {"id": 3, "bbox": [977.0, 4.0, 251.0, 238.0], "category_id": 1}, {"id": 4, "bbox": [598.0, 133.0, 257.0, 37.0], "category_id": 2}, {"id": 5, "bbox": [5.0, 269.0, 1341.0, 75.0], "category_id": 4}, {"id": 6, "bbox": [203.0, 205.0, 36.0, 31.0], "category_id": 3}, {"id": 7, "bbox": [1029.0, 204.0, 36.0, 31.0], "category_id": 3}, {"id": 8, "bbox": [452.0, 38.0, 40.0, 151.0], "category_id": 1}], "reactions": [{"reactants": [2, 8], "conditions": [1, 4], "products": [3]}], "corefs": [[2, 6], [8, 0], [3, 7]], "caption": "Table 1. Condition Investigation Using Pyrazolidin-3-one as an Oxidative DGa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 449, 416, 479], "ImageBB": [82, 486, 419, 572]}, "diagram_type": "single"}, {"id": 243, "width": 1308, "height": 2248, "file_name": "ol901684h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1086.0, 223.0, 37.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [552.0, 149.0, 334.0, 43.0], "category_id": 2}, {"id": 2, "bbox": [553.0, 0.0, 335.0, 129.0], "category_id": 2}, {"id": 3, "bbox": [907.0, 75.0, 367.0, 146.0], "category_id": 1}, {"id": 4, "bbox": [275.0, 113.0, 231.0, 61.0], "category_id": 1}, {"id": 5, "bbox": [37.0, 68.0, 191.0, 162.0], "category_id": 1}, {"id": 6, "bbox": [5.0, 311.0, 1303.0, 1937.0], "category_id": 4}, {"id": 7, "bbox": [143.0, 228.0, 38.0, 35.0], "category_id": 3}, {"id": 8, "bbox": [381.0, 223.0, 33.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [5, 4], "conditions": [2, 1], "products": [3]}], "corefs": [[5, 7], [4, 8], [3, 0]], "caption": "Table 3. Nickel-Catalyzed Direct Alkynylation of Various 5-Aryloxazoles 4 with Alkynyl Bromides 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 360, 102], "ImageBB": [63, 111, 390, 673]}, "diagram_type": "single"}, {"id": 952, "width": 1356, "height": 932, "file_name": "acs.orglett.6b00233-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1021.58, 187.94, 305.93, 48.17], "category_id": 3}, {"id": 1, "bbox": [661.38, 495.97, 44.09, 40.71], "category_id": 3}, {"id": 2, "bbox": [548.1, 316.85, 301.86, 185.23], "category_id": 1}, {"id": 3, "bbox": [14.92, 345.35, 314.07, 135.69], "category_id": 1}, {"id": 4, "bbox": [349.34, 358.92, 167.55, 45.45], "category_id": 2}, {"id": 5, "bbox": [346.63, 434.23, 175.01, 122.12], "category_id": 2}, {"id": 6, "bbox": [851.99, 318.21, 146.53, 89.56], "category_id": 2}, {"id": 7, "bbox": [769.91, 143.16, 111.25, 85.49], "category_id": 2}, {"id": 8, "bbox": [1035.15, 302.6, 300.5, 213.72], "category_id": 1}, {"id": 9, "bbox": [390.05, 249.0, 102.42, 98.38], "category_id": 1}, {"id": 10, "bbox": [993.77, 2.71, 320.17, 168.95], "category_id": 1}, {"id": 11, "bbox": [753.63, 591.64, 197.4, 96.34], "category_id": 2}, {"id": 12, "bbox": [991.05, 627.6, 303.22, 204.22], "category_id": 1}, {"id": 13, "bbox": [1130.79, 533.29, 122.78, 43.42], "category_id": 3}, {"id": 14, "bbox": [1105.69, 846.07, 123.46, 44.1], "category_id": 3}], "caption": "Scheme 3. Concise Synthesis Crispine A and Analogues", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 141, 757, 156], "ImageBB": [448, 162, 787, 395]}, "reactions": [{"reactants": [3], "conditions": [9, 4, 5], "products": [2]}, {"reactants": [2], "conditions": [7], "products": [10]}, {"reactants": [2], "conditions": [6], "products": [8]}, {"reactants": [2], "conditions": [11], "products": [12]}], "diagram_type": "tree"}, {"id": 1136, "width": 1144, "height": 656, "file_name": "ol0069002-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [592.89, 569.71, 32.05, 41.22], "category_id": 3}, {"id": 1, "bbox": [1063.88, 469.51, 31.48, 43.51], "category_id": 3}, {"id": 2, "bbox": [101.29, 111.65, 33.77, 34.93], "category_id": 2}, {"id": 3, "bbox": [871.02, 242.2, 26.9, 38.36], "category_id": 3}, {"id": 4, "bbox": [755.42, 27.48, 388.58, 242.77], "category_id": 1}, {"id": 5, "bbox": [651.83, 101.34, 76.12, 45.24], "category_id": 2}, {"id": 6, "bbox": [0.0, 131.12, 40.06, 48.09], "category_id": 3}, {"id": 7, "bbox": [940.84, 436.3, 25.75, 42.94], "category_id": 2}, {"id": 8, "bbox": [438.37, 443.17, 36.63, 38.36], "category_id": 2}, {"id": 9, "bbox": [231.78, 2.29, 358.25, 245.06], "category_id": 1}, {"id": 10, "bbox": [374.28, 246.2, 32.62, 40.08], "category_id": 3}, {"id": 11, "bbox": [136.2, 563.98, 34.34, 44.09], "category_id": 3}, {"id": 12, "bbox": [57.8, 351.56, 325.06, 245.06], "category_id": 1}, {"id": 13, "bbox": [22.32, 435.73, 34.34, 47.52], "category_id": 2}, {"id": 14, "bbox": [517.35, 316.06, 390.87, 334.95], "category_id": 1}], "caption": "Scheme 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 437, 269, 451], "ImageBB": [100, 455, 386, 619]}, "reactions": [{"reactants": [6], "conditions": [2], "products": [9]}, {"reactants": [9], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [13], "products": [12]}, {"reactants": [12], "conditions": [8], "products": [14]}, {"reactants": [14], "conditions": [7], "products": [1]}], "diagram_type": "multiple"}, {"id": 158, "width": 2816, "height": 1176, "file_name": "op700060e-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [962.0, 56.0, 172.0, 67.0], "category_id": 2}, {"id": 1, "bbox": [995.0, 123.0, 102.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [1799.5, 12.6, 279.9, 199.2], "category_id": 1}, {"id": 3, "bbox": [734.4, 36.5, 217.7, 161.3], "category_id": 1}, {"id": 4, "bbox": [1213.7, 28.7, 293.8, 171.9], "category_id": 1}, {"id": 5, "bbox": [1544.4, 59.0, 249.6, 53.0], "category_id": 2}, {"id": 6, "bbox": [1538.0, 131.5, 237.0, 52.3], "category_id": 2}, {"id": 7, "bbox": [14.0, 239.0, 2802.0, 937.0], "category_id": 4}], "reactions": [{"reactants": [3], "conditions": [0, 1], "products": [4]}, {"reactants": [4], "conditions": [5, 6], "products": [2]}], "corefs": [], "caption": "Table 3. Tandem SNAr/oxidation evaluation with alternative pyridine and aromatic substrates (HPLC purity data is reported for isolated solids) ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 746, 73], "ImageBB": [58, 88, 762, 382]}, "diagram_type": "single"}, {"id": 768, "width": 1348, "height": 1216, "file_name": "jo9602433-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [804.6, 294.6, 483.1, 516.4], "category_id": 1}, {"id": 1, "bbox": [118.1, 279.0, 480.2, 519.0], "category_id": 1}, {"id": 2, "bbox": [1094.5, 242.82, 195.61, 57.05], "category_id": 2}, {"id": 3, "bbox": [1138.52, 531.33, 202.12, 61.94], "category_id": 2}, {"id": 4, "bbox": [314.0, 811.7, 66.5, 57.3], "category_id": 3}, {"id": 5, "bbox": [1014.0, 813.0, 73.0, 58.7], "category_id": 3}, {"id": 6, "bbox": [14.0, 529.0, 38.0, 60.0], "category_id": 3}, {"id": 7, "bbox": [1.0, 902.0, 1347.0, 314.0], "category_id": 4}, {"id": 8, "bbox": [510.96, 650.32, 254.28, 58.68], "category_id": 2}, {"id": 9, "bbox": [540.3, 506.88, 193.97, 53.79], "category_id": 2}, {"id": 10, "bbox": [540.3, 575.34, 193.97, 58.68], "category_id": 2}, {"id": 11, "bbox": [283.0, 188.0, 65.0, 52.0], "category_id": 2}, {"id": 12, "bbox": [8.0, 51.0, 113.0, 69.0], "category_id": 2}, {"id": 13, "bbox": [217.0, 0.0, 195.0, 62.0], "category_id": 2}, {"id": 14, "bbox": [225.0, 106.0, 176.0, 60.0], "category_id": 2}, {"id": 15, "bbox": [525.63, 270.53, 193.97, 66.83], "category_id": 2}], "reactions": [{"reactants": [12], "conditions": [13, 14, 11], "products": [6, 1, 0]}], "corefs": [[1, 4], [0, 5]], "caption": "Table 4. Treatment of (Z)-4 with BTMBr3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [474, 55, 718, 68], "ImageBB": [429, 75, 766, 379]}, "diagram_type": "multiple"}, {"id": 636, "width": 1356, "height": 1212, "file_name": "ol501085y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [343.0, 229.0, 150.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [538.0, 122.0, 447.0, 97.0], "category_id": 2}, {"id": 2, "bbox": [596.0, 17.0, 333.0, 98.0], "category_id": 2}, {"id": 3, "bbox": [1042.8, 0.0, 308.5, 241.0], "category_id": 1}, {"id": 4, "bbox": [1.0, 301.0, 1352.0, 911.0], "category_id": 4}, {"id": 5, "bbox": [6.2, 2.6, 260.3, 234.8], "category_id": 1}, {"id": 6, "bbox": [46.0, 229.0, 204.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [338.0, 85.0, 160.0, 71.0], "category_id": 2}], "reactions": [{"reactants": [5, 7], "conditions": [2, 1], "products": [3]}], "corefs": [[5, 6]], "caption": "Table 2. Reaction Optimization for PyBidine-NiCl2- Catalyzed Asymmetric Nitro-Mannich Reaction ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 251, 742, 281], "ImageBB": [448, 287, 787, 590]}, "diagram_type": "single"}, {"id": 1042, "width": 2488, "height": 1480, "file_name": "jo010230b-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1942.86, 843.79, 545.14, 201.62], "category_id": 1}, {"id": 1, "bbox": [570.6, 1016.78, 47.98, 59.74], "category_id": 3}, {"id": 2, "bbox": [497.5, 48.54, 358.8, 197.88], "category_id": 1}, {"id": 3, "bbox": [958.75, 367.52, 31.9, 39.41], "category_id": 2}, {"id": 4, "bbox": [960.63, 1148.07, 26.27, 48.79], "category_id": 2}, {"id": 5, "bbox": [1848.13, 219.29, 52.53, 61.92], "category_id": 3}, {"id": 6, "bbox": [2164.4, 107.03, 32.36, 39.82], "category_id": 2}, {"id": 7, "bbox": [1286.94, 509.01, 507.81, 200.37], "category_id": 1}, {"id": 8, "bbox": [1575.69, 1018.03, 80.9, 67.2], "category_id": 3}, {"id": 9, "bbox": [0.0, 59.74, 344.76, 131.92], "category_id": 1}, {"id": 10, "bbox": [0.0, 837.57, 158.07, 192.9], "category_id": 1}, {"id": 11, "bbox": [1202.31, 573.73, 33.6, 34.85], "category_id": 2}, {"id": 12, "bbox": [2334.91, 682.0, 52.28, 60.99], "category_id": 3}, {"id": 13, "bbox": [581.24, 426.87, 598.66, 339.76], "category_id": 1}, {"id": 14, "bbox": [441.84, 840.06, 430.64, 160.54], "category_id": 1}, {"id": 15, "bbox": [1858.22, 567.51, 41.07, 42.31], "category_id": 2}, {"id": 16, "bbox": [576.26, 1237.06, 883.68, 204.11], "category_id": 1}, {"id": 17, "bbox": [995.7, 1412.54, 89.61, 67.21], "category_id": 3}, {"id": 18, "bbox": [2334.91, 1016.78, 82.15, 68.45], "category_id": 3}, {"id": 19, "bbox": [902.35, 677.03, 52.28, 64.71], "category_id": 3}, {"id": 20, "bbox": [1712.6, 38.58, 358.45, 212.82], "category_id": 1}, {"id": 21, "bbox": [1321.79, 215.3, 52.27, 67.21], "category_id": 3}, {"id": 22, "bbox": [1202.31, 836.33, 632.26, 209.08], "category_id": 1}, {"id": 23, "bbox": [2039.94, 1415.03, 74.67, 63.47], "category_id": 3}, {"id": 24, "bbox": [1529.64, 1294.31, 33.61, 43.56], "category_id": 2}, {"id": 25, "bbox": [500.34, 216.55, 57.25, 65.96], "category_id": 3}, {"id": 26, "bbox": [1634.19, 110.76, 31.11, 36.09], "category_id": 2}, {"id": 27, "bbox": [1858.22, 903.53, 47.3, 43.56], "category_id": 2}, {"id": 28, "bbox": [0.0, 2482.84, 16.18, -1002.84], "category_id": 3}, {"id": 29, "bbox": [2290.11, 53.51, 182.95, 133.17], "category_id": 1}, {"id": 30, "bbox": [281.28, 901.04, 27.39, 43.56], "category_id": 2}, {"id": 31, "bbox": [1942.86, 505.28, 545.14, 197.88], "category_id": 1}, {"id": 32, "bbox": [1138.83, 3.73, 420.68, 334.78], "category_id": 1}, {"id": 33, "bbox": [83.39, 220.28, 44.81, 59.74], "category_id": 3}, {"id": 34, "bbox": [1641.66, 1228.35, 838.87, 204.11], "category_id": 1}], "caption": "Scheme 1. Synthesis of (5Z,8Z)-[10,11,12,12-2H]Tetradeca-5,8-dienoic Acid (13)a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [167, 63, 682, 77], "ImageBB": [115, 84, 737, 454]}, "reactions": [{"reactants": [9], "conditions": [], "products": [2]}, {"reactants": [2, 32], "conditions": [3], "products": [13]}, {"reactants": [29], "conditions": [6], "products": [20]}, {"reactants": [20], "conditions": [26], "products": [32]}, {"reactants": [13], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [15], "products": [31]}, {"reactants": [31], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [27], "products": [22]}, {"reactants": [14, 22], "conditions": [4], "products": [16]}, {"reactants": [16], "conditions": [24], "products": [34]}, {"reactants": [10], "conditions": [30], "products": [14]}], "diagram_type": "tree"}, {"id": 896, "width": 1348, "height": 380, "file_name": "acs.joc.6b01262-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1025.0, 5.0, 301.0, 189.0], "category_id": 1}, {"id": 1, "bbox": [677.0, 11.0, 323.0, 186.0], "category_id": 1}, {"id": 2, "bbox": [4.0, 271.0, 1343.0, 100.0], "category_id": 4}, {"id": 3, "bbox": [404.0, 127.0, 176.0, 82.0], "category_id": 2}, {"id": 4, "bbox": [22.0, 30.0, 307.0, 153.0], "category_id": 1}, {"id": 5, "bbox": [1160.0, 183.0, 47.0, 34.0], "category_id": 3}, {"id": 6, "bbox": [355.0, 21.0, 268.0, 99.0], "category_id": 2}, {"id": 7, "bbox": [104.0, 198.0, 37.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [831.0, 188.0, 45.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [6, 3], "products": [1, 0]}], "corefs": [[4, 7], [1, 8], [0, 5]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 365, 738, 386], "ImageBB": [449, 392, 786, 487]}, "diagram_type": "single"}, {"id": 906, "width": 1348, "height": 376, "file_name": "acs.joc.5b01366-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [15.0, 304.0, 1326.0, 69.0], "category_id": 4}, {"id": 1, "bbox": [631.0, 68.0, 181.0, 48.0], "category_id": 2}, {"id": 2, "bbox": [188.0, 203.0, 68.0, 66.0], "category_id": 3}, {"id": 3, "bbox": [1128.0, 224.0, 71.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [987.3, 1.0, 295.6, 236.0], "category_id": 1}, {"id": 5, "bbox": [61.0, 3.0, 377.0, 216.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1], "products": [4]}], "corefs": [[5, 2], [4, 3]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 371, 110], "ImageBB": [82, 116, 419, 210]}, "diagram_type": "single"}, {"id": 574, "width": 1356, "height": 1132, "file_name": "acs.orglett.5b00740-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [341.0, 370.0, 200.0, 72.0], "category_id": 3}, {"id": 1, "bbox": [969.0, 507.0, 335.0, 75.0], "category_id": 3}, {"id": 2, "bbox": [525.0, 253.0, 364.0, 85.0], "category_id": 3}, {"id": 3, "bbox": [1012.0, 156.0, 316.0, 201.0], "category_id": 2}, {"id": 4, "bbox": [383.0, 6.0, 681.0, 272.0], "category_id": 1}, {"id": 5, "bbox": [17.0, 222.0, 377.0, 290.0], "category_id": 1}, {"id": 6, "bbox": [660.0, 366.0, 678.0, 281.0], "category_id": 1}, {"id": 7, "bbox": [241.0, 571.0, 37.0, 61.0], "category_id": 3}, {"id": 8, "bbox": [67.0, 717.0, 1239.0, 411.0], "category_id": 4}, {"id": 9, "bbox": [0.0, 26.0, 191.0, 197.0], "category_id": 2}, {"id": 10, "bbox": [22.0, 520.0, 534.0, 96.4], "category_id": 1}], "reactions": [{"reactants": [10, 5], "conditions": [9], "products": [4]}, {"reactants": [4], "conditions": [3], "products": [6]}], "corefs": [[10, 7], [5, 0], [4, 2], [6, 1]], "caption": "Figure 1. TEM images of Oxime-MSNPs: (a) 150,000\u00d7 magni\ufb01ca- tion; (b,c) 500,000\u00d7 magni\ufb01cation of nanoparticles at two di\ufb00erent locations on the dried nanoparticle aggregate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 409, 784, 451], "ImageBB": [448, 116, 787, 399]}, "diagram_type": "tree"}, {"id": 799, "width": 1348, "height": 288, "file_name": "jo501006u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.0, 214.0, 1341.0, 73.0], "category_id": 4}, {"id": 1, "bbox": [347.68, 139.38, 193.16, 50.83], "category_id": 2}, {"id": 2, "bbox": [602.85, 55.01, 246.01, 51.84], "category_id": 1}, {"id": 3, "bbox": [847.85, 55.01, 155.54, 52.86], "category_id": 2}, {"id": 4, "bbox": [601.2, 1.0, 211.5, 48.0], "category_id": 2}, {"id": 5, "bbox": [1125.1, 95.3, 136.4, 51.5], "category_id": 1}, {"id": 6, "bbox": [666.2, 134.2, 293.6, 50.7], "category_id": 2}, {"id": 7, "bbox": [340.3, 86.0, 203.4, 52.3], "category_id": 1}, {"id": 8, "bbox": [81.0, 79.0, 107.0, 64.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [4, 2, 3, 6], "products": [5]}], "corefs": [], "caption": "Table 1. Coupling Reaction of Alkyl (Pseudo)halides with n- BuMgCl Using Phenylpropyne as an Additivea ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 353, 417, 387], "ImageBB": [82, 394, 419, 466]}, "diagram_type": "single"}, {"id": 363, "width": 1120, "height": 720, "file_name": "ol102784c-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.0, 518.0, 238.0, 99.0], "category_id": 1}, {"id": 1, "bbox": [158.0, 417.0, 259.0, 93.0], "category_id": 1}, {"id": 2, "bbox": [185.0, 309.0, 216.0, 100.0], "category_id": 1}, {"id": 3, "bbox": [239.61, 24.1, 139.95, 123.54], "category_id": 1}, {"id": 4, "bbox": [28.0, 218.0, 1061.0, 500.0], "category_id": 4}, {"id": 5, "bbox": [402.0, 96.0, 311.0, 59.0], "category_id": 2}, {"id": 6, "bbox": [796.0, 23.5, 321.0, 137.5], "category_id": 1}, {"id": 7, "bbox": [3.0, 17.7, 199.4, 142.13], "category_id": 1}, {"id": 8, "bbox": [377.07, 2.0, 376.0, 88.0], "category_id": 2}, {"id": 9, "bbox": [506.0, 623.0, 363.0, 89.0], "category_id": 1}, {"id": 10, "bbox": [496.0, 509.0, 376.0, 110.0], "category_id": 1}, {"id": 11, "bbox": [475.0, 408.0, 409.0, 97.0], "category_id": 1}, {"id": 12, "bbox": [521.0, 311.0, 311.0, 91.0], "category_id": 1}, {"id": 13, "bbox": [180.0, 618.0, 233.0, 94.0], "category_id": 1}], "reactions": [{"reactants": [7, 3], "conditions": [8, 5], "products": [6]}], "corefs": [], "caption": "Table 5. Copper-Catalyzed Cross-Coupling Reaction of Different Aryl Iodidesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 493, 713, 520], "ImageBB": [453, 529, 733, 709]}, "diagram_type": "single"}, {"id": 105, "width": 1408, "height": 1760, "file_name": "ja0014685-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [832.04, 258.08, 438.84, 246.94], "category_id": 1}, {"id": 1, "bbox": [113.73, 931.28, 1289.64, 56.5], "category_id": 2}, {"id": 2, "bbox": [155.3, 253.0, 358.05, 246.97], "category_id": 1}, {"id": 3, "bbox": [205.81, 692.4, 289.87, 188.86], "category_id": 1}, {"id": 4, "bbox": [592.16, 727.75, 150.98, 138.36], "category_id": 1}, {"id": 5, "bbox": [746.19, 583.82, 138.35, 100.48], "category_id": 2}, {"id": 6, "bbox": [1152.73, 578.77, 166.13, 92.91], "category_id": 2}, {"id": 7, "bbox": [917.89, 773.21, 113.11, 34.82], "category_id": 2}, {"id": 8, "bbox": [493.68, 467.67, 22.2, 34.82], "category_id": 3}, {"id": 9, "bbox": [1241.11, 467.67, 24.72, 32.3], "category_id": 3}, {"id": 10, "bbox": [465.9, 869.16, 22.2, 34.83], "category_id": 3}, {"id": 11, "bbox": [1114.85, 710.08, 34.83, 44.92], "category_id": 3}, {"id": 12, "bbox": [998.7, 874.21, 27.25, 34.83], "category_id": 3}, {"id": 13, "bbox": [1241.11, 874.21, 22.2, 34.83], "category_id": 3}, {"id": 14, "bbox": [1215.86, 773.21, 42.4, 34.82], "category_id": 2}, {"id": 15, "bbox": [597.2, 336.4, 24.73, 29.74], "category_id": 2}, {"id": 16, "bbox": [733.56, 336.36, 24.74, 34.84], "category_id": 2}, {"id": 17, "bbox": [685.58, 563.62, 22.2, 27.25], "category_id": 2}, {"id": 18, "bbox": [1082.03, 588.87, 22.2, 27.25], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [15, 16], "products": [0]}, {"reactants": [0], "conditions": [17, 5], "products": [3, 4]}, {"reactants": [0], "conditions": [18, 6], "products": [11]}, {"reactants": [11], "conditions": [7], "products": [12]}, {"reactants": [11], "conditions": [14], "products": [13]}], "corefs": [[2, 8], [0, 9], [3, 10]], "caption": "Figure 1. 1H NMR spectrum (400 MHz) for 2 at -50 \u00b0C in CD2Cl2. The signals marked with +, *, and # corresponds to those for 5, mesitylene, and triphenylmethane, respectively. A signal for the two mesityl ring protons of 2 is overlapped with signals for triphenylmethane. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 476, 775, 533], "ImageBB": [424, 36, 776, 475]}, "diagram_type": "tree"}, {"id": 683, "width": 1348, "height": 1156, "file_name": "ol401443a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [61.0, 91.0, 205.0, 168.0], "category_id": 1}, {"id": 1, "bbox": [691.0, 0.0, 250.0, 294.0], "category_id": 1}, {"id": 2, "bbox": [137.0, 263.0, 75.0, 55.0], "category_id": 3}, {"id": 3, "bbox": [766.0, 291.0, 76.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [1014.0, 280.0, 50.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [11.0, 391.9, 1337.0, 764.1], "category_id": 4}, {"id": 6, "bbox": [262.0, 17.0, 443.9, 188.5], "category_id": 2}, {"id": 7, "bbox": [329.0, 213.0, 298.0, 137.0], "category_id": 2}, {"id": 8, "bbox": [933.6, 0.0, 354.4, 280.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [6, 7], "products": [1, 8]}], "corefs": [[0, 2], [1, 3], [8, 4]], "caption": "Table 1. Catalyst Screening", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 583, 100], "ImageBB": [436, 112, 773, 401]}, "diagram_type": "single"}, {"id": 1329, "width": 2820, "height": 1964, "file_name": "op400242j-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1184.99, 541.93, 342.8, 222.98], "category_id": 1}, {"id": 1, "bbox": [1390.96, 220.16, 42.32, 50.8], "category_id": 3}, {"id": 2, "bbox": [1412.12, 1875.58, 53.6, 47.98], "category_id": 3}, {"id": 3, "bbox": [1953.83, 357.05, 166.46, 95.97], "category_id": 2}, {"id": 4, "bbox": [1156.78, 1611.67, 420.39, 269.56], "category_id": 1}, {"id": 5, "bbox": [1410.71, 326.0, 167.87, 135.49], "category_id": 2}, {"id": 6, "bbox": [1410.71, 1350.59, 64.89, 50.8], "category_id": 3}, {"id": 7, "bbox": [1227.31, 1119.14, 325.88, 220.16], "category_id": 1}, {"id": 8, "bbox": [541.71, 541.93, 348.45, 225.8], "category_id": 1}, {"id": 9, "bbox": [1917.15, 0.0, 356.91, 273.79], "category_id": 1}, {"id": 10, "bbox": [850.66, 961.08, 201.73, 138.3], "category_id": 2}, {"id": 11, "bbox": [761.78, 350.0, 150.95, 103.02], "category_id": 2}, {"id": 12, "bbox": [1951.01, 547.57, 324.46, 225.81], "category_id": 1}, {"id": 13, "bbox": [1390.96, 842.53, 239.82, 160.88], "category_id": 2}, {"id": 14, "bbox": [960.69, 182.05, 105.8, 46.58], "category_id": 2}, {"id": 15, "bbox": [541.71, 0.0, 345.62, 225.8], "category_id": 1}, {"id": 16, "bbox": [1667.45, 873.58, 177.75, 50.8], "category_id": 2}, {"id": 17, "bbox": [1158.19, 0.0, 375.25, 217.34], "category_id": 1}, {"id": 18, "bbox": [1574.35, 160.89, 296.25, 139.71], "category_id": 2}, {"id": 19, "bbox": [1458.1, 1422.42, 134.14, 131.61], "category_id": 2}, {"id": 20, "bbox": [1574.35, 72.8, 307.53, 54.9], "category_id": 2}, {"id": 21, "bbox": [966.6, 93.14, 98.9, 44.16], "category_id": 2}], "caption": "Scheme 5. Conversion of pyrrolotriazine 2 to PIV-protected pyrrolotriazine 3", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 479, 519, 494], "ImageBB": [82, 501, 787, 992]}, "reactions": [{"reactants": [17], "conditions": [20, 18], "products": [9]}, {"reactants": [9], "conditions": [3], "products": [12]}, {"reactants": [17], "conditions": [21, 14], "products": [15]}, {"reactants": [15], "conditions": [11], "products": [8]}, {"reactants": [8], "conditions": [10], "products": [7]}, {"reactants": [17], "conditions": [5], "products": [0]}, {"reactants": [0], "conditions": [13], "products": [7]}, {"reactants": [7], "conditions": [19], "products": [4]}], "diagram_type": "graph"}, {"id": 699, "width": 1352, "height": 848, "file_name": "ol047761h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [970.0, 49.0, 235.0, 139.0], "category_id": 1}, {"id": 1, "bbox": [124.0, 0.0, 269.0, 216.0], "category_id": 1}, {"id": 2, "bbox": [427.0, 44.0, 476.0, 57.0], "category_id": 2}, {"id": 3, "bbox": [0.0, 241.0, 1352.0, 607.0], "category_id": 4}, {"id": 4, "bbox": [1189.0, 179.0, 33.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [333.0, 177.0, 28.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [428.0, 134.0, 456.0, 62.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [2, 6], "products": [0]}], "corefs": [[1, 5], [0, 4]], "caption": "Table 1. Lactonization Study of Bn2N-R-Me-Ser", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 196, 699, 210], "ImageBB": [439, 218, 777, 430]}, "diagram_type": "single"}, {"id": 216, "width": 2808, "height": 1784, "file_name": "op030202q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1274.0, 149.9, 234.0, 101.1], "category_id": 2}, {"id": 1, "bbox": [882.2, 0.0, 224.8, 305.2], "category_id": 1}, {"id": 2, "bbox": [1697.8, 11.5, 229.9, 298.5], "category_id": 1}, {"id": 3, "bbox": [1274.0, 5.0, 234.0, 108.3], "category_id": 2}, {"id": 4, "bbox": [955.0, 366.0, 58.0, 70.0], "category_id": 3}, {"id": 5, "bbox": [1780.0, 363.0, 68.0, 70.0], "category_id": 3}, {"id": 6, "bbox": [38.0, 474.0, 2668.0, 1277.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [3, 0], "products": [2]}], "corefs": [[1, 4], [2, 5]], "caption": "Table 2. Aromatic ring hydrogenation of phenyl alanine: catalyst screening", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 490, 67], "ImageBB": [74, 83, 776, 529]}, "diagram_type": "single"}, {"id": 367, "width": 1352, "height": 1784, "file_name": "ol102784c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [38.0, 231.8, 240.6, 107.0], "category_id": 1}, {"id": 1, "bbox": [381.0, 367.0, 53.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [555.0, 2.0, 201.0, 52.0], "category_id": 2}, {"id": 3, "bbox": [482.0, 67.0, 355.0, 62.0], "category_id": 2}, {"id": 4, "bbox": [364.0, 38.0, 116.0, 45.0], "category_id": 2}, {"id": 5, "bbox": [189.0, 6.0, 152.0, 127.0], "category_id": 1}, {"id": 6, "bbox": [669.0, 133.0, 643.0, 252.0], "category_id": 1}, {"id": 7, "bbox": [873.0, 0.0, 290.0, 133.0], "category_id": 1}, {"id": 8, "bbox": [963.0, 367.0, 52.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [585.0, 367.0, 50.0, 39.0], "category_id": 3}, {"id": 10, "bbox": [146.0, 364.0, 47.0, 44.0], "category_id": 3}, {"id": 11, "bbox": [0.0, 430.8, 1352.0, 1353.2], "category_id": 4}, {"id": 12, "bbox": [536.09, 217.62, 217.5, 119.1], "category_id": 1}, {"id": 13, "bbox": [284.94, 194.31, 240.8, 147.59], "category_id": 1}], "reactions": [{"reactants": [5, 4], "conditions": [2, 3], "products": [7]}], "corefs": [[0, 10], [13, 1], [12, 9], [6, 8]], "caption": "Table 1. Optimization of Reaction Conditions in the Copper-Catalyzed Coupling of Iodobenzene and Potassium Thiocyanatea ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 342, 362, 383], "ImageBB": [58, 392, 396, 838]}, "diagram_type": "single"}, {"id": 1005, "width": 1348, "height": 556, "file_name": "ja954050t-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1066.8, 303.35, 275.13, 252.65], "category_id": 1}, {"id": 1, "bbox": [338.52, 155.72, 230.62, 45.16], "category_id": 2}, {"id": 2, "bbox": [662.2, 312.79, 40.46, 45.16], "category_id": 2}, {"id": 3, "bbox": [818.2, 156.39, 212.86, 45.17], "category_id": 2}, {"id": 4, "bbox": [823.37, 88.31, 190.16, 43.14], "category_id": 2}, {"id": 5, "bbox": [1002.07, 407.16, 53.27, 43.82], "category_id": 2}, {"id": 6, "bbox": [602.86, 122.01, 211.74, 50.56], "category_id": 2}, {"id": 7, "bbox": [0.0, 18.88, 299.41, 256.83], "category_id": 1}, {"id": 8, "bbox": [319.64, 91.68, 249.5, 41.12], "category_id": 2}, {"id": 9, "bbox": [0.0, 87.63, 2.7, 45.17], "category_id": 2}, {"id": 10, "bbox": [1056.01, 2.7, 291.99, 254.81], "category_id": 1}, {"id": 11, "bbox": [124.08, 315.48, 54.62, 45.84], "category_id": 3}], "caption": "Scheme 7", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 56, 485, 70], "ImageBB": [429, 75, 766, 214]}, "reactions": [{"reactants": [7], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [1], "products": [7]}, {"reactants": [6], "conditions": [4], "products": [10]}, {"reactants": [10], "conditions": [3], "products": [6]}, {"reactants": [6], "conditions": [2], "products": [0]}, {"reactants": [0], "conditions": [], "products": [6]}], "diagram_type": "tree"}, {"id": 40, "width": 1348, "height": 1012, "file_name": "ja5017206-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [63.44, 216.08, 139.06, 46.4], "category_id": 3}, {"id": 1, "bbox": [908.29, 217.39, 246.19, 45.09], "category_id": 3}, {"id": 2, "bbox": [225.4, 546.45, 161.26, 45.09], "category_id": 3}, {"id": 3, "bbox": [212.3, 824.59, 187.42, 43.79], "category_id": 3}, {"id": 4, "bbox": [772.49, 824.59, 187.42, 43.79], "category_id": 3}, {"id": 5, "bbox": [784.24, 546.45, 166.53, 45.09], "category_id": 3}, {"id": 6, "bbox": [13.81, 5.85, 251.39, 200.45], "category_id": 1}, {"id": 7, "bbox": [903.59, 6.16, 274.41, 200.61], "category_id": 1}, {"id": 8, "bbox": [1234.91, 71.75, 96.15, 43.0], "category_id": 3}, {"id": 9, "bbox": [178.35, 346.67, 256.63, 191.34], "category_id": 1}, {"id": 10, "bbox": [598.82, 346.67, 539.99, 191.34], "category_id": 1}, {"id": 11, "bbox": [179.65, 622.19, 251.41, 191.34], "category_id": 1}, {"id": 12, "bbox": [596.2, 622.19, 543.91, 192.65], "category_id": 1}, {"id": 13, "bbox": [357.24, 46.33, 277.53, 43.78], "category_id": 2}, {"id": 14, "bbox": [721.56, 47.63, 120.83, 43.79], "category_id": 2}, {"id": 15, "bbox": [372.91, 127.29, 242.27, 167.84], "category_id": 2}, {"id": 16, "bbox": [726.79, 128.59, 109.07, 35.96], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [13, 15, 14, 16], "products": [7, 8]}], "corefs": [[6, 0], [7, 1], [9, 2], [10, 5], [11, 3], [12, 4]], "caption": "Table 3. APF Rearrangement of Racemic (Z)-1 Catalyzed by (R)-3a as Reference for Crossover Experimentsa ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 125], "ImageBB": [449, 131, 786, 384]}, "diagram_type": "single"}, {"id": 882, "width": 1348, "height": 484, "file_name": "ol503618m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.0, 252.0, 370.0, 135.0], "category_id": 3}, {"id": 1, "bbox": [54.0, 207.0, 38.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [407.0, 206.0, 56.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [1141.0, 206.0, 32.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [997.0, 243.0, 186.0, 88.0], "category_id": 3}, {"id": 5, "bbox": [584.0, 121.0, 369.0, 83.0], "category_id": 2}, {"id": 6, "bbox": [3.0, 408.0, 1345.0, 76.0], "category_id": 4}, {"id": 7, "bbox": [324.7, 57.7, 192.4, 112.6], "category_id": 1}, {"id": 8, "bbox": [25.8, 8.7, 208.1, 242.0], "category_id": 1}, {"id": 9, "bbox": [577.0, 34.0, 353.0, 82.0], "category_id": 2}, {"id": 10, "bbox": [1034.3, 4.4, 294.0, 208.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [9, 5], "products": [10]}], "corefs": [[8, 1], [7, 2], [10, 3], [8, 0], [10, 4]], "caption": "Table 1. Optimization of the Reaction Parametersa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 138, 372, 157], "ImageBB": [82, 162, 419, 283]}, "diagram_type": "single"}, {"id": 1207, "width": 1352, "height": 1472, "file_name": "ol800418m-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [567.16, 1128.12, 215.07, 94.25], "category_id": 2}, {"id": 1, "bbox": [260.74, 252.57, 62.61, 48.6], "category_id": 3}, {"id": 2, "bbox": [1035.61, 773.19, 52.3, 50.81], "category_id": 3}, {"id": 3, "bbox": [563.47, 24.3, 209.19, 95.73], "category_id": 2}, {"id": 4, "bbox": [104.59, 1100.13, 364.6, 263.62], "category_id": 1}, {"id": 5, "bbox": [739.51, 335.05, 348.4, 146.53], "category_id": 2}, {"id": 6, "bbox": [526.65, 135.49, 282.84, 154.64], "category_id": 2}, {"id": 7, "bbox": [903.03, 534.6, 337.35, 234.9], "category_id": 1}, {"id": 8, "bbox": [261.48, 765.09, 55.98, 50.07], "category_id": 3}, {"id": 9, "bbox": [1072.44, 254.78, 55.25, 45.66], "category_id": 3}, {"id": 10, "bbox": [139.95, 905.0, 155.41, 101.62], "category_id": 2}, {"id": 11, "bbox": [109.01, 505.88, 360.18, 261.42], "category_id": 1}, {"id": 12, "bbox": [280.63, 1365.96, 67.03, 53.02], "category_id": 3}, {"id": 13, "bbox": [486.87, 1248.14, 403.64, 112.67], "category_id": 2}, {"id": 14, "bbox": [525.17, 546.39, 349.87, 105.3], "category_id": 2}, {"id": 15, "bbox": [868.41, 1093.51, 363.13, 270.24], "category_id": 1}, {"id": 16, "bbox": [1104.85, 372.6, 120.8, 64.8], "category_id": 2}, {"id": 17, "bbox": [525.91, 658.31, 349.13, 150.22], "category_id": 2}, {"id": 18, "bbox": [1038.56, 1363.75, 47.14, 50.08], "category_id": 3}, {"id": 19, "bbox": [329.25, 866.71, 702.68, 191.45], "category_id": 2}, {"id": 20, "bbox": [109.01, 0.0, 346.93, 245.95], "category_id": 1}, {"id": 21, "bbox": [902.3, 0.0, 340.29, 245.95], "category_id": 1}], "caption": "Scheme 4. Preparation of Diol 14", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [138, 74, 314, 89], "ImageBB": [58, 96, 396, 464]}, "reactions": [{"reactants": [20], "conditions": [3, 6], "products": [21]}, {"reactants": [21], "conditions": [5, 16], "products": [7]}, {"reactants": [7], "conditions": [14, 17], "products": [11]}, {"reactants": [11], "conditions": [10, 19], "products": [4]}, {"reactants": [4], "conditions": [0, 13], "products": [15]}], "diagram_type": "tree"}, {"id": 816, "width": 1348, "height": 496, "file_name": "jo4014707-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1086.0, 295.0, 144.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [65.5, 44.0, 185.5, 233.0], "category_id": 1}, {"id": 2, "bbox": [521.2, 0.3, 470.7, 149.5], "category_id": 2}, {"id": 3, "bbox": [1022.3, 47.0, 262.7, 229.0], "category_id": 1}, {"id": 4, "bbox": [314.14, 139.18, 178.92, 51.85], "category_id": 2}, {"id": 5, "bbox": [6.0, 379.0, 1334.0, 117.0], "category_id": 4}, {"id": 6, "bbox": [112.0, 301.0, 63.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [635.0, 186.0, 242.0, 49.0], "category_id": 2}, {"id": 8, "bbox": [379.0, 229.0, 53.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [2, 7], "products": [3]}], "corefs": [[1, 6], [4, 8], [3, 0]], "caption": "Table 3. Asymmetric 1,4-Addition of 2a to N-Me-maleimide (6a)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 417, 125], "ImageBB": [82, 131, 419, 255]}, "diagram_type": "single"}, {"id": 955, "width": 1704, "height": 1188, "file_name": "acs.orglett.6b01059-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [234.42, 379.47, 92.91, 63.96], "category_id": 3}, {"id": 1, "bbox": [503.97, 566.15, 139.77, 108.39], "category_id": 1}, {"id": 2, "bbox": [300.03, 578.99, 162.58, 52.77], "category_id": 2}, {"id": 3, "bbox": [185.94, 544.76, 58.47, 42.78], "category_id": 2}, {"id": 4, "bbox": [328.55, 263.8, 159.73, 52.77], "category_id": 2}, {"id": 5, "bbox": [310.01, 316.57, 79.87, 37.08], "category_id": 2}, {"id": 6, "bbox": [245.83, 221.02, 35.66, 39.93], "category_id": 2}, {"id": 7, "bbox": [144.58, 285.2, 38.5, 38.5], "category_id": 2}, {"id": 8, "bbox": [1222.76, 510.53, 85.57, 44.21], "category_id": 2}, {"id": 9, "bbox": [1237.02, 404.99, 136.92, 54.2], "category_id": 2}, {"id": 10, "bbox": [1163.56, 737.62, 41.77, 44.35], "category_id": 3}, {"id": 11, "bbox": [981.14, 470.71, 329.04, 240.48], "category_id": 1}, {"id": 12, "bbox": [981.14, 126.21, 114.23, 43.49], "category_id": 2}, {"id": 13, "bbox": [811.51, 239.62, 58.82, 45.2], "category_id": 3}, {"id": 14, "bbox": [95.47, 422.11, 150.03, 59.69], "category_id": 2}, {"id": 15, "bbox": [627.39, 722.27, 60.52, 53.73], "category_id": 3}, {"id": 16, "bbox": [705.81, 648.08, 315.4, 240.48], "category_id": 1}, {"id": 17, "bbox": [561.75, 661.73, 44.33, 47.75], "category_id": 3}, {"id": 18, "bbox": [519.13, 166.28, 190.94, 115.13], "category_id": 1}, {"id": 19, "bbox": [768.04, 871.5, 47.73, 47.76], "category_id": 3}, {"id": 20, "bbox": [685.35, 3.41, 283.86, 241.33], "category_id": 1}, {"id": 21, "bbox": [575.39, 263.5, 57.96, 43.49], "category_id": 3}, {"id": 22, "bbox": [981.14, 169.7, 394.68, 240.47], "category_id": 1}], "caption": "Scheme 3. Proposed Mechanism", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 797, 633, 812], "ImageBB": [433, 830, 859, 1127]}, "reactions": [{"reactants": [1], "conditions": [15], "products": [16]}, {"reactants": [16], "conditions": [], "products": [11]}, {"reactants": [11, 8], "conditions": [], "products": [22, 9]}, {"reactants": [22], "conditions": [12], "products": [20]}, {"reactants": [6, 4, 5], "conditions": [], "products": [7, 0, 14]}, {"reactants": [14], "conditions": [3], "products": [2]}, {"reactants": [18, 2], "conditions": [], "products": [4, 1]}], "diagram_type": "graph"}, {"id": 920, "width": 2820, "height": 1096, "file_name": "acs.joc.5b02237-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1355.69, 286.41, 47.96, 49.39], "category_id": 3}, {"id": 1, "bbox": [1819.81, 105.82, 187.62, 60.67], "category_id": 2}, {"id": 2, "bbox": [1524.97, 33.86, 260.98, 80.42], "category_id": 2}, {"id": 3, "bbox": [1433.28, 616.57, 272.26, 274.13], "category_id": 1}, {"id": 4, "bbox": [1165.38, 887.21, 68.06, 53.17], "category_id": 3}, {"id": 5, "bbox": [1529.05, 889.34, 63.8, 53.17], "category_id": 3}, {"id": 6, "bbox": [1437.51, 445.85, 850.65, 173.54], "category_id": 2}, {"id": 7, "bbox": [1783.13, 678.65, 93.11, 55.02], "category_id": 2}, {"id": 8, "bbox": [1527.79, 145.32, 255.34, 52.21], "category_id": 2}, {"id": 9, "bbox": [1719.65, 746.37, 221.48, 53.61], "category_id": 2}, {"id": 10, "bbox": [1132.8, 67.72, 80.41, 57.85], "category_id": 2}, {"id": 11, "bbox": [804.1, 0.0, 272.27, 279.36], "category_id": 1}, {"id": 12, "bbox": [1101.58, 215.18, 153.13, 42.53], "category_id": 2}, {"id": 13, "bbox": [591.18, 449.11, 663.53, 168.01], "category_id": 2}, {"id": 14, "bbox": [1958.06, 613.74, 276.5, 280.77], "category_id": 1}, {"id": 15, "bbox": [907.08, 286.41, 36.68, 45.15], "category_id": 3}, {"id": 16, "bbox": [2052.58, 893.1, 84.64, 53.62], "category_id": 3}, {"id": 17, "bbox": [636.23, 894.51, 64.89, 42.33], "category_id": 3}, {"id": 18, "bbox": [536.07, 613.74, 266.62, 275.13], "category_id": 1}, {"id": 19, "bbox": [536.07, 967.88, 847.83, 81.83], "category_id": 2}, {"id": 20, "bbox": [1132.8, 145.32, 80.41, 57.85], "category_id": 2}, {"id": 21, "bbox": [1059.44, 620.8, 259.57, 245.5], "category_id": 1}, {"id": 22, "bbox": [804.1, 736.49, 249.7, 52.21], "category_id": 2}, {"id": 23, "bbox": [1254.12, 0.0, 265.21, 280.77], "category_id": 1}, {"id": 24, "bbox": [1132.8, 375.3, 526.19, 53.62], "category_id": 2}], "caption": "Scheme 1. Photochemical Transformations of Stilbenes/Diarylethenes", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 476, 110], "ImageBB": [82, 116, 787, 390]}, "reactions": [{"reactants": [11], "conditions": [10, 20, 12], "products": [23]}, {"reactants": [23], "conditions": [2, 8], "products": [1]}, {"reactants": [18], "conditions": [22], "products": [21]}, {"reactants": [3], "conditions": [7, 9], "products": [14]}], "diagram_type": "multiple"}, {"id": 374, "width": 1416, "height": 908, "file_name": "ol1018773-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [370.7, 669.2, 458.6, 147.9], "category_id": 1}, {"id": 1, "bbox": [631.3, 861.0, 48.7, 47.0], "category_id": 3}, {"id": 2, "bbox": [1180.0, 861.0, 41.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [356.0, 571.0, 47.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [121.7, 218.3, 452.3, 330.7], "category_id": 1}, {"id": 5, "bbox": [870.5, 220.6, 490.2, 340.7], "category_id": 1}, {"id": 6, "bbox": [1010.3, 690.6, 350.6, 172.4], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [0, 6]}], "corefs": [[4, 3], [0, 1], [6, 2]], "caption": "Figure 1. Retrosynthesis of 1 highlighting the chirons from stereoselective hydrogenations. ", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 834, 760, 862], "ImageBB": [408, 600, 762, 827]}, "diagram_type": "multiple"}, {"id": 316, "width": 1344, "height": 1332, "file_name": "ol3023903-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [319.0, 371.0, 39.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [125.0, 1118.0, 1079.0, 214.0], "category_id": 2}, {"id": 2, "bbox": [574.0, 301.0, 246.0, 80.0], "category_id": 2}, {"id": 3, "bbox": [331.0, 1074.0, 268.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [941.0, 371.0, 39.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [198.9, 815.9, 404.0, 282.0], "category_id": 1}, {"id": 6, "bbox": [825.0, 1069.0, 326.0, 46.1], "category_id": 3}, {"id": 7, "bbox": [258.0, 161.7, 286.9, 207.3], "category_id": 1}, {"id": 8, "bbox": [878.1, 207.7, 164.2, 156.6], "category_id": 1}, {"id": 9, "bbox": [641.4, 443.9, 565.9, 271.5], "category_id": 1}, {"id": 10, "bbox": [603.0, 163.4, 172.4, 108.7], "category_id": 1}, {"id": 11, "bbox": [796.7, 782.3, 329.0, 252.4], "category_id": 1}, {"id": 12, "bbox": [854.0, 683.43, 275.0, 49.0], "category_id": 3}, {"id": 13, "bbox": [136.0, 426.7, 499.0, 260.3], "category_id": 1}, {"id": 14, "bbox": [210.0, 683.0, 302.7, 52.9], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [10, 2], "products": [8]}], "corefs": [[7, 0], [8, 4], [13, 14], [9, 12], [5, 3], [11, 6]], "caption": "Figure 2. Synthesis of trifluoromethyl olefins via strategy A.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 1007, 756, 1020], "ImageBB": [437, 661, 773, 994]}, "diagram_type": "single"}, {"id": 42, "width": 1352, "height": 344, "file_name": "ja5017206-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [790.24, 46.64, 242.62, 90.7], "category_id": 2}, {"id": 1, "bbox": [1071.65, 43.58, 242.62, 173.29], "category_id": 1}, {"id": 2, "bbox": [528.2, 44.6, 237.53, 169.21], "category_id": 1}, {"id": 3, "bbox": [23.49, 44.6, 233.45, 170.23], "category_id": 1}, {"id": 4, "bbox": [234.55, 157.77, 271.18, 79.49], "category_id": 2}, {"id": 5, "bbox": [1025.73, 248.99, 297.72, 86.66], "category_id": 2}, {"id": 6, "bbox": [572.0, 241.85, 124.39, 30.59], "category_id": 2}, {"id": 7, "bbox": [302.86, 93.54, 144.75, 41.76], "category_id": 2}, {"id": 8, "bbox": [786.16, 155.73, 242.62, 80.51], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [7, 4], "products": [2]}, {"reactants": [2], "conditions": [0, 8], "products": [1]}], "corefs": [[2, 6], [1, 5]], "caption": "Figure 1. Catalytic sequence for providing optically active \u03b2-amino aldehydes having an alkyl substituent at the \u03b2-position. 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Synthetic route and conditions used for large-scale production of 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 509, 67], "ImageBB": [160, 71, 690, 666]}, "reactions": [{"reactants": [15], "conditions": [19, 4], "products": [28]}, {"reactants": [28], "conditions": [2], "products": [37]}, {"reactants": [28], "conditions": [39], "products": [37]}, {"reactants": [37], "conditions": [5], "products": [11]}, {"reactants": [11], "conditions": [3, 6], "products": [10]}, {"reactants": [10], "conditions": [14, 24], "products": [30]}, {"reactants": [30], "conditions": [9], "products": [34]}, {"reactants": [34], "conditions": [17, 32], "products": [33]}, {"reactants": [33], "conditions": [12, 26], "products": [29]}, {"reactants": [29], "conditions": [31], "products": [38, 22]}, {"reactants": [35], "conditions": [0], "products": [25, 1]}, {"reactants": [8], "conditions": [], "products": [27]}], "diagram_type": "tree"}, {"id": 1342, "width": 2152, "height": 736, "file_name": "op700026n-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1779.52, 0.0, 346.64, 320.74], "category_id": 1}, {"id": 1, "bbox": [629.77, 660.84, 47.37, 51.67], "category_id": 3}, {"id": 2, "bbox": [1137.9, 4.31, 345.57, 314.27], "category_id": 1}, {"id": 3, "bbox": [1982.98, 307.82, 50.6, 51.66], "category_id": 3}, {"id": 4, "bbox": [1000.1, 552.14, 46.3, 49.51], "category_id": 3}, {"id": 5, "bbox": [1503.92, 108.71, 218.54, 55.96], "category_id": 2}, {"id": 6, "bbox": [385.4, 424.06, 402.63, 311.94], "category_id": 1}, {"id": 7, "bbox": [1331.68, 311.05, 48.44, 44.13], "category_id": 3}, {"id": 8, "bbox": [348.8, 127.0, 180.86, 47.36], "category_id": 2}, {"id": 9, "bbox": [709.44, 309.97, 48.44, 47.36], "category_id": 3}, {"id": 10, "bbox": [0.0, 4.31, 375.71, 309.97], "category_id": 1}, {"id": 11, "bbox": [123.8, 308.9, 45.22, 48.43], "category_id": 3}, {"id": 12, "bbox": [1638.49, 663.0, 455.38, 59.19], "category_id": 3}, {"id": 13, "bbox": [865.54, 395.0, 447.84, 222.79], "category_id": 1}, {"id": 14, "bbox": [1418.88, 395.0, 733.12, 314.28], "category_id": 1}, {"id": 15, "bbox": [535.04, 3.23, 376.79, 313.2], "category_id": 1}, {"id": 16, "bbox": [87.2, 504.78, 110.88, 53.82], "category_id": 2}], "caption": "Scheme 1. Synthesis of amide 1 (MK-0364, taranabant) via resolution", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 465, 67], "ImageBB": [156, 71, 694, 255]}, "reactions": [{"reactants": [10], "conditions": [8], "products": [15]}, {"reactants": [15], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [5], "products": [0]}, {"reactants": [0], "conditions": [16], "products": [6]}, {"reactants": [6, 13], "conditions": [], "products": [14]}], "diagram_type": "multiple"}, {"id": 151, "width": 1012, "height": 680, "file_name": "op700178q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [110.0, 479.0, 146.0, 51.0], "category_id": 2}, {"id": 1, "bbox": [64.0, 576.0, 261.0, 67.0], "category_id": 2}, {"id": 2, "bbox": [686.6, 29.8, 324.4, 257.2], "category_id": 1}, {"id": 3, "bbox": [1.5, 36.7, 311.8, 255.4], "category_id": 1}, {"id": 4, "bbox": [412.2, 423.8, 515.4, 256.2], "category_id": 1}, {"id": 5, "bbox": [984.0, 267.0, 28.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [262.0, 263.0, 47.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [727.0, 630.0, 53.0, 48.0], "category_id": 3}, {"id": 8, "bbox": [390.0, 59.0, 193.0, 60.0], "category_id": 2}, {"id": 9, "bbox": [394.0, 169.0, 118.0, 44.0], "category_id": 2}, {"id": 10, "bbox": [394.0, 249.0, 161.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [8, 9, 10], "products": [2]}, {"reactants": [2], "conditions": [0, 1], "products": [4]}], "corefs": [[3, 6], [2, 5], [4, 7]], "caption": "Table 1. Catalyst N-substituent optimisation studya", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 456, 341, 470], "ImageBB": [158, 275, 411, 445]}, "diagram_type": "multiple"}, {"id": 566, "width": 1352, "height": 896, "file_name": "acs.orglett.5b01077-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [481.0, 178.0, 331.0, 67.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 472.0, 1339.0, 415.0], "category_id": 4}, {"id": 2, "bbox": [521.0, 258.0, 232.0, 96.0], "category_id": 2}, {"id": 3, "bbox": [459.0, 78.0, 192.0, 58.0], "category_id": 2}, {"id": 4, "bbox": [502.0, 371.0, 187.0, 55.0], "category_id": 2}, {"id": 5, "bbox": [52.0, 354.0, 194.0, 58.0], "category_id": 2}, {"id": 6, "bbox": [1261.0, 396.0, 48.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [17.5, 130.0, 252.5, 200.6], "category_id": 1}, {"id": 8, "bbox": [284.8, 13.8, 197.2, 185.1], "category_id": 1}, {"id": 9, "bbox": [806.3, 4.0, 521.2, 450.1], "category_id": 1}, {"id": 10, "bbox": [300.2, 236.2, 197.5, 186.5], "category_id": 1}], "reactions": [{"reactants": [7, 8, 10], "conditions": [0, 2], "products": [9]}], "corefs": [[9, 6]], "caption": "Table 3. Competition Experiments", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 542, 275, 558], "ImageBB": [82, 563, 420, 787]}, "diagram_type": "single"}, {"id": 597, "width": 2820, "height": 3484, "file_name": "acs.oprd.6b00117-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2127.0, 261.0, 63.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [475.11, 41.06, 329.0, 230.0], "category_id": 1}, {"id": 2, "bbox": [1291.0, 0.0, 496.0, 120.0], "category_id": 2}, {"id": 3, "bbox": [1388.0, 172.0, 286.0, 94.0], "category_id": 2}, {"id": 4, "bbox": [622.0, 257.0, 29.0, 36.0], "category_id": 3}, {"id": 5, "bbox": [1000.0, 266.0, 59.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 321.0, 2820.0, 898.0], "category_id": 4}, {"id": 7, "bbox": [1893.0, 1292.0, 471.0, 285.0], "category_id": 1}, {"id": 8, "bbox": [1288.0, 1306.0, 487.0, 96.0], "category_id": 2}, {"id": 9, "bbox": [1397.0, 1466.0, 277.0, 99.0], "category_id": 2}, {"id": 10, "bbox": [606.0, 1555.0, 25.0, 33.0], "category_id": 3}, {"id": 11, "bbox": [988.0, 1554.0, 52.0, 36.0], "category_id": 3}, {"id": 12, "bbox": [2135.0, 1552.0, 68.0, 43.0], "category_id": 3}, {"id": 13, "bbox": [914.1, 1343.0, 215.6, 199.1], "category_id": 1}, {"id": 14, "bbox": [453.11, 1340.0, 333.0, 219.0], "category_id": 1}, {"id": 15, "bbox": [1871.89, 0.0, 468.61, 276.1], "category_id": 1}, {"id": 16, "bbox": [914.11, 49.83, 229.59, 204.97], "category_id": 1}], "reactions": [{"reactants": [1, 16], "conditions": [2, 3], "products": [15]}, {"reactants": [14, 13], "conditions": [8, 9], "products": [7]}], "corefs": [[1, 4], [16, 5], [15, 0], [14, 10], [13, 11], [7, 12]], "caption": "Table 2. Solvent Screening for the Radical Arylation of Quinoline N-Oxide 16", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 513, 111], "ImageBB": [82, 116, 787, 987]}, "diagram_type": "multiple"}, {"id": 379, "width": 1288, "height": 1792, "file_name": "ol071386m-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [625.0, 52.0, 190.0, 43.0], "category_id": 2}, {"id": 1, "bbox": [651.0, 120.0, 128.0, 92.0], "category_id": 2}, {"id": 2, "bbox": [863.0, 0.0, 274.0, 146.0], "category_id": 1}, {"id": 3, "bbox": [963.0, 163.0, 30.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [3.0, 236.0, 1285.0, 1556.0], "category_id": 4}, {"id": 5, "bbox": [242.0, 167.0, 30.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [404.0, 84.0, 138.0, 51.0], "category_id": 1}, {"id": 7, "bbox": [473.0, 172.0, 39.0, 30.0], "category_id": 3}, {"id": 8, "bbox": [142.4, 28.0, 187.6, 116.0], "category_id": 1}], "reactions": [{"reactants": [8, 6], "conditions": [0, 1], "products": [2]}], "corefs": [[8, 5], [6, 7], [2, 3]], "caption": "Table 2. Pt/SPOs-Catalyzed [2 + 1] Cycloaddition of 4 with 5aa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 475, 736, 507], "ImageBB": [447, 513, 769, 961]}, "diagram_type": "single"}, {"id": 855, "width": 2808, "height": 3020, "file_name": "jo200666z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.0, 405.0, 2765.0, 2615.0], "category_id": 4}, {"id": 1, "bbox": [877.0, 263.0, 34.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [1171.0, 255.0, 40.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [1790.0, 263.0, 28.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [1134.0, 118.0, 130.0, 95.0], "category_id": 1}, {"id": 5, "bbox": [1279.0, 169.0, 356.0, 95.0], "category_id": 2}, {"id": 6, "bbox": [1261.0, 79.0, 343.0, 51.0], "category_id": 2}, {"id": 7, "bbox": [1645.0, 17.0, 418.0, 323.0], "category_id": 1}, {"id": 8, "bbox": [741.0, 8.0, 359.0, 242.0], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [6, 5], "products": [7]}], "corefs": [[8, 1], [4, 2], [7, 3]], "caption": "Table 2. Alkenylation of 2-(Phenylsul\ufb01nyl)pyridines with Alkenesa", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 441, 108], "ImageBB": [71, 117, 773, 872]}, "diagram_type": "single"}, {"id": 36, "width": 1348, "height": 1444, "file_name": "ja5080739-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [70.41, 28.42, 202.19, 108.59], "category_id": 1}, {"id": 1, "bbox": [601.23, 95.15, 289.73, 79.13], "category_id": 2}, {"id": 2, "bbox": [601.66, 12.82, 315.3, 80.43], "category_id": 2}, {"id": 3, "bbox": [1056.22, 27.98, 255.07, 110.77], "category_id": 1}, {"id": 4, "bbox": [301.37, 5.02, 249.43, 159.73], "category_id": 1}, {"id": 5, "bbox": [1.21, 173.2, 1336.07, 1267.11], "category_id": 4}, {"id": 6, "bbox": [1106.06, 133.71, 25.4, 34.07], "category_id": 3}, {"id": 7, "bbox": [483.37, 134.15, 43.59, 33.2], "category_id": 3}, {"id": 8, "bbox": [112.44, 135.01, 19.76, 33.2], "category_id": 3}], "reactions": [{"reactants": [0, 4], "conditions": [2, 1], "products": [3]}], "corefs": [[0, 8], [4, 7], [3, 6]], "caption": "Table 4. Scope of the Asymmetric Reactiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 596, 702, 617], "ImageBB": [449, 623, 786, 984]}, "diagram_type": "single"}, {"id": 559, "width": 1348, "height": 388, "file_name": "acs.orglett.5b02003-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [155.0, 220.0, 59.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [492.0, 216.0, 64.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [655.0, 78.0, 335.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [12.0, 309.0, 1333.0, 74.0], "category_id": 4}, {"id": 4, "bbox": [1110.92, 248.02, 83.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [385.0, 49.1, 278.1, 165.9], "category_id": 1}, {"id": 6, "bbox": [722.2, 140.0, 184.6, 50.0], "category_id": 2}, {"id": 7, "bbox": [981.2, 1.0, 347.6, 253.0], "category_id": 1}, {"id": 8, "bbox": [25.3, 29.0, 341.7, 199.0], "category_id": 1}], "reactions": [{"reactants": [8, 5], "conditions": [2, 6], "products": [7]}], "corefs": [[8, 0], [5, 1], [7, 4]], "caption": "Table 1. Screening of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 288, 352, 309], "ImageBB": [82, 315, 419, 412]}, "diagram_type": "single"}, {"id": 152, "width": 1352, "height": 1204, "file_name": "op7001694-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 902.0, 1351.0, 270.0], "category_id": 2}, {"id": 1, "bbox": [435.0, 57.0, 283.0, 59.0], "category_id": 2}, {"id": 2, "bbox": [983.0, 226.23, 52.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [795.0, 3.0, 399.5, 197.0], "category_id": 1}, {"id": 4, "bbox": [151.0, 45.0, 265.0, 160.0], "category_id": 1}, {"id": 5, "bbox": [259.0, 227.0, 47.9, 56.0], "category_id": 3}, {"id": 6, "bbox": [46.0, 289.0, 1250.0, 598.0], "category_id": 4}, {"id": 7, "bbox": [519.0, 154.0, 112.0, 57.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [1, 7], "products": [3]}], "corefs": [[4, 5], [3, 2]], "caption": "Table 1. Solvent effect on the decarboxylative Blaise reaction of 4a ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 259, 347, 286], "ImageBB": [58, 301, 396, 602]}, "diagram_type": "single"}, {"id": 925, "width": 1352, "height": 1264, "file_name": "acs.joc.6b01262-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 611.53, 238.75, 171.82], "category_id": 1}, {"id": 1, "bbox": [310.44, 654.14, 170.44, 126.5], "category_id": 1}, {"id": 2, "bbox": [16.23, 117.03, 233.34, 165.06], "category_id": 1}, {"id": 3, "bbox": [29.08, 311.85, 808.23, 52.77], "category_id": 2}, {"id": 4, "bbox": [826.49, 627.08, 306.38, 171.83], "category_id": 1}, {"id": 5, "bbox": [16.23, 1001.17, 294.89, 161.68], "category_id": 1}, {"id": 6, "bbox": [24.35, 562.82, 665.51, 46.68], "category_id": 2}, {"id": 7, "bbox": [787.26, 987.64, 305.03, 171.15], "category_id": 1}, {"id": 8, "bbox": [308.41, 191.44, 71.02, 38.56], "category_id": 2}, {"id": 9, "bbox": [533.63, 683.91, 152.85, 48.7], "category_id": 2}, {"id": 10, "bbox": [394.98, 225.94, 259.04, 41.94], "category_id": 2}, {"id": 11, "bbox": [442.33, 1111.43, 260.39, 94.03], "category_id": 2}, {"id": 12, "bbox": [702.04, 158.29, 175.17, 47.36], "category_id": 2}, {"id": 13, "bbox": [856.24, 347.7, 304.36, 168.44], "category_id": 1}, {"id": 14, "bbox": [938.76, 97.41, 305.7, 169.79], "category_id": 1}, {"id": 15, "bbox": [16.23, 375.44, 228.6, 168.44], "category_id": 1}, {"id": 16, "bbox": [733.15, 219.85, 110.24, 41.94], "category_id": 2}, {"id": 17, "bbox": [422.04, 1019.44, 296.23, 63.58], "category_id": 2}, {"id": 18, "bbox": [486.29, 477.59, 280.68, 73.05], "category_id": 2}, {"id": 19, "bbox": [303.0, 442.41, 134.59, 51.41], "category_id": 2}, {"id": 20, "bbox": [551.89, 744.79, 114.98, 45.32], "category_id": 2}, {"id": 21, "bbox": [483.58, 380.85, 229.96, 79.15], "category_id": 2}, {"id": 22, "bbox": [826.49, 1170.96, 297.58, 42.62], "category_id": 2}, {"id": 23, "bbox": [861.65, 803.64, 296.92, 43.97], "category_id": 2}, {"id": 24, "bbox": [45.8, 888.2, 537.2, 88.62], "category_id": 2}, {"id": 25, "bbox": [956.34, 269.91, 296.24, 75.76], "category_id": 2}, {"id": 26, "bbox": [871.8, 526.97, 296.91, 43.97], "category_id": 2}, {"id": 27, "bbox": [34.15, 1.53, 257.96, 51.57], "category_id": 2}, {"id": 28, "bbox": [361.91, 127.47, 315.62, 83.46], "category_id": 2}, {"id": 29, "bbox": [38.71, 71.33, 641.86, 53.11], "category_id": 2}], "caption": "Scheme 1. Di\ufb00erent Approaches to Primary \u03b1-Ketoamides", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 367, 411, 387], "ImageBB": [82, 392, 420, 708]}, "reactions": [{"reactants": [2, 8], "conditions": [28, 10, 12, 16], "products": [14]}, {"reactants": [15, 19], "conditions": [21, 18], "products": [13]}, {"reactants": [0, 1], "conditions": [9, 20], "products": [4]}, {"reactants": [5], "conditions": [17, 11], "products": [7]}], "diagram_type": "multiple"}, {"id": 708, "width": 1316, "height": 1588, "file_name": "ol0349920-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [25.5, 4.1, 287.5, 217.5], "category_id": 1}, {"id": 1, "bbox": [315.13, 31.87, 285.0, 84.0], "category_id": 2}, {"id": 2, "bbox": [966.0, 69.0, 104.0, 52.9], "category_id": 2}, {"id": 3, "bbox": [330.51, 115.13, 255.0, 148.5], "category_id": 2}, {"id": 4, "bbox": [622.29, 2.1, 324.91, 188.39], "category_id": 1}, {"id": 5, "bbox": [1108.0, 57.0, 186.0, 140.0], "category_id": 1}, {"id": 6, "bbox": [949.0, 121.0, 133.0, 44.0], "category_id": 2}, {"id": 7, "bbox": [87.0, 208.0, 58.0, 61.0], "category_id": 3}, {"id": 8, "bbox": [676.0, 205.0, 78.0, 67.0], "category_id": 3}, {"id": 9, "bbox": [1178.0, 205.0, 61.0, 61.0], "category_id": 3}, {"id": 10, "bbox": [17.0, 304.0, 1299.0, 1284.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [1, 3], "products": [4]}, {"reactants": [4], "conditions": [2, 6], "products": [5]}], "corefs": [[0, 7], [4, 8], [5, 9]], "caption": "Table 2. 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Synthesis of the Bromide 12", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 643, 102], "ImageBB": [437, 111, 773, 531]}, "reactions": [{"reactants": [11], "conditions": [19, 4], "products": [5]}, {"reactants": [5], "conditions": [15, 9], "products": [6]}, {"reactants": [6], "conditions": [18, 3], "products": [1]}, {"reactants": [1], "conditions": [17, 21, 16], "products": [10]}, {"reactants": [10], "conditions": [22, 0], "products": [20]}], "diagram_type": "tree"}, {"id": 1216, "width": 1352, "height": 1196, "file_name": "ol9005322-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [302.32, 566.19, 282.71, 78.47], "category_id": 2}, {"id": 1, "bbox": [136.62, 489.07, 45.99, 44.65], "category_id": 2}, {"id": 2, "bbox": [136.62, 915.91, 44.64, 45.32], "category_id": 2}, {"id": 3, "bbox": [135.94, 16.23, 46.67, 49.39], "category_id": 2}, {"id": 4, "bbox": [676.34, 516.81, 129.86, 431.57], "category_id": 1}, {"id": 5, "bbox": [158.26, 976.79, 93.34, 161.67], "category_id": 1}, {"id": 6, "bbox": [713.54, 1009.94, 254.3, 49.38], "category_id": 2}, {"id": 7, "bbox": [1133.54, 625.71, 49.38, 50.06], "category_id": 3}, {"id": 8, "bbox": [522.13, 0.0, 137.3, 486.37], "category_id": 1}, {"id": 9, "bbox": [543.78, 978.14, 140.67, 163.03], "category_id": 1}, {"id": 10, "bbox": [158.26, 546.57, 136.62, 209.7], "category_id": 1}, {"id": 11, "bbox": [256.33, 133.26, 123.77, 233.38], "category_id": 1}, {"id": 12, "bbox": [808.22, 602.04, 265.13, 48.03], "category_id": 2}, {"id": 13, "bbox": [890.06, 654.8, 96.72, 41.94], "category_id": 2}, {"id": 14, "bbox": [832.57, 794.15, 48.02, 46.0], "category_id": 3}, {"id": 15, "bbox": [913.06, 379.49, 58.16, 51.41], "category_id": 3}, {"id": 16, "bbox": [1030.74, 1028.88, 180.58, 56.82], "category_id": 1}, {"id": 17, "bbox": [319.23, 1007.23, 147.44, 52.09], "category_id": 2}, {"id": 18, "bbox": [302.32, 654.13, 260.39, 41.94], "category_id": 2}, {"id": 19, "bbox": [280.68, 383.55, 41.26, 45.32], "category_id": 3}, {"id": 20, "bbox": [835.28, 48.03, 242.8, 302.37], "category_id": 1}, {"id": 21, "bbox": [171.11, 791.44, 56.82, 46.0], "category_id": 3}, {"id": 22, "bbox": [676.34, 380.16, 53.43, 50.74], "category_id": 3}], "caption": "Scheme 3. (a) Nitrile Oxide Precursors 9-11, (b) Synthesis of  the Dabcyl-Oxime 10, and (c) Depiction of the Nitrile Oxide            Preparation via Hydroximoyl Chlorides ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [64, 179, 388, 221], "ImageBB": [58, 229, 396, 528]}, "reactions": [{"reactants": [10], "conditions": [0, 18], "products": [4]}, {"reactants": [4], "conditions": [12, 13], "products": [7]}, {"reactants": [5], "conditions": [17], "products": [9]}, {"reactants": [9], "conditions": [6], "products": [16]}], "diagram_type": "multiple"}, {"id": 1377, "width": 1128, "height": 1016, "file_name": "op990067a-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [870.69, 817.97, 157.43, 46.82], "category_id": 2}, {"id": 1, "bbox": [5.08, 190.11, 59.25, 46.25], "category_id": 3}, {"id": 2, "bbox": [921.47, 230.72, 105.52, 39.49], "category_id": 2}, {"id": 3, "bbox": [640.46, 401.09, 47.96, 36.1], "category_id": 3}, {"id": 4, "bbox": [116.81, 99.85, 211.6, 101.54], "category_id": 2}, {"id": 5, "bbox": [843.6, 76.72, 253.93, 118.46], "category_id": 2}, {"id": 6, "bbox": [919.78, 746.32, 30.47, 50.78], "category_id": 3}, {"id": 7, "bbox": [352.68, 5.08, 468.35, 397.7], "category_id": 1}, {"id": 8, "bbox": [733.0, 248.8, 87.47, 81.77], "category_id": 2}, {"id": 9, "bbox": [459.27, 828.75, 86.42, 79.87], "category_id": 2}, {"id": 10, "bbox": [808.85, 446.44, 291.97, 154.5], "category_id": 4}, {"id": 11, "bbox": [76.74, 584.42, 473.44, 406.17], "category_id": 1}], "caption": "Scheme 5", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [467, 73, 749, 327]}, "reactions": [{"reactants": [1], "conditions": [4], "products": [7]}, {"reactants": [7], "conditions": [5, 2], "products": [11]}, {"reactants": [11], "conditions": [], "products": [6]}], "diagram_type": "multiple"}, {"id": 876, "width": 1352, "height": 660, "file_name": "ol701624y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [852.1, 190.17, 140.72, 47.48], "category_id": 2}, {"id": 1, "bbox": [11.0, 322.0, 1334.0, 327.0], "category_id": 4}, {"id": 2, "bbox": [853.0, 27.0, 409.0, 211.0], "category_id": 1}, {"id": 3, "bbox": [266.0, 256.0, 86.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1054.0, 256.0, 81.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [511.0, 146.0, 280.0, 121.0], "category_id": 2}, {"id": 6, "bbox": [514.0, 8.0, 239.0, 96.0], "category_id": 2}, {"id": 7, "bbox": [85.14, 19.86, 385.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [6, 5], "products": [2]}], "corefs": [[7, 3], [2, 4]], "caption": "Table 2.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 798, 120, 811], "ImageBB": [73, 814, 411, 979]}, "diagram_type": "single"}, {"id": 905, "width": 1352, "height": 1312, "file_name": "acs.joc.5b01547-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [228.0, 10.0, 192.0, 180.0], "category_id": 1}, {"id": 1, "bbox": [305.0, 218.0, 31.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [967.0, 216.0, 39.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [441.0, 44.0, 350.0, 46.0], "category_id": 2}, {"id": 4, "bbox": [437.0, 111.0, 391.0, 101.8], "category_id": 2}, {"id": 5, "bbox": [869.0, 6.0, 246.0, 183.0], "category_id": 1}, {"id": 6, "bbox": [2.0, 276.0, 1350.0, 1033.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [3, 4], "products": [5]}], "corefs": [[0, 1], [5, 2]], "caption": "Table 1. Synthesis of \u03b1-Functionalized Trichloromethylcarbinols 2a-la ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 366, 299, 400], "ImageBB": [82, 407, 420, 735]}, "diagram_type": "single"}, {"id": 1223, "width": 1324, "height": 572, "file_name": "op010068e-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [502.71, 513.21, 250.36, 52.97], "category_id": 2}, {"id": 1, "bbox": [0.0, 143.04, 53.65, 47.01], "category_id": 3}, {"id": 2, "bbox": [245.06, 2.65, 332.49, 307.92], "category_id": 1}, {"id": 3, "bbox": [623.92, 98.01, 143.06, 50.32], "category_id": 2}, {"id": 4, "bbox": [199.36, 489.37, 27.82, 43.04], "category_id": 3}, {"id": 5, "bbox": [1057.74, 85.42, 219.23, 55.63], "category_id": 2}, {"id": 6, "bbox": [917.99, 305.28, 52.99, 39.07], "category_id": 3}, {"id": 7, "bbox": [260.96, 409.9, 712.67, 90.73], "category_id": 2}, {"id": 8, "bbox": [617.29, 165.55, 157.64, 48.34], "category_id": 2}, {"id": 9, "bbox": [1053.77, 488.04, 153.0, 46.36], "category_id": 3}, {"id": 10, "bbox": [400.71, 324.48, 60.27, 41.06], "category_id": 3}, {"id": 11, "bbox": [75.51, 101.32, 125.84, 56.28], "category_id": 2}, {"id": 12, "bbox": [806.06, 5.96, 215.92, 292.03], "category_id": 1}], "caption": "Scheme 8", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 172, 135, 186], "ImageBB": [77, 192, 408, 335]}, "reactions": [{"reactants": [1], "conditions": [11], "products": [2]}, {"reactants": [2], "conditions": [3, 8], "products": [12]}, {"reactants": [12], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [7, 0], "products": [9]}], "diagram_type": "multiple"}, {"id": 537, "width": 1692, "height": 1828, "file_name": "jo000081h-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [859.38, 13.3, 289.19, 130.0], "category_id": 1}, {"id": 1, "bbox": [980.0, 1724.0, 202.0, 56.8], "category_id": 2}, {"id": 2, "bbox": [306.5, 348.0, 1058.9, 141.5], "category_id": 1}, {"id": 3, "bbox": [477.5, 0.7, 166.7, 138.2], "category_id": 1}, {"id": 4, "bbox": [8.0, 1076.0, 403.0, 301.1], "category_id": 1}, {"id": 5, "bbox": [561.0, 1082.0, 401.0, 286.1], "category_id": 1}, {"id": 6, "bbox": [57.0, 1571.5, 340.0, 256.5], "category_id": 1}, {"id": 7, "bbox": [1081.0, 1076.0, 418.0, 294.0], "category_id": 1}, {"id": 8, "bbox": [509.0, 1503.0, 455.0, 325.0], "category_id": 1}, {"id": 9, "bbox": [471.0, 722.0, 142.0, 106.0], "category_id": 2}, {"id": 10, "bbox": [422.0, 1082.0, 146.0, 113.0], "category_id": 2}, {"id": 11, "bbox": [966.0, 1091.0, 133.0, 99.0], "category_id": 2}, {"id": 12, "bbox": [1398.0, 391.0, 72.0, 61.0], "category_id": 3}, {"id": 13, "bbox": [1212.24, 931.28, 265.31, 47.72], "category_id": 2}, {"id": 14, "bbox": [1211.0, 1580.9, 338.0, 247.1], "category_id": 1}, {"id": 15, "bbox": [404.0, 1605.7, 182.0, 82.3], "category_id": 2}, {"id": 16, "bbox": [1038.0, 578.0, 457.0, 426.4], "category_id": 1}, {"id": 17, "bbox": [543.0, 592.0, 432.8, 412.0], "category_id": 1}, {"id": 18, "bbox": [10.0, 603.7, 439.3, 390.4], "category_id": 1}, {"id": 19, "bbox": [1497.0, 598.0, 166.5, 140.0], "category_id": 2}, {"id": 20, "bbox": [981.2, 1528.4, 220.8, 159.6], "category_id": 2}], "reactions": [{"reactants": [16], "conditions": [19], "products": [4]}, {"reactants": [4], "conditions": [10], "products": [5]}, {"reactants": [5], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [15], "products": [8]}, {"reactants": [8], "conditions": [20, 1], "products": [14]}], "corefs": [[2, 12]], "caption": "Figure 4. Proposed terpenoid biosynthetic pathway, based upon 13C acetate labeling studies, for the production of the mangicol carbon skeleton. ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 535, 775, 562], "ImageBB": [214, 65, 637, 522]}, "diagram_type": "tree"}, {"id": 268, "width": 1356, "height": 3796, "file_name": "ol801035c-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 438.8, 1356.0, 2974.2], "category_id": 4}, {"id": 1, "bbox": [318.0, 194.0, 43.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [255.0, 304.0, 771.0, 77.0], "category_id": 2}, {"id": 3, "bbox": [411.0, 150.0, 464.0, 163.0], "category_id": 2}, {"id": 4, "bbox": [478.0, 71.0, 321.0, 50.0], "category_id": 2}, {"id": 5, "bbox": [109.0, 0.0, 280.0, 194.0], "category_id": 1}, {"id": 6, "bbox": [811.0, 0.0, 445.0, 194.0], "category_id": 1}, {"id": 7, "bbox": [2.0, 3431.0, 1354.0, 365.0], "category_id": 2}, {"id": 8, "bbox": [995.0, 191.0, 110.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 3], "products": [6]}], "corefs": [[5, 1], [6, 8]], "caption": "Table 2. Direct regioselective C-2 arylation of 2", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 677, 88], "ImageBB": [424, 97, 763, 1046]}, "diagram_type": "single"}, {"id": 684, "width": 1344, "height": 2048, "file_name": "ol4013926-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 1227.0, 1336.0, 821.0], "category_id": 4}, {"id": 1, "bbox": [205.0, 834.0, 98.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [668.0, 829.0, 105.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [1076.0, 831.0, 122.0, 48.0], "category_id": 3}, {"id": 4, "bbox": [630.0, 236.0, 238.0, 141.0], "category_id": 2}, {"id": 5, "bbox": [1052.0, 317.0, 78.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [342.9, 148.1, 263.7, 293.3], "category_id": 1}, {"id": 7, "bbox": [460.2, 459.4, 422.8, 363.32], "category_id": 1}, {"id": 8, "bbox": [29.8, 461.0, 428.8, 355.3], "category_id": 1}, {"id": 9, "bbox": [883.6, 458.7, 433.4, 371.3], "category_id": 1}, {"id": 10, "bbox": [662.0, 93.4, 189.2, 108.7], "category_id": 2}, {"id": 11, "bbox": [891.0, 92.0, 421.2, 242.0], "category_id": 1}, {"id": 12, "bbox": [509.0, 889.0, 494.0, 333.0], "category_id": 3}, {"id": 13, "bbox": [18.0, 885.0, 487.0, 294.0], "category_id": 3}, {"id": 14, "bbox": [1001.0, 885.0, 249.0, 101.0], "category_id": 3}, {"id": 15, "bbox": [60.4, 1.2, 430.6, 234.8], "category_id": 1}], "reactions": [{"reactants": [15, 6], "conditions": [10, 4], "products": [11]}], "corefs": [[11, 5], [8, 1], [8, 13], [7, 2], [7, 12], [9, 3], [9, 14]], "caption": "Table 1. Effect of Catalystsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 221, 101], "ImageBB": [71, 112, 407, 624]}, "diagram_type": "single"}, {"id": 7, "width": 1356, "height": 500, "file_name": "jacs.5b05415-Figure-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [797.21, 451.89, 142.27, 39.23], "category_id": 3}, {"id": 1, "bbox": [315.77, 372.22, 326.71, 89.46], "category_id": 2}, {"id": 2, "bbox": [360.79, 267.45, 239.26, 85.13], "category_id": 2}, {"id": 3, "bbox": [368.59, 148.82, 221.94, 46.16], "category_id": 2}, {"id": 4, "bbox": [360.79, 44.91, 239.26, 85.13], "category_id": 2}, {"id": 5, "bbox": [715.81, 274.38, 299.01, 167.38], "category_id": 1}, {"id": 6, "bbox": [18.76, 293.43, 239.24, 128.42], "category_id": 1}, {"id": 7, "bbox": [724.47, 55.3, 299.01, 170.86], "category_id": 1}, {"id": 8, "bbox": [17.03, 57.9, 238.39, 166.52], "category_id": 1}, {"id": 9, "bbox": [1036.2, 119.38, 304.19, 79.07], "category_id": 3}, {"id": 10, "bbox": [1089.88, 276.11, 229.73, 165.65], "category_id": 1}, {"id": 11, "bbox": [1123.65, 451.89, 159.6, 39.23], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [4, 3], "products": [7]}, {"reactants": [6], "conditions": [2, 1], "products": [5, 10]}], "corefs": [[7, 9], [5, 0], [10, 11]], "caption": "Figure 6. Achieving cyclization via synergistic catalysis.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 356, 711, 370], "ImageBB": [448, 222, 787, 347]}, "diagram_type": "multiple"}, {"id": 90, "width": 1348, "height": 1920, "file_name": "ja053650h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [490.55, 84.21, 311.53, 46.22], "category_id": 2}, {"id": 1, "bbox": [951.35, 63.27, 339.46, 218.43], "category_id": 1}, {"id": 2, "bbox": [57.68, 7.41, 316.18, 220.76], "category_id": 1}, {"id": 3, "bbox": [474.26, 158.68, 358.07, 46.22], "category_id": 2}, {"id": 4, "bbox": [6.5, 300.65, 1340.16, 1617.12], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [0, 3], "products": [1]}], "corefs": [], "caption": "Table 2. Intramolecular Carbonylation of 2-(2-Iodophenoxy)aniline (3, R1 ) R2 ) H, X ) I) with Different Palladium-Complexed Dendrimersa ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 772, 100], "ImageBB": [439, 102, 776, 582]}, "diagram_type": "single"}, {"id": 567, "width": 1352, "height": 1368, "file_name": "acs.orglett.5b01077-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1012.0, 237.0, 87.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [220.0, 237.0, 49.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [607.0, 127.0, 291.0, 48.0], "category_id": 2}, {"id": 3, "bbox": [390.0, 21.0, 182.0, 206.0], "category_id": 1}, {"id": 4, "bbox": [868.0, 0.0, 410.0, 249.0], "category_id": 1}, {"id": 5, "bbox": [608.0, 2.0, 366.0, 106.0], "category_id": 2}, {"id": 6, "bbox": [456.0, 229.0, 95.0, 52.0], "category_id": 3}, {"id": 7, "bbox": [76.0, 16.0, 250.0, 197.0], "category_id": 1}, {"id": 8, "bbox": [26.0, 302.0, 1307.0, 1066.0], "category_id": 4}], "reactions": [{"reactants": [7, 3], "conditions": [5, 2], "products": [4]}], "corefs": [[7, 1], [3, 6], [4, 0]], "caption": "Table 2. Nitrone Scopea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 586, 111], "ImageBB": [448, 116, 786, 458]}, "diagram_type": "single"}, {"id": 1154, "width": 1352, "height": 1048, "file_name": "ol051365x-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [913.06, 762.43, 384.83, 186.05], "category_id": 1}, {"id": 1, "bbox": [449.09, 431.62, 77.78, 43.29], "category_id": 2}, {"id": 2, "bbox": [1080.11, 946.45, 50.05, 46.0], "category_id": 3}, {"id": 3, "bbox": [871.8, 516.86, 103.48, 51.41], "category_id": 2}, {"id": 4, "bbox": [703.39, 211.75, 137.97, 168.45], "category_id": 1}, {"id": 5, "bbox": [664.16, 261.81, 48.02, 35.86], "category_id": 2}, {"id": 6, "bbox": [49.37, 8.79, 236.72, 181.31], "category_id": 1}, {"id": 7, "bbox": [526.19, 396.44, 336.14, 184.69], "category_id": 1}, {"id": 8, "bbox": [913.06, 4.06, 393.63, 184.69], "category_id": 1}, {"id": 9, "bbox": [858.95, 408.62, 124.45, 54.12], "category_id": 2}, {"id": 10, "bbox": [158.26, 816.56, 118.36, 64.26], "category_id": 2}, {"id": 11, "bbox": [242.81, 663.66, 137.97, 107.57], "category_id": 2}, {"id": 12, "bbox": [669.57, 31.12, 202.91, 51.41], "category_id": 2}, {"id": 13, "bbox": [1092.29, 581.13, 40.58, 48.03], "category_id": 3}, {"id": 14, "bbox": [503.2, 186.72, 51.4, 47.35], "category_id": 3}, {"id": 15, "bbox": [444.35, 512.12, 102.13, 47.36], "category_id": 2}, {"id": 16, "bbox": [1097.02, 654.19, 102.8, 95.39], "category_id": 2}, {"id": 17, "bbox": [974.6, 391.7, 331.41, 189.43], "category_id": 1}, {"id": 18, "bbox": [664.16, 104.86, 232.66, 94.04], "category_id": 2}, {"id": 19, "bbox": [1092.29, 232.05, 200.19, 140.55], "category_id": 2}, {"id": 20, "bbox": [150.15, 190.78, 37.2, 44.65], "category_id": 3}, {"id": 21, "bbox": [208.99, 593.98, 49.37, 45.33], "category_id": 3}, {"id": 22, "bbox": [329.38, 8.79, 324.64, 181.31], "category_id": 1}, {"id": 23, "bbox": [1085.52, 187.4, 35.85, 46.67], "category_id": 3}, {"id": 24, "bbox": [54.78, 403.88, 387.55, 190.1], "category_id": 1}, {"id": 25, "bbox": [630.35, 585.19, 42.61, 43.97], "category_id": 3}], "caption": "Scheme 1. Synthesis of Twisted \u03c0-System Molecule TM-1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [85, 546, 398, 559], "ImageBB": [73, 563, 411, 825]}, "reactions": [{"reactants": [6, 22], "conditions": [12, 18], "products": [8]}, {"reactants": [8], "conditions": [19], "products": [17]}, {"reactants": [17], "conditions": [9, 3], "products": [7]}, {"reactants": [7], "conditions": [1, 15], "products": [24]}, {"reactants": [24], "conditions": [11], "products": [10]}, {"reactants": [17], "conditions": [16], "products": [0]}], "diagram_type": "tree"}, {"id": 1339, "width": 1704, "height": 1192, "file_name": "op5003165-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [302.61, 11.09, 242.94, 301.91], "category_id": 1}, {"id": 1, "bbox": [1136.28, 540.71, 492.71, 303.62], "category_id": 1}, {"id": 2, "bbox": [1310.18, 875.03, 57.96, 46.91], "category_id": 3}, {"id": 3, "bbox": [901.01, 356.5, 37.51, 39.23], "category_id": 3}, {"id": 4, "bbox": [302.61, 534.74, 485.88, 301.92], "category_id": 1}, {"id": 5, "bbox": [826.0, 28.14, 244.65, 303.62], "category_id": 1}, {"id": 6, "bbox": [900.16, 683.14, 130.42, 45.2], "category_id": 2}, {"id": 7, "bbox": [612.89, 100.64, 137.25, 51.17], "category_id": 2}, {"id": 8, "bbox": [916.36, 619.18, 99.73, 42.64], "category_id": 2}, {"id": 9, "bbox": [1349.39, 448.6, 203.73, 79.32], "category_id": 2}, {"id": 10, "bbox": [479.92, 875.89, 50.29, 44.35], "category_id": 3}, {"id": 11, "bbox": [1310.18, 348.82, 53.7, 46.91], "category_id": 3}, {"id": 12, "bbox": [1184.02, 7.68, 343.53, 232.83], "category_id": 1}, {"id": 13, "bbox": [364.84, 353.08, 38.36, 40.09], "category_id": 3}, {"id": 14, "bbox": [609.48, 173.13, 152.59, 75.91], "category_id": 2}], "caption": "Scheme 5. Formation of core 10", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 797, 266, 812], "ImageBB": [10, 829, 436, 1127]}, "reactions": [{"reactants": [0], "conditions": [7, 14], "products": [5]}, {"reactants": [5, 12], "conditions": [9], "products": [1]}, {"reactants": [1], "conditions": [8, 6], "products": [4]}], "diagram_type": "tree"}, {"id": 104, "width": 1348, "height": 1320, "file_name": "ja011003u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [217.17, 362.46, 182.55, 46.28], "category_id": 3}, {"id": 1, "bbox": [266.57, 1263.46, 56.5, 47.99], "category_id": 3}, {"id": 2, "bbox": [1000.66, 898.97, 56.5, 47.99], "category_id": 3}, {"id": 3, "bbox": [6.33, 7.47, 577.72, 293.65], "category_id": 1}, {"id": 4, "bbox": [761.97, 505.54, 575.83, 363.73], "category_id": 1}, {"id": 5, "bbox": [57.46, 825.6, 539.85, 388.34], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [5]}], "corefs": [[3, 0], [4, 2], [5, 1]], "caption": "Table 2. Experimental and Calculated (DFT) 13C NMR Spectra", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 466, 756, 480], "ImageBB": [440, 125, 777, 455]}, "diagram_type": "tree"}, {"id": 1246, "width": 2192, "height": 1352, "file_name": "op034033l-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [915.62, 204.0, 207.25, 57.04], "category_id": 2}, {"id": 1, "bbox": [0.0, 769.94, 357.47, 137.1], "category_id": 1}, {"id": 2, "bbox": [731.4, 201.81, 126.1, 63.61], "category_id": 2}, {"id": 3, "bbox": [733.59, 103.1, 127.2, 64.71], "category_id": 2}, {"id": 4, "bbox": [1248.97, 489.17, 356.38, 137.1], "category_id": 1}, {"id": 5, "bbox": [537.31, 773.23, 175.45, 140.39], "category_id": 1}, {"id": 6, "bbox": [1463.89, 717.3, 327.87, 185.36], "category_id": 1}, {"id": 7, "bbox": [915.62, 105.29, 276.33, 62.52], "category_id": 2}, {"id": 8, "bbox": [731.4, 347.68, 51.54, 58.13], "category_id": 2}, {"id": 9, "bbox": [803.77, 303.81, 168.87, 136.0], "category_id": 1}, {"id": 10, "bbox": [648.06, 545.1, 166.68, 64.71], "category_id": 2}, {"id": 11, "bbox": [1699.65, 527.55, 175.45, 70.2], "category_id": 2}, {"id": 12, "bbox": [237.95, 99.81, 131.59, 58.13], "category_id": 2}, {"id": 13, "bbox": [26.32, 202.91, 235.76, 64.71], "category_id": 2}, {"id": 14, "bbox": [16.45, 508.91, 346.51, 197.42], "category_id": 1}, {"id": 15, "bbox": [26.32, 99.81, 172.16, 58.13], "category_id": 2}, {"id": 16, "bbox": [9.9, 316.97, 342.09, 133.81], "category_id": 1}, {"id": 17, "bbox": [0.0, 976.14, 561.3, 68.06], "category_id": 2}, {"id": 18, "bbox": [19.8, 1258.6, 108.3, 45.5], "category_id": 2}, {"id": 19, "bbox": [813.7, 822.1, 158.3, 51.5], "category_id": 2}, {"id": 20, "bbox": [1415.1, 1102.9, 264.44, 40.22], "category_id": 2}, {"id": 21, "bbox": [453.97, 554.97, 97.59, 58.13], "category_id": 2}, {"id": 22, "bbox": [1977.08, 522.07, 62.82, 60.33], "category_id": 2}, {"id": 23, "bbox": [1421.7, 1243.8, 267.1, 44.1], "category_id": 2}, {"id": 24, "bbox": [1898.3, 796.27, 126.7, 59.23], "category_id": 2}, {"id": 25, "bbox": [26.4, 2.43, 512.45, 56.2], "category_id": 2}, {"id": 26, "bbox": [1780.33, 1286.88, 128.94, 47.94], "category_id": 2}, {"id": 27, "bbox": [1598.49, 1286.88, 115.71, 51.24], "category_id": 2}, {"id": 28, "bbox": [1464.59, 1286.88, 87.61, 49.59], "category_id": 2}, {"id": 29, "bbox": [1915.88, 1243.9, 186.8, 49.59], "category_id": 2}, {"id": 30, "bbox": [1734.04, 1243.9, 132.25, 44.63], "category_id": 2}, {"id": 31, "bbox": [1777.02, 1144.71, 128.94, 46.29], "category_id": 2}, {"id": 32, "bbox": [1593.53, 1144.71, 114.06, 51.25], "category_id": 2}, {"id": 33, "bbox": [1462.93, 1144.71, 85.96, 51.25], "category_id": 2}, {"id": 34, "bbox": [1986.96, 1103.39, 191.74, 46.31], "category_id": 2}, {"id": 35, "bbox": [1730.73, 1101.73, 206.64, 47.94], "category_id": 2}, {"id": 36, "bbox": [269.4, 1306.72, 148.78, 44.63], "category_id": 2}, {"id": 37, "bbox": [72.68, 1305.06, 150.43, 46.29], "category_id": 2}, {"id": 38, "bbox": [537.2, 1257.12, 284.33, 54.56], "category_id": 2}, {"id": 39, "bbox": [366.93, 1257.12, 110.76, 52.9], "category_id": 2}, {"id": 40, "bbox": [161.95, 1258.78, 157.04, 51.24], "category_id": 2}, {"id": 41, "bbox": [269.4, 1138.1, 148.78, 44.63], "category_id": 2}, {"id": 42, "bbox": [72.68, 1136.45, 150.43, 46.28], "category_id": 2}, {"id": 43, "bbox": [623.16, 1088.51, 287.64, 54.55], "category_id": 2}, {"id": 44, "bbox": [363.63, 1088.51, 203.33, 54.55], "category_id": 2}, {"id": 45, "bbox": [160.3, 1088.51, 157.04, 51.24], "category_id": 2}, {"id": 46, "bbox": [13.17, 1088.51, 114.06, 51.24], "category_id": 2}, {"id": 47, "bbox": [2071.27, 804.18, 117.37, 52.9], "category_id": 2}, {"id": 48, "bbox": [2091.11, 523.15, 85.96, 57.86], "category_id": 2}], "caption": "Scheme 2. Relevant Equations for the One-Pot Synthesis of Oxazolidinone 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 228, 501, 242], "ImageBB": [151, 246, 699, 584]}, "reactions": [{"reactants": [15, 12], "conditions": [], "products": [3, 7]}, {"reactants": [13], "conditions": [], "products": [2, 0]}, {"reactants": [16], "conditions": [], "products": [9]}, {"reactants": [14, 21, 10], "conditions": [], "products": [4, 11, 22, 48]}, {"reactants": [1, 5, 19], "conditions": [], "products": [6, 24, 47]}, {"reactants": [46, 45, 44, 43, 42, 41], "conditions": [], "products": [20, 35, 34, 33, 32, 31]}, {"reactants": [18, 40, 39, 38, 37, 36], "conditions": [], "products": [23, 30, 29, 28, 27, 26]}], "diagram_type": "multiple"}, {"id": 1218, "width": 1352, "height": 812, "file_name": "ol901760a-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [690.54, 0.0, 154.21, 249.44], "category_id": 1}, {"id": 1, "bbox": [848.8, 688.16, 35.85, 42.59], "category_id": 3}, {"id": 2, "bbox": [259.04, 334.62, 204.93, 79.09], "category_id": 2}, {"id": 3, "bbox": [572.86, 672.61, 235.36, 78.42], "category_id": 3}, {"id": 4, "bbox": [436.91, 37.18, 190.73, 80.44], "category_id": 2}, {"id": 5, "bbox": [777.11, 283.24, 180.79, 56.86], "category_id": 1}, {"id": 6, "bbox": [1023.3, 0.0, 135.27, 259.58], "category_id": 1}, {"id": 7, "bbox": [184.64, 0.0, 204.93, 250.12], "category_id": 1}, {"id": 8, "bbox": [748.71, 225.78, 83.86, 40.56], "category_id": 3}, {"id": 9, "bbox": [604.65, 404.92, 135.94, 256.2], "category_id": 1}, {"id": 10, "bbox": [896.82, 73.68, 109.57, 43.27], "category_id": 2}, {"id": 11, "bbox": [436.91, 137.23, 199.52, 48.67], "category_id": 2}, {"id": 12, "bbox": [827.84, 402.21, 198.84, 300.14], "category_id": 1}, {"id": 13, "bbox": [896.82, 135.87, 100.1, 39.89], "category_id": 2}, {"id": 14, "bbox": [239.42, 249.44, 144.06, 48.0], "category_id": 3}, {"id": 15, "bbox": [778.47, 346.11, 211.69, 40.56], "category_id": 2}, {"id": 16, "bbox": [1070.64, 263.64, 93.34, 42.58], "category_id": 3}], "caption": "Scheme 4. Base-Free Cyclization of Enynylpyridine Z-1b and        Intermediate Carbene-Trapping Experiments ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [66, 653, 386, 681], "ImageBB": [58, 689, 396, 892]}, "reactions": [{"reactants": [7], "conditions": [2], "products": [9, 12]}, {"reactants": [7], "conditions": [4, 11], "products": [0]}, {"reactants": [0], "conditions": [10, 13], "products": [6]}, {"reactants": [0, 5], "conditions": [15], "products": [9, 12]}], "diagram_type": "graph"}, {"id": 1035, "width": 1132, "height": 728, "file_name": "jo001614p-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 266.8, 399.8, 57.21], "category_id": 2}, {"id": 1, "bbox": [181.21, 671.82, 44.74, 52.68], "category_id": 3}, {"id": 2, "bbox": [104.2, 457.7, 229.91, 199.96], "category_id": 1}, {"id": 3, "bbox": [555.52, 64.58, 48.7, 53.24], "category_id": 2}, {"id": 4, "bbox": [855.09, 451.47, 195.37, 229.98], "category_id": 1}, {"id": 5, "bbox": [795.82, 270.92, 331.23, 44.58], "category_id": 2}, {"id": 6, "bbox": [536.27, 5.1, 115.52, 47.01], "category_id": 1}, {"id": 7, "bbox": [769.58, 10.76, 161.92, 63.14], "category_id": 1}, {"id": 8, "bbox": [361.29, 594.78, 439.43, 66.84], "category_id": 2}, {"id": 9, "bbox": [416.78, 457.7, 327.88, 51.55], "category_id": 2}, {"id": 10, "bbox": [945.69, 672.95, 40.21, 47.58], "category_id": 3}, {"id": 11, "bbox": [813.18, 98.56, 140.44, 58.35], "category_id": 2}, {"id": 12, "bbox": [190.84, 45.88, 182.34, 143.32], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [101, 83, 384, 265]}, "reactions": [{"reactants": [2], "conditions": [8], "products": [4]}, {"reactants": [4], "conditions": [9], "products": [2]}, {"reactants": [2], "conditions": [0], "products": [12, 6]}, {"reactants": [6, 7, 11], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [], "products": [6]}], "diagram_type": "graph"}, {"id": 541, "width": 1348, "height": 392, "file_name": "acs.orglett.6b00233-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [210.9, 248.0, 50.1, 45.0], "category_id": 3}, {"id": 1, "bbox": [443.0, 9.9, 210.0, 94.1], "category_id": 2}, {"id": 2, "bbox": [739.9, 39.9, 128.1, 51.1], "category_id": 2}, {"id": 3, "bbox": [965.0, 10.0, 373.0, 212.8], "category_id": 1}, {"id": 4, "bbox": [6.0, 313.0, 1342.0, 78.0], "category_id": 4}, {"id": 5, "bbox": [725.0, 140.0, 227.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [14.0, 4.0, 370.0, 227.0], "category_id": 1}, {"id": 7, "bbox": [1181.0, 254.0, 27.0, 38.0], "category_id": 3}, {"id": 8, "bbox": [459.0, 143.0, 124.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [1, 8, 2, 5], "products": [3]}], "corefs": [[6, 0], [3, 7]], "caption": "Table 3. Reaction with Carbon Nucleophilesa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 548, 336, 569], "ImageBB": [82, 575, 419, 673]}, "diagram_type": "single"}, {"id": 417, "width": 1352, "height": 800, "file_name": "op400055z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 471.0, 1342.0, 328.0], "category_id": 4}, {"id": 1, "bbox": [2.0, 0.0, 326.0, 227.0], "category_id": 1}, {"id": 2, "bbox": [609.0, 36.0, 82.0, 73.0], "category_id": 2}, {"id": 3, "bbox": [388.0, 118.0, 538.0, 337.0], "category_id": 1}, {"id": 4, "bbox": [901.0, 388.0, 40.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [1164.0, 235.0, 108.0, 62.0], "category_id": 3}, {"id": 6, "bbox": [81.0, 227.0, 115.0, 51.0], "category_id": 3}, {"id": 7, "bbox": [1026.0, 1.0, 323.0, 227.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2, 3], "products": [7]}], "corefs": [[1, 6], [3, 4], [7, 5]], "caption": "Table 1. Asymmetric hydrogenation of enamides using 9 as catalysta ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 404, 417, 434], "ImageBB": [82, 440, 420, 640]}, "diagram_type": "single"}, {"id": 703, "width": 1352, "height": 1676, "file_name": "ol035681s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [359.87, 148.49, 60.81, 63.24], "category_id": 2}, {"id": 1, "bbox": [654.0, 251.0, 295.0, 76.0], "category_id": 2}, {"id": 2, "bbox": [31.0, 340.0, 1276.0, 1336.0], "category_id": 4}, {"id": 3, "bbox": [934.0, 36.0, 416.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [359.1, 0.0, 522.9, 116.4], "category_id": 2}, {"id": 5, "bbox": [413.0, 150.0, 248.0, 171.0], "category_id": 1}, {"id": 6, "bbox": [3.0, 38.2, 331.0, 172.8], "category_id": 1}, {"id": 7, "bbox": [145.75, 226.86, 44.94, 56.16], "category_id": 3}, {"id": 8, "bbox": [1078.11, 229.1, 42.69, 56.17], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [4, 0, 5, 1], "products": [3]}], "corefs": [[6, 7], [3, 8]], "caption": "Table 3. Cu(II)-Catalyzed N-Arylation of 1,4-Dioxa-8-azaspiro[4.5]decanea ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 296, 104], "ImageBB": [74, 109, 412, 528]}, "diagram_type": "single"}, {"id": 432, "width": 3396, "height": 1160, "file_name": "op300101d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1671.0, 54.0, 51.0, 35.0], "category_id": 2}, {"id": 1, "bbox": [1447.0, 238.0, 29.0, 35.0], "category_id": 3}, {"id": 2, "bbox": [1930.0, 239.0, 24.0, 32.0], "category_id": 3}, {"id": 3, "bbox": [300.0, 306.0, 2809.0, 612.0], "category_id": 4}, {"id": 4, "bbox": [1390.0, 9.0, 138.0, 186.0], "category_id": 1}, {"id": 5, "bbox": [1884.0, 18.0, 114.0, 190.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [5]}], "corefs": [[4, 1], [5, 2]], "caption": "Table 2. Familiarization runs using cyclohexanone oxime 4 as model substratea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 810, 530, 831], "ImageBB": [10, 837, 859, 1127]}, "diagram_type": "single"}, {"id": 578, "width": 1348, "height": 332, "file_name": "acs.orglett.5b00663-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [837.0, 4.0, 316.0, 152.0], "category_id": 1}, {"id": 1, "bbox": [297.0, 151.0, 48.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [960.0, 149.0, 40.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [6.0, 210.0, 1334.0, 122.0], "category_id": 2}, {"id": 4, "bbox": [540.0, 22.0, 252.0, 75.0], "category_id": 2}, {"id": 5, "bbox": [586.0, 110.0, 164.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [199.0, 54.0, 281.0, 103.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 5], "products": [0]}], "corefs": [[6, 1], [0, 2]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 366, 109], "ImageBB": [82, 116, 419, 199]}, "diagram_type": "single"}, {"id": 558, "width": 1348, "height": 352, "file_name": "acs.orglett.5b02003-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [490.92, 201.03, 41.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [128.0, 199.0, 61.0, 49.9], "category_id": 3}, {"id": 2, "bbox": [1148.92, 209.97, 41.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [987.0, 1.0, 342.9, 237.0], "category_id": 1}, {"id": 4, "bbox": [644.3, 67.0, 332.3, 46.1], "category_id": 2}, {"id": 5, "bbox": [20.2, 24.1, 321.7, 184.8], "category_id": 1}, {"id": 6, "bbox": [366.0, 39.0, 273.0, 156.0], "category_id": 1}, {"id": 7, "bbox": [745.17, 126.68, 86.41, 42.69], "category_id": 2}, {"id": 8, "bbox": [8.0, 279.0, 1333.0, 73.0], "category_id": 4}], "reactions": [{"reactants": [5, 6], "conditions": [4, 7], "products": [3]}], "corefs": [[5, 1], [6, 0], [3, 2]], "caption": "Table 2. Scope of Cyclopropane 1,1-Diestersa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 709, 110], "ImageBB": [449, 116, 786, 204]}, "diagram_type": "single"}, {"id": 1343, "width": 2136, "height": 804, "file_name": "op700026n-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 4.27, 343.0, 313.99], "category_id": 1}, {"id": 1, "bbox": [1185.0, 39.52, 313.09, 107.86], "category_id": 2}, {"id": 2, "bbox": [767.21, 4.27, 351.55, 311.86], "category_id": 1}, {"id": 3, "bbox": [712.71, 751.87, 47.02, 50.2], "category_id": 3}, {"id": 4, "bbox": [465.88, 176.22, 101.51, 49.13], "category_id": 2}, {"id": 5, "bbox": [373.99, 0.0, 319.49, 148.45], "category_id": 2}, {"id": 6, "bbox": [1586.77, 4.27, 353.69, 313.99], "category_id": 1}, {"id": 7, "bbox": [1401.92, 466.71, 734.08, 315.06], "category_id": 1}, {"id": 8, "bbox": [922.15, 402.63, 445.57, 221.08], "category_id": 1}, {"id": 9, "bbox": [1073.88, 578.85, 42.74, 45.93], "category_id": 3}, {"id": 10, "bbox": [1307.89, 189.04, 99.37, 48.06], "category_id": 2}, {"id": 11, "bbox": [424.21, 466.71, 477.63, 315.06], "category_id": 1}, {"id": 12, "bbox": [45.95, 524.39, 292.78, 100.39], "category_id": 2}, {"id": 13, "bbox": [260.72, 242.44, 48.09, 51.26], "category_id": 3}, {"id": 14, "bbox": [1766.29, 726.24, 231.87, 55.53], "category_id": 3}, {"id": 15, "bbox": [141.05, 657.89, 102.58, 56.6], "category_id": 2}, {"id": 16, "bbox": [1807.96, 243.5, 56.63, 51.27], "category_id": 3}, {"id": 17, "bbox": [1027.93, 244.57, 47.02, 48.06], "category_id": 3}, {"id": 18, "bbox": [1002.29, 653.61, 267.13, 114.28], "category_id": 2}], "caption": "Scheme 5. Synthesis of amide 1 (MK-0364, taranabant) from bromo alcohol 5", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 510, 67], "ImageBB": [158, 71, 692, 272]}, "reactions": [{"reactants": [0], "conditions": [5, 4], "products": [2]}, {"reactants": [2], "conditions": [1, 10], "products": [6]}, {"reactants": [6], "conditions": [12, 15], "products": [11]}, {"reactants": [11, 8], "conditions": [18], "products": [7]}], "diagram_type": "multiple"}, {"id": 220, "width": 1348, "height": 1044, "file_name": "op0256183-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.0, 253.8, 1345.0, 790.2], "category_id": 4}, {"id": 1, "bbox": [476.0, 123.0, 349.0, 102.0], "category_id": 2}, {"id": 2, "bbox": [42.0, 16.0, 372.0, 125.0], "category_id": 1}, {"id": 3, "bbox": [508.0, 26.0, 271.0, 46.0], "category_id": 2}, {"id": 4, "bbox": [942.0, 12.0, 378.0, 136.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [3, 1], "products": [4]}], "corefs": [], "caption": "Table 1. Effect of reduced precatalyst loadings", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 444, 698, 458], "ImageBB": [439, 462, 776, 723]}, "diagram_type": "single"}, {"id": 237, "width": 1344, "height": 948, "file_name": "op000061h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [62.8, 209.2, 43.6, 50.8], "category_id": 3}, {"id": 1, "bbox": [206.54, 162.44, 164.92, 64.74], "category_id": 2}, {"id": 2, "bbox": [17.1, 43.0, 177.0, 158.0], "category_id": 1}, {"id": 3, "bbox": [850.55, 204.0, 55.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [258.5, 88.5, 76.6, 62.5], "category_id": 1}, {"id": 5, "bbox": [1079.9, 30.8, 250.5, 167.5], "category_id": 1}, {"id": 6, "bbox": [401.0, 2.0, 381.0, 106.7], "category_id": 2}, {"id": 7, "bbox": [807.7, 26.3, 282.0, 173.8], "category_id": 1}, {"id": 8, "bbox": [1115.0, 202.93, 53.8, 56.4], "category_id": 3}, {"id": 9, "bbox": [18.0, 300.0, 1326.0, 648.0], "category_id": 4}, {"id": 10, "bbox": [450.0, 131.0, 274.0, 119.3], "category_id": 2}], "reactions": [{"reactants": [2, 4], "conditions": [6, 10], "products": [7, 5]}], "corefs": [[2, 0], [7, 3], [5, 8]], "caption": "Table 1. Effect of transition metal salt on aerobic oxidation of 3-methylpyridine (1) by NHPIa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 401, 81], "ImageBB": [74, 88, 410, 326]}, "diagram_type": "single"}, {"id": 1333, "width": 2820, "height": 1732, "file_name": "op400269b-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [538.89, 905.35, 210.19, 53.59], "category_id": 2}, {"id": 1, "bbox": [223.0, 587.3, 775.0, 285.62], "category_id": 1}, {"id": 2, "bbox": [853.48, 208.71, 36.68, 46.54], "category_id": 3}, {"id": 3, "bbox": [538.89, 1633.01, 225.71, 55.0], "category_id": 2}, {"id": 4, "bbox": [234.18, 73.33, 125.55, 200.25], "category_id": 1}, {"id": 5, "bbox": [444.37, 104.35, 167.88, 45.13], "category_id": 2}, {"id": 6, "bbox": [478.23, 196.02, 86.05, 47.94], "category_id": 2}, {"id": 7, "bbox": [1082.01, 104.35, 170.7, 47.95], "category_id": 2}, {"id": 8, "bbox": [2460.27, 33.84, 135.43, 279.22], "category_id": 1}, {"id": 9, "bbox": [386.53, 1084.45, 210.2, 49.35], "category_id": 2}, {"id": 10, "bbox": [2202.11, 98.71, 218.66, 50.77], "category_id": 2}, {"id": 11, "bbox": [1702.72, 906.76, 38.09, 42.31], "category_id": 3}, {"id": 12, "bbox": [1015.71, 624.72, 214.43, 53.59], "category_id": 2}, {"id": 13, "bbox": [538.89, 445.62, 31.03, 52.18], "category_id": 3}, {"id": 14, "bbox": [234.18, 1248.03, 766.01, 351.14], "category_id": 1}, {"id": 15, "bbox": [1900.22, 369.47, 153.77, 47.95], "category_id": 2}, {"id": 16, "bbox": [2025.77, 249.61, 110.04, 47.94], "category_id": 2}, {"id": 17, "bbox": [1251.3, 38.08, 433.08, 267.93], "category_id": 1}, {"id": 18, "bbox": [665.85, 29.61, 355.5, 280.63], "category_id": 1}, {"id": 19, "bbox": [1034.05, 1393.28, 220.07, 128.33], "category_id": 1}, {"id": 20, "bbox": [1571.53, 396.27, 143.89, 46.53], "category_id": 2}, {"id": 21, "bbox": [1118.69, 194.61, 84.64, 43.71], "category_id": 2}, {"id": 22, "bbox": [658.8, 1083.04, 87.46, 46.53], "category_id": 2}, {"id": 23, "bbox": [1815.58, 0.0, 325.87, 342.68], "category_id": 1}, {"id": 24, "bbox": [444.37, 291.91, 148.13, 43.72], "category_id": 2}, {"id": 25, "bbox": [1333.12, 585.23, 780.12, 287.69], "category_id": 1}, {"id": 26, "bbox": [1082.01, 730.48, 86.05, 49.36], "category_id": 2}, {"id": 27, "bbox": [2269.82, 194.61, 84.65, 49.35], "category_id": 2}, {"id": 28, "bbox": [537.3, 437.53, 238.82, 180.79], "category_id": 1}, {"id": 29, "bbox": [988.16, 1428.52, 35.71, 51.34], "category_id": 3}, {"id": 30, "bbox": [1437.51, 208.71, 39.5, 46.54], "category_id": 3}], "caption": "Scheme 8. Overall synthesis of 1\u00b7bis maleate salt (17% overall yield) from cyclohexenone", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 585, 110], "ImageBB": [82, 116, 787, 549]}, "reactions": [{"reactants": [4], "conditions": [5, 6], "products": [18]}, {"reactants": [18], "conditions": [7, 21], "products": [17]}, {"reactants": [8], "conditions": [10, 27], "products": [23]}, {"reactants": [17, 23], "conditions": [20], "products": [25]}, {"reactants": [25], "conditions": [12, 26], "products": [1]}, {"reactants": [1, 28], "conditions": [9, 22], "products": [14, 19]}], "diagram_type": "tree"}, {"id": 276, "width": 1352, "height": 1620, "file_name": "ol8006106-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 420.0, 1352.0, 1200.0], "category_id": 4}, {"id": 1, "bbox": [55.4, 61.0, 124.6, 56.5], "category_id": 2}, {"id": 2, "bbox": [832.0, 8.4, 513.7, 354.6], "category_id": 1}, {"id": 3, "bbox": [194.3, 0.0, 503.0, 357.9], "category_id": 1}, {"id": 4, "bbox": [0.0, 114.0, 49.0, 61.0], "category_id": 3}, {"id": 5, "bbox": [711.91, 57.0, 110.0, 65.0], "category_id": 2}, {"id": 6, "bbox": [457.0, 306.0, 98.0, 52.6], "category_id": 3}, {"id": 7, "bbox": [1101.0, 310.0, 98.0, 50.6], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1], "products": [3]}, {"reactants": [3], "conditions": [5], "products": [2]}], "corefs": [[3, 6], [2, 7]], "caption": "Table 1. Synthesis of N2-Modified 2\u2032-Deoxyguanosine Analogues from 3 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 74, 339, 102], "ImageBB": [58, 111, 396, 516]}, "diagram_type": "single"}, {"id": 213, "width": 1352, "height": 1128, "file_name": "op034064g-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [136.0, 608.0, 102.0, 66.0], "category_id": 2}, {"id": 1, "bbox": [981.0, 631.1, 63.0, 57.3], "category_id": 2}, {"id": 2, "bbox": [0.0, 817.1, 1339.0, 310.9], "category_id": 4}, {"id": 3, "bbox": [668.0, 473.1, 233.5, 296.4], "category_id": 1}, {"id": 4, "bbox": [252.0, 580.6, 100.9, 51.8], "category_id": 2}, {"id": 5, "bbox": [949.0, 553.0, 103.0, 58.4], "category_id": 2}, {"id": 6, "bbox": [404.0, 651.1, 234.0, 51.3], "category_id": 2}, {"id": 7, "bbox": [0.0, 4.0, 1343.0, 336.0], "category_id": 4}, {"id": 8, "bbox": [354.0, 472.0, 293.0, 154.0], "category_id": 1}, {"id": 9, "bbox": [1143.17, 595.8, 77.11, 42.34], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [4, 8, 6], "products": [3]}, {"reactants": [3], "conditions": [5, 1], "products": [9]}], "corefs": [], "caption": "Table 5. Coupling temperature effect on selectivity", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 354, 67], "ImageBB": [74, 70, 412, 352]}, "diagram_type": "single"}, {"id": 614, "width": 1352, "height": 364, "file_name": "acs.oprd.5b00303-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [701.0, 213.0, 151.0, 59.0], "category_id": 2}, {"id": 1, "bbox": [12.0, 285.0, 1334.0, 79.0], "category_id": 4}, {"id": 2, "bbox": [1205.0, 219.0, 129.0, 52.0], "category_id": 2}, {"id": 3, "bbox": [37.0, 213.0, 90.0, 63.0], "category_id": 2}, {"id": 4, "bbox": [463.0, 144.0, 136.0, 45.0], "category_id": 2}, {"id": 5, "bbox": [476.0, 46.0, 103.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [954.0, 54.0, 162.0, 55.0], "category_id": 2}, {"id": 7, "bbox": [1150.1, 29.1, 201.9, 182.9], "category_id": 1}, {"id": 8, "bbox": [679.9, 2.0, 220.2, 182.5], "category_id": 1}, {"id": 9, "bbox": [254.3, 70.0, 170.7, 150.9], "category_id": 1}, {"id": 10, "bbox": [6.0, 85.0, 205.0, 100.7], "category_id": 1}], "reactions": [{"reactants": [10, 9], "conditions": [5, 4], "products": [8]}, {"reactants": [8], "conditions": [6], "products": [7]}], "corefs": [[10, 3], [8, 0], [7, 2]], "caption": "Table 1. Preparation of N-Vinylisobutyramidea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 203, 714, 225], "ImageBB": [448, 230, 786, 321]}, "diagram_type": "single"}, {"id": 16, "width": 1348, "height": 524, "file_name": "ja9612413-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [851.09, 5.62, 220.64, 116.48], "category_id": 1}, {"id": 1, "bbox": [6.65, 168.31, 1336.25, 355.69], "category_id": 4}, {"id": 2, "bbox": [265.75, 44.35, 400.54, 66.56], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [0]}], "corefs": [], "caption": "Table 2. Substituent Group Effects on the Turnover Frequencies for Primary Aminoalkyne Hydroamination/Cyclizationa ", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 50, 761, 75], "ImageBB": [438, 84, 775, 214]}, "diagram_type": "single"}, {"id": 620, "width": 1356, "height": 1668, "file_name": "ol502664f-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [392.0, 6.0, 558.0, 189.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 433.0, 1356.0, 1235.0], "category_id": 4}, {"id": 2, "bbox": [137.3, 116.1, 171.0, 140.0], "category_id": 1}, {"id": 3, "bbox": [402.0, 227.8, 552.0, 193.6], "category_id": 2}, {"id": 4, "bbox": [1069.3, 141.7, 150.0, 130.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [0, 3], "products": [4]}], "corefs": [], "caption": "Table 3. Lignin Model Oxidations with Catalytic Amounts of DDQ ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 294, 784, 324], "ImageBB": [448, 330, 787, 747]}, "diagram_type": "single"}, {"id": 1190, "width": 1356, "height": 712, "file_name": "ol500248h-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.01, 61.72, 180.44, 48.16], "category_id": 2}, {"id": 1, "bbox": [1168.78, 403.57, 35.95, 40.02], "category_id": 3}, {"id": 2, "bbox": [482.98, 613.15, 181.11, 40.7], "category_id": 2}, {"id": 3, "bbox": [502.65, 176.35, 103.79, 47.48], "category_id": 2}, {"id": 4, "bbox": [458.9, 270.63, 129.9, 114.62], "category_id": 1}, {"id": 5, "bbox": [681.05, 450.9, 259.13, 207.7], "category_id": 1}, {"id": 6, "bbox": [676.3, 458.9, 29.8, 33.1], "category_id": 3}, {"id": 7, "bbox": [951.71, 236.71, 259.13, 193.31], "category_id": 1}, {"id": 8, "bbox": [191.97, 406.28, 38.67, 35.27], "category_id": 3}, {"id": 9, "bbox": [484.33, 403.57, 42.06, 41.37], "category_id": 3}, {"id": 10, "bbox": [739.9, 307.4, 96.7, 49.2], "category_id": 2}, {"id": 11, "bbox": [679.02, 165.5, 23.74, 36.62], "category_id": 3}, {"id": 12, "bbox": [143.13, 284.87, 207.57, 119.38], "category_id": 1}, {"id": 13, "bbox": [667.49, 19.67, 212.32, 196.7], "category_id": 1}, {"id": 14, "bbox": [979.52, 612.47, 139.74, 37.31], "category_id": 2}, {"id": 15, "bbox": [504.01, 69.86, 139.06, 35.95], "category_id": 2}, {"id": 16, "bbox": [504.01, 507.34, 103.78, 48.84], "category_id": 2}], "caption": "Scheme 1. Possible Pathways for Pd-Catalyzed Double Arylations of 2-Arylbenzimidazoles and 1,2-Dihaloarenes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 545, 768, 575], "ImageBB": [448, 582, 787, 760]}, "reactions": [{"reactants": [12, 4], "conditions": [15], "products": [13]}, {"reactants": [13], "conditions": [0], "products": [7]}, {"reactants": [12, 4], "conditions": [10], "products": [7]}, {"reactants": [12, 4], "conditions": [2], "products": [5]}, {"reactants": [5], "conditions": [14], "products": [7]}], "diagram_type": "graph"}, {"id": 1334, "width": 1356, "height": 1468, "file_name": "op400278d-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.16, 1144.14, 321.0, 198.28], "category_id": 1}, {"id": 1, "bbox": [929.2, 1351.24, 249.75, 45.53], "category_id": 2}, {"id": 2, "bbox": [365.07, 114.56, 172.62, 135.12], "category_id": 2}, {"id": 3, "bbox": [429.71, 847.46, 315.85, 259.23], "category_id": 1}, {"id": 4, "bbox": [17.63, 1352.7, 374.62, 44.07], "category_id": 2}, {"id": 5, "bbox": [33.79, 425.93, 246.81, 160.83], "category_id": 1}, {"id": 6, "bbox": [885.86, 929.71, 96.96, 50.67], "category_id": 2}, {"id": 7, "bbox": [135.89, 35.25, 224.04, 144.67], "category_id": 1}, {"id": 8, "bbox": [462.76, 1133.86, 344.51, 261.44], "category_id": 1}, {"id": 9, "bbox": [929.2, 1128.72, 100.63, 49.2], "category_id": 2}, {"id": 10, "bbox": [789.64, 138.06, 236.52, 88.13], "category_id": 2}, {"id": 11, "bbox": [88.15, 1042.8, 88.88, 47.0], "category_id": 2}, {"id": 12, "bbox": [166.01, 895.19, 103.57, 48.47], "category_id": 2}, {"id": 13, "bbox": [254.15, 534.62, 37.46, 52.14], "category_id": 3}, {"id": 14, "bbox": [860.89, 334.87, 493.61, 316.51], "category_id": 1}, {"id": 15, "bbox": [132.95, 663.87, 246.81, 199.75], "category_id": 1}, {"id": 16, "bbox": [1082.72, 710.87, 146.91, 55.81], "category_id": 2}, {"id": 17, "bbox": [625.83, 405.37, 229.92, 132.19], "category_id": 2}, {"id": 18, "bbox": [600.12, 0.0, 245.34, 136.59], "category_id": 2}, {"id": 19, "bbox": [721.32, 975.97, 39.67, 51.41], "category_id": 3}, {"id": 20, "bbox": [732.92, 1288.33, 39.72, 43.51], "category_id": 3}, {"id": 21, "bbox": [1109.37, 993.22, 88.92, 45.4], "category_id": 2}, {"id": 22, "bbox": [1186.94, 516.5, 39.72, 41.62], "category_id": 3}, {"id": 23, "bbox": [1082.72, 1082.46, 147.64, 47.73], "category_id": 2}], "caption": "Scheme 3. Proposed NHC\u2212Pd-catalyzed amination pathway for alkyl and aryl amines ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 477, 784, 507], "ImageBB": [448, 513, 787, 880]}, "reactions": [{"reactants": [5, 7], "conditions": [2, 18, 10], "products": [14]}, {"reactants": [14, 16], "conditions": [], "products": [3, 8, 21, 23]}, {"reactants": [8], "conditions": [11], "products": [0, 5]}, {"reactants": [3], "conditions": [12], "products": [5, 15]}], "diagram_type": "graph"}, {"id": 584, "width": 1356, "height": 1676, "file_name": "acs.oprd.6b00188-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [243.43, 487.43, 56.0, 50.0], "category_id": 3}, {"id": 1, "bbox": [389.0, 179.0, 442.0, 68.0], "category_id": 2}, {"id": 2, "bbox": [414.0, 290.0, 392.0, 121.0], "category_id": 2}, {"id": 3, "bbox": [834.0, 556.0, 460.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [924.0, 473.0, 68.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [16.0, 624.0, 1340.0, 1014.0], "category_id": 4}, {"id": 6, "bbox": [893.0, 6.0, 324.0, 522.0], "category_id": 1}, {"id": 7, "bbox": [1094.0, 142.0, 6.0, 6.0], "category_id": 1}, {"id": 8, "bbox": [71.2, 37.0, 283.8, 439.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [1, 2], "products": [6]}], "corefs": [[8, 0], [6, 4]], "caption": "Table 1. Condensation of Racemic Tetralone 1 Mediated by Ti(IV) Alkoxides ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 309, 784, 339], "ImageBB": [448, 346, 787, 765]}, "diagram_type": "single"}, {"id": 757, "width": 1344, "height": 820, "file_name": "jo9902998-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [591.0, 292.0, 351.0, 55.0], "category_id": 2}, {"id": 1, "bbox": [247.0, 8.0, 153.0, 233.0], "category_id": 1}, {"id": 2, "bbox": [954.0, 3.0, 146.0, 237.0], "category_id": 1}, {"id": 3, "bbox": [1014.0, 268.0, 27.0, 32.0], "category_id": 3}, {"id": 4, "bbox": [310.0, 266.0, 29.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [709.0, 169.0, 92.0, 38.0], "category_id": 2}, {"id": 6, "bbox": [2.0, 365.0, 1341.0, 455.0], "category_id": 4}, {"id": 7, "bbox": [484.0, 128.0, 90.0, 43.0], "category_id": 2}, {"id": 8, "bbox": [596.0, 32.0, 302.0, 107.0], "category_id": 2}], "reactions": [{"reactants": [1, 7], "conditions": [8, 5], "products": [2]}], "corefs": [[1, 4], [2, 3]], "caption": "Table 2. Pd-Catalyzed Allylic Alkylation of 7a", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [106, 63, 375, 76], "ImageBB": [74, 81, 410, 286]}, "diagram_type": "single"}, {"id": 501, "width": 1352, "height": 720, "file_name": "ol053021c-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [863.8, 156.5, 295.8, 211.1], "category_id": 1}, {"id": 1, "bbox": [1044.0, 429.1, 238.9, 210.9], "category_id": 1}, {"id": 2, "bbox": [592.0, 659.0, 185.0, 61.0], "category_id": 3}, {"id": 3, "bbox": [348.0, 662.0, 198.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [115.0, 660.0, 189.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [186.0, 351.0, 46.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [940.0, 327.0, 62.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [315.1, 429.0, 272.9, 207.9], "category_id": 1}, {"id": 8, "bbox": [562.4, 429.2, 216.6, 212.8], "category_id": 1}, {"id": 9, "bbox": [790.1, 430.2, 235.9, 209.7], "category_id": 1}, {"id": 10, "bbox": [438.6, 270.1, 277.9, 97.8], "category_id": 2}, {"id": 11, "bbox": [403.3, 141.0, 353.7, 99.0], "category_id": 2}, {"id": 12, "bbox": [107.2, 162.0, 208.3, 212.3], "category_id": 1}, {"id": 13, "bbox": [1084.0, 664.0, 173.0, 56.0], "category_id": 3}, {"id": 14, "bbox": [841.0, 660.0, 173.0, 60.0], "category_id": 3}, {"id": 15, "bbox": [75.2, 432.0, 231.8, 207.9], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [11, 10], "products": [0]}], "corefs": [[12, 5], [0, 6], [15, 4], [7, 3], [8, 2], [9, 14], [1, 13]], "caption": "Figure 2. Relative reactivity of (NR)-indoles.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 243, 680, 256], "ImageBB": [439, 51, 777, 231]}, "diagram_type": "single"}, {"id": 1092, "width": 1208, "height": 1112, "file_name": "jo961049j-Scheme-c14.png", "license": 0, "bboxes": [{"id": 0, "bbox": [426.64, 906.5, 326.32, 137.79], "category_id": 2}, {"id": 1, "bbox": [0.0, 0.0, 356.54, 442.37], "category_id": 1}, {"id": 2, "bbox": [0.0, 703.45, 395.21, 339.03], "category_id": 1}, {"id": 3, "bbox": [957.82, 1062.42, 66.47, 49.56], "category_id": 3}, {"id": 4, "bbox": [816.41, 707.07, 332.97, 335.41], "category_id": 1}, {"id": 5, "bbox": [493.11, 829.75, 169.81, 55.0], "category_id": 2}, {"id": 6, "bbox": [956.01, 401.28, 64.66, 49.55], "category_id": 3}, {"id": 7, "bbox": [168.6, 1062.42, 59.22, 47.74], "category_id": 3}, {"id": 8, "bbox": [998.91, 520.94, 209.09, 107.57], "category_id": 2}, {"id": 9, "bbox": [429.66, 255.63, 323.3, 97.91], "category_id": 2}, {"id": 10, "bbox": [788.01, 0.0, 339.62, 394.03], "category_id": 1}, {"id": 11, "bbox": [167.39, 403.09, 55.6, 48.95], "category_id": 3}, {"id": 12, "bbox": [445.37, 121.47, 281.61, 114.82], "category_id": 2}], "caption": "Scheme 14", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [569, 49, 640, 63], "ImageBB": [456, 71, 758, 349]}, "reactions": [{"reactants": [1], "conditions": [12, 9], "products": [10]}, {"reactants": [10], "conditions": [8], "products": [4]}, {"reactants": [4], "conditions": [5, 0], "products": [2]}], "diagram_type": "tree"}, {"id": 715, "width": 1344, "height": 676, "file_name": "ol034434l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [932.03, 140.01, 36.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [3.0, 219.0, 1334.0, 457.0], "category_id": 4}, {"id": 2, "bbox": [270.3, 6.0, 280.7, 118.7], "category_id": 1}, {"id": 3, "bbox": [800.33, 9.9, 280.47, 116.01], "category_id": 1}, {"id": 4, "bbox": [394.01, 139.03, 31.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [644.0, 4.0, 50.0, 45.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [5], "products": [3]}], "corefs": [[2, 4], [3, 0]], "caption": "Table 1. Reduction of N,N-Dibenzylhydroxylamine (1) with Indium Metal ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 437, 392, 465], "ImageBB": [74, 471, 410, 640]}, "diagram_type": "single"}, {"id": 272, "width": 1348, "height": 644, "file_name": "ol801034x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [74.2, 70.0, 301.4, 221.1], "category_id": 1}, {"id": 1, "bbox": [322.2, 31.9, 266.7, 220.1], "category_id": 1}, {"id": 2, "bbox": [612.0, 40.0, 332.0, 101.0], "category_id": 2}, {"id": 3, "bbox": [946.0, 0.0, 329.0, 267.0], "category_id": 1}, {"id": 4, "bbox": [460.0, 277.0, 49.0, 62.0], "category_id": 3}, {"id": 5, "bbox": [1087.0, 285.0, 45.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [116.0, 277.0, 40.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [1.0, 355.0, 1347.0, 289.0], "category_id": 4}, {"id": 8, "bbox": [617.0, 184.0, 358.0, 101.0], "category_id": 2}], "reactions": [{"reactants": [0, 1], "conditions": [2, 8], "products": [3]}], "corefs": [[0, 6], [1, 4], [3, 5]], "caption": "Table 1. Reation of 1 with Isatin to Generate Compound 5a", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 243, 736, 258], "ImageBB": [425, 267, 762, 428]}, "diagram_type": "single"}, {"id": 1077, "width": 3396, "height": 1148, "file_name": "jo500696n-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1383.01, 260.23, 102.44, 48.66], "category_id": 2}, {"id": 1, "bbox": [993.83, 560.14, 67.95, 59.41], "category_id": 2}, {"id": 2, "bbox": [693.13, 531.28, 95.14, 50.93], "category_id": 3}, {"id": 3, "bbox": [2346.11, 607.67, 88.34, 61.1], "category_id": 2}, {"id": 4, "bbox": [1002.32, 363.24, 248.03, 91.66], "category_id": 2}, {"id": 5, "bbox": [1651.28, 100.15, 57.76, 47.52], "category_id": 2}, {"id": 6, "bbox": [1651.28, 612.76, 64.56, 56.01], "category_id": 2}, {"id": 7, "bbox": [1172.21, 548.26, 372.04, 276.67], "category_id": 1}, {"id": 8, "bbox": [1002.32, 203.69, 59.46, 52.62], "category_id": 2}, {"id": 9, "bbox": [1858.54, 548.26, 375.45, 278.37], "category_id": 1}, {"id": 10, "bbox": [2546.58, 288.56, 383.94, 49.22], "category_id": 2}, {"id": 11, "bbox": [1100.85, 40.74, 445.1, 220.66], "category_id": 1}, {"id": 12, "bbox": [445.1, 290.25, 530.04, 266.5], "category_id": 1}, {"id": 13, "bbox": [1172.21, 796.08, 110.42, 49.22], "category_id": 2}, {"id": 14, "bbox": [1810.97, 40.74, 441.7, 218.96], "category_id": 1}, {"id": 15, "bbox": [1523.87, 376.82, 334.67, 61.11], "category_id": 2}, {"id": 16, "bbox": [2555.07, 826.63, 375.45, 52.62], "category_id": 2}, {"id": 17, "bbox": [2509.2, 45.83, 438.3, 213.87], "category_id": 1}, {"id": 18, "bbox": [2264.57, 364.94, 251.43, 86.57], "category_id": 2}, {"id": 19, "bbox": [2346.11, 86.57, 81.55, 64.5], "category_id": 2}, {"id": 20, "bbox": [2568.66, 549.96, 363.55, 271.58], "category_id": 1}], "caption": "Scheme 2. Possible Photocyclization Pathways for 2-Styrylquinolines", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 808, 468, 823], "ImageBB": [10, 840, 859, 1127]}, "reactions": [{"reactants": [12], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [8], "products": [12]}, {"reactants": [11], "conditions": [5], "products": [14]}, {"reactants": [14], "conditions": [], "products": [11]}, {"reactants": [14], "conditions": [19], "products": [17]}, {"reactants": [12], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [1], "products": [12]}, {"reactants": [7], "conditions": [6], "products": [9]}, {"reactants": [9], "conditions": [], "products": [7]}, {"reactants": [9], "conditions": [3], "products": [20]}], "diagram_type": "tree"}, {"id": 1036, "width": 1336, "height": 1816, "file_name": "jo001614p-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [343.28, 1385.39, 69.02, 52.69], "category_id": 3}, {"id": 1, "bbox": 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[], "products": [6]}, {"reactants": [6], "conditions": [], "products": [17]}, {"reactants": [6], "conditions": [], "products": [21]}, {"reactants": [21], "conditions": [], "products": [6]}, {"reactants": [21], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [21]}, {"reactants": [8], "conditions": [], "products": [10]}, {"reactants": [8], "conditions": [], "products": [26]}, {"reactants": [26], "conditions": [], "products": [8]}, {"reactants": [26], "conditions": [], "products": [20]}], "diagram_type": "tree"}, {"id": 437, "width": 2820, "height": 760, "file_name": "op200351g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [237.0, 25.0, 605.0, 337.0], "category_id": 1}, {"id": 1, "bbox": [1776.0, 204.0, 180.0, 62.0], "category_id": 2}, {"id": 2, "bbox": [2219.0, 271.0, 73.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [1422.0, 266.0, 85.0, 66.0], "category_id": 3}, {"id": 4, "bbox": [495.0, 271.0, 66.0, 56.0], "category_id": 3}, {"id": 5, "bbox": [223.0, 419.0, 2382.0, 293.0], "category_id": 4}, {"id": 6, "bbox": [1971.0, 66.0, 632.0, 235.0], "category_id": 1}, {"id": 7, "bbox": [1781.0, 102.0, 157.0, 77.0], "category_id": 2}, {"id": 8, "bbox": [783.0, 68.0, 308.0, 111.0], "category_id": 2}, {"id": 9, "bbox": [728.3, 227.4, 415.6, 119.0], "category_id": 2}, {"id": 10, "bbox": [1141.0, 63.0, 619.0, 244.7], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [8, 9], "products": [10]}, {"reactants": [10], "conditions": [7, 1], "products": [6]}], "corefs": [[0, 4], [10, 3], [6, 2]], "caption": "Table 2. PFR cyclization results for ketoamide (11) cyclization and deprotection", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 656, 537, 671], "ImageBB": [82, 677, 787, 867]}, "diagram_type": "single"}, {"id": 150, "width": 1196, "height": 404, "file_name": "op7001886-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [137.1, 336.0, 279.4, 65.2], "category_id": 3}, {"id": 1, "bbox": [1019.0, 341.0, 55.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [914.0, 0.0, 279.0, 330.0], "category_id": 1}, {"id": 3, "bbox": [665.5, 64.9, 228.7, 194.7], "category_id": 1}, {"id": 4, "bbox": [7.0, 65.1, 501.0, 291.9], "category_id": 1}, {"id": 5, "bbox": [726.0, 336.0, 44.2, 60.8], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [], "products": [3, 2]}], "corefs": [[4, 0], [3, 5], [2, 1]], "caption": "Figure 2", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 541, 476, 555], "ImageBB": [444, 437, 743, 538]}, "diagram_type": "single"}, {"id": 205, "width": 1344, "height": 756, "file_name": "op034181b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [813.0, 7.0, 326.0, 202.0], "category_id": 1}, {"id": 1, "bbox": [284.0, 200.0, 55.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [0.0, 276.0, 1339.0, 363.0], "category_id": 4}, {"id": 3, "bbox": [42.0, 668.0, 959.0, 71.0], "category_id": 2}, {"id": 4, "bbox": [598.1, 136.1, 129.7, 47.9], "category_id": 2}, {"id": 5, "bbox": [511.9, 63.1, 333.1, 50.8], "category_id": 2}, {"id": 6, "bbox": [901.05, 199.0, 45.0, 54.0], "category_id": 3}, {"id": 7, "bbox": [199.0, 1.0, 305.8, 191.8], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 4], "products": [0]}], "corefs": [[7, 1], [0, 6]], "caption": "Table 2. Esterification of 2,4,6-trimethylbenzoic acid", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 367, 67], "ImageBB": [74, 70, 410, 259]}, "diagram_type": "single"}, {"id": 938, "width": 1352, "height": 1408, "file_name": "acs.orglett.5b01044-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [902.97, 717.03, 331.74, 285.26], "category_id": 1}, {"id": 1, "bbox": [198.62, 950.88, 238.78, 90.86], "category_id": 3}, {"id": 2, "bbox": [607.85, 953.69, 243.7, 87.34], "category_id": 3}, {"id": 3, "bbox": [674.06, 640.96, 55.64, 39.04], "category_id": 3}, {"id": 4, "bbox": [488.11, 1044.55, 374.01, 312.74], "category_id": 1}, {"id": 5, "bbox": [185.24, 291.6, 214.83, 84.52], "category_id": 3}, {"id": 6, "bbox": [962.13, 111.99, 299.35, 226.8], "category_id": 1}, {"id": 7, "bbox": [197.92, 1310.8, 238.07, 50.71], "category_id": 3}, {"id": 8, "bbox": [1067.08, 643.07, 47.89, 38.74], "category_id": 3}, {"id": 9, "bbox": [185.24, 645.19, 100.02, 42.26], "category_id": 3}, {"id": 10, "bbox": [900.85, 1125.55, 360.63, 231.74], "category_id": 1}, {"id": 11, "bbox": [490.93, 737.46, 319.77, 266.24], "category_id": 1}, {"id": 12, "bbox": [612.07, 1313.62, 220.46, 51.41], "category_id": 3}, {"id": 13, "bbox": [534.6, 460.65, 295.12, 221.16], "category_id": 1}, {"id": 14, "bbox": [89.45, 111.99, 269.06, 226.8], "category_id": 1}, {"id": 15, "bbox": [226.8, 381.76, 281.03, 82.41], "category_id": 2}, {"id": 16, "bbox": [1088.91, 354.29, 160.59, 109.88], "category_id": 2}, {"id": 17, "bbox": [393.73, 0.0, 627.57, 80.3], "category_id": 2}, {"id": 18, "bbox": [926.21, 460.65, 296.53, 223.98], "category_id": 1}, {"id": 19, "bbox": [1012.14, 953.69, 245.82, 86.64], "category_id": 3}, {"id": 20, "bbox": [1086.1, 293.71, 86.63, 45.79], "category_id": 3}, {"id": 21, "bbox": [806.47, 151.44, 164.11, 81.0], "category_id": 2}, {"id": 22, "bbox": [659.97, 364.15, 273.99, 84.52], "category_id": 2}, {"id": 23, "bbox": [87.34, 1129.08, 324.7, 229.62], "category_id": 1}, {"id": 24, "bbox": [88.04, 460.65, 284.56, 221.16], "category_id": 1}, {"id": 25, "bbox": [87.34, 778.31, 326.11, 225.39], "category_id": 1}, {"id": 26, "bbox": [1012.84, 1310.1, 238.78, 53.53], "category_id": 3}, {"id": 27, "bbox": [525.44, 116.22, 260.61, 222.57], "category_id": 1}, {"id": 28, "bbox": [376.12, 151.44, 128.89, 78.88], "category_id": 2}, {"id": 29, "bbox": [638.8, 289.08, 141.99, 43.95], "category_id": 3}], "caption": "Scheme 5. Conversion of Pyridones 2 to Pyridine Derivatives", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 110], "ImageBB": [82, 116, 420, 468]}, "reactions": [{"reactants": [27], "conditions": [28], "products": [14]}, {"reactants": [27], "conditions": [21], "products": [6]}, {"reactants": [14], "conditions": [17], "products": [6]}, {"reactants": [14], "conditions": [15], "products": [24]}, {"reactants": [27], "conditions": [22], "products": [13]}, {"reactants": [13], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [13]}, {"reactants": [18], "conditions": [16], "products": [6]}], "diagram_type": "graph"}, {"id": 19, "width": 1312, "height": 1020, "file_name": "ja9535975-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [531.65, 101.94, 191.52, 54.64], "category_id": 2}, {"id": 1, "bbox": [815.94, 8.49, 421.84, 140.19], "category_id": 1}, {"id": 2, "bbox": [538.23, 23.6, 171.78, 29.7], "category_id": 2}, {"id": 3, "bbox": [92.06, 4.54, 299.45, 144.14], "category_id": 1}, {"id": 4, "bbox": [1021.25, 170.37, 44.12, 37.54], "category_id": 3}, {"id": 5, "bbox": [3.88, 241.45, 1299.71, 770.61], "category_id": 4}, {"id": 6, "bbox": [289.48, 171.69, 42.8, 37.54], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [2, 0], "products": [1]}], "corefs": [[3, 6], [1, 4]], "caption": "Table 1. Comparison of Reaction Conditions for the Photopromoted Pauson-Khand Reaction ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 70, 693, 95], "ImageBB": [434, 100, 762, 355]}, "diagram_type": "single"}, {"id": 148, "width": 2816, "height": 2116, "file_name": "op700249f-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1182.0, 211.0, 241.9, 134.2], "category_id": 2}, {"id": 1, "bbox": [591.0, 354.9, 258.0, 87.1], "category_id": 3}, {"id": 2, "bbox": [65.0, 465.0, 2689.0, 433.0], "category_id": 4}, {"id": 3, "bbox": [1967.0, 358.0, 115.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [1626.0, 30.0, 743.0, 309.0], "category_id": 1}, {"id": 5, "bbox": [1163.0, 3.0, 266.0, 147.0], "category_id": 1}, {"id": 6, "bbox": [464.0, 71.0, 627.0, 258.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 0], "products": [4]}], "corefs": [[6, 1], [4, 3]], "caption": "Figure 3. Reaction profile of triazole-linked glycosidic amino acid 45 with glycinamide. identity of the impurities could not be established, although it    concomitant decreas was clear that enzymatic hydrolysis of the starting material was    by HPLC resulting  not an issue. Since glycinamide was added to the reaction           2). Next, a slightly  mixture in excess, formation of a tripeptide (NTGA-Gly-Gly-         involving addition of NH2) might be one of the possibilities.                             to methyl ester 45 in ", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 841, 536, 940], "ImageBB": [58, 308, 762, 837]}, "diagram_type": "single"}, {"id": 1082, "width": 1356, "height": 1224, "file_name": "jo501736w-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1202.02, 854.2, 51.55, 54.28], "category_id": 3}, {"id": 1, "bbox": [727.98, 26.5, 101.39, 55.83], "category_id": 2}, {"id": 2, "bbox": [630.7, 50.3, 261.32, 182.1], "category_id": 1}, {"id": 3, "bbox": [174.02, 646.58, 61.72, 63.18], "category_id": 2}, {"id": 4, "bbox": [182.84, 980.13, 58.78, 64.65], "category_id": 2}, {"id": 5, "bbox": [944.93, 2.71, 170.94, 108.39], "category_id": 1}, {"id": 6, "bbox": [754.31, 230.68, 54.27, 50.21], "category_id": 3}, {"id": 7, "bbox": [93.61, 322.28, 396.83, 174.36], "category_id": 1}, {"id": 8, "bbox": [388.01, 926.8, 383.94, 194.72], "category_id": 1}, {"id": 9, "bbox": [223.85, 207.61, 43.42, 49.53], "category_id": 3}, {"id": 10, "bbox": [733.96, 316.85, 385.3, 196.75], "category_id": 1}, {"id": 11, "bbox": [328.32, 855.56, 79.36, 67.84], "category_id": 2}, {"id": 12, "bbox": [421.25, 48.85, 126.85, 56.31], "category_id": 2}, {"id": 13, "bbox": [991.05, 507.5, 50.2, 50.88], "category_id": 3}, {"id": 14, "bbox": [269.98, 515.64, 48.16, 52.24], "category_id": 3}, {"id": 15, "bbox": [506.04, 588.92, 86.83, 54.95], "category_id": 2}, {"id": 16, "bbox": [972.06, 700.19, 383.94, 147.22], "category_id": 1}, {"id": 17, "bbox": [1019.54, 93.63, 48.84, 46.81], "category_id": 3}, {"id": 18, "bbox": [389.37, 668.3, 383.94, 196.75], "category_id": 1}, {"id": 19, "bbox": [97.68, 54.96, 253.7, 147.23], "category_id": 1}, {"id": 20, "bbox": [623.39, 860.98, 43.42, 46.82], "category_id": 3}, {"id": 21, "bbox": [623.39, 1129.66, 42.06, 47.49], "category_id": 3}], "caption": "Scheme 3. A Proposed Mechanism for the Halide-Mediated Electrochemical Synthesis of 2-Aminobenzoxazoles ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 233, 784, 263], "ImageBB": [448, 269, 787, 575]}, "reactions": [{"reactants": [19], "conditions": [12], "products": [1, 2]}, {"reactants": [1, 2], "conditions": [], "products": [19]}, {"reactants": [2, 5], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [2, 5]}, {"reactants": [10], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [10]}, {"reactants": [8, 4], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [16, 3]}], "diagram_type": "graph"}, {"id": 936, "width": 1356, "height": 1304, "file_name": "acs.orglett.5b00776-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [849.96, 970.61, 147.2, 61.05], "category_id": 2}, {"id": 1, "bbox": [328.99, 312.69, 45.45, 56.97], "category_id": 3}, {"id": 2, "bbox": [586.76, 308.62, 56.31, 59.01], "category_id": 3}, {"id": 3, "bbox": [609.83, 1209.37, 64.44, 50.87], "category_id": 3}, {"id": 4, "bbox": [951.71, 595.53, 385.97, 383.9], "category_id": 1}, {"id": 5, "bbox": [476.19, 425.28, 297.12, 271.99], "category_id": 1}, {"id": 6, "bbox": [499.26, 871.59, 294.4, 337.78], "category_id": 1}, {"id": 7, "bbox": [46.13, 843.78, 269.3, 361.52], "category_id": 1}, {"id": 8, "bbox": [1177.6, 314.72, 49.52, 54.26], "category_id": 3}, {"id": 9, "bbox": [819.43, 315.4, 63.77, 54.26], "category_id": 3}, {"id": 10, "bbox": [299.15, 612.48, 197.39, 64.44], "category_id": 2}, {"id": 11, "bbox": [819.43, 915.0, 41.38, 47.47], "category_id": 2}, {"id": 12, "bbox": [136.35, 1199.19, 50.87, 48.84], "category_id": 3}, {"id": 13, "bbox": [951.71, 0.0, 381.23, 312.01], "category_id": 1}, {"id": 14, "bbox": [183.5, 64.9, 72.23, 65.33], "category_id": 2}, {"id": 15, "bbox": [819.43, 694.56, 50.2, 54.94], "category_id": 2}, {"id": 16, "bbox": [770.29, 9.33, 164.37, 299.0], "category_id": 1}, {"id": 17, "bbox": [550.13, 14.92, 140.67, 231.58], "category_id": 1}, {"id": 18, "bbox": [22.39, 18.31, 124.81, 234.01], "category_id": 1}, {"id": 19, "bbox": [865.78, 626.11, 73.57, 50.1], "category_id": 2}, {"id": 20, "bbox": [48.16, 440.2, 290.33, 264.53], "category_id": 1}, {"id": 21, "bbox": [608.47, 707.44, 60.37, 61.73], "category_id": 3}, {"id": 22, "bbox": [1207.1, 435.2, 62.7, 66.4], "category_id": 1}, {"id": 23, "bbox": [63.09, 308.62, 61.05, 61.04], "category_id": 3}, {"id": 24, "bbox": [1178.95, 986.89, 48.17, 54.26], "category_id": 3}, {"id": 25, "bbox": [299.15, 25.1, 147.88, 235.36], "category_id": 1}, {"id": 26, "bbox": [136.35, 707.44, 54.94, 56.98], "category_id": 3}], "caption": "Scheme 5. Plausible Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 630, 110], "ImageBB": [448, 116, 787, 442]}, "reactions": [{"reactants": [18], "conditions": [14], "products": [25]}, {"reactants": [25], "conditions": [], "products": [18]}, {"reactants": [25], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [25]}, {"reactants": [17, 16], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [17, 16]}, {"reactants": [4], "conditions": [15, 19], "products": [5]}, {"reactants": [5], "conditions": [10], "products": [20]}, {"reactants": [4], "conditions": [11, 0], "products": [6]}, {"reactants": [6], "conditions": [], "products": [7]}], "diagram_type": "tree"}, {"id": 615, "width": 1356, "height": 808, "file_name": "acs.oprd.5b00282-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [961.0, 45.0, 277.0, 326.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 98.0, 276.0, 272.0], "category_id": 1}, {"id": 2, "bbox": [531.0, 180.0, 210.0, 33.0], "category_id": 2}, {"id": 3, "bbox": [339.0, 211.0, 37.0, 33.0], "category_id": 2}, {"id": 4, "bbox": [84.0, 409.0, 138.0, 67.0], "category_id": 2}, {"id": 5, "bbox": [336.0, 411.0, 172.0, 30.0], "category_id": 2}, {"id": 6, "bbox": [823.0, 400.0, 97.0, 29.0], "category_id": 2}, {"id": 7, "bbox": [1036.0, 408.0, 175.0, 69.0], "category_id": 2}, {"id": 8, "bbox": [1295.0, 208.0, 54.0, 40.0], "category_id": 2}, {"id": 9, "bbox": [805.0, 734.0, 99.0, 28.0], "category_id": 2}, {"id": 10, "bbox": [585.0, 590.0, 68.0, 28.0], "category_id": 2}, {"id": 11, "bbox": [304.0, 661.0, 280.0, 36.0], "category_id": 2}, {"id": 12, "bbox": [285.0, 775.0, 169.0, 28.0], "category_id": 2}], "reactions": [{"reactants": [1, 3, 5], "conditions": [2], "products": [0, 8, 6]}, {"reactants": [0, 8, 6], "conditions": [], "products": [1, 3, 5]}, {"reactants": [9], "conditions": [10], "products": [11]}, {"reactants": [11], "conditions": [], "products": [12]}], "corefs": [[1, 4], [0, 7]], "caption": "Figure 1. Bio-oxidation/hydroxylation reaction of \u03b1-isophorone to 4- hydroxy-\u03b1-isophorone. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 820, 784, 851], "ImageBB": [448, 612, 787, 814]}, "diagram_type": "graph"}, {"id": 269, "width": 1352, "height": 524, "file_name": "ol801035c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [910.0, 191.0, 350.0, 199.0], "category_id": 1}, {"id": 1, "bbox": [424.0, 80.0, 220.0, 57.0], "category_id": 2}, {"id": 2, "bbox": [260.0, 210.0, 33.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [884.0, 200.0, 27.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1253.0, 191.0, 46.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [1180.0, 347.0, 53.0, 42.0], "category_id": 3}, {"id": 6, "bbox": [313.0, 156.0, 437.0, 156.1], "category_id": 2}, {"id": 7, "bbox": [0.0, 424.0, 1342.0, 100.0], "category_id": 4}, {"id": 8, "bbox": [1037.1, 2.0, 265.9, 196.8], "category_id": 1}, {"id": 9, "bbox": [681.6, 14.0, 348.4, 181.5], "category_id": 1}, {"id": 10, "bbox": [49.1, 24.7, 263.9, 177.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [1, 6], "products": [9, 8, 0]}], "corefs": [[10, 2], [9, 3], [8, 4], [0, 5]], "caption": "Table 1. Study of the Direct Phenylation of 2", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 296, 88], "ImageBB": [58, 97, 396, 228]}, "diagram_type": "single"}, {"id": 1277, "width": 1356, "height": 2360, "file_name": "op100104z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 0.0, 231.37, 253.83], "category_id": 1}, {"id": 1, "bbox": [734.24, 316.4, 499.33, 514.74], "category_id": 1}, {"id": 2, "bbox": [565.44, 577.31, 31.87, 38.96], "category_id": 2}, {"id": 3, "bbox": [621.22, 1303.15, 36.83, 36.84], "category_id": 3}, {"id": 4, "bbox": [397.81, 10.63, 213.66, 253.82], "category_id": 1}, {"id": 5, "bbox": [238.45, 1322.26, 28.33, 36.6], "category_id": 3}, {"id": 6, "bbox": [1110.81, 96.81, 36.59, 34.24], "category_id": 2}, {"id": 7, "bbox": [49.58, 1050.73, 409.62, 337.64], "category_id": 1}, {"id": 8, "bbox": [766.11, 7.08, 265.6, 249.11], "category_id": 1}, {"id": 9, "bbox": [653.97, 92.09, 40.14, 40.14], "category_id": 2}, {"id": 10, "bbox": [1023.45, 1369.48, 36.6, 37.78], "category_id": 3}, {"id": 11, "bbox": [0.0, 1581.99, 1356.0, 691.83], "category_id": 2}, {"id": 12, "bbox": [238.45, 822.87, 28.33, 37.78], "category_id": 3}, {"id": 13, "bbox": [844.02, 251.47, 33.06, 33.05], "category_id": 3}, {"id": 14, "bbox": [0.0, 1419.07, 1356.0, 114.52], "category_id": 2}, {"id": 15, "bbox": [82.63, 265.63, 31.87, 36.6], "category_id": 3}, {"id": 16, "bbox": [822.77, 891.35, 533.23, 518.27], "category_id": 1}, {"id": 17, "bbox": [275.05, 94.45, 29.51, 33.05], "category_id": 2}, {"id": 18, "bbox": [47.22, 344.73, 537.1, 515.92], "category_id": 1}, {"id": 19, "bbox": [537.11, 1021.21, 259.69, 252.65], "category_id": 1}, {"id": 20, "bbox": [912.49, 783.91, 24.79, 33.06], "category_id": 3}, {"id": 21, "bbox": [478.08, 259.73, 29.51, 33.06], "category_id": 3}], "caption": "Scheme 1. Original synthesis of 1a", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 425, 619, 439], "ImageBB": [424, 448, 763, 1038]}, "reactions": [{"reactants": [0], "conditions": [17], "products": [4]}, {"reactants": [4], "conditions": [9], "products": [8]}, {"reactants": [8], "conditions": [6], "products": [18]}, {"reactants": [18], "conditions": [2], "products": [1]}], "diagram_type": "multiple"}, {"id": 1114, "width": 1120, "height": 2248, "file_name": "jo9816515-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [559.02, 1583.38, 420.66, 286.77], "category_id": 1}, {"id": 1, "bbox": [913.32, 2105.18, 200.21, 142.82], "category_id": 1}, {"id": 2, "bbox": [669.24, 2135.3, 230.58, 75.59], "category_id": 3}, {"id": 3, "bbox": [887.45, 647.75, 129.35, 61.85], "category_id": 2}, {"id": 4, "bbox": [825.59, 253.03, 131.6, 69.72], "category_id": 3}, {"id": 5, "bbox": [701.86, 900.77, 391.43, 330.63], "category_id": 1}, {"id": 6, "bbox": [575.89, 1257.26, 60.74, 60.73], "category_id": 3}, {"id": 7, "bbox": [92.23, 51.73, 383.55, 151.82], "category_id": 1}, {"id": 8, "bbox": [125.98, 1880.27, 177.71, 71.97], "category_id": 3}, {"id": 9, "bbox": [743.48, 3.37, 271.07, 224.92], "category_id": 1}, {"id": 10, "bbox": [202.46, 253.03, 173.22, 69.72], "category_id": 3}, {"id": 11, "bbox": [701.86, 1897.14, 138.35, 64.1], "category_id": 3}, {"id": 12, "bbox": [602.88, 405.97, 147.35, 93.34], "category_id": 2}, {"id": 13, "bbox": [0.0, 1997.22, 620.88, 213.67], "category_id": 3}, {"id": 14, "bbox": [0.0, 1583.38, 409.42, 282.27], "category_id": 1}, {"id": 15, "bbox": [916.7, 1966.86, 192.33, 139.45], "category_id": 1}, {"id": 16, "bbox": [311.56, 1376.46, 192.34, 114.71], "category_id": 2}, {"id": 17, "bbox": [95.61, 900.77, 439.78, 330.63], "category_id": 1}, {"id": 18, "bbox": [165.34, 654.5, 132.73, 62.97], "category_id": 2}, {"id": 19, "bbox": [669.24, 2002.85, 235.08, 75.34], "category_id": 3}, {"id": 20, "bbox": [885.2, 1378.71, 201.34, 97.84], "category_id": 2}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [102, 83, 382, 645]}, "reactions": [{"reactants": [7, 9], "conditions": [12], "products": [17]}, {"reactants": [7, 9], "conditions": [12], "products": [5]}, {"reactants": [17], "conditions": [16], "products": [14]}, {"reactants": [5], "conditions": [20], "products": [0]}], "diagram_type": "tree"}, {"id": 489, "width": 1352, "height": 2216, "file_name": "ol060473w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [118.0, 57.0, 184.0, 138.4], "category_id": 1}, {"id": 1, "bbox": [335.0, 151.0, 564.0, 68.0], "category_id": 2}, {"id": 2, "bbox": [3.0, 282.0, 1349.0, 1934.0], "category_id": 4}, {"id": 3, "bbox": [924.8, 0.0, 355.5, 255.1], "category_id": 1}, {"id": 4, "bbox": [345.0, 64.0, 546.0, 63.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [4, 1], "products": [3]}], "corefs": [], "caption": "Table 2. Direct Amidation of Quinoline and Isoquinoline N-Oxides with Various Amides ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 193, 743, 221], "ImageBB": [439, 222, 777, 776]}, "diagram_type": "single"}, {"id": 644, "width": 1352, "height": 2752, "file_name": "ol500618w-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [417.0, 276.0, 157.5, 52.9], "category_id": 2}, {"id": 1, "bbox": [395.1, 52.0, 167.9, 137.4], "category_id": 1}, {"id": 2, "bbox": [1134.7, 17.1, 217.3, 197.9], "category_id": 1}, {"id": 3, "bbox": [678.0, 128.55, 351.5, 140.15], "category_id": 2}, {"id": 4, "bbox": [19.0, 276.0, 140.0, 48.0], "category_id": 2}, {"id": 5, "bbox": [3.0, 375.0, 460.0, 110.0], "category_id": 2}, {"id": 6, "bbox": [1224.0, 223.0, 47.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [80.0, 225.0, 36.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [0.0, 18.0, 195.0, 197.0], "category_id": 1}, {"id": 9, "bbox": [459.0, 227.0, 33.0, 38.0], "category_id": 3}, {"id": 10, "bbox": [11.0, 487.0, 1341.0, 2265.0], "category_id": 4}, {"id": 11, "bbox": [684.0, 8.0, 349.0, 79.0], "category_id": 2}], "reactions": [{"reactants": [8, 1], "conditions": [11, 3], "products": [2]}], "corefs": [[8, 7], [1, 9], [2, 6]], "caption": "Table 3. Cyanation of Alkenyl Halides", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 666, 110], "ImageBB": [448, 116, 786, 804]}, "diagram_type": "single"}, {"id": 419, "width": 2820, "height": 1804, "file_name": "op300364p-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [646.0, 256.0, 65.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [2390.0, 241.0, 56.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [317.0, 98.0, 253.0, 162.0], "category_id": 1}, {"id": 3, "bbox": [1934.0, 244.0, 49.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [1101.0, 104.0, 402.0, 65.3], "category_id": 2}, {"id": 5, "bbox": [1780.0, 82.09, 331.0, 185.0], "category_id": 1}, {"id": 6, "bbox": [858.0, 192.9, 878.0, 69.4], "category_id": 2}, {"id": 7, "bbox": [2216.0, 49.42, 291.0, 214.0], "category_id": 1}, {"id": 8, "bbox": [621.0, 123.0, 183.6, 83.3], "category_id": 1}, {"id": 9, "bbox": [0.3, 351.0, 2715.7, 1453.0], "category_id": 4}], "reactions": [{"reactants": [2, 8], "conditions": [4, 6], "products": [5, 7]}], "corefs": [[8, 0], [5, 3], [7, 1]], "caption": "Table 5. A Generic Heck\u2212Mizoroki Protocol for Dimethylpentene", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 574, 450, 590], "ImageBB": [82, 117, 787, 568]}, "diagram_type": "single"}, {"id": 535, "width": 1336, "height": 1152, "file_name": "jo000694u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [959.4, 82.7, 376.6, 423.3], "category_id": 1}, {"id": 1, "bbox": [15.69, 667.69, 380.91, 444.0], "category_id": 1}, {"id": 2, "bbox": [534.0, 95.69, 385.0, 420.0], "category_id": 1}, {"id": 3, "bbox": [683.0, 512.0, 47.0, 36.3], "category_id": 3}, {"id": 4, "bbox": [1091.0, 503.7, 59.3, 43.3], "category_id": 3}, {"id": 5, "bbox": [4.0, 106.0, 313.4, 407.7], "category_id": 1}, {"id": 6, "bbox": [351.0, 125.0, 162.0, 47.0], "category_id": 2}, {"id": 7, "bbox": [162.0, 557.0, 233.0, 96.0], "category_id": 2}, {"id": 8, "bbox": [150.0, 1104.0, 47.0, 43.0], "category_id": 3}, {"id": 9, "bbox": [131.0, 507.0, 48.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [6], "products": [2, 0]}, {"reactants": [5], "conditions": [7], "products": [1]}, {"reactants": [1], "conditions": [], "products": [2]}], "corefs": [[5, 9], [2, 3], [0, 4], [1, 8]], "caption": "Figure 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 148, 131, 161], "ImageBB": [75, 171, 409, 459]}, "diagram_type": "graph"}, {"id": 648, "width": 1352, "height": 2200, "file_name": "ol500248h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [87.7, 85.0, 245.3, 138.0], "category_id": 1}, {"id": 1, "bbox": [393.8, 76.0, 181.2, 131.0], "category_id": 1}, {"id": 2, "bbox": [946.0, 2.0, 311.0, 237.0], "category_id": 1}, {"id": 3, "bbox": [1230.0, 219.0, 28.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [467.0, 219.0, 27.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [197.0, 223.0, 34.0, 32.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 271.0, 1352.0, 1924.0], "category_id": 4}, {"id": 7, "bbox": [599.33, 148.33, 378.0, 44.0], "category_id": 2}, {"id": 8, "bbox": [596.0, 46.0, 371.0, 83.5], "category_id": 2}], "reactions": [{"reactants": [0, 1], "conditions": [8, 7], "products": [2]}], "corefs": [[0, 5], [1, 4], [2, 3]], "caption": "Table 1. Pd-Catalyzed Annulation of Benzimidazole Derivative with o-Dihalobenzenea ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 248, 374, 279], "ImageBB": [82, 285, 420, 835]}, "diagram_type": "single"}, {"id": 1070, "width": 1352, "height": 1076, "file_name": "jo400755q-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.23, 588.35, 77.78, 56.13], "category_id": 2}, {"id": 1, "bbox": [75.5, 273.89, 470.98, 287.41], "category_id": 1}, {"id": 2, "bbox": [371.31, 568.06, 223.59, 107.34], "category_id": 2}, {"id": 3, "bbox": [498.46, 696.55, 114.98, 61.54], "category_id": 2}, {"id": 4, "bbox": [685.81, 697.9, 392.27, 288.09], "category_id": 1}, {"id": 5, "bbox": [622.23, 248.19, 504.55, 345.57], "category_id": 1}, {"id": 6, "bbox": [344.93, 2.71, 181.94, 233.31], "category_id": 1}, {"id": 7, "bbox": [526.87, 248.19, 177.87, 86.56], "category_id": 2}, {"id": 8, "bbox": [101.45, 702.64, 395.66, 287.41], "category_id": 1}, {"id": 9, "bbox": [885.2, 625.18, 60.71, 47.79], "category_id": 2}, {"id": 10, "bbox": [601.02, 569.64, 202.8, 85.25], "category_id": 2}, {"id": 11, "bbox": [253.55, 476.63, 31.0, 46.5], "category_id": 3}, {"id": 12, "bbox": [792.2, 510.22, 36.17, 46.5], "category_id": 3}, {"id": 13, "bbox": [1123.4, 778.38, 150.82, 252.24], "category_id": 1}], "caption": "Scheme 3. Plausible Catalytic Cycle", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 675, 284, 690], "ImageBB": [82, 696, 420, 965]}, "reactions": [{"reactants": [1, 6], "conditions": [7], "products": [5]}, {"reactants": [5, 9], "conditions": [10], "products": [3, 4, 13]}, {"reactants": [3, 8], "conditions": [2], "products": [0, 1]}], "diagram_type": "graph"}, {"id": 859, "width": 1344, "height": 2528, "file_name": "jo200480h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [63.0, 160.0, 257.0, 164.0], "category_id": 1}, {"id": 1, "bbox": [409.0, 1.0, 397.0, 120.0], "category_id": 1}, {"id": 2, "bbox": [583.0, 91.0, 34.0, 33.0], "category_id": 3}, {"id": 3, "bbox": [72.0, 384.0, 193.0, 54.0], "category_id": 2}, {"id": 4, "bbox": [953.0, 392.0, 189.0, 41.0], "category_id": 2}, {"id": 5, "bbox": [973.0, 332.0, 135.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [94.0, 332.0, 99.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [906.0, 34.0, 378.0, 293.0], "category_id": 1}, {"id": 8, "bbox": [2.0, 2445.0, 578.0, 58.0], "category_id": 2}, {"id": 9, "bbox": [75.0, 514.4, 1200.0, 1870.6], "category_id": 4}, {"id": 10, "bbox": [274.26, 123.74, 599.0, 102.1], "category_id": 2}, {"id": 11, "bbox": [440.69, 234.47, 332.29, 55.43], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [1, 10, 11], "products": [7]}], "corefs": [[0, 6], [1, 2], [7, 5]], "caption": "Table 2. Heteroannulation Reaction between Halogenated 4-Acetamido-3-iodopyridines 4 9 and Diphenylacetylene (2) ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 397, 122], "ImageBB": [71, 133, 407, 765]}, "diagram_type": "single"}, {"id": 167, "width": 1348, "height": 516, "file_name": "op500334b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [763.0, 5.0, 477.0, 277.0], "category_id": 1}, {"id": 1, "bbox": [108.0, 2.0, 313.0, 280.0], "category_id": 1}, {"id": 2, "bbox": [891.0, 251.0, 123.0, 73.0], "category_id": 3}, {"id": 3, "bbox": [157.0, 261.0, 125.0, 70.0], "category_id": 3}, {"id": 4, "bbox": [513.0, 44.0, 179.0, 112.0], "category_id": 2}, {"id": 5, "bbox": [554.0, 209.0, 65.0, 41.0], "category_id": 2}, {"id": 6, "bbox": [6.0, 352.0, 1337.0, 164.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [0]}], "corefs": [[1, 3], [0, 2]], "caption": "Table 1. Optimization of the Hurtley reaction of 6a, 6b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 463, 396, 478], "ImageBB": [82, 484, 419, 613]}, "diagram_type": "single"}, {"id": 81, "width": 1412, "height": 2660, "file_name": "ja075824w-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [309.2, 271.79, 184.1, 53.11], "category_id": 2}, {"id": 1, "bbox": [1026.15, 119.39, 289.47, 299.87], "category_id": 1}, {"id": 2, "bbox": [28.65, 119.4, 220.2, 299.86], "category_id": 1}, {"id": 3, "bbox": [619.27, 322.71, 265.81, 48.32], "category_id": 2}, {"id": 4, "bbox": [516.57, 169.66, 471.21, 107.44], "category_id": 2}, {"id": 5, "bbox": [291.7, 342.85, 210.76, 50.33], "category_id": 2}], "reactions": [{"reactants": [2, 0], "conditions": [4, 3], "products": [1]}], "corefs": [], "caption": "Figure 3. Effect of auxiliary base on the DMAP-catalyzed acetylation, isobutyrylation, and pivaloylation of l-menthol with acid anhydride. The reaction of l-menthol (5 mmol) was conducted with (RCO)2O (5.5 mmol) under solvent-free conditions or in heptane (5 mL): red squares, 1 (0.1 mol %) and i-Pr2NEt (1.1 equiv); green circles, 1 (0.1 mol %) without i-Pr2- NEt; blue triangles, i-Pr2NEt (1.1 equiv) without 1. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 704, 409, 779], "ImageBB": [74, 35, 427, 700]}, "diagram_type": "single"}, {"id": 505, "width": 1348, "height": 1012, "file_name": "ol051920v-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [668.0, 122.0, 183.0, 51.0], "category_id": 2}, {"id": 1, "bbox": [627.0, 52.0, 278.0, 54.0], "category_id": 2}, {"id": 2, "bbox": [464.0, 208.0, 54.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [211.0, 190.0, 25.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [1004.0, 185.0, 30.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [932.0, 0.0, 286.0, 182.0], "category_id": 1}, {"id": 6, "bbox": [143.0, 5.0, 227.0, 178.0], "category_id": 1}, {"id": 7, "bbox": [31.0, 301.0, 1294.0, 711.0], "category_id": 4}, {"id": 8, "bbox": [416.0, 50.0, 184.0, 153.0], "category_id": 1}], "reactions": [{"reactants": [6, 8], "conditions": [1, 0], "products": [5]}], "corefs": [[6, 3], [8, 2], [5, 4]], "caption": "Table 2. Reactions of Salicylic Aldehydes 1 (0.5 mmol) with 3-Methylpenta-3,4-dien-2-one 2a (1.0 mmol) in the Presence of DBU (10 mol %) in DMSO at Room Temperature ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 768, 120], "ImageBB": [439, 125, 776, 378]}, "diagram_type": "single"}, {"id": 246, "width": 1348, "height": 380, "file_name": "ol9005079-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [683.0, 4.0, 192.0, 92.0], "category_id": 2}, {"id": 1, "bbox": [526.0, 204.0, 56.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [104.0, 204.0, 31.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [5.0, 277.0, 1339.0, 97.0], "category_id": 2}, {"id": 4, "bbox": [685.0, 137.0, 159.0, 90.0], "category_id": 2}, {"id": 5, "bbox": [1134.0, 199.0, 35.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [348.0, 21.0, 266.0, 203.0], "category_id": 1}, {"id": 7, "bbox": [30.0, 41.0, 238.0, 166.0], "category_id": 1}, {"id": 8, "bbox": [927.0, 18.0, 395.0, 197.0], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [0, 4], "products": [8]}], "corefs": [[7, 2], [6, 1], [8, 5]], "caption": "Table 3. Proving the Scope of Indoles in the tBuTMG-Catalyzed Alkylation Process with 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 176, 670, 203], "ImageBB": [425, 212, 762, 307]}, "diagram_type": "single"}, {"id": 827, "width": 1352, "height": 968, "file_name": "jo4007046-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1106.0, 738.0, 33.6, 30.0], "category_id": 3}, {"id": 1, "bbox": [1217.8, 524.5, 92.9, 254.5], "category_id": 1}, {"id": 2, "bbox": [1072.0, 520.3, 97.8, 203.7], "category_id": 1}, {"id": 3, "bbox": [922.5, 519.0, 87.5, 200.6], "category_id": 1}, {"id": 4, "bbox": [668.0, 559.0, 241.9, 57.0], "category_id": 1}, {"id": 5, "bbox": [545.0, 523.8, 91.6, 196.5], "category_id": 1}, {"id": 6, "bbox": [635.0, 687.0, 20.0, 29.0], "category_id": 3}, {"id": 7, "bbox": [1310.0, 665.0, 19.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [946.0, 735.0, 37.0, 30.0], "category_id": 3}, {"id": 9, "bbox": [716.0, 648.0, 95.0, 31.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [4, 9], "products": [3, 2, 1]}], "corefs": [[5, 6], [3, 8], [2, 0], [1, 7]], "caption": "Figure 3. Ratio between the yield of 4-allyltoluene (6) and that of the other photoproducts (toluene 1a and 4-methylanisole 1b) from the irradiation of 4-chlorotoluene (1) in MeOH in the presence of an increasing amount of allyltrimethylsilane (ATMS). ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1004, 417, 1059], "ImageBB": [82, 743, 420, 985]}, "diagram_type": "single"}, {"id": 482, "width": 1344, "height": 1088, "file_name": "ol0616236-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [905.0, 231.8, 356.8, 92.4], "category_id": 3}, {"id": 1, "bbox": [95.0, 309.0, 416.5, 97.4], "category_id": 3}, {"id": 2, "bbox": [646.0, 0.0, 146.0, 134.6], "category_id": 1}, {"id": 3, "bbox": [926.9, 16.2, 270.8, 178.2], "category_id": 1}, {"id": 4, "bbox": [601.0, 159.0, 248.6, 99.8], "category_id": 2}, {"id": 5, "bbox": [83.9, 25.2, 399.5, 237.0], "category_id": 1}, {"id": 6, "bbox": [325.0, 226.0, 50.0, 52.0], "category_id": 3}, {"id": 7, "bbox": [2.0, 448.0, 1342.0, 640.0], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [2, 4], "products": [3]}], "corefs": [[5, 6], [3, 0]], "caption": "Table 2. Condensations of 2b and 2c with Aldehydes", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 580, 359, 593], "ImageBB": [74, 602, 410, 874]}, "diagram_type": "single"}, {"id": 139, "width": 1284, "height": 1228, "file_name": "op8001596-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [969.0, 0.0, 307.1, 229.7], "category_id": 1}, {"id": 1, "bbox": [362.0, 43.5, 494.0, 64.5], "category_id": 2}, {"id": 2, "bbox": [119.5, 251.2, 60.3, 69.8], "category_id": 3}, {"id": 3, "bbox": [1080.0, 296.9, 40.7, 63.1], "category_id": 3}, {"id": 4, "bbox": [363.91, 130.58, 392.09, 64.22], "category_id": 2}, {"id": 5, "bbox": [8.0, 373.0, 1276.0, 855.0], "category_id": 4}, {"id": 6, "bbox": [7.7, 23.4, 309.1, 178.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [1, 4], "products": [0]}], "corefs": [[6, 2], [0, 3]], "caption": "Figure 2. Decomposition profile of 2-lithio-3,4-difluoroanisole 6 (0.47 M). 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Overall comparison of productivities", "pdf": {"Page": 12, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 311, 60], "ImageBB": [58, 61, 411, 424]}, "diagram_type": "multiple"}, {"id": 381, "width": 1348, "height": 1760, "file_name": "ol071385u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [514.4, 135.1, 315.6, 68.9], "category_id": 2}, {"id": 1, "bbox": [196.58, 205.78, 66.64, 56.08], "category_id": 3}, {"id": 2, "bbox": [925.5, 0.0, 348.0, 283.6], "category_id": 1}, {"id": 3, "bbox": [1000.52, 197.6, 54.9, 63.6], "category_id": 3}, {"id": 4, "bbox": [6.0, 299.0, 1342.0, 1461.0], "category_id": 4}, {"id": 5, "bbox": [620.6, 52.0, 136.8, 57.1], "category_id": 2}, {"id": 6, "bbox": [85.6, 13.0, 368.7, 254.7], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 0], "products": [2]}], "corefs": [[6, 1], [2, 3]], "caption": "Table 2. Pd-Catalyzed Cyclization of Propargylic Compounds 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 356, 774, 369], "ImageBB": [439, 371, 776, 811]}, "diagram_type": "single"}, {"id": 164, "width": 1348, "height": 476, "file_name": "op500334b-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [97.0, 242.0, 38.0, 30.0], "category_id": 3}, {"id": 1, "bbox": [438.0, 33.0, 326.0, 99.8], "category_id": 2}, {"id": 2, "bbox": [24.0, 7.0, 349.0, 271.0], "category_id": 1}, {"id": 3, "bbox": [809.0, 15.0, 501.0, 273.0], "category_id": 1}, {"id": 4, "bbox": [560.0, 187.0, 59.0, 37.0], "category_id": 2}, {"id": 5, "bbox": [482.0, 235.0, 221.0, 29.0], "category_id": 2}, {"id": 6, "bbox": [920.0, 226.0, 36.0, 33.0], "category_id": 3}, {"id": 7, "bbox": [9.0, 311.0, 1334.0, 165.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [1, 4, 5], "products": [3]}], "corefs": [[2, 0], [3, 6]], "caption": "Table 4. Optimization of the base and copper catalyst of the Hurtley reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 125], "ImageBB": [449, 131, 786, 250]}, "diagram_type": "single"}, {"id": 1040, "width": 1324, "height": 1336, "file_name": "jo010170+-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.39, 499.91, 403.02, 203.85], "category_id": 1}, {"id": 1, "bbox": [880.88, 496.57, 367.59, 204.51], "category_id": 1}, {"id": 2, "bbox": [842.12, 0.0, 457.82, 245.28], "category_id": 1}, {"id": 3, "bbox": [1037.28, 255.3, 52.8, 42.78], "category_id": 3}, {"id": 4, "bbox": [880.88, 987.8, 342.86, 201.17], "category_id": 1}, {"id": 5, "bbox": [126.99, 49.46, 457.81, 202.5], "category_id": 1}, {"id": 6, "bbox": [189.81, 1010.52, 332.84, 205.18], "category_id": 1}, {"id": 7, "bbox": [926.33, 706.8, 296.08, 132.63], "category_id": 3}, {"id": 8, "bbox": [260.4, 255.2, 178.4, 101.0], "category_id": 3}, {"id": 9, "bbox": [214.54, 1226.9, 260.66, 101.08], "category_id": 3}, {"id": 10, "bbox": [6.02, 713.8, 760.57, 137.5], "category_id": 3}, {"id": 11, "bbox": [856.4, 1199.8, 401.0, 121.5], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 271, 636, 285], "ImageBB": [442, 291, 773, 625]}, "reactions": [{"reactants": [5], "conditions": [], "products": [0]}, {"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [0], "conditions": [], "products": [1]}, {"reactants": [0, 1], "conditions": [], "products": [6]}], "diagram_type": "graph"}, {"id": 116, "width": 1196, "height": 1184, "file_name": "op9802071-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 891.0, 246.0, 207.3], "category_id": 1}, {"id": 1, "bbox": [464.0, 165.4, 377.0, 332.6], "category_id": 1}, {"id": 2, "bbox": [660.0, 898.0, 349.0, 205.6], "category_id": 1}, {"id": 3, "bbox": [290.0, 834.0, 380.0, 157.4], "category_id": 2}, {"id": 4, "bbox": [694.0, 585.0, 65.9, 47.8], "category_id": 3}, {"id": 5, "bbox": [72.0, 94.0, 342.0, 442.0], "category_id": 1}, {"id": 6, "bbox": [266.0, 588.0, 59.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [60.0, 1114.0, 99.0, 50.0], "category_id": 3}, {"id": 8, "bbox": [831.0, 1139.0, 47.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3], "products": [2]}], "corefs": [[5, 6], [1, 4], [0, 7], [2, 8]], "caption": "Figure 1.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 432, 129, 446], "ImageBB": [128, 269, 427, 565]}, "diagram_type": "single"}, {"id": 323, "width": 1476, "height": 3744, "file_name": "ol301556a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [417.94, 241.88, 244.0, 50.0], "category_id": 2}, {"id": 1, "bbox": [1273.0, 235.0, 106.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [401.0, 16.0, 265.0, 85.0], "category_id": 2}, {"id": 3, "bbox": [152.0, 383.0, 1324.0, 1937.0], "category_id": 4}, {"id": 4, "bbox": [125.0, 2313.0, 1351.0, 1342.0], "category_id": 2}, {"id": 5, "bbox": [781.0, 237.0, 102.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [143.0, 39.0, 241.0, 149.8], "category_id": 1}, {"id": 7, "bbox": [1229.0, 31.0, 229.0, 198.9], "category_id": 1}, {"id": 8, "bbox": [706.9, 6.0, 234.1, 202.4], "category_id": 1}, {"id": 9, "bbox": [946.9, 134.0, 269.1, 85.0], "category_id": 2}, {"id": 10, "bbox": [947.0, 16.0, 273.0, 92.0], "category_id": 2}, {"id": 11, "bbox": [516.6, 128.8, 152.6, 115.2], "category_id": 1}, {"id": 12, "bbox": [727.0, 272.0, 201.0, 43.0], "category_id": 2}, {"id": 13, "bbox": [401.9, 130.3, 118.3, 96.92], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [2, 13, 11, 0], "products": [8]}, {"reactants": [8], "conditions": [10, 9], "products": [7]}], "corefs": [[8, 5], [7, 1]], "caption": "Table 2. 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