dev3.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 1045, "width": 2140, "height": 1636, "file_name": "jo0108865-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [254.79, 103.85, 178.78, 66.38], "category_id": 2}, {"id": 1, "bbox": [1873.44, 20.34, 266.56, 314.76], "category_id": 1}, {"id": 2, "bbox": [41.75, 865.04, 343.64, 64.24], "category_id": 2}, {"id": 3, "bbox": [974.19, 1573.78, 276.2, 55.67], "category_id": 3}, {"id": 4, "bbox": [1475.38, 77.44, 398.23, 55.67], "category_id": 2}, {"id": 5, "bbox": [1471.4, 504.25, 266.08, 207.7], "category_id": 1}, {"id": 6, "bbox": [1495.54, 730.15, 156.3, 56.74], "category_id": 3}, {"id": 7, "bbox": [1477.34, 1130.55, 267.63, 107.06], "category_id": 3}, {"id": 8, "bbox": [1470.92, 174.51, 129.53, 58.88], "category_id": 2}, {"id": 9, "bbox": [0.0, 510.68, 232.31, 208.76], "category_id": 1}, {"id": 10, "bbox": [1154.04, 312.61, 491.37, 105.99], "category_id": 3}, {"id": 11, "bbox": [571.67, 41.75, 200.19, 245.17], "category_id": 1}, {"id": 12, "bbox": [41.75, 321.18, 165.93, 103.85], "category_id": 3}, {"id": 13, "bbox": [41.75, 964.61, 165.93, 101.71], "category_id": 2}, {"id": 14, "bbox": [0.0, 61.02, 185.2, 240.89], "category_id": 1}, {"id": 15, "bbox": [969.9, 981.74, 285.84, 103.85], "category_id": 2}, {"id": 16, "bbox": [571.67, 314.76, 285.83, 107.06], "category_id": 3}, {"id": 17, "bbox": [377.9, 1581.27, 324.37, 54.6], "category_id": 3}, {"id": 18, "bbox": [377.9, 520.31, 140.24, 64.24], "category_id": 2}, {"id": 19, "bbox": [969.9, 885.38, 291.19, 62.1], "category_id": 2}, {"id": 20, "bbox": [1265.37, 6.42, 189.49, 296.56], "category_id": 1}, {"id": 21, "bbox": [499.94, 844.7, 385.39, 207.7], "category_id": 1}, {"id": 22, "bbox": [681.93, 735.5, 475.32, 58.88], "category_id": 3}, {"id": 23, "bbox": [807.18, 192.71, 279.41, 62.09], "category_id": 2}, {"id": 24, "bbox": [896.04, 1282.58, 328.65, 230.18], "category_id": 1}, {"id": 25, "bbox": [527.77, 1096.29, 337.22, 63.17], "category_id": 3}, {"id": 26, "bbox": [278.34, 183.07, 143.45, 56.74], "category_id": 2}, {"id": 27, "bbox": [1837.04, 350.09, 302.96, 64.23], "category_id": 3}, {"id": 28, "bbox": [113.48, 1339.32, 50.31, 51.39], "category_id": 3}, {"id": 29, "bbox": [41.75, 741.92, 73.87, 53.53], "category_id": 3}, {"id": 30, "bbox": [762.22, 499.97, 271.92, 211.98], "category_id": 1}, {"id": 31, "bbox": [348.99, 1286.86, 326.52, 243.02], "category_id": 1}, {"id": 32, "bbox": [1410.97, 867.18, 371.47, 237.68], "category_id": 1}, {"id": 33, "bbox": [965.62, 1086.66, 264.43, 133.82], "category_id": 1}, {"id": 34, "bbox": [807.18, 92.07, 313.67, 66.38], "category_id": 2}, {"id": 35, "bbox": [1150.83, 518.17, 195.9, 72.8], "category_id": 2}], "caption": "Scheme 4", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 64, 453, 78], "ImageBB": [158, 85, 693, 494]}, "reactions": [{"reactants": [14], "conditions": [0, 26], "products": [11]}, {"reactants": [11], "conditions": [34, 23], "products": [20]}, {"reactants": [20], "conditions": [4, 8], "products": [1]}, {"reactants": [9], "conditions": [18], "products": [30]}, {"reactants": [30], "conditions": [35], "products": [5]}, {"reactants": [5], "conditions": [2, 13], "products": [21]}, {"reactants": [21], "conditions": [19, 15, 33], "products": [32]}, {"reactants": [32], "conditions": [28], "products": [31]}], "diagram_type": "multiple"}, {"id": 607, "width": 1356, "height": 300, "file_name": "acs.oprd.5b00371-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [518.0, 35.0, 191.0, 46.0], "category_id": 2}, {"id": 1, "bbox": [905.0, 6.0, 338.0, 223.0], "category_id": 1}, {"id": 2, "bbox": [112.0, 39.0, 272.0, 139.0], "category_id": 1}, {"id": 3, "bbox": [1101.0, 216.0, 25.0, 33.0], "category_id": 3}, {"id": 4, "bbox": [208.0, 214.0, 26.0, 39.0], "category_id": 3}, {"id": 5, "bbox": [470.0, 116.0, 280.0, 99.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [0, 5], "products": [1]}], "corefs": [[2, 4], [1, 3]], "caption": "Table 3. Comparison of the Amount of BF3OEt2 for the Formation of 3a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 701, 767, 731], "ImageBB": [448, 621, 787, 696]}, "diagram_type": "single"}, {"id": 404, "width": 1352, "height": 1772, "file_name": "op400278d-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [34.14, 840.0, 388.0, 111.0], "category_id": 3}, {"id": 1, "bbox": [544.0, 844.0, 364.0, 105.0], "category_id": 3}, {"id": 2, "bbox": [548.0, 134.8, 241.2, 65.2], "category_id": 2}, {"id": 3, "bbox": [150.8, 1123.0, 427.3, 383.1], "category_id": 1}, {"id": 4, "bbox": [1045.5, 530.8, 306.5, 320.2], "category_id": 1}, {"id": 5, "bbox": [534.4, 438.5, 406.6, 385.7], "category_id": 1}, {"id": 6, "bbox": [12.0, 984.0, 1158.0, 115.0], "category_id": 2}, {"id": 7, "bbox": [5.0, 316.0, 1132.0, 105.0], "category_id": 2}, {"id": 8, "bbox": [7.0, 425.5, 435.7, 394.0], "category_id": 1}, {"id": 9, "bbox": [866.0, 0.0, 450.0, 305.0], "category_id": 1}, {"id": 10, "bbox": [50.4, 51.4, 171.3, 198.6], "category_id": 1}, {"id": 11, "bbox": [143.0, 1529.0, 417.9, 109.9], "category_id": 3}, {"id": 12, "bbox": [1102.0, 874.2, 177.0, 43.8], "category_id": 3}, {"id": 13, "bbox": [812.75, 1532.37, 468.0, 207.0], "category_id": 3}, {"id": 14, "bbox": [824.6, 1121.4, 443.4, 427.6], "category_id": 1}, {"id": 15, "bbox": [274.66, 244.73, 190.03, 57.01], "category_id": 2}, {"id": 16, "bbox": [307.91, 47.58, 171.03, 201.9], "category_id": 1}, {"id": 17, "bbox": [34.75, 244.73, 192.4, 56.97], "category_id": 2}], "reactions": [{"reactants": [10, 16], "conditions": [2], "products": [9]}], "corefs": [[8, 0], [5, 1], [4, 12], [3, 11], [14, 13]], "caption": "Table 7. Formation of symmetric triarylamines with Pd- PEPPSI-IPentCl (84) in the presence of excess aryl chloride and aniline derivatives ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 94, 416, 139], "ImageBB": [82, 146, 420, 589]}, "diagram_type": "single"}, {"id": 27, "width": 1352, "height": 1396, "file_name": "ja9039289-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [283.2, 176.39, 302.82, 48.83], "category_id": 2}, {"id": 1, "bbox": [239.97, 3.46, 387.48, 137.1], "category_id": 2}, {"id": 2, "bbox": [951.48, 165.58, 374.82, 50.63], "category_id": 2}, {"id": 3, "bbox": [1052.35, 53.9, 153.31, 50.6], "category_id": 2}, {"id": 4, "bbox": [647.06, 100.73, 254.18, 111.88], "category_id": 1}, {"id": 5, "bbox": [23.82, 98.93, 201.98, 110.08], "category_id": 1}, {"id": 6, "bbox": [2.2, 264.65, 1345.76, 1129.61], "category_id": 4}, {"id": 7, "bbox": [1109.99, 106.13, 39.83, 45.24], "category_id": 3}, {"id": 8, "bbox": [1111.79, 214.21, 39.83, 41.63], "category_id": 3}, {"id": 9, "bbox": [749.74, 216.01, 39.82, 39.83], "category_id": 3}, {"id": 10, "bbox": [95.87, 214.21, 34.42, 41.63], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [1, 0], "products": [4, 3, 2]}], "corefs": [[5, 10], [4, 9], [3, 7], [2, 8]], "caption": "Table 2. Screening of Cobalt and Nickel Salts in the Presence of Various NHC Ligands ", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 384, 81], "ImageBB": [58, 89, 396, 438]}, "diagram_type": "single"}, {"id": 1241, "width": 916, "height": 1456, "file_name": "op0255736-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [13.1, 426.09, 211.86, 190.83], "category_id": 1}, {"id": 1, "bbox": [112.85, 622.02, 45.86, 44.43], "category_id": 3}, {"id": 2, "bbox": [481.96, 6.56, 247.53, 258.56], "category_id": 1}, {"id": 3, "bbox": [625.38, 1416.67, 37.86, 34.96], "category_id": 3}, {"id": 4, "bbox": [102.65, 252.01, 35.68, 42.98], "category_id": 3}, {"id": 5, "bbox": [671.25, 1000.04, 186.37, 179.91], "category_id": 2}, {"id": 6, "bbox": [753.51, 574.68, 157.26, 135.48], "category_id": 2}, {"id": 7, "bbox": [619.56, 929.39, 48.77, 48.8], "category_id": 3}, {"id": 8, "bbox": [288.3, 914.83, 133.23, 123.09], "category_id": 2}, {"id": 9, "bbox": [11.65, 11.65, 235.88, 223.61], "category_id": 1}, {"id": 10, "bbox": [240.25, 581.96, 192.2, 83.76], "category_id": 2}, {"id": 11, "bbox": [756.43, 180.63, 152.88, 130.38], "category_id": 2}, {"id": 12, "bbox": [395.11, 451.05, 47.2, 38.45], "category_id": 2}, {"id": 13, "bbox": [263.55, 186.46, 179.09, 158.78], "category_id": 2}, {"id": 14, "bbox": [472.49, 771.34, 342.18, 186.46], "category_id": 1}, {"id": 15, "bbox": [481.96, 1189.42, 321.79, 218.51], "category_id": 1}, {"id": 16, "bbox": [472.49, 394.77, 326.89, 219.97], "category_id": 1}, {"id": 17, "bbox": [602.08, 1368.6, 188.56, 50.25], "category_id": 2}, {"id": 18, "bbox": [240.25, 378.75, 260.64, 162.42], "category_id": 1}, {"id": 19, "bbox": [32.76, 729.82, 325.43, 225.79], "category_id": 1}, {"id": 20, "bbox": [288.3, 31.32, 158.71, 107.07], "category_id": 1}], "caption": "Scheme 1. First-generation synthesis", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 306, 651, 320], "ImageBB": [494, 325, 723, 689]}, "reactions": [{"reactants": [9, 20], "conditions": [13], "products": [2]}, {"reactants": [2], "conditions": [11], "products": [0]}, {"reactants": [0, 18], "conditions": [10], "products": [16]}, {"reactants": [16], "conditions": [6], "products": [19]}, {"reactants": [19], "conditions": [8], "products": [14]}, {"reactants": [14], "conditions": [5], "products": [15, 17]}], "diagram_type": "tree"}, {"id": 638, "width": 1312, "height": 1336, "file_name": "ol501019y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [211.0, 215.0, 193.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [7.0, 273.0, 1305.0, 1063.0], "category_id": 4}, {"id": 2, "bbox": [945.0, 175.0, 26.0, 34.0], "category_id": 3}, {"id": 3, "bbox": [289.0, 185.0, 29.0, 32.0], "category_id": 3}, {"id": 4, "bbox": [245.0, 13.0, 145.0, 168.0], "category_id": 1}, {"id": 5, "bbox": [407.0, 50.0, 361.0, 59.0], "category_id": 2}, {"id": 6, "bbox": [855.0, 206.0, 196.0, 56.0], "category_id": 2}, {"id": 7, "bbox": [449.0, 114.0, 283.0, 87.9], "category_id": 2}, {"id": 8, "bbox": [796.0, 2.0, 308.0, 172.1], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [5, 7], "products": [8]}], "corefs": [[4, 3], [8, 2]], "caption": "Table 4. Palladium-Catalyzed Homocoupling of 3- Substituted Furans and Thiophenesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 733, 125], "ImageBB": [453, 131, 781, 465]}, "diagram_type": "single"}, {"id": 863, "width": 1356, "height": 992, "file_name": "jo2003264-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [306.0, 102.0, 135.0, 47.0], "category_id": 1}, {"id": 1, "bbox": [354.0, 166.0, 31.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [86.0, 163.0, 45.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [2.0, 102.0, 213.0, 47.0], "category_id": 1}, {"id": 4, "bbox": [517.0, 127.0, 281.0, 78.0], "category_id": 2}, {"id": 5, "bbox": [707.0, 327.0, 53.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [1111.0, 329.0, 53.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [554.28, 198.83, 294.0, 128.0], "category_id": 1}, {"id": 8, "bbox": [941.0, 198.83, 415.0, 127.0], "category_id": 1}, {"id": 9, "bbox": [9.2, 444.2, 1331.8, 547.8], "category_id": 4}, {"id": 10, "bbox": [469.11, 8.0, 762.0, 100.0], "category_id": 2}], "reactions": [{"reactants": [3, 0], "conditions": [10, 4], "products": [7, 8]}], "corefs": [[3, 2], [0, 1], [7, 5], [8, 6]], "caption": "Table 2. E\ufb00ects of Additives in the Ir-Catalyzed Oxidative Methyl Esteri\ufb01cation of 1a with 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 759, 122], "ImageBB": [436, 133, 775, 381]}, "diagram_type": "multiple"}, {"id": 479, "width": 1356, "height": 1940, "file_name": "ol0703579-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [41.0, 1014.0, 1219.0, 70.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 1146.0, 1356.0, 671.0], "category_id": 2}, {"id": 2, "bbox": [573.0, 76.0, 304.0, 64.0], "category_id": 2}, {"id": 3, "bbox": [8.0, 300.0, 1348.0, 714.0], "category_id": 4}, {"id": 4, "bbox": [1001.0, 220.0, 60.0, 55.0], "category_id": 3}, {"id": 5, "bbox": [416.0, 214.0, 45.0, 51.0], "category_id": 3}, {"id": 6, "bbox": [148.0, 223.0, 48.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [596.0, 146.0, 245.0, 106.0], "category_id": 2}, {"id": 8, "bbox": [879.0, 6.0, 360.2, 266.8], "category_id": 1}, {"id": 9, "bbox": [348.2, 85.6, 201.8, 184.2], "category_id": 1}, {"id": 10, "bbox": [43.0, 2.6, 293.0, 208.8], "category_id": 1}], "reactions": [{"reactants": [10, 9], "conditions": [2, 7], "products": [8]}], "corefs": [[10, 6], [9, 5], [8, 4]], "caption": "Table 1. Optimized Catalytic Asymmetric Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 724, 89], "ImageBB": [439, 93, 777, 578]}, "diagram_type": "single"}, {"id": 169, "width": 1352, "height": 704, "file_name": "op5002462-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [93.0, 38.8, 352.0, 288.2], "category_id": 1}, {"id": 1, "bbox": [484.0, 87.0, 330.0, 101.0], "category_id": 2}, {"id": 2, "bbox": [894.0, 101.0, 365.0, 236.0], "category_id": 1}, {"id": 3, "bbox": [831.6, 450.0, 350.4, 235.0], "category_id": 1}, {"id": 4, "bbox": [362.2, 449.0, 333.8, 194.0], "category_id": 1}, {"id": 5, "bbox": [414.0, 642.0, 157.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [894.0, 651.0, 157.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [959.0, 303.0, 161.0, 57.0], "category_id": 3}, {"id": 8, "bbox": [230.0, 313.0, 35.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [478.0, 229.0, 360.0, 90.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [1, 9], "products": [2, 4, 3]}], "corefs": [[0, 8], [2, 7], [4, 5], [3, 6]], "caption": "Figure 2. Allylic oxidation of valencene with SeO2 and TBHP.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 688, 379, 703], "ImageBB": [82, 502, 420, 678]}, "diagram_type": "multiple"}, {"id": 415, "width": 2820, "height": 2056, "file_name": "op400242j-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1477.0, 281.0, 45.0, 34.0], "category_id": 3}, {"id": 1, "bbox": [476.0, 789.0, 646.0, 395.0], "category_id": 1}, {"id": 2, "bbox": [699.0, 1170.0, 276.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [1340.0, 651.0, 254.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [439.0, 651.0, 28.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [536.0, 269.0, 26.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [2274.0, 524.0, 25.0, 33.0], "category_id": 3}, {"id": 7, "bbox": [1211.0, 893.0, 582.0, 49.0], "category_id": 2}, {"id": 8, "bbox": [1211.0, 947.0, 354.0, 42.0], "category_id": 2}, {"id": 9, "bbox": [804.0, 574.0, 193.0, 40.0], "category_id": 2}, {"id": 10, "bbox": [1251.0, 34.0, 406.0, 263.0], "category_id": 1}, {"id": 11, "bbox": [1885.0, 139.0, 644.0, 395.0], "category_id": 1}, {"id": 12, "bbox": [1307.0, 422.0, 353.0, 235.0], "category_id": 1}, {"id": 13, "bbox": [1213.0, 1001.0, 420.0, 43.0], "category_id": 2}, {"id": 14, "bbox": [1211.0, 1054.0, 579.0, 99.0], "category_id": 2}, {"id": 15, "bbox": [756.0, 65.0, 455.0, 50.0], "category_id": 2}, {"id": 16, "bbox": [818.0, 176.0, 301.0, 99.0], "category_id": 2}, {"id": 17, "bbox": [285.0, 408.0, 349.0, 237.0], "category_id": 1}, {"id": 18, "bbox": [288.0, 38.0, 408.0, 261.0], "category_id": 1}, {"id": 19, "bbox": [806.0, 467.0, 280.0, 46.0], "category_id": 2}, {"id": 20, "bbox": [805.0, 523.0, 207.0, 37.0], "category_id": 2}, {"id": 21, "bbox": [754.0, 120.0, 347.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [18], "conditions": [15, 21, 16], "products": [10]}, {"reactants": [17], "conditions": [19, 20, 9], "products": [12]}, {"reactants": [10, 12], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [7, 8, 13, 14], "products": [1]}], "corefs": [[18, 5], [10, 0], [11, 6], [17, 4], [12, 3], [1, 2]], "caption": "Figure 4. FTIR spectroscopy of DIPEA-catalyzed and DIPEA-free chlorinations.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 640, 471, 654], "ImageBB": [82, 116, 787, 630]}, "diagram_type": "tree"}, {"id": 923, "width": 1352, "height": 780, "file_name": "acs.joc.5b02382-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 294.9, 214.4, 100.78], "category_id": 1}, {"id": 1, "bbox": [726.39, 248.23, 121.06, 138.77], "category_id": 1}, {"id": 2, "bbox": [645.9, 293.55, 50.73, 41.25], "category_id": 2}, {"id": 3, "bbox": [461.94, 588.44, 319.91, 106.19], "category_id": 1}, {"id": 4, "bbox": [401.74, 449.79, 201.55, 96.72], "category_id": 1}, {"id": 5, "bbox": [1170.74, 251.61, 181.26, 131.22], "category_id": 1}, {"id": 6, "bbox": [627.64, 492.4, 257.01, 45.32], "category_id": 2}, {"id": 7, "bbox": [276.62, 286.11, 50.73, 33.81], "category_id": 2}, {"id": 8, "bbox": [802.14, 627.0, 161.64, 41.26], "category_id": 2}, {"id": 9, "bbox": [498.46, 537.72, 43.29, 33.14], "category_id": 3}, {"id": 10, "bbox": [925.91, 339.54, 121.06, 41.26], "category_id": 2}, {"id": 11, "bbox": [897.5, 278.67, 248.89, 40.58], "category_id": 2}, {"id": 12, "bbox": [256.33, 357.8, 104.83, 35.85], "category_id": 2}, {"id": 13, "bbox": [516.05, 399.06, 27.73, 32.47], "category_id": 3}, {"id": 14, "bbox": [771.03, 389.59, 42.6, 37.2], "category_id": 3}, {"id": 15, "bbox": [597.88, 703.43, 25.03, 31.11], "category_id": 3}, {"id": 16, "bbox": [522.81, 4.06, 169.08, 94.69], "category_id": 1}, {"id": 17, "bbox": [624.94, 140.01, 240.1, 81.16], "category_id": 2}, {"id": 18, "bbox": [417.98, 286.11, 186.67, 109.57], "category_id": 1}], "caption": "Scheme 1. Transition-Metal-Catalyzed Cyclization/ Functionalization of Propargylic Amides To Synthesize Oxazoles ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 743, 393, 788], "ImageBB": [82, 795, 420, 990]}, "reactions": [{"reactants": [18], "conditions": [2], "products": [1]}, {"reactants": [18], "conditions": [17], "products": [16]}, {"reactants": [18], "conditions": [7, 12], "products": [0]}, {"reactants": [18], "conditions": [11, 10], "products": [5]}, {"reactants": [18], "conditions": [4, 6], "products": [3]}], "diagram_type": "tree"}, {"id": 685, "width": 1344, "height": 1004, "file_name": "ol4013926-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [434.2, 877.3, 547.8, 106.0], "category_id": 2}, {"id": 1, "bbox": [22.6, 367.5, 432.4, 377.0], "category_id": 1}, {"id": 2, "bbox": [478.9, 368.2, 437.8, 378.9], "category_id": 1}, {"id": 3, "bbox": [972.3, 366.0, 335.0, 415.2], "category_id": 1}, {"id": 4, "bbox": [291.9, 186.8, 457.9, 96.7], "category_id": 2}, {"id": 5, "bbox": [474.0, 745.0, 312.0, 99.0], "category_id": 3}, {"id": 6, "bbox": [188.0, 747.0, 103.0, 61.0], "category_id": 3}], "reactions": [], "corefs": [[1, 6], [2, 5]], "caption": "Figure 1. Bifunctional quaternary phophonium salts and a possible working model. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 581, 405, 608], "ImageBB": [71, 317, 407, 568]}, "diagram_type": "tree"}, {"id": 345, "width": 1356, "height": 1192, "file_name": "ol202027k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [653.0, 220.0, 24.0, 31.0], "category_id": 3}, {"id": 1, "bbox": [1195.0, 184.0, 20.0, 26.0], "category_id": 3}, {"id": 2, "bbox": [451.0, 84.0, 95.0, 29.0], "category_id": 2}, {"id": 3, "bbox": [1.0, 72.0, 258.0, 146.0], "category_id": 1}, {"id": 4, "bbox": [329.0, 55.0, 105.0, 30.0], "category_id": 1}, {"id": 5, "bbox": [311.0, 183.0, 123.0, 35.0], "category_id": 1}, {"id": 6, "bbox": [1057.6, 20.8, 285.6, 197.6], "category_id": 1}, {"id": 7, "bbox": [595.0, 4.0, 152.0, 212.0], "category_id": 1}, {"id": 8, "bbox": [814.0, 14.0, 176.0, 184.0], "category_id": 1}, {"id": 9, "bbox": [6.0, 382.0, 1342.0, 807.0], "category_id": 4}, {"id": 10, "bbox": [192.0, 223.0, 40.0, 32.0], "category_id": 3}, {"id": 11, "bbox": [881.0, 225.0, 22.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [3, 4], "conditions": [2], "products": [7, 8]}, {"reactants": [3, 5], "conditions": [2], "products": [7, 8]}], "corefs": [[3, 10], [7, 0], [8, 11], [6, 1]], "caption": "Table 2. Regioselectivity of the Nitroso Diels Alder Reaction of 1,2-Dihydropyridine 1b ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 768, 114], "ImageBB": [436, 126, 775, 424]}, "diagram_type": "single"}, {"id": 722, "width": 1348, "height": 1352, "file_name": "ol0173127-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1002.6, 17.9, 309.2, 144.5], "category_id": 1}, {"id": 1, "bbox": [319.9, 0.0, 229.1, 160.0], "category_id": 1}, {"id": 2, "bbox": [282.47, 157.6, 197.55, 52.56], "category_id": 2}, {"id": 3, "bbox": [3.0, 272.9, 1345.0, 1077.1], "category_id": 4}, {"id": 4, "bbox": [22.0, 51.0, 150.6, 52.7], "category_id": 2}, {"id": 5, "bbox": [349.0, 209.0, 48.6, 47.7], "category_id": 3}, {"id": 6, "bbox": [82.0, 204.0, 62.8, 51.0], "category_id": 3}, {"id": 7, "bbox": [586.0, 2.0, 362.0, 65.0], "category_id": 2}, {"id": 8, "bbox": [597.0, 95.0, 358.0, 155.0], "category_id": 2}], "reactions": [{"reactants": [4, 1], "conditions": [7, 8], "products": [0]}], "corefs": [[4, 6], [1, 5]], "caption": "Table 1. Effect of Additives and Catalysts", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 311, 301, 324], "ImageBB": [74, 329, 411, 667]}, "diagram_type": "single"}, {"id": 29, "width": 1352, "height": 1604, "file_name": "ja9039289-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1051.85, 47.37, 152.05, 46.83], "category_id": 2}, {"id": 1, "bbox": [646.54, 106.01, 253.81, 105.48], "category_id": 1}, {"id": 2, "bbox": [99.8, 216.39, 27.87, 36.5], "category_id": 3}, {"id": 3, "bbox": [27.36, 100.84, 198.62, 105.48], "category_id": 1}, {"id": 4, "bbox": [1.32, 265.0, 1343.15, 1334.87], "category_id": 4}, {"id": 5, "bbox": [1113.94, 216.39, 33.05, 38.22], "category_id": 3}, {"id": 6, "bbox": [1113.94, 99.11, 31.32, 39.95], "category_id": 3}, {"id": 7, "bbox": [750.03, 216.39, 33.04, 38.22], "category_id": 3}, {"id": 8, "bbox": [286.07, 178.45, 296.93, 45.12], "category_id": 2}, {"id": 9, "bbox": [244.68, 4.25, 379.71, 134.81], "category_id": 2}, {"id": 10, "bbox": [951.82, 168.1, 371.09, 45.12], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [9, 8], "products": [1, 0, 10]}], "corefs": [[3, 2], [1, 7], [0, 6], [10, 5]], "caption": "Table 1. Effect of Iron Salts and Additives on the Cross-Coupling of Chlorobenzene with p-TolMgBr ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 385, 81], "ImageBB": [58, 89, 396, 490]}, "diagram_type": "single"}, {"id": 1162, "width": 1352, "height": 1228, "file_name": "ol060531d-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [471.41, 400.31, 289.47, 288.06], "category_id": 1}, {"id": 1, "bbox": [140.0, 537.57, 272.57, 99.41], "category_id": 2}, {"id": 2, "bbox": [988.81, 314.43, 46.66, 52.07], "category_id": 3}, {"id": 3, "bbox": [668.22, 831.04, 281.36, 104.14], "category_id": 2}, {"id": 4, "bbox": [928.61, 0.0, 299.62, 293.47], "category_id": 1}, {"id": 5, "bbox": [971.22, 810.08, 257.01, 294.15], "category_id": 1}, {"id": 6, "bbox": [703.39, 160.93, 154.88, 58.16], "category_id": 2}, {"id": 7, "bbox": [1033.44, 1123.84, 54.11, 51.39], "category_id": 3}, {"id": 8, "bbox": [431.5, 314.43, 44.64, 51.39], "category_id": 3}, {"id": 9, "bbox": [542.42, 688.37, 48.7, 48.68], "category_id": 3}, {"id": 10, "bbox": [470.73, 1117.07, 49.37, 49.37], "category_id": 3}, {"id": 11, "bbox": [144.06, 449.67, 332.08, 64.24], "category_id": 2}, {"id": 12, "bbox": [176.52, 806.02, 157.59, 154.85], "category_id": 2}, {"id": 13, "bbox": [1005.04, 686.34, 47.34, 50.71], "category_id": 3}, {"id": 14, "bbox": [938.08, 398.95, 290.15, 291.44], "category_id": 1}, {"id": 15, "bbox": [761.56, 540.28, 175.84, 89.93], "category_id": 2}, {"id": 16, "bbox": [704.07, 81.14, 169.76, 66.27], "category_id": 2}, {"id": 17, "bbox": [367.93, 810.08, 291.5, 292.12], "category_id": 1}, {"id": 18, "bbox": [669.57, 957.49, 267.83, 106.84], "category_id": 2}, {"id": 19, "bbox": [131.21, 0.0, 509.96, 352.97], "category_id": 1}, {"id": 20, "bbox": [761.56, 454.4, 170.43, 59.51], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 153, 631, 166], "ImageBB": [439, 171, 777, 478]}, "reactions": [{"reactants": [19], "conditions": [16, 6], "products": [4]}, {"reactants": [4], "conditions": [11, 1], "products": [0]}, {"reactants": [0], "conditions": [20, 15], "products": [14]}, {"reactants": [14], "conditions": [12], "products": [17]}, {"reactants": [17], "conditions": [3, 18], "products": [5]}], "diagram_type": "multiple"}, {"id": 895, "width": 1348, "height": 328, "file_name": "acs.joc.6b01262-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 253.0, 1342.0, 75.0], "category_id": 4}, {"id": 1, "bbox": [496.0, 21.0, 376.0, 107.0], "category_id": 2}, {"id": 2, "bbox": [550.0, 143.0, 248.0, 75.0], "category_id": 2}, {"id": 3, "bbox": [263.0, 182.0, 26.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [1057.0, 178.0, 36.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [118.1, 41.4, 317.8, 158.2], "category_id": 1}, {"id": 6, "bbox": [905.0, 6.0, 327.0, 185.7], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1, 2], "products": [6]}], "corefs": [[5, 3], [6, 4]], "caption": "Table 2. E\ufb00ect of Alkyl in the Alkoxy Group in the Benzylimidatesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 372, 125], "ImageBB": [82, 131, 419, 213]}, "diagram_type": "single"}, {"id": 280, "width": 1184, "height": 2508, "file_name": "ol800288b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [100.65, 145.57, 255.32, 58.18], "category_id": 2}, {"id": 1, "bbox": [559.58, 152.04, 80.8, 48.47], "category_id": 2}, {"id": 2, "bbox": [282.0, 6.0, 279.2, 302.7], "category_id": 1}, {"id": 3, "bbox": [19.0, 489.39, 1150.0, 2018.61], "category_id": 4}, {"id": 4, "bbox": [3.0, 338.0, 140.0, 54.0], "category_id": 2}, {"id": 5, "bbox": [175.0, 317.0, 570.0, 161.3], "category_id": 2}, {"id": 6, "bbox": [805.2, 232.9, 348.8, 105.7], "category_id": 1}, {"id": 7, "bbox": [1.0, 252.5, 128.0, 67.6], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [0, 2, 1, 5], "products": [6]}], "corefs": [], "caption": "Table 3. Aziridination of Olefins Catalyzed by 10% IPrCu(DBM)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 717, 104], "ImageBB": [460, 105, 756, 732]}, "diagram_type": "single"}, {"id": 808, "width": 3396, "height": 1324, "file_name": "jo4027148-Figure-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1696.0, 810.0, 331.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [2121.0, 971.4, 313.0, 285.8], "category_id": 1}, {"id": 2, "bbox": [2505.0, 752.0, 363.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [1934.0, 1030.0, 59.0, 47.0], "category_id": 2}, {"id": 4, "bbox": [507.0, 753.0, 361.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [770.0, 1274.0, 319.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [1650.0, 1275.0, 48.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [2259.0, 1273.0, 51.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [2599.0, 1278.0, 378.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [1653.0, 702.0, 47.0, 37.0], "category_id": 3}, {"id": 10, "bbox": [412.0, 288.0, 555.0, 439.0], "category_id": 1}, {"id": 11, "bbox": [1098.0, 380.0, 254.0, 91.0], "category_id": 2}, {"id": 12, "bbox": [1435.0, 318.0, 476.0, 375.0], "category_id": 1}, {"id": 13, "bbox": [1982.0, 383.0, 312.0, 87.0], "category_id": 2}, {"id": 14, "bbox": [1504.0, 965.0, 345.0, 277.0], "category_id": 1}, {"id": 15, "bbox": [794.0, 1053.0, 276.0, 118.0], "category_id": 1}, {"id": 16, "bbox": [1234.0, 1003.0, 131.0, 80.0], "category_id": 2}, {"id": 17, "bbox": [2405.0, 289.0, 554.0, 440.0], "category_id": 1}, {"id": 18, "bbox": [2726.0, 953.0, 177.0, 285.0], "category_id": 1}, {"id": 19, "bbox": [2556.0, 1030.0, 55.0, 36.0], "category_id": 2}], "reactions": [{"reactants": [10], "conditions": [11], "products": [12]}, {"reactants": [17], "conditions": [13], "products": [12]}, {"reactants": [12], "conditions": [0], "products": [14]}, {"reactants": [15], "conditions": [16], "products": [14]}, {"reactants": [14], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [19], "products": [18]}], "corefs": [[10, 4], [12, 9], [17, 2], [15, 5], [14, 6], [1, 7], [18, 8]], "caption": "Figure 7. Retrosynthesis of the piperarborenines from methyl coumalate (78).", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 362, 463, 376], "ImageBB": [10, 22, 859, 353]}, "diagram_type": "tree"}, {"id": 500, "width": 1352, "height": 1272, "file_name": "ol053021c-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [438.7, 138.3, 386.3, 118.7], "category_id": 2}, {"id": 1, "bbox": [476.9, 293.2, 310.7, 117.6], "category_id": 2}, {"id": 2, "bbox": [922.6, 167.2, 346.8, 233.0], "category_id": 1}, {"id": 3, "bbox": [81.7, 141.5, 313.6, 237.6], "category_id": 1}, {"id": 4, "bbox": [143.0, 323.0, 84.0, 84.0], "category_id": 3}, {"id": 5, "bbox": [41.0, 429.0, 1242.0, 842.0], "category_id": 4}, {"id": 6, "bbox": [977.0, 341.0, 74.0, 60.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0, 1], "products": [2]}], "corefs": [[3, 4], [2, 6]], "caption": "Figure 3. Direct comparison of catalysts 1a-d, conversion established by HPLC or GC analysis with benzoic acid and dodecane, respectively, as internal standards (average of 2-3 runs). ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 692, 775, 733], "ImageBB": [439, 362, 777, 680]}, "diagram_type": "single"}, {"id": 226, "width": 1396, "height": 1296, "file_name": "op010232y-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 10.0, 405.3, 221.6], "category_id": 1}, {"id": 1, "bbox": [448.0, 78.0, 146.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [243.0, 269.0, 54.0, 62.0], "category_id": 3}, {"id": 3, "bbox": [807.0, 320.0, 229.0, 65.0], "category_id": 2}, {"id": 4, "bbox": [936.0, 229.0, 49.0, 61.0], "category_id": 3}, {"id": 5, "bbox": [64.0, 641.0, 1332.0, 655.0], "category_id": 4}, {"id": 6, "bbox": [629.0, 0.0, 472.6, 235.0], "category_id": 1}, {"id": 7, "bbox": [456.0, 156.0, 135.0, 56.0], "category_id": 2}, {"id": 8, "bbox": [186.0, 336.0, 154.0, 60.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [1, 7], "products": [6]}], "corefs": [[0, 2], [6, 4]], "caption": "Figure 2. Effect of pH on reaction rate.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 401, 664, 415], "ImageBB": [424, 73, 773, 397]}, "diagram_type": "multiple"}, {"id": 618, "width": 3396, "height": 1556, "file_name": "acs.oprd.5b00170-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1844.0, 1414.0, 186.0, 61.0], "category_id": 2}, {"id": 1, "bbox": [773.0, 287.0, 254.0, 120.0], "category_id": 1}, {"id": 2, "bbox": [1338.0, 522.0, 181.0, 48.0], "category_id": 2}, {"id": 3, "bbox": [815.0, 1510.0, 55.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1501.0, 1510.0, 59.0, 46.0], "category_id": 3}, {"id": 5, "bbox": [2344.0, 1510.0, 34.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [1518.0, 1096.0, 27.0, 37.0], "category_id": 3}, {"id": 7, "bbox": [2344.0, 1090.0, 34.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [2340.0, 755.0, 38.0, 45.0], "category_id": 3}, {"id": 9, "bbox": [1513.0, 759.0, 40.0, 42.0], "category_id": 3}, {"id": 10, "bbox": [1505.0, 423.0, 56.0, 44.0], "category_id": 3}, {"id": 11, "bbox": [808.0, 423.0, 66.0, 44.0], "category_id": 3}, {"id": 12, "bbox": [2170.0, 1191.0, 179.0, 44.0], "category_id": 2}, {"id": 13, "bbox": [2170.0, 863.0, 177.0, 40.0], "category_id": 2}, {"id": 14, "bbox": [1401.0, 289.0, 318.0, 122.0], "category_id": 1}, {"id": 15, "bbox": [1074.0, 1411.0, 296.0, 61.0], "category_id": 2}, {"id": 16, "bbox": [1333.0, 1184.0, 191.0, 58.0], "category_id": 2}, {"id": 17, "bbox": [1074.0, 1032.0, 293.0, 66.0], "category_id": 2}, {"id": 18, "bbox": [849.0, 851.0, 188.0, 61.0], "category_id": 2}, {"id": 19, "bbox": [1338.0, 848.0, 186.0, 64.0], "category_id": 2}, {"id": 20, "bbox": [1805.0, 702.0, 269.0, 66.0], "category_id": 2}, {"id": 21, "bbox": [1071.0, 699.0, 294.0, 64.0], "category_id": 2}, {"id": 22, "bbox": [1069.0, 374.0, 306.0, 56.0], "category_id": 2}, {"id": 23, "bbox": [2099.0, 1298.0, 523.0, 196.0], "category_id": 1}, {"id": 24, "bbox": [1402.0, 1333.0, 315.0, 122.0], "category_id": 1}, {"id": 25, "bbox": [773.0, 1333.0, 253.0, 121.0], "category_id": 1}, {"id": 26, "bbox": [2104.0, 936.0, 517.0, 164.0], "category_id": 1}, {"id": 27, "bbox": [1401.0, 942.0, 327.0, 153.0], "category_id": 1}, {"id": 28, "bbox": [2102.0, 588.0, 519.0, 178.0], "category_id": 1}, {"id": 29, "bbox": [1404.0, 624.0, 298.0, 123.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [18], "products": [25]}, {"reactants": [14], "conditions": [22], "products": [1]}, {"reactants": [14], "conditions": [2], "products": [29]}, {"reactants": [29], "conditions": [19], "products": [27]}, {"reactants": [27], "conditions": [16], "products": [24]}, {"reactants": [24], "conditions": [15], "products": [25]}, {"reactants": [29], "conditions": [21, 18], "products": [25]}, {"reactants": [27], "conditions": [17, 18], "products": [25]}, {"reactants": [29, 27], "conditions": [20], "products": [28]}, {"reactants": [28], "conditions": [13], "products": [26]}, {"reactants": [26], "conditions": [12], "products": [23]}, {"reactants": [23], "conditions": [0], "products": [24]}], "corefs": [[1, 11], [14, 10], [25, 3], [29, 9], [27, 6], [24, 4], [28, 8], [26, 7], [23, 5]], "caption": "Figure 1. Mechanistic pathways for the reduction of 1-iodo-4-nitrobenzene.1e", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 418, 457, 435], "ImageBB": [10, 22, 859, 411]}, "diagram_type": "graph"}, {"id": 560, "width": 1348, "height": 1276, "file_name": "acs.orglett.5b01842-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [859.0, 5.0, 299.0, 146.7], "category_id": 1}, {"id": 1, "bbox": [416.9, 22.0, 228.1, 62.0], "category_id": 1}, {"id": 2, "bbox": [683.4, 1.4, 163.6, 38.6], "category_id": 2}, {"id": 3, "bbox": [191.4, 5.0, 168.3, 126.6], "category_id": 1}, {"id": 4, "bbox": [6.0, 206.0, 1340.0, 1070.0], "category_id": 4}, {"id": 5, "bbox": [494.0, 130.0, 33.0, 31.0], "category_id": 3}, {"id": 6, "bbox": [263.0, 134.0, 28.0, 31.0], "category_id": 3}, {"id": 7, "bbox": [1001.0, 146.0, 32.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [3, 1], "conditions": [2], "products": [0]}], "corefs": [[3, 6], [1, 5], [0, 7]], "caption": "Table 1. Reductive Amination of Phenol: Reaction Condition Optimization ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 523, 417, 553], "ImageBB": [82, 560, 419, 879]}, "diagram_type": "single"}, {"id": 1237, "width": 1336, "height": 556, "file_name": "op0202179-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [509.27, 0.0, 187.13, 54.11], "category_id": 2}, {"id": 1, "bbox": [531.33, 503.7, 154.38, 47.43], "category_id": 2}, {"id": 2, "bbox": [535.34, 425.54, 145.69, 44.76], "category_id": 2}, {"id": 3, "bbox": [0.0, 275.23, 370.26, 62.8], "category_id": 1}, {"id": 4, "bbox": [0.0, 42.09, 243.27, 58.78], "category_id": 1}, {"id": 5, "bbox": [934.33, 10.69, 157.73, 43.42], "category_id": 2}, {"id": 6, "bbox": [0.0, 456.27, 296.74, 61.46], "category_id": 1}, {"id": 7, "bbox": [415.7, 83.5, 366.25, 101.55], "category_id": 2}, {"id": 8, "bbox": [886.88, 247.17, 259.31, 49.44], "category_id": 2}, {"id": 9, "bbox": [932.33, 87.51, 167.08, 46.77], "category_id": 2}, {"id": 10, "bbox": [854.13, 452.93, 475.85, 62.79], "category_id": 1}, {"id": 11, "bbox": [934.33, 330.01, 165.75, 45.43], "category_id": 2}, {"id": 12, "bbox": [534.0, 325.33, 138.34, 58.12], "category_id": 2}, {"id": 13, "bbox": [467.83, 245.17, 270.01, 48.1], "category_id": 2}], "caption": "Scheme 1. Continuous synthesis of short peptides", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 246, 721, 260], "ImageBB": [441, 265, 775, 404]}, "reactions": [{"reactants": [4], "conditions": [0, 7, 5, 9], "products": [3]}, {"reactants": [3], "conditions": [13, 12, 8, 11], "products": [6]}, {"reactants": [6], "conditions": [2, 1], "products": [10]}], "diagram_type": "multiple"}, {"id": 1304, "width": 1356, "height": 656, "file_name": "op300058f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [48.84, 396.07, 248.95, 160.06], "category_id": 1}, {"id": 1, "bbox": [1270.53, 69.86, 85.47, 54.93], "category_id": 2}, {"id": 2, "bbox": [111.93, 194.65, 35.95, 40.01], "category_id": 3}, {"id": 3, "bbox": [300.5, 567.66, 37.99, 40.69], "category_id": 3}, {"id": 4, "bbox": [339.17, 36.62, 239.45, 120.05], "category_id": 1}, {"id": 5, "bbox": [1019.54, 193.29, 37.99, 43.4], "category_id": 3}, {"id": 6, "bbox": [801.12, 2.71, 405.65, 191.26], "category_id": 1}, {"id": 7, "bbox": [449.06, 191.25, 43.41, 43.41], "category_id": 3}, {"id": 8, "bbox": [320.18, 407.6, 240.81, 137.68], "category_id": 1}, {"id": 9, "bbox": [0.0, 31.2, 274.73, 132.93], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 505, 110], "ImageBB": [448, 116, 787, 280]}, "reactions": [{"reactants": [9, 4], "conditions": [], "products": [6, 1]}, {"reactants": [6, 1], "conditions": [], "products": [9, 4]}, {"reactants": [9, 4], "conditions": [], "products": [0, 8]}, {"reactants": [0, 8], "conditions": [], "products": [9, 4]}], "diagram_type": "tree"}, {"id": 400, "width": 1356, "height": 1124, "file_name": "op4003467-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [800.6, 16.6, 316.2, 281.9], "category_id": 1}, {"id": 1, "bbox": [342.49, 274.03, 78.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [321.57, 752.52, 184.0, 204.0], "category_id": 2}, {"id": 3, "bbox": [561.47, 647.0, 75.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [539.47, 877.48, 154.0, 61.0], "category_id": 2}, {"id": 5, "bbox": [374.7, 390.5, 302.3, 274.5], "category_id": 1}, {"id": 6, "bbox": [806.0, 391.5, 315.5, 320.5], "category_id": 1}, {"id": 7, "bbox": [220.1, 70.5, 316.9, 171.5], "category_id": 1}, {"id": 8, "bbox": [559.0, 189.6, 177.5, 91.4], "category_id": 1}, {"id": 9, "bbox": [564.0, 85.0, 144.0, 62.5], "category_id": 2}, {"id": 10, "bbox": [992.0, 276.0, 57.0, 57.0], "category_id": 3}, {"id": 11, "bbox": [230.0, 560.0, 150.0, 62.0], "category_id": 2}, {"id": 12, "bbox": [245.5, 463.6, 111.5, 49.4], "category_id": 2}, {"id": 13, "bbox": [490.0, 1023.0, 59.0, 62.0], "category_id": 3}, {"id": 14, "bbox": [209.0, 647.0, 231.0, 59.0], "category_id": 2}, {"id": 15, "bbox": [952.0, 703.0, 65.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [9, 8], "products": [0]}, {"reactants": [0], "conditions": [12, 11, 14], "products": [5, 6]}, {"reactants": [5], "conditions": [2, 4], "products": [13]}], "corefs": [[7, 1], [0, 10], [5, 3], [6, 15]], "caption": "Table 1. Dechlorination of 18", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 824, 619, 839], "ImageBB": [448, 537, 787, 818]}, "diagram_type": "tree"}, {"id": 306, "width": 1300, "height": 1696, "file_name": "ol302997q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [403.0, 271.0, 53.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [543.0, 57.2, 376.3, 93.8], "category_id": 2}, {"id": 2, "bbox": [587.0, 163.6, 301.7, 50.8], "category_id": 2}, {"id": 3, "bbox": [278.0, 70.3, 253.8, 180.8], "category_id": 1}, {"id": 4, "bbox": [965.7, 5.0, 334.3, 248.3], "category_id": 1}, {"id": 5, "bbox": [2.2, 74.7, 261.1, 203.2], "category_id": 1}, {"id": 6, "bbox": [1115.37, 271.0, 59.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [74.0, 271.0, 67.0, 52.0], "category_id": 3}, {"id": 8, "bbox": [0.0, 361.0, 1300.0, 1335.0], "category_id": 4}], "reactions": [{"reactants": [5, 3], "conditions": [1, 2], "products": [4]}], "corefs": [[5, 7], [3, 0], [4, 6]], "caption": "Table 2. Diels Alder Reaction of 3,5-Di-tert-butyl 1,2-Benzo- quinone with Arynes ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 768, 114], "ImageBB": [442, 126, 767, 550]}, "diagram_type": "single"}, {"id": 361, "width": 1368, "height": 1372, "file_name": "ol1030487-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [257.0, 318.0, 217.0, 135.0], "category_id": 1}, {"id": 1, "bbox": [338.84, 141.32, 228.5, 71.4], "category_id": 2}, {"id": 2, "bbox": [559.0, 320.2, 105.0, 127.8], "category_id": 1}, {"id": 3, "bbox": [326.0, 455.0, 42.0, 46.2], "category_id": 3}, {"id": 4, "bbox": [1033.0, 0.0, 318.0, 195.0], "category_id": 1}, {"id": 5, "bbox": [353.1, 34.4, 210.9, 65.6], "category_id": 1}, {"id": 6, "bbox": [0.0, 30.0, 295.0, 186.3], "category_id": 1}, {"id": 7, "bbox": [531.36, 77.27, 45.98, 42.3], "category_id": 3}, {"id": 8, "bbox": [1124.0, 214.0, 103.0, 44.0], "category_id": 3}, {"id": 9, "bbox": [0.0, 559.0, 1366.0, 813.0], "category_id": 4}, {"id": 10, "bbox": [593.0, 455.0, 26.0, 37.0], "category_id": 3}, {"id": 11, "bbox": [144.0, 214.0, 95.0, 37.0], "category_id": 3}, {"id": 12, "bbox": [730.0, 217.0, 100.0, 38.0], "category_id": 3}, {"id": 13, "bbox": [649.0, 2.0, 308.0, 201.0], "category_id": 1}, {"id": 14, "bbox": [799.0, 457.0, 46.0, 42.0], "category_id": 3}, {"id": 15, "bbox": [737.0, 328.0, 205.0, 125.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 1], "products": [13, 4]}], "corefs": [[6, 11], [5, 7], [13, 12], [4, 8], [0, 3], [2, 10], [15, 14]], "caption": "Table 1. Screening of Catalyst, Solvent, and Reaction Condi- tions for the Synthesis of Pentasubstituted Cyclopentanecar- baldehydesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 553, 762, 594], "ImageBB": [436, 593, 778, 936]}, "diagram_type": "single"}, {"id": 1234, "width": 1264, "height": 900, "file_name": "op020049k-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [849.83, 267.51, 398.99, 225.13], "category_id": 1}, {"id": 1, "bbox": [545.69, 648.85, 302.25, 60.71], "category_id": 2}, {"id": 2, "bbox": [338.29, 191.62, 34.78, 46.8], "category_id": 3}, {"id": 3, "bbox": [911.8, 566.0, 352.2, 228.3], "category_id": 1}, {"id": 4, "bbox": [545.69, 20.87, 598.17, 104.98], "category_id": 2}, {"id": 5, "bbox": [182.11, 5.69, 326.27, 169.49], "category_id": 1}, {"id": 6, "bbox": [1117.3, 853.74, 33.52, 40.48], "category_id": 3}, {"id": 7, "bbox": [339.55, 496.44, 45.53, 43.63], "category_id": 3}, {"id": 8, "bbox": [364.85, 849.95, 34.14, 42.37], "category_id": 3}, {"id": 9, "bbox": [153.65, 568.53, 356.63, 225.77], "category_id": 1}, {"id": 10, "bbox": [100.54, 267.51, 436.93, 225.76], "category_id": 1}, {"id": 11, "bbox": [604.49, 337.7, 146.7, 65.14], "category_id": 2}, {"id": 12, "bbox": [1117.93, 497.07, 39.21, 45.53], "category_id": 3}, {"id": 13, "bbox": [17.07, 650.74, 86.0, 51.86], "category_id": 2}], "caption": "Scheme 1. Synthesis of 2 using diazomethane", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 332, 67], "ImageBB": [85, 73, 401, 298]}, "reactions": [{"reactants": [5], "conditions": [4], "products": [10]}, {"reactants": [10], "conditions": [11], "products": [0]}, {"reactants": [0], "conditions": [13], "products": [9]}, {"reactants": [9], "conditions": [1], "products": [3]}], "diagram_type": "multiple"}, {"id": 1078, "width": 1356, "height": 436, "file_name": "jo501006u-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [548.1, 197.89, 54.94, 50.83], "category_id": 2}, {"id": 1, "bbox": [664.09, 16.27, 153.31, 151.8], "category_id": 1}, {"id": 2, "bbox": [1007.33, 149.1, 261.16, 98.27], "category_id": 2}, {"id": 3, "bbox": [692.58, 312.43, 127.53, 49.47], "category_id": 2}, {"id": 4, "bbox": [320.85, 346.31, 94.29, 46.76], "category_id": 2}, {"id": 5, "bbox": [281.51, 270.41, 176.37, 54.89], "category_id": 1}, {"id": 6, "bbox": [349.34, 22.36, 276.09, 53.54], "category_id": 2}, {"id": 7, "bbox": [664.09, 185.69, 151.95, 61.0], "category_id": 1}, {"id": 8, "bbox": [187.22, 314.46, 54.95, 52.18], "category_id": 2}, {"id": 9, "bbox": [87.51, 132.15, 191.29, 73.2], "category_id": 1}, {"id": 10, "bbox": [489.76, 305.65, 118.03, 54.22], "category_id": 1}], "caption": "Scheme 1. Possible Pathways in Metal-Catalyzed Alkyl\u2212 Alkyl Cross-Coupling ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 729, 765, 759], "ImageBB": [448, 765, 787, 874]}, "reactions": [{"reactants": [9], "conditions": [6], "products": [1]}, {"reactants": [9], "conditions": [], "products": [0, 7]}, {"reactants": [8], "conditions": [5, 4], "products": [10, 3]}], "diagram_type": "graph"}, {"id": 1143, "width": 1352, "height": 876, "file_name": "ol016693l-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [505.9, 657.16, 341.55, 49.36], "category_id": 2}, {"id": 1, "bbox": [482.23, 304.24, 376.04, 114.26], "category_id": 2}, {"id": 2, "bbox": [311.12, 4.06, 248.21, 183.22], "category_id": 1}, {"id": 3, "bbox": [254.98, 699.08, 206.28, 49.36], "category_id": 2}, {"id": 4, "bbox": [961.08, 533.44, 29.08, 38.54], "category_id": 3}, {"id": 5, "bbox": [566.1, 744.38, 204.93, 49.36], "category_id": 2}, {"id": 6, "bbox": [254.98, 338.05, 192.08, 156.85], "category_id": 1}, {"id": 7, "bbox": [567.45, 452.31, 204.93, 52.06], "category_id": 2}, {"id": 8, "bbox": [895.47, 349.54, 192.76, 172.41], "category_id": 1}, {"id": 9, "bbox": [870.45, 185.93, 34.49, 43.94], "category_id": 3}, {"id": 10, "bbox": [749.38, 0.0, 252.95, 180.52], "category_id": 1}, {"id": 11, "bbox": [885.24, 648.84, 188.24, 137.76], "category_id": 1}, {"id": 12, "bbox": [926.7, 748.44, 34.38, 40.56], "category_id": 3}, {"id": 13, "bbox": [277.97, 526.68, 117.01, 55.92], "category_id": 2}, {"id": 14, "bbox": [894.8, 350.22, 192.08, 171.73], "category_id": 1}, {"id": 15, "bbox": [482.23, 593.61, 372.66, 56.79], "category_id": 2}, {"id": 16, "bbox": [443.68, 186.6, 39.23, 45.3], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 75, 265, 88], "ImageBB": [73, 94, 411, 313]}, "reactions": [{"reactants": [14], "conditions": [1, 7], "products": [6]}], "diagram_type": "multiple"}, {"id": 803, "width": 2820, "height": 996, "file_name": "jo501006u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1257.0, 28.0, 675.4, 89.3], "category_id": 2}, {"id": 1, "bbox": [1616.24, 115.22, 431.72, 76.56], "category_id": 2}, {"id": 2, "bbox": [605.0, 165.0, 142.0, 65.0], "category_id": 1}, {"id": 3, "bbox": [920.0, 160.0, 298.0, 73.0], "category_id": 1}, {"id": 4, "bbox": [1256.83, 117.35, 359.41, 70.18], "category_id": 1}, {"id": 5, "bbox": [1435.0, 211.0, 283.0, 65.0], "category_id": 2}, {"id": 6, "bbox": [2122.0, 172.0, 197.0, 74.0], "category_id": 1}, {"id": 7, "bbox": [365.0, 298.0, 2087.0, 698.0], "category_id": 4}, {"id": 8, "bbox": [930.0, 235.0, 274.0, 70.0], "category_id": 2}], "reactions": [{"reactants": [2, 3], "conditions": [0, 4, 1, 5], "products": [6]}], "corefs": [], "caption": "Figure 1. Time-course of reaction of RBr and n-BuMgCl (a) with 500 mol ppm of CuCl2 (R = PhCH(Me)CH2: 1m) and (b) 25 mol ppm of CuCl2 (R = n-Non). With alkyne R-n-Bu: \u25cf (solid line), R-H: \u25cb (dashed line), without alkyne R-n-Bu: \u25a0 (solid line), R-H: \u25a1 (dashed line). ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1032, 784, 1060], "ImageBB": [82, 763, 787, 1012]}, "diagram_type": "single"}, {"id": 20, "width": 1156, "height": 448, "file_name": "ja953272o-Figure-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.16, 124.19, 302.44, 241.17], "category_id": 1}, {"id": 1, "bbox": [297.74, 155.93, 304.66, 52.2], "category_id": 2}, {"id": 2, "bbox": [696.56, 392.66, 170.88, 46.2], "category_id": 2}, {"id": 3, "bbox": [98.51, 395.27, 131.64, 46.21], "category_id": 2}, {"id": 4, "bbox": [615.9, 122.71, 348.21, 243.39], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1], "products": [4]}, {"reactants": [4], "conditions": [], "products": [0]}], "corefs": [[0, 3], [4, 2]], "caption": "Figure 9. An equilibrium between agostic and anagostic conformers.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 143, 764, 156], "ImageBB": [476, 27, 765, 139]}, "diagram_type": "single"}, {"id": 785, "width": 1356, "height": 736, "file_name": "jo502578x-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [352.0, 30.0, 293.0, 259.0], "category_id": 1}, {"id": 1, "bbox": [26.0, 36.0, 285.0, 113.2], "category_id": 1}, {"id": 2, "bbox": [1167.0, 252.0, 38.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [816.0, 309.0, 39.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [477.0, 309.0, 42.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [150.0, 310.0, 46.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [121.65, 220.75, 102.27, 48.06], "category_id": 2}, {"id": 7, "bbox": [1043.0, 51.0, 286.0, 164.0], "category_id": 1}, {"id": 8, "bbox": [692.0, 38.0, 289.0, 238.0], "category_id": 1}], "reactions": [{"reactants": [1, 6], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [7]}], "corefs": [[7, 4]], "caption": "Figure 3. Detailed mechanism and energy pro\ufb01le of the reaction of SIMes (2) with chloroform in chloroform (blue) and energies of the stationary points A, B, and 4 in n-hexane (green). The energy pro\ufb01le was obtained by DFT calculations at the B3LYP/6-311++G** level of theory (free energies at 25 \u00b0C including ZPE corrections in kcal/mol with the IEFPCM solvation model); see the Supporting Information for details. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 339, 784, 436], "ImageBB": [448, 146, 787, 330]}, "diagram_type": "single"}, {"id": 599, "width": 2820, "height": 2492, "file_name": "acs.oprd.6b00117-Figure-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1359.0, 159.0, 264.0, 103.0], "category_id": 2}, {"id": 1, "bbox": [1816.0, 11.0, 578.0, 242.0], "category_id": 1}, {"id": 2, "bbox": [1335.0, 506.0, 240.0, 101.0], "category_id": 2}, {"id": 3, "bbox": [1240.0, 365.0, 438.0, 104.0], "category_id": 2}, {"id": 4, "bbox": [504.0, 407.0, 297.0, 161.2], "category_id": 1}, {"id": 5, "bbox": [1260.0, 5.0, 464.0, 101.0], "category_id": 2}, {"id": 6, "bbox": [1787.0, 365.0, 525.0, 234.4], "category_id": 1}, {"id": 7, "bbox": [836.0, 31.0, 328.0, 218.6], "category_id": 1}, {"id": 8, "bbox": [455.5, 651.0, 1894.5, 1044.2], "category_id": 4}, {"id": 9, "bbox": [2023.0, 592.0, 151.0, 48.0], "category_id": 3}, {"id": 10, "bbox": [983.0, 594.0, 60.0, 46.0], "category_id": 3}, {"id": 11, "bbox": [895.0, 398.0, 302.0, 189.0], "category_id": 1}, {"id": 12, "bbox": [632.0, 596.0, 59.0, 48.0], "category_id": 3}, {"id": 13, "bbox": [406.0, 44.0, 334.0, 172.0], "category_id": 1}, {"id": 14, "bbox": [2078.0, 258.0, 169.0, 48.0], "category_id": 3}, {"id": 15, "bbox": [950.0, 260.0, 53.0, 37.0], "category_id": 3}, {"id": 16, "bbox": [424.0, 1780.0, 1977.0, 683.0], "category_id": 4}, {"id": 17, "bbox": [557.0, 255.0, 59.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [13, 7], "conditions": [5, 0], "products": [1]}, {"reactants": [4, 11], "conditions": [3, 2], "products": [6]}], "corefs": [[13, 17], [7, 15], [1, 14], [4, 12], [11, 10], [6, 9]], "caption": "Figure 8. Wavenumbers monitoring and potential intermediate identi\ufb01cation.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 988, 451, 1002], "ImageBB": [82, 355, 787, 978]}, "diagram_type": "multiple"}, {"id": 399, "width": 1352, "height": 1232, "file_name": "op500072b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [931.0, 1135.0, 38.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [5.0, 0.0, 1347.0, 330.0], "category_id": 4}, {"id": 2, "bbox": [62.0, 1011.0, 256.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [616.0, 690.0, 52.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [298.0, 822.0, 907.0, 410.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 379.0, 897.0, 423.0], "category_id": 1}, {"id": 6, "bbox": [19.0, 892.1, 331.0, 89.9], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [6, 2], "products": [4]}], "corefs": [[5, 3], [4, 0]], "caption": "Table 3. Selective O-alkylation of triol 14", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 243, 317, 258], "ImageBB": [82, 265, 420, 573]}, "diagram_type": "multiple"}, {"id": 861, "width": 1356, "height": 896, "file_name": "jo2003264-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [84.0, 227.0, 47.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [879.0, 237.0, 51.0, 39.0], "category_id": 3}, {"id": 2, "bbox": [1184.0, 235.0, 53.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [320.0, 5.0, 440.0, 144.0], "category_id": 2}, {"id": 4, "bbox": [333.0, 165.0, 268.0, 80.0], "category_id": 2}, {"id": 5, "bbox": [11.0, 421.0, 1330.0, 475.0], "category_id": 4}, {"id": 6, "bbox": [1050.0, 63.0, 303.0, 154.0], "category_id": 1}, {"id": 7, "bbox": [0.0, 95.0, 200.0, 101.0], "category_id": 1}, {"id": 8, "bbox": [753.0, 63.0, 263.0, 150.0], "category_id": 1}, {"id": 9, "bbox": [253.0, 130.0, 33.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [7, 9], "conditions": [3, 4], "products": [8, 6]}], "corefs": [[7, 0], [8, 1], [6, 2]], "caption": "Table 4. Ir-Catalyzed Oxidative Methyl Esteri\ufb01cation of r,\u03c9- Diols 5a with 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 88, 771, 122], "ImageBB": [436, 133, 775, 357]}, "diagram_type": "single"}, {"id": 212, "width": 1128, "height": 468, "file_name": "op0340661-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [383.7, 408.37, 52.74, 51.89], "category_id": 3}, {"id": 1, "bbox": [614.0, 0.0, 358.0, 237.0], "category_id": 1}, {"id": 2, "bbox": [104.67, 179.53, 42.54, 49.34], "category_id": 3}, {"id": 3, "bbox": [706.95, 181.23, 40.84, 47.64], "category_id": 3}, {"id": 4, "bbox": [4.0, 21.0, 307.0, 209.0], "category_id": 1}, {"id": 5, "bbox": [372.0, 142.0, 227.0, 43.0], "category_id": 2}, {"id": 6, "bbox": [355.0, 50.0, 202.0, 50.0], "category_id": 2}, {"id": 7, "bbox": [302.0, 250.0, 443.3, 214.0], "category_id": 1}, {"id": 8, "bbox": [685.0, 232.6, 441.0, 233.4], "category_id": 1}, {"id": 9, "bbox": [769.05, 407.51, 51.9, 46.79], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [6, 5], "products": [1, 7, 8]}], "corefs": [[4, 2], [1, 3], [7, 0], [8, 9]], "caption": "Table 1. Alkylation of 9 with ethylbromoacetate in the presence of K2CO3 in DMF ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 767, 740, 796], "ImageBB": [467, 638, 749, 755]}, "diagram_type": "multiple"}, {"id": 63, "width": 1344, "height": 1220, "file_name": "ja312277g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1076.65, 32.98, 219.63, 117.92], "category_id": 1}, {"id": 1, "bbox": [155.3, 153.71, 24.24, 33.77], "category_id": 3}, {"id": 2, "bbox": [318.92, 147.36, 162.44, 40.12], "category_id": 2}, {"id": 3, "bbox": [523.84, 115.59, 503.98, 130.67], "category_id": 2}, {"id": 4, "bbox": [581.03, 1.21, 367.36, 87.78], "category_id": 2}, {"id": 5, "bbox": [345.92, 79.05, 102.08, 48.07], "category_id": 1}, {"id": 6, "bbox": [48.87, 42.51, 178.33, 94.14], "category_id": 1}, {"id": 7, "bbox": [7.57, 274.44, 1328.43, 940.83], "category_id": 4}], "reactions": [{"reactants": [6, 5], "conditions": [4, 3], "products": [0]}], "corefs": [[6, 1]], "caption": "Table 2. Evaluation of Alkyl Halides", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 655, 111], "ImageBB": [449, 116, 785, 421]}, "diagram_type": "single"}, {"id": 426, "width": 1348, "height": 592, "file_name": "op300235t-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [438.0, 444.0, 58.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [985.0, 445.0, 51.0, 50.0], "category_id": 3}, {"id": 2, "bbox": [32.0, 246.0, 54.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [34.0, 509.0, 1295.0, 68.0], "category_id": 4}, {"id": 4, "bbox": [799.0, 5.0, 524.6, 440.0], "category_id": 1}, {"id": 5, "bbox": [237.2, 0.0, 504.6, 441.9], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [5, 4]}], "corefs": [[5, 0], [4, 1]], "caption": "Table 2. Investigations into electrophilic halogenationa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 393, 110], "ImageBB": [82, 116, 419, 264]}, "diagram_type": "single"}, {"id": 478, "width": 1352, "height": 1816, "file_name": "ol0703579-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [183.0, 244.0, 88.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [632.0, 172.0, 239.0, 86.0], "category_id": 2}, {"id": 2, "bbox": [1005.0, 238.0, 86.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [474.0, 247.0, 56.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [123.0, 18.0, 280.0, 240.0], "category_id": 1}, {"id": 5, "bbox": [399.0, 104.0, 212.0, 162.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 318.0, 1344.0, 1177.0], "category_id": 4}, {"id": 7, "bbox": [901.0, 11.0, 325.0, 276.0], "category_id": 1}, {"id": 8, "bbox": [0.0, 1521.0, 1347.0, 155.0], "category_id": 2}, {"id": 9, "bbox": [804.0, 1746.0, 548.0, 70.0], "category_id": 2}, {"id": 10, "bbox": [616.0, 117.0, 271.0, 40.0], "category_id": 2}], "reactions": [{"reactants": [4, 5], "conditions": [10, 1], "products": [7]}], "corefs": [[4, 0], [5, 3], [7, 2]], "caption": "Table 2. Variation of the Imine Substrate", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 583, 662, 596], "ImageBB": [439, 599, 777, 1053]}, "diagram_type": "single"}, {"id": 556, "width": 1348, "height": 436, "file_name": "acs.orglett.5b02279-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [991.0, 0.0, 350.0, 300.0], "category_id": 1}, {"id": 1, "bbox": [355.0, 7.0, 242.0, 249.0], "category_id": 1}, {"id": 2, "bbox": [27.0, 355.0, 1310.0, 77.0], "category_id": 4}, {"id": 3, "bbox": [6.0, 18.0, 339.0, 237.0], "category_id": 1}, {"id": 4, "bbox": [827.0, 167.0, 128.0, 35.0], "category_id": 2}, {"id": 5, "bbox": [829.0, 28.0, 164.0, 123.0], "category_id": 2}, {"id": 6, "bbox": [1116.0, 276.0, 34.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [600.0, 53.0, 222.0, 134.0], "category_id": 1}, {"id": 8, "bbox": [585.0, 204.0, 420.0, 140.0], "category_id": 3}, {"id": 9, "bbox": [411.07, 248.0, 58.0, 38.0], "category_id": 3}, {"id": 10, "bbox": [195.95, 197.98, 46.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [1, 7], "conditions": [5, 4], "products": [0]}], "corefs": [[3, 10], [1, 9], [7, 8], [0, 6]], "caption": "Table 1. Screening Conditions of [4 + 3] Cycloadditiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 196, 405, 217], "ImageBB": [82, 223, 419, 332]}, "diagram_type": "single"}, {"id": 951, "width": 1352, "height": 700, "file_name": "acs.orglett.6b00233-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [954.99, 566.23, 384.16, 85.91], "category_id": 2}, {"id": 1, "bbox": [1117.31, 161.01, 171.79, 87.26], "category_id": 2}, {"id": 2, "bbox": [728.42, 38.56, 344.93, 199.57], "category_id": 1}, {"id": 3, "bbox": [453.15, 417.4, 56.81, 40.59], "category_id": 2}, {"id": 4, "bbox": [766.97, 583.82, 36.52, 40.59], "category_id": 3}, {"id": 5, "bbox": [498.46, 64.94, 60.87, 48.71], "category_id": 2}, {"id": 6, "bbox": [389.57, 147.48, 251.6, 84.56], "category_id": 2}, {"id": 7, "bbox": [585.71, 388.31, 327.35, 186.71], "category_id": 1}, {"id": 8, "bbox": [10.82, 24.35, 329.38, 198.89], "category_id": 1}, {"id": 9, "bbox": [194.11, 251.66, 33.82, 38.56], "category_id": 3}, {"id": 10, "bbox": [183.96, 598.02, 35.85, 41.95], "category_id": 3}, {"id": 11, "bbox": [4.06, 390.34, 330.73, 188.74], "category_id": 1}, {"id": 12, "bbox": [931.99, 263.83, 24.35, 39.24], "category_id": 3}], "caption": "Scheme 2. Strategy for Fused Tetrahydroisoquinolines", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 383, 110], "ImageBB": [82, 116, 420, 291]}, "reactions": [{"reactants": [8], "conditions": [5, 6], "products": [2]}, {"reactants": [2], "conditions": [1], "products": [11]}, {"reactants": [11], "conditions": [3], "products": [7]}], "diagram_type": "multiple"}, {"id": 418, "width": 1356, "height": 936, "file_name": "op400050n-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [899.3, 397.3, 240.7, 198.7], "category_id": 1}, {"id": 1, "bbox": [522.0, 401.7, 192.0, 163.3], "category_id": 1}, {"id": 2, "bbox": [505.1, 44.0, 302.9, 191.0], "category_id": 1}, {"id": 3, "bbox": [705.8, 734.0, 273.2, 195.7], "category_id": 1}, {"id": 4, "bbox": [251.9, 731.3, 325.1, 204.7], "category_id": 1}, {"id": 5, "bbox": [215.3, 391.5, 176.7, 205.5], "category_id": 1}, {"id": 6, "bbox": [733.0, 616.0, 113.0, 62.0], "category_id": 2}, {"id": 7, "bbox": [738.0, 423.0, 82.0, 63.0], "category_id": 2}, {"id": 8, "bbox": [642.0, 283.0, 156.0, 58.0], "category_id": 2}, {"id": 9, "bbox": [295.0, 618.0, 200.0, 54.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [8], "products": [2]}, {"reactants": [1], "conditions": [], "products": [5]}, {"reactants": [1], "conditions": [7], "products": [0]}, {"reactants": [1], "conditions": [9], "products": [4]}, {"reactants": [1], "conditions": [6], "products": [3]}], "corefs": [], "caption": "Figure 2. Possible oxirane ring-opening reactions.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 741, 691, 755], "ImageBB": [448, 498, 787, 732]}, "diagram_type": "tree"}, {"id": 845, "width": 1356, "height": 1308, "file_name": "jo201478d-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [66.5, 346.0, 427.5, 258.0], "category_id": 1}, {"id": 1, "bbox": [1035.0, 1205.0, 64.0, 60.0], "category_id": 3}, {"id": 2, "bbox": [4.0, 271.0, 613.0, 82.0], "category_id": 2}, {"id": 3, "bbox": [4.0, 0.0, 325.0, 55.0], "category_id": 2}, {"id": 4, "bbox": [903.0, 898.3, 70.5, 65.7], "category_id": 3}, {"id": 5, "bbox": [1156.0, 898.5, 73.0, 61.5], "category_id": 3}, {"id": 6, "bbox": [308.0, 1205.8, 56.0, 61.2], "category_id": 3}, {"id": 7, "bbox": [667.26, 1207.55, 74.5, 59.7], "category_id": 3}, {"id": 8, "bbox": [645.0, 106.8, 267.5, 65.9], "category_id": 2}, {"id": 9, "bbox": [496.0, 415.8, 269.2, 53.7], "category_id": 2}, {"id": 10, "bbox": [10.0, 971.5, 619.0, 53.5], "category_id": 2}, {"id": 11, "bbox": [170.0, 212.0, 71.0, 59.0], "category_id": 3}, {"id": 12, "bbox": [905.0, 1025.0, 317.0, 193.0], "category_id": 1}, {"id": 13, "bbox": [543.0, 1025.2, 376.0, 196.8], "category_id": 1}, {"id": 14, "bbox": [123.0, 1029.0, 435.0, 153.7], "category_id": 1}, {"id": 15, "bbox": [770.0, 750.0, 237.0, 136.0], "category_id": 1}, {"id": 16, "bbox": [801.0, 331.0, 396.5, 249.2], "category_id": 1}, {"id": 17, "bbox": [423.0, 886.0, 71.0, 78.0], "category_id": 3}, {"id": 18, "bbox": [960.0, 59.5, 382.7, 203.0], "category_id": 1}, {"id": 19, "bbox": [450.5, 90.3, 143.3, 133.8], "category_id": 1}, {"id": 20, "bbox": [9.0, 61.0, 399.7, 202.2], "category_id": 1}, {"id": 21, "bbox": [978.0, 560.3, 69.0, 62.7], "category_id": 3}, {"id": 22, "bbox": [243.0, 561.8, 72.7, 59.2], "category_id": 3}, {"id": 23, "bbox": [477.0, 208.8, 71.2, 59.2], "category_id": 3}, {"id": 24, "bbox": [53.0, 734.0, 200.0, 177.0], "category_id": 1}, {"id": 25, "bbox": [288.0, 707.0, 415.0, 204.0], "category_id": 1}, {"id": 26, "bbox": [1052.0, 719.0, 284.0, 190.0], "category_id": 1}, {"id": 27, "bbox": [1146.0, 210.0, 81.0, 65.0], "category_id": 3}, {"id": 28, "bbox": [141.0, 886.0, 65.0, 78.0], "category_id": 3}], "reactions": [{"reactants": [20, 19], "conditions": [8], "products": [18]}, {"reactants": [0], "conditions": [9], "products": [16]}, {"reactants": [16], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [24, 25]}, {"reactants": [24, 25], "conditions": [], "products": [0]}, {"reactants": [16], "conditions": [], "products": [15, 26]}, {"reactants": [15, 26], "conditions": [], "products": [16]}], "corefs": [[20, 11], [19, 23], [18, 27], [0, 22], [16, 21], [24, 28], [25, 17], [15, 4], [26, 5], [14, 6], [13, 7], [12, 1]], "caption": "Table 4. E\ufb00ects of Additives on the Addition/ISMS Reaction Sequence ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 482, 771, 512], "ImageBB": [436, 133, 775, 460]}, "diagram_type": "tree"}, {"id": 1324, "width": 1356, "height": 828, "file_name": "op300343q-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1033.79, 0.0, 322.21, 377.14], "category_id": 1}, {"id": 1, "bbox": [528.43, 0.0, 286.26, 377.14], "category_id": 1}, {"id": 2, "bbox": [385.3, 665.41, 125.49, 71.23], "category_id": 3}, {"id": 3, "bbox": [531.14, 263.86, 47.48, 54.26], "category_id": 3}, {"id": 4, "bbox": [845.21, 61.73, 142.45, 63.08], "category_id": 2}, {"id": 5, "bbox": [0.0, 6.1, 248.95, 292.35], "category_id": 1}, {"id": 6, "bbox": [982.91, 269.29, 128.89, 56.97], "category_id": 3}, {"id": 7, "bbox": [261.16, 21.03, 211.64, 101.74], "category_id": 2}, {"id": 8, "bbox": [1097.55, 516.87, 44.77, 62.4], "category_id": 3}, {"id": 9, "bbox": [122.1, 369.0, 238.1, 187.21], "category_id": 2}, {"id": 10, "bbox": [433.46, 407.66, 323.57, 376.46], "category_id": 1}], "caption": "Scheme 1. Synthetic route to solifenacin (1)", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 472, 700, 487], "ImageBB": [448, 493, 787, 700]}, "reactions": [{"reactants": [5], "conditions": [7], "products": [1]}, {"reactants": [1], "conditions": [4], "products": [0]}, {"reactants": [0], "conditions": [9], "products": [10]}, {"reactants": [10], "conditions": [], "products": [8]}], "diagram_type": "multiple"}, {"id": 1048, "width": 1332, "height": 1016, "file_name": "jo011082s-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [974.85, 644.86, 273.86, 234.49], "category_id": 1}, {"id": 1, "bbox": [762.7, 219.84, 50.23, 49.86], "category_id": 3}, {"id": 2, "bbox": [21.99, 212.9, 310.51, 170.3], "category_id": 3}, {"id": 3, "bbox": [0.0, 17.99, 358.49, 197.01], "category_id": 1}, {"id": 4, "bbox": [138.6, 405.04, 377.14, 61.28], "category_id": 2}, {"id": 5, "bbox": [1050.14, 890.01, 168.58, 55.96], "category_id": 3}, {"id": 6, "bbox": [176.58, 904.0, 43.31, 45.3], "category_id": 3}, {"id": 7, "bbox": [391.14, 113.92, 179.24, 128.57], "category_id": 1}, {"id": 8, "bbox": [1148.76, 205.18, 47.31, 50.63], "category_id": 3}, {"id": 9, "bbox": [44.64, 659.52, 300.52, 234.49], "category_id": 1}, {"id": 10, "bbox": [315.84, 604.89, 46.65, 54.63], "category_id": 3}, {"id": 11, "bbox": [522.41, 640.86, 281.85, 235.16], "category_id": 1}, {"id": 12, "bbox": [637.01, 0.0, 284.53, 217.84], "category_id": 1}, {"id": 13, "bbox": [612.36, 892.68, 101.28, 55.29], "category_id": 3}, {"id": 14, "bbox": [194.57, 476.32, 279.19, 134.56], "category_id": 1}, {"id": 15, "bbox": [1078.79, 28.65, 253.21, 181.86], "category_id": 1}, {"id": 16, "bbox": [138.6, 487.64, 53.3, 62.62], "category_id": 2}, {"id": 17, "bbox": [553.72, 953.3, 682.33, 60.62], "category_id": 2}, {"id": 18, "bbox": [362.49, 122.58, 53.97, 55.96], "category_id": 2}, {"id": 19, "bbox": [365.82, 0.0, 271.19, 98.59], "category_id": 2}, {"id": 20, "bbox": [937.53, 46.63, 126.6, 59.29], "category_id": 2}, {"id": 21, "bbox": [408.46, 710.81, 119.94, 63.29], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [76, 83, 409, 337]}, "reactions": [{"reactants": [3], "conditions": [19, 18, 7], "products": [12]}, {"reactants": [12], "conditions": [20], "products": [15]}, {"reactants": [3], "conditions": [4, 16, 14], "products": [9]}, {"reactants": [9], "conditions": [21], "products": [11, 0]}], "diagram_type": "tree"}, {"id": 724, "width": 1308, "height": 2828, "file_name": "ol0171867-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [540.34, 0.0, 386.67, 113.86], "category_id": 2}, {"id": 1, "bbox": [278.77, 30.46, 132.68, 166.8], "category_id": 1}, {"id": 2, "bbox": [39.94, 91.12, 106.15, 49.28], "category_id": 1}, {"id": 3, "bbox": [2.03, 265.5, 1300.27, 2558.85], "category_id": 4}, {"id": 4, "bbox": [532.75, 129.03, 276.74, 109.93], "category_id": 2}, {"id": 5, "bbox": [1082.43, 38.04, 166.8, 163.01], "category_id": 1}], "reactions": [{"reactants": [2, 1], "conditions": [0, 4], "products": [5]}], "corefs": [], "caption": "Table 3. Amination of Aryl Iodides with Different Amines", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 386, 89], "ImageBB": [80, 93, 407, 800]}, "diagram_type": "single"}, {"id": 156, "width": 2816, "height": 832, "file_name": "op700160a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1499.37, 63.54, 78.57, 63.72], "category_id": 2}, {"id": 1, "bbox": [1798.0, 274.0, 61.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [1153.0, 268.0, 172.0, 66.0], "category_id": 3}, {"id": 3, "bbox": [1729.0, 3.0, 211.0, 256.0], "category_id": 1}, {"id": 4, "bbox": [911.0, 274.0, 133.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [6.0, 340.0, 2810.0, 492.0], "category_id": 4}, {"id": 6, "bbox": [878.0, 0.0, 202.0, 265.0], "category_id": 1}, {"id": 7, "bbox": [1140.0, 0.0, 194.0, 259.0], "category_id": 1}], "reactions": [{"reactants": [6, 7], "conditions": [0], "products": [3]}], "corefs": [[6, 4], [7, 2], [3, 1]], "caption": "Table 1. Screening of oxidation conditions for conversion of bisfuran alcohol, 1, to ketone, 9", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 564, 60], "ImageBB": [58, 74, 762, 282]}, "diagram_type": "single"}, {"id": 711, "width": 1344, "height": 1300, "file_name": "ol034469l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [990.0, 209.0, 93.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [206.3, 71.0, 327.7, 136.1], "category_id": 1}, {"id": 2, "bbox": [930.9, 25.3, 204.6, 176.9], "category_id": 1}, {"id": 3, "bbox": [333.0, 202.0, 73.0, 52.0], "category_id": 3}, {"id": 4, "bbox": [2.0, 280.0, 1342.0, 1020.0], "category_id": 4}, {"id": 5, "bbox": [563.0, 159.0, 342.5, 47.0], "category_id": 2}, {"id": 6, "bbox": [610.0, 4.0, 243.0, 133.4], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [6, 5], "products": [2]}], "corefs": [[1, 3], [2, 0]], "caption": "Table 2. Intramolecular Reductive Dimerization Scope", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 364, 89], "ImageBB": [74, 93, 410, 418]}, "diagram_type": "single"}, {"id": 1144, "width": 1352, "height": 1804, "file_name": "ol025887d-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [751.75, 204.86, 172.37, 55.05], "category_id": 2}, {"id": 1, "bbox": [462.96, 580.28, 203.96, 46.92], "category_id": 2}, {"id": 2, "bbox": [309.54, 849.21, 254.5, 174.17], "category_id": 2}, {"id": 3, "bbox": [751.75, 0.0, 247.27, 175.08], "category_id": 2}, {"id": 4, "bbox": [304.13, 147.1, 121.83, 59.56], "category_id": 2}, {"id": 5, "bbox": [82.12, 147.1, 167.88, 61.37], "category_id": 2}, {"id": 6, "bbox": [52.34, 333.0, 497.26, 434.08], "category_id": 1}, {"id": 7, "bbox": [462.96, 425.96, 224.72, 128.15], "category_id": 2}, {"id": 8, "bbox": [95.66, 853.72, 189.52, 96.56], "category_id": 2}, {"id": 9, "bbox": [309.54, 1054.06, 178.69, 55.05], "category_id": 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"op800033c-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [311.02, 336.04, 122.16, 60.73], "category_id": 2}, {"id": 1, "bbox": [1115.3, 228.42, 56.13, 43.58], "category_id": 3}, {"id": 2, "bbox": [704.57, 549.94, 60.09, 42.25], "category_id": 3}, {"id": 3, "bbox": [704.57, 228.42, 60.09, 41.6], "category_id": 3}, {"id": 4, "bbox": [640.52, 344.62, 215.93, 175.61], "category_id": 1}, {"id": 5, "bbox": [0.0, 14.52, 224.51, 176.93], "category_id": 1}, {"id": 6, "bbox": [994.46, 26.41, 293.18, 180.23], "category_id": 1}, {"id": 7, "bbox": [640.52, 21.79, 231.08, 181.55], "category_id": 1}, {"id": 8, "bbox": [283.94, 49.51, 277.34, 50.18], "category_id": 2}, {"id": 9, "bbox": [75.28, 229.75, 35.66, 40.27], "category_id": 3}, {"id": 10, "bbox": [328.18, 129.4, 188.86, 97.04], "category_id": 2}], "caption": "Scheme 4", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 319, 119, 333], "ImageBB": [62, 338, 392, 487]}, "reactions": [{"reactants": [5], "conditions": [8, 10], "products": [7]}, {"reactants": [5], "conditions": [0], "products": [4]}], "diagram_type": "tree"}, {"id": 82, "width": 1272, "height": 964, "file_name": "ja075824w-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [645.33, 156.18, 197.81, 45.93], "category_id": 2}, {"id": 1, "bbox": [615.21, 4.3, 254.29, 107.43], "category_id": 2}, {"id": 2, "bbox": [7.69, 19.36, 286.93, 221.66], "category_id": 1}, {"id": 3, "bbox": [925.24, 21.87, 339.65, 221.66], "category_id": 1}, {"id": 4, "bbox": [362.91, 107.22, 220.39, 52.21], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [1, 0], "products": [3]}], "corefs": [], "caption": "Figure 2. Solvent effect in the DMAP-catalyzed isobutyrylation of l-menthol. The reaction of l-menthol (5 mmol) was conducted with (i-PrCO)2O (5 mmol) in the presence of 1 (0.1 mol %) in solvent (5 mL): green circles, no solvent; red squares, heptane; blue triangles, THF; orange squares, CH3CN; black circles, CH2Cl2. 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Substrate Scopea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 487, 229, 508], "ImageBB": [82, 514, 419, 1005]}, "diagram_type": "single"}, {"id": 1255, "width": 1352, "height": 1684, "file_name": "op049954q-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [305.86, 155.01, 181.15, 42.12], "category_id": 2}, {"id": 1, "bbox": [342.09, 58.97, 123.01, 58.13], "category_id": 2}, {"id": 2, "bbox": [821.51, 62.34, 111.22, 47.17], "category_id": 2}, {"id": 3, "bbox": [934.42, 946.04, 343.77, 737.96], "category_id": 1}, {"id": 4, "bbox": [754.11, 1118.74, 167.67, 109.51], "category_id": 2}, {"id": 5, "bbox": [581.38, 635.19, 141.55, 280.52], "category_id": 1}, {"id": 6, "bbox": [750.76, 1592.96, 56.6, 52.56], "category_id": 3}, {"id": 7, "bbox": [0.0, 0.0, 306.7, 288.95], "category_id": 1}, {"id": 8, "bbox": [1157.7, 1533.21, 49.71, 51.38], "category_id": 3}, {"id": 9, "bbox": [488.7, 0.0, 301.64, 281.37], "category_id": 1}, {"id": 10, "bbox": 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KR of trans-Cyclohexane-1,2-diol 1 with Boc2O using Various Reaction Conditions", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 300, 600, 320], "ImageBB": [82, 131, 787, 297]}, "diagram_type": "single"}, {"id": 1275, "width": 1908, "height": 1052, "file_name": "op100103v-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [858.08, 298.74, 54.4, 40.08], "category_id": 3}, {"id": 1, "bbox": [911.53, 801.72, 51.54, 42.95], "category_id": 3}, {"id": 2, "bbox": [1195.96, 619.43, 222.39, 101.17], "category_id": 2}, {"id": 3, "bbox": [372.25, 166.07, 282.52, 83.99], "category_id": 2}, {"id": 4, "bbox": [505.87, 628.97, 138.4, 36.27], "category_id": 2}, {"id": 5, "bbox": [1646.47, 1008.84, 38.18, 41.99], "category_id": 3}, {"id": 6, "bbox": [708.22, 0.0, 353.16, 327.37], "category_id": 1}, {"id": 7, "bbox": [374.16, 86.85, 172.76, 44.86], "category_id": 2}, {"id": 8, "bbox": [1129.15, 162.25, 323.56, 126.94], "category_id": 2}, {"id": 9, "bbox": [1127.24, 77.31, 305.43, 47.72], "category_id": 2}, {"id": 10, "bbox": [711.09, 459.08, 465.78, 295.88], "category_id": 1}, {"id": 11, "bbox": [21.0, 2.86, 281.57, 271.06], "category_id": 1}, {"id": 12, "bbox": [506.83, 507.76, 129.81, 83.03], "category_id": 2}, {"id": 13, "bbox": [1454.62, 340.73, 453.38, 650.93], "category_id": 1}, {"id": 14, "bbox": [1332.45, 430.45, 36.27, 41.99], "category_id": 3}, {"id": 15, "bbox": [106.9, 271.06, 48.68, 41.04], "category_id": 3}, {"id": 16, "bbox": [1221.73, 335.96, 177.53, 244.34], "category_id": 1}, {"id": 17, "bbox": [188.99, 801.72, 54.4, 42.95], "category_id": 3}, {"id": 18, "bbox": [21.0, 416.13, 455.28, 382.73], "category_id": 1}], "caption": "Scheme 5. Initial conditions for stage two for the synthesis of imidazo[5,1-c][1,4]benzoxazine-3-carboxylate 9", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 461, 657, 475], "ImageBB": [171, 480, 648, 743]}, "reactions": [{"reactants": [11], "conditions": [7, 3], "products": [6]}, {"reactants": [6], "conditions": [9, 8], "products": [18]}, {"reactants": [18], "conditions": [12, 4], "products": [10]}, {"reactants": [10, 16], "conditions": [2], "products": [13]}], "diagram_type": "multiple"}, {"id": 731, "width": 1348, "height": 704, "file_name": "ol016212y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [923.2, 4.0, 252.8, 240.8], "category_id": 1}, {"id": 1, "bbox": [108.3, 5.0, 252.7, 234.8], "category_id": 1}, {"id": 2, "bbox": [924.0, 275.0, 322.0, 41.0], "category_id": 2}, {"id": 3, "bbox": [437.0, 99.0, 434.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [5.0, 365.0, 1343.0, 339.0], "category_id": 4}, {"id": 5, "bbox": [124.0, 270.0, 549.0, 58.0], "category_id": 2}, {"id": 6, "bbox": [543.0, 165.0, 201.0, 49.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [3, 6], "products": [0]}], "corefs": [], "caption": "Table 3. Comparison of the Fiber-Supported Amino Alcohol P3 with 3 and 5 as Catalysts in the Reduction of PhCOMe with NaBH4/Me3SiCl ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 747, 770, 791], "ImageBB": [439, 792, 776, 968]}, "diagram_type": "single"}, {"id": 79, "width": 2816, "height": 1156, "file_name": "ja1048847-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1568.01, 245.3, 32.09, 37.41], "category_id": 3}, {"id": 1, "bbox": [4.42, 339.8, 2809.48, 816.2], "category_id": 4}, {"id": 2, "bbox": [1457.02, 25.87, 301.43, 178.26], "category_id": 1}, {"id": 3, "bbox": [695.53, 241.77, 203.75, 85.18], "category_id": 3}, {"id": 4, "bbox": [1813.79, 4.63, 322.68, 216.49], "category_id": 1}, {"id": 5, "bbox": [675.5, 2.51, 324.8, 218.61], "category_id": 1}, {"id": 6, "bbox": [1013.17, 159.66, 360.9, 97.56], "category_id": 2}, {"id": 7, "bbox": [1015.29, 21.62, 413.99, 95.44], "category_id": 2}, {"id": 8, "bbox": [1888.33, 231.16, 51.56, 49.78], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [7, 6], "products": [2, 4]}], "corefs": [[5, 3], [2, 0], [4, 8]], "caption": "Table 1. Synthesis of Cyclobutarenes: Study of C(sp3)-H Arylation Parameters", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 56, 455, 69], "ImageBB": [58, 78, 762, 367]}, "diagram_type": "single"}, {"id": 451, "width": 2808, "height": 928, "file_name": "op2001047-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1958.15, 201.35, 77.5, 64.9], "category_id": 3}, {"id": 1, "bbox": [11.0, 274.0, 2797.0, 654.0], "category_id": 4}, {"id": 2, "bbox": [667.35, 199.35, 56.0, 67.0], "category_id": 3}, {"id": 3, "bbox": [437.3, 4.5, 343.7, 221.6], "category_id": 1}, {"id": 4, "bbox": [1156.5, 25.7, 433.7, 220.7], "category_id": 1}, {"id": 5, "bbox": [1627.9, 24.1, 743.5, 218.9], "category_id": 1}, {"id": 6, "bbox": [1434.53, 204.0, 56.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [897.95, 152.75, 192.71, 57.18], "category_id": 2}, {"id": 8, "bbox": [828.07, 36.28, 326.12, 101.65], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [8, 7], "products": [4, 5]}], "corefs": [[3, 2], [4, 6], [5, 0]], "caption": "Table 4. Reaction Optimization for the Microwave-assisted Aldol Reaction of p-Anisaldehyde (4b) with Acetonea", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 697, 109], "ImageBB": [71, 117, 773, 349]}, "diagram_type": "single"}, {"id": 282, "width": 1348, "height": 948, "file_name": "ol800288b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [517.0, 3.0, 250.0, 43.0], "category_id": 2}, {"id": 1, "bbox": [887.0, 10.0, 303.0, 91.0], "category_id": 1}, {"id": 2, "bbox": [161.0, 39.0, 265.0, 64.0], "category_id": 1}, {"id": 3, "bbox": [9.0, 289.0, 1334.0, 659.0], "category_id": 4}, {"id": 4, "bbox": [470.0, 84.0, 325.0, 155.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [0, 4], "products": [1]}], "corefs": [], "caption": "Table 1. Aziridination of 1-Hexene Catalyzed by IPrCuCla", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 475, 752, 489], "ImageBB": [439, 494, 776, 731]}, "diagram_type": "single"}, {"id": 245, "width": 1352, "height": 1056, "file_name": "ol901684h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [114.0, 223.0, 42.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 294.0, 1352.0, 762.0], "category_id": 4}, {"id": 2, "bbox": [611.0, 141.0, 212.0, 107.0], "category_id": 2}, {"id": 3, "bbox": [549.0, 0.0, 348.0, 145.0], "category_id": 2}, {"id": 4, "bbox": [369.0, 224.0, 69.0, 59.0], "category_id": 3}, {"id": 5, "bbox": [1115.0, 224.0, 70.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [914.9, 72.8, 407.2, 138.0], "category_id": 1}, {"id": 7, "bbox": [278.0, 111.2, 266.0, 63.5], "category_id": 1}, {"id": 8, "bbox": [25.8, 79.0, 208.2, 135.5], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [3, 2], "products": [6]}], "corefs": [[8, 0], [7, 4], [6, 5]], "caption": "Table 1. Optimization for Nickel-Catalyzed Direct Alkynylation of Benzoxazole (1) with (Bromoethynyl)benzene (2a)a ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 195, 390, 222], "ImageBB": [58, 231, 396, 495]}, "diagram_type": "single"}, {"id": 642, "width": 1356, "height": 1428, "file_name": "ol5007604-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [818.28, 12.16, 341.92, 540.54], "category_id": 1}, {"id": 1, "bbox": [307.0, 561.0, 46.8, 49.4], "category_id": 3}, {"id": 2, "bbox": [519.0, 188.0, 346.2, 107.0], "category_id": 2}, {"id": 3, "bbox": [619.8, 310.0, 135.2, 49.6], "category_id": 2}, {"id": 4, "bbox": [1003.48, 559.84, 54.0, 54.0], "category_id": 3}, {"id": 5, "bbox": [593.44, 139.83, 200.58, 46.0], "category_id": 1}, {"id": 6, "bbox": [203.0, 5.0, 286.0, 535.0], "category_id": 1}, {"id": 7, "bbox": [14.0, 636.0, 1342.0, 792.0], "category_id": 4}], "reactions": [{"reactants": [6], "conditions": [5, 2, 3], "products": [0]}], "corefs": [[6, 1], [0, 4]], "caption": "Table 1. [2 + 1 + 2 + 1] Cycloaddition on Strained Precursor", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 110], "ImageBB": [448, 116, 787, 473]}, "diagram_type": "single"}, {"id": 497, "width": 1356, "height": 1040, "file_name": "ol053021c-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [14.0, 270.0, 1311.0, 770.0], "category_id": 4}, {"id": 1, "bbox": [795.0, 450.0, 217.0, 204.0], "category_id": 1}, {"id": 2, "bbox": [923.0, 45.0, 291.0, 213.0], "category_id": 1}, {"id": 3, "bbox": [715.0, 648.0, 380.0, 192.0], "category_id": 1}, {"id": 4, "bbox": [234.0, 859.0, 346.0, 122.0], "category_id": 1}, {"id": 5, "bbox": [449.0, 0.0, 359.0, 108.0], "category_id": 2}, {"id": 6, "bbox": [113.18, 45.97, 293.0, 138.0], "category_id": 1}, {"id": 7, "bbox": [463.0, 142.0, 359.0, 103.0], "category_id": 2}, {"id": 8, "bbox": [677.0, 838.0, 455.0, 202.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 7], "products": [2]}], "corefs": [], "caption": "Table 3. Direct Arylation of Imidazo[1,2-a]pyridinesa", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 359, 89], "ImageBB": [73, 98, 412, 358]}, "diagram_type": "single"}, {"id": 534, "width": 1344, "height": 1540, "file_name": "jo000745n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [320.0, 369.0, 715.0, 1171.0], "category_id": 4}, {"id": 1, "bbox": [439.0, 113.0, 164.0, 111.0], "category_id": 2}, {"id": 2, "bbox": [420.4, 28.0, 183.4, 60.0], "category_id": 2}, {"id": 3, "bbox": [268.0, 73.0, 145.0, 60.0], "category_id": 1}, {"id": 4, "bbox": [650.4, 69.7, 391.0, 58.1], "category_id": 1}, {"id": 5, "bbox": [728.0, 261.0, 205.0, 54.0], "category_id": 1}, {"id": 6, "bbox": [694.0, 150.0, 122.0, 105.0], "category_id": 2}, {"id": 7, "bbox": [788.0, 316.6, 97.0, 38.2], "category_id": 3}, {"id": 8, "bbox": [859.0, 142.0, 199.0, 113.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [2, 1], "products": [4]}, {"reactants": [4], "conditions": [6, 8], "products": [5]}], "corefs": [[5, 7]], "caption": "Table 1. Preparation of Isothiocyanates 9-16 from     Primary Amines through Thiocarbamates ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [91, 64, 391, 89], "ImageBB": [74, 90, 410, 475]}, "diagram_type": "tree"}, {"id": 1262, "width": 1048, "height": 312, "file_name": "op0501803-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [644.84, 6.81, 82.84, 51.36], "category_id": 2}, {"id": 1, "bbox": [153.08, 6.81, 100.66, 51.88], "category_id": 2}, {"id": 2, "bbox": [0.0, 5.24, 72.35, 48.74], "category_id": 2}, {"id": 3, "bbox": [644.84, 114.25, 231.73, 194.95], "category_id": 1}, {"id": 4, "bbox": [0.0, 190.76, 85.45, 53.45], "category_id": 2}, {"id": 5, "bbox": [471.31, 4.72, 89.13, 50.83], "category_id": 2}, {"id": 6, "bbox": [968.84, 192.33, 79.16, 48.21], "category_id": 2}, {"id": 7, "bbox": [182.97, 115.29, 225.43, 196.0], "category_id": 1}], "caption": "Scheme 3. Postulated mechanism of the formation of hydrazoic acid in presence of protic components ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 419, 740, 447], "ImageBB": [477, 451, 739, 529]}, "reactions": [{"reactants": [2, 1], "conditions": [], "products": [5, 0]}, {"reactants": [4, 7], "conditions": [], "products": [3, 6]}, {"reactants": [3, 6], "conditions": [], "products": [4, 7]}], "diagram_type": "multiple"}, {"id": 653, "width": 1324, "height": 1352, "file_name": "ol403122a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [754.0, 103.0, 303.0, 61.0], "category_id": 2}, {"id": 1, "bbox": [1108.0, 28.2, 187.1, 121.9], "category_id": 1}, {"id": 2, "bbox": [851.0, 52.7, 118.5, 54.3], "category_id": 2}, {"id": 3, "bbox": [511.0, 23.0, 199.3, 125.6], "category_id": 1}, {"id": 4, "bbox": [277.0, 44.0, 150.0, 52.0], "category_id": 2}, {"id": 5, "bbox": [11.0, 185.0, 1313.0, 1167.0], "category_id": 4}, {"id": 6, "bbox": [229.0, 100.0, 227.0, 57.0], "category_id": 2}, {"id": 7, "bbox": [30.0, 65.0, 180.0, 63.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [4, 6], "products": [3]}, {"reactants": [3], "conditions": [2, 0], "products": [1]}], "corefs": [], "caption": "Table 3. Extending the Substrate Scope for the in Situ Electrophilic Trapping of Metal Sul\ufb01nates with Alternative Alkyl Halidesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 412, 140], "ImageBB": [85, 146, 416, 484]}, "diagram_type": "single"}, {"id": 254, "width": 1348, "height": 1180, "file_name": "ol802141g-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [678.0, 301.0, 111.0, 55.0], "category_id": 2}, {"id": 1, "bbox": [699.0, 236.0, 72.0, 53.0], "category_id": 2}, {"id": 2, "bbox": [1019.0, 236.2, 221.0, 83.6], "category_id": 1}, {"id": 3, "bbox": [489.4, 145.6, 238.6, 248.3], "category_id": 1}, {"id": 4, "bbox": [820.6, 178.2, 179.4, 221.2], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [4, 2]}], "corefs": [], "caption": "Figure 2. UV spectra of 9e (solid line, ca. 1 \u00d7 10-4 M in 20% aqueous methanol) and its 300 nm photolysis (dashed lines, every 5 min). ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 856, 761, 886], "ImageBB": [425, 557, 762, 852]}, "diagram_type": "single"}, {"id": 266, "width": 1348, "height": 1020, "file_name": "ol8013717-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [19.72, 0.69, 321.08, 239.0], "category_id": 1}, {"id": 1, "bbox": [1145.0, 247.4, 65.0, 46.9], "category_id": 3}, {"id": 2, "bbox": [989.3, 0.0, 337.9, 240.9], "category_id": 1}, {"id": 3, "bbox": [714.5, 11.2, 186.9, 99.1], "category_id": 2}, {"id": 4, "bbox": [105.5, 245.3, 207.0, 58.7], "category_id": 3}, {"id": 5, "bbox": [449.5, 89.8, 191.5, 64.7], "category_id": 2}, {"id": 6, "bbox": [686.8, 132.9, 234.9, 147.0], "category_id": 2}, {"id": 7, "bbox": [2.0, 323.0, 1344.0, 694.0], "category_id": 4}, {"id": 8, "bbox": [425.8, 167.3, 223.6, 60.5], "category_id": 3}], "reactions": [{"reactants": [0, 5], "conditions": [3, 6], "products": [2]}], "corefs": [[0, 4], [5, 8], [2, 1]], "caption": "Table 1. Cu-Mediated Cross-Coupling of 1 and 2aa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 693, 88], "ImageBB": [425, 97, 762, 352]}, "diagram_type": "single"}, {"id": 1185, "width": 1344, "height": 580, "file_name": "ol4017244-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [341.55, 61.21, 190.27, 51.79], "category_id": 2}, {"id": 1, "bbox": [26.89, 6.05, 302.55, 186.32], "category_id": 1}, {"id": 2, "bbox": [455.84, 265.02, 166.07, 45.06], "category_id": 2}, {"id": 3, "bbox": [824.96, 61.88, 166.06, 47.09], "category_id": 2}, {"id": 4, "bbox": [855.21, 155.38, 105.56, 51.79], "category_id": 2}, {"id": 5, "bbox": [545.94, 54.48, 270.95, 135.2], "category_id": 1}, {"id": 6, "bbox": [1016.57, 2.69, 270.95, 183.63], "category_id": 1}, {"id": 7, "bbox": [385.25, 164.12, 105.56, 47.09], "category_id": 2}, {"id": 8, "bbox": [658.22, 234.75, 141.19, 91.48], "category_id": 2}, {"id": 9, "bbox": [543.25, 345.73, 303.22, 183.63], "category_id": 1}, {"id": 10, "bbox": [997.07, 212.55, 324.74, 100.22], "category_id": 2}], "caption": "Scheme 1. Palladium-Catalyzed Carbonylative Couplings of Aryl Diazonium Salts ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 390, 116], "ImageBB": [71, 127, 407, 272]}, "reactions": [{"reactants": [5], "conditions": [8], "products": [9]}, {"reactants": [5], "conditions": [3, 4], "products": [6]}], "diagram_type": "tree"}, {"id": 810, "width": 3396, "height": 1416, "file_name": "jo4027148-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2290.5, 434.6, 183.4, 116.0], "category_id": 1}, {"id": 1, "bbox": [1105.0, 381.0, 622.0, 369.6], "category_id": 1}, {"id": 2, "bbox": [1846.2, 388.0, 265.8, 346.0], "category_id": 1}, {"id": 3, "bbox": [751.0, 416.2, 315.0, 117.8], "category_id": 1}, {"id": 4, "bbox": [1019.7, 963.84, 190.1, 113.6], "category_id": 1}, {"id": 5, "bbox": [2611.0, 1293.0, 53.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [2627.0, 388.0, 429.0, 370.0], "category_id": 1}, {"id": 7, "bbox": [412.0, 378.0, 297.0, 384.0], "category_id": 1}, {"id": 8, "bbox": [1421.0, 924.0, 277.0, 338.0], "category_id": 1}, {"id": 9, "bbox": [531.0, 923.0, 280.0, 349.0], "category_id": 1}, {"id": 10, "bbox": [1871.0, 923.0, 409.0, 356.0], "category_id": 1}, {"id": 11, "bbox": [2426.0, 924.0, 422.0, 351.0], "category_id": 1}, {"id": 12, "bbox": [2203.0, 778.0, 338.0, 37.0], "category_id": 2}, {"id": 13, "bbox": [1957.0, 784.0, 50.0, 49.0], "category_id": 3}, {"id": 14, "bbox": [1388.0, 785.0, 56.0, 48.0], "category_id": 3}, {"id": 15, "bbox": [2044.0, 1293.0, 53.0, 37.0], "category_id": 3}, {"id": 16, "bbox": [1529.0, 1293.0, 49.0, 44.0], "category_id": 3}, {"id": 17, "bbox": [934.82, 933.28, 99.88, 61.47], "category_id": 2}, {"id": 18, "bbox": [752.98, 387.77, 94.76, 64.03], "category_id": 2}, {"id": 19, "bbox": [2202.56, 408.26, 99.88, 56.34], "category_id": 2}, {"id": 20, "bbox": [2811.0, 789.0, 49.0, 35.0], "category_id": 3}, {"id": 21, "bbox": [640.0, 1293.0, 61.0, 47.0], "category_id": 3}, {"id": 22, "bbox": [539.0, 789.0, 56.0, 44.0], "category_id": 3}, {"id": 23, "bbox": [2200.0, 598.0, 338.0, 173.0], "category_id": 2}, {"id": 24, "bbox": [754.0, 584.0, 324.0, 179.0], "category_id": 2}, {"id": 25, "bbox": [654.0, 763.0, 527.0, 42.0], "category_id": 2}, {"id": 26, "bbox": [951.0, 1120.0, 332.0, 119.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [18, 3, 24, 25], "products": [1]}, {"reactants": [2], "conditions": [19, 0, 23, 12], "products": [6]}, {"reactants": [9], "conditions": [17, 4, 26], "products": [8, 10, 11]}], "corefs": [[7, 22], [1, 14], [2, 13], [6, 20], [9, 21], [8, 16], [10, 15], [11, 5]], "caption": "Figure 5. (A) Daugulis\u2019 methylene C\u2212H arylation. (B) Statistical arylation of 28 with 1 equiv of iodobenzene.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 386, 620, 400], "ImageBB": [10, 22, 859, 376]}, "diagram_type": "multiple"}, {"id": 762, "width": 1344, "height": 1672, "file_name": "jo962200s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [512.0, 1082.0, 76.0, 64.8], "category_id": 3}, {"id": 1, "bbox": [106.0, 1144.52, 130.6, 46.1], "category_id": 2}, {"id": 2, "bbox": [707.0, 1274.0, 384.9, 398.0], "category_id": 1}, {"id": 3, "bbox": [237.25, 1010.72, 47.07, 56.03], "category_id": 3}, {"id": 4, "bbox": [421.52, 1430.76, 251.0, 58.0], "category_id": 2}, {"id": 5, "bbox": [1192.04, 1387.26, 47.07, 51.55], "category_id": 3}, {"id": 6, "bbox": [512.0, 1348.0, 76.0, 58.8], "category_id": 3}, {"id": 7, "bbox": [143.3, 721.7, 296.1, 266.0], "category_id": 1}, {"id": 8, "bbox": [777.0, 712.0, 415.0, 422.0], "category_id": 1}, {"id": 9, "bbox": [130.0, 1265.0, 345.0, 275.0], "category_id": 1}, {"id": 10, "bbox": [591.0, 816.0, 147.0, 64.0], "category_id": 2}, {"id": 11, "bbox": [54.0, 534.0, 491.0, 74.0], "category_id": 2}, {"id": 12, "bbox": [5.0, 0.0, 1331.0, 525.0], "category_id": 4}, {"id": 13, "bbox": [380.75, 822.66, 198.99, 315.47], "category_id": 1}, {"id": 14, "bbox": [237.0, 1549.0, 86.0, 68.0], "category_id": 3}], "reactions": [{"reactants": [7, 13], "conditions": [10], "products": [8]}, {"reactants": [7], "conditions": [1], "products": [9]}, {"reactants": [9], "conditions": [], "products": [7]}, {"reactants": [9], "conditions": [6, 4], "products": [2]}, {"reactants": [2], "conditions": [], "products": [5]}], "corefs": [[7, 3], [13, 0], [9, 14]], "caption": "Table 1. Reaction of 6-Amino-1,3-dimethyl-5-    thioformyluracil (1) with Enamines 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [108, 49, 373, 74], "ImageBB": [73, 76, 409, 494]}, "diagram_type": "graph"}, {"id": 162, "width": 1416, "height": 1576, "file_name": "op700039r-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 374.0, 1374.9, 1197.9], "category_id": 1}, {"id": 1, "bbox": [1029.46, 0.0, 386.54, 252.0], "category_id": 1}, {"id": 2, "bbox": [6.34, 0.0, 741.56, 286.2], "category_id": 1}, {"id": 3, "bbox": [862.0, 83.0, 40.0, 45.0], "category_id": 2}, {"id": 4, "bbox": [60.0, 283.0, 1356.0, 76.0], "category_id": 2}, {"id": 5, "bbox": [279.0, 224.0, 55.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [1281.0, 219.0, 57.0, 63.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [3], "products": [1]}], "corefs": [[2, 5], [1, 6]], "caption": "Figure 1. Accelerating rate calorimetry (ARC) of 1.0 vol. 30 wt % H2O2 in 2.5 vol. formic acid (14.6 wt % performic acid assuming 100% conversion); 5 \u00b0C , O-corrected onset temper- ature, 179 \u00b0C adiabatic temperature rise (ATR), 252 \u00b0C/min maximum temperature rate, 1972 psi/min maximum pressure rate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 617, 409, 700], "ImageBB": [73, 220, 427, 614]}, "diagram_type": "single"}, {"id": 457, "width": 2808, "height": 824, "file_name": "op200052z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2248.0, 541.0, 71.0, 61.0], "category_id": 3}, {"id": 1, "bbox": [673.0, 441.0, 234.1, 112.6], "category_id": 2}, {"id": 2, "bbox": [1449.0, 166.9, 548.6, 481.0], "category_id": 1}, {"id": 3, "bbox": [941.2, 286.5, 448.9, 225.5], "category_id": 1}, {"id": 4, "bbox": [271.9, 304.9, 394.2, 223.8], "category_id": 1}, {"id": 5, "bbox": [675.4, 238.1, 253.1, 180.4], "category_id": 1}, {"id": 6, "bbox": [2027.0, 0.0, 508.0, 652.0], "category_id": 1}, {"id": 7, "bbox": [23.0, 726.0, 2768.0, 94.0], "category_id": 4}, {"id": 8, "bbox": [1707.0, 550.0, 58.0, 56.0], "category_id": 3}, {"id": 9, "bbox": [1126.0, 550.0, 54.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [394.0, 560.0, 61.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [5, 1], "products": [3, 2, 6]}], "corefs": [[4, 10], [3, 9], [2, 8], [6, 0]], "caption": "Table 1. Carbonate base screen for the di\ufb02uoromethylation of 5a", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 432, 108], "ImageBB": [71, 117, 773, 323]}, "diagram_type": "single"}, {"id": 851, "width": 1356, "height": 1176, "file_name": "jo2008675-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1162.0, 204.0, 106.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 8.0, 226.0, 190.0], "category_id": 1}, {"id": 2, "bbox": [10.0, 415.0, 1346.0, 761.0], "category_id": 4}, {"id": 3, "bbox": [664.0, 77.0, 288.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [667.0, 138.0, 278.0, 39.0], "category_id": 2}, {"id": 5, "bbox": [261.0, 187.0, 446.4, 146.1], "category_id": 3}, {"id": 6, "bbox": [356.3, 29.6, 195.3, 161.0], "category_id": 1}, {"id": 7, "bbox": [1029.6, 23.9, 326.4, 172.1], "category_id": 1}, {"id": 8, "bbox": [68.0, 202.0, 66.8, 48.0], "category_id": 3}], "reactions": [{"reactants": [1, 6], "conditions": [3, 4], "products": [7]}], "corefs": [[1, 8], [6, 5], [7, 0]], "caption": "Table 4. Domino Reaction of 2-Hydroxyaryl-r,\u03b2-unsatu- rated Ketones 2, 2-Hydroxyarylimines 4, 2-Hydroxyarylni- troalkenes 3, and Salicylic Aldehydes 1 to 1,3-Dicarbonyl Compounds (8a and 8b)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 519, 758, 580], "ImageBB": [436, 589, 775, 883]}, "diagram_type": "single"}, {"id": 1066, "width": 1356, "height": 1384, "file_name": "jo300771f-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1015.3, 1197.9, 147.87, 51.5], "category_id": 2}, {"id": 1, "bbox": [741.52, 15.23, 299.1, 277.63], "category_id": 1}, {"id": 2, "bbox": [9.0, 693.73, 301.18, 273.48], "category_id": 1}, {"id": 3, "bbox": [401.57, 0.0, 294.95, 144.7], "category_id": 2}, {"id": 4, "bbox": [437.57, 1163.83, 221.56, 51.93], "category_id": 2}, {"id": 5, "bbox": [486.04, 168.93, 123.24, 96.93], "category_id": 2}, {"id": 6, "bbox": [824.6, 1293.3, 249.26, 53.31], "category_id": 3}, {"id": 7, "bbox": [123.24, 940.21, 72.01, 60.92], "category_id": 3}, {"id": 8, "bbox": [401.57, 1008.75, 301.18, 148.16], "category_id": 2}, {"id": 9, "bbox": [9.0, 16.62, 292.5, 268.48], "category_id": 1}, {"id": 10, "bbox": [744.29, 693.73, 335.41, 270.02], "category_id": 1}, {"id": 11, "bbox": [413.85, 400.4, 280.79, 98.02], "category_id": 2}, {"id": 12, "bbox": [1164.84, 1143.07, 61.47, 48.18], "category_id": 3}, {"id": 13, "bbox": [918.94, 1026.77, 149.53, 53.16], "category_id": 2}, {"id": 14, "bbox": [1021.95, 863.94, 149.53, 49.85], "category_id": 2}, {"id": 15, "bbox": [923.92, 692.81, 154.52, 49.85], "category_id": 2}, {"id": 16, "bbox": [893.15, 297.02, 75.47, 47.08], "category_id": 3}, {"id": 17, "bbox": [434.11, 830.12, 225.02, 51.93], "category_id": 2}, {"id": 18, "bbox": [796.91, 956.82, 274.87, 52.62], "category_id": 3}, {"id": 19, "bbox": [877.4, 631.34, 122.95, 41.54], "category_id": 3}, {"id": 20, "bbox": [741.52, 360.02, 295.28, 274.28], "category_id": 1}, {"id": 21, "bbox": [741.52, 1027.44, 298.18, 273.48], "category_id": 1}, {"id": 22, "bbox": [434.11, 500.57, 231.25, 54.0], "category_id": 2}, {"id": 23, "bbox": [399.49, 679.88, 301.18, 145.4], "category_id": 2}, {"id": 24, "bbox": [1015.3, 533.31, 151.2, 53.17], "category_id": 2}, {"id": 25, "bbox": [918.94, 367.17, 151.19, 49.84], "category_id": 2}, {"id": 26, "bbox": [1164.84, 127.92, 61.47, 49.84], "category_id": 3}, {"id": 27, "bbox": [280.94, 240.9, 154.51, 54.82], "category_id": 2}, {"id": 28, "bbox": [102.47, 294.94, 116.32, 55.39], "category_id": 3}], "caption": "Scheme 4. Isotopic Labeling Experiments", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 313, 683, 328], "ImageBB": [448, 335, 787, 681]}, "reactions": [{"reactants": [9], "conditions": [3, 5], "products": [1, 26]}, {"reactants": [2], "conditions": [11, 22], "products": [20]}, {"reactants": [2], "conditions": [23, 17], "products": [10]}, {"reactants": [2], "conditions": [8, 4], "products": [21, 12]}], "diagram_type": "tree"}, {"id": 517, "width": 2808, "height": 1160, "file_name": "jo0157425-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [493.0, 407.0, 140.0, 62.0], "category_id": 3}, {"id": 1, "bbox": [117.0, 511.0, 2598.0, 649.0], "category_id": 4}, {"id": 2, "bbox": [1319.0, 446.0, 67.0, 65.0], "category_id": 3}, {"id": 3, "bbox": [1744.0, 448.0, 96.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [2193.0, 446.0, 91.0, 73.0], "category_id": 3}, {"id": 5, "bbox": [387.0, 57.0, 376.0, 308.0], "category_id": 1}, {"id": 6, "bbox": [1147.0, 83.0, 379.0, 295.0], "category_id": 1}, {"id": 7, "bbox": [1591.0, 77.0, 387.0, 312.0], "category_id": 1}, {"id": 8, "bbox": [2040.0, 103.0, 392.0, 307.0], "category_id": 1}, {"id": 9, "bbox": [1029.25, 142.8, 44.47, 52.94], "category_id": 3}, {"id": 10, "bbox": [914.9, 2.0, 117.7, 193.0], "category_id": 1}, {"id": 11, "bbox": [813.0, 282.0, 256.4, 153.4], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [10, 11], "products": [6, 7, 8]}], "corefs": [[5, 0], [10, 9], [6, 2], [7, 3], [8, 4]], "caption": "Table 1. Reaction of Enolates of Mandelic Acid Acetal 7 with 2-Cyclopenten-1-one (5)", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [175, 64, 674, 76], "ImageBB": [74, 87, 776, 377]}, "diagram_type": "single"}, {"id": 889, "width": 1356, "height": 616, "file_name": "acs.oprd.5b00148-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [953.2, 40.1, 297.4, 205.5], "category_id": 1}, {"id": 1, "bbox": [425.0, 55.1, 508.0, 94.5], "category_id": 2}, {"id": 2, "bbox": [102.2, 48.2, 301.6, 209.96], "category_id": 1}, {"id": 3, "bbox": [261.0, 333.0, 877.0, 257.0], "category_id": 4}, {"id": 4, "bbox": [438.67, 176.57, 440.75, 109.42], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [1, 4], "products": [0]}], "corefs": [], "caption": "Figure 2. Stereospeci\ufb01c cross-coupling reactions of benzylic ethers and esters. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 785, 784, 813], "ImageBB": [448, 622, 787, 776]}, "diagram_type": "single"}, {"id": 628, "width": 1332, "height": 1824, "file_name": "ol501422k-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [53.1, 716.7, 349.9, 137.3], "category_id": 1}, {"id": 1, "bbox": [438.0, 1010.0, 419.0, 144.0], "category_id": 1}, {"id": 2, "bbox": [414.0, 705.0, 443.0, 153.0], "category_id": 1}, {"id": 3, "bbox": [160.0, 289.0, 917.0, 389.0], "category_id": 4}, {"id": 4, "bbox": [914.0, 194.0, 196.0, 46.0], "category_id": 2}, {"id": 5, "bbox": [1140.0, 191.0, 110.0, 75.0], "category_id": 3}, {"id": 6, "bbox": [150.0, 202.0, 97.0, 76.0], "category_id": 3}, {"id": 7, "bbox": [558.0, 1766.0, 49.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [1026.0, 1774.0, 44.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [982.0, 1603.0, 347.0, 146.0], "category_id": 1}, {"id": 10, "bbox": [494.0, 1607.0, 356.0, 183.0], "category_id": 1}, {"id": 11, "bbox": [105.0, 882.0, 139.5, 44.2], "category_id": 3}, {"id": 12, "bbox": [551.0, 1491.0, 138.2, 41.0], "category_id": 3}, {"id": 13, "bbox": [54.0, 1597.0, 353.0, 141.0], "category_id": 1}, {"id": 14, "bbox": [1042.0, 1487.0, 121.8, 43.2], "category_id": 3}, {"id": 15, "bbox": [106.0, 1170.0, 137.0, 41.8], "category_id": 3}, {"id": 16, "bbox": [551.0, 1175.0, 137.2, 42.0], "category_id": 3}, {"id": 17, "bbox": [1042.0, 1175.0, 128.2, 42.4], "category_id": 3}, {"id": 18, "bbox": [44.0, 7.0, 331.3, 149.0], "category_id": 1}, {"id": 19, "bbox": [102.0, 1489.0, 143.4, 35.4], "category_id": 3}, {"id": 20, "bbox": [894.0, 1318.0, 438.0, 144.0], "category_id": 1}, {"id": 21, "bbox": [434.0, 1321.0, 423.0, 141.0], "category_id": 1}, {"id": 22, "bbox": [555.0, 890.0, 135.0, 41.4], "category_id": 3}, {"id": 23, "bbox": [109.0, 1773.0, 35.0, 46.0], "category_id": 3}, {"id": 24, "bbox": [419.74, 13.11, 135.01, 121.77], "category_id": 1}, {"id": 25, "bbox": [908.0, 4.0, 359.0, 149.0], "category_id": 1}, {"id": 26, "bbox": [569.0, 92.0, 308.0, 50.0], "category_id": 2}, {"id": 27, "bbox": [10.0, 1318.0, 397.0, 142.0], "category_id": 1}, {"id": 28, "bbox": [914.0, 1006.0, 417.0, 146.0], "category_id": 1}, {"id": 29, "bbox": [573.0, 7.0, 291.8, 38.0], "category_id": 2}, {"id": 30, "bbox": [3.0, 1011.0, 401.0, 141.0], "category_id": 1}], "reactions": [{"reactants": [18, 24], "conditions": [29, 26], "products": [25]}], "corefs": [[18, 6], [25, 5], [0, 11], [2, 22], [30, 15], [1, 16], [28, 17], [27, 19], [21, 12], [20, 14], [13, 23], [10, 7], [9, 8]], "caption": "Table 4. Nucleophilc Addition of Alkylazaarenes to tert-Butyl Nitritea ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 424, 417, 458], "ImageBB": [84, 464, 417, 920]}, "diagram_type": "single"}, {"id": 454, "width": 2808, "height": 416, "file_name": "op2001047-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1092.0, 226.0, 115.1, 56.5], "category_id": 2}, {"id": 1, "bbox": [1275.0, 27.0, 361.0, 106.1], "category_id": 2}, {"id": 2, "bbox": [723.0, 55.0, 283.0, 174.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 321.0, 2799.0, 95.0], "category_id": 4}, {"id": 4, "bbox": [1911.0, 221.0, 73.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [874.0, 229.0, 73.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [1364.0, 159.0, 191.0, 56.0], "category_id": 2}, {"id": 7, "bbox": [1659.0, 5.0, 428.0, 210.0], "category_id": 1}, {"id": 8, "bbox": [1064.0, 72.0, 171.0, 126.0], "category_id": 1}], "reactions": [{"reactants": [2, 8], "conditions": [1, 6], "products": [7]}], "corefs": [[2, 5], [8, 0], [7, 4]], "caption": "Table 1. Optimization of the Mizoroki Heck reaction of 4-iodoanisole (3b) and methyl vinyl ketone (MVK) under microwave batch and continuous \ufb02ow conditionsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 770, 123], "ImageBB": [71, 133, 773, 237]}, "diagram_type": "single"}, {"id": 325, "width": 1348, "height": 3692, "file_name": "ol301535j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [588.0, 69.0, 136.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [808.0, 254.0, 87.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [436.0, 258.0, 34.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [9.0, 3226.0, 1339.0, 466.0], "category_id": 2}, {"id": 4, "bbox": [585.0, 133.0, 132.0, 94.0], "category_id": 2}, {"id": 5, "bbox": [371.1, 18.0, 204.7, 210.2], "category_id": 1}, {"id": 6, "bbox": [755.8, 4.3, 227.7, 249.6], "category_id": 1}, {"id": 7, "bbox": [2.0, 348.5, 1346.0, 2850.5], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [0, 4], "products": [6]}], "corefs": [[5, 2], [6, 1]], "caption": "Table 2. Tandem Reactions Initiated by an R2-NH2 Intermo- lecular Aza-Michael Addition Followed by an 8-endo-tet In- tramolecular Ring-Opening of an Epoxide ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 763, 129], "ImageBB": [436, 139, 773, 1062]}, "diagram_type": "single"}, {"id": 610, "width": 1352, "height": 936, "file_name": "acs.oprd.5b00331-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1042.0, 54.0, 310.0, 483.0], "category_id": 1}, {"id": 1, "bbox": [31.0, 141.0, 259.0, 203.0], "category_id": 1}, {"id": 2, "bbox": [552.0, 801.0, 48.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [998.0, 801.0, 47.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [1280.0, 436.0, 49.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [752.0, 435.0, 48.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [149.0, 372.0, 47.0, 43.0], "category_id": 3}, {"id": 7, "bbox": [301.0, 597.0, 366.0, 311.0], "category_id": 1}, {"id": 8, "bbox": [718.0, 573.0, 353.0, 363.0], "category_id": 1}, {"id": 9, "bbox": [510.0, 86.0, 305.0, 426.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [0]}], "corefs": [[1, 6], [9, 5], [0, 4], [7, 2], [8, 3]], "caption": "Figure 1. Target compounds selected as building block in the synthesis of BCPs modulator focused libraries. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 848, 417, 876], "ImageBB": [82, 604, 420, 838]}, "diagram_type": "single"}, {"id": 573, "width": 1348, "height": 1140, "file_name": "acs.orglett.5b00776-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [754.6, 0.0, 535.4, 395.0], "category_id": 1}, {"id": 1, "bbox": [301.0, 324.9, 290.0, 310.1], "category_id": 1}, {"id": 2, "bbox": [44.0, 312.9, 270.0, 311.1], "category_id": 1}, {"id": 3, "bbox": [1120.0, 336.0, 73.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [718.0, 523.0, 587.0, 326.0], "category_id": 1}, {"id": 5, "bbox": [6.0, 963.0, 1340.0, 176.0], "category_id": 4}, {"id": 6, "bbox": [814.0, 408.0, 474.0, 67.0], "category_id": 2}, {"id": 7, "bbox": [579.0, 405.0, 195.0, 68.0], "category_id": 2}, {"id": 8, "bbox": [808.0, 874.0, 482.0, 64.0], "category_id": 2}, {"id": 9, "bbox": [1122.0, 820.0, 71.0, 59.0], "category_id": 3}, {"id": 10, "bbox": [202.0, 635.0, 69.0, 56.0], "category_id": 3}, {"id": 11, "bbox": [438.0, 639.0, 73.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [7], "products": [0, 4]}], "corefs": [[2, 10], [1, 11], [0, 3], [4, 9]], "caption": "Table 1. C versus N Selectivity in Reaction of AH 1a with DD 2aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 152, 410, 186], "ImageBB": [82, 193, 419, 478]}, "diagram_type": "single"}, {"id": 1064, "width": 2820, "height": 1056, "file_name": "jo202324f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [698.3, 773.32, 129.78, 60.68], "category_id": 2}, {"id": 1, "bbox": [640.46, 0.0, 939.53, 50.8], "category_id": 2}, {"id": 2, "bbox": [1419.17, 845.29, 200.32, 57.86], "category_id": 2}, {"id": 3, "bbox": [1365.56, 52.21, 242.64, 255.43], "category_id": 1}, {"id": 4, "bbox": [1400.83, 769.09, 265.21, 64.91], "category_id": 2}, {"id": 5, "bbox": [1668.86, 397.95, 475.41, 272.36], "category_id": 1}, {"id": 6, "bbox": [640.46, 344.33, 674.32, 59.27], "category_id": 2}, {"id": 7, "bbox": [1400.83, 543.3, 207.37, 49.39], "category_id": 2}, {"id": 8, "bbox": [640.46, 848.12, 249.7, 52.21], "category_id": 2}, {"id": 9, "bbox": [905.67, 424.76, 466.95, 221.56], "category_id": 1}, {"id": 10, "bbox": [1904.45, 46.57, 272.27, 245.54], "category_id": 1}, {"id": 11, "bbox": [640.46, 128.42, 217.25, 141.11], "category_id": 1}, {"id": 12, "bbox": [1129.97, 206.03, 193.27, 43.75], "category_id": 2}, {"id": 13, "bbox": [1162.42, 132.65, 128.38, 59.27], "category_id": 2}, {"id": 14, "bbox": [914.14, 681.6, 521.96, 306.22], "category_id": 1}, {"id": 15, "bbox": [868.99, 142.53, 251.11, 135.47], "category_id": 1}, {"id": 16, "bbox": [1668.86, 683.01, 476.82, 330.21], "category_id": 1}, {"id": 17, "bbox": [1623.72, 136.88, 276.5, 55.04], "category_id": 2}, {"id": 18, "bbox": [640.46, 500.97, 217.25, 139.7], "category_id": 1}, {"id": 19, "bbox": [1427.63, 465.69, 176.34, 66.32], "category_id": 2}], "caption": "Scheme 1. Our Previous Works on the Cascade Reactions of Stable Sulfur Ylides with Nitroolefins", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 638, 110], "ImageBB": [82, 116, 787, 380]}, "reactions": [{"reactants": [11, 15], "conditions": [13, 12], "products": [3]}, {"reactants": [3], "conditions": [17], "products": [10]}, {"reactants": [18, 9], "conditions": [19, 7], "products": [5]}, {"reactants": [5], "conditions": [0, 8], "products": [14]}, {"reactants": [14], "conditions": [4, 2], "products": [16]}], "diagram_type": "multiple"}, {"id": 1031, "width": 1176, "height": 944, "file_name": "jo0014156-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1048.93, 895.41, 40.59, 45.88], "category_id": 3}, {"id": 1, "bbox": [1005.98, 334.16, 58.24, 50.59], "category_id": 3}, {"id": 2, "bbox": [0.0, 1173.68, 1176.0, -229.68], "category_id": 2}, {"id": 3, "bbox": [0.0, 0.0, 377.68, 357.69], "category_id": 1}, {"id": 4, "bbox": [0.0, 737.74, 234.73, 181.79], "category_id": 1}, {"id": 5, "bbox": [278.85, 317.1, 43.54, 53.53], "category_id": 3}, {"id": 6, "bbox": [758.9, 617.72, 413.57, 289.45], "category_id": 1}, {"id": 7, "bbox": [720.66, 0.0, 415.34, 353.57], "category_id": 1}, {"id": 8, "bbox": [157.66, 525.95, 400.04, 212.97], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [96, 83, 390, 319]}, "reactions": [{"reactants": [3], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [8, 4]}], "diagram_type": "tree"}, {"id": 783, "width": 1348, "height": 1684, "file_name": "jo502752u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 202.0, 1346.0, 1482.0], "category_id": 4}, {"id": 1, "bbox": [525.0, 78.0, 267.0, 65.0], "category_id": 2}, {"id": 2, "bbox": [605.0, 6.0, 104.0, 53.0], "category_id": 2}, {"id": 3, "bbox": [228.0, 137.0, 39.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [891.0, 1.0, 293.0, 141.0], "category_id": 1}, {"id": 5, "bbox": [168.0, 3.0, 277.0, 135.0], "category_id": 1}, {"id": 6, "bbox": [944.0, 133.0, 42.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [2, 1], "products": [4]}], "corefs": [[5, 3], [4, 6]], "caption": "Table 1. Hydration of Benzonitrilea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 285, 110], "ImageBB": [82, 116, 419, 537]}, "diagram_type": "single"}, {"id": 136, "width": 1352, "height": 536, "file_name": "op8002097-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [643.0, 333.0, 238.0, 110.0], "category_id": 2}, {"id": 1, "bbox": [1.0, 481.0, 57.0, 55.0], "category_id": 3}, {"id": 2, "bbox": [1148.0, 79.0, 199.0, 406.0], "category_id": 1}, {"id": 3, "bbox": [682.0, 256.0, 145.0, 47.0], "category_id": 2}, {"id": 4, "bbox": [189.0, 256.0, 236.0, 59.0], "category_id": 2}, {"id": 5, "bbox": [430.0, 102.0, 200.0, 390.0], "category_id": 1}, {"id": 6, "bbox": [909.0, 91.0, 203.0, 390.0], "category_id": 1}, {"id": 7, "bbox": [9.0, 91.2, 201.0, 412.8], "category_id": 1}, {"id": 8, "bbox": [431.0, 494.0, 40.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [3, 0], "products": [6, 2]}], "corefs": [[7, 1], [5, 8]], "caption": "Table 2. Results of enzymatic screening for ester formation (organic media) ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 191, 386, 218], "ImageBB": [58, 45, 396, 179]}, "diagram_type": "single"}, {"id": 468, "width": 1356, "height": 464, "file_name": "op100267p-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1077.11, 307.98, 70.8, 53.8], "category_id": 3}, {"id": 1, "bbox": [138.96, 305.84, 46.6, 56.5], "category_id": 3}, {"id": 2, "bbox": [906.4, 0.0, 431.2, 270.7], "category_id": 1}, {"id": 3, "bbox": [2.0, 41.7, 366.8, 224.9], "category_id": 1}, {"id": 4, "bbox": [395.0, 25.0, 439.8, 115.8], "category_id": 2}, {"id": 5, "bbox": [394.7, 169.62, 503.13, 107.37], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4, 5], "products": [2]}], "corefs": [[3, 1], [2, 0]], "caption": "Figure 1. Three-step telescoped synthesis of electron-de\ufb01cient amide- substituted arylboronic acids. ", "pdf": {"Page": 1, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 453, 771, 481], "ImageBB": [436, 323, 775, 439]}, "diagram_type": "single"}, {"id": 1165, "width": 1352, "height": 1344, "file_name": "ol060868f-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1000.3, 824.53, 79.81, 60.87], "category_id": 3}, {"id": 1, "bbox": [372.3, 1162.72, 277.66, 61.58], "category_id": 3}, {"id": 2, "bbox": [154.83, 1177.75, 127.46, 109.72], "category_id": 2}, {"id": 3, "bbox": [372.65, 1235.84, 271.05, 54.86], "category_id": 3}, {"id": 4, "bbox": [710.16, 900.96, 284.06, 107.55], "category_id": 2}, {"id": 5, "bbox": [698.66, 570.88, 525.51, 242.82], "category_id": 1}, {"id": 6, "bbox": [424.74, 140.01, 117.01, 64.94], "category_id": 2}, {"id": 7, "bbox": [144.06, 79.81, 107.54, 71.7], "category_id": 3}, {"id": 8, "bbox": [131.21, 641.22, 516.05, 495.8], "category_id": 1}, {"id": 9, "bbox": [566.1, 362.55, 463.29, 118.37], "category_id": 2}, {"id": 10, "bbox": [1004.36, 260.41, 85.22, 60.2], "category_id": 3}, {"id": 11, "bbox": [802.81, 1031.5, 129.18, 77.11], "category_id": 2}, {"id": 12, "bbox": [300.97, 0.0, 368.6, 107.55], "category_id": 2}, {"id": 13, "bbox": [1069.97, 382.84, 109.56, 69.67], "category_id": 2}, {"id": 14, "bbox": [765.61, 2.71, 442.33, 247.56], "category_id": 1}], "caption": "Scheme 4. Synthesis of Nucleoside Analogues 17 and 18", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [453, 408, 760, 421], "ImageBB": [439, 426, 777, 762]}, "reactions": [{"reactants": [7], "conditions": [12, 6], "products": [14]}, {"reactants": [14], "conditions": [9, 13], "products": [5]}, {"reactants": [5], "conditions": [4, 11], "products": [8]}], "diagram_type": "tree"}, {"id": 1002, "width": 1284, "height": 404, "file_name": "ja806814c-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [644.89, 47.58, 138.74, 39.86], "category_id": 2}, {"id": 1, "bbox": [189.48, 48.22, 135.53, 39.22], "category_id": 2}, {"id": 2, "bbox": [1018.72, 3.86, 261.43, 153.02], "category_id": 1}, {"id": 3, "bbox": [836.3, 265.54, 143.24, 134.38], "category_id": 1}, {"id": 4, "bbox": [915.31, 161.38, 57.16, 41.8], "category_id": 2}, {"id": 5, "bbox": [0.0, 8.36, 168.93, 149.17], "category_id": 1}, {"id": 6, "bbox": [366.12, 12.22, 247.94, 163.95], "category_id": 1}, {"id": 7, "bbox": [414.94, 313.12, 181.13, 43.08], "category_id": 2}, {"id": 8, "bbox": [836.3, 17.36, 150.95, 107.37], "category_id": 1}], "caption": "Scheme 2. Proposed Mechanism of Methanol Formation", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 569, 340, 581], "ImageBB": [66, 593, 387, 694]}, "reactions": [{"reactants": [5], "conditions": [1], "products": [6]}, {"reactants": [6], "conditions": [0], "products": [8, 2]}, {"reactants": [8], "conditions": [4], "products": [3]}, {"reactants": [3], "conditions": [], "products": [7]}], "diagram_type": "tree"}, {"id": 1137, "width": 1204, "height": 388, "file_name": "ol0069002-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 116.73, 42.16, 49.34], "category_id": 3}, {"id": 1, "bbox": [656.51, 92.06, 36.74, 37.31], "category_id": 2}, {"id": 2, "bbox": [1015.48, 323.11, 115.64, 51.75], "category_id": 3}, {"id": 3, "bbox": [156.0, 5.42, 408.96, 359.21], "category_id": 1}, {"id": 4, "bbox": [770.34, 2.41, 433.66, 306.86], "category_id": 1}, {"id": 5, "bbox": [83.72, 92.06, 34.93, 38.51], "category_id": 2}, {"id": 6, "bbox": [548.09, 279.19, 239.21, 47.21], "category_id": 3}, {"id": 7, "bbox": [440.88, 294.23, 35.54, 47.54], "category_id": 2}, {"id": 8, "bbox": [548.41, 332.49, 276.94, 45.4], "category_id": 3}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 494, 635, 508], "ImageBB": [457, 513, 758, 610]}, "reactions": [{"reactants": [0], "conditions": [5], "products": [3]}, {"reactants": [3], "conditions": [1], "products": [4]}], "diagram_type": "single"}, {"id": 1375, "width": 1340, "height": 708, "file_name": "op990050s-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [268.8, 437.25, 47.6, 50.29], "category_id": 3}, {"id": 1, "bbox": [177.64, 291.72, 237.3, 146.87], "category_id": 1}, {"id": 2, "bbox": [49.6, 438.59, 41.57, 52.98], "category_id": 3}, {"id": 3, "bbox": [546.99, 413.1, 310.37, 171.68], "category_id": 1}, {"id": 4, "bbox": [1023.6, 398.35, 316.4, 244.11], "category_id": 1}, {"id": 5, "bbox": [1093.99, 341.35, 42.23, 48.95], "category_id": 3}, {"id": 6, "bbox": [1008.18, 4.02, 225.24, 324.58], "category_id": 1}, {"id": 7, "bbox": [1082.59, 659.22, 46.25, 48.29], "category_id": 3}, {"id": 8, "bbox": [0.0, 313.85, 127.36, 118.03], "category_id": 1}, {"id": 9, "bbox": [551.69, 30.85, 207.13, 306.47], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 299, 501, 313], "ImageBB": [441, 319, 776, 496]}, "reactions": [{"reactants": [8, 1], "conditions": [], "products": [3, 9]}, {"reactants": [9], "conditions": [], "products": [6]}, {"reactants": [3], "conditions": [], "products": [4]}], "diagram_type": "tree"}, {"id": 476, "width": 2816, "height": 948, "file_name": "op100072y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2038.63, 248.75, 68.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [664.88, 244.0, 57.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [1337.24, 0.75, 536.36, 216.35], "category_id": 1}, {"id": 3, "bbox": [1556.88, 244.75, 54.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [1908.6, 3.0, 457.4, 214.3], "category_id": 1}, {"id": 5, "bbox": [454.1, 6.0, 525.9, 216.0], "category_id": 1}, {"id": 6, "bbox": [1009.0, 144.0, 287.0, 105.0], "category_id": 2}, {"id": 7, "bbox": [994.0, 50.0, 307.0, 75.0], "category_id": 2}, {"id": 8, "bbox": [11.0, 313.0, 2734.0, 635.0], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [7, 6], "products": [2, 4]}], "corefs": [[5, 1], [2, 3], [4, 0]], "caption": "Table 1. Hydrogenolysis vs dechlorination selectivity varying solvent or inorganic additives", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 358, 558, 372], "ImageBB": [58, 372, 762, 609]}, "diagram_type": "single"}, {"id": 531, "width": 1344, "height": 1020, "file_name": "jo000745n-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.3, 25.0, 394.6, 206.1], "category_id": 1}, {"id": 1, "bbox": [664.3, 39.8, 192.3, 61.4], "category_id": 2}, {"id": 2, "bbox": [702.0, 136.0, 142.7, 60.0], "category_id": 2}, {"id": 3, "bbox": [139.7, 135.9, 87.3, 62.1], "category_id": 2}, {"id": 4, "bbox": [391.0, 195.0, 56.2, 45.1], "category_id": 3}, {"id": 5, "bbox": [1020.6, 235.0, 123.4, 46.6], "category_id": 3}, {"id": 6, "bbox": [309.0, 36.0, 314.8, 153.0], "category_id": 1}, {"id": 7, "bbox": [17.0, 289.0, 1327.0, 731.0], "category_id": 4}, {"id": 8, "bbox": [30.94, 93.27, 45.89, 53.29], "category_id": 3}, {"id": 9, "bbox": [94.0, 25.0, 175.0, 77.0], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [9, 3], "products": [6]}, {"reactants": [6], "conditions": [1, 2], "products": [0]}], "corefs": [[6, 4], [0, 5]], "caption": "Table 4. Preparation of Protected Thioureas 43-47 from         Diphenylethylenediamine 7 through the         Ethoxycarbonylated Ethylenediamine 42 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 601, 409, 638], "ImageBB": [74, 640, 410, 895]}, "diagram_type": "single"}, {"id": 713, "width": 1352, "height": 396, "file_name": "ol034469l-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1033.0, 159.1, 190.0, 218.0], "category_id": 1}, {"id": 1, "bbox": [329.0, 210.9, 148.2, 48.1], "category_id": 2}, {"id": 2, "bbox": [133.0, 139.0, 185.0, 257.0], "category_id": 1}, {"id": 3, "bbox": [524.4, 200.1, 288.6, 136.4], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [1], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}], "corefs": [], "caption": "Figure 2. Model for diastereoselectivity.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 868, 654, 881], "ImageBB": [439, 757, 777, 856]}, "diagram_type": "single"}, {"id": 180, "width": 1288, "height": 1288, "file_name": "op0602270-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [411.0, 139.6, 465.1, 69.4], "category_id": 2}, {"id": 1, "bbox": [407.0, 17.4, 445.9, 73.6], "category_id": 2}, {"id": 2, "bbox": [75.0, 229.0, 217.8, 56.0], "category_id": 3}, {"id": 3, "bbox": [933.4, 7.0, 354.6, 217.1], "category_id": 1}, {"id": 4, "bbox": [3.0, 4.5, 348.7, 230.5], "category_id": 1}, {"id": 5, "bbox": [1079.0, 225.0, 70.0, 62.0], "category_id": 3}, {"id": 6, "bbox": [1.0, 315.0, 1287.0, 973.0], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [1, 0], "products": [3]}], "corefs": [[4, 2], [3, 5]], "caption": "Figure 4. Dependency of hydrogen consumption versus reac- tion time. Reactions were carried out under isobaric conditions (1.0 bar) at 25 \u00b0C. [Rh(cod)2]BF4 (0.0072 mmol) and 0.015 mmol ligand 6a were stirred for 10 min under hydrogen atmosphere in 10.0 mL of methanol. Afterwards the substrate (0.72 mmol) was added in 1.0 mL of methanol. The conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 378, 409, 489], "ImageBB": [81, 53, 403, 375]}, "diagram_type": "single"}, {"id": 1257, "width": 1356, "height": 1592, "file_name": "op050061n-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [520.23, 1412.01, 50.19, 41.42], "category_id": 3}, {"id": 1, "bbox": [348.94, 1109.38, 326.64, 326.53], "category_id": 1}, {"id": 2, "bbox": [90.82, 684.11, 235.02, 268.38], "category_id": 1}, {"id": 3, "bbox": [0.0, 1513.16, 562.45, 78.84], "category_id": 2}, {"id": 4, "bbox": [0.0, 1105.4, 296.36, 328.12], "category_id": 1}, {"id": 5, "bbox": [86.04, 425.28, 319.47, 160.87], "category_id": 1}, {"id": 6, "bbox": [169.69, 972.4, 41.43, 43.01], "category_id": 3}, {"id": 7, "bbox": [1238.83, 1414.4, 51.78, 39.03], "category_id": 3}, {"id": 8, "bbox": [219.09, 602.87, 38.24, 40.62], "category_id": 3}, {"id": 9, "bbox": [1131.28, 1112.57, 224.72, 285.11], "category_id": 1}, {"id": 10, "bbox": [1155.18, 425.28, 31.07, 36.63], "category_id": 3}, {"id": 11, "bbox": [172.88, 1412.81, 50.99, 40.62], "category_id": 3}, {"id": 12, "bbox": [696.29, 1052.04, 301.94, 384.66], "category_id": 1}, {"id": 13, "bbox": [839.7, 3.19, 489.15, 453.94], "category_id": 1}, {"id": 14, "bbox": [872.36, 1412.81, 48.6, 40.62], "category_id": 3}, {"id": 15, "bbox": [579.18, 595.71, 461.28, 269.18], "category_id": 1}, {"id": 16, "bbox": [751.26, 860.91, 50.2, 41.41], "category_id": 3}], "caption": "Scheme 2. New synthesis route for 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 285, 67], "ImageBB": [73, 71, 412, 469]}, "reactions": [{"reactants": [13], "conditions": [], "products": [15, 9]}, {"reactants": [15], "conditions": [], "products": [5, 2]}, {"reactants": [9], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4]}], "diagram_type": "tree"}, {"id": 1279, "width": 1352, "height": 968, "file_name": "op100197g-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [669.57, 39.92, 275.27, 258.47], "category_id": 1}, {"id": 1, "bbox": [514.02, 901.93, 59.51, 66.07], "category_id": 3}, {"id": 2, "bbox": [802.14, 426.27, 54.1, 61.57], "category_id": 3}, {"id": 3, "bbox": [426.77, 828.18, 207.64, 56.84], "category_id": 2}, {"id": 4, "bbox": [59.52, 299.74, 159.61, 48.04], "category_id": 2}, {"id": 5, "bbox": [980.01, 42.63, 115.66, 87.28], "category_id": 2}, {"id": 6, "bbox": [0.0, 359.28, 406.48, 63.61], "category_id": 2}, {"id": 7, "bbox": [144.06, 420.86, 58.84, 62.92], "category_id": 3}, {"id": 8, "bbox": [1000.3, 527.09, 351.7, 288.24], "category_id": 1}, {"id": 9, "bbox": [1130.84, 901.93, 50.72, 64.96], "category_id": 3}, {"id": 10, "bbox": [363.19, 527.09, 305.03, 286.88], "category_id": 1}, {"id": 11, "bbox": [0.0, 2.71, 305.03, 284.85], "category_id": 1}, {"id": 12, "bbox": [363.19, 45.33, 230.63, 111.65], "category_id": 2}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 119, 60], "ImageBB": [58, 65, 396, 307]}, "reactions": [{"reactants": [11], "conditions": [12], "products": [0]}, {"reactants": [0], "conditions": [5], "products": [10]}, {"reactants": [10], "conditions": [], "products": [8]}], "diagram_type": "multiple"}, {"id": 109, "width": 1344, "height": 632, "file_name": "ja001164i-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [520.4, 31.49, 202.84, 41.56], "category_id": 2}, {"id": 1, "bbox": [3.15, 274.1, 1337.42, 357.9], "category_id": 4}, {"id": 2, "bbox": [1136.1, 203.92, 22.29, 32.43], "category_id": 3}, {"id": 3, "bbox": [175.52, 202.91, 23.28, 33.45], "category_id": 3}, {"id": 4, "bbox": [1026.55, 6.13, 220.09, 173.42], "category_id": 1}, {"id": 5, "bbox": [97.42, 5.11, 300.22, 173.43], "category_id": 1}, {"id": 6, "bbox": [826.73, 33.52, 134.88, 35.47], "category_id": 2}, {"id": 7, "bbox": [480.84, 111.62, 267.76, 74.02], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [0, 7, 6], "products": [4]}], "corefs": [[5, 3], [4, 2]], "caption": "Table 4. Enantioselective Protonation of 5f-i by (R)-1\u201aSnCl4a", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 385, 78], "ImageBB": [74, 86, 410, 244]}, "diagram_type": "single"}, {"id": 1251, "width": 1176, "height": 1368, "file_name": "op049899l-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [258.66, 483.15, 223.76, 293.58], "category_id": 1}, {"id": 1, "bbox": [325.72, 792.47, 60.9, 45.16], "category_id": 3}, {"id": 2, "bbox": [559.06, 411.29, 184.08, 89.65], "category_id": 2}, {"id": 3, "bbox": [509.8, 1148.33, 277.82, 137.55], "category_id": 2}, {"id": 4, "bbox": [492.0, 1025.14, 318.88, 93.08], "category_id": 2}, {"id": 5, "bbox": [363.36, 231.99, 121.12, 86.91], "category_id": 2}, {"id": 6, "bbox": [323.67, 80.75, 195.71, 93.07], "category_id": 2}, {"id": 7, "bbox": [815.67, 1003.25, 360.33, 276.47], "category_id": 1}, {"id": 8, "bbox": [907.37, 303.85, 154.65, 45.85], "category_id": 2}, {"id": 9, "bbox": [957.51, 881.97, 105.11, 44.34], "category_id": 2}, {"id": 10, "bbox": [842.36, 427.71, 273.03, 355.86], "category_id": 1}, {"id": 11, "bbox": [281.24, 1296.14, 54.06, 40.38], "category_id": 3}, {"id": 12, "bbox": [210.08, 984.77, 226.5, 306.58], "category_id": 1}, {"id": 13, "bbox": [4.11, 15.06, 270.29, 271.68], "category_id": 1}, {"id": 14, "bbox": [84.17, 315.48, 30.79, 38.32], "category_id": 3}, {"id": 15, "bbox": [942.95, 789.73, 49.27, 44.48], "category_id": 3}, {"id": 16, "bbox": [963.48, 963.55, 92.38, 50.65], "category_id": 2}, {"id": 17, "bbox": [911.7, 1322.15, 51.1, 41.74], "category_id": 3}, {"id": 18, "bbox": [669.92, 299.74, 30.79, 39.01], "category_id": 3}, {"id": 19, "bbox": [575.49, 6.84, 268.92, 270.32], "category_id": 1}, {"id": 20, "bbox": [884.1, 144.4, 192.29, 125.23], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 375, 501, 389], "ImageBB": [461, 393, 755, 735]}, "reactions": [{"reactants": [13], "conditions": [6, 5], "products": [19]}, {"reactants": [19], "conditions": [2], "products": [0]}, {"reactants": [19, 20], "conditions": [8], "products": [10]}, {"reactants": [10], "conditions": [9, 16], "products": [7]}, {"reactants": [7], "conditions": [4, 3], "products": [12]}], "diagram_type": "tree"}, {"id": 769, "width": 1348, "height": 1156, "file_name": "jo9602433-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [963.0, 700.0, 60.0, 65.0], "category_id": 3}, {"id": 1, "bbox": [224.0, 84.0, 136.0, 121.4], "category_id": 2}, {"id": 2, "bbox": [326.0, 702.0, 36.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [234.0, 0.0, 133.0, 48.0], "category_id": 2}, {"id": 4, "bbox": [0.0, 29.0, 127.0, 89.0], "category_id": 2}, {"id": 5, "bbox": [1090.83, 517.63, 255.68, 105.37], "category_id": 2}, {"id": 6, "bbox": [435.35, 623.0, 192.15, 61.99], "category_id": 2}, {"id": 7, "bbox": [15.41, 299.14, 257.23, 106.92], "category_id": 2}, {"id": 8, "bbox": [6.8, 777.5, 1335.0, 376.5], "category_id": 4}, {"id": 9, "bbox": [630.9, 261.8, 664.4, 415.8], "category_id": 1}, {"id": 10, "bbox": [16.0, 192.2, 550.3, 507.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 1], "products": [10, 9]}], "corefs": [[10, 2], [9, 0]], "caption": "Table 3. Treatment of (E)-4 with BTMBr3 or Br2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [89, 261, 372, 274], "ImageBB": [63, 280, 400, 569]}, "diagram_type": "multiple"}, {"id": 5, "width": 1356, "height": 464, "file_name": "jacs.5b11315-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [293.25, 44.31, 101.58, 122.36], "category_id": 2}, {"id": 1, "bbox": [79.38, 47.68, 156.99, 143.22], "category_id": 1}, {"id": 2, "bbox": [476.82, 43.44, 292.08, 289.39], "category_id": 1}, {"id": 3, "bbox": [966.06, 55.56, 351.82, 262.64], "category_id": 1}, {"id": 4, "bbox": [314.9, 193.24, 62.61, 37.5], "category_id": 2}, {"id": 5, "bbox": [808.46, 55.56, 100.72, 119.68], "category_id": 2}, {"id": 6, "bbox": [817.12, 194.11, 84.26, 46.07], "category_id": 2}, {"id": 7, "bbox": [354.73, 395.86, 511.15, 43.48], "category_id": 2}, {"id": 8, "bbox": [1205.05, 417.51, 115.43, 38.28], "category_id": 4}, {"id": 9, "bbox": [81.11, 274.64, 171.71, 47.02], "category_id": 2}, {"id": 10, "bbox": [32.62, 106.65, 28.88, 35.69], "category_id": 3}, {"id": 11, "bbox": [732.27, 320.53, 32.3, 37.5], "category_id": 3}, {"id": 12, "bbox": [1276.92, 314.38, 32.3, 40.19], "category_id": 3}, {"id": 13, "bbox": [439.59, 158.61, 53.95, 50.49], "category_id": 2}], "reactions": [{"reactants": [1, 9], "conditions": [0, 4], "products": [2]}, {"reactants": [2], "conditions": [5, 6], "products": [3]}, {"reactants": [1, 9], "conditions": [7], "products": [3]}], "corefs": [[2, 11], [3, 12]], "caption": "Figure 4. Syntheses of 5 and 6.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 714, 600, 728], "ImageBB": [448, 589, 787, 705]}, "diagram_type": "graph"}, {"id": 1335, "width": 1356, "height": 1124, "file_name": "op4003467-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [346.63, 274.71, 68.51, 57.66], "category_id": 3}, {"id": 1, "bbox": [986.98, 274.71, 63.09, 55.62], "category_id": 3}, {"id": 2, "bbox": [798.41, 16.28, 318.81, 284.88], "category_id": 1}, {"id": 3, "bbox": [322.89, 760.37, 181.12, 190.61], "category_id": 2}, {"id": 4, "bbox": [944.93, 699.33, 68.51, 51.55], "category_id": 3}, {"id": 5, "bbox": [219.1, 71.22, 316.11, 170.93], "category_id": 1}, {"id": 6, "bbox": [563.7, 80.04, 147.88, 67.15], "category_id": 2}, {"id": 7, "bbox": [799.08, 390.7, 324.25, 316.09], "category_id": 1}, {"id": 8, "bbox": [564.38, 651.17, 67.83, 54.26], "category_id": 3}, {"id": 9, "bbox": [492.47, 1028.98, 55.63, 52.23], "category_id": 3}, {"id": 10, "bbox": [551.49, 876.36, 137.02, 63.76], "category_id": 2}, {"id": 11, "bbox": [374.44, 392.74, 306.61, 272.67], "category_id": 1}, {"id": 12, "bbox": [558.95, 189.25, 172.3, 93.6], "category_id": 1}, {"id": 13, "bbox": [217.75, 646.42, 202.14, 65.12], "category_id": 2}, {"id": 14, "bbox": [234.71, 462.6, 118.7, 52.91], "category_id": 2}, {"id": 15, "bbox": [234.71, 560.95, 139.73, 61.05], "category_id": 2}], "caption": "Scheme 3. 3,3-Dimethyl-2,3-dihydro-4-hydroxybenzofuran", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 515, 773, 530], "ImageBB": [448, 537, 787, 818]}, "reactions": [{"reactants": [5, 12], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [14, 15, 13], "products": [11, 7]}, {"reactants": [11], "conditions": [3, 10], "products": [9]}], "diagram_type": "tree"}, {"id": 672, "width": 1356, "height": 2528, "file_name": "ol401812h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [518.0, 98.0, 331.0, 147.5], "category_id": 2}, {"id": 1, "bbox": [998.0, 200.0, 33.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [925.0, 4.0, 181.0, 137.0], "category_id": 1}, {"id": 3, "bbox": [3.0, 294.0, 1351.0, 2061.0], "category_id": 4}, {"id": 4, "bbox": [514.0, 1.0, 323.0, 80.0], "category_id": 2}, {"id": 5, "bbox": [246.6, 1.0, 178.4, 103.5], "category_id": 1}, {"id": 6, "bbox": [286.0, 202.0, 131.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [257.0, 200.0, 31.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 0], "products": [2]}], "corefs": [[5, 7], [2, 1]], "caption": "Table 2. Substrate Scope of Epoxidation", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 653, 100], "ImageBB": [436, 112, 775, 744]}, "diagram_type": "single"}, {"id": 1011, "width": 960, "height": 972, "file_name": "ja980022+-Scheme-c12.png", "license": 0, "bboxes": [{"id": 0, "bbox": [756.82, 739.09, 69.02, 50.57], "category_id": 3}, {"id": 1, "bbox": [291.16, 237.77, 49.09, 54.46], "category_id": 3}, {"id": 2, "bbox": [113.74, 425.46, 347.54, 297.1], "category_id": 1}, {"id": 3, "bbox": [787.44, 241.66, 51.04, 52.03], "category_id": 3}, {"id": 4, "bbox": [0.0, 194.98, 44.23, 49.6], "category_id": 3}, {"id": 5, "bbox": [150.68, 0.0, 331.99, 293.69], "category_id": 1}, {"id": 6, "bbox": [582.32, 441.51, 376.22, 307.3], "category_id": 1}, {"id": 7, "bbox": [361.15, 726.45, 63.68, 48.62], "category_id": 3}, {"id": 8, "bbox": [34.03, 796.47, 493.85, 175.53], "category_id": 1}, {"id": 9, "bbox": [0.0, 92.39, 44.23, 52.51], "category_id": 3}, {"id": 10, "bbox": [583.78, 0.0, 374.76, 296.12], "category_id": 1}], "caption": "Scheme 12", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 277, 503, 291], "ImageBB": [488, 296, 728, 539]}, "reactions": [{"reactants": [9, 4], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [10]}, {"reactants": [5], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [6]}, {"reactants": [10], "conditions": [], "products": [6]}], "diagram_type": "graph"}, {"id": 250, "width": 1228, "height": 1876, "file_name": "ol802669r-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [847.0, 213.5, 334.1, 182.8], "category_id": 1}, {"id": 1, "bbox": [998.0, 144.0, 44.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [980.0, 392.0, 47.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [140.0, 310.0, 34.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 482.1, 1228.0, 1393.9], "category_id": 4}, {"id": 5, "bbox": [848.47, 0.0, 374.7, 149.0], "category_id": 1}, {"id": 6, "bbox": [391.0, 85.0, 385.0, 111.0], "category_id": 2}, {"id": 7, "bbox": [393.0, 203.0, 325.0, 98.9], "category_id": 2}, {"id": 8, "bbox": [2.8, 104.8, 345.2, 206.2], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6, 7], "products": [5, 0]}], "corefs": [[8, 3], [5, 1], [0, 2]], "caption": "Table 2. Synthesis of Substituted 3,4-Dihydro-2(1H)- quinolinonesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 700, 102], "ImageBB": [440, 111, 747, 580]}, "diagram_type": "single"}, {"id": 1188, "width": 1704, "height": 652, "file_name": "ol5000692-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [302.61, 79.28, 167.08, 43.48], "category_id": 1}, {"id": 1, "bbox": [289.82, 156.86, 169.64, 58.82], "category_id": 2}, {"id": 2, "bbox": [1023.76, 7.67, 243.8, 292.41], "category_id": 1}, {"id": 3, "bbox": [588.17, 34.1, 274.49, 235.29], "category_id": 1}, {"id": 4, "bbox": [1278.64, 105.71, 80.13, 41.77], "category_id": 2}, {"id": 5, "bbox": [1379.23, 23.02, 245.49, 261.72], "category_id": 1}, {"id": 6, "bbox": [883.97, 92.92, 111.66, 52.01], "category_id": 2}], "caption": "Scheme 1. Formation of Iridium Amino-carbenes", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 943, 360, 958], "ImageBB": [10, 964, 436, 1127]}, "reactions": [{"reactants": [0, 1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [4], "products": [5]}], "diagram_type": "single"}, {"id": 507, "width": 1348, "height": 992, "file_name": "ol051901l-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1119.0, 265.0, 41.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [149.0, 263.0, 68.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [699.0, 43.0, 200.0, 88.0], "category_id": 2}, {"id": 3, "bbox": [32.0, 22.0, 340.0, 250.0], "category_id": 1}, {"id": 4, "bbox": [475.88, 170.16, 203.45, 59.84], "category_id": 3}, {"id": 5, "bbox": [17.0, 359.0, 1327.0, 633.0], "category_id": 4}, {"id": 6, "bbox": [748.0, 148.4, 97.6, 48.6], "category_id": 2}, {"id": 7, "bbox": [499.3, 104.0, 160.1, 58.9], "category_id": 2}, {"id": 8, "bbox": [975.9, 3.0, 333.1, 294.0], "category_id": 1}], "reactions": [{"reactants": [3, 7], "conditions": [2, 6], "products": [8]}], "corefs": [[3, 1], [7, 4], [8, 0]], "caption": "Table 3. 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The Discovery Chemistry synthesis of 3", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 370, 110], "ImageBB": [82, 116, 420, 443]}, "reactions": [{"reactants": [20], "conditions": [3, 12], "products": [16]}, {"reactants": [16, 1], "conditions": [4], "products": [15]}, {"reactants": [15], "conditions": [5, 6, 11], "products": [18]}, {"reactants": [18], "conditions": [14, 9], "products": [7]}, {"reactants": [7], "conditions": [2, 19], "products": [22]}], "diagram_type": "multiple"}, {"id": 1346, "width": 1284, "height": 732, "file_name": "op7001694-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.2, 63.58, 214.54, 150.94], "category_id": 1}, {"id": 1, "bbox": [226.74, 677.59, 44.32, 52.67], "category_id": 3}, {"id": 2, "bbox": [854.29, 360.31, 405.94, 299.3], "category_id": 1}, {"id": 3, "bbox": [926.23, 50.74, 263.35, 127.17], "category_id": 1}, {"id": 4, "bbox": [563.96, 435.46, 74.51, 58.44], "category_id": 2}, {"id": 5, "bbox": [1030.93, 682.09, 41.1, 46.24], "category_id": 3}, {"id": 6, "bbox": [1006.52, 277.46, 41.75, 45.6], "category_id": 3}, {"id": 7, "bbox": [23.77, 401.42, 405.94, 202.95], "category_id": 1}, {"id": 8, "bbox": [3.85, 1.93, 290.33, 226.07], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 119, 60], "ImageBB": [66, 65, 387, 248]}, "reactions": [{"reactants": [8], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [4], "products": [7]}], "diagram_type": "tree"}, {"id": 1336, "width": 3396, "height": 1172, "file_name": "op4003467-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1447.04, 296.6, 61.46, 51.22], "category_id": 3}, {"id": 1, "bbox": [1892.2, 16.99, 277.2, 45.81], "category_id": 2}, {"id": 2, "bbox": [2355.5, 383.97, 243.74, 109.53], "category_id": 2}, {"id": 3, "bbox": [1483.1, 361.88, 293.9, 57.77], "category_id": 2}, {"id": 4, "bbox": [1257.1, 397.56, 144.45, 125.72], "category_id": 2}, {"id": 5, "bbox": [2342.71, 803.62, 62.86, 61.16], "category_id": 3}, {"id": 6, "bbox": [1262.25, 61.16, 280.31, 265.04], "category_id": 1}, {"id": 7, "bbox": [2150.74, 560.66, 332.98, 280.33], "category_id": 1}, {"id": 8, "bbox": [2561.86, 118.93, 74.75, 61.16], "category_id": 3}, {"id": 9, "bbox": [883.4, 125.72, 57.76, 64.57], "category_id": 3}, {"id": 10, "bbox": [2342.71, 295.62, 64.56, 54.37], "category_id": 3}, {"id": 11, "bbox": [761.08, 416.25, 339.77, 460.42], "category_id": 1}, {"id": 12, "bbox": [1141.63, 667.7, 135.9, 127.42], "category_id": 2}, {"id": 13, "bbox": [1612.21, 56.07, 315.98, 270.13], "category_id": 1}, {"id": 14, "bbox": [1036.3, 73.06, 152.89, 64.56], "category_id": 2}, {"id": 15, "bbox": [1036.3, 844.39, 66.25, 57.77], "category_id": 3}, {"id": 16, "bbox": [1432.13, 847.79, 67.95, 54.37], "category_id": 3}, {"id": 17, "bbox": [1036.3, 164.8, 163.09, 78.15], "category_id": 2}, {"id": 18, "bbox": [1262.25, 567.46, 298.99, 273.53], "category_id": 1}, {"id": 19, "bbox": [1793.98, 293.92, 71.36, 57.77], "category_id": 3}, {"id": 20, "bbox": [1967.27, 168.2, 149.5, 127.42], "category_id": 2}, {"id": 21, "bbox": [1967.27, 81.55, 142.7, 59.46], "category_id": 2}, {"id": 22, "bbox": [2150.74, 378.87, 135.91, 117.23], "category_id": 2}, {"id": 23, "bbox": [2201.71, 56.07, 299.0, 273.53], "category_id": 1}, {"id": 24, "bbox": [1141.63, 592.94, 113.82, 59.47], "category_id": 2}], "caption": "Scheme 5. 7-Bromo-5-chloro-4-methoxy-3,3-dimethyl-2,3-dihydrobenzofuran", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 802, 510, 817], "ImageBB": [10, 834, 859, 1127]}, "reactions": [{"reactants": [9], "conditions": [14, 17], "products": [6, 13]}, {"reactants": [6], "conditions": [4], "products": [18]}, {"reactants": [18], "conditions": [24, 12], "products": [11]}, {"reactants": [13], "conditions": [21, 20], "products": [23, 8]}, {"reactants": [23], "conditions": [22, 2], "products": [7]}], "diagram_type": "graph"}, {"id": 200, "width": 1356, "height": 1156, "file_name": "op049889k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [995.0, 0.0, 360.0, 334.0], "category_id": 1}, {"id": 1, "bbox": [608.1, 18.8, 366.9, 328.2], "category_id": 1}, {"id": 2, "bbox": [174.4, 178.8, 363.1, 152.8], "category_id": 1}, {"id": 3, "bbox": [10.0, 423.6, 1344.0, 732.4], "category_id": 4}, {"id": 4, "bbox": [340.0, 321.0, 57.3, 58.4], "category_id": 3}, {"id": 5, "bbox": [716.8, 334.0, 87.2, 54.1], "category_id": 3}, {"id": 6, "bbox": [1177.4, 350.1, 86.9, 55.8], "category_id": 3}, {"id": 7, "bbox": [0.0, 139.0, 45.3, 53.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2], "products": [1, 0]}], "corefs": [[2, 4], [1, 5], [0, 6]], "caption": "Table 1. Cycloaddition optimization", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 273, 67], "ImageBB": [73, 71, 412, 361]}, "diagram_type": "single"}, {"id": 590, "width": 1356, "height": 1144, "file_name": "acs.oprd.6b00180-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [159.0, 212.3, 48.8, 55.7], "category_id": 3}, {"id": 1, "bbox": [1210.3, 212.7, 55.1, 50.3], "category_id": 3}, {"id": 2, "bbox": [0.0, 65.0, 288.1, 160.2], "category_id": 1}, {"id": 3, "bbox": [380.6, 75.6, 249.4, 146.1], "category_id": 1}, {"id": 4, "bbox": [666.9, 80.3, 281.1, 56.7], "category_id": 2}, {"id": 5, "bbox": [706.96, 155.36, 202.44, 51.34], "category_id": 2}, {"id": 6, "bbox": [13.0, 283.0, 1343.0, 861.0], "category_id": 4}, {"id": 7, "bbox": [989.0, 0.0, 362.0, 237.0], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [4, 5], "products": [7]}], "corefs": [[2, 0], [7, 1]], "caption": "Table 3. Screening Conditions for 100 mL Scale Pd(OAc)2 Catalyzed Suzuki Reaction of 4-Bromoanisole (1) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 363, 783, 408], "ImageBB": [448, 414, 787, 700]}, "diagram_type": "single"}, {"id": 1280, "width": 928, "height": 936, "file_name": "op100205s-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [815.42, 307.16, 112.58, 60.4], "category_id": 2}, {"id": 1, "bbox": [569.67, 558.14, 304.93, 377.86], "category_id": 1}, {"id": 2, "bbox": [790.61, 842.35, 113.75, 55.72], "category_id": 2}, {"id": 3, "bbox": [108.13, 22.48, 283.67, 370.84], "category_id": 1}, {"id": 4, "bbox": [300.52, 265.02, 93.15, 54.32], "category_id": 2}, {"id": 5, "bbox": [584.18, 21.54, 280.86, 371.78], "category_id": 1}, {"id": 6, "bbox": [278.98, 625.56, 203.63, 105.35], "category_id": 2}], "caption": "Scheme 10. LiOAc-catalyzed Hunsdiecker reaction of 17a", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 311, 747, 325], "ImageBB": [408, 65, 640, 299]}, "reactions": [{"reactants": [3], "conditions": [], "products": [5]}, {"reactants": [3], "conditions": [6], "products": [1]}], "diagram_type": "tree"}, {"id": 425, "width": 1348, "height": 568, "file_name": "op300235t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [204.0, 395.0, 59.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [1161.0, 392.0, 61.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [46.0, 9.0, 309.0, 391.0], "category_id": 1}, {"id": 3, "bbox": [457.2, 9.0, 339.4, 391.0], "category_id": 1}, {"id": 4, "bbox": [640.0, 395.0, 60.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [951.0, 14.0, 348.0, 381.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}], "corefs": [[2, 0], [3, 4], [5, 1]], "caption": "Table 3. Halogenation via organometallationa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 564, 341, 585], "ImageBB": [82, 591, 419, 733]}, "diagram_type": "single"}, {"id": 1317, "width": 1356, "height": 1792, "file_name": "op300213s-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.65, 934.1, 89.61, 52.89], "category_id": 2}, {"id": 1, "bbox": [475.86, 1068.7, 305.59, 275.97], "category_id": 1}, {"id": 2, "bbox": [148.76, 0.0, 316.35, 290.7], "category_id": 1}, {"id": 3, "bbox": [516.19, 504.1, 306.49, 291.05], "category_id": 1}, {"id": 4, "bbox": [951.72, 1307.02, 355.78, 52.89], "category_id": 2}, {"id": 5, "bbox": [246.28, 369.59, 71.58, 39.26], "category_id": 2}, {"id": 6, "bbox": [495.68, 1009.26, 60.04, 39.26], "category_id": 2}, {"id": 7, "bbox": [768.17, 485.06, 60.04, 36.94], "category_id": 2}, {"id": 8, "bbox": [0.0, 1052.43, 326.2, 284.17], "category_id": 1}, {"id": 9, "bbox": [1224.16, 197.22, 93.2, 59.16], "category_id": 2}, {"id": 10, "bbox": [656.89, 372.03, 343.23, 51.09], "category_id": 2}, {"id": 11, "bbox": [1201.75, 1530.24, 87.83, 56.47], "category_id": 2}, {"id": 12, "bbox": [48.39, 838.18, 345.92, 49.3], "category_id": 2}, {"id": 13, "bbox": [1011.77, 992.37, 319.03, 285.07], "category_id": 1}, {"id": 14, "bbox": [660.47, 24.2, 320.83, 330.79], "category_id": 1}, {"id": 15, "bbox": [1031.48, 488.56, 315.45, 300.31], "category_id": 1}, {"id": 16, "bbox": [589.67, 1514.1, 236.59, 240.25], "category_id": 1}, {"id": 17, "bbox": [56.46, 503.8, 312.76, 285.07], "category_id": 1}], "caption": "Scheme 3. Reaction mechanism showing base hydrolysis of TACDNB ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 413, 783, 443], "ImageBB": [448, 449, 787, 897]}, "reactions": [{"reactants": [2, 5], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [9], "products": [15]}, {"reactants": [15], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [15]}, {"reactants": [3, 7], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [8]}], "diagram_type": "tree"}, {"id": 74, "width": 1344, "height": 1668, "file_name": "ja206047h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [348.08, 100.39, 165.04, 102.33], "category_id": 1}, {"id": 1, "bbox": [1073.39, 108.75, 257.01, 156.68], "category_id": 1}, {"id": 2, "bbox": [356.94, 272.45, 117.5, 39.1], "category_id": 2}, {"id": 3, "bbox": [66.44, 271.75, 116.1, 41.2], "category_id": 2}, {"id": 4, "bbox": [15.74, 92.03, 261.19, 165.04], "category_id": 1}, {"id": 5, "bbox": [189.23, 271.8, 45.89, 34.7], "category_id": 3}, {"id": 6, "bbox": [586.37, 192.36, 411.68, 77.25], "category_id": 2}, {"id": 7, "bbox": [686.7, 4.24, 198.48, 171.31], "category_id": 1}, {"id": 8, "bbox": [1187.86, 272.45, 43.3, 33.5], "category_id": 3}, {"id": 9, "bbox": [1.11, 351.22, 1339.74, 1312.57], "category_id": 4}, {"id": 10, "bbox": [477.68, 271.79, 29.12, 33.41], "category_id": 3}], "reactions": [{"reactants": [4, 0], "conditions": [7, 6], "products": [1]}], "corefs": [[4, 5], [0, 10], [1, 8]], "caption": "Table 1. Optimization of Catalytic Enantioselective Arylation", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 396, 108], "ImageBB": [71, 117, 407, 534]}, "diagram_type": "single"}, {"id": 787, "width": 1352, "height": 496, "file_name": "jo501913z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 373.0, 1352.0, 123.0], "category_id": 4}, {"id": 1, "bbox": [0.0, 34.0, 184.0, 212.0], "category_id": 1}, {"id": 2, "bbox": [360.0, 0.0, 140.0, 247.0], "category_id": 1}, {"id": 3, "bbox": [918.0, 16.0, 432.0, 216.0], "category_id": 1}, {"id": 4, "bbox": [560.0, 113.0, 254.0, 54.0], "category_id": 2}, {"id": 5, "bbox": [1105.0, 298.0, 60.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [659.0, 50.0, 33.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [389.0, 299.0, 62.0, 50.0], "category_id": 3}, {"id": 8, "bbox": [34.0, 299.0, 55.0, 52.0], "category_id": 3}, {"id": 9, "bbox": [584.0, 199.0, 202.0, 97.0], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [6, 4, 9], "products": [3]}], "corefs": [[1, 8], [2, 7], [3, 5]], "caption": "Table 3. Claisen\u2212Schmidt Condensation of Acetophenone and Benzaldehyde ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 172, 411, 202], "ImageBB": [82, 208, 420, 332]}, "diagram_type": "single"}, {"id": 626, "width": 1480, "height": 2100, "file_name": "ol501424f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [331.5, 214.86, 38.97, 49.85], "category_id": 3}, {"id": 1, "bbox": [646.89, 214.86, 43.51, 49.85], "category_id": 3}, {"id": 2, "bbox": [1195.2, 224.83, 41.69, 48.04], "category_id": 3}, {"id": 3, "bbox": [719.1, 249.2, 395.6, 252.4], "category_id": 1}, {"id": 4, "bbox": [1071.56, 4.56, 305.0, 215.0], "category_id": 1}, {"id": 5, "bbox": [809.0, 60.0, 254.0, 86.0], "category_id": 2}, {"id": 6, "bbox": [520.0, 50.0, 275.0, 132.0], "category_id": 1}, {"id": 7, "bbox": [857.0, 163.0, 148.0, 43.0], "category_id": 2}, {"id": 8, "bbox": [235.0, 67.0, 245.0, 141.0], "category_id": 1}, {"id": 9, "bbox": [134.0, 524.0, 1346.0, 1576.0], "category_id": 4}], "reactions": [{"reactants": [8, 6], "conditions": [5, 7], "products": [4]}], "corefs": [[8, 0], [6, 1], [4, 2]], "caption": "Table 1. Substrate Scope of NHC-Catalyzed aza-DA Reactiona ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 737, 125], "ImageBB": [416, 131, 786, 656]}, "diagram_type": "single"}, {"id": 487, "width": 1344, "height": 1160, "file_name": "ol060664z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1076.0, 223.0, 46.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [86.0, 225.0, 42.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [355.0, 5.0, 567.0, 164.0], "category_id": 2}, {"id": 3, "bbox": [558.0, 178.0, 164.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [2.0, 307.9, 1342.0, 852.1], "category_id": 4}, {"id": 5, "bbox": [957.0, 7.1, 317.1, 248.7], "category_id": 1}, {"id": 6, "bbox": [71.3, 1.6, 270.4, 274.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [2, 3], "products": [5]}], "corefs": [[6, 1], [5, 0]], "caption": "Table 2. Formation of Pyrroles 3 from 1 and Amines 2a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 372, 89], "ImageBB": [74, 98, 410, 388]}, "diagram_type": "single"}, {"id": 251, "width": 1352, "height": 1196, "file_name": "ol802669r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [152.0, 257.0, 62.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [1069.0, 258.0, 62.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [63.0, 56.0, 301.0, 208.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 332.0, 1348.0, 864.0], "category_id": 4}, {"id": 4, "bbox": [470.0, 0.0, 300.0, 147.0], "category_id": 2}, {"id": 5, "bbox": [938.0, 69.0, 351.0, 167.2], "category_id": 1}, {"id": 6, "bbox": [447.0, 162.0, 342.0, 62.2], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [4, 6], "products": [5]}], "corefs": [[2, 0], [5, 1]], "caption": "Table 1. Optimization of the Pd(0)-Catalyzed Cyclopropane Ring-Expansion Reaction of 1ba ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 369, 102], "ImageBB": [58, 111, 396, 410]}, "diagram_type": "single"}, {"id": 47, "width": 1348, "height": 396, "file_name": "ja410533y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [411.22, 6.65, 145.75, 135.42], "category_id": 1}, {"id": 1, "bbox": [439.63, 164.17, 45.9, 35.57], "category_id": 3}, {"id": 2, "bbox": [126.3, 204.63, 168.13, 39.02], "category_id": 2}, {"id": 3, "bbox": [393.14, 205.49, 137.15, 38.16], "category_id": 2}, {"id": 4, "bbox": [189.14, 165.04, 45.9, 34.71], "category_id": 3}, {"id": 5, "bbox": [1001.72, 25.59, 214.62, 136.28], "category_id": 1}, {"id": 6, "bbox": [7.13, 279.88, 1334.78, 116.12], "category_id": 4}, {"id": 7, "bbox": [1071.45, 190.0, 46.76, 37.29], "category_id": 3}, {"id": 8, "bbox": [612.65, 19.56, 316.19, 77.75], "category_id": 2}, {"id": 9, "bbox": [658.27, 133.19, 224.94, 118.2], "category_id": 2}, {"id": 10, "bbox": [128.88, 27.31, 162.97, 125.09], "category_id": 1}], "reactions": [{"reactants": [10, 0], "conditions": [8, 9], "products": [5]}], "corefs": [[10, 4], [0, 1], [5, 7]], "caption": "Table 1. Selected Optimization Experiments in the Ruthenium-Catalyzed C\u2212C Coupling of Diol 1b and Methyl Acrylate 2aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 140], "ImageBB": [449, 146, 786, 245]}, "diagram_type": "single"}, {"id": 1202, "width": 1352, "height": 960, "file_name": "ol503404p-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [273.92, 148.72, 103.48, 59.48], "category_id": 3}, {"id": 1, "bbox": [703.39, 836.87, 201.55, 43.27], "category_id": 2}, {"id": 2, "bbox": [399.04, 519.83, 175.85, 80.45], "category_id": 2}, {"id": 3, "bbox": [334.79, 623.26, 346.96, 277.16], "category_id": 1}, {"id": 4, "bbox": [610.06, 122.35, 252.27, 61.52], "category_id": 2}, {"id": 5, "bbox": [332.59, 432.16, 39.18, 46.1], "category_id": 3}, {"id": 6, "bbox": [1168.12, 510.53, 51.86, 47.25], "category_id": 3}, {"id": 7, "bbox": [952.96, 505.64, 150.82, 48.67], "category_id": 2}, {"id": 8, "bbox": [998.95, 107.48, 158.26, 60.16], "category_id": 2}, {"id": 9, "bbox": [546.48, 0.0, 146.09, 54.75], "category_id": 2}, {"id": 10, "bbox": [705.42, 738.18, 183.96, 80.44], "category_id": 2}, {"id": 11, "bbox": [794.02, 211.58, 217.11, 44.62], "category_id": 2}, {"id": 12, "bbox": [66.96, 205.5, 468.02, 294.05], "category_id": 1}, {"id": 13, "bbox": [1011.13, 840.93, 50.72, 55.43], "category_id": 3}, {"id": 14, "bbox": [952.96, 160.89, 328.02, 300.13], "category_id": 1}, {"id": 15, "bbox": [546.48, 211.58, 129.86, 62.19], "category_id": 2}, {"id": 16, "bbox": [334.79, 65.57, 238.74, 70.3], "category_id": 2}, {"id": 17, "bbox": [1108.52, 389.37, 58.16, 60.16], "category_id": 3}, {"id": 18, "bbox": [890.06, 48.67, 67.63, 50.02], "category_id": 3}, {"id": 19, "bbox": [855.57, 580.9, 372.66, 319.52], "category_id": 1}, {"id": 20, "bbox": [429.47, 866.62, 51.41, 50.69], "category_id": 3}], "caption": "Scheme 4. Proposed Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 692, 263, 707], "ImageBB": [82, 713, 420, 953]}, "reactions": [{"reactants": [3], "conditions": [2], "products": [12]}, {"reactants": [12, 15], "conditions": [], "products": [0, 4]}, {"reactants": [9, 16], "conditions": [], "products": [4]}, {"reactants": [4, 18], "conditions": [], "products": [8, 14]}, {"reactants": [14, 6], "conditions": [7], "products": [19]}, {"reactants": [19], "conditions": [10, 1], "products": [3]}], "diagram_type": "graph"}, {"id": 1067, "width": 1356, "height": 812, "file_name": "jo300771f-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [563.02, 676.8, 232.28, 41.2], "category_id": 3}, {"id": 1, "bbox": [309.32, 2.71, 392.38, 53.49], "category_id": 1}, {"id": 2, "bbox": [88.18, 561.15, 224.53, 54.96], "category_id": 2}, {"id": 3, "bbox": [385.49, 62.96, 241.34, 96.12], "category_id": 2}, {"id": 4, "bbox": [101.2, 346.22, 195.32, 47.04], "category_id": 1}, {"id": 5, "bbox": [563.4, 720.5, 177.96, 46.02], "category_id": 3}, {"id": 6, "bbox": [925.93, 252.41, 57.66, 56.32], "category_id": 3}, {"id": 7, "bbox": [459.24, 171.67, 97.0, 45.46], "category_id": 2}, {"id": 8, "bbox": [381.23, 323.66, 642.38, 365.05], "category_id": 1}, {"id": 9, "bbox": [187.22, 255.81, 61.73, 48.17], "category_id": 3}, {"id": 10, "bbox": [679.7, 0.0, 641.7, 312.12], "category_id": 1}, {"id": 11, "bbox": [332.39, 670.39, 139.06, 99.74], "category_id": 2}, {"id": 12, "bbox": [38.67, 80.07, 304.57, 164.2], "category_id": 1}, {"id": 13, "bbox": [61.73, 398.6, 274.05, 143.55], "category_id": 2}], "caption": "Scheme 9. Preparation of 9c", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 611, 110], "ImageBB": [448, 116, 787, 319]}, "reactions": [{"reactants": [12], "conditions": [1, 3, 7], "products": [10]}, {"reactants": [10], "conditions": [4, 13, 2], "products": [8]}, {"reactants": [0], "conditions": [11], "products": [5]}], "diagram_type": "multiple"}, {"id": 204, "width": 1348, "height": 988, "file_name": "op034181b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1011.35, 215.35, 42.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [377.89, 168.0, 265.91, 102.7], "category_id": 2}, {"id": 2, "bbox": [118.3, 204.32, 51.4, 56.4], "category_id": 3}, {"id": 3, "bbox": [324.0, 3.0, 384.4, 133.0], "category_id": 1}, {"id": 4, "bbox": [135.0, 13.0, 141.8, 281.0], "category_id": 1}, {"id": 5, "bbox": [718.95, 78.0, 500.55, 131.0], "category_id": 1}, {"id": 6, "bbox": [527.0, 91.0, 50.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [5.0, 311.0, 1343.0, 677.0], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [3, 1], "products": [5]}], "corefs": [[4, 2], [3, 6], [5, 0]], "caption": "Table 3. Suzuki coupling results", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 271, 257, 285], "ImageBB": [74, 288, 410, 535]}, "diagram_type": "single"}, {"id": 231, "width": 1184, "height": 468, "file_name": "op000111i-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [55.7, 236.1, 179.1, 132.7], "category_id": 1}, {"id": 1, "bbox": [434.0, 101.0, 139.8, 54.0], "category_id": 2}, {"id": 2, "bbox": [58.0, 5.5, 181.5, 131.9], "category_id": 1}, {"id": 3, "bbox": [762.5, 225.0, 184.8, 138.5], "category_id": 1}, {"id": 4, "bbox": [748.9, 7.0, 176.4, 129.3], "category_id": 1}, {"id": 5, "bbox": [1076.29, 31.46, 85.0, 63.0], "category_id": 2}, {"id": 6, "bbox": [401.0, 219.0, 220.0, 52.0], "category_id": 2}, {"id": 7, "bbox": [1071.0, 267.0, 113.0, 59.0], "category_id": 2}, {"id": 8, "bbox": [394.0, 19.0, 227.0, 57.0], "category_id": 2}, {"id": 9, "bbox": [4.0, 408.0, 656.0, 60.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [8, 1], "products": [4]}, {"reactants": [0], "conditions": [6], "products": [3]}], "corefs": [], "caption": "Figure 3. Catalysed and uncatalyzed reduction of prochiral ketones by borane. 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Strategy for synthetic diversification of monoterpene indole alkaloids using Pd-catalyzed Suzuki Miyaura coupling reaction. Alkaloid analogs with chlorine and bromine at the 7-position of the indole ring were obtained by culturing transgenic tryptophan decarboxylase-suppressed hairy root cultures in the presence of 7-chlorotryptamine 1a or 7-bromotryptamine 1b (a). Alkaloid analogs with chlorine at the 6-position of the indole ring were obtained by culturing hairy root cultures that express a mutant strictosidine synthase enzyme (V214M) in the presence of 6-chlorotryptamine 1c (b). Alkaloid analogs with chlorine at the 7-position of the indole ring could also be obtained from hairy root cultures that express prokaryotic halogenases, RebH and RebF (c). 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Rates of Catalysis for the Oxidation of Bromide by Hydrogen Peroxide in the Presence of Phenylseleno-Containing Molecules As Determined by the Rate of Bromination of Cyclohexene ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 178, 401, 237], "ImageBB": [73, 238, 411, 502]}, "diagram_type": "single"}, {"id": 770, "width": 1348, "height": 1072, "file_name": "jo9602433-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [472.81, 462.75, 185.37, 57.48], "category_id": 2}, {"id": 1, "bbox": [1119.46, 472.81, 191.12, 58.92], "category_id": 2}, {"id": 2, "bbox": [308.0, 646.0, 69.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [734.3, 275.1, 491.6, 370.3], "category_id": 1}, {"id": 4, "bbox": [960.0, 656.0, 66.7, 52.5], "category_id": 3}, {"id": 5, "bbox": [93.2, 259.0, 478.8, 372.4], "category_id": 1}, {"id": 6, "bbox": [33.0, 55.0, 126.0, 72.0], "category_id": 3}, {"id": 7, "bbox": [6.0, 756.0, 1342.0, 316.0], "category_id": 4}, {"id": 8, "bbox": [242.0, 0.0, 215.0, 56.0], "category_id": 2}, {"id": 9, "bbox": [283.0, 104.0, 183.0, 57.0], "category_id": 2}, {"id": 10, "bbox": [324.0, 179.0, 79.0, 51.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [8, 9, 10], "products": [5, 3]}], "corefs": [[5, 2], [3, 4]], "caption": "Table 2. Treatment of (Z)-3 with BTMABr3 or Br2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [451, 670, 742, 683], "ImageBB": [429, 391, 766, 659]}, "diagram_type": "multiple"}, {"id": 95, "width": 2128, "height": 1584, "file_name": "ja0516864-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [630.45, 475.0, 22.55, 33.27], "category_id": 3}, {"id": 1, "bbox": [403.41, 602.7, 1384.4, 403.28], "category_id": 4}, {"id": 2, "bbox": [439.22, 1536.16, 27.94, 35.35], "category_id": 3}, {"id": 3, "bbox": [1619.3, 1475.0, 172.49, 98.37], "category_id": 3}, {"id": 4, "bbox": [1109.87, 1475.03, 305.83, 102.04], "category_id": 3}, {"id": 5, "bbox": [828.27, 1536.16, 26.09, 33.5], "category_id": 3}, {"id": 6, "bbox": [4.22, 101.67, 392.88, 116.87], "category_id": 1}, {"id": 7, "bbox": [98.71, 272.11, 233.59, 96.49], "category_id": 1}, {"id": 8, "bbox": [495.17, 94.26, 389.23, 324.36], "category_id": 1}, {"id": 9, "bbox": [1197.3, 88.7, 389.22, 326.21], "category_id": 1}, {"id": 10, "bbox": [1710.5, 7.19, 320.65, 444.78], "category_id": 1}, {"id": 11, "bbox": [930.54, 160.96, 240.99, 44.64], "category_id": 2}, {"id": 12, "bbox": [989.82, 292.49, 142.8, 35.35], "category_id": 2}, {"id": 13, "bbox": [1365.75, 474.1, 21.66, 33.27], "category_id": 3}, {"id": 14, "bbox": [1869.65, 475.0, 17.19, 33.27], "category_id": 3}, {"id": 15, "bbox": [287.31, 1089.68, 313.24, 416.99], "category_id": 1}, {"id": 16, "bbox": [674.5, 1085.97, 315.1, 413.29], "category_id": 1}, {"id": 17, "bbox": [1089.49, 1119.32, 291.01, 268.78], "category_id": 1}, {"id": 18, "bbox": [1491.52, 1130.44, 389.18, 159.47], "category_id": 1}, {"id": 19, "bbox": [1982.83, 331.4, 139.1, 37.2], "category_id": 1}], "reactions": [{"reactants": [6, 7], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [11, 12], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10]}], "corefs": [[8, 0], [9, 13], [10, 14], [15, 2], [16, 5], [17, 4], [18, 3]], "caption": "Table 1. Selected Experimental NMR Spectroscopic Data of Aryl-Substituted Vinyl Cations. NMR Chemical Shifts \u03b4 versus TMS, Coupling Constants 1J (Hz) in Bracketsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 487, 766, 511], "ImageBB": [159, 80, 691, 476]}, "diagram_type": "single"}, {"id": 344, "width": 1348, "height": 1452, "file_name": "ol202395s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [148.7, 366.9, 65.6, 67.4], "category_id": 3}, {"id": 1, "bbox": [475.11, 371.0, 64.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [1084.0, 368.0, 62.4, 55.0], "category_id": 3}, {"id": 3, "bbox": [381.7, 1.2, 283.3, 277.2], "category_id": 1}, {"id": 4, "bbox": [17.7, 3.0, 349.3, 277.0], "category_id": 1}, {"id": 5, "bbox": [747.0, 118.0, 112.0, 60.3], "category_id": 2}, {"id": 6, "bbox": [668.0, 199.8, 313.0, 125.5], "category_id": 2}, {"id": 7, "bbox": [962.0, 21.0, 386.0, 350.0], "category_id": 1}, {"id": 8, "bbox": [2.0, 511.4, 1346.0, 940.6], "category_id": 4}], "reactions": [{"reactants": [4, 3], "conditions": [5, 6], "products": [7]}], "corefs": [[4, 0], [3, 1], [7, 2]], "caption": "Table 1. Reaction of P-Alkenyl-\u03bb5-phosphazenes and Aryne Precursors in the Presence of CsFa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 756, 115], "ImageBB": [436, 126, 773, 489]}, "diagram_type": "single"}, {"id": 635, "width": 1348, "height": 1100, "file_name": "ol501165h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [574.1, 746.0, 261.9, 258.2], "category_id": 1}, {"id": 1, "bbox": [221.0, 475.0, 286.6, 211.8], "category_id": 1}, {"id": 2, "bbox": [830.88, 130.0, 318.7, 261.0], "category_id": 1}, {"id": 3, "bbox": [273.1, 154.0, 266.9, 210.7], "category_id": 1}, {"id": 4, "bbox": [337.0, 25.6, 170.0, 52.4], "category_id": 1}, {"id": 5, "bbox": [555.0, 148.0, 269.0, 219.2], "category_id": 1}, {"id": 6, "bbox": [577.0, 349.3, 72.0, 39.7], "category_id": 3}, {"id": 7, "bbox": [881.6, 659.9, 163.0, 48.6], "category_id": 3}, {"id": 8, "bbox": [518.0, 62.0, 413.0, 50.0], "category_id": 2}, {"id": 9, "bbox": [549.0, 4.0, 320.0, 43.0], "category_id": 2}, {"id": 10, "bbox": [951.0, 31.0, 116.0, 42.0], "category_id": 3}, {"id": 11, "bbox": [7.0, 1028.0, 1311.0, 72.0], "category_id": 4}, {"id": 12, "bbox": [581.0, 475.0, 247.0, 179.0], "category_id": 1}, {"id": 13, "bbox": [887.0, 437.0, 258.0, 206.0], "category_id": 1}, {"id": 14, "bbox": [273.0, 716.0, 250.0, 213.0], "category_id": 1}, {"id": 15, "bbox": [594.0, 958.0, 68.0, 36.0], "category_id": 3}, {"id": 16, "bbox": [244.0, 663.0, 72.0, 33.0], "category_id": 3}, {"id": 17, "bbox": [880.0, 743.0, 262.0, 225.7], "category_id": 1}, {"id": 18, "bbox": [896.0, 957.0, 67.0, 36.0], "category_id": 3}, {"id": 19, "bbox": [828.8, 343.6, 235.2, 90.4], "category_id": 3}, {"id": 20, "bbox": [191.7, 345.0, 263.3, 130.3], "category_id": 3}, {"id": 21, "bbox": [189.3, 916.0, 254.7, 78.0], "category_id": 3}, {"id": 22, "bbox": [564.86, 652.04, 265.08, 89.3], "category_id": 3}, {"id": 23, "bbox": [267.18, 25.49, 39.69, 52.45], "category_id": 3}], "reactions": [{"reactants": [23, 4], "conditions": [9, 8], "products": [10]}], "corefs": [[3, 20], [5, 6], [2, 19], [1, 16], [12, 22], [13, 7], [14, 21], [0, 15], [17, 18]], "caption": "Table 1. Cyclocarbopalladation/Stille Coupling", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 347, 110], "ImageBB": [82, 116, 419, 391]}, "diagram_type": "single"}, {"id": 649, "width": 1356, "height": 2340, "file_name": "ol500121z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [996.0, 294.0, 233.0, 100.0], "category_id": 1}, {"id": 1, "bbox": [204.0, 211.0, 91.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [82.0, 946.0, 1214.0, 1234.9], "category_id": 4}, {"id": 3, "bbox": [489.0, 163.0, 76.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [1080.0, 192.0, 26.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [1086.0, 428.0, 26.0, 32.0], "category_id": 3}, {"id": 6, "bbox": [643.0, 133.0, 290.0, 89.0], "category_id": 2}, {"id": 7, "bbox": [702.0, 63.0, 172.0, 40.0], "category_id": 2}, {"id": 8, "bbox": [1014.0, 0.0, 195.0, 179.0], "category_id": 1}, {"id": 9, "bbox": [481.0, 99.0, 92.0, 38.0], "category_id": 1}, {"id": 10, "bbox": [136.0, 85.0, 253.0, 107.0], "category_id": 1}, {"id": 11, "bbox": [611.0, 255.0, 353.0, 289.0], "category_id": 3}, {"id": 12, "bbox": [120.0, 260.0, 596.0, 665.0], "category_id": 3}], "reactions": [{"reactants": [10, 9], "conditions": [7, 6], "products": [8, 0]}], "corefs": [[10, 1], [10, 12], [9, 3], [9, 11], [8, 4], [0, 5]], "caption": "Table 2. [Pd(cod)(C3H5)]BF4/bpy-Catalyzed Double Alkylation of 1 with 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 748, 125], "ImageBB": [448, 131, 787, 716]}, "diagram_type": "single"}, {"id": 877, "width": 1352, "height": 640, "file_name": "ol701624y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 301.0, 1352.0, 339.0], "category_id": 4}, {"id": 1, "bbox": [71.0, 0.0, 390.0, 129.0], "category_id": 1}, {"id": 2, "bbox": [870.0, 0.0, 409.0, 219.0], "category_id": 1}, {"id": 3, "bbox": [869.37, 165.48, 145.9, 54.39], "category_id": 2}, {"id": 4, "bbox": [493.0, 8.0, 299.0, 54.0], "category_id": 2}, {"id": 5, "bbox": [489.0, 99.0, 309.0, 122.0], "category_id": 2}, {"id": 6, "bbox": [208.0, 154.0, 82.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [1068.0, 233.0, 88.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [2]}], "corefs": [[1, 6], [2, 7]], "caption": "Table 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 449, 120, 462], "ImageBB": [73, 466, 411, 626]}, "diagram_type": "single"}], "roles": [{"id": 1, "name": "reactants"}, {"id": 2, "name": "conditions"}, {"id": 3, "name": "products"}]}