dev1.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 1235, "width": 2192, "height": 456, "file_name": "op020098x-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 26.35, 404.63, 201.98], "category_id": 1}, {"id": 1, "bbox": [460.55, 379.82, 372.83, 76.18], "category_id": 2}, {"id": 2, "bbox": [527.44, 47.2, 637.09, 210.77], "category_id": 1}, {"id": 3, "bbox": [1303.8, 0.0, 888.2, 245.9], "category_id": 1}], "caption": "Scheme 3. Oligonucleotide synthesis using I-linker solid support", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 534, 434, 548], "ImageBB": [151, 552, 699, 666]}, "reactions": [{"reactants": [0], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [3]}], "diagram_type": "multiple"}, {"id": 627, "width": 1752, "height": 1960, "file_name": "ol501424f-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1118.0, 1551.0, 35.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [950.0, 1594.0, 439.0, 96.0], "category_id": 2}, {"id": 2, "bbox": [192.0, 1590.0, 409.0, 100.0], "category_id": 2}, {"id": 3, "bbox": [549.0, 1401.0, 374.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [601.0, 1466.0, 197.0, 58.0], "category_id": 2}, {"id": 5, "bbox": [763.0, 936.0, 263.0, 91.0], "category_id": 2}, {"id": 6, "bbox": [307.0, 1103.0, 47.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [607.0, 1097.0, 66.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [1151.0, 1111.0, 51.0, 41.0], "category_id": 3}, {"id": 9, "bbox": [303.0, 1534.0, 33.0, 37.0], "category_id": 3}, {"id": 10, "bbox": [890.0, 1220.0, 267.0, 62.0], "category_id": 2}, {"id": 11, "bbox": [89.0, 61.0, 1404.0, 579.6], "category_id": 2}, {"id": 12, "bbox": [187.1, 960.8, 259.4, 129.1], "category_id": 1}, {"id": 13, "bbox": [489.1, 931.6, 269.0, 135.7], "category_id": 1}, {"id": 14, "bbox": [1018.1, 883.1, 315.2, 213.4], "category_id": 1}, {"id": 15, "bbox": [941.6, 1341.6, 393.9, 210.8], "category_id": 1}, {"id": 16, "bbox": [188.5, 1354.1, 298.3, 184.3], "category_id": 1}, {"id": 17, "bbox": [810.0, 1039.0, 148.0, 48.4], "category_id": 2}, {"id": 18, "bbox": [108.0, 689.9, 1361.0, 140.1], "category_id": 2}], "reactions": [{"reactants": [12, 13], "conditions": [5, 17], "products": [14]}, {"reactants": [14], "conditions": [10], "products": [15]}, {"reactants": [15], "conditions": [3, 4], "products": [16]}], "corefs": [[12, 6], [13, 7], [14, 8], [15, 0], [16, 9]], "caption": "Figure 3. (Top) Blown-up orbital interactions of diene and dienophile in the inverse demand Diels\u2212Alder. (Bottom) HOMO\u2212LUMO interaction diagram of the reactants. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 592, 784, 634], "ImageBB": [421, 637, 859, 1127]}, "diagram_type": "tree"}, {"id": 582, "width": 1356, "height": 1192, "file_name": "acs.orglett.5b00081-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [989.0, 419.0, 285.0, 267.4], "category_id": 1}, {"id": 1, "bbox": [87.0, 358.0, 212.4, 175.8], "category_id": 1}, {"id": 2, "bbox": [603.0, 39.0, 325.0, 266.9], "category_id": 1}, {"id": 3, "bbox": [985.08, 39.73, 286.12, 263.07], "category_id": 1}, {"id": 4, "bbox": [83.0, 62.0, 124.1, 117.8], "category_id": 1}, {"id": 5, "bbox": [681.0, 690.0, 182.0, 38.0], "category_id": 2}, {"id": 6, "bbox": [681.0, 317.0, 218.0, 36.0], "category_id": 2}, {"id": 7, "bbox": [1059.0, 311.0, 157.0, 36.0], "category_id": 2}, {"id": 8, "bbox": [87.98, 181.57, 115.91, 107.27], "category_id": 1}, {"id": 9, "bbox": [299.04, 416.86, 254.32, 257.78], "category_id": 1}, {"id": 10, "bbox": [266.0, 62.0, 290.0, 257.0], "category_id": 1}, {"id": 11, "bbox": [910.0, 129.0, 55.0, 55.0], "category_id": 1}, {"id": 12, "bbox": [632.0, 424.0, 286.0, 258.0], "category_id": 1}, {"id": 13, "bbox": [504.0, 734.0, 280.0, 389.0], "category_id": 1}, {"id": 14, "bbox": [965.0, 742.0, 287.0, 382.0], "category_id": 1}, {"id": 15, "bbox": [113.0, 735.0, 327.0, 383.0], "category_id": 1}, {"id": 16, "bbox": [191.0, 1148.0, 126.0, 39.0], "category_id": 2}, {"id": 17, "bbox": [528.0, 1147.0, 251.0, 43.0], "category_id": 2}, {"id": 18, "bbox": [1044.0, 1152.0, 145.0, 33.0], "category_id": 2}, {"id": 19, "bbox": [1092.0, 690.0, 117.0, 35.0], "category_id": 2}, {"id": 20, "bbox": [323.0, 308.0, 157.0, 38.0], "category_id": 2}, {"id": 21, "bbox": [376.0, 689.0, 149.0, 38.0], "category_id": 2}], "reactions": [{"reactants": [4, 8], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [11], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [9]}, {"reactants": [9, 1], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}], "corefs": [[10, 20], [2, 6], [3, 7], [0, 19], [12, 5], [9, 21], [15, 16], [13, 17], [14, 18]], "caption": "Figure 4. Plausible biosynthetic route for duclauxins.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 882, 706, 896], "ImageBB": [448, 575, 787, 873]}, "diagram_type": "tree"}, {"id": 942, "width": 1352, "height": 944, "file_name": "acs.orglett.5b01872-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [58.17, 625.43, 277.97, 171.07], "category_id": 1}, {"id": 1, "bbox": [874.51, 208.93, 57.48, 45.98], "category_id": 3}, {"id": 2, "bbox": [550.54, 772.16, 56.14, 45.3], "category_id": 3}, {"id": 3, "bbox": [26.38, 354.3, 424.74, 220.42], "category_id": 1}, {"id": 4, "bbox": [26.38, 58.15, 259.71, 143.34], "category_id": 1}, {"id": 5, "bbox": [528.63, 295.75, 177.92, 55.53], "category_id": 1}, {"id": 6, "bbox": [1091.61, 150.1, 200.87, 116.3], "category_id": 2}, {"id": 7, "bbox": [1183.59, 752.55, 83.19, 75.05], "category_id": 3}, {"id": 8, "bbox": [530.93, 469.92, 169.76, 76.4], "category_id": 2}, {"id": 9, "bbox": [296.91, 73.02, 87.25, 46.66], "category_id": 2}, {"id": 10, "bbox": [280.68, 502.38, 55.46, 45.97], "category_id": 3}, {"id": 11, "bbox": [779.82, 61.53, 265.8, 143.34], "category_id": 1}, {"id": 12, "bbox": [746.0, 601.77, 445.71, 204.19], "category_id": 1}, {"id": 13, "bbox": [779.82, 323.87, 411.89, 249.5], "category_id": 1}, {"id": 14, "bbox": [0.0, 835.71, 1211.32, 64.91], "category_id": 2}, {"id": 15, "bbox": [227.93, 152.13, 228.6, 121.71], "category_id": 2}, {"id": 16, "bbox": [211.02, 770.8, 58.16, 46.66], "category_id": 3}, {"id": 17, "bbox": [1200.5, 482.77, 49.37, 43.95], "category_id": 3}, {"id": 18, "bbox": [1057.79, 2.3, 275.95, 122.11], "category_id": 2}, {"id": 19, "bbox": [477.49, 351.5, 278.66, 77.18], "category_id": 2}, {"id": 20, "bbox": [121.74, 208.93, 45.99, 45.98], "category_id": 3}, {"id": 21, "bbox": [499.14, 37.19, 277.3, 87.22], "category_id": 2}, {"id": 22, "bbox": [448.41, 116.97, 39.23, 43.95], "category_id": 3}, {"id": 23, "bbox": [570.83, 151.46, 142.71, 114.94], "category_id": 2}, {"id": 24, "bbox": [1124.75, 519.96, 196.14, 48.68], "category_id": 2}, {"id": 25, "bbox": [334.79, 614.62, 355.75, 175.12], "category_id": 1}], "caption": "Scheme 2. An Attempt to Prepare the Divinyl Intermediate", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 504, 417, 519], "ImageBB": [82, 525, 420, 761]}, "reactions": [{"reactants": [4], "conditions": [9, 15], "products": [22]}, {"reactants": [22], "conditions": [21, 23], "products": [11]}, {"reactants": [11], "conditions": [18, 6], "products": [3]}, {"reactants": [3], "conditions": [5, 19, 8], "products": [13, 12]}], "diagram_type": "multiple"}, {"id": 962, "width": 1304, "height": 1964, "file_name": "ja0161958-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [991.39, 1088.6, 47.16, 49.12], "category_id": 2}, {"id": 1, "bbox": [293.72, 1089.22, 42.44, 49.52], "category_id": 2}, {"id": 2, "bbox": [295.5, 1296.89, 51.1, 52.07], "category_id": 2}, {"id": 3, "bbox": [925.56, 1900.14, 162.12, 57.97], "category_id": 3}, {"id": 4, "bbox": [0.0, 1395.14, 631.78, 498.12], "category_id": 1}, {"id": 5, "bbox": [239.74, 336.99, 62.88, 47.16], "category_id": 3}, {"id": 6, "bbox": [925.56, 1197.66, 62.88, 49.12], "category_id": 3}, {"id": 7, "bbox": [239.74, 1191.76, 60.92, 53.06], "category_id": 3}, {"id": 8, "bbox": [925.56, 336.99, 62.88, 50.11], "category_id": 3}, {"id": 9, "bbox": [303.61, 485.35, 45.19, 47.16], "category_id": 2}, {"id": 10, "bbox": [65.83, 0.0, 455.9, 310.47], "category_id": 1}, {"id": 11, "bbox": [239.74, 992.32, 63.87, 51.09], "category_id": 3}, {"id": 12, "bbox": [930.47, 990.35, 59.93, 50.11], "category_id": 3}, {"id": 13, "bbox": [743.79, 0.0, 458.84, 307.52], "category_id": 1}, {"id": 14, "bbox": [660.27, 1398.09, 639.63, 483.38], "category_id": 1}, {"id": 15, "bbox": [474.57, 1407.91, 94.32, 63.86], "category_id": 2}, {"id": 16, "bbox": [995.32, 1306.71, 48.14, 47.16], "category_id": 2}, {"id": 17, "bbox": [611.14, 73.69, 33.41, 49.12], "category_id": 2}, {"id": 18, "bbox": [65.83, 468.65, 460.81, 500.09], "category_id": 1}, {"id": 19, "bbox": [207.32, 1910.95, 169.98, 53.05], "category_id": 3}, {"id": 20, "bbox": [1167.26, 1394.16, 98.26, 65.82], "category_id": 2}, {"id": 21, "bbox": [739.86, 465.7, 458.84, 498.12], "category_id": 1}, {"id": 22, "bbox": [995.32, 479.46, 42.25, 48.14], "category_id": 2}, {"id": 23, "bbox": [0.0, 1960.07, 0.98, 3.93], "category_id": 3}], "caption": "Scheme 1. Synthesis of the Biomimetic Supramolecular Calix[6]arene-Based Cuprous Systems Presenting Two Different Cavitiesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 761, 100], "ImageBB": [446, 100, 772, 591]}, "reactions": [{"reactants": [10], "conditions": [17], "products": [13]}, {"reactants": [10], "conditions": [9], "products": [18]}, {"reactants": [13], "conditions": [22], "products": [21]}, {"reactants": [18], "conditions": [1], "products": [7]}, {"reactants": [7], "conditions": [2], "products": [4, 15]}, {"reactants": [21], "conditions": [0], "products": [6]}, {"reactants": [6], "conditions": [16], "products": [14, 20]}], "diagram_type": "tree"}, {"id": 208, "width": 1120, "height": 728, "file_name": "op0340964-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [13.0, 605.5, 188.0, 117.5], "category_id": 3}, {"id": 1, "bbox": [832.0, 606.5, 187.0, 117.5], "category_id": 3}, {"id": 2, "bbox": [851.6, 332.7, 268.4, 222.7], "category_id": 1}, {"id": 3, "bbox": [371.5, 162.7, 286.8, 61.5], "category_id": 2}, {"id": 4, "bbox": [4.9, 210.9, 247.2, 171.5], "category_id": 1}, {"id": 5, "bbox": [366.0, 345.0, 160.2, 97.3], "category_id": 2}, {"id": 6, "bbox": [849.9, 0.0, 264.1, 227.6], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 5], "products": [6, 2]}], "corefs": [[4, 0], [2, 1]], "caption": "Figure 2. Enzymatic and uncatalyzed hydrocyanation of benzaldehyde and 2-chlorobenzaldehyde. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 436, 409, 464], "ImageBB": [102, 251, 382, 433]}, "diagram_type": "tree"}, {"id": 854, "width": 1344, "height": 712, "file_name": "jo2008675-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [784.0, 114.0, 86.0, 44.0], "category_id": 2}, {"id": 1, "bbox": [105.0, 231.0, 48.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [1120.0, 234.0, 55.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [7.1, 19.1, 296.9, 209.9], "category_id": 1}, {"id": 4, "bbox": [367.3, 73.4, 319.7, 128.5], "category_id": 1}, {"id": 5, "bbox": [493.0, 219.0, 40.9, 50.9], "category_id": 3}, {"id": 6, "bbox": [4.0, 350.1, 1340.0, 361.9], "category_id": 4}, {"id": 7, "bbox": [991.4, 2.9, 346.5, 229.1], "category_id": 1}, {"id": 8, "bbox": [691.0, 164.0, 243.9, 49.9], "category_id": 2}], "reactions": [{"reactants": [3, 4], "conditions": [0, 8], "products": [7]}], "corefs": [[3, 1], [4, 5], [7, 2]], "caption": "Table 1. Reaction of 2-Hydroxyaryl-r,\u03b2-unsaturated Ketone 2a and Diethyl R-Bromomalonate 5 under Di\ufb00erent Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 245, 771, 290], "ImageBB": [437, 300, 773, 478]}, "diagram_type": "single"}, {"id": 1199, "width": 1356, "height": 552, "file_name": "ol502842f-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [109.89, 433.17, 58.34, 37.96], "category_id": 3}, {"id": 1, "bbox": [941.53, 385.04, 69.87, 36.61], "category_id": 2}, {"id": 2, "bbox": [36.63, 260.31, 206.22, 228.45], "category_id": 1}, {"id": 3, "bbox": [110.57, 179.64, 59.01, 38.64], "category_id": 3}, {"id": 4, "bbox": [834.36, 31.18, 281.51, 82.7], "category_id": 2}, {"id": 5, "bbox": [1117.9, 6.1, 192.65, 215.57], "category_id": 1}, {"id": 6, "bbox": [1105.01, 260.99, 214.36, 223.02], "category_id": 1}, {"id": 7, "bbox": [590.83, 140.32, 215.04, 213.54], "category_id": 1}, {"id": 8, "bbox": [250.31, 305.05, 317.46, 74.57], "category_id": 2}, {"id": 9, "bbox": [36.63, 2.71, 210.29, 225.74], "category_id": 1}, {"id": 10, "bbox": [307.97, 21.01, 253.69, 111.18], "category_id": 2}, {"id": 11, "bbox": [1169.46, 460.28, 52.23, 33.22], "category_id": 3}, {"id": 12, "bbox": [1176.24, 203.37, 58.34, 37.28], "category_id": 3}, {"id": 13, "bbox": [378.51, 140.32, 69.19, 35.93], "category_id": 2}, {"id": 14, "bbox": [851.32, 284.03, 252.34, 77.96], "category_id": 2}, {"id": 15, "bbox": [250.31, 228.45, 261.16, 73.45], "category_id": 2}, {"id": 16, "bbox": [280.83, 396.56, 257.77, 43.39], "category_id": 2}, {"id": 17, "bbox": [941.53, 134.22, 69.2, 35.93], "category_id": 2}, {"id": 18, "bbox": [678.34, 340.3, 46.8, 37.96], "category_id": 3}], "caption": "Scheme 6. Synthesis of Useful Synthetic Intermediates", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 750, 110], "ImageBB": [448, 116, 787, 254]}, "reactions": [{"reactants": [7], "conditions": [10, 13], "products": [9]}, {"reactants": [7], "conditions": [4, 17], "products": [5]}, {"reactants": [7], "conditions": [14, 1], "products": [6]}, {"reactants": [7], "conditions": [15, 8, 16], "products": [2]}], "diagram_type": "tree"}, {"id": 98, "width": 1348, "height": 884, "file_name": "ja0289088-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [522.13, 7.34, 218.09, 169.49], "category_id": 1}, {"id": 1, "bbox": [255.38, 187.24, 177.76, 128.14], "category_id": 1}, {"id": 2, "bbox": [511.8, 254.45, 314.23, 187.07], "category_id": 2}, {"id": 3, "bbox": [553.14, 203.78, 217.06, 39.23], "category_id": 2}, {"id": 4, "bbox": [7.04, 458.85, 1335.42, 416.06], "category_id": 4}, {"id": 5, "bbox": [725.81, 142.78, 146.75, 33.02], "category_id": 2}, {"id": 6, "bbox": [631.72, 127.27, 64.08, 48.53], "category_id": 1}, {"id": 7, "bbox": [916.05, 186.21, 177.77, 128.14], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [0, 6, 5, 3, 2], "products": [7]}], "corefs": [], "caption": "Table 3. Variation of the Amount of Water", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 654, 76], "ImageBB": [439, 84, 776, 305]}, "diagram_type": "single"}, {"id": 888, "width": 1348, "height": 560, "file_name": "ol5029892-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [173.06, 131.92, 35.29, 44.76], "category_id": 3}, {"id": 1, "bbox": [1060.54, 129.33, 43.9, 47.35], "category_id": 3}, {"id": 2, "bbox": [13.0, 473.0, 1335.0, 87.0], "category_id": 4}, {"id": 3, "bbox": [965.0, 364.0, 383.0, 52.5], "category_id": 3}, {"id": 4, "bbox": [405.0, 357.0, 192.0, 60.1], "category_id": 3}, {"id": 5, "bbox": [649.0, 368.0, 297.0, 51.4], "category_id": 3}, {"id": 6, "bbox": [119.9, 67.9, 145.8, 59.7], "category_id": 1}, {"id": 7, "bbox": [365.0, 249.0, 272.5, 68.4], "category_id": 1}, {"id": 8, "bbox": [14.12, 408.92, 309.72, 50.16], "category_id": 2}, {"id": 9, "bbox": [331.0, 109.4, 490.1, 50.5], "category_id": 2}, {"id": 10, "bbox": [989.5, 4.0, 185.5, 124.8], "category_id": 1}, {"id": 11, "bbox": [115.0, 368.7, 105.5, 38.3], "category_id": 3}, {"id": 12, "bbox": [1021.2, 207.3, 251.7, 148.7], "category_id": 1}, {"id": 13, "bbox": [673.4, 228.1, 246.3, 105.6], "category_id": 1}, {"id": 14, "bbox": [9.7, 186.5, 319.5, 191.7], "category_id": 1}, {"id": 15, "bbox": [325.0, 4.0, 596.0, 90.3], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [15, 9], "products": [10]}], "corefs": [[6, 0], [10, 1], [14, 11], [7, 4], [13, 5], [12, 3]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 268, 110], "ImageBB": [82, 116, 419, 256]}, "diagram_type": "single"}, {"id": 545, "width": 956, "height": 1096, "file_name": "acs.orglett.5b03589-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [364.7, 138.0, 202.4, 113.8], "category_id": 1}, {"id": 1, "bbox": [368.26, 249.75, 256.1, 47.72], "category_id": 2}, {"id": 2, "bbox": [55.0, 56.0, 241.0, 127.0], "category_id": 1}, {"id": 3, "bbox": [632.0, 34.0, 275.0, 150.0], "category_id": 1}, {"id": 4, "bbox": [14.0, 408.2, 942.0, 687.8], "category_id": 4}, {"id": 5, "bbox": [78.0, 191.0, 214.0, 55.0], "category_id": 3}, {"id": 6, "bbox": [707.0, 199.0, 40.0, 36.0], "category_id": 3}, {"id": 7, "bbox": [323.0, 297.0, 358.0, 80.0], "category_id": 2}, {"id": 8, "bbox": [325.0, 0.0, 271.0, 115.0], "category_id": 2}, {"id": 9, "bbox": [320.85, 174.82, 44.08, 48.48], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [8, 9, 0, 1, 7], "products": [3]}], "corefs": [[2, 5], [3, 6]], "caption": "Table 4. Scope of the Tandem Coupling/Cyclization Reaction with Functionalized 2-Pyridylhydrazines ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 572, 417, 602], "ImageBB": [131, 609, 370, 883]}, "diagram_type": "single"}, {"id": 1298, "width": 1352, "height": 864, "file_name": "op2003216-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 85.88, 201.55, 284.69], "category_id": 1}, {"id": 1, "bbox": [536.34, 443.6, 246.86, 100.09], "category_id": 2}, {"id": 2, "bbox": [524.16, 83.85, 273.24, 334.73], "category_id": 1}, {"id": 3, "bbox": [1011.13, 449.01, 206.28, 235.33], "category_id": 1}, {"id": 4, "bbox": [964.46, 366.51, 48.69, 48.69], "category_id": 3}, {"id": 5, "bbox": [79.81, 371.92, 44.64, 48.69], "category_id": 3}, {"id": 6, "bbox": [1220.11, 365.16, 47.35, 50.04], "category_id": 3}, {"id": 7, "bbox": [1143.01, 83.85, 208.99, 275.23], "category_id": 1}, {"id": 8, "bbox": [836.63, 154.86, 43.96, 48.68], "category_id": 2}, {"id": 9, "bbox": [254.98, 646.47, 115.65, 104.82], "category_id": 1}, {"id": 10, "bbox": [0.0, 577.5, 202.23, 241.41], "category_id": 1}, {"id": 11, "bbox": [888.71, 85.88, 237.39, 269.14], "category_id": 1}, {"id": 12, "bbox": [222.52, 4.06, 234.01, 132.54], "category_id": 1}, {"id": 13, "bbox": [984.07, 693.81, 260.39, 52.07], "category_id": 2}, {"id": 14, "bbox": [219.81, 137.27, 261.07, 56.13], "category_id": 2}], "caption": "Scheme 3. Postulated reaction mechanism for the bromoacetylation of 2 ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 363, 125], "ImageBB": [82, 131, 420, 347]}, "reactions": [{"reactants": [0, 12], "conditions": [14], "products": [2]}, {"reactants": [2], "conditions": [8], "products": [11, 7]}], "diagram_type": "tree"}, {"id": 1173, "width": 1356, "height": 1136, "file_name": "ol202027k-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1071.78, 305.86, 130.24, 56.29], "category_id": 2}, {"id": 1, "bbox": [502.65, 539.15, 270.66, 141.06], "category_id": 1}, {"id": 2, "bbox": [972.74, 879.59, 383.26, 215.66], "category_id": 1}, {"id": 3, "bbox": [326.28, 176.33, 266.59, 330.95], "category_id": 1}, {"id": 4, "bbox": [866.24, 427.25, 58.34, 54.93], "category_id": 3}, {"id": 5, "bbox": [830.29, 260.42, 250.98, 143.09], "category_id": 1}, {"id": 6, "bbox": [609.83, 16.95, 115.31, 60.36], "category_id": 2}, {"id": 7, "bbox": [349.34, 547.97, 117.36, 208.87], "category_id": 1}, {"id": 8, "bbox": [1136.9, 707.34, 58.33, 61.71], "category_id": 3}, {"id": 9, "bbox": [797.73, 0.0, 126.85, 208.88], "category_id": 1}, {"id": 10, "bbox": [681.05, 927.74, 143.13, 65.11], "category_id": 2}, {"id": 11, "bbox": [996.48, 45.44, 119.39, 58.32], "category_id": 2}, {"id": 12, "bbox": [253.02, 897.23, 125.49, 53.57], "category_id": 2}, {"id": 13, "bbox": [400.22, 875.53, 294.4, 215.66], "category_id": 1}, {"id": 14, "bbox": [1235.8, 766.4, 113.19, 58.64], "category_id": 2}, {"id": 15, "bbox": [0.0, 918.93, 61.73, 63.75], "category_id": 3}, {"id": 16, "bbox": [126.85, 925.71, 117.35, 57.65], "category_id": 2}, {"id": 17, "bbox": [553.52, 704.63, 63.77, 57.64], "category_id": 3}, {"id": 18, "bbox": [439.56, 6.1, 121.43, 145.81], "category_id": 1}, {"id": 19, "bbox": [972.06, 566.28, 383.94, 209.92], "category_id": 1}], "caption": "Scheme 2. Plausible Reaction Mechanism for the Copper-Cat- alyzed Soft Enolization Perkin Acyl-Mannich Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 402, 116], "ImageBB": [71, 127, 410, 411]}, "reactions": [{"reactants": [18], "conditions": [6], "products": [9, 11]}, {"reactants": [3], "conditions": [], "products": [5, 0]}, {"reactants": [5, 0], "conditions": [], "products": [3]}, {"reactants": [7, 1], "conditions": [], "products": [19]}, {"reactants": [19, 14], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [19, 14]}, {"reactants": [2], "conditions": [], "products": [13, 10]}, {"reactants": [13, 10], "conditions": [], "products": [2]}, {"reactants": [13], "conditions": [12], "products": [15, 16]}], "diagram_type": "tree"}, {"id": 764, "width": 1156, "height": 1316, "file_name": "jo961365y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [711.0, 1253.0, 66.0, 57.0], "category_id": 3}, {"id": 1, "bbox": [355.0, 190.0, 205.0, 92.0], "category_id": 1}, {"id": 2, "bbox": [155.0, 1264.0, 68.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [692.0, 727.0, 116.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [170.0, 726.0, 116.0, 57.0], "category_id": 3}, {"id": 5, "bbox": [461.0, 287.0, 26.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [721.0, 922.0, 251.0, 58.0], "category_id": 2}, {"id": 7, "bbox": [726.0, 868.0, 229.0, 57.0], "category_id": 2}, {"id": 8, "bbox": [10.0, 922.0, 238.0, 56.0], "category_id": 2}, {"id": 9, "bbox": [7.0, 867.0, 227.0, 54.0], "category_id": 2}, {"id": 10, "bbox": [0.0, 434.0, 241.0, 63.0], "category_id": 2}, {"id": 11, "bbox": [683.0, 432.0, 300.0, 69.0], "category_id": 2}, {"id": 12, "bbox": [356.0, 357.0, 258.0, 59.0], "category_id": 2}, {"id": 13, "bbox": [590.0, 539.0, 305.0, 183.0], "category_id": 1}, {"id": 14, "bbox": [42.6, 1076.0, 377.4, 186.0], "category_id": 1}, {"id": 15, "bbox": [86.3, 554.9, 305.7, 165.1], "category_id": 1}, {"id": 16, "bbox": [549.0, 1079.0, 395.0, 183.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [12, 10], "products": [15]}, {"reactants": [1], "conditions": [12, 11], "products": [13]}, {"reactants": [15], "conditions": [9, 8], "products": [14]}, {"reactants": [13], "conditions": [7, 6], "products": [16]}], "corefs": [[1, 5], [15, 4], [13, 3], [14, 2], [16, 0]], "caption": "Table 1. Comparison of the % of Enantiomeric Excess of    (R)- and (S)-6 in Asymmetric Dihydroxylation of 5 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 361, 772, 386], "ImageBB": [486, 20, 775, 349]}, "diagram_type": "tree"}, {"id": 203, "width": 1316, "height": 1416, "file_name": "op034198u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [706.5, 83.0, 593.0, 360.0], "category_id": 1}, {"id": 1, "bbox": [32.2, 1056.0, 590.6, 350.0], "category_id": 1}, {"id": 2, "bbox": [1119.0, 705.0, 192.0, 61.6], "category_id": 2}, {"id": 3, "bbox": [56.0, 651.0, 375.0, 119.0], "category_id": 2}, {"id": 4, "bbox": [744.0, 941.0, 59.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [17.0, 79.0, 363.0, 361.0], "category_id": 1}, {"id": 6, "bbox": [963.0, 400.0, 38.0, 57.0], "category_id": 3}, {"id": 7, "bbox": [191.0, 402.0, 42.0, 54.0], "category_id": 3}, {"id": 8, "bbox": [467.0, 472.0, 614.0, 468.0], "category_id": 1}, {"id": 9, "bbox": [494.0, 300.0, 113.0, 70.0], "category_id": 2}, {"id": 10, "bbox": [398.0, 159.0, 280.0, 113.0], "category_id": 2}, {"id": 11, "bbox": [282.0, 1370.0, 46.0, 44.0], "category_id": 3}, {"id": 12, "bbox": [1168.0, 806.0, 99.0, 54.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [10, 9], "products": [0]}, {"reactants": [0], "conditions": [3], "products": [8]}, {"reactants": [8], "conditions": [2, 12], "products": [1]}], "corefs": [[5, 7], [0, 6], [8, 4], [1, 11]], "caption": "Figure 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 128, 129, 142], "ImageBB": [74, 152, 403, 506]}, "diagram_type": "multiple"}, {"id": 814, "width": 1352, "height": 416, "file_name": "jo401608v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [85.0, 225.0, 60.0, 49.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 26.0, 272.0, 203.0], "category_id": 1}, {"id": 2, "bbox": [317.0, 106.0, 266.0, 66.0], "category_id": 1}, {"id": 3, "bbox": [1047.0, 1.0, 305.0, 274.0], "category_id": 1}, {"id": 4, "bbox": [591.0, 75.0, 452.0, 50.7], "category_id": 2}, {"id": 5, "bbox": [1108.0, 225.0, 56.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [16.0, 308.0, 1315.0, 108.0], "category_id": 4}, {"id": 7, "bbox": [432.0, 224.0, 49.0, 55.0], "category_id": 3}, {"id": 8, "bbox": [648.47, 144.78, 339.53, 99.93], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [4, 8], "products": [3]}], "corefs": [[1, 0], [2, 7], [3, 5]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 268, 110], "ImageBB": [82, 116, 420, 220]}, "diagram_type": "single"}, {"id": 750, "width": 1344, "height": 712, "file_name": "jo990938e-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [520.97, 49.86, 34.46, 40.54], "category_id": 3}, {"id": 1, "bbox": [665.0, 187.0, 92.0, 33.0], "category_id": 3}, {"id": 2, "bbox": [1011.0, 189.0, 93.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [5.0, 268.0, 1339.0, 444.0], "category_id": 4}, {"id": 4, "bbox": [148.0, 18.0, 248.0, 161.0], "category_id": 1}, {"id": 5, "bbox": [445.0, 5.0, 120.0, 113.0], "category_id": 1}, {"id": 6, "bbox": [601.0, 22.0, 249.0, 161.0], "category_id": 1}, {"id": 7, "bbox": [940.0, 21.0, 251.0, 161.0], "category_id": 1}, {"id": 8, "bbox": [238.0, 190.0, 27.0, 34.0], "category_id": 3}, {"id": 9, "bbox": [420.0, 62.0, 41.0, 32.0], "category_id": 2}, {"id": 10, "bbox": [387.0, 135.0, 199.0, 84.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [9, 5, 10], "products": [6, 7]}], "corefs": [[4, 8], [5, 0], [6, 1], [7, 2]], "caption": "Table 6. Additions of Transient Chiral Allenylindium  Reagents from Mesylate 7 to Representative Achiral                      Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [83, 64, 398, 101], "ImageBB": [74, 110, 410, 288]}, "diagram_type": "single"}, {"id": 532, "width": 1344, "height": 1988, "file_name": "jo000745n-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [662.0, 23.0, 408.0, 204.0], "category_id": 1}, {"id": 1, "bbox": [808.0, 232.0, 110.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [19.0, 293.0, 1325.0, 1695.0], "category_id": 4}, {"id": 3, "bbox": [409.0, 29.0, 172.0, 60.0], "category_id": 2}, {"id": 4, "bbox": [235.0, 84.0, 126.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [3], "products": [0]}], "corefs": [[0, 1]], "caption": "Table 3. Preparation of Protected Thioureas 28-41 by            Protection of Thioureas 17-27 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [81, 64, 402, 89], "ImageBB": [74, 90, 410, 587]}, "diagram_type": "single"}, {"id": 616, "width": 1352, "height": 744, "file_name": "acs.oprd.5b00278-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [721.04, 39.26, 70.95, 58.49], "category_id": 2}, {"id": 1, "bbox": [545.0, 40.0, 114.9, 58.0], "category_id": 2}, {"id": 2, "bbox": [450.0, 689.0, 179.0, 51.0], "category_id": 2}, {"id": 3, "bbox": [608.0, 600.0, 131.0, 58.0], "category_id": 2}, {"id": 4, "bbox": [620.0, 130.0, 115.0, 56.0], "category_id": 2}, {"id": 5, "bbox": [9.0, 281.0, 286.0, 237.0], "category_id": 1}, {"id": 6, "bbox": [877.0, 268.0, 128.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [312.0, 258.0, 200.0, 100.0], "category_id": 2}, {"id": 8, "bbox": [337.0, 382.0, 154.0, 84.0], "category_id": 2}, {"id": 9, "bbox": [1044.0, 274.0, 294.0, 244.0], "category_id": 1}, {"id": 10, "bbox": [520.0, 277.0, 291.0, 246.0], "category_id": 1}, {"id": 11, "bbox": [734.0, 691.0, 126.0, 47.0], "category_id": 2}, {"id": 12, "bbox": [843.0, 317.0, 190.0, 46.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [7], "products": [10]}, {"reactants": [10], "conditions": [8], "products": [5]}, {"reactants": [10], "conditions": [6, 12], "products": [9]}, {"reactants": [9, 0], "conditions": [4], "products": [5, 1]}, {"reactants": [5, 2], "conditions": [3], "products": [9, 11]}], "corefs": [], "caption": "Figure 2. Catalytic cycle of GOase including the reduction to the semioxidized inactive form. The active site is simpli\ufb01ed to only shown the copper-Tyr272 coordination. Adapted with permission from ref 8. Copyright 2003 American Chemical Society. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 785, 417, 840], "ImageBB": [82, 589, 420, 775]}, "diagram_type": "graph"}, {"id": 1227, "width": 1152, "height": 864, "file_name": "op010073i-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [684.05, 12.68, 156.75, 162.47], "category_id": 1}, {"id": 1, "bbox": [31.12, 629.15, 305.43, 165.93], "category_id": 1}, {"id": 2, "bbox": [96.82, 171.69, 40.91, 42.64], "category_id": 3}, {"id": 3, "bbox": [432.79, 640.1, 291.03, 62.22], "category_id": 2}, {"id": 4, "bbox": [306.01, 520.83, 42.07, 45.52], "category_id": 3}, {"id": 5, "bbox": [199.4, 372.19, 282.95, 131.36], "category_id": 1}, {"id": 6, "bbox": [560.15, 303.63, 406.86, 131.93], "category_id": 2}, {"id": 7, "bbox": [908.23, 137.12, 217.26, 53.01], "category_id": 2}, {"id": 8, "bbox": [147.53, 816.4, 42.65, 46.09], "category_id": 3}, {"id": 9, "bbox": [723.82, 195.89, 38.03, 42.63], "category_id": 3}, {"id": 10, "bbox": [945.69, 815.82, 38.03, 44.94], "category_id": 3}, {"id": 11, "bbox": [0.0, 17.86, 264.52, 131.94], "category_id": 1}, {"id": 12, "bbox": [303.7, 0.0, 312.35, 85.27], "category_id": 2}, {"id": 13, "bbox": [807.38, 614.75, 306.01, 169.38], "category_id": 1}, {"id": 14, "bbox": [907.08, 52.43, 218.41, 51.85], "category_id": 2}, {"id": 15, "bbox": [466.79, 750.14, 220.15, 57.61], "category_id": 2}], "caption": "Scheme 1. Literature synthesis of 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 417, 644, 431], "ImageBB": [464, 438, 752, 654]}, "reactions": [{"reactants": [11], "conditions": [12], "products": [0]}, {"reactants": [0], "conditions": [14, 7], "products": [5]}, {"reactants": [5], "conditions": [6], "products": [1]}, {"reactants": [1], "conditions": [3, 15], "products": [13]}], "diagram_type": "multiple"}, {"id": 298, "width": 1344, "height": 788, "file_name": "ol400025a-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [734.0, 514.1, 486.0, 238.9], "category_id": 1}, {"id": 1, "bbox": [126.1, 509.1, 248.9, 205.9], "category_id": 1}, {"id": 2, "bbox": [485.0, 166.1, 332.0, 241.9], "category_id": 1}, {"id": 3, "bbox": [123.0, 166.0, 339.9, 236.8], "category_id": 1}, {"id": 4, "bbox": [863.0, 206.1, 237.0, 153.8], "category_id": 1}, {"id": 5, "bbox": [421.0, 508.0, 296.0, 218.0], "category_id": 1}, {"id": 6, "bbox": [964.0, 752.0, 24.0, 27.0], "category_id": 3}, {"id": 7, "bbox": [556.0, 746.0, 35.0, 30.0], "category_id": 3}, {"id": 8, "bbox": [176.6, 415.97, 258.4, 60.5], "category_id": 3}, {"id": 9, "bbox": [515.4, 417.0, 261.6, 59.5], "category_id": 3}, {"id": 10, "bbox": [128.2, 723.0, 280.8, 58.5], "category_id": 3}, {"id": 11, "bbox": [861.4, 411.0, 252.6, 60.5], "category_id": 3}], "reactions": [], "corefs": [[3, 8], [2, 9], [4, 11], [1, 10], [5, 7], [0, 6]], "caption": "Figure 1. Squaramide catalysts.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 269, 604, 282], "ImageBB": [437, 59, 773, 256]}, "diagram_type": "multiple"}, {"id": 655, "width": 1348, "height": 328, "file_name": "ol403122a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [9.0, 251.0, 1318.0, 77.0], "category_id": 4}, {"id": 1, "bbox": [251.39, 143.36, 206.59, 49.07], "category_id": 2}, {"id": 2, "bbox": [287.1, 84.7, 139.8, 43.6], "category_id": 2}, {"id": 3, "bbox": [503.2, 75.4, 249.3, 121.5], "category_id": 1}, {"id": 4, "bbox": [788.6, 7.2, 216.1, 120.8], "category_id": 1}, {"id": 5, "bbox": [1001.9, 60.6, 292.1, 133.1], "category_id": 1}, {"id": 6, "bbox": [794.0, 139.0, 187.0, 76.4], "category_id": 2}, {"id": 7, "bbox": [53.0, 98.0, 158.0, 62.7], "category_id": 2}, {"id": 8, "bbox": [1121.53, 184.28, 54.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2, 1], "products": [3]}, {"reactants": [3], "conditions": [4, 6], "products": [5]}], "corefs": [[5, 8]], "caption": "Table 1. Initial Screening and Optimization of Conditions for S-Alkylation of DABSO-Generated Magnesium Sul\ufb01natesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 411, 140], "ImageBB": [82, 146, 419, 228]}, "diagram_type": "single"}, {"id": 1286, "width": 1412, "height": 956, "file_name": "op200086t-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [96.06, 808.34, 99.6, 59.3], "category_id": 3}, {"id": 1, "bbox": [1106.15, 195.55, 233.8, 61.42], "category_id": 3}, {"id": 2, "bbox": [16.95, 8.47, 261.35, 166.61], "category_id": 1}, {"id": 3, "bbox": [1123.81, 9.18, 215.44, 169.43], "category_id": 1}, {"id": 4, "bbox": [577.8, 808.34, 223.2, 89.66], "category_id": 3}, {"id": 5, "bbox": [562.26, 617.02, 268.41, 171.55], "category_id": 1}, {"id": 6, "bbox": [578.5, 0.0, 244.4, 170.14], "category_id": 1}, {"id": 7, "bbox": [0.0, 619.14, 290.31, 171.55], "category_id": 1}, {"id": 8, "bbox": [28.86, 392.55, 235.27, 49.35], "category_id": 3}, {"id": 9, "bbox": [497.1, 301.89, 389.06, 80.31], "category_id": 3}, {"id": 10, "bbox": [497.1, 397.14, 401.68, 80.34], "category_id": 3}, {"id": 11, "bbox": [300.2, 36.1, 204.84, 39.7], "category_id": 2}, {"id": 12, "bbox": [497.4, 202.6, 366.6, 81.7], "category_id": 3}, {"id": 13, "bbox": [29.9, 290.9, 229.2, 53.7], "category_id": 3}, {"id": 14, "bbox": [1109.68, 292.27, 245.81, 60.01], "category_id": 3}, {"id": 15, "bbox": [1111.9, 385.9, 244.0, 58.1], "category_id": 3}, {"id": 16, "bbox": [29.6, 195.55, 224.69, 60.01], "category_id": 3}, {"id": 17, "bbox": [868.11, 38.4, 208.37, 35.1], "category_id": 2}, {"id": 18, "bbox": [309.4, 645.5, 204.12, 45.2], "category_id": 2}], "caption": "Scheme 1. Substrates and products of bioreductions", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 572, 362, 587], "ImageBB": [71, 597, 424, 836]}, "reactions": [{"reactants": [2], "conditions": [11], "products": [6]}, {"reactants": [3], "conditions": [17], "products": [6]}, {"reactants": [7], "conditions": [18], "products": [5]}], "diagram_type": "multiple"}, {"id": 2, "width": 1356, "height": 688, "file_name": "jacs.5b12989-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.65, 262.6, 1338.95, 417.44], "category_id": 4}, {"id": 1, "bbox": [965.41, 10.46, 176.88, 169.79], "category_id": 1}, {"id": 2, "bbox": [624.51, 10.46, 176.0, 169.79], "category_id": 1}, {"id": 3, "bbox": [209.94, 14.9, 176.88, 165.3], "category_id": 1}, {"id": 4, "bbox": [399.03, 42.42, 119.18, 58.82], "category_id": 2}, {"id": 5, "bbox": [399.03, 122.3, 172.44, 62.38], "category_id": 2}, {"id": 6, "bbox": [815.38, 103.68, 134.27, 33.07], "category_id": 2}, {"id": 7, "bbox": [288.95, 206.65, 23.3, 29.52], "category_id": 3}, {"id": 8, "bbox": [707.96, 206.65, 25.97, 29.52], "category_id": 3}, {"id": 9, "bbox": [1051.52, 206.65, 49.94, 29.52], "category_id": 3}, {"id": 10, "bbox": [815.38, 35.32, 100.54, 59.7], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4, 5], "products": [2]}, {"reactants": [2], "conditions": [10, 6], "products": [1]}], "corefs": [[3, 7], [2, 8], [1, 9]], "caption": "Table 3. Mechanistic Insight from O-Alkyl Group Variance of the Oxyboration Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 784, 125], "ImageBB": [448, 131, 787, 303]}, "diagram_type": "single"}, {"id": 667, "width": 1276, "height": 2064, "file_name": "ol401909z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [58.0, 8.0, 254.4, 244.7], "category_id": 1}, {"id": 1, "bbox": [370.3, 70.0, 153.7, 116.1], "category_id": 1}, {"id": 2, "bbox": [7.0, 266.6, 1269.0, 1797.4], "category_id": 4}, {"id": 3, "bbox": [828.6, 2.7, 383.1, 249.3], "category_id": 1}, {"id": 4, "bbox": [410.0, 189.0, 41.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [534.0, 136.0, 274.0, 53.0], "category_id": 2}, {"id": 6, "bbox": [574.0, 78.0, 175.0, 58.0], "category_id": 2}, {"id": 7, "bbox": [1064.0, 194.0, 53.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [0, 1], "conditions": [6, 5], "products": [3]}], "corefs": [[1, 4], [3, 7]], "caption": "Table 3. Cu-Catalyzed Synthesis of Fullerooxazole from C60 and Amidea ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 303, 758, 330], "ImageBB": [445, 341, 764, 857]}, "diagram_type": "single"}, {"id": 383, "width": 1352, "height": 1680, "file_name": "op500224x-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1011.0, 698.0, 171.0, 91.0], "category_id": 3}, {"id": 1, "bbox": [123.0, 1165.0, 197.0, 99.0], "category_id": 3}, {"id": 2, "bbox": [548.0, 1170.0, 174.0, 90.0], "category_id": 3}, {"id": 3, "bbox": [234.0, 1591.0, 174.0, 89.0], "category_id": 3}, {"id": 4, "bbox": [972.0, 1173.0, 168.0, 86.0], "category_id": 3}, {"id": 5, "bbox": [543.0, 704.0, 191.0, 81.0], "category_id": 3}, {"id": 6, "bbox": [869.0, 1593.0, 175.0, 87.0], "category_id": 3}, {"id": 7, "bbox": [140.0, 703.0, 167.0, 82.0], "category_id": 3}, {"id": 8, "bbox": [895.0, 105.0, 83.0, 38.0], "category_id": 2}, {"id": 9, "bbox": [642.0, 306.0, 91.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [1166.0, 302.0, 80.0, 64.0], "category_id": 3}, {"id": 11, "bbox": [109.0, 306.0, 60.0, 60.0], "category_id": 3}, {"id": 12, "bbox": [9.0, 1277.0, 613.0, 302.0], "category_id": 1}, {"id": 13, "bbox": [661.0, 1275.0, 649.0, 302.0], "category_id": 1}, {"id": 14, "bbox": [1050.0, 7.0, 302.0, 295.0], "category_id": 1}, {"id": 15, "bbox": [5.0, 860.0, 463.0, 292.0], "category_id": 1}, {"id": 16, "bbox": [402.0, 848.0, 454.0, 313.0], "category_id": 1}, {"id": 17, "bbox": [459.0, 386.0, 369.0, 318.0], "category_id": 1}, {"id": 18, "bbox": [264.0, 93.0, 222.0, 58.0], "category_id": 2}, {"id": 19, "bbox": [864.0, 390.0, 473.0, 302.0], "category_id": 1}, {"id": 20, "bbox": [817.0, 801.0, 528.0, 398.0], "category_id": 1}, {"id": 21, "bbox": [537.0, 3.0, 306.0, 302.0], "category_id": 1}, {"id": 22, "bbox": [0.0, 6.0, 269.0, 295.0], "category_id": 1}, {"id": 23, "bbox": [828.0, 176.0, 219.0, 45.0], "category_id": 2}, {"id": 24, "bbox": [324.0, 175.0, 103.0, 94.0], "category_id": 2}, {"id": 25, "bbox": [34.0, 382.0, 405.0, 318.0], "category_id": 1}], "reactions": [{"reactants": [22], "conditions": [18, 24], "products": [21]}, {"reactants": [21], "conditions": [8, 23], "products": [14]}], "corefs": [[22, 11], [21, 9], [14, 10], [25, 7], [17, 5], [19, 0], [15, 1], [16, 2], [20, 4], [12, 3], [13, 6]], "caption": "Table 7. Thermodynamic protonation with carbon nucleophile addition products ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 734, 125], "ImageBB": [448, 131, 786, 551]}, "diagram_type": "single"}, {"id": 732, "width": 1348, "height": 800, "file_name": "ol016212y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [916.9, 2.1, 313.0, 241.7], "category_id": 1}, {"id": 1, "bbox": [13.0, 342.0, 1323.0, 458.0], "category_id": 4}, {"id": 2, "bbox": [516.0, 174.0, 239.9, 49.6], "category_id": 2}, {"id": 3, "bbox": [96.4, 7.3, 265.2, 236.5], "category_id": 1}, {"id": 4, "bbox": [428.0, 101.0, 428.0, 54.0], "category_id": 2}, {"id": 5, "bbox": [107.0, 261.0, 333.0, 56.0], "category_id": 2}, {"id": 6, "bbox": [924.0, 260.0, 339.0, 53.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4, 2], "products": [0]}], "corefs": [], "caption": "Table 2. Comparison of the Fiber-Supported Amino Alcohol P3 with 3 and 5 as Catalysts in the Addition of Et2Zn to PhCHO ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 276, 761, 320], "ImageBB": [439, 322, 776, 522]}, "diagram_type": "single"}, {"id": 1248, "width": 1064, "height": 568, "file_name": "op0340661-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [51.63, 470.26, 112.84, 44.15], "category_id": 2}, {"id": 1, "bbox": [661.07, 5.32, 240.06, 40.96], "category_id": 2}, {"id": 2, "bbox": [545.04, 195.23, 121.89, 41.5], "category_id": 2}, {"id": 3, "bbox": [220.89, 514.41, 36.73, 44.16], "category_id": 3}, {"id": 4, "bbox": [339.59, 155.33, 133.59, 48.95], "category_id": 2}, {"id": 5, "bbox": [446.04, 258.0, 116.03, 46.29], "category_id": 2}, {"id": 6, "bbox": [463.6, 48.41, 121.36, 47.34], "category_id": 2}, {"id": 7, "bbox": [714.83, 260.66, 316.17, 43.63], "category_id": 2}, {"id": 8, "bbox": [37.26, 244.17, 30.87, 40.96], "category_id": 3}, {"id": 9, "bbox": [661.07, 317.59, 217.17, 45.21], "category_id": 2}, {"id": 10, "bbox": [51.63, 397.91, 150.1, 47.35], "category_id": 2}, {"id": 11, "bbox": [6.92, 110.12, 297.0, 153.2], "category_id": 1}, {"id": 12, "bbox": [204.39, 335.67, 324.15, 226.62], "category_id": 1}, {"id": 13, "bbox": [690.35, 114.37, 370.46, 150.02], "category_id": 1}], "caption": "Scheme 7. pH dependence of ureide formation", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 664, 339, 678], "ImageBB": [109, 686, 375, 828]}, "reactions": [{"reactants": [11, 4], "conditions": [2], "products": [13]}, {"reactants": [13], "conditions": [10, 0], "products": [12]}], "diagram_type": "tree"}, {"id": 617, "width": 1356, "height": 432, "file_name": "acs.oprd.5b00251-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1156.0, 102.0, 86.0, 56.0], "category_id": 2}, {"id": 1, "bbox": [493.0, 60.0, 353.0, 53.0], "category_id": 2}, {"id": 2, "bbox": [113.0, 104.0, 100.0, 56.0], "category_id": 2}, {"id": 3, "bbox": [295.5, 51.91, 162.6, 125.78], "category_id": 1}, {"id": 4, "bbox": [875.0, 40.0, 214.0, 133.8], "category_id": 1}, {"id": 5, "bbox": [185.3, 229.0, 98.6, 177.9], "category_id": 1}, {"id": 6, "bbox": [1014.0, 234.1, 170.0, 149.9], "category_id": 1}, {"id": 7, "bbox": [805.1, 219.0, 133.9, 213.0], "category_id": 1}, {"id": 8, "bbox": [362.0, 236.5, 210.9, 131.1], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [1], "products": [4, 0]}, {"reactants": [5, 8], "conditions": [], "products": [7, 6]}], "corefs": [], "caption": "Figure 2. Reaction scheme for in situ epoxidation with peracetic acid.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 946, 784, 960], "ImageBB": [448, 829, 787, 937]}, "diagram_type": "multiple"}, {"id": 969, "width": 1904, "height": 1748, "file_name": "ja029499i-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1096.3, 1263.71, 62.86, 84.76], "category_id": 2}, {"id": 1, "bbox": [1026.77, 5.71, 279.07, 233.32], "category_id": 1}, {"id": 2, "bbox": [1249.65, 1132.29, 252.41, 63.81], "category_id": 2}, {"id": 3, "bbox": [1522.88, 522.55, 146.89, 58.76], "category_id": 2}, {"id": 4, "bbox": [1045.82, 554.24, 274.31, 120.95], "category_id": 1}, {"id": 5, "bbox": [1533.37, 1561.28, 107.02, 52.46], "category_id": 2}, {"id": 6, "bbox": [0.0, 1276.09, 284.79, 286.65], "category_id": 1}, {"id": 7, "bbox": [1621.11, 1289.42, 271.46, 218.08], "category_id": 1}, {"id": 8, "bbox": [454.33, 647.57, 278.12, 281.88], "category_id": 1}, {"id": 9, "bbox": [486.72, 999.92, 94.29, 60.0], "category_id": 2}, {"id": 10, "bbox": [1358.23, 1021.83, 96.2, 63.8], "category_id": 2}, {"id": 11, "bbox": [1250.6, 925.64, 289.55, 63.81], "category_id": 2}, {"id": 12, "bbox": [1621.11, 697.09, 282.89, 235.22], "category_id": 1}, {"id": 13, "bbox": [1235.36, 361.88, 86.68, 52.37], "category_id": 2}, {"id": 14, "bbox": [806.75, 392.35, 160.01, 99.99], "category_id": 2}, {"id": 15, "bbox": [928.66, 1034.21, 219.07, 63.8], "category_id": 2}, {"id": 16, "bbox": [1249.65, 787.56, 62.86, 50.47], "category_id": 2}, {"id": 17, "bbox": [1045.82, 1501.79, 280.98, 243.79], "category_id": 1}, {"id": 18, "bbox": [456.24, 1122.77, 282.88, 285.69], "category_id": 1}, {"id": 19, "bbox": [365.75, 1382.75, 120.01, 57.14], "category_id": 2}, {"id": 20, "bbox": [1248.1, 1382.4, 139.4, 62.4], "category_id": 2}], "caption": "Scheme 1. Proposed Reaction Topology for the Simultaneous Interconnected Unicyclic Rh and Bimetallic Rh-Mn CBER Hydroformylation Reactions ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 764, 88], "ImageBB": [187, 88, 663, 525]}, "reactions": [{"reactants": [1], "conditions": [13], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [8], "conditions": [], "products": [14, 4]}, {"reactants": [4, 3], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [4]}, {"reactants": [12], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [12]}, {"reactants": [7], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [7]}, {"reactants": [17], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [17]}, {"reactants": [18], "conditions": [9], "products": [8]}, {"reactants": [8], "conditions": [], 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[455.7, 963.0, 517.1, 215.5], "category_id": 1}, {"id": 39, "bbox": [8.0, 937.0, 323.0, 273.4], "category_id": 1}, {"id": 40, "bbox": [1.53, 8.05, 1350.47, 1359.17], "category_id": 4}, {"id": 41, "bbox": [975.9, 131.1, 339.3, 197.4], "category_id": 1}], "reactions": [{"reactants": [32], "conditions": [23, 22], "products": [29]}, {"reactants": [29], "conditions": [0, 28], "products": [41]}, {"reactants": [33], "conditions": [3, 4], "products": [31]}, {"reactants": [31], "conditions": [1, 2], "products": [30]}, {"reactants": [34], "conditions": [5, 6], "products": [35]}, {"reactants": [35], "conditions": [8, 7], "products": [36]}, {"reactants": [39], "conditions": [10, 11], "products": [38]}, {"reactants": [38], "conditions": [9, 12], "products": [37]}], "corefs": [[32, 27], [29, 26], [41, 25], [33, 14], [31, 13], [30, 24], [34, 18], [35, 20], [36, 19], [39, 17], [38, 16], [37, 15]], "caption": "Table 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 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Synthesis of [\u03ba4-Tptm]ZnF", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 332, 661, 349], "ImageBB": [453, 355, 782, 539]}, "reactions": [{"reactants": [1], "conditions": [3], "products": [6]}, {"reactants": [6], "conditions": [2], "products": [1]}, {"reactants": [4], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [5], "products": [0]}, {"reactants": [0], "conditions": [7], "products": [6]}], "diagram_type": "tree"}, {"id": 761, "width": 1348, "height": 492, "file_name": "jo971595s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [55.0, 266.0, 1231.0, 226.0], "category_id": 4}, {"id": 1, "bbox": [132.0, 180.0, 60.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [669.0, 8.0, 318.0, 145.0], "category_id": 1}, {"id": 3, "bbox": [1028.0, 9.0, 289.0, 153.0], "category_id": 1}, {"id": 4, "bbox": [31.0, 4.0, 333.0, 144.0], "category_id": 1}, {"id": 5, "bbox": [765.0, 183.0, 63.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [1138.0, 187.0, 62.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [457.0, 39.0, 50.0, 38.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [7], "products": [2, 3]}], "corefs": [[4, 1], [2, 5], [3, 6]], "caption": "Table 2. Synperiplanar versus Antiperiplanar Attack in                the Radical Reductiona ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [441, 49, 772, 74], "ImageBB": [438, 79, 775, 202]}, "diagram_type": "single"}, {"id": 1364, "width": 1356, "height": 780, "file_name": "op900265h-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [832.32, 737.13, 145.17, 42.05], "category_id": 3}, {"id": 1, "bbox": [963.92, 2.71, 388.01, 289.57], "category_id": 1}, {"id": 2, "bbox": [0.0, 2.71, 482.3, 291.6], "category_id": 1}, {"id": 3, "bbox": [548.1, 368.91, 771.27, 388.57], "category_id": 1}, {"id": 4, "bbox": [490.44, 2.71, 454.49, 291.6], "category_id": 1}, {"id": 5, "bbox": [668.84, 309.91, 34.6, 35.26], "category_id": 3}, {"id": 6, "bbox": [1145.71, 308.55, 37.31, 38.66], "category_id": 3}, {"id": 7, "bbox": [202.15, 308.55, 32.56, 37.3], "category_id": 3}], "caption": "Scheme 1. Synthetic route to S-0139 4 from oleanolic acid 1", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 315, 759, 329], "ImageBB": [424, 334, 763, 529]}, "reactions": [{"reactants": [2], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}], "diagram_type": "multiple"}, {"id": 435, "width": 1348, "height": 440, "file_name": "op300031r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [423.8, 90.0, 170.2, 51.9], "category_id": 2}, {"id": 1, "bbox": [77.0, 4.0, 274.0, 290.0], "category_id": 1}, {"id": 2, "bbox": [1.0, 365.0, 1347.0, 75.0], "category_id": 4}, {"id": 3, "bbox": [653.0, 8.0, 300.0, 279.0], "category_id": 1}, {"id": 4, "bbox": [666.0, 293.0, 269.0, 48.0], "category_id": 2}, {"id": 5, "bbox": [990.0, 291.0, 268.0, 42.0], "category_id": 2}, {"id": 6, "bbox": [972.0, 9.0, 305.0, 281.0], "category_id": 1}, {"id": 7, "bbox": [394.45, 157.99, 240.93, 51.84], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [0, 7], "products": [3, 6]}], "corefs": [], "caption": "Table 1. Screening of MeMgBr Addition to Cyclobutanone Substrates ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 782, 125], "ImageBB": [449, 131, 786, 241]}, "diagram_type": "single"}, {"id": 966, "width": 968, "height": 1116, "file_name": "ja0176346-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 1113.77, 7.26, 2.23], "category_id": 3}, {"id": 1, "bbox": [24.01, 474.54, 252.39, 178.65], "category_id": 1}, {"id": 2, "bbox": [785.65, 1056.26, 53.6, 44.11], "category_id": 3}, {"id": 3, "bbox": [0.0, 832.39, 284.78, 231.69], "category_id": 1}, {"id": 4, "bbox": [341.17, 2.23, 237.32, 187.58], "category_id": 1}, {"id": 5, "bbox": [454.53, 419.27, 52.48, 40.19], "category_id": 3}, {"id": 6, "bbox": [687.93, 525.34, 245.69, 121.15], "category_id": 1}, {"id": 7, "bbox": [357.37, 473.42, 242.9, 305.38], "category_id": 1}, {"id": 8, "bbox": [773.92, 184.23, 78.74, 44.11], "category_id": 3}, {"id": 9, "bbox": [357.37, 244.53, 242.9, 173.06], "category_id": 1}, {"id": 10, "bbox": [63.66, 85.97, 142.94, 47.46], "category_id": 2}, {"id": 11, "bbox": [118.94, 648.16, 53.6, 37.97], "category_id": 3}, {"id": 12, "bbox": [128.99, 133.43, 50.25, 41.31], "category_id": 3}, {"id": 13, "bbox": [668.83, 242.53, 28.14, 32.15], "category_id": 2}, {"id": 14, "bbox": [0.0, 1113.77, 7.26, 2.23], "category_id": 3}, {"id": 15, "bbox": [441.68, 186.47, 73.15, 41.87], "category_id": 3}, {"id": 16, "bbox": [786.21, 646.49, 35.73, 39.64], "category_id": 3}, {"id": 17, "bbox": [262.44, 60.85, 34.06, 32.94], "category_id": 2}, {"id": 18, "bbox": [339.5, 423.73, 32.94, 42.99], "category_id": 3}, {"id": 19, "bbox": [623.72, 63.64, 34.06, 42.43], "category_id": 2}, {"id": 20, "bbox": [496.96, 899.39, 96.05, 104.95], "category_id": 1}, {"id": 21, "bbox": [686.26, 844.12, 246.8, 152.97], "category_id": 1}, {"id": 22, "bbox": [454.53, 783.82, 46.34, 35.73], "category_id": 3}, {"id": 23, "bbox": [0.0, 1113.77, 968.0, 2.23], "category_id": 2}, {"id": 24, "bbox": [127.87, 1069.1, 54.16, 43.55], "category_id": 3}, {"id": 25, "bbox": [579.05, 434.9, 30.71, 34.61], "category_id": 3}, {"id": 26, "bbox": [668.95, 0.0, 242.34, 184.23], "category_id": 1}, {"id": 27, "bbox": [357.37, 894.36, 117.82, 172.51], "category_id": 1}], "caption": "Scheme 3 a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 338, 132, 351], "ImageBB": [122, 351, 364, 630]}, "reactions": [{"reactants": [10], "conditions": [17], "products": [4]}, {"reactants": [4], "conditions": [19], "products": [26]}, {"reactants": [26], "conditions": [13], "products": [9]}, {"reactants": [9], "conditions": [18], "products": [1, 7]}, {"reactants": [9], "conditions": [25], "products": [6]}, {"reactants": [3], "conditions": [], "products": [1]}, {"reactants": [27], "conditions": [], "products": [3]}, {"reactants": [20], "conditions": [], "products": [21]}], "diagram_type": "graph"}, {"id": 907, "width": 1352, "height": 420, "file_name": "acs.joc.5b00685-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [993.3, 239.0, 229.7, 33.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 0.0, 437.7, 218.0], "category_id": 1}, {"id": 2, "bbox": [39.8, 239.0, 358.2, 34.2], "category_id": 3}, {"id": 3, "bbox": [478.0, 129.0, 139.0, 42.0], "category_id": 2}, {"id": 4, "bbox": [479.0, 84.0, 95.0, 33.0], "category_id": 2}, {"id": 5, "bbox": [467.0, 17.0, 128.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [860.0, 2.0, 492.0, 243.0], "category_id": 1}, {"id": 7, "bbox": [606.0, 1.0, 215.0, 86.5], "category_id": 1}, {"id": 8, "bbox": [9.0, 301.0, 1343.0, 118.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [5, 7, 4, 3], "products": [6]}], "corefs": [[1, 2], [6, 0]], "caption": "Table 2. Optimization of the Rapid Conversion of Thiamine to Fursultiamine by Disul\ufb01de Formation ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 416, 784, 446], "ImageBB": [448, 453, 786, 558]}, "diagram_type": "single"}, {"id": 329, "width": 1344, "height": 696, "file_name": "ol300842d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [107.0, 39.2, 430.2, 201.0], "category_id": 1}, {"id": 1, "bbox": [579.0, 66.5, 263.0, 43.2], "category_id": 2}, {"id": 2, "bbox": [616.0, 175.0, 210.0, 50.0], "category_id": 2}, {"id": 3, "bbox": [213.0, 228.0, 54.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [1014.0, 228.0, 52.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [671.0, 123.0, 93.0, 45.0], "category_id": 2}, {"id": 6, "bbox": [6.0, 287.0, 1338.0, 409.0], "category_id": 4}, {"id": 7, "bbox": [911.0, 3.0, 334.0, 237.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1, 5, 2], "products": [7]}], "corefs": [[0, 3], [7, 4]], "caption": "Table 1. Optimization of Reaction Condition", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 312, 100], "ImageBB": [71, 112, 407, 286]}, "diagram_type": "single"}, {"id": 44, "width": 1320, "height": 696, "file_name": "ja410533y-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [669.97, 22.52, 289.73, 80.68], "category_id": 2}, {"id": 1, "bbox": [1094.04, 3.6, 190.15, 172.23], "category_id": 1}, {"id": 2, "bbox": [372.33, 51.38, 196.11, 136.39], "category_id": 1}, {"id": 3, "bbox": [90.61, 45.41, 138.38, 130.42], "category_id": 1}, {"id": 4, "bbox": [396.22, 256.45, 165.25, 37.84], "category_id": 2}, {"id": 5, "bbox": [462.91, 212.65, 32.86, 32.86], "category_id": 3}, {"id": 6, "bbox": [1104.0, 212.65, 176.21, 39.83], "category_id": 3}, {"id": 7, "bbox": [78.66, 212.65, 178.2, 39.83], "category_id": 3}, {"id": 8, "bbox": [83.64, 255.46, 168.24, 38.83], "category_id": 2}, {"id": 9, "bbox": [8.98, 303.24, 1302.12, 386.25], "category_id": 4}, {"id": 10, "bbox": [642.1, 131.02, 342.45, 121.46], "category_id": 2}], "reactions": [{"reactants": [3, 2], "conditions": [0, 10], "products": [1]}], "corefs": [[3, 7], [2, 5], [1, 6]], "caption": "Table 5. Hydrohydroxyalkylation of Hydroxyl-Substituted Methacrylate 2i with Diols 1b, 1f, 1j, and 1l to Form \u03b1-exo- Methylene-\u03b3-butyrolactones 5b, 5f, 5j, and 5la ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 536, 784, 581], "ImageBB": [452, 588, 782, 762]}, "diagram_type": "single"}, {"id": 565, "width": 1348, "height": 376, "file_name": "acs.orglett.5b01385-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [13.0, 304.0, 1335.0, 66.0], "category_id": 4}, {"id": 1, "bbox": [1063.0, 212.0, 62.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [564.0, 162.0, 307.0, 87.0], "category_id": 2}, {"id": 3, "bbox": [115.0, 219.0, 166.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [343.0, 220.0, 156.0, 56.0], "category_id": 2}, {"id": 5, "bbox": [129.5, 70.3, 135.4, 115.5], "category_id": 1}, {"id": 6, "bbox": [537.2, 2.93, 355.78, 126.0], "category_id": 2}, {"id": 7, "bbox": [369.2, 55.0, 96.7, 158.0], "category_id": 1}, {"id": 8, "bbox": [969.3, 50.1, 254.5, 159.9], "category_id": 1}], "reactions": [{"reactants": [5, 7], "conditions": [6, 2], "products": [8]}], "corefs": [[8, 1]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 738, 110], "ImageBB": [449, 116, 786, 210]}, "diagram_type": "single"}, {"id": 992, "width": 1352, "height": 1116, "file_name": "ja3058138-Scheme-c11.png", "license": 0, "bboxes": [{"id": 0, "bbox": [625.61, 330.82, 229.28, 89.98], "category_id": 2}, {"id": 1, "bbox": [4.73, 1015.56, 755.74, 61.62], "category_id": 2}, {"id": 2, "bbox": [144.74, 939.03, 50.72, 41.94], "category_id": 3}, {"id": 3, "bbox": [1011.13, 564.23, 50.04, 37.88], "category_id": 3}, {"id": 4, "bbox": [735.18, 692.09, 252.95, 95.39], "category_id": 2}, {"id": 5, "bbox": [1100.4, 181.31, 45.99, 35.86], "category_id": 3}, {"id": 6, "bbox": [580.3, 2.71, 300.29, 86.59], "category_id": 2}, {"id": 7, "bbox": [238.75, 31.12, 299.62, 112.98], "category_id": 1}, {"id": 8, "bbox": [1166.01, 932.26, 52.08, 44.65], "category_id": 3}, {"id": 9, "bbox": [96.04, 443.81, 253.63, 132.6], "category_id": 2}, {"id": 10, "bbox": [646.58, 767.86, 50.72, 48.72], "category_id": 3}, {"id": 11, "bbox": [588.41, 113.66, 283.39, 135.98], "category_id": 2}, {"id": 12, "bbox": [497.11, 566.26, 49.37, 35.85], "category_id": 3}, {"id": 13, "bbox": [263.1, 697.51, 334.11, 92.0], "category_id": 2}, {"id": 14, "bbox": [10.15, 650.82, 219.8, 321.36], "category_id": 1}, {"id": 15, "bbox": [373.34, 274.0, 219.13, 301.05], "category_id": 1}, {"id": 16, "bbox": [10.82, 406.6, 52.08, 48.03], "category_id": 3}, {"id": 17, "bbox": [263.1, 803.72, 274.59, 91.33], "category_id": 2}, {"id": 18, "bbox": [645.23, 443.81, 202.22, 131.24], "category_id": 2}, {"id": 19, "bbox": [746.68, 804.4, 235.36, 54.12], "category_id": 2}, {"id": 20, "bbox": [877.21, 274.0, 221.84, 303.08], "category_id": 1}, {"id": 21, "bbox": [941.46, 10.15, 388.22, 180.63], "category_id": 1}, {"id": 22, "bbox": [1038.18, 640.68, 300.97, 286.85], "category_id": 1}, {"id": 23, "bbox": [1132.87, 328.79, 144.73, 92.01], "category_id": 2}, {"id": 24, "bbox": [96.04, 330.82, 256.33, 89.98], "category_id": 2}, {"id": 25, "bbox": [10.82, 24.36, 172.47, 165.75], "category_id": 1}, {"id": 26, "bbox": [353.72, 163.04, 48.02, 39.24], "category_id": 3}, {"id": 27, "bbox": [1132.87, 442.45, 159.61, 101.48], "category_id": 2}], "caption": "Scheme 11. Synthesis of Key Aminoalcohol 11a", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 303, 352, 324], "ImageBB": [82, 330, 420, 609]}, "reactions": [{"reactants": [25, 7], "conditions": [6, 11], "products": [21]}, {"reactants": [16], "conditions": [24, 9], "products": [15]}, {"reactants": [15], "conditions": [0, 18], "products": [20]}, {"reactants": [20], "conditions": [23, 27], "products": [14]}, {"reactants": [14], "conditions": [13, 17], "products": [10]}, {"reactants": [10], "conditions": [4, 19], "products": [22]}], "diagram_type": "multiple"}, {"id": 1214, "width": 1348, "height": 888, "file_name": "ol802669r-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [56.64, 462.3, 294.02, 330.83], "category_id": 1}, {"id": 1, "bbox": [1098.5, 711.52, 39.11, 43.17], "category_id": 3}, {"id": 2, "bbox": [463.94, 496.38, 333.13, 333.84], "category_id": 1}, {"id": 3, "bbox": [574.54, 678.47, 37.76, 46.54], "category_id": 3}, {"id": 4, "bbox": [191.51, 772.22, 33.72, 43.16], "category_id": 3}, {"id": 5, "bbox": [596.11, 32.37, 353.36, 101.84], "category_id": 2}, {"id": 6, "bbox": [621.74, 156.47, 302.78, 92.39], "category_id": 2}, {"id": 7, "bbox": [364.82, 254.26, 42.48, 42.49], "category_id": 3}, {"id": 8, "bbox": [956.88, 468.73, 334.48, 335.19], "category_id": 1}, {"id": 9, "bbox": [975.09, 0.0, 293.34, 306.86], "category_id": 1}, {"id": 10, "bbox": [159.82, 20.91, 422.13, 246.84], "category_id": 1}, {"id": 11, "bbox": [1080.29, 223.24, 37.76, 49.9], "category_id": 3}], "caption": "Scheme 3. Reaction with Diaminoacetal 5", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [483, 74, 702, 89], "ImageBB": [425, 96, 762, 318]}, "reactions": [{"reactants": [10], "conditions": [5, 6], "products": [9]}, {"reactants": [10], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [2]}, {"reactants": [8], "conditions": [], "products": [9]}], "diagram_type": "graph"}, {"id": 420, "width": 2820, "height": 2032, "file_name": "op300363s-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2154.0, 260.0, 71.0, 52.0], "category_id": 3}, {"id": 1, "bbox": [1771.0, 263.0, 67.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [1400.0, 260.0, 52.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [1757.0, 873.1, 603.8, 476.5], "category_id": 1}, {"id": 4, "bbox": [518.72, 262.72, 59.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [947.17, 261.45, 75.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [2054.0, 29.0, 330.0, 275.1], "category_id": 1}, {"id": 7, "bbox": [1637.9, 7.0, 312.2, 302.6], "category_id": 1}, {"id": 8, "bbox": [1248.1, 0.0, 303.9, 304.1], "category_id": 1}, {"id": 9, "bbox": [862.2, 15.4, 298.4, 228.3], "category_id": 1}, {"id": 10, "bbox": [439.3, 38.5, 268.3, 202.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [], "products": [7]}, {"reactants": [8], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10]}, {"reactants": [7], "conditions": [], "products": [6]}], "corefs": [[10, 4], [9, 5], [8, 2], [7, 1], [6, 0]], "caption": "Figure 5. 1H NMR analysis of a sample containing dienylimine 9a after extraction of the reaction mixture with sat. NaHCO3/EtOAc. Conditions: 1 mmol 2-ethylphenylhydrazine hydrochloride 1a, 1 equiv DHF, 1.5 mL MeOH/H2O 2:1; 20% H2SO4; 5 min reaction temperature at 130 \u00b0C. ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 631, 784, 662], "ImageBB": [82, 116, 787, 624]}, "diagram_type": "single"}, {"id": 518, "width": 1252, "height": 928, "file_name": "jo011082s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [364.0, 788.0, 104.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [842.0, 404.0, 44.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [482.0, 513.0, 45.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [106.0, 387.0, 49.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [308.0, 867.0, 703.0, 61.0], "category_id": 2}, {"id": 5, "bbox": [823.0, 777.0, 182.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [388.2, 315.3, 274.1, 183.0], "category_id": 1}, {"id": 7, "bbox": [2.0, 224.5, 356.9, 194.9], "category_id": 1}, {"id": 8, "bbox": [740.3, 572.0, 274.9, 199.0], "category_id": 1}, {"id": 9, "bbox": [686.4, 201.4, 339.5, 173.8], "category_id": 1}, {"id": 10, "bbox": [259.2, 582.7, 321.8, 193.2], "category_id": 1}, {"id": 11, "bbox": [375.0, 238.0, 145.0, 57.0], "category_id": 2}, {"id": 12, "bbox": [367.0, 349.0, 50.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [11, 12, 6], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10, 8]}], "corefs": [[7, 3], [6, 2], [9, 1], [10, 0], [8, 5]], "caption": "Table 2. 1,3-Dienes 10 and 11", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [520, 279, 695, 291], "ImageBB": [464, 35, 777, 267]}, "diagram_type": "multiple"}, {"id": 801, "width": 1352, "height": 912, "file_name": "jo501006u-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [455.0, 39.8, 352.4, 54.1], "category_id": 2}, {"id": 1, "bbox": [569.0, 180.3, 270.0, 50.6], "category_id": 2}, {"id": 2, "bbox": [235.0, 135.0, 204.0, 75.0], "category_id": 1}, {"id": 3, "bbox": [3.0, 237.0, 1349.0, 675.0], "category_id": 4}, {"id": 4, "bbox": [454.72, 107.52, 249.39, 52.57], "category_id": 1}, {"id": 5, "bbox": [1206.57, 150.31, 140.59, 45.24], "category_id": 2}, {"id": 6, "bbox": [701.67, 106.3, 256.73, 57.46], "category_id": 2}, {"id": 7, "bbox": [9.0, 135.0, 172.0, 73.0], "category_id": 1}, {"id": 8, "bbox": [938.0, 151.0, 230.6, 45.0], "category_id": 1}], "reactions": [{"reactants": [7, 2], "conditions": [0, 4, 6, 1], "products": [8, 5]}], "corefs": [], "caption": "Figure 3. Plots of the yields of the cross-coupling product (\u25a0, left axis) and nonane (\u25c6, right axis) against the amount of phenylpropyne used at 3 h reaction time. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 749, 417, 793], "ImageBB": [82, 514, 420, 742]}, "diagram_type": "single"}, {"id": 858, "width": 1356, "height": 1020, "file_name": "jo200480h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.88, 128.53, 138.1, 46.48], "category_id": 3}, {"id": 1, "bbox": [274.7, 31.0, 537.6, 110.9], "category_id": 1}, {"id": 2, "bbox": [50.4, 366.0, 177.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [427.0, 278.0, 338.8, 58.2], "category_id": 2}, {"id": 4, "bbox": [4.7, 140.6, 302.5, 213.9], "category_id": 1}, {"id": 5, "bbox": [859.0, 3.0, 497.0, 370.0], "category_id": 1}, {"id": 6, "bbox": [266.0, 164.0, 591.0, 112.0], "category_id": 2}, {"id": 7, "bbox": [960.0, 372.0, 153.0, 39.0], "category_id": 3}, {"id": 8, "bbox": [4.0, 494.0, 1352.0, 526.0], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [1, 6, 3], "products": [5]}], "corefs": [[4, 2], [1, 0], [5, 7]], "caption": "Table 3. Heteroannulation Reaction between 4-Acetamido- 3-iodopyridines 1, 4, and 6 and Symmetrical Diarylacetylenes 16 18 ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 771, 137], "ImageBB": [436, 148, 775, 403]}, "diagram_type": "single"}, {"id": 499, "width": 1356, "height": 2660, "file_name": "ol053021c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [889.0, 1.0, 346.0, 265.0], "category_id": 1}, {"id": 1, "bbox": [468.0, 80.4, 363.0, 49.6], "category_id": 2}, {"id": 2, "bbox": [15.0, 285.0, 1334.0, 2375.0], "category_id": 4}, {"id": 3, "bbox": [477.0, 174.0, 364.0, 92.0], "category_id": 2}, {"id": 4, "bbox": [617.28, 25.02, 74.88, 57.06], "category_id": 3}, {"id": 5, "bbox": [84.0, 0.0, 359.0, 267.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [4, 1, 3], "products": [0]}], "corefs": [], "caption": "Table 1. Substrate Scope of the Reactiona,b", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 242, 305, 256], "ImageBB": [73, 256, 412, 921]}, "diagram_type": "single"}, {"id": 986, "width": 1356, "height": 980, "file_name": "ja2031294-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [629.5, 206.3, 69.87, 49.53], "category_id": 2}, {"id": 1, "bbox": [12.89, 447.2, 61.05, 68.54], "category_id": 3}, {"id": 2, "bbox": [9.41, 2.35, 65.69, 59.15], "category_id": 3}, {"id": 3, "bbox": [1183.02, 118.76, 172.98, 244.97], "category_id": 1}, {"id": 4, "bbox": [643.74, 669.1, 113.29, 51.58], "category_id": 2}, {"id": 5, "bbox": [629.5, 745.79, 160.09, 58.36], "category_id": 2}, {"id": 6, "bbox": [455.84, 698.28, 100.4, 63.11], "category_id": 2}, {"id": 7, "bbox": [422.61, 223.26, 145.16, 69.22], "category_id": 2}, {"id": 8, "bbox": [1176.92, 582.24, 168.9, 239.55], "category_id": 1}, {"id": 9, "bbox": [757.03, 156.76, 371.73, 203.58], "category_id": 1}, {"id": 10, "bbox": [841.82, 619.57, 292.36, 201.54], "category_id": 1}, {"id": 11, "bbox": [0.0, 456.02, 356.81, 386.81], "category_id": 1}, {"id": 12, "bbox": [0.0, 0.0, 362.23, 389.52], "category_id": 1}], "caption": "Scheme 1. UP-Catalyzed (A) Phosphorolysis and (B) Arsenolysis of Uridine ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 369, 122], "ImageBB": [71, 133, 410, 378]}, "reactions": [{"reactants": [12, 7], "conditions": [0], "products": [9, 3]}, {"reactants": [9, 3], "conditions": [], "products": [7, 12]}, {"reactants": [11, 6], "conditions": [4, 5], "products": [10, 8]}], "diagram_type": "multiple"}, {"id": 561, "width": 1352, "height": 776, "file_name": "acs.orglett.5b01754-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1192.0, 218.0, 77.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [339.0, 210.0, 74.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [6.0, 293.0, 1346.0, 483.0], "category_id": 4}, {"id": 3, "bbox": [476.0, 99.0, 391.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [479.0, 174.0, 391.0, 57.7], "category_id": 2}, {"id": 5, "bbox": [943.7, 6.6, 318.5, 262.9], "category_id": 1}, {"id": 6, "bbox": [85.3, 3.9, 322.8, 263.5], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 4], "products": [5]}], "corefs": [[6, 1], [5, 0]], "caption": "Table 3. Proposed Direct Interconversion of BINOL and H8-BINOL-Based Chiral Br\u00f8nsted Acid ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 387, 771, 417], "ImageBB": [448, 424, 786, 618]}, "diagram_type": "single"}, {"id": 91, "width": 1344, "height": 1248, "file_name": "ja053650h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [880.34, 53.93, 312.11, 201.68], "category_id": 1}, {"id": 1, "bbox": [541.49, 144.7, 225.88, 36.8], "category_id": 2}, {"id": 2, "bbox": [558.12, 76.62, 186.56, 36.78], "category_id": 2}, {"id": 3, "bbox": [149.69, 7.04, 289.42, 204.7], "category_id": 1}, {"id": 4, "bbox": [2.95, 276.3, 1336.23, 964.1], "category_id": 4}], "reactions": [{"reactants": [3], "conditions": [2, 1], "products": [0]}], "corefs": [], "caption": "Table 1. Intramolecular Carbonylation of 2-(2-Iodophenoxy)aniline (3, R1 ) R2 ) H, X ) I) with G1-Pd under Different Reaction Conditionsa ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 406, 100], "ImageBB": [74, 102, 410, 414]}, "diagram_type": "single"}, {"id": 75, "width": 1356, "height": 1136, "file_name": "ja2014746-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [269.68, 430.42, 20.43, 28.16], "category_id": 3}, {"id": 1, "bbox": [37.04, 5.39, 527.1, 139.56], "category_id": 1}, {"id": 2, "bbox": [6.0, 631.97, 640.29, 481.94], "category_id": 1}, {"id": 3, "bbox": [668.32, 622.33, 680.23, 506.73], "category_id": 1}, {"id": 4, "bbox": [650.89, 32.01, 86.31, 37.5], "category_id": 2}, {"id": 5, "bbox": [603.56, 88.22, 176.54, 62.64], "category_id": 2}, {"id": 6, "bbox": [631.67, 287.91, 86.31, 36.02], "category_id": 2}, {"id": 7, "bbox": [22.25, 240.57, 518.23, 160.27], "category_id": 1}, {"id": 8, "bbox": [821.0, 5.39, 501.96, 135.12], "category_id": 1}, {"id": 9, "bbox": [806.21, 234.66, 504.91, 163.23], "category_id": 1}, {"id": 10, "bbox": [584.33, 344.11, 175.06, 62.65], "category_id": 2}, {"id": 11, "bbox": [288.5, 148.86, 16.79, 30.11], "category_id": 3}, {"id": 12, "bbox": [1047.81, 429.83, 20.43, 26.37], "category_id": 3}, {"id": 13, "bbox": [1066.24, 151.03, 20.43, 27.56], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [8]}, {"reactants": [7], "conditions": [6, 10], "products": [9]}], "corefs": [[1, 11], [8, 13], [7, 0], [9, 12]], "caption": "Figure 1. (Left) ORTEP drawing of 2 (50% probability level). One of the tert-butyl groups on Si3 is disordered, and the minor contribution (occupancy factor 0.299) and hydrogen atoms are omitted for clarity. # indicates the following symmetry transformation:  x,  y \u00fe 1,  z. Selected bond lengths (\u00c5) and angles (deg): Si1 Si2 = 2.3675(6), Si1 Si3 = 2.3737(6), Si1 C1 = 1.8174(14), C1 C2 = 1.423(2), C1 C3# = 1.422(2), C2 C3 = 1.3700(19). Si2 Si1 Si3 = 122.86(2), Si2 Si1 C1 = 117.52(5), Si3 Si1 C1 = 119.58(5), Si1 C1 C2 = 120.66(11), Si1 C1 C3# = 124.39(11), C2 C1 C3# = 114.94(12), C1 C2 C3 = 122.78(13), C2 C3 C1# = 122.29(13). (Right) ORTEP drawing of 4 (50% probability level). Hydrogen atoms are omitted for clarity. # indicates the following symmetry transformation:  x \u00fe 1/2,  y \u00fe 1/2, z. Selected bond lengths (\u00c5) and angles (deg): Si1 Si2 = 2.3554(14), Si1 Si3 = 2.3524(14), Si1 C2 = 1.9108(19), C1 C2 = 1.387(3), C1 C2# = 1.387(3), C2 C3 = 1.395(5), C3 C4 = 1.386(4), C4 C3# = 1.386(4). Si2 Si1 Si3 = 122.21(5), Si2 Si1 C2 = 117.15(5), Si3 Si1 C2 = 119.29(5), C2 C1 C2# = 123.2(4), Si1 C2 C1 = 120.8(3), Si1 C2 C3 = 121.73(17), C1 C2 C3 = 117.5(2), C2 C3 C4 = 121.0(3), C3 C4 C3# = 119.7(4). ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 430, 405, 707], "ImageBB": [71, 133, 410, 417]}, "diagram_type": "multiple"}, {"id": 1007, "width": 1252, "height": 1476, "file_name": "ja9612413-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [602.35, 2.95, 458.41, 335.96], "category_id": 1}, {"id": 1, "bbox": [0.0, 1097.22, 343.25, 59.07], "category_id": 1}, {"id": 2, "bbox": [808.3, 342.6, 347.68, 53.17], "category_id": 2}, {"id": 3, "bbox": [583.9, 523.5, 437.0, 353.68], "category_id": 1}, {"id": 4, "bbox": [844.47, 461.48, 225.88, 63.5], "category_id": 2}, {"id": 5, "bbox": [577.25, 1138.57, 494.58, 337.43], "category_id": 1}, {"id": 6, "bbox": [367.61, 965.79, 284.2, 51.68], "category_id": 2}, {"id": 7, "bbox": [86.37, 377.31, 293.79, 152.84], "category_id": 1}, {"id": 8, "bbox": [71.6, 657.15, 293.8, 190.5], "category_id": 1}, {"id": 9, "bbox": [916.81, 965.79, 311.51, 51.68], "category_id": 2}], "caption": "Scheme 2. Simplified Catalytic Cycle for the Hydroamination/Cyclization of Aminoalkynes ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 50, 690, 78], "ImageBB": [451, 84, 764, 453]}, "reactions": [{"reactants": [0, 2], "conditions": [], "products": [3, 4]}, {"reactants": [3], "conditions": [9], "products": [5]}, {"reactants": [5, 1], "conditions": [6], "products": [3, 8]}, {"reactants": [8], "conditions": [], "products": [7]}], "diagram_type": "graph"}, {"id": 666, "width": 1344, "height": 976, "file_name": "ol402047d-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [848.0, 277.0, 32.0, 35.0], "category_id": 3}, {"id": 1, "bbox": [273.0, 96.0, 159.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [186.0, 148.0, 306.0, 51.0], "category_id": 2}, {"id": 3, "bbox": [2.0, 396.0, 1342.0, 580.0], "category_id": 4}, {"id": 4, "bbox": [1100.0, 129.0, 159.0, 80.0], "category_id": 2}, {"id": 5, "bbox": [987.0, 306.0, 28.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [958.0, 6.0, 99.0, 305.0], "category_id": 1}, {"id": 7, "bbox": [685.0, 78.0, 31.0, 33.0], "category_id": 3}, {"id": 8, "bbox": [535.0, 150.0, 242.0, 168.0], "category_id": 2}, {"id": 9, "bbox": [90.0, 125.0, 78.0, 47.0], "category_id": 2}, {"id": 10, "bbox": [594.7, 108.0, 163.1, 42.0], "category_id": 2}, {"id": 11, "bbox": [560.0, 24.1, 207.5, 77.9], "category_id": 1}, {"id": 12, "bbox": [820.0, 12.0, 93.7, 259.7], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [1, 2, 11, 10, 8], "products": [12, 6, 4]}], "corefs": [[11, 7], [12, 0], [6, 5]], "caption": "Table 1. Optimization of CCR Employing PSTAa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 336, 101], "ImageBB": [71, 112, 407, 356]}, "diagram_type": "single"}, {"id": 11, "width": 1356, "height": 704, "file_name": "jacs.5b05415-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1045.69, 250.49, 264.53, 168.23], "category_id": 1}, {"id": 1, "bbox": [18.31, 496.66, 277.24, 167.33], "category_id": 1}, {"id": 2, "bbox": [1020.26, 496.66, 311.76, 167.33], "category_id": 1}, {"id": 3, "bbox": [243.59, 293.18, 271.79, 42.88], "category_id": 2}, {"id": 4, "bbox": [279.01, 357.68, 184.59, 43.78], "category_id": 2}, {"id": 5, "bbox": [784.98, 286.83, 179.14, 42.87], "category_id": 2}, {"id": 6, "bbox": [779.53, 125.13, 217.29, 44.7], "category_id": 2}, {"id": 7, "bbox": [757.73, 352.23, 229.1, 83.75], "category_id": 2}, {"id": 8, "bbox": [293.55, 555.71, 249.08, 43.78], "category_id": 2}, {"id": 9, "bbox": [267.2, 620.2, 274.52, 70.13], "category_id": 2}, {"id": 10, "bbox": [804.97, 552.07, 141.89, 37.43], "category_id": 2}, {"id": 11, "bbox": [758.64, 609.3, 236.36, 44.7], "category_id": 2}, {"id": 12, "bbox": [124.59, 411.27, 46.51, 38.34], "category_id": 3}, {"id": 13, "bbox": [618.75, 425.81, 49.24, 37.42], "category_id": 3}, {"id": 14, "bbox": [1150.16, 214.15, 53.77, 38.34], "category_id": 3}, {"id": 15, "bbox": [1151.97, 422.17, 50.15, 40.16], "category_id": 3}, {"id": 16, "bbox": [120.95, 659.26, 49.24, 36.52], "category_id": 3}, {"id": 17, "bbox": [1151.06, 659.26, 51.97, 38.34], "category_id": 3}, {"id": 18, "bbox": [789.53, 67.0, 199.12, 42.87], "category_id": 2}, {"id": 19, "bbox": [553.35, 271.38, 166.41, 156.43], "category_id": 1}, {"id": 20, "bbox": [17.4, 271.38, 225.46, 126.45], "category_id": 1}, {"id": 21, "bbox": [1056.59, 44.29, 243.63, 168.23], "category_id": 1}], "reactions": [{"reactants": [20], "conditions": [3, 4], "products": [19]}, {"reactants": [19], "conditions": [18, 6], "products": [21]}, {"reactants": [19], "conditions": [5, 7], "products": [0]}, {"reactants": [19], "conditions": [8, 9], "products": [1]}, {"reactants": [19], "conditions": [10, 11], "products": [2]}], "corefs": [[20, 12], [19, 13], [21, 14], [0, 15], [2, 17], [1, 16]], "caption": "Figure 1. Gold catalysis and radical reaction relay.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 825, 688, 839], "ImageBB": [448, 640, 787, 816]}, "diagram_type": "tree"}, {"id": 387, "width": 1704, "height": 1952, "file_name": "op500224x-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [168.0, 310.0, 67.0, 54.0], "category_id": 3}, {"id": 1, "bbox": [700.0, 308.0, 73.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [1238.0, 310.0, 74.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [341.0, 67.0, 170.0, 70.0], "category_id": 2}, {"id": 4, "bbox": [351.0, 173.0, 158.0, 91.0], "category_id": 2}, {"id": 5, "bbox": [940.0, 98.0, 93.0, 45.0], "category_id": 2}, {"id": 6, "bbox": [726.0, 805.0, 491.0, 291.0], "category_id": 1}, {"id": 7, "bbox": [910.0, 405.0, 480.0, 302.0], "category_id": 1}, {"id": 8, "bbox": [68.0, 403.0, 398.0, 304.0], "category_id": 1}, {"id": 9, "bbox": [44.0, 0.0, 292.0, 301.0], "category_id": 1}, {"id": 10, "bbox": [496.0, 401.0, 375.0, 306.0], "category_id": 1}, {"id": 11, "bbox": [274.0, 1107.0, 170.0, 89.0], "category_id": 3}, {"id": 12, "bbox": [966.0, 1522.0, 169.0, 89.0], "category_id": 3}, {"id": 13, "bbox": [247.0, 712.0, 184.0, 86.0], "category_id": 3}, {"id": 14, "bbox": [587.0, 708.0, 199.0, 95.0], "category_id": 3}, {"id": 15, "bbox": [1061.0, 708.0, 188.0, 95.0], "category_id": 3}, {"id": 16, "bbox": [899.0, 1105.0, 173.0, 87.0], "category_id": 3}, {"id": 17, "bbox": [291.0, 1529.0, 171.0, 84.0], "category_id": 3}, {"id": 18, "bbox": [111.2, 835.0, 501.8, 285.0], "category_id": 1}, {"id": 19, "bbox": [76.7, 1209.0, 582.3, 306.3], "category_id": 1}, {"id": 20, "bbox": [584.7, 0.0, 286.3, 306.7], "category_id": 1}, {"id": 21, "bbox": [1107.0, 0.0, 305.0, 305.8], "category_id": 1}, {"id": 22, "bbox": [891.9, 165.0, 212.1, 65.7], "category_id": 2}, {"id": 23, "bbox": [777.5, 1198.0, 545.5, 326.0], "category_id": 1}], "reactions": [{"reactants": [9], "conditions": [3, 4], "products": [20]}, {"reactants": [20], "conditions": [5, 22], "products": [21]}], "corefs": [[9, 0], [20, 1], [21, 2], [8, 13], [10, 14], [7, 15], [18, 11], [6, 16], [19, 17], [23, 12]], "caption": "Table 3. Kinetic protonation and carbon nucleophile addition products ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 603, 747, 633], "ImageBB": [433, 639, 859, 1127]}, "diagram_type": "single"}, {"id": 1051, "width": 1796, "height": 956, "file_name": "jo0157425-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [376.45, 893.39, 47.62, 50.28], "category_id": 3}, {"id": 1, "bbox": [0.0, 118.52, 35.94, 52.08], "category_id": 3}, {"id": 2, "bbox": [1466.27, 587.21, 329.73, 304.38], "category_id": 1}, {"id": 3, "bbox": [1199.43, 296.3, 38.63, 46.69], "category_id": 3}, {"id": 4, "bbox": [1224.59, 907.75, 40.43, 45.8], "category_id": 3}, {"id": 5, "bbox": [274.93, 5.39, 334.22, 305.28], "category_id": 1}, {"id": 6, "bbox": [451.92, 297.2, 47.62, 50.28], "category_id": 3}, {"id": 7, "bbox": [824.78, 897.88, 44.92, 52.97], "category_id": 3}, {"id": 8, "bbox": [1064.66, 628.51, 309.07, 213.7], "category_id": 1}, {"id": 9, "bbox": [1640.57, 907.75, 36.83, 45.8], "category_id": 3}, {"id": 10, "bbox": [780.75, 591.7, 113.21, 187.66], "category_id": 1}, {"id": 11, "bbox": [933.49, 62.85, 530.98, 179.58], "category_id": 1}, {"id": 12, "bbox": [207.54, 527.05, 335.12, 275.65], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 64, 453, 78], "ImageBB": [201, 83, 650, 322]}, "reactions": [{"reactants": [1], "conditions": [], "products": [5, 11]}, {"reactants": [5], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [10, 8]}], "diagram_type": "tree"}, {"id": 949, "width": 1352, "height": 788, "file_name": "acs.orglett.5b02709-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [672.96, 89.27, 343.58, 231.28], "category_id": 1}, {"id": 1, "bbox": [1043.59, 236.02, 235.37, 48.01], "category_id": 2}, {"id": 2, "bbox": [1092.29, 672.89, 162.32, 61.54], "category_id": 1}, {"id": 3, "bbox": [503.2, 524.11, 177.2, 87.24], "category_id": 2}, {"id": 4, "bbox": [4.06, 511.26, 371.98, 223.17], "category_id": 1}, {"id": 5, "bbox": [1137.6, 502.47, 154.88, 147.43], "category_id": 1}, {"id": 6, "bbox": [309.76, 607.97, 163.68, 123.08], "category_id": 1}, {"id": 7, "bbox": [709.48, 504.5, 156.23, 235.34], "category_id": 1}, {"id": 8, "bbox": [25.7, 0.0, 564.07, 461.89], "category_id": 1}, {"id": 9, "bbox": [1015.18, 359.1, 318.56, 47.34], "category_id": 2}, {"id": 10, "bbox": [1044.27, 110.23, 233.33, 89.95], "category_id": 2}, {"id": 11, "bbox": [879.24, 273.89, 39.23, 48.02], "category_id": 3}, {"id": 12, "bbox": [193.43, 695.89, 38.55, 39.22], "category_id": 3}, {"id": 13, "bbox": [1123.4, 600.53, 40.58, 45.99], "category_id": 3}, {"id": 14, "bbox": [902.24, 518.7, 180.58, 85.89], "category_id": 2}, {"id": 15, "bbox": [838.66, 701.3, 33.82, 41.25], "category_id": 3}, {"id": 16, "bbox": [329.38, 403.74, 205.6, 45.98], "category_id": 3}], "caption": "Scheme 1. Retrosynthetic Analysis", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 276, 110], "ImageBB": [82, 116, 420, 313]}, "reactions": [{"reactants": [8], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [10, 1], "products": [9]}, {"reactants": [4, 6], "conditions": [3], "products": [7]}, {"reactants": [7], "conditions": [14], "products": [5, 2]}], "diagram_type": "multiple"}, {"id": 1055, "width": 2808, "height": 824, "file_name": "jo2001534-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [313.25, 626.76, 318.87, 57.62], "category_id": 3}, {"id": 1, "bbox": [1210.85, 26.7, 325.89, 309.17], "category_id": 1}, {"id": 2, "bbox": [2211.0, 22.48, 328.7, 316.2], "category_id": 1}, {"id": 3, "bbox": [2338.83, 625.36, 84.28, 54.8], "category_id": 3}, {"id": 4, "bbox": [1806.42, 622.66, 137.65, 61.41], "category_id": 3}, {"id": 5, "bbox": [351.6, 482.89, 120.71, 120.71], "category_id": 2}, {"id": 6, "bbox": [266.89, 43.56, 325.89, 451.1], "category_id": 1}, {"id": 7, "bbox": [1695.48, 22.48, 328.7, 316.2], "category_id": 1}, {"id": 8, "bbox": [1807.2, 477.8, 114.3, 126.1], "category_id": 2}, {"id": 9, "bbox": [1250.19, 622.55, 257.06, 61.83], "category_id": 3}, {"id": 10, "bbox": [796.47, 622.55, 297.79, 59.02], "category_id": 3}, {"id": 11, "bbox": [0.0, 727.3, 1471.8, 87.77], "category_id": 2}, {"id": 12, "bbox": [1288.11, 477.8, 120.69, 127.1], "category_id": 2}, {"id": 13, "bbox": [733.25, 33.73, 334.32, 363.97], "category_id": 1}, {"id": 14, "bbox": [845.0, 479.9, 120.7, 125.0], "category_id": 2}, {"id": 15, "bbox": [2306.52, 477.8, 162.95, 126.1], "category_id": 2}], "caption": "Scheme 8. Calculated 6-Exo-Trig Cyclization of 1d- as Model for the Formation of Type 8 Compounds from 5d-h for the Gas Phase and SCRF-CPCM(UAKS) Solution-Phase Simulations (THF) (Relative Energies: SCS-MP2/6-311\u00feG(d,p)//B3LYP/6- 31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 770, 138], "ImageBB": [71, 148, 773, 354]}, "reactions": [{"reactants": [6], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [6]}, {"reactants": [13], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [13]}, {"reactants": [1], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [2]}], "diagram_type": "single"}, {"id": 113, "width": 1188, "height": 1476, "file_name": "op990099y-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [147.0, 222.0, 357.0, 80.0], "category_id": 2}, {"id": 1, "bbox": [838.0, 230.0, 350.0, 72.0], "category_id": 2}, {"id": 2, "bbox": [819.0, 1388.0, 250.1, 73.6], "category_id": 2}, {"id": 3, "bbox": [272.3, 1017.6, 574.5, 458.4], "category_id": 1}, {"id": 4, "bbox": [41.0, 593.0, 1023.0, 220.9], "category_id": 1}, {"id": 5, "bbox": [654.0, 409.7, 201.0, 92.5], "category_id": 2}, {"id": 6, "bbox": [729.0, 867.0, 251.4, 71.2], "category_id": 2}, {"id": 7, "bbox": [9.0, 0.0, 567.0, 197.2], "category_id": 1}, {"id": 8, "bbox": [753.0, 2.0, 435.0, 188.9], "category_id": 1}], "reactions": [{"reactants": [7, 8], "conditions": [5], "products": [4, 3]}], "corefs": [[7, 0], [8, 1], [4, 6], [3, 2]], "caption": "Figure 1. Reaction scheme for the reaction between diphenyl oxide with benzyl chloride over sulphated zirconia catalyst. 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General Scheme for Synthesis of Glutamine Conjugates", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 457, 110], "ImageBB": [82, 116, 787, 362]}, "reactions": [{"reactants": [10], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [7]}], "diagram_type": "tree"}, {"id": 73, "width": 1336, "height": 1736, "file_name": "ja206047h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1197.4, 264.23, 22.5, 29.81], "category_id": 3}, {"id": 1, "bbox": [6.81, 76.21, 263.06, 165.16], "category_id": 1}, {"id": 2, "bbox": [442.01, 264.23, 41.82, 30.69], "category_id": 3}, {"id": 3, "bbox": [2.5, 311.16, 1329.0, 1420.38], "category_id": 4}, {"id": 4, "bbox": [228.27, 264.23, 16.64, 29.81], "category_id": 3}, {"id": 5, "bbox": [630.27, 193.08, 357.15, 74.61], "category_id": 2}, {"id": 6, "bbox": [357.06, 102.32, 182.56, 99.89], "category_id": 1}, {"id": 7, "bbox": [692.08, 4.42, 215.19, 169.51], "category_id": 1}, {"id": 8, "bbox": [1070.6, 93.61, 256.5, 156.46], "category_id": 1}, {"id": 9, "bbox": [6.81, 261.12, 213.02, 41.18], "category_id": 2}], "reactions": [{"reactants": [1, 6], "conditions": [7, 5], "products": [8]}], "corefs": [[1, 4], [6, 2], [8, 0]], "caption": "Table 2. Scope of N-Acyloxazolidinone Componenta,b", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 87, 738, 109], "ImageBB": [438, 117, 772, 551]}, "diagram_type": "single"}, {"id": 1208, "width": 1348, "height": 1668, "file_name": "ol8005198-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [113.51, 437.23, 137.39, 60.08], "category_id": 3}, {"id": 1, "bbox": [711.1, 1547.84, 543.34, 64.25], "category_id": 2}, {"id": 2, "bbox": [45.9, 1109.77, 141.06, 69.26], "category_id": 3}, {"id": 3, "bbox": [358.89, 1143.99, 98.48, 55.07], "category_id": 2}, {"id": 4, "bbox": [718.61, 1221.59, 531.66, 62.58], "category_id": 2}, {"id": 5, "bbox": [552.52, 862.79, 128.53, 59.24], "category_id": 2}, {"id": 6, "bbox": [48.41, 1335.07, 142.72, 68.42], "category_id": 3}, {"id": 7, "bbox": [792.05, 4.1, 292.35, 88.11], "category_id": 1}, {"id": 8, "bbox": [281.44, 442.63, 102.12, 56.07], "category_id": 2}, {"id": 9, "bbox": [271.25, 610.79, 116.02, 57.58], "category_id": 2}, {"id": 10, "bbox": [93.48, 526.52, 310.48, 60.91], "category_id": 2}, {"id": 11, "bbox": [695.24, 211.11, 307.14, 184.4], "category_id": 1}, {"id": 12, "bbox": [300.47, 261.17, 70.1, 50.07], "category_id": 3}, {"id": 13, "bbox": [356.39, 1330.06, 102.65, 55.91], "category_id": 2}, {"id": 14, "bbox": [113.51, 601.61, 139.38, 58.41], "category_id": 3}, {"id": 15, "bbox": [546.68, 946.23, 127.7, 51.73], "category_id": 2}, {"id": 16, "bbox": [25.04, 0.0, 550.85, 126.0], "category_id": 1}, {"id": 17, "bbox": [701.92, 865.29, 61.76, 55.07], "category_id": 3}, {"id": 18, "bbox": [473.23, 143.52, 283.78, 100.13], "category_id": 2}, {"id": 19, "bbox": [557.53, 1153.16, 201.14, 60.92], "category_id": 3}, {"id": 20, "bbox": [738.64, 360.47, 133.54, 56.74], "category_id": 3}, {"id": 21, "bbox": [95.98, 526.52, 307.98, 59.24], "category_id": 2}, {"id": 22, "bbox": [25.04, 0.0, 551.69, 126.0], "category_id": 1}, {"id": 23, "bbox": [469.89, 707.59, 796.24, 141.85], "category_id": 1}, {"id": 24, "bbox": [701.92, 947.06, 63.43, 51.74], "category_id": 3}, {"id": 25, "bbox": [557.53, 1494.44, 199.48, 59.24], "category_id": 3}, {"id": 26, "bbox": [27.54, 567.4, 62.6, 52.57], "category_id": 3}, {"id": 27, "bbox": [704.42, 587.43, 133.54, 58.41], "category_id": 3}, {"id": 28, "bbox": [267.91, 1336.74, 924.77, 208.6], "category_id": 1}, {"id": 29, "bbox": [27.54, 399.69, 58.43, 57.57], "category_id": 3}, {"id": 30, "bbox": [1064.15, 362.14, 132.7, 57.57], "category_id": 3}, {"id": 31, "bbox": [878.86, 900.34, 171.93, 61.74], "category_id": 2}, {"id": 32, "bbox": [95.98, 110.14, 156.91, 59.25], "category_id": 2}, {"id": 33, "bbox": [45.9, 818.56, 368.91, 110.15], "category_id": 2}, {"id": 34, "bbox": [22.53, 1232.43, 63.44, 61.75], "category_id": 3}, {"id": 35, "bbox": [1064.15, 938.72, 128.53, 59.24], "category_id": 2}, {"id": 36, "bbox": [115.18, 360.47, 216.17, 54.24], "category_id": 2}, {"id": 37, "bbox": [95.15, 258.67, 136.04, 55.91], "category_id": 2}, {"id": 38, "bbox": [300.47, 187.74, 70.1, 53.41], "category_id": 3}, {"id": 39, "bbox": [1016.57, 211.11, 311.32, 184.4], "category_id": 1}, {"id": 40, "bbox": [93.48, 183.57, 137.71, 57.58], "category_id": 2}, {"id": 41, "bbox": [300.47, 115.15, 69.27, 54.24], "category_id": 3}, {"id": 42, "bbox": [162.75, 1214.91, 232.86, 111.81], "category_id": 2}, {"id": 43, "bbox": [45.9, 712.59, 407.3, 73.43], "category_id": 2}, {"id": 44, "bbox": [394.78, 450.59, 799.57, 142.68], "category_id": 1}, {"id": 45, "bbox": [856.33, 108.47, 137.71, 57.58], "category_id": 3}, {"id": 46, "bbox": [272.92, 994.63, 919.76, 207.77], "category_id": 1}, {"id": 47, "bbox": [544.2, 257.83, 92.62, 50.07], "category_id": 2}], "caption": "Scheme 1. Synthesis of (2S,3\u2032R)- and (2R,3\u2032R)-1", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [467, 224, 718, 239], "ImageBB": [425, 247, 762, 664]}, "reactions": [{"reactants": [29], "conditions": [36, 0, 8], "products": [44]}, {"reactants": [26], "conditions": [21, 14, 9], "products": [44]}, {"reactants": [44], "conditions": [43, 33], "products": [23]}, {"reactants": [34], "conditions": [42, 2], "products": [46]}, {"reactants": [34], "conditions": [42, 6], "products": [28]}], "diagram_type": "tree"}, {"id": 357, "width": 1352, "height": 3592, "file_name": "ol200038n-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [330.0, 1353.0, 103.0, 56.0], "category_id": 2}, {"id": 1, "bbox": [201.0, 2994.0, 911.0, 598.0], "category_id": 1}, {"id": 2, "bbox": [996.0, 845.0, 40.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [589.0, 1854.0, 58.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [652.0, 1531.0, 64.0, 61.0], "category_id": 3}, {"id": 5, "bbox": [1028.0, 1703.0, 53.0, 63.0], "category_id": 3}, {"id": 6, "bbox": [1081.0, 1536.0, 64.0, 53.0], "category_id": 3}, {"id": 7, "bbox": [417.0, 1573.0, 381.0, 342.0], "category_id": 1}, {"id": 8, "bbox": [128.0, 1343.0, 170.0, 63.0], "category_id": 2}, {"id": 9, "bbox": [308.0, 1671.0, 85.0, 61.0], "category_id": 2}, {"id": 10, "bbox": [817.0, 1740.0, 116.0, 101.0], "category_id": 2}, {"id": 11, "bbox": [5.0, 2015.0, 1347.0, 846.0], "category_id": 2}, {"id": 12, "bbox": [83.0, 1168.0, 429.0, 69.0], "category_id": 2}, {"id": 13, "bbox": [858.0, 581.0, 321.0, 293.0], "category_id": 1}, {"id": 14, "bbox": [298.0, 728.0, 353.0, 261.0], "category_id": 2}, {"id": 15, "bbox": [96.0, 692.0, 172.0, 61.0], "category_id": 2}, {"id": 16, "bbox": [296.0, 613.0, 253.0, 100.0], "category_id": 2}, {"id": 17, "bbox": [299.0, 511.0, 465.0, 96.0], "category_id": 2}, {"id": 18, "bbox": [7.0, 304.0, 1344.0, 175.0], "category_id": 2}, {"id": 19, "bbox": [1.0, 10.0, 1351.0, 153.0], "category_id": 2}, {"id": 20, "bbox": [881.5, 1673.46, 58.66, 52.37], "category_id": 2}, {"id": 21, "bbox": [789.31, 617.51, 64.95, 52.38], "category_id": 2}, {"id": 22, "bbox": [91.4, 1747.1, 185.9, 53.4], "category_id": 2}, {"id": 23, "bbox": [480.63, 603.52, 304.37, 83.28], "category_id": 1}, {"id": 24, "bbox": [142.0, 1663.0, 103.0, 64.8], "category_id": 2}, {"id": 25, "bbox": [696.0, 883.0, 599.0, 264.0], "category_id": 3}, {"id": 26, "bbox": [914.0, 1228.6, 346.6, 322.3], "category_id": 1}, {"id": 27, "bbox": [494.2, 1225.7, 339.2, 326.8], "category_id": 1}, {"id": 28, "bbox": [67.0, 1388.0, 53.0, 55.0], "category_id": 3}, {"id": 29, "bbox": [152.0, 1419.0, 133.0, 63.2], "category_id": 2}], "reactions": [{"reactants": [15], "conditions": [17, 16, 23, 14], "products": [13]}, {"reactants": [28], "conditions": [8, 29, 0], "products": [27, 26]}, {"reactants": [27], "conditions": [], "products": [26]}, {"reactants": [26], "conditions": [], "products": [27]}, {"reactants": [26], "conditions": [24, 22, 9], "products": [7]}, {"reactants": [7], "conditions": [20, 10], "products": [5]}], "corefs": [[13, 2], [13, 25], [27, 4], [26, 6], [7, 3]], "caption": "Figure 2. Single-crystal X-ray structure of 9a. Hydrogen atoms are omitted for clarity except polar N-H bonds. Selected bond lengths (A\u030a): C5-O1 1.224(3), C12-O2 1.200(3), N1-C1 1.368(3), N1-C4 1.340(3). 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Model for Stereoselection in the Anti Diol Series", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [262, 75, 586, 88], "ImageBB": [73, 94, 777, 271]}, "reactions": [{"reactants": [17], "conditions": [1], "products": [11]}, {"reactants": [11], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [], "products": [17]}, {"reactants": [11], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [11]}, {"reactants": [15], "conditions": [21], "products": [12]}, {"reactants": [10], "conditions": [8, 9], "products": [20]}, {"reactants": [2], "conditions": [24], "products": [18]}, {"reactants": [25], "conditions": [14, 22], "products": [13]}], "diagram_type": "graph"}, {"id": 1191, "width": 1352, "height": 1016, "file_name": "ol500248h-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [89.7, 2.7, 182.19, 114.27], "category_id": 1}, {"id": 1, "bbox": [656.05, 438.82, 71.01, 37.19], "category_id": 2}, {"id": 2, "bbox": [325.32, 124.41, 179.9, 40.57], "category_id": 3}, {"id": 3, "bbox": [918.47, 42.6, 171.11, 38.54], "category_id": 2}, {"id": 4, "bbox": [987.45, 440.17, 31.79, 35.84], "category_id": 3}, {"id": 5, "bbox": [100.1, 438.82, 158.26, 40.57], "category_id": 3}, {"id": 6, "bbox": [877.21, 253.56, 253.63, 185.26], "category_id": 1}, {"id": 7, "bbox": [520.1, 71.67, 345.61, 41.92], "category_id": 2}, {"id": 8, "bbox": [384.16, 869.53, 44.64, 41.24], "category_id": 3}, {"id": 9, "bbox": [325.32, 438.15, 177.88, 42.59], "category_id": 3}, {"id": 10, "bbox": [81.16, 541.6, 198.84, 115.62], "category_id": 1}, {"id": 11, "bbox": [535.77, 131.68, 454.94, 98.8], "category_id": 2}, {"id": 12, "bbox": [349.67, 6.76, 134.59, 81.14], "category_id": 1}, {"id": 13, "bbox": [100.1, 665.33, 158.26, 37.87], "category_id": 3}, {"id": 14, "bbox": [574.89, 334.69, 238.74, 33.81], "category_id": 2}, {"id": 15, "bbox": [543.1, 392.17, 301.65, 39.21], "category_id": 2}, {"id": 16, "bbox": [520.1, 605.83, 345.61, 86.55], "category_id": 2}, {"id": 17, "bbox": [543.1, 10.14, 337.49, 40.57], "category_id": 2}, {"id": 18, "bbox": [345.61, 663.3, 146.09, 41.25], "category_id": 3}, {"id": 19, "bbox": [574.89, 541.6, 238.74, 39.89], "category_id": 2}, {"id": 20, "bbox": [100.77, 124.41, 150.83, 40.57], "category_id": 3}, {"id": 21, "bbox": [918.47, 572.7, 171.11, 38.54], "category_id": 2}, {"id": 22, "bbox": [465.32, 892.52, 479.52, 70.99], "category_id": 2}, {"id": 23, "bbox": [349.67, 530.78, 133.24, 113.59], "category_id": 1}, {"id": 24, "bbox": [574.89, 798.53, 231.31, 33.14], "category_id": 2}, {"id": 25, "bbox": [877.21, 678.18, 253.63, 190.67], "category_id": 1}, {"id": 26, "bbox": [81.16, 261.67, 198.84, 154.16], "category_id": 1}, {"id": 27, "bbox": [100.1, 438.15, 158.26, 41.24], "category_id": 3}, {"id": 28, "bbox": [998.95, 874.94, 63.58, 36.51], "category_id": 3}, {"id": 29, "bbox": [349.67, 321.17, 131.21, 85.2], "category_id": 1}, {"id": 30, "bbox": [100.1, 730.92, 255.65, 211.63], "category_id": 1}], "caption": "Scheme 3. Investigation of the Reaction Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 324, 376, 339], "ImageBB": [82, 346, 420, 600]}, "reactions": [{"reactants": [26, 29], "conditions": [14, 15, 1], "products": [6]}, {"reactants": [30], "conditions": [24, 22], "products": [25]}], "diagram_type": "multiple"}, {"id": 984, "width": 1356, "height": 864, "file_name": "ja200818w-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [542.67, 0.0, 177.73, 114.01], "category_id": 1}, {"id": 1, "bbox": [0.0, 0.0, 2.71, 4.07], "category_id": 2}, {"id": 2, "bbox": [0.0, 0.0, 2.71, 6.79], "category_id": 2}, {"id": 3, "bbox": [0.0, 0.0, 2.71, 8.82], "category_id": 2}, {"id": 4, "bbox": [530.71, 764.39, 69.49, 46.67], "category_id": 2}, {"id": 5, "bbox": [0.0, 319.63, 263.87, 177.12], "category_id": 1}, {"id": 6, "bbox": [633.2, 762.76, 108.9, 53.61], "category_id": 1}, {"id": 7, "bbox": [971.38, 354.24, 380.55, 160.83], "category_id": 1}, {"id": 8, "bbox": [138.38, 517.1, 33.24, 44.79], "category_id": 3}, {"id": 9, "bbox": [377.16, 487.92, 510.11, 133.01], "category_id": 2}, {"id": 10, "bbox": [1103.66, 548.32, 42.05, 47.5], "category_id": 3}, {"id": 11, "bbox": [307.97, 280.95, 588.12, 71.93], "category_id": 2}], "caption": "Scheme 1. Formation of 2 by Two Di\ufb00erent Pathways", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 373, 107], "ImageBB": [71, 117, 410, 333]}, "reactions": [{"reactants": [5], "conditions": [11], "products": [0, 7]}, {"reactants": [5], "conditions": [9], "products": [4, 6, 7]}], "diagram_type": "graph"}, {"id": 9, "width": 1352, "height": 668, "file_name": "jacs.5b05415-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [401.16, 160.63, 343.02, 141.0], "category_id": 2}, {"id": 1, "bbox": [404.61, 52.71, 341.3, 89.2], "category_id": 2}, {"id": 2, "bbox": [1208.39, 416.18, 53.8, 40.85], "category_id": 3}, {"id": 3, "bbox": [956.29, 416.18, 52.08, 40.85], "category_id": 3}, {"id": 4, "bbox": [1148.82, 231.42, 51.21, 39.13], "category_id": 3}, {"id": 5, "bbox": [889.81, 231.42, 52.08, 39.13], "category_id": 3}, {"id": 6, "bbox": [1191.12, 482.66, 84.02, 44.3], "category_id": 2}, {"id": 7, "bbox": [1190.26, 588.85, 84.88, 43.44], "category_id": 2}, {"id": 8, "bbox": [1125.51, 278.05, 108.19, 39.12], "category_id": 2}, {"id": 9, "bbox": [81.72, 307.4, 98.7, 40.85], "category_id": 2}, {"id": 10, "bbox": [163.74, 213.29, 49.48, 37.4], "category_id": 3}, {"id": 11, "bbox": [1061.62, 48.4, 226.47, 176.39], "category_id": 1}, {"id": 12, "bbox": [833.7, 46.67, 163.44, 161.72], "category_id": 1}, {"id": 13, "bbox": [61.0, 420.5, 300.72, 180.71], "category_id": 1}, {"id": 14, "bbox": [77.4, 76.02, 228.2, 125.46], "category_id": 1}, {"id": 15, "bbox": [200.0, 278.05, 141.86, 85.74], "category_id": 2}, {"id": 16, "bbox": [872.54, 276.32, 85.75, 39.99], "category_id": 2}, {"id": 17, "bbox": [394.25, 573.31, 505.33, 89.2], "category_id": 2}, {"id": 18, "bbox": [467.64, 400.64, 356.83, 36.53], "category_id": 2}, {"id": 19, "bbox": [161.15, 606.98, 52.94, 40.85], "category_id": 3}, {"id": 20, "bbox": [390.8, 459.35, 504.47, 89.2], "category_id": 2}], "reactions": [{"reactants": [14], "conditions": [1, 0], "products": [12, 11]}, {"reactants": [14], "conditions": [9, 15], "products": [13]}, {"reactants": [13], "conditions": [18, 20, 17], "products": [3, 2]}], "corefs": [[14, 10], [12, 5], [11, 4], [13, 19]], "caption": "Figure 4. Mechanistic investigation.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 414, 254, 428], "ImageBB": [82, 237, 420, 404]}, "diagram_type": "tree"}, {"id": 1353, "width": 1352, "height": 1164, "file_name": "op800136f-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [892.77, 0.0, 43.28, 47.33], "category_id": 3}, {"id": 1, "bbox": [921.85, 104.12, 232.66, 54.77], "category_id": 2}, {"id": 2, "bbox": [708.8, 700.47, 507.26, 448.27], "category_id": 1}, {"id": 3, "bbox": [681.75, 97.36, 118.36, 57.47], "category_id": 2}, {"id": 4, "bbox": [1263.4, 288.03, 88.6, 61.53], "category_id": 2}, {"id": 5, "bbox": [663.49, 214.33, 512.66, 243.41], "category_id": 1}, {"id": 6, "bbox": [0.0, 537.52, 371.99, 164.98], "category_id": 1}, {"id": 7, "bbox": [164.35, 442.19, 237.39, 57.47], "category_id": 2}, {"id": 8, "bbox": [424.74, 266.39, 121.74, 54.09], "category_id": 2}, {"id": 9, "bbox": [131.21, 699.12, 71.02, 52.06], "category_id": 3}, {"id": 10, "bbox": [870.45, 466.53, 99.42, 50.03], "category_id": 3}, {"id": 11, "bbox": [922.53, 1108.17, 71.69, 55.83], "category_id": 3}, {"id": 12, "bbox": [309.76, 290.73, 45.32, 59.5], "category_id": 3}, {"id": 13, "bbox": [992.86, 617.98, 115.66, 54.77], "category_id": 2}, {"id": 14, "bbox": [923.2, 546.31, 43.29, 50.03], "category_id": 3}, {"id": 15, "bbox": [131.21, 289.38, 73.72, 58.83], "category_id": 3}], "caption": "Scheme 6", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 486, 119, 500], "ImageBB": [58, 505, 396, 796]}, "reactions": [{"reactants": [5, 4], "conditions": [1], "products": [3, 9]}, {"reactants": [5, 4], "conditions": [], "products": [15, 12]}, {"reactants": [15, 12], "conditions": [8], "products": [5]}, {"reactants": [15], "conditions": [7], "products": [6]}, {"reactants": [5, 4], "conditions": [14], "products": [13, 2]}, {"reactants": [2], "conditions": [], "products": [5]}], "diagram_type": "tree"}, {"id": 848, "width": 1344, "height": 912, "file_name": "jo201478d-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [317.0, 220.0, 213.0, 83.4], "category_id": 2}, {"id": 1, "bbox": [612.0, 259.8, 223.0, 191.0], "category_id": 1}, {"id": 2, "bbox": [975.14, 432.84, 87.36, 38.39], "category_id": 3}, {"id": 3, "bbox": [457.0, 187.0, 36.2, 39.1], "category_id": 3}, {"id": 4, "bbox": [922.6, 291.7, 222.8, 156.5], "category_id": 1}, {"id": 5, "bbox": [644.3, 0.0, 251.1, 200.4], "category_id": 1}, {"id": 6, "bbox": [1019.0, 474.0, 62.0, 49.0], "category_id": 2}, {"id": 7, "bbox": [261.0, 188.0, 37.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [504.0, 667.0, 340.0, 245.0], "category_id": 1}, {"id": 9, "bbox": [200.1, 7.9, 152.7, 175.7], "category_id": 1}, {"id": 10, "bbox": [390.8, 23.4, 143.2, 141.9], "category_id": 1}, {"id": 11, "bbox": [743.0, 210.1, 43.9, 44.3], "category_id": 3}], "reactions": [{"reactants": [9, 10], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4, 6]}], "corefs": [[9, 7], [10, 3], [5, 11], [4, 2]], "caption": "Figure 1. Proposed steric hindrance limiting the transformation of trans-stilbene oxide to the desired DHP product. 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", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 372, 761, 399], "ImageBB": [424, 424, 763, 1038]}, "diagram_type": "multiple"}, {"id": 892, "width": 2820, "height": 824, "file_name": "acs.oprd.5b00070-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1454.62, 699.0, 133.98, 46.79], "category_id": 2}, {"id": 1, "bbox": [1054.0, 36.0, 258.0, 75.0], "category_id": 2}, {"id": 2, "bbox": [674.12, 645.83, 242.44, 59.55], "category_id": 3}, {"id": 3, "bbox": [676.24, 209.86, 236.07, 57.42], "category_id": 3}, {"id": 4, "bbox": [1405.7, 154.57, 238.2, 53.16], "category_id": 3}, {"id": 5, "bbox": [1456.74, 211.99, 133.98, 48.91], "category_id": 2}, {"id": 6, "bbox": [1052.0, 530.0, 274.0, 82.0], "category_id": 2}, {"id": 7, "bbox": [1412.08, 745.79, 219.05, 44.66], "category_id": 2}, {"id": 8, "bbox": [1925.0, 428.0, 292.0, 79.0], "category_id": 3}, {"id": 9, "bbox": [1118.0, 733.0, 148.0, 66.0], "category_id": 2}, {"id": 10, "bbox": [536.0, 430.0, 242.0, 73.0], "category_id": 2}, {"id": 11, "bbox": [1132.0, 241.0, 101.0, 66.0], "category_id": 2}, {"id": 12, "bbox": [815.0, 412.0, 230.0, 114.0], "category_id": 2}, {"id": 13, "bbox": [1623.0, 431.6, 207.9, 65.6], "category_id": 2}, {"id": 14, "bbox": [1397.0, 637.0, 256.0, 58.5], "category_id": 3}, {"id": 15, "bbox": [736.8, 716.3, 115.1, 62.7], "category_id": 2}, {"id": 16, "bbox": [621.0, 131.4, 349.6, 61.4], "category_id": 2}, {"id": 17, "bbox": [1400.0, 262.7, 244.7, 51.8], "category_id": 2}, {"id": 18, "bbox": [1048.0, 138.0, 274.0, 64.0], "category_id": 2}, {"id": 19, "bbox": [1041.0, 630.0, 281.0, 69.0], "category_id": 2}], "reactions": [{"reactants": [16, 3], "conditions": [18, 11], "products": [4, 5, 17]}, {"reactants": [16, 3], "conditions": [10, 12], "products": [2, 15]}, {"reactants": [2, 15], "conditions": [19, 9], "products": [14, 0, 7]}, {"reactants": [4, 5, 17, 14, 0, 7], "conditions": [13], "products": [8]}], "corefs": [], "caption": "Figure 2. Investigation of two potential process routes for the synthesis of rif S.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 558, 471, 572], "ImageBB": [82, 343, 787, 549]}, "diagram_type": "graph"}, {"id": 160, "width": 876, "height": 240, "file_name": "op700060e-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [351.0, 86.0, 172.0, 61.0], "category_id": 2}, {"id": 1, "bbox": [378.0, 16.0, 113.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [552.6, 5.0, 323.4, 188.0], "category_id": 1}, {"id": 3, "bbox": [6.0, 0.0, 323.0, 156.0], "category_id": 1}, {"id": 4, "bbox": [187.0, 141.0, 30.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [645.0, 196.0, 114.3, 35.4], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [2]}], "corefs": [[3, 4], [2, 5]], "caption": "Figure 2. Oxidation of 2 with concentrated sodium hypochlorite.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 109, 394, 123], "ImageBB": [117, 46, 336, 106]}, "diagram_type": "single"}, {"id": 463, "width": 1344, "height": 1176, "file_name": "op200005e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 872.0, 1342.0, 301.0], "category_id": 4}, {"id": 1, "bbox": [1028.0, 690.0, 59.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [49.0, 611.0, 187.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [433.0, 367.0, 153.0, 42.0], "category_id": 2}, {"id": 4, "bbox": [919.0, 258.0, 59.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [113.0, 308.0, 35.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [628.0, 364.0, 705.0, 328.0], "category_id": 1}, {"id": 7, "bbox": [34.0, 433.0, 205.0, 153.0], "category_id": 1}, {"id": 8, "bbox": [19.0, 69.0, 338.0, 244.0], "category_id": 1}, {"id": 9, "bbox": [732.0, 0.0, 456.0, 246.0], "category_id": 1}, {"id": 10, "bbox": [424.0, 271.0, 115.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [8, 7], "conditions": [10, 3], "products": [9, 6]}], "corefs": [[8, 5], [7, 2], [9, 4], [6, 1]], "caption": "Table 1. Formation of Amide 13 from 8 and Homopiperazine", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 446, 405, 461], "ImageBB": [71, 471, 407, 765]}, "diagram_type": "single"}, {"id": 514, "width": 1352, "height": 1056, "file_name": "ol051342i-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [548.0, 91.0, 210.0, 54.0], "category_id": 2}, {"id": 1, "bbox": [39.0, 0.0, 402.0, 221.0], "category_id": 1}, {"id": 2, "bbox": [469.0, 3.0, 381.0, 80.0], "category_id": 2}, {"id": 3, "bbox": [22.0, 306.0, 1311.0, 741.0], "category_id": 4}, {"id": 4, "bbox": [186.0, 230.0, 58.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [1056.0, 232.0, 47.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [919.0, 1.0, 402.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [2, 0], "products": [6]}], "corefs": [[1, 4], [6, 5]], "caption": "Table 1. Pictet-Spengler Reaction of Thioortho Esters with N-Tosyltryptamines ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 460, 758, 488], "ImageBB": [439, 496, 777, 760]}, "diagram_type": "single"}, {"id": 835, "width": 1348, "height": 2672, "file_name": "jo302142v-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [17.0, 201.0, 359.0, 258.0], "category_id": 1}, {"id": 1, "bbox": [394.0, 183.0, 227.0, 258.0], "category_id": 1}, {"id": 2, "bbox": [861.0, 498.0, 89.0, 69.0], "category_id": 3}, {"id": 3, "bbox": [177.0, 411.0, 50.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 838.0, 1348.0, 1834.0], "category_id": 4}, {"id": 5, "bbox": [445.0, 443.0, 153.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [42.0, 73.0, 325.0, 96.0], "category_id": 2}, {"id": 7, "bbox": [854.0, 226.0, 103.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [735.0, 0.0, 590.0, 283.0], "category_id": 1}, {"id": 9, "bbox": [25.86, 558.82, 1296.6, 243.56], "category_id": 4}, {"id": 10, "bbox": [717.0, 272.0, 626.0, 286.0], "category_id": 1}], "reactions": [{"reactants": [0, 1], "conditions": [], "products": [8, 10]}], "corefs": [[0, 3], [1, 5], [8, 7], [10, 2]], "caption": "Table 2. Aldol Reactions of the Ti(IV) \u201cate\u201d Enolate of 1a (R = MOM, Et3Si) with (\u00b1)-5a ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 184, 417, 220], "ImageBB": [82, 224, 419, 892]}, "diagram_type": "tree"}, {"id": 1294, "width": 1344, "height": 684, "file_name": "op200176f-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [230.61, 579.9, 39.67, 43.72], "category_id": 3}, {"id": 1, "bbox": [71.27, 8.07, 329.44, 170.2], "category_id": 1}, {"id": 2, "bbox": [248.76, 182.31, 59.84, 48.44], "category_id": 3}, {"id": 3, "bbox": [471.98, 0.0, 403.4, 133.87], "category_id": 1}, {"id": 4, "bbox": [696.54, 371.35, 80.68, 47.09], "category_id": 2}, {"id": 5, "bbox": [68.58, 347.8, 635.36, 219.99], "category_id": 1}, {"id": 6, "bbox": [974.89, 409.7, 57.15, 49.1], "category_id": 3}, {"id": 7, "bbox": [646.79, 198.46, 628.63, 205.85], "category_id": 1}], "caption": "Scheme 4. Preparation of Intermediate 9 from Dinitroaniline ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 229, 331, 259], "ImageBB": [71, 270, 407, 441]}, "reactions": [{"reactants": [1, 3], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [4], "products": [5]}], "diagram_type": "tree"}, {"id": 172, "width": 1352, "height": 1452, "file_name": "op500224x-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [410.0, 803.0, 392.0, 303.0], "category_id": 1}, {"id": 1, "bbox": [4.0, 1167.0, 392.0, 285.0], "category_id": 1}, {"id": 2, "bbox": [989.0, 1083.0, 163.0, 70.0], "category_id": 3}, {"id": 3, "bbox": [572.0, 1095.6, 174.0, 85.4], "category_id": 3}, {"id": 4, "bbox": [225.0, 1086.0, 162.0, 84.5], "category_id": 3}, {"id": 5, "bbox": [45.0, 824.0, 417.0, 271.0], "category_id": 1}, {"id": 6, "bbox": [739.0, 779.0, 582.0, 361.0], "category_id": 1}, {"id": 7, "bbox": [338.0, 1179.0, 396.0, 273.0], "category_id": 1}, {"id": 8, "bbox": [696.0, 1181.0, 319.0, 271.0], "category_id": 1}, {"id": 9, "bbox": [944.0, 1203.0, 408.0, 249.0], "category_id": 1}, {"id": 10, "bbox": [969.0, 347.0, 102.0, 61.0], "category_id": 3}, {"id": 11, "bbox": [710.0, 350.0, 85.0, 56.0], "category_id": 3}, {"id": 12, "bbox": [114.0, 356.0, 61.0, 43.0], "category_id": 3}, {"id": 13, "bbox": [112.0, 722.0, 88.0, 61.0], "category_id": 3}, {"id": 14, "bbox": [1118.0, 727.0, 101.0, 63.0], "category_id": 3}, {"id": 15, "bbox": [613.0, 727.0, 88.0, 65.0], "category_id": 3}, {"id": 16, "bbox": [207.0, 0.0, 76.0, 56.0], "category_id": 3}, {"id": 17, "bbox": [1068.0, 108.0, 224.0, 72.0], "category_id": 2}, {"id": 18, "bbox": [1059.0, 200.0, 219.0, 91.0], "category_id": 2}, {"id": 19, "bbox": [315.0, 124.0, 214.0, 70.0], "category_id": 2}, {"id": 20, "bbox": [304.0, 216.0, 234.0, 100.0], "category_id": 2}, {"id": 21, "bbox": [486.0, 681.0, 327.0, 50.0], "category_id": 2}, {"id": 22, "bbox": [22.0, 0.0, 279.0, 169.0], "category_id": 1}, {"id": 23, "bbox": [1.0, 94.0, 273.0, 256.0], "category_id": 1}, {"id": 24, "bbox": [597.0, 33.0, 313.0, 314.0], "category_id": 1}, {"id": 25, "bbox": [969.0, 60.0, 81.0, 274.0], "category_id": 1}, {"id": 26, "bbox": [26.0, 406.0, 289.0, 303.0], "category_id": 1}, {"id": 27, "bbox": [335.0, 566.0, 124.0, 59.0], "category_id": 1}, {"id": 28, "bbox": [500.0, 429.0, 309.0, 264.0], "category_id": 1}, {"id": 29, "bbox": [983.0, 426.0, 349.0, 312.0], "category_id": 1}], "reactions": [{"reactants": [22, 23], "conditions": [19, 20], "products": [24]}, {"reactants": [24, 25], "conditions": [17, 18], "products": [29]}, {"reactants": [26], "conditions": [27], "products": [28]}], "corefs": [[22, 16], [23, 12], [24, 11], [25, 10], [26, 13], [28, 15], [29, 14], [5, 4], [0, 3], [6, 2]], "caption": "Table 9. Tropane synthesis via azomethine ylides", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 727, 110], "ImageBB": [448, 116, 786, 479]}, "diagram_type": "multiple"}, {"id": 901, "width": 1352, "height": 1536, "file_name": "acs.joc.6b00020-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1042.0, 1008.0, 137.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [640.0, 1011.0, 133.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [0.0, 1072.0, 408.0, 307.0], "category_id": 1}, {"id": 3, "bbox": [406.0, 1071.0, 399.0, 300.0], "category_id": 1}, {"id": 4, "bbox": [887.0, 0.0, 394.0, 286.0], "category_id": 1}, {"id": 5, "bbox": [136.5, 589.2, 152.1, 64.5], "category_id": 3}, {"id": 6, "bbox": [872.0, 696.0, 410.0, 290.0], "category_id": 1}, {"id": 7, "bbox": [408.0, 692.0, 410.0, 303.0], "category_id": 1}, {"id": 8, "bbox": [4.0, 686.0, 391.0, 325.0], "category_id": 1}, {"id": 9, "bbox": [877.0, 313.0, 470.0, 298.0], "category_id": 1}, {"id": 10, "bbox": [410.0, 305.0, 482.0, 317.0], "category_id": 1}, {"id": 11, "bbox": [4.0, 310.0, 374.0, 250.0], "category_id": 1}, {"id": 12, "bbox": [159.0, 260.0, 44.0, 43.0], "category_id": 3}, {"id": 13, "bbox": [1083.0, 265.0, 35.0, 38.0], "category_id": 3}, {"id": 14, "bbox": [550.0, 30.0, 183.0, 52.0], "category_id": 1}, {"id": 15, "bbox": [475.0, 74.0, 343.0, 72.0], "category_id": 2}, {"id": 16, "bbox": [458.0, 174.0, 389.0, 110.0], "category_id": 2}, {"id": 17, "bbox": [19.69, 36.0, 362.0, 217.0], "category_id": 1}, {"id": 18, "bbox": [149.0, 1013.0, 126.0, 45.0], "category_id": 3}, {"id": 19, "bbox": [143.0, 1429.0, 133.0, 51.0], "category_id": 3}, {"id": 20, "bbox": [1065.0, 1427.0, 134.0, 55.0], "category_id": 3}, {"id": 21, "bbox": [545.0, 1414.0, 343.0, 120.0], "category_id": 3}, {"id": 22, "bbox": [631.0, 624.0, 153.0, 60.0], "category_id": 3}, {"id": 23, "bbox": [1024.0, 621.0, 160.0, 61.8], "category_id": 3}, {"id": 24, "bbox": [868.0, 1070.9, 469.0, 346.1], "category_id": 1}], "reactions": [{"reactants": [17], "conditions": [14, 15, 16], "products": [4]}], "corefs": [[17, 12], [4, 13], [11, 5], [10, 22], [9, 23], [8, 18], [7, 1], [6, 0], [2, 19], [3, 21], [24, 20]], "caption": "Table 1. [Co]-Catalyzed [2 + 2 + 2]-Cyclotrimerization Reaction of Diynes 2/2\u2032 with Various Alkynesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 233, 396, 263], "ImageBB": [82, 269, 420, 653]}, "diagram_type": "single"}, {"id": 396, "width": 1704, "height": 1296, "file_name": "op500102h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [495.0, 227.0, 105.9, 47.0], "category_id": 3}, {"id": 1, "bbox": [288.36, 306.0, 1319.0, 737.0], "category_id": 4}, {"id": 2, "bbox": [1248.2, 12.0, 289.1, 210.0], "category_id": 1}, {"id": 3, "bbox": [378.8, 4.0, 319.3, 212.7], "category_id": 1}, {"id": 4, "bbox": [1361.0, 230.0, 94.2, 45.4], "category_id": 3}, {"id": 5, "bbox": [757.0, 9.0, 449.2, 92.2], "category_id": 2}, {"id": 6, "bbox": [756.43, 126.85, 330.08, 105.97], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [5, 6], "products": [2]}], "corefs": [[3, 0], [2, 4]], "caption": "Table 3. Decarboxylation of 3,5-bis(\ufb02uoroalkyl)pyrazoles 5", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 781, 414, 796], "ImageBB": [10, 803, 436, 1127]}, "diagram_type": "single"}, {"id": 836, "width": 1348, "height": 996, "file_name": "jo302142v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [33.0, 568.0, 1284.0, 240.0], "category_id": 4}, {"id": 1, "bbox": [731.0, 0.0, 582.3, 268.0], "category_id": 1}, {"id": 2, "bbox": [734.0, 279.0, 577.0, 269.7], "category_id": 1}, {"id": 3, "bbox": [24.0, 189.0, 352.0, 258.3], "category_id": 1}, {"id": 4, "bbox": [408.0, 187.0, 212.0, 244.3], "category_id": 1}, {"id": 5, "bbox": [8.0, 832.0, 1340.0, 164.0], "category_id": 4}, {"id": 6, "bbox": [43.0, 85.0, 320.0, 73.0], "category_id": 2}, {"id": 7, "bbox": [862.0, 500.0, 91.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [856.0, 231.0, 95.0, 47.0], "category_id": 3}, {"id": 9, "bbox": [439.0, 442.0, 159.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [170.0, 409.0, 65.0, 47.7], "category_id": 3}], "reactions": [{"reactants": [3, 4], "conditions": [], "products": [1, 2]}], "corefs": [[3, 10], [4, 9], [1, 8], [2, 7]], "caption": "Table 1. Aldol Reactions of the (c-Hex)2B Enolate of 1a (R = MOM, Et3Si) with (\u00b1)-5a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 127], "ImageBB": [82, 131, 419, 380]}, "diagram_type": "tree"}, {"id": 375, "width": 1220, "height": 2488, "file_name": "ol101839m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [98.0, 0.0, 152.0, 124.0], "category_id": 1}, {"id": 1, "bbox": [896.7, 5.0, 144.3, 121.0], "category_id": 1}, {"id": 2, "bbox": [119.34, 143.0, 100.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [9.0, 522.0, 1211.0, 1966.0], "category_id": 4}, {"id": 4, "bbox": [926.0, 150.0, 89.7, 46.3], "category_id": 3}, {"id": 5, "bbox": [288.0, 13.0, 491.6, 50.0], "category_id": 2}, {"id": 6, "bbox": [95.0, 207.0, 1033.0, 280.0], "category_id": 4}, {"id": 7, "bbox": [293.26, 76.81, 336.85, 50.03], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [3, 7], "products": [1]}], "corefs": [[0, 2], [1, 4]], "caption": "Table 1. The Oxidation of a Variety of Secondary Alcohols with Hydrogen Peroxide Promoted by 3a ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 156, 369, 183], "ImageBB": [74, 192, 379, 814]}, "diagram_type": "single"}, {"id": 979, "width": 1352, "height": 828, "file_name": "ja064212t-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1094.99, 71.05, 234.01, 213.14], "category_id": 1}, {"id": 1, "bbox": [454.5, 758.51, 62.22, 55.49], "category_id": 3}, {"id": 2, "bbox": [734.5, 525.07, 230.63, 215.85], "category_id": 1}, {"id": 3, "bbox": [960.1, 441.2, 95.5, 60.8], "category_id": 2}, {"id": 4, "bbox": [966.6, 18.3, 94.1, 59.4], "category_id": 2}, {"id": 5, "bbox": [251.3, 16.3, 100.0, 62.5], "category_id": 2}, {"id": 6, "bbox": [389.57, 495.98, 223.87, 242.91], "category_id": 1}, {"id": 7, "bbox": [454.5, 333.58, 60.87, 54.81], "category_id": 3}, {"id": 8, "bbox": [252.3, 445.0, 97.3, 56.4], "category_id": 2}, {"id": 9, "bbox": [1094.99, 495.3, 232.66, 209.76], "category_id": 1}, {"id": 10, "bbox": [1193.06, 332.91, 58.84, 54.8], "category_id": 3}, {"id": 11, "bbox": [100.1, 757.84, 59.52, 56.16], "category_id": 3}, {"id": 12, "bbox": [1164.65, 758.51, 61.55, 55.49], "category_id": 3}, {"id": 13, "bbox": [100.1, 334.94, 58.16, 52.77], "category_id": 3}, {"id": 14, "bbox": [31.11, 495.3, 222.52, 243.59], "category_id": 1}, {"id": 15, "bbox": [734.5, 117.74, 231.99, 197.57], "category_id": 1}, {"id": 16, "bbox": [31.11, 71.72, 228.6, 244.95], "category_id": 1}, {"id": 17, "bbox": [389.57, 71.72, 231.98, 245.62], "category_id": 1}, {"id": 18, "bbox": [835.28, 334.94, 59.52, 52.1], "category_id": 3}, {"id": 19, "bbox": [805.52, 757.16, 65.6, 58.19], "category_id": 3}], "caption": "Scheme 2. Schematic Description of the (R) and (\u03b2) Conformers in Phospha(III)guanidines (X ) Lone Pair, Chalcogen) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 765, 88], "ImageBB": [439, 92, 777, 299]}, "reactions": [{"reactants": [16], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [16]}, {"reactants": [15], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [15]}, {"reactants": [14], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [14]}, {"reactants": [2], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [2]}], "diagram_type": "graph"}, {"id": 974, "width": 888, "height": 520, "file_name": "ja052327b-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [727.64, 4.0, 100.83, 148.29], "category_id": 1}, {"id": 1, "bbox": [710.76, 429.33, 33.31, 42.18], "category_id": 3}, {"id": 2, "bbox": [741.41, 407.58, 137.26, 80.36], "category_id": 1}, {"id": 3, "bbox": [375.81, 388.04, 255.43, 129.2], "category_id": 1}, {"id": 4, "bbox": [490.87, 179.81, 185.24, 96.35], "category_id": 1}, {"id": 5, "bbox": [782.72, 143.41, 105.28, 151.84], "category_id": 1}, {"id": 6, "bbox": [213.67, 150.96, 189.24, 139.41], "category_id": 1}, {"id": 7, "bbox": [2.67, 426.67, 227.44, 84.36], "category_id": 1}, {"id": 8, "bbox": [681.06, 275.04, 30.14, 37.5], "category_id": 2}], "caption": "Scheme 4. Postulated Mechanisms for the Formation of Methylcyclopentane and Methylenecyclopentane ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 257, 358, 281], "ImageBB": [131, 285, 353, 415]}, "reactions": [{"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [3]}, {"reactants": [7], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [4], "products": [0, 5]}, {"reactants": [3], "conditions": [8], "products": [2]}], "diagram_type": "graph"}, {"id": 177, "width": 1272, "height": 700, "file_name": "op0602270-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [436.0, 369.0, 400.0, 54.0], "category_id": 2}, {"id": 1, "bbox": [420.0, 29.0, 400.0, 50.0], "category_id": 2}, {"id": 2, "bbox": [956.0, 352.0, 311.0, 215.0], "category_id": 1}, {"id": 3, "bbox": [941.0, 7.0, 310.0, 217.0], "category_id": 1}, {"id": 4, "bbox": [3.0, 9.0, 312.0, 218.0], "category_id": 1}, {"id": 5, "bbox": [13.0, 349.0, 230.0, 310.0], "category_id": 1}, {"id": 6, "bbox": [368.0, 491.0, 569.0, 52.0], "category_id": 2}, {"id": 7, "bbox": [379.0, 147.0, 518.0, 48.0], "category_id": 2}, {"id": 8, "bbox": [998.0, 246.0, 260.0, 90.0], "category_id": 3}, {"id": 9, "bbox": [287.0, 602.0, 216.0, 88.0], "category_id": 3}, {"id": 10, "bbox": [995.0, 606.0, 261.0, 89.0], "category_id": 3}, {"id": 11, "bbox": [95.0, 248.0, 218.0, 83.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1, 7], "products": [3]}, {"reactants": [5], "conditions": [0, 6], "products": [2]}], "corefs": [[4, 11], [3, 8], [5, 9], [2, 10]], "caption": "Table 2. Influence of ester group on conversion and enantioselectivity ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 726, 81], "ImageBB": [449, 89, 767, 264]}, "diagram_type": "multiple"}, {"id": 315, "width": 1352, "height": 1832, "file_name": "ol3023903-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [863.0, 215.8, 134.6, 131.2], "category_id": 1}, {"id": 1, "bbox": [625.0, 396.7, 326.9, 204.3], "category_id": 1}, {"id": 2, "bbox": [1028.4, 443.4, 280.2, 233.6], "category_id": 1}, {"id": 3, "bbox": [0.0, 1094.7, 515.0, 279.3], "category_id": 1}, {"id": 4, "bbox": [27.6, 452.8, 546.8, 229.3], "category_id": 1}, {"id": 5, "bbox": [375.1, 156.7, 187.5, 191.2], "category_id": 1}, {"id": 6, "bbox": [521.0, 681.8, 454.0, 301.1], "category_id": 1}, {"id": 7, "bbox": [22.0, 760.9, 466.0, 225.1], "category_id": 1}, {"id": 8, "bbox": [973.0, 801.4, 365.6, 255.6], "category_id": 1}, {"id": 9, "bbox": [912.1, 1148.0, 351.9, 211.0], "category_id": 1}, {"id": 10, "bbox": [588.0, 1257.2, 268.6, 217.8], "category_id": 1}, {"id": 11, "bbox": [586.0, 289.1, 219.0, 67.9], "category_id": 2}, {"id": 12, "bbox": [1033.0, 1058.0, 241.0, 40.0], "category_id": 3}, {"id": 13, "bbox": [123.0, 1298.0, 148.0, 79.0], "category_id": 3}, {"id": 14, "bbox": [1032.0, 687.0, 283.0, 39.0], "category_id": 3}, {"id": 15, "bbox": [238.0, 663.0, 278.0, 42.0], "category_id": 3}, {"id": 16, "bbox": [664.0, 904.0, 118.0, 83.0], "category_id": 3}, {"id": 17, "bbox": [88.0, 984.0, 310.0, 45.0], "category_id": 3}, {"id": 18, "bbox": [971.0, 1313.0, 154.0, 68.0], "category_id": 3}, {"id": 19, "bbox": [731.0, 1434.0, 123.0, 76.0], "category_id": 3}, {"id": 20, "bbox": [477.0, 1137.0, 132.0, 76.0], "category_id": 3}, {"id": 21, "bbox": [721.0, 554.0, 146.0, 79.0], "category_id": 3}, {"id": 22, "bbox": [907.0, 351.0, 37.0, 31.0], "category_id": 3}, {"id": 23, "bbox": [607.0, 172.0, 166.0, 92.0], "category_id": 1}, {"id": 24, "bbox": [6.0, 1505.0, 1346.0, 327.0], "category_id": 2}, {"id": 25, "bbox": [451.0, 1003.0, 395.0, 225.0], "category_id": 1}, {"id": 26, "bbox": [401.0, 353.0, 27.0, 26.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [23, 11], "products": [0]}], "corefs": [[5, 26], [0, 22], [4, 15], [1, 21], [2, 14], [7, 17], [6, 16], [8, 12], [3, 13], [25, 20], [10, 19], [9, 18]], "caption": "Figure 3. Scope of the radical olefination process via strategy B.", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 530, 405, 543], "ImageBB": [71, 59, 409, 517]}, "diagram_type": "single"}, {"id": 828, "width": 1348, "height": 476, "file_name": "jo400501k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [544.0, 41.3, 199.0, 138.7], "category_id": 1}, {"id": 1, "bbox": [624.0, 205.0, 94.2, 82.8], "category_id": 2}, {"id": 2, "bbox": [272.0, 105.3, 253.0, 169.5], "category_id": 1}, {"id": 3, "bbox": [772.0, 5.0, 302.8, 372.1], "category_id": 1}, {"id": 4, "bbox": [18.0, 381.0, 1330.0, 95.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [0, 1], "products": [3]}], "corefs": [], "caption": "Table 2. Preparation of Chiral Diaminesa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 317, 110], "ImageBB": [82, 116, 419, 235]}, "diagram_type": "single"}, {"id": 1347, "width": 1352, "height": 1664, "file_name": "op700175d-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [459.52, 560.22, 228.93, 147.33], "category_id": 1}, {"id": 1, "bbox": [0.0, 827.42, 1351.09, 836.58], "category_id": 4}, {"id": 2, "bbox": [0.0, 134.85, 382.1, 184.8], "category_id": 1}, {"id": 3, "bbox": [744.22, 567.71, 61.61, 59.93], "category_id": 2}, {"id": 4, "bbox": [202.29, 272.2, 49.95, 53.27], "category_id": 3}, {"id": 5, "bbox": [527.78, 710.88, 85.75, 34.96], "category_id": 3}, {"id": 6, "bbox": [596.88, 432.86, 51.61, 63.26], "category_id": 2}, {"id": 7, "bbox": [863.27, 103.22, 487.82, 204.77], "category_id": 1}, {"id": 8, "bbox": [491.99, 309.66, 154.0, 56.6], "category_id": 2}, {"id": 9, "bbox": [459.52, 206.44, 215.61, 71.59], "category_id": 1}, {"id": 10, "bbox": [742.56, 168.98, 47.45, 61.6], "category_id": 2}, {"id": 11, "bbox": [1079.13, 611.03, 92.21, 55.96], "category_id": 2}, {"id": 12, "bbox": [978.15, 337.13, 138.18, 52.44], "category_id": 2}, {"id": 13, "bbox": [114.88, 661.77, 137.36, 53.28], "category_id": 2}, {"id": 14, "bbox": [459.52, 0.0, 213.11, 52.44], "category_id": 1}, {"id": 15, "bbox": [950.67, 611.83, 78.33, 57.77], "category_id": 2}, {"id": 16, "bbox": [459.52, 0.0, 213.11, 53.27], "category_id": 2}, {"id": 17, "bbox": [0.0, 472.81, 392.92, 185.63], "category_id": 1}, {"id": 18, "bbox": [1116.33, 279.69, 105.73, 51.61], "category_id": 3}, {"id": 19, "bbox": [596.88, 98.23, 75.75, 59.93], "category_id": 2}, {"id": 20, "bbox": [459.52, 0.0, 213.11, 52.44], "category_id": 2}], "caption": "Scheme 3. Species involved in the reaction between sulfonyl aniline 1 with cyanamide ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 392, 73], "ImageBB": [58, 79, 396, 495]}, "reactions": [{"reactants": [2, 9], "conditions": [10], "products": [7]}, {"reactants": [20], "conditions": [19], "products": [9]}, {"reactants": [9], "conditions": [], "products": [20]}, {"reactants": [9], "conditions": [6], "products": [0]}, {"reactants": [0], "conditions": [3], "products": [15, 11]}, {"reactants": [2], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [2]}], "diagram_type": "tree"}, {"id": 1131, "width": 1244, "height": 1660, "file_name": "jo991681n-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [440.93, 509.04, 748.99, 300.61], "category_id": 3}, {"id": 1, "bbox": [1067.03, 215.91, 34.04, 38.2], "category_id": 2}, {"id": 2, "bbox": [739.03, 1327.0, 494.9, 158.61], "category_id": 3}, {"id": 3, "bbox": [248.1, 157.78, 50.3, 54.62], "category_id": 3}, {"id": 4, "bbox": [0.0, 823.77, 638.56, 499.91], "category_id": 1}, {"id": 5, "bbox": [20.76, 1330.33, 724.08, 296.45], "category_id": 3}, {"id": 6, "bbox": [577.94, 3.32, 434.28, 495.76], "category_id": 1}, {"id": 7, "bbox": [651.84, 1056.29, 41.52, 49.82], "category_id": 2}, {"id": 8, "bbox": [329.08, 157.5, 39.86, 55.8], "category_id": 3}, {"id": 9, "bbox": [440.93, 212.59, 44.84, 42.35], "category_id": 2}, {"id": 10, "bbox": [739.03, 818.79, 504.97, 502.4], "category_id": 1}, {"id": 11, "bbox": [229.44, 251.16, 57.79, 49.82], "category_id": 3}, {"id": 12, "bbox": [319.12, 251.16, 53.8, 49.82], "category_id": 3}, {"id": 13, "bbox": [229.44, 346.82, 57.79, 47.83], "category_id": 3}, {"id": 14, "bbox": [321.11, 346.82, 55.8, 47.83], "category_id": 3}], "caption": "Scheme 4a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 63, 641, 77], "ImageBB": [453, 85, 764, 500]}, "reactions": [{"reactants": [3, 8], "conditions": 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Impurities derived from CDMT-mediated coupling of 2 and 4.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 533, 437, 547], "ImageBB": [82, 116, 787, 524]}, "diagram_type": "single"}, {"id": 184, "width": 1356, "height": 812, "file_name": "op060175e-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [120.0, 599.0, 205.8, 92.3], "category_id": 2}, {"id": 1, "bbox": [864.0, 287.0, 435.6, 91.2], "category_id": 2}, {"id": 2, "bbox": [3.0, 183.0, 472.0, 344.0], "category_id": 1}, {"id": 3, "bbox": [531.0, 146.0, 190.0, 66.0], "category_id": 2}, {"id": 4, "bbox": [534.0, 551.0, 208.0, 72.0], "category_id": 2}, {"id": 5, "bbox": [962.0, 201.0, 143.0, 51.0], "category_id": 2}, {"id": 6, "bbox": [1001.0, 615.0, 163.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [921.0, 718.0, 432.0, 94.0], "category_id": 2}, {"id": 8, "bbox": [600.0, 0.0, 481.0, 345.0], "category_id": 1}, {"id": 9, "bbox": [670.0, 428.0, 479.0, 354.0], "category_id": 1}, {"id": 10, "bbox": [192.0, 527.0, 87.0, 54.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [3], "products": [8, 5]}, {"reactants": [2], "conditions": [4], "products": [9, 6]}], "corefs": [[2, 10]], "caption": "Figure 2. Resolution of 1a and 4 with both antipodes of DPTTA. a: Yields were calculated relative to the theoretical amount, which is half of the starting racemate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 544, 409, 586], "ImageBB": [73, 338, 412, 541]}, "diagram_type": "tree"}, {"id": 3, "width": 1332, "height": 1220, "file_name": "jacs.5b12989-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [68.92, 18.54, 200.34, 184.61], "category_id": 1}, {"id": 1, "bbox": [771.01, 2.8, 143.67, 101.17], "category_id": 2}, {"id": 2, "bbox": [771.01, 116.14, 206.64, 175.16], "category_id": 2}, {"id": 3, "bbox": [963.06, 223.19, 299.52, 61.82], "category_id": 3}, {"id": 4, "bbox": [169.66, 223.19, 22.47, 28.76], "category_id": 3}, {"id": 5, "bbox": [2.8, 316.06, 1325.9, 896.15], "category_id": 4}, {"id": 6, "bbox": [1000.84, 24.84, 192.48, 187.75], "category_id": 1}, {"id": 7, "bbox": [558.5, 24.84, 192.47, 184.61], "category_id": 1}, {"id": 8, "bbox": [627.75, 223.19, 28.77, 28.76], "category_id": 3}, {"id": 9, "bbox": [290.88, 48.45, 132.66, 66.54], "category_id": 2}, {"id": 10, "bbox": [292.45, 135.03, 190.9, 72.84], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [9, 10], "products": [7]}, {"reactants": [7], "conditions": [1, 2], "products": [6]}], "corefs": [[0, 4], [7, 8], [6, 3]], "caption": "Table 2. Synthesis of Borylated Isocoumarins and 2-Pyrones via the Oxyboration Reactiona,b ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 413, 125], "ImageBB": [84, 131, 417, 436]}, "diagram_type": "single"}, {"id": 1096, "width": 1352, "height": 1584, "file_name": "jo961323+-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [690.03, 992.87, 68.13, 47.55], "category_id": 3}, {"id": 1, "bbox": [690.03, 1500.8, 71.3, 46.75], "category_id": 3}, {"id": 2, "bbox": [128.34, 1058.64, 342.25, 462.76], "category_id": 1}, {"id": 3, "bbox": [6.62, 1.86, 287.18, 568.57], "category_id": 1}, {"id": 4, "bbox": [965.0, 3.77, 374.61, 433.55], "category_id": 1}, {"id": 5, "bbox": [42.75, 564.73, 346.08, 437.35], "category_id": 1}, {"id": 6, "bbox": [476.3, 570.43, 346.09, 433.56], "category_id": 1}, {"id": 7, "bbox": [995.43, 566.63, 336.58, 454.47], "category_id": 1}, {"id": 8, "bbox": [1014.45, 1068.64, 273.82, 418.34], "category_id": 1}, {"id": 9, "bbox": [272.84, 298.51, 81.76, 53.24], "category_id": 2}, {"id": 10, "bbox": [761.54, 279.49, 83.67, 49.44], "category_id": 2}, {"id": 11, "bbox": [883.24, 726.36, 51.34, 51.34], "category_id": 2}, {"id": 12, "bbox": [21.83, 1241.68, 43.74, 47.54], "category_id": 2}, {"id": 13, "bbox": [61.76, 435.42, 72.26, 53.24], "category_id": 3}, {"id": 14, "bbox": [668.36, 433.52, 66.56, 53.24], "category_id": 3}, {"id": 15, "bbox": [1157.06, 431.62, 79.87, 53.24], "category_id": 3}, {"id": 16, "bbox": [250.02, 990.68, 74.16, 51.34], "category_id": 3}, {"id": 17, "bbox": [1132.34, 992.58, 76.06, 47.54], "category_id": 3}, {"id": 18, "bbox": [217.69, 1502.2, 79.87, 55.14], "category_id": 3}, {"id": 19, "bbox": [1065.79, 1500.29, 163.53, 55.15], "category_id": 3}, {"id": 20, "bbox": [417.36, 230.05, 45.63, 49.44], "category_id": 2}, {"id": 21, "bbox": [480.88, 7.13, 379.48, 438.2], "category_id": 1}, {"id": 22, "bbox": [826.3, 1242.48, 119.62, 46.75], "category_id": 2}, {"id": 23, "bbox": [463.46, 1244.85, 45.94, 44.38], "category_id": 2}, {"id": 24, "bbox": [885.71, 236.13, 35.65, 45.17], "category_id": 2}, {"id": 25, "bbox": [535.55, 1058.64, 282.03, 382.73], "category_id": 1}, {"id": 26, "bbox": [463.46, 425.52, 43.57, 45.16], "category_id": 2}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [206, 49, 275, 63], "ImageBB": [73, 70, 411, 466]}, "reactions": [{"reactants": [3], "conditions": [20], "products": [21]}, {"reactants": [21], "conditions": [24], "products": [4]}, {"reactants": [21], "conditions": [26], "products": [6]}, {"reactants": [6], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [11], "products": [7]}, {"reactants": [7], "conditions": [12], "products": [2]}, {"reactants": [2], "conditions": [23], "products": [25]}, {"reactants": [25], "conditions": [22], "products": [8]}], "diagram_type": "tree"}, {"id": 270, "width": 1352, "height": 932, "file_name": "ol801035c-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [77.0, 541.0, 227.0, 178.0], "category_id": 1}, {"id": 1, "bbox": [909.0, 706.0, 309.0, 177.0], "category_id": 1}, {"id": 2, "bbox": [399.0, 596.0, 201.0, 46.0], "category_id": 2}, {"id": 3, "bbox": [318.0, 667.0, 387.0, 123.0], "category_id": 2}, {"id": 4, "bbox": [247.0, 742.0, 33.0, 37.0], "category_id": 3}, {"id": 5, "bbox": [827.0, 742.0, 29.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [1225.0, 744.0, 26.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [1139.0, 863.0, 35.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [1052.0, 541.0, 219.0, 178.0], "category_id": 1}, {"id": 9, "bbox": [679.0, 541.0, 294.0, 176.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [9, 8, 1]}], "corefs": [[0, 4], [9, 5], [8, 6], [1, 7]], "caption": "Figure 1. 4-Thiazolylcarboxylic esters are units of the heterocyclic core in the d series of thiopeptide antibiotics exemplified by sulfomycinamte and micrococcinate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 285, 394, 327], "ImageBB": [425, 132, 763, 365]}, "diagram_type": "single"}, {"id": 134, "width": 1352, "height": 1008, "file_name": "op800270e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [816.0, 218.0, 71.0, 71.0], "category_id": 3}, {"id": 1, "bbox": [213.0, 218.0, 57.0, 60.0], "category_id": 3}, {"id": 2, "bbox": [15.0, 326.0, 1328.0, 670.0], "category_id": 4}, {"id": 3, "bbox": [1284.0, 222.0, 68.0, 63.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 4.0, 356.0, 317.9], "category_id": 1}, {"id": 5, "bbox": [598.8, 6.0, 355.2, 314.7], "category_id": 1}, {"id": 6, "bbox": [928.0, 3.0, 399.3, 311.0], "category_id": 1}, {"id": 7, "bbox": [367.0, 26.5, 216.7, 91.5], "category_id": 2}, {"id": 8, "bbox": [396.0, 124.0, 154.0, 54.5], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [7, 8], "products": [5, 6]}], "corefs": [[4, 1], [5, 0], [6, 3]], "caption": "Table 1. Effect of base and solvent on enolization selectivity of 9 ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 388, 73], "ImageBB": [58, 88, 396, 340]}, "diagram_type": "single"}, {"id": 548, "width": 1348, "height": 360, "file_name": "acs.orglett.5b03589-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [708.57, 202.92, 29.49, 39.65], "category_id": 3}, {"id": 1, "bbox": [1115.21, 211.05, 46.76, 41.68], "category_id": 3}, {"id": 2, "bbox": [554.0, 72.1, 245.0, 146.5], "category_id": 1}, {"id": 3, "bbox": [198.25, 62.12, 31.51, 36.6], "category_id": 3}, {"id": 4, "bbox": [144.37, 145.48, 210.43, 114.88], "category_id": 1}, {"id": 5, "bbox": [339.5, 109.0, 153.5, 36.0], "category_id": 2}, {"id": 6, "bbox": [816.4, 107.9, 182.6, 37.1], "category_id": 2}, {"id": 7, "bbox": [252.12, 174.96, 32.53, 36.6], "category_id": 3}, {"id": 8, "bbox": [141.0, 6.0, 205.9, 117.7], "category_id": 1}, {"id": 9, "bbox": [1020.1, 58.1, 187.9, 147.2], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [5], "products": [2]}, {"reactants": [2], "conditions": [6], "products": [9]}], "corefs": [[8, 3], [4, 7], [2, 0], [9, 1]], "caption": "Table 1. Coupling and Dehydration Reagent Investigations", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 187, 409, 202], "ImageBB": [82, 208, 419, 298]}, "diagram_type": "single"}, {"id": 112, "width": 1348, "height": 800, "file_name": "ja001164i-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [150.24, 10.55, 161.65, 188.06], "category_id": 1}, {"id": 1, "bbox": [1135.14, 214.97, 24.96, 33.03], "category_id": 3}, {"id": 2, "bbox": [599.13, 69.21, 216.64, 45.61], "category_id": 2}, {"id": 3, "bbox": [251.36, 217.27, 24.95, 34.14], "category_id": 3}, {"id": 4, "bbox": [6.23, 284.94, 1336.71, 507.81], "category_id": 4}, {"id": 5, "bbox": [537.15, 159.88, 334.86, 74.31], "category_id": 2}, {"id": 6, "bbox": [1016.81, 7.11, 180.02, 188.05], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [2, 5], "products": [6]}], "corefs": [[0, 3], [6, 1]], "caption": "Table 1. Enantioselective Protonation of 3a-f by (R)-1\u201aSnCl4a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 753, 78], "ImageBB": [439, 86, 776, 286]}, "diagram_type": "single"}, {"id": 674, "width": 1348, "height": 1052, "file_name": "ol4017854-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [165.87, 4.87, 215.23, 211.83], "category_id": 1}, {"id": 1, "bbox": [988.9, 1.0, 193.9, 227.0], "category_id": 1}, {"id": 2, "bbox": [3.4, 371.5, 1342.6, 531.5], "category_id": 4}, {"id": 3, "bbox": [261.93, 242.29, 55.37, 51.21], "category_id": 3}, {"id": 4, "bbox": [492.0, 156.0, 359.0, 48.0], "category_id": 2}, {"id": 5, "bbox": [518.0, 49.0, 299.0, 62.0], "category_id": 2}, {"id": 6, "bbox": [1084.0, 245.0, 58.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [5, 4], "products": [1]}], "corefs": [[0, 3], [1, 6]], "caption": "Table 1. Conditions Optimization", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 617, 100], "ImageBB": [436, 112, 773, 375]}, "diagram_type": "single"}, {"id": 1231, "width": 1324, "height": 900, "file_name": "op0101106-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [504.7, 847.23, 52.32, 50.35], "category_id": 3}, {"id": 1, "bbox": [28.48, 577.63, 239.76, 72.2], "category_id": 2}, {"id": 2, "bbox": [1036.55, 370.29, 49.01, 53.66], "category_id": 3}, {"id": 3, "bbox": [28.48, 688.25, 225.86, 66.91], "category_id": 2}, {"id": 4, "bbox": [88.75, 370.29, 48.35, 55.64], "category_id": 3}, {"id": 5, "bbox": [742.47, 2.65, 127.17, 88.76], "category_id": 2}, {"id": 6, "bbox": [947.8, 2.65, 376.2, 372.28], "category_id": 1}, {"id": 7, "bbox": [0.0, 15.9, 236.45, 311.33], "category_id": 1}, {"id": 8, "bbox": [291.43, 231.18, 150.34, 62.93], "category_id": 2}, {"id": 9, "bbox": [429.85, 24.51, 419.26, 373.6], "category_id": 1}, {"id": 10, "bbox": [520.59, 385.53, 48.35, 49.02], "category_id": 3}, {"id": 11, "bbox": [423.89, 473.63, 641.8, 366.98], "category_id": 1}], "caption": "Scheme 1. Previous synthetic route of 4", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 253, 668, 267], "ImageBB": [443, 273, 774, 498]}, "reactions": [{"reactants": [7], "conditions": [8], "products": [9]}, {"reactants": [9], "conditions": [5], "products": [6]}, {"reactants": [6], "conditions": [1, 3], "products": [11]}], "diagram_type": "multiple"}, {"id": 1124, "width": 872, "height": 1520, "file_name": "jo991457y-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 1345.87, 123.9, 59.31], "category_id": 2}, {"id": 1, "bbox": [0.0, 53.23, 208.27, 120.14], "category_id": 1}, {"id": 2, "bbox": [726.66, 888.12, 33.44, 46.39], "category_id": 3}, {"id": 3, "bbox": [158.1, 1304.05, 115.54, 124.7], "category_id": 1}, {"id": 4, "bbox": [702.34, 1475.14, 44.08, 42.58], "category_id": 3}, {"id": 5, "bbox": [649.89, 703.35, 149.74, 167.29], "category_id": 1}, {"id": 6, "bbox": [328.36, 32.7, 62.33, 53.98], "category_id": 2}, {"id": 7, "bbox": [70.69, 710.96, 41.81, 45.62], "category_id": 3}, {"id": 8, "bbox": [132.26, 346.73, 167.22, 69.96], "category_id": 2}, {"id": 9, "bbox": [82.85, 190.1, 38.01, 47.9], "category_id": 3}, {"id": 10, "bbox": [6.84, 587.01, 181.67, 118.62], "category_id": 1}, {"id": 11, "bbox": [607.32, 3.04, 216.63, 152.84], "category_id": 1}, {"id": 12, "bbox": [589.08, 425.05, 117.82, 63.87], "category_id": 2}, {"id": 13, "bbox": [557.16, 1008.26, 135.29, 118.62], "category_id": 2}, {"id": 14, "bbox": [608.84, 1335.99, 202.19, 120.14], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 142, 636, 156], "ImageBB": [499, 162, 717, 542]}, "reactions": [{"reactants": [1], "conditions": [6], "products": [11]}, {"reactants": [11], "conditions": [], "products": [1]}, {"reactants": [10], "conditions": [8], "products": [11]}, {"reactants": [11], "conditions": [12], "products": [5]}, {"reactants": [5], "conditions": [13], "products": [14]}, {"reactants": [14], "conditions": [], "products": [0, 3]}], "diagram_type": "tree"}, {"id": 223, "width": 1084, "height": 1884, "file_name": "op020019h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [689.0, 835.0, 395.0, 123.0], "category_id": 2}, {"id": 1, "bbox": [321.0, 6.0, 683.0, 247.0], "category_id": 1}, {"id": 2, "bbox": [1.0, 219.0, 331.0, 215.0], "category_id": 2}, {"id": 3, "bbox": [706.0, 375.0, 357.0, 54.0], "category_id": 2}, {"id": 4, "bbox": [356.0, 551.0, 608.0, 193.0], "category_id": 1}, {"id": 5, "bbox": [298.0, 987.0, 623.0, 320.0], "category_id": 1}, {"id": 6, "bbox": [290.0, 1387.0, 347.0, 110.0], "category_id": 2}, {"id": 7, "bbox": [804.0, 1419.0, 191.0, 152.0], "category_id": 1}, {"id": 8, "bbox": [479.0, 1612.0, 353.0, 185.0], "category_id": 1}, {"id": 9, "bbox": [435.0, 1831.0, 460.0, 53.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [3], "products": [4]}, {"reactants": [4], "conditions": [0], "products": [5]}, {"reactants": [5], "conditions": [6], "products": [7, 8]}], "corefs": [], "caption": "Figure 1. Periodate-coupled chromogenic assay principle for esterase/lipase activity. C2-CLIPS-O (2-hydroxy-4-(p-nitrophe- noxy)butylacetate (1)), C3-CLIPS-O (2-hydroxy-4-(p-nitrophe- noxy)butylpropionate (2)), C10-CLIPS-O (2-hydroxy-4-(p- nitrophenoxy)butyldecanoate (3)) and C16-CLIPS-O 2-hydroxy- 4-(p-nitrophenoxy)butylpalmitate (4)). 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Halogenation through a zincate intermediatea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 669, 759, 690], "ImageBB": [449, 696, 786, 990]}, "diagram_type": "single"}, {"id": 795, "width": 1348, "height": 376, "file_name": "jo501216h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [23.0, 8.0, 264.0, 167.0], "category_id": 1}, {"id": 1, "bbox": [802.0, 33.0, 265.0, 138.0], "category_id": 1}, {"id": 2, "bbox": [342.0, 5.0, 380.0, 91.0], "category_id": 2}, {"id": 3, "bbox": [344.0, 142.0, 367.0, 44.0], "category_id": 2}, {"id": 4, "bbox": [1090.0, 80.0, 235.0, 49.0], "category_id": 2}, {"id": 5, "bbox": [43.0, 193.0, 98.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [841.0, 192.0, 102.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [11.0, 262.0, 1329.0, 114.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [1]}], "corefs": [[0, 5], [1, 6]], "caption": "Table 2. 1-Iodo-4-nitrobenzene-Catalyzed Synthesis of Benzoxazoles with Oxonea ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 388, 125], "ImageBB": [82, 131, 419, 225]}, "diagram_type": "single"}, {"id": 959, "width": 1284, "height": 616, "file_name": "ja012253d-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.21, 340.81, 371.9, 204.74], "category_id": 1}, {"id": 1, "bbox": [711.05, 327.97, 308.31, 283.69], "category_id": 1}, {"id": 2, "bbox": [265.92, 35.3, 68.09, 59.69], "category_id": 2}, {"id": 3, "bbox": [404.02, 23.11, 204.9, 188.69], "category_id": 1}, {"id": 4, "bbox": [818.0, 5.81, 222.0, 166.19], "category_id": 1}, {"id": 5, "bbox": [0.0, 464.04, 69.37, 46.85], "category_id": 2}, {"id": 6, "bbox": [1114.51, 4.42, 164.61, 137.5], "category_id": 1}, {"id": 7, "bbox": [11.56, 37.87, 155.44, 158.53], "category_id": 1}], "caption": "Scheme 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 146, 125, 158], "ImageBB": [82, 158, 403, 312]}, 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Tetrahydropyridines generated via kinetic iminiums from carbon electrophile addition and subsequent reduction ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 800]}, "diagram_type": "single"}, {"id": 32, "width": 1176, "height": 1376, "file_name": "ja511913h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.06, 29.9, 199.07, 101.43], "category_id": 1}, {"id": 1, "bbox": [275.28, 3.27, 158.24, 156.47], "category_id": 1}, {"id": 2, "bbox": [518.52, 122.23, 275.42, 74.79], "category_id": 2}, {"id": 3, "bbox": [41.0, 170.09, 150.11, 31.71], "category_id": 2}, {"id": 4, "bbox": [274.5, 168.43, 158.45, 31.69], "category_id": 2}, {"id": 5, "bbox": [901.62, 166.76, 253.52, 40.03], "category_id": 2}, {"id": 6, "bbox": [506.09, 6.82, 298.5, 85.45], "category_id": 2}, {"id": 7, "bbox": [910.9, 3.27, 232.81, 154.69], "category_id": 1}, {"id": 8, "bbox": [1.85, 232.31, 1168.49, 1136.53], "category_id": 4}], "reactions": [{"reactants": [0, 1], "conditions": [6, 2], "products": [7]}], "corefs": [[0, 3], [1, 4], [7, 5]], "caption": "Table 2. Decarboxylative Ole\ufb01nation: Vinyl Halide Scopea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 407, 111], "ImageBB": [104, 116, 398, 460]}, "diagram_type": "single"}, {"id": 347, "width": 2712, "height": 2348, "file_name": "ol2017998-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1383.0, 150.0, 280.0, 77.4], "category_id": 2}, {"id": 1, "bbox": [551.7, 21.6, 350.7, 238.3], "category_id": 1}, {"id": 2, "bbox": [978.0, 46.6, 250.1, 162.7], "category_id": 1}, {"id": 3, "bbox": [1007.0, 257.0, 202.0, 54.7], "category_id": 2}, {"id": 4, "bbox": [644.1, 205.0, 154.9, 52.0], "category_id": 3}, {"id": 5, "bbox": [1828.3, 2.0, 336.9, 209.0], "category_id": 1}, {"id": 6, "bbox": [19.0, 370.6, 2693.0, 1977.4], "category_id": 4}, {"id": 7, "bbox": [1238.0, 2.0, 578.0, 116.0], "category_id": 2}, {"id": 8, "bbox": [1987.0, 208.0, 54.0, 52.0], "category_id": 3}, {"id": 9, "bbox": [1077.0, 213.0, 63.0, 44.0], "category_id": 3}, {"id": 10, "bbox": [614.0, 251.0, 217.0, 58.0], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [7, 0], "products": [5]}], "corefs": [[1, 4], [2, 9], [5, 8]], "caption": "Table 3. Preparative Palladium-Catalyzed Allylations of Substituted Aromatic Bromides Using (Z)-1b and 3a", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 651, 101], "ImageBB": [83, 112, 761, 699]}, "diagram_type": "single"}, {"id": 668, "width": 1352, "height": 2176, "file_name": "ol401909z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1028.0, 223.0, 61.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [609.0, 68.0, 189.0, 52.0], "category_id": 2}, {"id": 2, "bbox": [35.0, 305.0, 1317.0, 1871.0], "category_id": 4}, {"id": 3, "bbox": [479.0, 166.0, 29.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [864.6, 0.0, 403.0, 248.0], "category_id": 1}, {"id": 5, "bbox": [87.0, 4.0, 248.8, 244.0], "category_id": 1}, {"id": 6, "bbox": [399.8, 52.0, 168.2, 114.8], "category_id": 1}, {"id": 7, "bbox": [565.0, 130.6, 274.0, 46.6], "category_id": 2}], "reactions": [{"reactants": [5, 6], "conditions": [1, 7], "products": [4]}], "corefs": [[6, 3], [4, 0]], "caption": "Table 2. Substrate Scope of Cu-Catalyzed Synthesis of Fulleroimidazole from C60 and Amidinesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 361, 116], "ImageBB": [71, 126, 409, 670]}, "diagram_type": "single"}, {"id": 1211, "width": 1352, "height": 864, "file_name": "ol801034x-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1038.18, 299.57, 52.75, 56.12], "category_id": 3}, {"id": 1, "bbox": [1100.4, 744.52, 46.67, 55.45], "category_id": 3}, {"id": 2, "bbox": [1205.91, 342.17, 131.89, 68.98], "category_id": 2}, {"id": 3, "bbox": [32.46, 54.77, 303.68, 221.13], "category_id": 1}, {"id": 4, "bbox": [144.06, 744.52, 45.99, 55.45], "category_id": 3}, {"id": 5, "bbox": [915.76, 2.7, 351.7, 280.64], "category_id": 1}, {"id": 6, "bbox": [4.06, 502.44, 353.72, 164.32], "category_id": 1}, {"id": 7, "bbox": [105.51, 290.1, 41.93, 52.07], "category_id": 3}, {"id": 8, "bbox": [504.55, 290.1, 47.34, 59.51], "category_id": 3}, {"id": 9, "bbox": [657.4, 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"category_id": 1}], "reactions": [{"reactants": [1], "conditions": [3, 2], "products": [5]}], "corefs": [[1, 0], [5, 4]], "caption": "Figure 1 shows the 1H and 13C NMR spectra of germanium", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [438, 993, 760, 1008], "ImageBB": [450, 922, 737, 983]}, "diagram_type": "single"}, {"id": 981, "width": 1356, "height": 492, "file_name": "ja076333e-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [379.87, 42.7, 192.65, 46.1], "category_id": 2}, {"id": 1, "bbox": [417.18, 105.75, 107.18, 43.38], "category_id": 2}, {"id": 2, "bbox": [69.87, 156.58, 153.98, 44.07], "category_id": 3}, {"id": 3, "bbox": [627.46, 2.71, 437.53, 181.67], "category_id": 1}, {"id": 4, "bbox": [513.5, 385.02, 141.78, 46.77], "category_id": 2}, {"id": 5, "bbox": [0.0, 4.07, 338.49, 157.26], "category_id": 1}, {"id": 6, "bbox": [497.22, 258.94, 146.52, 96.93], "category_id": 1}, {"id": 7, "bbox": [721.07, 252.84, 634.93, 185.05], 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Synthesis of Lys-NTA-SH", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 274, 76], "ImageBB": [73, 80, 412, 203]}, "reactions": [{"reactants": [5], "conditions": [0, 1], "products": [3]}, {"reactants": [3], "conditions": [10, 12], "products": [8]}, {"reactants": [8], "conditions": [6, 4], "products": [7]}], "diagram_type": "multiple"}, {"id": 763, "width": 1384, "height": 1620, "file_name": "jo961824v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1081.0, 1516.0, 27.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [88.0, 308.0, 285.0, 214.0], "category_id": 1}, {"id": 2, "bbox": [852.0, 498.0, 132.0, 46.0], "category_id": 2}, {"id": 3, "bbox": [856.0, 417.0, 528.0, 48.0], "category_id": 2}, {"id": 4, "bbox": [573.0, 244.0, 232.0, 427.0], "category_id": 1}, {"id": 5, "bbox": [94.0, 892.0, 470.0, 552.0], "category_id": 1}, {"id": 6, "bbox": [878.0, 895.0, 469.0, 555.0], "category_id": 1}, {"id": 7, "bbox": [668.0, 1202.0, 91.0, 42.0], "category_id": 2}, {"id": 8, "bbox": [681.0, 1112.0, 65.0, 54.0], "category_id": 2}, {"id": 9, "bbox": [610.0, 694.0, 436.0, 149.0], "category_id": 3}, {"id": 10, "bbox": [128.0, 723.0, 417.9, 93.7], "category_id": 3}, {"id": 11, "bbox": [219.0, 1476.3, 396.3, 141.7], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [3, 2], "products": [5]}, {"reactants": [5], "conditions": [8, 7], "products": [6]}], "corefs": [[1, 10], [4, 9], [5, 11], [6, 0]], "caption": " Table 1. BF3-Promoted Addition Reaction of 1,2-Naphthoquinones with 1,1-Diarylethylenesa ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [469, 437, 743, 462], "ImageBB": [424, 20, 770, 425]}, "diagram_type": "multiple"}, {"id": 22, "width": 1352, "height": 1080, "file_name": "ja905415r-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [431.53, 84.4, 251.45, 105.12], "category_id": 2}, {"id": 1, "bbox": [990.35, 31.45, 279.31, 258.41], "category_id": 1}, {"id": 2, "bbox": [710.24, 4.97, 254.23, 291.86], "category_id": 1}, {"id": 3, "bbox": [76.18, 59.32, 336.45, 234.72], "category_id": 1}, {"id": 4, "bbox": [2.32, 321.3, 1343.99, 753.13], "category_id": 4}, {"id": 5, "bbox": [1178.47, 265.56, 56.35, 42.41], "category_id": 3}, {"id": 6, "bbox": [306.11, 266.96, 54.96, 41.01], "category_id": 3}, {"id": 7, "bbox": [431.53, 204.25, 248.66, 49.38], "category_id": 2}, {"id": 8, "bbox": [863.53, 271.14, 53.56, 42.41], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0, 7], "products": [2, 1]}], "corefs": [[3, 6], [2, 8], [1, 5]], "caption": "Table 5. Comparison of the enantioselectivities of 2a and 3a, isolated from the reaction of 1a using different Au catalysts.a ", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 365, 81], "ImageBB": [58, 89, 396, 359]}, "diagram_type": "single"}, {"id": 402, "width": 1704, "height": 1124, "file_name": "op400278d-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [65.1, 18.1, 217.7, 175.9], "category_id": 1}, {"id": 1, "bbox": [611.0, 121.0, 333.0, 101.0], "category_id": 2}, {"id": 2, "bbox": [609.0, 0.0, 345.0, 96.0], "category_id": 2}, {"id": 3, "bbox": [981.0, 0.0, 427.0, 221.0], "category_id": 1}, {"id": 4, "bbox": [603.0, 764.0, 298.0, 76.0], "category_id": 3}, {"id": 5, "bbox": [180.0, 762.0, 265.0, 82.0], "category_id": 3}, {"id": 6, "bbox": [83.0, 199.0, 197.0, 92.0], "category_id": 3}, {"id": 7, "bbox": [332.0, 203.0, 189.0, 90.0], "category_id": 3}, {"id": 8, "bbox": [1176.0, 203.0, 68.0, 47.0], "category_id": 3}, {"id": 9, "bbox": [532.45, 311.04, 429.55, 413.96], "category_id": 1}, {"id": 10, "bbox": [82.5, 308.5, 429.5, 432.0], "category_id": 1}, {"id": 11, "bbox": [1113.97, 760.0, 161.0, 59.0], "category_id": 3}, {"id": 12, "bbox": [979.47, 313.07, 430.93, 407.43], "category_id": 1}, {"id": 13, "bbox": [309.51, 12.09, 248.61, 191.35], "category_id": 1}], "reactions": [{"reactants": [0, 13], "conditions": [2, 1], "products": [3]}], "corefs": [[0, 6], [13, 7], [3, 8], [10, 5], [9, 4], [12, 11]], "caption": "Table 9. Pyridine optimization of the IPentCl-Pd-based pre- catalysts in room temperature aryl aminations ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 797, 782, 830], "ImageBB": [433, 846, 859, 1127]}, "diagram_type": "single"}, {"id": 911, "width": 2820, "height": 3452, "file_name": "acs.joc.5b00301-Figure-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [210.0, 1965.0, 2365.7, 1487.0], "category_id": 4}, {"id": 1, "bbox": [345.6, 1049.1, 177.4, 133.6], "category_id": 1}, {"id": 2, "bbox": [1953.0, 1196.0, 136.0, 62.0], "category_id": 2}, {"id": 3, "bbox": [2143.0, 1182.0, 111.0, 88.0], "category_id": 2}, {"id": 4, "bbox": [417.0, 1626.0, 128.0, 83.0], "category_id": 2}, {"id": 5, "bbox": [896.0, 1626.0, 136.0, 85.0], "category_id": 2}, {"id": 6, "bbox": [762.0, 1173.0, 120.0, 88.0], "category_id": 2}, {"id": 7, "bbox": [1811.7, 110.4, 163.5, 127.7], "category_id": 1}, {"id": 8, "bbox": [1966.4, 343.1, 273.3, 272.7], "category_id": 1}, {"id": 9, "bbox": [1240.4, 0.0, 319.8, 183.1], "category_id": 1}, {"id": 10, "bbox": [563.0, 1176.0, 134.0, 80.0], "category_id": 2}, {"id": 11, "bbox": [1818.0, 1632.0, 120.0, 73.5], "category_id": 2}, {"id": 12, "bbox": [2271.0, 1636.8, 131.2, 69.2], "category_id": 2}, {"id": 13, "bbox": [583.4, 347.0, 268.8, 263.1], "category_id": 1}, {"id": 14, "bbox": [254.42, 1769.15, 247.65, 181.21], "category_id": 1}, {"id": 15, "bbox": [932.96, 1769.15, 235.57, 183.23], "category_id": 1}, {"id": 16, "bbox": [1647.74, 1767.14, 237.59, 185.24], "category_id": 1}, {"id": 17, "bbox": [2328.29, 1767.14, 221.48, 183.22], "category_id": 1}, {"id": 18, "bbox": [579.4, 783.0, 278.5, 272.3], "category_id": 1}, {"id": 19, "bbox": [932.0, 1048.0, 161.9, 133.2], "category_id": 1}, {"id": 20, "bbox": [1969.2, 785.0, 266.5, 269.5], "category_id": 1}, {"id": 21, "bbox": [2320.8, 1054.2, 153.8, 129.8], "category_id": 1}, {"id": 22, "bbox": [1726.4, 1056.0, 174.8, 123.5], "category_id": 1}, {"id": 23, "bbox": [893.22, 1308.92, 331.28, 266.3], "category_id": 1}, {"id": 24, "bbox": [215.0, 1305.5, 335.9, 271.2], "category_id": 1}, {"id": 25, "bbox": [1597.8, 1308.1, 328.0, 267.8], "category_id": 1}, {"id": 26, "bbox": [2274.7, 1310.7, 323.9, 267.5], "category_id": 1}, {"id": 27, "bbox": [847.2, 111.0, 178.5, 129.5], "category_id": 1}], "reactions": [{"reactants": [14], "conditions": [], "products": [24]}, {"reactants": [24], "conditions": [], "products": [14]}, {"reactants": [15], "conditions": [], "products": [23]}, {"reactants": [23], "conditions": [], "products": [15]}, {"reactants": [24], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [1], "products": [24]}, {"reactants": [23], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [19], "products": [23]}, {"reactants": [18], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [18]}, {"reactants": [13], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [27], "products": [13]}, {"reactants": [9], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [7], "products": [9]}, {"reactants": [8], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [], "products": [8]}, {"reactants": [20], "conditions": [22], "products": [25]}, {"reactants": [25], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [21], "products": [26]}, {"reactants": [26], "conditions": [], "products": [20]}, {"reactants": [25], "conditions": [], "products": [16]}, {"reactants": [16], "conditions": [], "products": [25]}, {"reactants": [26], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [26]}], "corefs": [], "caption": "Figure 8. Overlaid benzoin reaction coordinates: pyrrolidinone-based triazolium (I\u2032).", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 988, 487, 1002], "ImageBB": [82, 116, 787, 979]}, "diagram_type": "tree"}, {"id": 887, "width": 1356, "height": 796, "file_name": "ol5029892-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1142.03, 249.92, 66.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [731.2, 56.0, 289.8, 100.7], "category_id": 2}, {"id": 2, "bbox": [159.0, 245.0, 64.9, 51.9], "category_id": 3}, {"id": 3, "bbox": [404.3, 109.0, 233.8, 107.9], "category_id": 1}, {"id": 4, "bbox": [765.0, 323.0, 217.0, 50.0], "category_id": 2}, {"id": 5, "bbox": [1105.1, 5.1, 145.7, 227.9], "category_id": 1}, {"id": 6, "bbox": [494.0, 248.9, 57.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [105.2, 104.4, 171.8, 126.4], "category_id": 1}, {"id": 8, "bbox": [726.2, 181.0, 287.8, 137.9], "category_id": 1}, {"id": 9, "bbox": [34.0, 396.0, 1288.0, 379.0], "category_id": 4}], "reactions": [{"reactants": [7, 3], "conditions": [1, 8], "products": [5]}], "corefs": [[7, 2], [3, 6], [5, 0]], "caption": "Table 3. Reactivity of Benzylic Grignard Reagent with O- Benzoyl-N-hydroxypiperidine ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 773, 125], "ImageBB": [448, 131, 787, 330]}, "diagram_type": "single"}, {"id": 1020, "width": 2820, "height": 1624, "file_name": "jacs.5b07904-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [983.26, 761.44, 237.0, 249.58], "category_id": 1}, {"id": 1, "bbox": [2420.77, 954.62, 196.09, 188.95], "category_id": 1}, {"id": 2, "bbox": [538.89, 342.65, 173.52, 181.9], "category_id": 1}, {"id": 3, "bbox": [313.18, 349.7, 166.46, 149.47], "category_id": 1}, {"id": 4, "bbox": [766.01, 851.69, 136.84, 60.63], "category_id": 2}, {"id": 5, "bbox": [403.46, 1198.56, 253.93, 256.64], "category_id": 1}, {"id": 6, "bbox": [909.9, 1294.45, 162.24, 142.42], "category_id": 1}, {"id": 7, "bbox": [1083.42, 38.07, 179.16, 194.59], "category_id": 1}, {"id": 8, "bbox": [1763.38, 650.04, 258.16, 249.59], "category_id": 1}, {"id": 9, "bbox": [2413.72, 305.99, 203.14, 197.41], "category_id": 1}, {"id": 10, "bbox": [2018.72, 1238.05, 232.77, 249.58], "category_id": 1}, {"id": 11, "bbox": [1596.92, 153.7, 93.11, 47.94], "category_id": 2}, {"id": 12, "bbox": [1591.28, 1403.02, 102.98, 43.72], "category_id": 2}, {"id": 13, "bbox": [2011.67, 259.45, 239.82, 93.07], "category_id": 2}, {"id": 14, "bbox": [2413.72, 1173.18, 229.94, 56.41], "category_id": 2}, {"id": 15, "bbox": [1763.38, 0.0, 239.82, 252.4], "category_id": 1}, {"id": 16, "bbox": [2011.67, 0.0, 244.05, 252.4], "category_id": 1}, {"id": 17, "bbox": [2011.67, 0.0, 245.46, 249.58], "category_id": 1}, {"id": 18, "bbox": [1297.24, 45.25, 180.77, 185.03], "category_id": 1}, {"id": 19, "bbox": [2028.8, 655.62, 244.59, 240.31], "category_id": 1}, {"id": 20, "bbox": [1994.8, 1493.53, 233.93, 89.33], "category_id": 2}, {"id": 21, "bbox": [730.75, 917.96, 213.01, 43.71], "category_id": 2}, {"id": 22, "bbox": [1340.8, 1280.35, 179.94, 188.95], "category_id": 1}, {"id": 23, "bbox": [1113.2, 1491.86, 206.1, 94.47], "category_id": 2}, {"id": 24, "bbox": [2011.7, 450.1, 166.43, 130.85], "category_id": 2}, {"id": 25, "bbox": [1733.76, 1496.09, 234.94, 90.24], "category_id": 2}, {"id": 26, "bbox": [2412.31, 542.88, 236.99, 52.17], "category_id": 2}, {"id": 27, "bbox": [1231.5, 1128.4, 112.9, 115.29], "category_id": 2}, {"id": 28, "bbox": [876.59, 57.4, 156.11, 139.3], "category_id": 1}, {"id": 29, "bbox": [2011.67, 1039.23, 170.93, 137.97], "category_id": 2}, {"id": 30, "bbox": [1223.08, 1011.02, 242.64, 87.43], "category_id": 2}, {"id": 31, "bbox": [1733.76, 259.45, 258.16, 93.07], "category_id": 2}, {"id": 32, "bbox": [952.23, 1012.43, 244.05, 81.79], "category_id": 2}, {"id": 33, "bbox": [1125.8, 1278.94, 181.92, 190.36], "category_id": 1}, {"id": 34, "bbox": [517.0, 573.5, 115.0, 120.26], "category_id": 2}, {"id": 35, "bbox": [536.07, 139.6, 124.14, 111.39], "category_id": 2}, {"id": 36, "bbox": [1248.47, 760.03, 231.36, 250.99], "category_id": 1}, {"id": 37, "bbox": [1591.28, 1338.16, 114.26, 53.58], "category_id": 2}, {"id": 38, "bbox": [399.23, 764.26, 248.28, 256.63], "category_id": 1}, {"id": 39, "bbox": [1760.56, 1233.82, 237.0, 253.81], "category_id": 1}, {"id": 40, "bbox": [1338.76, 1490.45, 204.55, 91.65], "category_id": 2}, {"id": 41, "bbox": [1578.58, 84.6, 126.96, 60.64], "category_id": 2}, {"id": 42, "bbox": [580.54, 196.25, 131.86, 99.95], "category_id": 2}], "caption": "Scheme 2. Enantioselectively Competing Reaction Pathways Involving Kinetic Resolution ((S)-Pathway) and Chiral Catalysis ((R)-Pathway) for the (S)-Pr-Mediated Asymmetric Hydrogenation of IP on Supported Pd Catalyst ", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 784, 125], "ImageBB": [82, 131, 787, 537]}, "reactions": [{"reactants": [3, 2], "conditions": [35, 42], "products": [28, 7, 18]}, {"reactants": [28, 7, 18], "conditions": [41], "products": [15, 17]}, {"reactants": [15, 17], "conditions": [11], "products": [28, 7, 18]}, {"reactants": [15, 17], "conditions": [24], "products": [8, 19]}, {"reactants": [38], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [38]}, {"reactants": [38], "conditions": [], "products": [3, 2]}, {"reactants": [3, 2], "conditions": [34], "products": [38]}, {"reactants": [38], "conditions": [4, 21], "products": [0, 36]}, {"reactants": [0, 36], "conditions": [27], "products": [6, 33, 32]}, {"reactants": [6, 33, 32], "conditions": [], "products": [0, 36]}, {"reactants": [6, 33, 32], "conditions": [37], "products": [39, 10]}, {"reactants": [39, 10], "conditions": [12], "products": [6, 33, 32]}, {"reactants": [39, 10], "conditions": [29], "products": [8, 19]}], "diagram_type": "graph"}, {"id": 730, "width": 1348, "height": 644, "file_name": "ol016212y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [930.0, 281.0, 321.0, 43.0], "category_id": 2}, {"id": 1, "bbox": [1.0, 352.0, 1347.0, 292.0], "category_id": 4}, {"id": 2, "bbox": [406.0, 92.0, 377.0, 51.0], "category_id": 2}, {"id": 3, "bbox": [442.0, 169.0, 357.0, 94.0], "category_id": 2}, {"id": 4, "bbox": [101.2, 5.0, 266.6, 230.8], "category_id": 1}, {"id": 5, "bbox": [920.0, 6.0, 313.8, 237.0], "category_id": 1}, {"id": 6, "bbox": [107.5, 277.0, 340.5, 55.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [2, 3], "products": [5]}], "corefs": [], "caption": "Table 4. Titanium-Mediated Addition of Et2Zn to PhCHO Using P2 and 2 ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 748, 104], "ImageBB": [439, 107, 776, 268]}, "diagram_type": "single"}, {"id": 358, "width": 1348, "height": 3576, "file_name": "ol200038n-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [298.0, 688.0, 279.5, 101.0], "category_id": 2}, {"id": 1, "bbox": [300.0, 549.0, 352.8, 96.0], "category_id": 2}, {"id": 2, "bbox": [463.0, 420.0, 330.0, 77.0], "category_id": 1}, {"id": 3, "bbox": [298.0, 805.0, 290.5, 58.0], "category_id": 2}, {"id": 4, "bbox": [623.0, 1633.0, 146.4, 40.0], "category_id": 3}, {"id": 5, "bbox": [2.0, 2136.0, 1346.0, 614.0], "category_id": 2}, {"id": 6, "bbox": [760.0, 1683.0, 407.0, 281.0], "category_id": 1}, {"id": 7, "bbox": [81.0, 1690.0, 628.0, 292.0], "category_id": 1}, {"id": 8, "bbox": [886.0, 1332.0, 411.0, 278.0], "category_id": 1}, {"id": 9, "bbox": [482.0, 1328.0, 399.0, 275.0], "category_id": 1}, {"id": 10, "bbox": [49.0, 1256.0, 430.0, 420.0], "category_id": 1}, {"id": 11, "bbox": [699.0, 964.0, 412.0, 275.0], "category_id": 1}, {"id": 12, "bbox": [211.0, 962.0, 412.0, 282.0], "category_id": 1}, {"id": 13, "bbox": [827.0, 900.0, 35.0, 35.0], "category_id": 3}, {"id": 14, "bbox": [607.0, 637.0, 393.0, 263.0], "category_id": 1}, {"id": 15, "bbox": [800.0, 420.0, 51.0, 56.0], "category_id": 3}, {"id": 16, "bbox": [1070.0, 642.0, 35.0, 50.0], "category_id": 3}, {"id": 17, "bbox": [882.0, 344.0, 372.0, 322.0], "category_id": 1}, {"id": 18, "bbox": [291.0, 427.0, 231.0, 94.0], "category_id": 2}, {"id": 19, "bbox": [293.0, 329.0, 449.0, 93.0], "category_id": 2}, {"id": 20, "bbox": [2.0, 113.0, 1282.0, 175.0], "category_id": 2}, {"id": 21, "bbox": [940.0, 1967.0, 147.8, 51.0], "category_id": 3}, {"id": 22, "bbox": [1034.79, 1633.59, 143.6, 40.0], "category_id": 3}, {"id": 23, "bbox": [276.0, 2962.0, 802.0, 608.0], "category_id": 1}, {"id": 24, "bbox": [89.0, 514.0, 182.0, 51.0], "category_id": 2}, {"id": 25, "bbox": [845.0, 1254.0, 151.6, 44.0], "category_id": 3}, {"id": 26, "bbox": [274.0, 1632.0, 144.2, 40.0], "category_id": 3}, {"id": 27, "bbox": [489.0, 1964.0, 139.9, 55.0], "category_id": 3}, {"id": 28, "bbox": [419.0, 1256.0, 148.6, 44.0], "category_id": 3}], "reactions": [{"reactants": [24], "conditions": [19, 18, 2, 1], "products": [17]}, {"reactants": [17], "conditions": [0, 3], "products": [14]}], "corefs": [[2, 15], [17, 16], [14, 13], [12, 28], [11, 25], [10, 26], [9, 4], [8, 22], [7, 27], [6, 21]], "caption": "Figure 1. Single-crystal X-ray structure of 2a. Hydrogen atoms are omitted for clarity except polar N-H bonds. Selected bond lengths (A\u030a): N1-C1 1.390(2), N1-C6 1.363(2), N2-N3 1.350(2), N2-C4 1.372(2), N3-C5 1.327(2), N4-N2 1.438(2). ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 966, 771, 1021], "ImageBB": [436, 59, 773, 953]}, "diagram_type": "multiple"}, {"id": 1245, "width": 1248, "height": 1400, "file_name": "op0300488-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [972.31, 619.81, 130.3, 70.74], "category_id": 2}, {"id": 1, "bbox": [695.61, 49.72, 526.08, 314.46], "category_id": 1}, {"id": 2, "bbox": [491.06, 82.64, 125.39, 62.33], "category_id": 2}, {"id": 3, "bbox": [63.75, 586.19, 198.24, 84.05], "category_id": 1}, {"id": 4, "bbox": [179.33, 301.15, 45.53, 46.92], "category_id": 3}, {"id": 5, "bbox": [941.49, 1354.48, 56.74, 45.52], "category_id": 3}, {"id": 6, "bbox": [727.13, 1071.54, 481.25, 284.34], "category_id": 1}, {"id": 7, "bbox": [305.42, 552.58, 562.51, 310.95], "category_id": 1}, {"id": 8, "bbox": [0.0, 11.21, 442.02, 233.21], "category_id": 1}, {"id": 9, "bbox": [32.22, 1055.43, 535.9, 233.21], "category_id": 1}, {"id": 10, "bbox": [253.59, 1310.36, 65.14, 47.62], "category_id": 3}], "caption": "Scheme 1. Allylation of \u03b2-D-glucose pentaacetate 2 using ZnCl2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 284, 392, 313], "ImageBB": [86, 316, 398, 666]}, "reactions": [{"reactants": [8], "conditions": [2], "products": [1]}, {"reactants": [1], "conditions": [3], "products": [7]}, {"reactants": [7], "conditions": [0], "products": [9, 6]}], "diagram_type": "multiple"}, {"id": 1158, "width": 1352, "height": 416, "file_name": "ol052113z-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [746.68, 296.7, 195.82, 62.9], "category_id": 2}, {"id": 1, "bbox": [144.78, 101.45, 81.57, 54.04], "category_id": 2}, {"id": 2, "bbox": [261.02, 96.35, 174.35, 60.16], "category_id": 2}, {"id": 3, "bbox": [524.08, 100.43, 267.14, 67.3], "category_id": 2}, {"id": 4, "bbox": [89.73, 4.59, 137.64, 57.1], "category_id": 2}, {"id": 5, "bbox": [268.16, 7.65, 101.96, 55.06], "category_id": 2}, {"id": 6, "bbox": [450.67, 3.57, 186.58, 65.25], "category_id": 2}, {"id": 7, "bbox": [684.16, 10.71, 151.92, 59.13], "category_id": 2}, {"id": 8, "bbox": [932.94, 7.65, 214.12, 64.23], "category_id": 2}, {"id": 9, "bbox": [1190.9, 15.8, 79.53, 47.93], "category_id": 2}, {"id": 10, "bbox": [384.39, 1.53, 54.04, 30.59], "category_id": 2}, {"id": 11, "bbox": [666.82, 190.16, 53.02, 29.57], "category_id": 2}, {"id": 12, "bbox": [1087.92, 192.2, 139.69, 60.15], "category_id": 2}, {"id": 13, "bbox": [968.63, 194.24, 76.47, 59.13], "category_id": 2}, {"id": 14, "bbox": [736.16, 193.22, 188.62, 59.13], "category_id": 2}, {"id": 15, "bbox": [425.18, 190.16, 219.21, 67.29], "category_id": 2}, {"id": 16, "bbox": [981.88, 305.37, 91.77, 50.98], "category_id": 2}, {"id": 17, "bbox": [480.24, 299.25, 172.31, 58.12], "category_id": 2}, {"id": 18, "bbox": [865.71, 96.08, 355.76, 69.69], "category_id": 2}, {"id": 19, "bbox": [140.0, 187.42, 248.0, 71.04], "category_id": 2}, {"id": 20, "bbox": [327.35, 306.2, 107.75, 57.81], "category_id": 2}], "caption": "Scheme 5. Possible Single-Electron-Transfer Pathway", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [462, 75, 751, 88], "ImageBB": [439, 93, 777, 197]}, "reactions": [{"reactants": [4, 5], "conditions": [10], "products": [6, 7]}, {"reactants": [6, 7], "conditions": [], "products": [4, 5]}, {"reactants": [6, 7], "conditions": [], "products": [8, 9]}, {"reactants": [8, 9], "conditions": [], "products": [6, 7]}, {"reactants": [1, 2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [1, 2]}, {"reactants": [3], "conditions": [], "products": [18]}, {"reactants": [19, 15], "conditions": [11], "products": [14, 13, 12]}, {"reactants": [20, 17], "conditions": [], "products": [0, 16]}], "diagram_type": "multiple"}, {"id": 712, "width": 1348, "height": 1088, "file_name": "ol034469l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [592.0, 147.0, 326.0, 71.0], "category_id": 2}, {"id": 1, "bbox": [932.0, 18.0, 228.0, 189.0], "category_id": 1}, {"id": 2, "bbox": [193.0, 63.0, 378.0, 143.0], "category_id": 1}, {"id": 3, "bbox": [1018.0, 201.0, 75.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [346.0, 201.0, 72.0, 60.0], "category_id": 3}, {"id": 5, "bbox": [633.0, 0.0, 249.0, 144.0], "category_id": 2}, {"id": 6, "bbox": [2.0, 280.0, 1342.0, 808.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [5, 0], "products": [1]}], "corefs": [[2, 4], [1, 3]], "caption": "Table 1. Screen of Solvents and Br\u00f8nsted Acids", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 314, 698, 327], "ImageBB": [439, 331, 776, 603]}, "diagram_type": "single"}, {"id": 176, "width": 1336, "height": 880, "file_name": "op0602270-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 232.0, 559.0, 181.7], "category_id": 3}, {"id": 1, "bbox": [734.0, 225.72, 602.0, 189.18], "category_id": 3}, {"id": 2, "bbox": [826.0, 778.0, 455.0, 88.0], "category_id": 3}, {"id": 3, "bbox": [31.0, 785.0, 403.0, 88.6], "category_id": 3}, {"id": 4, "bbox": [412.0, 502.0, 393.0, 60.0], "category_id": 2}, {"id": 5, "bbox": [307.0, 607.0, 543.0, 60.0], "category_id": 2}, {"id": 6, "bbox": [394.0, 16.0, 399.0, 64.0], "category_id": 2}, {"id": 7, "bbox": [362.0, 122.0, 495.0, 62.0], "category_id": 2}, {"id": 8, "bbox": [13.0, 481.0, 249.0, 300.0], "category_id": 1}, {"id": 9, "bbox": [869.0, 488.0, 337.0, 218.0], "category_id": 1}, {"id": 10, "bbox": [4.0, 1.0, 340.0, 216.0], "category_id": 1}, {"id": 11, "bbox": [863.0, 0.0, 355.0, 219.0], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [6, 7], "products": [11]}, {"reactants": [8], "conditions": [4, 5], "products": [9]}], "corefs": [[10, 0], [11, 1], [8, 3], [9, 2]], "caption": "Table 3. Influence of \u03b23-substitution on conversion and enantioselectivity ", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 377, 81], "ImageBB": [75, 89, 409, 309]}, "diagram_type": "multiple"}, {"id": 1138, "width": 1352, "height": 668, "file_name": "ol010283f-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [630.35, 469.78, 179.9, 46.64], "category_id": 2}, {"id": 1, "bbox": [630.35, 537.37, 171.11, 44.61], "category_id": 2}, {"id": 2, "bbox": [71.69, 10.82, 250.25, 250.77], "category_id": 1}, {"id": 3, "bbox": [1094.99, 138.57, 166.38, 40.55], "category_id": 2}, {"id": 4, "bbox": [375.37, 65.57, 257.01, 65.56], "category_id": 2}, {"id": 5, "bbox": [142.71, 406.24, 399.04, 199.4], "category_id": 1}, {"id": 6, "bbox": [1095.67, 54.75, 162.32, 79.76], "category_id": 2}, {"id": 7, "bbox": [462.62, 156.82, 79.13, 44.61], "category_id": 2}, {"id": 8, "bbox": [872.48, 458.29, 333.43, 146.68], "category_id": 1}, {"id": 9, "bbox": [698.66, 0.0, 274.59, 273.76], "category_id": 1}], "caption": "Scheme 2. Proposed Mechanism", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [517, 75, 698, 88], "ImageBB": [439, 94, 777, 261]}, "reactions": [{"reactants": [2], "conditions": [4, 7], "products": [9]}, {"reactants": [9], "conditions": [6, 3], "products": [5]}, {"reactants": [5], "conditions": [0, 1], "products": [8]}], "diagram_type": "multiple"}, {"id": 1069, "width": 1356, "height": 520, "file_name": "jo400501k-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [408.36, 0.0, 217.07, 166.25], "category_id": 1}, {"id": 1, "bbox": [1136.22, 289.07, 215.71, 188.65], "category_id": 1}, {"id": 2, "bbox": [1160.64, 2.71, 187.22, 171.01], "category_id": 1}, {"id": 3, "bbox": [4.07, 21.04, 230.64, 143.85], "category_id": 1}, {"id": 4, "bbox": [1138.25, 189.32, 80.73, 69.9], "category_id": 2}, {"id": 5, "bbox": [790.94, 0.0, 191.97, 181.86], "category_id": 1}, {"id": 6, "bbox": [255.06, 43.43, 122.1, 52.25], "category_id": 2}, {"id": 7, "bbox": [1010.05, 100.43, 105.82, 47.5], "category_id": 2}, {"id": 8, "bbox": [996.48, 32.57, 122.78, 50.22], "category_id": 2}, {"id": 9, "bbox": [619.32, 32.57, 135.67, 55.65], "category_id": 2}], "caption": "Scheme 6. Mechanism of the Diamine Synthesis", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 636, 721, 651], "ImageBB": [448, 657, 787, 787]}, "reactions": [{"reactants": [3], "conditions": [6], "products": [0]}, {"reactants": [0], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [8, 7], "products": [2]}, {"reactants": [2], "conditions": [4], "products": [1]}], "diagram_type": "tree"}], "roles": [{"id": 1, "name": "reactants"}, {"id": 2, "name": "conditions"}, {"id": 3, "name": "products"}]}