dev0.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 1376, "width": 1200, "height": 2316, "file_name": "op990067a-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [320.77, 2114.41, 164.45, 82.26], "category_id": 2}, {"id": 1, "bbox": [809.46, 2080.81, 259.4, 120.49], "category_id": 1}, {"id": 2, "bbox": [397.2, 1064.73, 409.95, 285.01], "category_id": 1}, {"id": 3, "bbox": [877.79, 309.34, 195.71, 57.93], "category_id": 2}, {"id": 4, "bbox": [152.86, 279.22, 257.08, 114.7], "category_id": 1}, {"id": 5, "bbox": [620.71, 1387.98, 37.05, 46.34], "category_id": 3}, {"id": 6, "bbox": [620.71, 2256.91, 56.74, 59.09], "category_id": 3}, {"id": 7, "bbox": 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Conversion of Acid 27 to Akt Inhibitor 1", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 378, 110], "ImageBB": [82, 116, 420, 612]}, "reactions": [{"reactants": [18], "conditions": [2, 19], "products": [20]}, {"reactants": [20], "conditions": [22, 12], "products": [0, 5]}, {"reactants": [0], "conditions": [6], "products": [5]}, {"reactants": [5], "conditions": [24, 15], "products": [25]}, {"reactants": [25], "conditions": [14, 11], "products": [23]}, {"reactants": [23], "conditions": [26, 17], "products": [21]}, {"reactants": [21], "conditions": [9], "products": [3, 1]}], "diagram_type": "multiple"}, {"id": 1099, "width": 1280, "height": 944, "file_name": "jo962200s-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [618.55, 566.73, 459.75, 342.61], "category_id": 1}, {"id": 1, "bbox": [1238.38, 698.01, 41.62, 56.35], "category_id": 3}, {"id": 2, "bbox": [138.31, 132.56, 201.7, 129.35], "category_id": 1}, {"id": 3, "bbox": [851.63, 404.08, 40.98, 45.46], "category_id": 3}, {"id": 4, "bbox": [731.25, 94.78, 304.79, 283.04], "category_id": 1}, {"id": 5, "bbox": [0.0, 235.02, 37.78, 53.15], "category_id": 3}, {"id": 6, "bbox": [0.0, 572.5, 517.38, 302.9], "category_id": 1}, {"id": 7, "bbox": [242.04, 894.61, 51.87, 42.9], "category_id": 3}, {"id": 8, "bbox": [1051.41, 321.47, 188.25, 116.55], "category_id": 1}, {"id": 9, "bbox": [516.74, 407.92, 62.11, 46.11], "category_id": 3}, {"id": 10, "bbox": [413.01, 0.0, 290.7, 384.87], "category_id": 1}, {"id": 11, "bbox": [242.04, 329.15, 94.13, 57.64], "category_id": 2}, {"id": 12, "bbox": [779.27, 895.89, 64.03, 45.46], "category_id": 3}, {"id": 13, "bbox": [1142.06, 838.58, 79.33, 50.99], "category_id": 2}], "caption": "Scheme 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 49, 635, 63], "ImageBB": [448, 69, 768, 305]}, "reactions": [{"reactants": [5, 2], "conditions": [], "products": [10, 11]}, {"reactants": [4], "conditions": [], "products": [10]}, {"reactants": [4], "conditions": [], "products": [8, 6]}, {"reactants": [6], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [1, 13]}], "diagram_type": "tree"}, {"id": 235, "width": 1348, "height": 916, "file_name": "op000095p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.86, 140.86, 39.88, 54.5], "category_id": 2}, {"id": 1, "bbox": [16.0, 381.0, 1332.0, 535.0], "category_id": 4}, {"id": 2, "bbox": [950.0, 0.0, 232.0, 343.0], "category_id": 1}, {"id": 3, "bbox": [621.4, 7.0, 239.9, 335.0], "category_id": 1}, {"id": 4, "bbox": [169.0, 1.0, 263.0, 343.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [3, 2]}], "corefs": [], "caption": "Table 2. Results from Oxidation of Benzylic Alcohols with the Modified Alkaline Nitrobenzene Method ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 496, 761, 524], "ImageBB": [439, 534, 776, 763]}, "diagram_type": "single"}, {"id": 23, "width": 1352, "height": 1096, "file_name": "ja905415r-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.3, 6.42, 304.6, 238.17], "category_id": 1}, {"id": 1, "bbox": [3.73, 484.41, 1342.66, 605.86], "category_id": 4}, {"id": 2, "bbox": [566.58, 161.98, 229.68, 52.91], "category_id": 2}, {"id": 3, "bbox": [1016.29, 277.94, 88.27, 44.43], "category_id": 3}, {"id": 4, "bbox": [201.72, 286.43, 405.04, 188.67], "category_id": 3}, {"id": 5, "bbox": [540.42, 94.94, 284.83, 50.09], "category_id": 2}, {"id": 6, "bbox": [884.77, 3.59, 260.8, 255.14], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [5, 2], "products": [6]}], "corefs": [[0, 4]], "caption": "Table 4. Enantioselective Au(I)-Catalyzed Allenediene [4C+2C] Cycloadditions with (S,S,S)-I and (R,R,R)-Ka ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 376, 81], "ImageBB": [58, 90, 396, 364]}, "diagram_type": "single"}, {"id": 1133, "width": 1352, "height": 1320, "file_name": "ol0002368-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [476.14, 401.88, 416.63, 332.88], "category_id": 1}, {"id": 1, "bbox": [476.14, 882.93, 421.36, 325.43], "category_id": 1}, {"id": 2, "bbox": [655.37, 1207.68, 50.05, 49.39], "category_id": 3}, {"id": 3, "bbox": [804.17, 2.71, 231.3, 294.98], "category_id": 1}, {"id": 4, "bbox": [37.2, 6.09, 234.01, 291.6], "category_id": 1}, {"id": 5, "bbox": [1114.61, 418.8, 66.28, 54.8], "category_id": 2}, {"id": 6, "bbox": [342.23, 58.19, 275.94, 188.08], "category_id": 1}, {"id": 7, "bbox": [656.05, 730.02, 54.11, 53.45], "category_id": 3}, {"id": 8, "bbox": [131.21, 284.16, 41.26, 50.74], "category_id": 3}, {"id": 9, "bbox": [1083.49, 282.13, 41.94, 52.77], "category_id": 3}, {"id": 10, "bbox": [246.86, 418.8, 70.34, 52.09], "category_id": 2}, {"id": 11, "bbox": [472.76, 283.48, 47.34, 51.42], "category_id": 3}, {"id": 12, "bbox": [1067.26, 2.03, 253.63, 236.8], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 410, 265, 423], "ImageBB": [73, 429, 411, 759]}, "reactions": [{"reactants": [4, 6], "conditions": [], "products": [3, 12]}, {"reactants": [3, 12], "conditions": [], "products": [4, 6]}, {"reactants": [4, 6], "conditions": [], "products": [0]}, {"reactants": [4, 6], "conditions": [], "products": [1]}, {"reactants": [3, 12], "conditions": [], "products": [0]}], "diagram_type": "graph"}, {"id": 515, "width": 1344, "height": 868, "file_name": "jo025987x-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [341.0, 274.0, 244.0, 106.0], "category_id": 3}, {"id": 1, "bbox": [1039.0, 274.0, 86.0, 52.9], "category_id": 3}, {"id": 2, "bbox": [874.0, 1.0, 252.0, 353.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 403.0, 1344.0, 465.0], "category_id": 4}, {"id": 4, "bbox": [556.0, 30.0, 325.0, 93.0], "category_id": 2}, {"id": 5, "bbox": [446.0, 98.0, 113.0, 56.0], "category_id": 2}, {"id": 6, "bbox": [203.0, 7.0, 193.0, 367.0], "category_id": 1}, {"id": 7, "bbox": [557.0, 130.0, 279.0, 57.0], "category_id": 2}], "reactions": [{"reactants": [6, 5], "conditions": [4, 7], "products": [2]}], "corefs": [[6, 0], [2, 1]], "caption": "Figure 2. d No separation by chiral HPLC.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [100, 315, 321, 328], "ImageBB": [74, 99, 410, 316]}, "diagram_type": "single"}, {"id": 1083, "width": 1356, "height": 912, "file_name": "jo501785d-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.07, 185.77, 232.67, 168.14], "category_id": 1}, {"id": 1, "bbox": [1213.55, 584.42, 51.55, 54.24], "category_id": 3}, {"id": 2, "bbox": [705.47, 31.19, 93.61, 55.59], "category_id": 2}, {"id": 3, "bbox": [752.96, 18.31, 354.09, 246.78], "category_id": 1}, {"id": 4, "bbox": [496.54, 820.36, 59.7, 50.85], "category_id": 3}, {"id": 5, "bbox": [274.73, 565.44, 125.49, 54.92], "category_id": 2}, {"id": 6, "bbox": [802.48, 336.96, 282.86, 94.92], "category_id": 2}, {"id": 7, "bbox": [330.35, 0.0, 346.63, 284.75], "category_id": 1}, {"id": 8, "bbox": [314.75, 528.15, 347.31, 287.47], "category_id": 1}, {"id": 9, "bbox": [515.54, 280.69, 45.45, 51.52], "category_id": 3}, {"id": 10, "bbox": [96.32, 429.84, 44.77, 50.85], "category_id": 2}, {"id": 11, "bbox": [1086.02, 656.29, 184.51, 96.95], "category_id": 2}, {"id": 12, "bbox": [997.16, 346.45, 352.73, 244.75], "category_id": 1}, {"id": 13, "bbox": [847.25, 817.65, 43.41, 50.17], "category_id": 3}, {"id": 14, "bbox": [69.19, 674.59, 44.77, 50.18], "category_id": 3}, {"id": 15, "bbox": [258.73, 289.06, 122.62, 45.98], "category_id": 2}, {"id": 16, "bbox": [953.74, 262.38, 40.71, 48.81], "category_id": 3}, {"id": 17, "bbox": [150.59, 372.89, 301.86, 134.24], "category_id": 1}, {"id": 18, "bbox": [700.72, 625.78, 347.99, 223.73], "category_id": 1}, {"id": 19, "bbox": [4.07, 521.37, 228.6, 158.65], "category_id": 1}, {"id": 20, "bbox": [69.19, 343.06, 44.77, 46.1], "category_id": 3}], "caption": "Scheme 1. Possible Reaction Pathways of Rhodium\u2212 Carbene A with \u03b2-Enamino Ester 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 491, 748, 522], "ImageBB": [448, 527, 787, 755]}, "reactions": [{"reactants": [19], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [10], "products": [19]}, {"reactants": [0, 17], "conditions": [], "products": [7]}, {"reactants": [19, 17], "conditions": [], "products": [8]}, {"reactants": [7], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [2, 3]}, {"reactants": [3], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [6], "products": [3]}, {"reactants": [12], "conditions": [11], "products": [18]}], "diagram_type": "graph"}, {"id": 958, "width": 1348, "height": 1320, "file_name": "ja011003u-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1001.39, 897.76, 59.34, 49.24], "category_id": 3}, {"id": 1, "bbox": [267.71, 1264.01, 57.99, 47.89], "category_id": 3}, {"id": 2, "bbox": [215.11, 362.21, 185.45, 47.88], "category_id": 3}, {"id": 3, "bbox": [759.3, 503.18, 584.65, 366.92], "category_id": 1}, {"id": 4, "bbox": [0.0, 6.74, 587.35, 295.44], "category_id": 1}, {"id": 5, "bbox": [54.62, 823.56, 545.54, 396.61], "category_id": 1}], "caption": "Scheme 1. Schematic Representation of the Potential Interconversion from Neutral [Hg(arene)2(AlCl4)2] (cf, 1 and 3) to Cationic [Hg(arene)2(AlCl4)2]+ (cf., 5) via an Asymmetrical Complex (cf, 7) ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 65, 770, 120], "ImageBB": [440, 125, 777, 455]}, "reactions": [{"reactants": [4], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}], "diagram_type": "tree"}, {"id": 1220, "width": 1224, "height": 1020, "file_name": "op010052o-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 116.32, 199.61, 361.21], "category_id": 1}, {"id": 1, "bbox": [947.85, 347.13, 243.09, 109.58], "category_id": 2}, {"id": 2, "bbox": [56.94, 478.75, 37.36, 45.31], "category_id": 3}, {"id": 3, "bbox": [720.07, 576.09, 503.93, 377.13], "category_id": 1}, {"id": 4, "bbox": [204.51, 346.51, 245.54, 64.29], "category_id": 2}, {"id": 5, "bbox": [443.92, 90.61, 504.54, 375.9], "category_id": 1}, {"id": 6, "bbox": [539.44, 784.86, 194.1, 58.77], "category_id": 2}, {"id": 7, "bbox": [309.83, 254.07, 44.7, 48.36], "category_id": 3}, {"id": 8, "bbox": [792.32, 476.91, 41.03, 43.47], "category_id": 3}, {"id": 9, "bbox": [303.09, 966.69, 43.48, 47.14], "category_id": 3}, {"id": 10, "bbox": [947.85, 965.46, 39.8, 46.53], "category_id": 3}, {"id": 11, "bbox": [20.21, 580.99, 505.15, 372.84], "category_id": 1}, {"id": 12, "bbox": [263.9, 2.45, 149.41, 247.95], "category_id": 1}], "caption": "Scheme 1. Reported synthesis of 6", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 269, 639, 283], "ImageBB": [455, 288, 761, 543]}, "reactions": [{"reactants": [0, 12], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [1], "products": [11]}, {"reactants": [11], "conditions": [6], "products": [3]}], "diagram_type": "multiple"}, {"id": 782, "width": 1032, "height": 1784, "file_name": "jo502752u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [680.0, 0.0, 168.0, 106.0], "category_id": 1}, {"id": 1, "bbox": [387.0, 1544.0, 247.0, 126.0], "category_id": 1}, {"id": 2, "bbox": [723.7, 730.6, 198.3, 155.6], "category_id": 1}, {"id": 3, "bbox": [764.6, 1309.2, 202.4, 154.0], "category_id": 1}, {"id": 4, "bbox": [348.8, 1038.8, 275.2, 159.6], "category_id": 1}, {"id": 5, "bbox": [42.0, 719.0, 215.1, 166.7], "category_id": 1}, {"id": 6, "bbox": [675.0, 394.0, 245.5, 150.5], "category_id": 1}, {"id": 7, "bbox": [64.8, 1546.4, 187.1, 116.4], "category_id": 1}, {"id": 8, "bbox": [648.0, 1568.6, 348.3, 95.1], "category_id": 1}, {"id": 9, "bbox": [373.0, 14.6, 241.0, 44.3], "category_id": 2}, {"id": 10, "bbox": [648.0, 1023.0, 273.3, 181.4], "category_id": 1}, {"id": 11, "bbox": [76.5, 1307.4, 208.8, 153.3], "category_id": 1}, {"id": 12, "bbox": [420.3, 1309.4, 208.4, 153.0], "category_id": 1}, {"id": 13, "bbox": [3.2, 1034.7, 278.6, 161.3], "category_id": 1}, {"id": 14, "bbox": [395.0, 397.0, 228.2, 149.4], "category_id": 1}, {"id": 15, "bbox": [12.0, 394.0, 247.4, 156.8], "category_id": 1}, {"id": 16, "bbox": [716.9, 100.39, 100.44, 40.65], "category_id": 3}, {"id": 17, "bbox": [357.0, 724.4, 269.0, 147.6], "category_id": 1}, {"id": 18, "bbox": [60.2, 170.8, 204.0, 151.2], "category_id": 1}, {"id": 19, "bbox": [681.0, 166.8, 239.4, 161.6], "category_id": 1}, {"id": 20, "bbox": [45.0, 902.0, 201.2, 56.9], "category_id": 3}, {"id": 21, "bbox": [406.01, 62.13, 129.14, 81.31], "category_id": 2}, {"id": 22, "bbox": [352.0, 169.0, 271.5, 155.4], "category_id": 1}, {"id": 23, "bbox": [413.0, 1675.0, 211.0, 48.0], "category_id": 3}, {"id": 24, "bbox": [85.0, 1683.0, 285.0, 86.0], "category_id": 3}, {"id": 25, "bbox": [686.0, 1468.0, 323.0, 73.0], "category_id": 3}, {"id": 26, "bbox": [419.0, 1466.0, 192.0, 45.0], "category_id": 3}, {"id": 27, "bbox": [83.0, 1462.0, 194.0, 49.0], "category_id": 3}, {"id": 28, "bbox": [759.0, 1210.0, 188.0, 41.0], "category_id": 3}, {"id": 29, "bbox": [413.0, 1212.0, 224.0, 43.0], "category_id": 3}, {"id": 30, "bbox": [83.0, 1204.0, 179.0, 45.0], "category_id": 3}, {"id": 31, "bbox": [700.1, 909.0, 218.9, 75.0], "category_id": 3}, {"id": 32, "bbox": [678.0, 603.0, 301.0, 86.0], "category_id": 3}, {"id": 33, "bbox": [344.0, 567.0, 295.0, 150.0], "category_id": 3}, {"id": 34, "bbox": [16.0, 562.0, 276.0, 112.0], "category_id": 3}, {"id": 35, "bbox": [751.0, 338.0, 174.0, 37.0], "category_id": 3}, {"id": 36, "bbox": [417.0, 336.0, 203.0, 39.0], "category_id": 3}, {"id": 37, "bbox": [61.0, 335.0, 194.0, 34.0], "category_id": 3}, {"id": 38, "bbox": [333.0, 876.0, 295.0, 150.6], "category_id": 3}, {"id": 39, "bbox": [153.1, 42.0, 130.9, 40.0], "category_id": 1}, {"id": 40, "bbox": [755.0, 1675.0, 206.3, 52.3], "category_id": 3}], "reactions": [{"reactants": [39], "conditions": [9, 21], "products": [0]}], "corefs": [[0, 16], [18, 37], [22, 36], [19, 35], [15, 34], [14, 33], [6, 32], [5, 20], [17, 38], [2, 31], [13, 30], [4, 29], [10, 28], [11, 27], [12, 26], [3, 25], [7, 24], [1, 23], [8, 40]], "caption": "Table 2. KOtBu-Promoted Hydration of the Nitriles", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 90, 743, 110], "ImageBB": [488, 116, 746, 562]}, "diagram_type": "single"}, {"id": 789, "width": 1352, "height": 2364, "file_name": "jo501910q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [669.54, 735.13, 129.92, 72.89], "category_id": 3}, {"id": 1, "bbox": [551.0, 1827.0, 408.0, 307.0], "category_id": 1}, {"id": 2, "bbox": [745.59, 224.94, 120.42, 60.21], "category_id": 3}, {"id": 3, "bbox": [311.45, 215.43, 129.93, 57.04], "category_id": 3}, {"id": 4, "bbox": [573.0, 1276.8, 333.2, 365.4], "category_id": 1}, {"id": 5, "bbox": [65.0, 1307.3, 377.7, 306.2], "category_id": 1}, {"id": 6, "bbox": [873.7, 856.2, 338.8, 310.0], "category_id": 1}, {"id": 7, "bbox": [431.5, 858.5, 347.0, 307.5], "category_id": 1}, {"id": 8, "bbox": [81.0, 1615.5, 636.8, 197.5], "category_id": 3}, {"id": 9, "bbox": [108.5, 852.5, 278.1, 311.9], "category_id": 1}, {"id": 10, "bbox": [398.0, 426.6, 387.9, 382.4], "category_id": 1}, {"id": 11, "bbox": [915.0, 1627.0, 404.0, 95.0], "category_id": 3}, {"id": 12, "bbox": [977.0, 2130.0, 229.0, 69.0], "category_id": 3}, {"id": 13, "bbox": [500.0, 1583.0, 199.1, 57.8], "category_id": 3}, {"id": 14, "bbox": [96.2, 1160.18, 340.1, 159.12], "category_id": 3}, {"id": 15, "bbox": [469.34, 1158.34, 343.0, 117.0], "category_id": 3}, {"id": 16, "bbox": [822.32, 1156.83, 383.88, 110.47], "category_id": 3}, {"id": 17, "bbox": [660.0, 2145.14, 233.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [138.2, 2205.5, 739.6, 120.7], "category_id": 3}, {"id": 19, "bbox": [959.49, 1805.2, 331.01, 322.46], "category_id": 1}, {"id": 20, "bbox": [255.4, 65.0, 338.6, 159.6], "category_id": 1}, {"id": 21, "bbox": [634.35, 3.83, 301.25, 229.47], "category_id": 1}, {"id": 22, "bbox": [618.32, 295.83, 473.0, 120.0], "category_id": 2}, {"id": 23, "bbox": [138.4, 1813.8, 411.6, 386.8], "category_id": 1}, {"id": 24, "bbox": [949.5, 1315.7, 333.1, 308.1], "category_id": 1}], "reactions": [{"reactants": [20, 21], "conditions": [22], "products": [10]}], "corefs": [[20, 3], [21, 2], [10, 0], [9, 14], [7, 15], [6, 16], [5, 8], [4, 13], [24, 11], [23, 18], [1, 17], [19, 12]], "caption": "Table 2. Synthesis of Various Substituted 5,6- Dihydrophenanthridines ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 233, 340, 263], "ImageBB": [82, 269, 420, 860]}, "diagram_type": "tree"}, {"id": 130, "width": 1356, "height": 984, "file_name": "op900102a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [180.0, 129.0, 273.0, 67.0], "category_id": 1}, {"id": 1, "bbox": [6.0, 226.0, 1350.0, 758.0], "category_id": 4}, {"id": 2, "bbox": [516.0, 5.0, 307.0, 79.0], "category_id": 2}, {"id": 3, "bbox": [515.0, 103.0, 271.0, 84.0], "category_id": 2}, {"id": 4, "bbox": [113.0, 0.0, 351.0, 46.0], "category_id": 1}, {"id": 5, "bbox": [918.4, 10.5, 321.8, 167.5], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [2, 3], "products": [5]}, {"reactants": [0], "conditions": [2, 3], "products": [5]}], "corefs": [], "caption": "Table 3. Silanation and nucleophilic substitution of (3-bromopropyl)trimethoxysilane or (3-bromopropyl)- trichlorosilane to S3x ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 462, 720, 503], "ImageBB": [424, 515, 763, 761]}, "diagram_type": "single"}, {"id": 1221, "width": 1080, "height": 1036, "file_name": "op010052o-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [388.21, 567.18, 315.9, 38.55], "category_id": 3}, {"id": 1, "bbox": [499.75, 358.65, 233.4, 45.37], "category_id": 2}, {"id": 2, "bbox": [341.99, 267.37, 170.73, 241.44], "category_id": 1}, {"id": 3, "bbox": [245.28, 649.79, 440.32, 314.9], "category_id": 1}, {"id": 4, "bbox": [102.65, 860.98, 81.04, 39.97], "category_id": 2}, {"id": 5, "bbox": [8.64, 286.81, 116.16, 218.22], "category_id": 1}, {"id": 6, "bbox": [45.92, 522.32, 30.26, 34.02], "category_id": 3}, {"id": 7, "bbox": [571.07, 305.72, 43.22, 34.03], "category_id": 3}, {"id": 8, "bbox": [897.93, 521.78, 24.31, 32.94], "category_id": 3}, {"id": 9, "bbox": [128.04, 278.71, 215.57, 124.23], "category_id": 2}, {"id": 10, "bbox": [555.94, 435.89, 73.47, 36.19], "category_id": 2}, {"id": 11, "bbox": [388.45, 527.18, 32.42, 35.65], "category_id": 3}, {"id": 12, "bbox": [179.37, 436.43, 76.18, 37.81], "category_id": 2}, {"id": 13, "bbox": [24.4, 779.96, 257.08, 51.32], "category_id": 2}, {"id": 14, "bbox": [429.6, 948.1, 32.8, 39.1], "category_id": 3}, {"id": 15, "bbox": [522.98, 3.24, 135.92, 304.96], "category_id": 1}, {"id": 16, "bbox": [429.25, 990.04, 340.78, 37.31], "category_id": 3}, {"id": 17, "bbox": [645.66, 237.6, 429.07, 310.92], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [107, 72, 377, 331]}, "reactions": [{"reactants": [5], "conditions": [9, 12], "products": [2]}, {"reactants": [2, 15], "conditions": [1, 10], "products": [17]}, {"reactants": [17], "conditions": [13, 4], "products": [3]}], "diagram_type": "multiple"}, {"id": 1366, "width": 1252, "height": 1412, "file_name": "op960008m-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.12, 990.31, 201.3, 100.3], "category_id": 1}, {"id": 1, "bbox": [16.95, 244.4, 40.26, 52.27], "category_id": 3}, {"id": 2, "bbox": [1016.4, 763.57, 113.01, 61.45], "category_id": 2}, {"id": 3, "bbox": [702.09, 1276.38, 237.32, 120.79], "category_id": 1}, {"id": 4, "bbox": [1104.69, 1031.98, 109.48, 61.45], "category_id": 2}, {"id": 5, "bbox": [437.21, 210.49, 110.9, 55.81], "category_id": 2}, {"id": 6, "bbox": [119.37, 206.26, 199.18, 95.35], "category_id": 1}, {"id": 7, "bbox": [466.88, 1285.56, 114.42, 60.75], "category_id": 2}, {"id": 8, "bbox": [692.9, 362.36, 332.68, 199.19], "category_id": 1}, {"id": 9, "bbox": [784.73, 973.35, 226.02, 152.58], "category_id": 1}, {"id": 10, "bbox": [692.9, 0.0, 313.61, 195.66], "category_id": 1}, {"id": 11, "bbox": [394.84, 1080.72, 355.28, 55.8], "category_id": 2}, {"id": 12, "bbox": [0.0, 1038.34, 43.79, 57.21], "category_id": 3}, {"id": 13, "bbox": [489.48, 986.78, 132.09, 60.04], "category_id": 2}, {"id": 14, "bbox": [1017.11, 1323.71, 90.41, 62.86], "category_id": 2}, {"id": 15, "bbox": [0.0, 1335.8, 45.8, 52.89], "category_id": 3}, {"id": 16, "bbox": [1161.9, 765.69, 90.1, 59.33], "category_id": 2}, {"id": 17, "bbox": [445.69, 665.38, 171.64, 70.64], "category_id": 2}, {"id": 18, "bbox": [696.96, 713.34, 216.54, 143.75], "category_id": 1}, {"id": 19, "bbox": [108.07, 1278.5, 198.47, 101.01], "category_id": 1}, {"id": 20, "bbox": [464.06, 1363.97, 115.13, 48.03], "category_id": 2}], "caption": "Scheme 7. Routes to propylene oxide", "pdf": {"Page": 11, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 171, 287, 185], "ImageBB": [85, 190, 398, 543]}, "reactions": [{"reactants": [6], "conditions": [5], "products": [10, 8]}, {"reactants": [10, 8, 17], "conditions": [], "products": [18, 2, 16]}, {"reactants": [0], "conditions": [13, 11], "products": [9, 4]}, {"reactants": [19], "conditions": [7, 20], "products": [3, 14]}], "diagram_type": "multiple"}, {"id": 328, "width": 1480, "height": 3744, "file_name": "ol300842d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [503.0, 62.0, 194.0, 67.0], "category_id": 2}, {"id": 1, "bbox": [499.0, 133.0, 202.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [274.0, 250.0, 35.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [849.0, 246.0, 88.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [1192.0, 250.0, 101.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [147.0, 382.0, 1310.0, 2932.0], "category_id": 4}, {"id": 6, "bbox": [115.0, 3364.0, 1365.0, 380.0], "category_id": 2}, {"id": 7, "bbox": [1127.0, 0.0, 308.0, 246.0], "category_id": 1}, {"id": 8, "bbox": [163.0, 0.0, 336.0, 233.0], "category_id": 1}, {"id": 9, "bbox": [711.0, 0.0, 383.0, 254.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [0, 1], "products": [9]}, {"reactants": [8], "conditions": [0, 1], "products": [7]}], "corefs": [[8, 2], [9, 3], [7, 4]], "caption": "Table 2. LDA-Mediated Regioselective Thia-Fries Rearrange- ment of Various Oxindole and Pyrazolone Derivatives ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 768, 114], "ImageBB": [404, 126, 774, 1062]}, "diagram_type": "single"}, {"id": 314, "width": 1344, "height": 1004, "file_name": "ol3023903-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [579.0, 287.0, 203.0, 63.0], "category_id": 2}, {"id": 1, "bbox": [589.0, 669.0, 242.0, 30.0], "category_id": 3}, {"id": 2, "bbox": [980.0, 723.0, 338.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [129.0, 916.0, 236.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [338.0, 164.0, 217.0, 179.0], "category_id": 1}, {"id": 5, "bbox": [507.0, 963.0, 336.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [1001.0, 940.0, 229.0, 34.0], "category_id": 3}, {"id": 7, "bbox": [967.0, 410.0, 295.0, 295.0], "category_id": 1}, {"id": 8, "bbox": [384.72, 341.51, 31.05, 36.23], "category_id": 3}, {"id": 9, "bbox": [873.78, 338.92, 40.11, 33.64], "category_id": 3}, {"id": 10, "bbox": [458.3, 743.6, 406.7, 216.8], "category_id": 1}, {"id": 11, "bbox": [839.8, 213.1, 110.6, 125.9], "category_id": 1}, {"id": 12, "bbox": [600.4, 172.1, 150.3, 88.9], "category_id": 1}, {"id": 13, "bbox": [89.0, 723.2, 322.1, 192.8], "category_id": 1}, {"id": 14, "bbox": [983.6, 778.9, 296.1, 146.6], "category_id": 1}, {"id": 15, "bbox": [134.0, 616.0, 272.0, 33.0], "category_id": 3}, {"id": 16, "bbox": [568.6, 428.9, 270.9, 227.8], "category_id": 1}, {"id": 17, "bbox": [81.6, 478.0, 431.4, 142.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [12, 0], "products": [11]}], "corefs": [[4, 8], [11, 9], [17, 15], [16, 1], [7, 2], [13, 3], [10, 5], [14, 6]], "caption": "Figure 4. Scope of the radical olefination for vinyl fluorides. Reaction conditions: olefin (2 equiv), xanthate (1 equiv), lauroyl peroxide was added in 30 mol % portions (with respect to the xanthate) every hour (5 7 h). For 10c, the reaction was run in refluxing DCE. ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 322, 771, 391], "ImageBB": [437, 58, 773, 309]}, "diagram_type": "single"}, {"id": 225, "width": 1344, "height": 1132, "file_name": "op0155211-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [979.0, 398.4, 170.0, 226.6], "category_id": 1}, {"id": 1, "bbox": [19.0, 176.54, 169.0, 147.0], "category_id": 1}, {"id": 2, "bbox": [907.0, 166.6, 250.4, 147.9], "category_id": 1}, {"id": 3, "bbox": [95.0, 458.4, 258.4, 158.6], "category_id": 1}, {"id": 4, "bbox": [376.92, 168.29, 136.0, 148.0], "category_id": 1}, {"id": 5, "bbox": [715.0, 197.0, 75.0, 48.1], "category_id": 2}, {"id": 6, "bbox": [925.2, 841.0, 355.9, 198.6], "category_id": 1}, {"id": 7, "bbox": [506.0, 1083.0, 53.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [166.0, 1074.0, 62.0, 53.0], "category_id": 3}, {"id": 9, "bbox": [435.0, 822.0, 186.0, 211.0], "category_id": 1}, {"id": 10, "bbox": [5.0, 801.0, 282.0, 227.0], "category_id": 1}, {"id": 11, "bbox": [710.0, 263.0, 90.0, 42.0], "category_id": 2}, {"id": 12, "bbox": [707.0, 498.0, 88.0, 41.0], "category_id": 2}, {"id": 13, "bbox": [710.0, 569.0, 80.0, 46.0], "category_id": 2}, {"id": 14, "bbox": [704.0, 870.0, 88.0, 40.0], "category_id": 2}, {"id": 15, "bbox": [704.0, 947.0, 99.0, 41.0], "category_id": 2}, {"id": 16, "bbox": [1060.0, 319.0, 56.0, 52.0], "category_id": 3}, {"id": 17, "bbox": [247.0, 633.0, 58.0, 51.0], "category_id": 3}, {"id": 18, "bbox": [1185.5, 224.62, 81.69, 52.51], "category_id": 1}, {"id": 19, "bbox": [354.01, 530.96, 78.77, 56.89], "category_id": 1}, {"id": 20, "bbox": [1268.65, 897.11, 75.35, 58.35], "category_id": 1}, {"id": 21, "bbox": [1058.0, 639.0, 61.0, 44.0], "category_id": 3}, {"id": 22, "bbox": [1058.0, 1078.0, 62.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [5, 11], "products": [2, 18]}, {"reactants": [3, 19], "conditions": [12, 13], "products": [0]}, {"reactants": [10, 9], "conditions": [14, 15], "products": [6, 20]}], "corefs": [[2, 16], [3, 17], [0, 21], [10, 8], [9, 7], [6, 22]], "caption": "Figure 2. Process of kinetic data extraction.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 528, 687, 542], "ImageBB": [440, 551, 776, 834]}, "diagram_type": "tree"}, {"id": 96, "width": 1476, "height": 2592, "file_name": "ja042849b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [410.07, 1736.83, 58.52, 27.84], "category_id": 2}, {"id": 1, "bbox": [886.51, 1806.28, 56.91, 27.84], "category_id": 2}, {"id": 2, "bbox": [1227.29, 1950.02, 139.31, 66.6], "category_id": 2}, {"id": 3, "bbox": [1413.02, 1969.4, 56.88, 27.84], "category_id": 2}, {"id": 4, "bbox": [731.46, 2174.52, 237.8, 32.68], "category_id": 2}, {"id": 5, "bbox": [728.23, 2373.17, 363.77, 31.07], "category_id": 2}, {"id": 6, "bbox": [729.85, 2268.19, 26.22, 31.07], "category_id": 2}, {"id": 7, "bbox": [222.72, 1869.27, 18.15, 27.84], "category_id": 3}, {"id": 8, "bbox": [497.28, 1867.65, 19.76, 27.85], "category_id": 3}, {"id": 9, "bbox": [1101.31, 1589.87, 344.39, 255.56], "category_id": 1}, {"id": 10, "bbox": [768.61, 1618.94, 292.71, 76.29], "category_id": 1}, {"id": 11, "bbox": [922.0, 1932.3, 268.52, 100.48], "category_id": 1}, {"id": 12, "bbox": [203.34, 2098.61, 444.53, 331.47], "category_id": 1}, {"id": 13, "bbox": [775.07, 2239.12, 200.65, 118.28], "category_id": 1}, {"id": 14, "bbox": [1099.7, 2096.99, 350.85, 257.18], "category_id": 1}, {"id": 15, "bbox": [361.62, 1601.17, 163.5, 102.13], "category_id": 2}, {"id": 16, "bbox": [130.66, 1589.87, 184.5, 255.56], "category_id": 1}, {"id": 17, "bbox": [557.04, 1589.87, 186.11, 255.56], "category_id": 1}, {"id": 18, "bbox": [196.19, 2446.31, 530.3, 138.89], "category_id": 4}, {"id": 19, "bbox": [879.27, 1426.11, 566.92, 39.14], "category_id": 2}, {"id": 20, "bbox": [135.58, 1427.37, 575.76, 37.88], "category_id": 2}, {"id": 21, "bbox": [799.72, 905.91, 665.41, 500.0], "category_id": 1}, {"id": 22, "bbox": [139.37, 952.63, 546.72, 369.95], "category_id": 1}, {"id": 23, "bbox": [1196.6, 1866.04, 18.15, 27.84], "category_id": 3}, {"id": 24, "bbox": [1256.36, 2378.01, 19.76, 26.23], "category_id": 3}, {"id": 25, "bbox": [859.05, 1725.53, 127.95, 63.37], "category_id": 2}], "reactions": [{"reactants": [16], "conditions": [15, 0], "products": [17]}, {"reactants": [17], "conditions": [10, 25, 1], "products": [9]}, {"reactants": [9], "conditions": [11, 2, 3], "products": [14]}, {"reactants": [14], "conditions": [4, 6, 13, 5], "products": [12]}], "corefs": [[22, 20], [21, 19], [16, 7], [17, 8], [9, 23], [14, 24], [12, 18]], "caption": "Table 1. Turnover Numbers for the Dismutation of H2O2 Catalyzed by Manganese Salophen Complexes ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 701, 723, 725], "ImageBB": [408, 42, 777, 690]}, "diagram_type": "multiple"}, {"id": 186, "width": 1232, "height": 636, "file_name": "op0601619-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1000.0, 295.0, 194.0, 81.0], "category_id": 3}, {"id": 1, "bbox": [565.0, 164.0, 364.0, 123.0], "category_id": 2}, {"id": 2, "bbox": [574.0, 7.0, 297.0, 122.0], "category_id": 2}, {"id": 3, "bbox": [429.0, 118.0, 79.0, 62.0], "category_id": 2}, {"id": 4, "bbox": [506.6, 400.9, 475.4, 232.1], "category_id": 2}, {"id": 5, "bbox": [916.4, 0.0, 309.6, 286.4], "category_id": 1}, {"id": 6, "bbox": [3.0, 6.0, 321.1, 281.1], "category_id": 1}, {"id": 7, "bbox": [139.2, 378.5, 340.4, 235.4], "category_id": 1}, {"id": 8, "bbox": [122.0, 306.77, 133.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [6, 3], "conditions": [2, 1], "products": [5]}], "corefs": [[6, 8], [5, 0]], "caption": "Figure 1. Reaction conditions and structure of the phosphine- oxazoline ligands. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 461, 775, 489], "ImageBB": [454, 299, 762, 458]}, "diagram_type": "single"}, {"id": 1010, "width": 1268, "height": 652, "file_name": "ja974106e-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [644.47, 406.21, 255.63, 173.28], "category_id": 1}, {"id": 1, "bbox": [198.54, 409.39, 319.06, 172.64], "category_id": 1}, {"id": 2, "bbox": [790.36, 93.94, 152.24, 61.56], "category_id": 2}, {"id": 3, "bbox": [517.6, 507.13, 107.84, 56.49], "category_id": 2}, {"id": 4, "bbox": [487.16, 74.9, 258.8, 175.18], "category_id": 1}, {"id": 5, "bbox": [570.89, 279.27, 63.43, 47.6], "category_id": 3}, {"id": 6, "bbox": [966.7, 74.9, 301.3, 214.53], "category_id": 1}, {"id": 7, "bbox": [747.23, 601.7, 64.06, 46.34], "category_id": 3}, {"id": 8, "bbox": [1019.98, 396.69, 234.7, 178.99], "category_id": 1}, {"id": 9, "bbox": [88.17, 78.7, 279.1, 178.36], "category_id": 1}, {"id": 10, "bbox": [79.29, 292.6, 320.96, 57.76], "category_id": 2}, {"id": 11, "bbox": [291.15, 602.34, 65.34, 47.6], "category_id": 3}, {"id": 12, "bbox": [1052.33, 279.27, 62.8, 44.43], "category_id": 3}], "caption": "Scheme 2. The catalytically active", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [577, 136, 774, 150], "ImageBB": [440, 156, 757, 319]}, "reactions": [{"reactants": [9], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [2], "products": [6]}, {"reactants": [6], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [3], "products": [0]}, {"reactants": [0], "conditions": [], "products": [8]}], "diagram_type": "multiple"}, {"id": 1043, "width": 1064, "height": 1372, "file_name": "jo010297z-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [85.77, 1008.92, 236.05, 274.54], "category_id": 1}, {"id": 1, "bbox": [733.53, 1059.71, 50.09, 61.77], "category_id": 3}, {"id": 2, "bbox": [0.0, 383.67, 185.95, 179.13], "category_id": 1}, {"id": 3, "bbox": [932.21, 713.15, 126.83, 62.59], "category_id": 2}, {"id": 4, "bbox": [933.86, 167.98, 126.82, 64.23], "category_id": 2}, {"id": 5, "bbox": [271.04, 481.13, 143.41, 58.34], "category_id": 2}, {"id": 6, "bbox": [472.78, 1094.03, 89.89, 72.07], "category_id": 2}, {"id": 7, "bbox": [534.53, 313.66, 54.9, 54.22], "category_id": 3}, {"id": 8, "bbox": [391.81, 0.0, 275.16, 301.99], "category_id": 1}, {"id": 9, "bbox": [380.14, 586.82, 283.4, 291.7], "category_id": 1}, {"id": 10, "bbox": [514.64, 893.62, 46.66, 59.02], "category_id": 3}, {"id": 11, "bbox": [426.8, 1188.06, 210.66, 64.52], "category_id": 2}, {"id": 12, "bbox": [803.52, 1057.65, 127.63, 66.58], "category_id": 2}, {"id": 13, "bbox": [0.0, 1371.31, 8.92, 0.69], "category_id": 3}, {"id": 14, "bbox": [867.33, 713.8, 53.37, 63.8], "category_id": 3}, {"id": 15, "bbox": [733.53, 1227.87, 51.27, 59.02], "category_id": 3}, {"id": 16, "bbox": [867.33, 167.47, 46.77, 65.03], "category_id": 3}, {"id": 17, "bbox": [803.74, 1227.04, 125.18, 60.94], "category_id": 2}, {"id": 18, "bbox": [188.7, 1311.6, 40.48, 54.22], "category_id": 3}, {"id": 19, "bbox": [299.17, 402.88, 76.17, 49.42], "category_id": 2}], "caption": "       Scheme 2. Synthesis of Novel Spiromethanofullerenes from Diazo Compounds ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [449, 64, 765, 92], "ImageBB": [475, 97, 741, 440]}, "reactions": [{"reactants": [2], "conditions": [19, 5, 8], "products": [16]}, {"reactants": [2], "conditions": [19, 5, 9], "products": [14]}, {"reactants": [0], "conditions": [6, 11], "products": [1, 15]}], "diagram_type": "tree"}, {"id": 284, "width": 1352, "height": 1448, "file_name": "ol800086s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [476.0, 198.0, 34.0, 52.0], "category_id": 3}, {"id": 1, "bbox": [12.0, 254.0, 1340.0, 1194.0], "category_id": 4}, {"id": 2, "bbox": [1084.0, 207.0, 35.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [119.0, 201.0, 51.7, 40.0], "category_id": 3}, {"id": 4, "bbox": [543.0, 24.0, 446.0, 97.0], "category_id": 2}, {"id": 5, "bbox": [174.3, 200.0, 147.7, 49.1], "category_id": 2}, {"id": 6, "bbox": [279.0, 6.0, 225.0, 227.8], "category_id": 1}, {"id": 7, "bbox": [983.3, 1.1, 252.2, 223.7], "category_id": 1}, {"id": 8, "bbox": [579.0, 122.5, 361.0, 95.5], "category_id": 2}, {"id": 9, "bbox": [157.9, 54.0, 66.0, 134.5], "category_id": 1}], "reactions": [{"reactants": [9, 6], "conditions": [4, 8], "products": [7]}], "corefs": [[9, 3], [6, 0], [7, 2]], "caption": "Table 3. Alkenyl Substitution Scope", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 311, 637, 324], "ImageBB": [439, 325, 777, 687]}, "diagram_type": "single"}, {"id": 1291, "width": 2360, "height": 1556, "file_name": "op200112g-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [466.33, 131.03, 56.67, 75.54], "category_id": 2}, {"id": 1, "bbox": [1846.44, 592.57, 488.77, 408.43], "category_id": 1}, {"id": 2, "bbox": [0.0, 56.66, 427.37, 337.6], "category_id": 1}, {"id": 3, "bbox": [1846.44, 10.62, 488.77, 404.89], "category_id": 1}, {"id": 4, "bbox": [1736.65, 134.57, 48.4, 72.0], "category_id": 2}, {"id": 5, "bbox": [1240.8, 338.78, 276.26, 55.48], "category_id": 2}, {"id": 6, "bbox": [1182.95, 1129.67, 494.67, 407.24], "category_id": 1}, {"id": 7, "bbox": [466.33, 266.78, 108.62, 59.02], "category_id": 2}, {"id": 8, "bbox": [1207.74, 15.35, 486.41, 396.62], "category_id": 1}, {"id": 9, "bbox": [120.42, 744.85, 224.31, 61.38], "category_id": 2}, {"id": 10, "bbox": [599.74, 53.12, 426.19, 334.06], "category_id": 1}, {"id": 11, "bbox": [1846.44, 1129.67, 491.13, 410.78], "category_id": 1}, {"id": 12, "bbox": [146.39, 339.96, 37.78, 46.04], "category_id": 3}, {"id": 13, "bbox": [756.76, 1313.81, 225.49, 57.84], "category_id": 2}, {"id": 14, "bbox": [1370.67, 430.85, 88.54, 80.27], "category_id": 2}, {"id": 15, "bbox": [595.02, 509.94, 417.93, 461.55], "category_id": 1}, {"id": 16, "bbox": [1185.31, 586.67, 469.88, 416.69], "category_id": 1}], "caption": "Scheme 5. Degradation of GLY I (1) and its dehydrated producta", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 435, 108], "ImageBB": [127, 117, 717, 506]}, "reactions": [{"reactants": [2], "conditions": [0], "products": [7, 10]}, {"reactants": [10], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [4], "products": [3]}, {"reactants": [8], "conditions": [14], "products": [16]}, {"reactants": [16], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [16]}, {"reactants": [3], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [1], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [], "products": [1]}, {"reactants": [11], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [11]}], "diagram_type": "tree"}, {"id": 742, "width": 1352, "height": 2756, "file_name": "ol006383n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [776.0, 208.0, 48.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [107.0, 218.0, 42.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [363.0, 10.0, 117.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [20.0, 376.0, 1332.0, 1998.0], "category_id": 4}, {"id": 4, "bbox": [81.0, 2379.0, 1063.0, 231.0], "category_id": 2}, {"id": 5, "bbox": [1034.0, 50.0, 257.0, 188.0], "category_id": 1}, {"id": 6, "bbox": [538.0, 15.0, 318.0, 369.0], "category_id": 1}, {"id": 7, "bbox": [363.0, 138.0, 117.0, 62.0], "category_id": 2}, {"id": 8, "bbox": [1095.0, 258.0, 82.0, 46.0], "category_id": 3}, {"id": 9, "bbox": [29.0, 7.0, 314.0, 364.0], "category_id": 1}, {"id": 10, "bbox": [864.0, 97.0, 178.0, 83.0], "category_id": 2}], "reactions": [{"reactants": [9], "conditions": [7], "products": [6]}, {"reactants": [6], "conditions": [10], "products": [5]}, {"reactants": [2], "conditions": [], "products": [7]}], "corefs": [[9, 1], [6, 0], [5, 8]], "caption": "Table 1. Ureas from Carboxylic Acids", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 348, 648, 361], "ImageBB": [439, 364, 777, 1053]}, "diagram_type": "single"}, {"id": 818, "width": 1348, "height": 1872, "file_name": "jo4014707-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [469.5, 837.0, 253.5, 185.2], "category_id": 1}, {"id": 1, "bbox": [65.0, 396.7, 360.5, 316.3], "category_id": 1}, {"id": 2, "bbox": [547.0, 745.0, 280.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [1051.0, 656.0, 126.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [763.0, 910.0, 456.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [766.0, 1098.0, 490.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [303.0, 162.0, 175.0, 35.0], "category_id": 2}, {"id": 7, "bbox": [112.0, 15.0, 124.0, 194.0], "category_id": 1}, {"id": 8, "bbox": [953.0, 468.0, 330.0, 180.0], "category_id": 1}, {"id": 9, "bbox": [463.32, 1031.44, 258.46, 203.26], "category_id": 1}, {"id": 10, "bbox": [483.0, 405.0, 405.0, 313.0], "category_id": 1}, {"id": 11, "bbox": [63.0, 859.0, 367.0, 310.0], "category_id": 1}, {"id": 12, "bbox": [659.0, 243.0, 247.0, 49.0], "category_id": 2}, {"id": 13, "bbox": [737.0, 196.0, 92.0, 39.0], "category_id": 2}, {"id": 14, "bbox": [733.0, 141.0, 98.0, 50.0], "category_id": 2}, {"id": 15, "bbox": [628.0, 69.0, 311.0, 50.0], "category_id": 2}, {"id": 16, "bbox": [571.0, 0.0, 435.0, 49.0], "category_id": 2}, {"id": 17, "bbox": [354.0, 227.0, 56.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [161.0, 227.0, 36.0, 45.0], "category_id": 3}, {"id": 19, "bbox": [3.0, 1243.0, 1345.0, 629.0], "category_id": 4}, {"id": 20, "bbox": [1067.0, 19.0, 199.0, 208.0], "category_id": 1}, {"id": 21, "bbox": [300.2, 103.0, 192.8, 54.0], "category_id": 2}, {"id": 22, "bbox": [1097.0, 232.0, 104.0, 44.0], "category_id": 3}, {"id": 23, "bbox": [152.0, 745.0, 195.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [7, 21], "conditions": [16, 15, 14, 13, 12], "products": [20]}], "corefs": [[7, 18], [21, 17], [20, 22], [1, 23], [10, 2], [8, 3]], "caption": "Table 1. Asymmetric 1,4-Addition of 2a to 1 at 0 \u00b0Ca", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 386, 111], "ImageBB": [82, 116, 419, 584]}, "diagram_type": "single"}, {"id": 1195, "width": 2816, "height": 836, "file_name": "ol501514b-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [245.11, 709.51, 46.49, 39.42], "category_id": 3}, {"id": 1, "bbox": [76.53, 152.1, 90.26, 46.02], "category_id": 2}, {"id": 2, "bbox": [301.29, 431.72, 210.6, 46.01], "category_id": 2}, {"id": 3, "bbox": [755.07, 503.98, 133.82, 50.68], "category_id": 3}, {"id": 4, "bbox": [211.5, 84.47, 277.32, 40.82], "category_id": 2}, {"id": 5, "bbox": [542.35, 211.16, 146.51, 43.64], "category_id": 3}, {"id": 6, "bbox": [30.99, 94.32, 142.28, 43.64], "category_id": 1}, {"id": 7, "bbox": [277.51, 135.14, 166.23, 40.83], "category_id": 2}, {"id": 8, "bbox": [178.91, 580.0, 202.85, 128.1], "category_id": 1}, {"id": 9, "bbox": [277.51, 335.05, 416.98, 83.05], "category_id": 2}, {"id": 10, "bbox": [817.05, 152.04, 240.89, 46.45], "category_id": 2}, {"id": 11, "bbox": [14.09, 242.13, 277.51, 260.44], "category_id": 1}, {"id": 12, "bbox": [709.99, 315.34, 197.22, 187.23], "category_id": 1}, {"id": 13, "bbox": [474.73, 660.24, 264.84, 43.64], "category_id": 2}, {"id": 14, "bbox": [1097.38, 29.56, 239.48, 181.6], "category_id": 1}, {"id": 15, "bbox": [955.1, 423.74, 249.34, 36.6], "category_id": 2}, {"id": 16, "bbox": [478.96, 67.57, 249.34, 132.33], "category_id": 1}, {"id": 17, "bbox": [957.92, 373.06, 246.52, 43.64], "category_id": 2}, {"id": 18, "bbox": [30.99, 512.42, 223.99, 43.64], "category_id": 3}, {"id": 19, "bbox": [755.07, 33.79, 336.68, 95.72], "category_id": 2}, {"id": 20, "bbox": [1128.37, 218.2, 145.1, 46.46], "category_id": 3}], "caption": "Scheme 3. Synthesis of 3-Methyl-4-phenyl-1H-pyrrol-2(5H)- one ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 562, 416, 592], "ImageBB": [82, 591, 786, 800]}, "reactions": [{"reactants": [6, 1], "conditions": [4, 7], "products": [16]}, {"reactants": [16], "conditions": [19, 10], "products": [14]}, {"reactants": [14], "conditions": [17, 15], "products": [12]}, {"reactants": [12], "conditions": [], "products": [8]}, {"reactants": [12], "conditions": [9, 2], "products": [11]}], "diagram_type": "tree"}, {"id": 878, "width": 1272, "height": 2012, "file_name": "ol7014434-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 296.4, 1272.0, 1715.6], "category_id": 4}, {"id": 1, "bbox": [111.1, 0.0, 377.9, 228.2], "category_id": 1}, {"id": 2, "bbox": [799.6, 0.0, 370.5, 219.6], "category_id": 1}, {"id": 3, "bbox": [579.0, 42.0, 106.0, 39.0], "category_id": 2}, {"id": 4, "bbox": [552.0, 110.0, 123.0, 41.0], "category_id": 2}, {"id": 5, "bbox": [251.0, 244.0, 33.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [930.0, 229.0, 63.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [3, 4], "products": [2]}], "corefs": [[1, 5], [2, 6]], "caption": "Table 3. Synthesis of Compounds of Type III from Type IIa", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 397, 89], "ImageBB": [83, 90, 401, 593]}, "diagram_type": "single"}, {"id": 1197, "width": 2820, "height": 916, "file_name": "ol502425f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1801.47, 315.99, 56.43, 50.78], "category_id": 3}, {"id": 1, "bbox": [1145.49, 83.23, 383.71, 290.6], "category_id": 1}, {"id": 2, "bbox": [2353.06, 435.9, 458.48, 416.14], "category_id": 1}, {"id": 3, "bbox": [218.66, 811.13, 49.37, 46.56], "category_id": 3}, {"id": 4, "bbox": [576.98, 499.38, 435.91, 338.56], "category_id": 1}, {"id": 5, "bbox": [1736.58, 12.7, 465.53, 344.2], "category_id": 1}, {"id": 6, "bbox": [2482.84, 792.8, 52.2, 52.19], "category_id": 3}, {"id": 7, "bbox": [482.46, 545.93, 158.0, 90.28], "category_id": 2}, {"id": 8, "bbox": [1509.45, 117.09, 217.25, 98.74], "category_id": 1}, {"id": 9, "bbox": [12.8, 134.7, 179.06, 103.0], "category_id": 1}, {"id": 10, "bbox": [1716.9, 436.7, 432.1, 400.5], "category_id": 1}, {"id": 11, "bbox": [31.9, 314.6, 347.6, 90.9], "category_id": 2}, {"id": 12, "bbox": [2194.71, 546.3, 123.34, 78.69], "category_id": 2}, {"id": 13, "bbox": [1854.43, 786.62, 44.67, 48.91], "category_id": 3}, {"id": 14, "bbox": [1012.89, 538.88, 167.87, 87.46], "category_id": 2}, {"id": 15, "bbox": [1156.78, 499.38, 444.37, 338.56], "category_id": 1}, {"id": 16, "bbox": [2131.58, 373.83, 180.57, 55.01], "category_id": 2}, {"id": 17, "bbox": [355.5, 88.87, 235.59, 176.34], "category_id": 1}, {"id": 18, "bbox": [2355.88, 12.7, 464.12, 409.09], "category_id": 1}, {"id": 19, "bbox": [160.82, 141.07, 215.84, 47.96], "category_id": 2}, {"id": 20, "bbox": [1261.17, 371.01, 146.71, 46.55], "category_id": 3}, {"id": 21, "bbox": [620.71, 88.87, 256.75, 179.16], "category_id": 1}, {"id": 22, "bbox": [26.8, 479.63, 438.73, 362.54], "category_id": 1}, {"id": 23, "bbox": [887.33, 114.26, 237.0, 71.95], "category_id": 2}], "caption": "Scheme 1. Plausible Biogenetic Pathway for 1 and 2 (Red, Newly Formed Rings)", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 530, 110], "ImageBB": [82, 116, 787, 345]}, "reactions": [{"reactants": [9], "conditions": [19], "products": [17]}, {"reactants": [17], "conditions": [], "products": [21]}, {"reactants": [21], "conditions": [23], "products": [1]}, {"reactants": [1, 8], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [5]}, {"reactants": [18], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [12], "products": [2]}, {"reactants": [10], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [10]}, {"reactants": [15], "conditions": [14], "products": [4]}, {"reactants": [4], "conditions": [7], "products": [22]}], "diagram_type": "tree"}, {"id": 539, "width": 1352, "height": 1148, "file_name": "acs.orglett.6b00661-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [660.0, 552.0, 586.0, 446.0], "category_id": 1}, {"id": 1, "bbox": [105.0, 114.0, 384.0, 319.0], "category_id": 1}, {"id": 2, "bbox": [1047.0, 117.0, 203.0, 313.0], "category_id": 1}, {"id": 3, "bbox": [148.7, 551.0, 515.3, 439.0], "category_id": 1}, {"id": 4, "bbox": [169.0, 433.0, 229.0, 66.0], "category_id": 2}, {"id": 5, "bbox": [514.0, 301.0, 441.0, 120.0], "category_id": 2}, {"id": 6, "bbox": [505.0, 157.0, 471.0, 114.0], "category_id": 2}, {"id": 7, "bbox": [733.0, 865.2, 392.5, 115.6], "category_id": 3}, {"id": 8, "bbox": [125.0, 856.0, 905.0, 292.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [6, 5], "products": [2]}], "corefs": [[3, 8], [0, 7]], "caption": "Figure 1. Gold(I)-catalyzed 6-exo-dig cyclization reaction and structures of gardnerine (1), hydroxygardnerine (2), hydroxygardnu- tine (3), and (E)-16-epi-normacusine B (4). ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 852, 417, 894], "ImageBB": [82, 556, 420, 843]}, "diagram_type": "multiple"}, {"id": 1103, "width": 1332, "height": 364, "file_name": "jo9717245-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [322.51, 318.08, 92.62, 45.34], "category_id": 3}, {"id": 1, "bbox": [766.95, 0.0, 345.83, 309.5], "category_id": 1}, {"id": 2, "bbox": [0.0, 149.37, 43.31, 52.68], "category_id": 3}, {"id": 3, "bbox": [854.88, 314.14, 90.41, 41.19], "category_id": 3}, {"id": 4, "bbox": [197.23, 0.0, 381.15, 307.2], "category_id": 1}, {"id": 5, "bbox": [1286.69, 149.37, 45.31, 52.68], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 64, 636, 78], "ImageBB": [442, 85, 775, 176]}, "reactions": [{"reactants": [4], "conditions": [], "products": [2]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4]}, {"reactants": [1], "conditions": [], "products": [5]}], "diagram_type": "single"}, {"id": 1357, "width": 992, "height": 1352, "file_name": "op9000687-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [470.08, 987.45, 399.74, 52.08], "category_id": 2}, {"id": 1, "bbox": [0.0, 327.35, 411.24, 177.87], "category_id": 1}, {"id": 2, "bbox": [469.41, 1043.59, 429.5, 48.7], "category_id": 2}, {"id": 3, "bbox": [772.42, 124.45, 56.14, 45.31], "category_id": 3}, {"id": 4, "bbox": [124.45, 734.5, 572.9, 202.9], "category_id": 1}, {"id": 5, "bbox": [263.79, 522.13, 373.36, 110.25], "category_id": 2}, {"id": 6, "bbox": [321.96, 1304.66, 62.22, 47.34], "category_id": 3}, {"id": 7, "bbox": [708.17, 190.73, 283.83, 104.83], "category_id": 2}, {"id": 8, "bbox": [319.25, 914.41, 67.64, 54.78], "category_id": 3}, {"id": 9, "bbox": [148.8, 1100.4, 547.19, 202.9], "category_id": 1}, {"id": 10, "bbox": [553.28, 313.14, 381.48, 167.74], "category_id": 1}, {"id": 11, "bbox": [100.1, 473.44, 58.17, 46.66], "category_id": 3}, {"id": 12, "bbox": [567.48, 2.71, 333.46, 117.0], "category_id": 1}, {"id": 13, "bbox": [753.49, 488.99, 60.19, 45.99], "category_id": 3}, {"id": 14, "bbox": [0.0, 1347.94, 0.68, 4.06], "category_id": 3}, {"id": 15, "bbox": [0.0, 1347.94, 8.79, 4.06], "category_id": 3}], "caption": "Scheme 5. 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Reactions of Salicylaldehyde 1a (0.5 mmol) with 3-Methylpenta-3,4-dien-2-one 2a (2.0 mmol) in the Presence of Various Lewis Bases and Solvents ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 402, 120], "ImageBB": [74, 125, 410, 481]}, "diagram_type": "single"}, {"id": 1371, "width": 1080, "height": 1404, "file_name": "op9800717-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [718.07, 414.39, 331.64, 224.75], "category_id": 1}, {"id": 1, "bbox": [605.65, 271.81, 92.75, 54.08], "category_id": 2}, {"id": 2, "bbox": [751.1, 1250.89, 318.28, 150.3], "category_id": 1}, {"id": 3, "bbox": [49.18, 410.88, 398.39, 229.66], "category_id": 1}, {"id": 4, "bbox": [411.03, 0.0, 423.68, 222.65], "category_id": 1}, {"id": 5, "bbox": [751.1, 828.07, 294.39, 233.88], "category_id": 1}], "caption": "Scheme 5", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 304, 135, 318], "ImageBB": [107, 323, 377, 674]}, "reactions": [{"reactants": [4], "conditions": [1], "products": [3, 0]}, {"reactants": [3, 0], "conditions": [], "products": [4]}, {"reactants": [3], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [3]}, {"reactants": [0], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [2]}], "diagram_type": "tree"}, {"id": 543, "width": 1316, "height": 1164, "file_name": "acs.orglett.5b03590-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [222.2, 2.0, 328.8, 215.0], "category_id": 1}, {"id": 1, "bbox": [778.0, 459.0, 90.4, 64.0], "category_id": 3}, {"id": 2, "bbox": [472.0, 457.0, 76.3, 70.0], "category_id": 3}, {"id": 3, "bbox": [131.0, 457.0, 79.2, 64.4], "category_id": 3}, {"id": 4, "bbox": [66.0, 866.0, 210.5, 205.0], "category_id": 1}, {"id": 5, "bbox": [649.0, 871.0, 344.3, 225.5], "category_id": 1}, {"id": 6, "bbox": [978.0, 863.1, 334.6, 211.5], "category_id": 1}, {"id": 7, "bbox": [1022.1, 561.3, 249.1, 203.2], "category_id": 1}, {"id": 8, "bbox": [721.8, 557.8, 212.5, 205.1], "category_id": 1}, {"id": 9, "bbox": [400.0, 563.0, 206.9, 201.7], "category_id": 1}, {"id": 10, "bbox": [0.0, 539.0, 339.0, 225.6], "category_id": 1}, {"id": 11, "bbox": [686.55, 262.8, 277.85, 203.4], "category_id": 1}, {"id": 12, "bbox": [863.0, 0.0, 228.3, 219.2], "category_id": 1}, {"id": 13, "bbox": [773.0, 1088.0, 107.0, 66.0], "category_id": 3}, {"id": 14, "bbox": [121.0, 774.0, 101.0, 77.0], "category_id": 3}, {"id": 15, "bbox": [558.0, 136.0, 276.0, 54.0], "category_id": 2}, {"id": 16, "bbox": [1100.0, 1085.0, 97.0, 79.0], "category_id": 3}, {"id": 17, "bbox": [0.0, 261.0, 339.0, 205.0], "category_id": 1}, {"id": 18, "bbox": [319.0, 263.0, 386.0, 207.0], "category_id": 1}, {"id": 19, "bbox": [1010.0, 258.0, 273.0, 205.0], "category_id": 1}, {"id": 20, "bbox": [339.0, 854.0, 334.0, 222.0], "category_id": 1}, {"id": 21, "bbox": [349.0, 226.0, 70.0, 35.0], "category_id": 3}, {"id": 22, "bbox": [915.0, 228.0, 85.0, 28.0], "category_id": 3}, {"id": 23, "bbox": [1104.0, 457.0, 86.0, 76.0], "category_id": 3}, {"id": 24, "bbox": [1113.0, 773.0, 78.0, 72.0], "category_id": 3}, {"id": 25, "bbox": [769.0, 765.0, 108.0, 74.0], "category_id": 3}, {"id": 26, "bbox": [448.0, 776.0, 88.0, 62.0], "category_id": 3}, {"id": 27, "bbox": [124.0, 1085.0, 100.0, 79.0], "category_id": 3}, {"id": 28, "bbox": [471.0, 1073.0, 85.0, 73.0], "category_id": 3}, {"id": 29, "bbox": [573.0, 90.0, 227.0, 49.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [29, 15], "products": [12]}], "corefs": [[0, 21], [12, 22], [17, 3], [18, 2], [11, 1], [19, 23], [10, 14], [9, 26], [8, 25], [7, 24], [4, 27], [20, 28], [5, 13], [6, 16]], "caption": "Table 2. Cascade Synthesis of Triazinonesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 138, 689, 159], "ImageBB": [453, 165, 782, 456]}, "diagram_type": "single"}, {"id": 293, "width": 1344, "height": 1024, "file_name": "ol400110c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 498.0, 1335.0, 526.0], "category_id": 4}, {"id": 1, "bbox": [1016.0, 325.0, 70.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [596.0, 189.0, 135.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [538.0, 98.9, 236.3, 57.1], "category_id": 2}, {"id": 4, "bbox": [318.0, 330.72, 63.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [156.2, 4.0, 335.5, 324.0], "category_id": 1}, {"id": 6, "bbox": [876.0, 21.0, 312.9, 289.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [3, 2], "products": [6]}], "corefs": [[5, 4], [6, 1]], "caption": "Table 1. Optimization Studies", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 237, 231, 250], "ImageBB": [71, 261, 407, 517]}, "diagram_type": "single"}, {"id": 939, "width": 1356, "height": 1092, "file_name": "acs.orglett.5b01309-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [209.61, 1009.14, 37.31, 38.68], "category_id": 3}, {"id": 1, "bbox": [959.17, 416.69, 392.76, 242.27], "category_id": 1}, {"id": 2, "bbox": [495.87, 259.24, 43.41, 46.15], "category_id": 3}, {"id": 3, "bbox": [754.99, 29.18, 395.47, 233.45], "category_id": 1}, {"id": 4, "bbox": [707.51, 662.35, 73.26, 42.76], "category_id": 3}, {"id": 5, "bbox": [231.31, 692.89, 231.32, 73.3], "category_id": 2}, {"id": 6, "bbox": [871.67, 274.85, 202.82, 40.04], "category_id": 3}, {"id": 7, "bbox": [510.79, 394.97, 389.37, 241.6], "category_id": 1}, {"id": 8, "bbox": [1117.22, 682.71, 78.01, 38.01], "category_id": 3}, {"id": 9, "bbox": [175.69, 272.14, 94.29, 44.11], "category_id": 3}, {"id": 10, "bbox": [5.51, 56.37, 381.47, 208.44], "category_id": 1}, {"id": 11, "bbox": [105.14, 634.53, 71.23, 37.32], "category_id": 3}, {"id": 12, "bbox": [439.56, 50.9, 194.69, 168.3], "category_id": 1}, {"id": 13, "bbox": [1016.15, 338.64, 84.12, 49.54], "category_id": 2}, {"id": 14, "bbox": [12.89, 407.86, 391.4, 265.35], "category_id": 1}, {"id": 15, "bbox": [47.48, 785.87, 373.77, 218.52], "category_id": 1}, {"id": 16, "bbox": [16.28, 690.86, 193.33, 72.61], "category_id": 2}], "caption": "Scheme 6. Zwitterion Formation in \u03b2-Lactam Formation", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 170, 768, 190], "ImageBB": [448, 196, 787, 469]}, "reactions": [{"reactants": [10, 12], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [13], "products": [1]}, {"reactants": [1], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [1]}, {"reactants": [14], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [16, 5], "products": [15]}], "diagram_type": "tree"}, {"id": 811, "width": 2820, "height": 936, "file_name": "jo4027148-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2025.0, 729.0, 213.0, 104.0], "category_id": 2}, {"id": 1, "bbox": [146.0, 884.0, 61.0, 52.0], "category_id": 3}, {"id": 2, "bbox": [422.0, 886.0, 68.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [1842.0, 886.0, 69.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [1000.0, 877.0, 61.0, 59.0], "category_id": 3}, {"id": 5, "bbox": [867.0, 152.0, 283.0, 60.2], "category_id": 2}, {"id": 6, "bbox": [1736.5, 151.6, 270.7, 59.9], "category_id": 2}, {"id": 7, "bbox": [366.8, 41.0, 343.2, 351.0], "category_id": 1}, {"id": 8, "bbox": [1481.0, 881.0, 67.0, 55.0], "category_id": 3}, {"id": 9, "bbox": [1274.3, 118.5, 346.7, 200.7], "category_id": 1}, {"id": 10, "bbox": [2116.0, 391.0, 343.0, 67.1], "category_id": 3}, {"id": 11, "bbox": [353.0, 398.0, 334.0, 57.6], "category_id": 3}, {"id": 12, "bbox": [2479.0, 884.0, 64.0, 52.0], "category_id": 3}, {"id": 13, "bbox": [867.9, 592.5, 328.1, 236.2], "category_id": 1}, {"id": 14, "bbox": [372.0, 619.0, 166.0, 177.7], "category_id": 1}, {"id": 15, "bbox": [2119.1, 46.8, 327.0, 340.2], "category_id": 1}, {"id": 16, "bbox": [52.0, 596.0, 244.0, 233.0], "category_id": 1}, {"id": 17, "bbox": [1331.0, 592.0, 363.0, 241.0], "category_id": 1}, {"id": 18, "bbox": [1753.0, 599.0, 244.0, 221.0], "category_id": 1}, {"id": 19, "bbox": [2272.0, 555.0, 493.0, 315.0], "category_id": 1}, {"id": 20, "bbox": [75.0, 70.0, 52.0, 64.0], "category_id": 3}, {"id": 21, "bbox": [77.0, 537.0, 44.0, 53.0], "category_id": 3}, {"id": 22, "bbox": [2009.0, 585.0, 247.0, 116.0], "category_id": 2}, {"id": 23, "bbox": [566.0, 725.6, 276.0, 132.4], "category_id": 2}, {"id": 24, "bbox": [587.0, 601.0, 246.0, 98.6], "category_id": 2}, {"id": 25, "bbox": [1299.0, 389.0, 310.0, 71.0], "category_id": 3}, {"id": 26, "bbox": [1756.61, 236.23, 231.81, 53.17], "category_id": 2}, {"id": 27, "bbox": [886.79, 238.36, 240.31, 53.16], "category_id": 2}, {"id": 28, "bbox": [395.52, 821.07, 123.35, 57.42], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [5, 27], "products": [9]}, {"reactants": [9], "conditions": [6, 26], "products": [15]}, {"reactants": [16, 14], "conditions": [24, 23], "products": [13]}, {"reactants": [17, 18], "conditions": [22, 0], "products": [19]}], "corefs": [[7, 11], [9, 25], [15, 10], [16, 1], [14, 2], [13, 4], [17, 8], [18, 3], [19, 12]], "caption": "Figure 3. Examples of (A) solid-state photochemistry and (B) photoredox-catalyzed [2 + 2] cycloadditions.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 870, 605, 884], "ImageBB": [82, 627, 787, 861]}, "diagram_type": "multiple"}, {"id": 1022, "width": 1024, "height": 556, "file_name": "jo000585f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [129.09, 196.65, 39.95, 47.62], "category_id": 3}, {"id": 1, "bbox": [809.36, 195.62, 105.53, 53.77], "category_id": 3}, {"id": 2, "bbox": [573.73, 344.13, 69.66, 53.26], "category_id": 2}, {"id": 3, "bbox": [188.0, 297.02, 289.42, 156.19], "category_id": 1}, {"id": 4, "bbox": [300.18, 489.57, 105.01, 56.33], "category_id": 3}, {"id": 5, "bbox": [727.92, 306.75, 261.25, 160.28], "category_id": 1}, {"id": 6, "bbox": [424.15, 121.88, 136.77, 49.16], "category_id": 2}, {"id": 7, "bbox": [675.67, 6.66, 345.26, 151.07], "category_id": 1}, {"id": 8, "bbox": [0.0, 3.07, 345.77, 149.54], "category_id": 1}, {"id": 9, "bbox": [364.5, 51.7, 256.87, 63.01], "category_id": 2}, {"id": 10, "bbox": [832.42, 494.69, 103.98, 55.82], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [114, 82, 370, 221]}, "reactions": [{"reactants": [8], "conditions": [9, 6], "products": [7]}, {"reactants": [7], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [2], "products": [5]}], "diagram_type": "multiple"}, {"id": 436, "width": 1352, "height": 792, "file_name": "op3000042-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [596.1, 645.88, 281.9, 140.8], "category_id": 1}, {"id": 1, "bbox": [17.0, 162.0, 217.5, 54.0], "category_id": 2}, {"id": 2, "bbox": [1081.5, 637.1, 249.8, 143.8], "category_id": 1}, {"id": 3, "bbox": [690.0, 532.2, 141.8, 46.8], "category_id": 1}, {"id": 4, "bbox": [588.7, 330.7, 189.5, 130.7], "category_id": 1}, {"id": 5, "bbox": [30.0, 261.0, 150.0, 55.0], "category_id": 2}, {"id": 6, "bbox": [458.0, 334.0, 55.0, 45.0], "category_id": 2}, {"id": 7, "bbox": [875.0, 616.0, 187.0, 84.0], "category_id": 2}, {"id": 8, "bbox": [60.6, 322.9, 287.0, 123.1], "category_id": 1}, {"id": 9, "bbox": [889.1, 322.7, 186.2, 120.7], "category_id": 1}, {"id": 10, "bbox": [588.8, 17.7, 190.4, 133.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6], "products": [4, 9]}, {"reactants": [4, 9], "conditions": [], "products": [8]}, {"reactants": [4], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [3], "products": [0]}, {"reactants": [0], "conditions": [], "products": [4]}, {"reactants": [0], "conditions": [7], "products": [2]}], "corefs": [], "caption": "Figure 1. Proposed isobutylene/acetic acid/tert-butyl acetate equili- brium. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 550, 784, 578], "ImageBB": [448, 343, 786, 541]}, "diagram_type": "tree"}, {"id": 645, "width": 1352, "height": 384, "file_name": "ol500618w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [648.86, 135.31, 342.84, 140.19], "category_id": 2}, {"id": 1, "bbox": [475.08, 195.0, 38.12, 40.9], "category_id": 3}, {"id": 2, "bbox": [1168.94, 188.32, 63.46, 54.78], "category_id": 3}, {"id": 3, "bbox": [76.63, 238.55, 136.67, 50.55], "category_id": 2}, {"id": 4, "bbox": [411.58, 238.27, 166.52, 50.63], "category_id": 2}, {"id": 5, "bbox": [3.37, 35.45, 281.33, 140.65], "category_id": 1}, {"id": 6, "bbox": [413.5, 48.2, 157.3, 113.9], "category_id": 1}, {"id": 7, "bbox": [1052.86, 36.59, 295.64, 140.51], "category_id": 1}, {"id": 8, "bbox": [6.0, 312.8, 1346.0, 71.2], "category_id": 4}, {"id": 9, "bbox": [116.5, 194.04, 55.7, 43.46], "category_id": 3}, {"id": 10, "bbox": [638.13, 5.14, 369.0, 88.0], "category_id": 2}], "reactions": [{"reactants": [5, 6], "conditions": [10, 0], "products": [7]}], "corefs": [[5, 9], [6, 1], [7, 2]], "caption": "Table 2. Optimization of the Reaction Conditions for the Cyanation Reaction of Alkenyl Bromide 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 407, 125], "ImageBB": [82, 131, 420, 227]}, "diagram_type": "single"}, {"id": 1161, "width": 1352, "height": 488, "file_name": "ol0604623-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [432.18, 41.27, 270.54, 67.65], "category_id": 1}, {"id": 1, "bbox": [436.91, 156.96, 259.72, 161.69], "category_id": 1}, {"id": 2, "bbox": [246.86, 79.83, 177.2, 150.19], "category_id": 1}, {"id": 3, "bbox": [261.74, 239.49, 122.42, 77.81], "category_id": 2}, {"id": 4, "bbox": [1074.7, 336.24, 156.24, 46.68], "category_id": 3}, {"id": 5, "bbox": [747.35, 4.06, 240.78, 219.2], "category_id": 1}, {"id": 6, "bbox": [0.0, 97.42, 234.01, 225.29], "category_id": 1}, {"id": 7, "bbox": [798.76, 246.26, 125.12, 74.42], "category_id": 2}, {"id": 8, "bbox": [963.78, 110.28, 388.22, 221.22], "category_id": 1}, {"id": 9, "bbox": [503.87, 311.88, 163.0, 121.1], "category_id": 3}, {"id": 10, "bbox": [79.81, 330.83, 156.23, 47.35], "category_id": 3}, {"id": 11, "bbox": [607.69, 153.76, 25.49, 33.64], "category_id": 3}, {"id": 12, "bbox": [587.29, 120.11, 76.47, 38.74], "category_id": 2}, {"id": 13, "bbox": [529.57, 103.51, 36.53, 36.53], "category_id": 3}], "caption": "Scheme 1. Reaction of Huisgen Zwitterion with Cyclic and                  Acyclic 1,2-Diones ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [448, 811, 767, 838], "ImageBB": [439, 842, 777, 964]}, "reactions": [{"reactants": [0], "conditions": [12], "products": [1]}, {"reactants": [1, 2], "conditions": [3], "products": [6]}, {"reactants": [1, 5], "conditions": [7], "products": [8]}], "diagram_type": "single"}, {"id": 433, "width": 3396, "height": 2324, "file_name": "op300087r-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2289.0, 818.0, 412.0, 110.0], "category_id": 2}, {"id": 1, "bbox": [840.55, 1412.75, 32.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [838.0, 820.0, 40.2, 44.5], "category_id": 3}, {"id": 3, "bbox": [1607.2, 850.0, 158.8, 61.0], "category_id": 2}, {"id": 4, "bbox": [594.0, 1023.0, 589.1, 389.0], "category_id": 1}, {"id": 5, "bbox": [2203.54, 1038.88, 590.0, 341.0], "category_id": 1}, {"id": 6, "bbox": [2211.0, 448.0, 578.8, 341.3], "category_id": 1}, {"id": 7, "bbox": [609.0, 451.0, 568.4, 377.0], "category_id": 1}, {"id": 8, "bbox": [2282.0, 1405.0, 419.0, 100.0], "category_id": 2}, {"id": 9, "bbox": [1286.0, 1208.0, 567.0, 142.0], "category_id": 2}, {"id": 10, "bbox": [1293.0, 1059.0, 794.0, 137.0], "category_id": 2}, {"id": 11, "bbox": [1615.0, 1408.0, 158.0, 56.0], "category_id": 2}, {"id": 12, "bbox": [1283.0, 633.0, 619.0, 200.0], "category_id": 2}, {"id": 13, "bbox": [1291.0, 470.0, 582.0, 156.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [13, 12], "products": [6]}, {"reactants": [4], "conditions": [10, 9], "products": [5]}], "corefs": [[7, 2], [6, 0], [4, 1], [5, 8]], "caption": "Figure 3. Optical micrographs of bosutinib monohydrate isolated from: A) water, and B) MIBK/water.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 612, 584, 626], "ImageBB": [10, 22, 859, 603]}, "diagram_type": "multiple"}, {"id": 135, "width": 1188, "height": 1220, "file_name": "op8002486-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 663.0, 401.0, 141.1], "category_id": 1}, {"id": 1, "bbox": [330.0, 174.0, 114.0, 50.1], "category_id": 2}, {"id": 2, "bbox": [3.0, 987.0, 409.0, 140.0], "category_id": 1}, {"id": 3, "bbox": [167.93, 1168.14, 69.17, 50.31], "category_id": 3}, {"id": 4, "bbox": [171.07, 826.98, 64.46, 55.02], "category_id": 3}, {"id": 5, "bbox": [171.07, 510.97, 64.46, 56.6], "category_id": 3}, {"id": 6, "bbox": [175.79, 166.67, 58.17, 51.88], "category_id": 3}, {"id": 7, "bbox": [1073.0, 525.0, 111.0, 54.0], "category_id": 2}, {"id": 8, "bbox": [325.0, 508.0, 122.0, 53.0], "category_id": 2}, {"id": 9, "bbox": [536.0, 343.0, 111.0, 56.0], "category_id": 2}, {"id": 10, "bbox": [946.0, 241.0, 207.0, 55.0], "category_id": 2}, {"id": 11, "bbox": [1080.0, 169.0, 100.0, 59.0], "category_id": 2}, {"id": 12, "bbox": [526.0, 7.0, 116.0, 69.0], "category_id": 2}, {"id": 13, "bbox": [702.0, 993.0, 426.0, 147.0], "category_id": 1}, {"id": 14, "bbox": [704.0, 663.0, 402.0, 138.0], "category_id": 1}, {"id": 15, "bbox": [704.0, 347.0, 444.0, 174.0], "category_id": 1}, {"id": 16, "bbox": [2.0, 339.0, 462.0, 163.0], "category_id": 1}, {"id": 17, "bbox": [701.0, 12.0, 375.0, 169.0], "category_id": 1}, {"id": 18, "bbox": [2.0, 4.0, 370.0, 164.0], "category_id": 1}, {"id": 19, "bbox": [329.0, 1145.0, 118.0, 55.0], "category_id": 2}, {"id": 20, "bbox": [1076.0, 1150.0, 106.0, 63.0], "category_id": 2}, {"id": 21, "bbox": [538.0, 1000.0, 111.0, 65.0], "category_id": 2}, {"id": 22, "bbox": [950.0, 894.0, 200.0, 62.0], "category_id": 2}, {"id": 23, "bbox": [1073.0, 791.0, 111.0, 50.0], "category_id": 2}, {"id": 24, "bbox": [533.0, 658.0, 114.0, 67.0], "category_id": 2}, {"id": 25, "bbox": [332.0, 829.0, 116.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [18], "conditions": [12], "products": [17]}, {"reactants": [17], "conditions": [], "products": [18]}, {"reactants": [17], "conditions": [10], "products": [15]}, {"reactants": [15], "conditions": [], "products": [17]}, {"reactants": [16], "conditions": [9], "products": [15]}, {"reactants": [15], "conditions": [], "products": [16]}, {"reactants": [0], "conditions": [24], "products": [14]}, {"reactants": [14], "conditions": [], "products": [0]}, {"reactants": [14], "conditions": [22], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}, {"reactants": [13], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [21], "products": [13]}], "corefs": [[18, 6], [16, 5], [0, 4], [2, 3]], "caption": "Table 1. Predicted reaction times for cyanate conversion to reach >95% with KOCN addition times of 0.25 h, 0.5 h, and 1 h (20 \u00b0C, 2 mol % excess of 15) ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 382, 760, 424], "ImageBB": [445, 65, 742, 370]}, "diagram_type": "tree"}, {"id": 549, "width": 1348, "height": 496, "file_name": "acs.orglett.5b03104-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [572.0, 235.0, 343.0, 52.9], "category_id": 2}, {"id": 1, "bbox": [624.0, 310.0, 239.0, 89.8], "category_id": 2}, {"id": 2, "bbox": [60.0, 220.3, 284.9, 143.4], "category_id": 1}, {"id": 3, "bbox": [924.1, 199.3, 359.6, 187.2], "category_id": 1}, {"id": 4, "bbox": [629.28, 175.27, 52.86, 45.75], "category_id": 3}, {"id": 5, "bbox": [7.13, 425.35, 1333.77, 70.15], "category_id": 4}, {"id": 6, "bbox": [590.4, 0.0, 309.3, 229.0], "category_id": 1}, {"id": 7, "bbox": [382.0, 243.0, 179.0, 104.0], "category_id": 1}], "reactions": [{"reactants": [2, 7], "conditions": [6, 0, 1], "products": [3]}], "corefs": [[6, 4]], "caption": "Table 1. Selected Entries of Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 744, 110], "ImageBB": [449, 116, 786, 240]}, "diagram_type": "single"}, {"id": 822, "width": 2820, "height": 1680, "file_name": "jo400755q-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [580.0, 1014.0, 391.0, 427.0], "category_id": 1}, {"id": 1, "bbox": [727.0, 0.0, 330.0, 317.0], "category_id": 1}, {"id": 2, "bbox": [1732.0, 90.0, 359.0, 69.0], "category_id": 2}, {"id": 3, "bbox": [1057.0, 30.0, 316.0, 99.0], "category_id": 2}, {"id": 4, "bbox": [1061.0, 139.0, 325.0, 95.0], "category_id": 2}, {"id": 5, "bbox": [1873.0, 401.0, 412.0, 447.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 1567.0, 2733.0, 113.0], "category_id": 2}, {"id": 7, "bbox": [1441.0, 427.5, 417.0, 420.5], "category_id": 1}, {"id": 8, "bbox": [1384.0, 0.0, 332.2, 311.7], "category_id": 1}, {"id": 9, "bbox": [542.3, 420.3, 355.4, 417.7], "category_id": 1}, {"id": 10, "bbox": [920.3, 416.0, 484.2, 458.0], "category_id": 1}, {"id": 11, "bbox": [1799.0, 1030.8, 481.7, 315.7], "category_id": 1}, {"id": 12, "bbox": [1221.3, 992.0, 298.7, 437.5], "category_id": 1}, {"id": 13, "bbox": [770.0, 304.0, 194.0, 53.0], "category_id": 3}, {"id": 14, "bbox": [1507.0, 304.0, 95.0, 53.0], "category_id": 3}, {"id": 15, "bbox": [1976.0, 867.0, 277.0, 73.0], "category_id": 3}, {"id": 16, "bbox": [1531.0, 863.0, 256.0, 68.0], "category_id": 3}, {"id": 17, "bbox": [1054.0, 874.0, 259.0, 60.0], "category_id": 3}, {"id": 18, "bbox": [603.0, 871.0, 255.0, 60.0], "category_id": 3}, {"id": 19, "bbox": [663.0, 1448.0, 254.0, 70.0], "category_id": 3}, {"id": 20, "bbox": [1223.0, 1450.0, 242.0, 66.0], "category_id": 3}, {"id": 21, "bbox": [1802.0, 1443.0, 263.0, 69.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [3, 4], "products": [8]}], "corefs": [[1, 13], [8, 14], [9, 18], [10, 17], [7, 16], [5, 15], [0, 19], [12, 20], [11, 21]], "caption": "Table 4. Ortho-Iodination of N-Aryl Ring of N,1-Diaryl-1H-tetrazol-5-aminea", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 517, 111], "ImageBB": [82, 116, 787, 536]}, "diagram_type": "single"}, {"id": 647, "width": 1348, "height": 420, "file_name": "ol500444z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [984.0, 275.0, 81.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [842.9, 93.6, 346.1, 156.7], "category_id": 1}, {"id": 2, "bbox": [462.3, 2.7, 275.8, 158.7], "category_id": 1}, {"id": 3, "bbox": [164.33, 109.25, 218.37, 142.45], "category_id": 1}, {"id": 4, "bbox": [220.0, 259.0, 78.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [508.0, 195.0, 231.0, 81.0], "category_id": 2}, {"id": 6, "bbox": [32.0, 352.0, 1294.0, 65.0], "category_id": 4}], "reactions": [{"reactants": [3], "conditions": [2, 5], "products": [1]}], "corefs": [[3, 4], [1, 0]], "caption": "Table 1. Synthesis of Quinoxalinesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 212, 285, 233], "ImageBB": [82, 239, 419, 344]}, "diagram_type": "single"}, {"id": 1365, "width": 884, "height": 864, "file_name": "op960008m-Scheme-c14.png", "license": 0, "bboxes": [{"id": 0, "bbox": [642.99, 652.2, 218.46, 211.8], "category_id": 1}, {"id": 1, "bbox": [628.4, 313.05, 255.6, 169.8], "category_id": 1}, {"id": 2, "bbox": [256.05, 321.01, 178.65, 108.78], "category_id": 1}, {"id": 3, "bbox": [256.05, 4.5, 175.12, 96.7], "category_id": 1}, {"id": 4, "bbox": [13.71, 38.03, 209.17, 71.37], "category_id": 1}, {"id": 5, "bbox": [636.9, 0.0, 247.1, 131.7], "category_id": 1}, {"id": 6, "bbox": [0.0, 292.71, 210.5, 149.46], "category_id": 1}, {"id": 7, "bbox": [256.05, 694.64, 154.33, 103.03], "category_id": 1}, {"id": 8, "bbox": [15.04, 704.81, 212.7, 84.9], "category_id": 1}], "caption": "Scheme 14. Selected reactions catalysed by KF/alumina", "pdf": {"Page": 14, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 197, 388, 211], "ImageBB": [131, 216, 352, 432]}, "reactions": [{"reactants": [4, 3], "conditions": [], "products": [5]}, {"reactants": [6, 2], "conditions": [], "products": [1]}, {"reactants": [8, 7], "conditions": [], "products": [0]}], "diagram_type": "multiple"}, {"id": 470, "width": 1352, "height": 732, "file_name": "op100205s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [971.0, 3.0, 377.0, 273.0], "category_id": 1}, {"id": 1, "bbox": [596.0, 11.0, 341.0, 275.0], "category_id": 1}, {"id": 2, "bbox": [2.0, 8.0, 339.0, 278.0], "category_id": 1}, {"id": 3, "bbox": [863.0, 252.0, 66.0, 34.0], "category_id": 3}, {"id": 4, "bbox": [1241.0, 252.0, 66.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [263.0, 250.0, 48.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [5.0, 305.0, 1338.0, 419.0], "category_id": 4}, {"id": 7, "bbox": [348.0, 105.0, 206.0, 40.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [7], "products": [1, 0]}], "corefs": [[2, 5], [1, 3], [0, 4]], "caption": "Table 3. Screen of conditions for pyridine N-methylation of 9b ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 386, 73], "ImageBB": [58, 88, 396, 271]}, "diagram_type": "single"}, {"id": 114, "width": 1012, "height": 1472, "file_name": "op990044w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [831.0, 1019.4, 42.8, 48.6], "category_id": 3}, {"id": 1, "bbox": [709.0, 932.7, 122.0, 196.3], "category_id": 1}, {"id": 2, "bbox": [241.5, 379.6, 123.5, 190.9], "category_id": 1}, {"id": 3, "bbox": [609.1, 628.8, 402.9, 191.5], "category_id": 1}, {"id": 4, "bbox": [650.0, 81.2, 289.2, 226.5], "category_id": 1}, {"id": 5, "bbox": [75.8, 78.5, 288.7, 226.8], "category_id": 1}, {"id": 6, "bbox": [0.0, 999.1, 279.9, 80.9], "category_id": 2}, {"id": 7, "bbox": [757.0, 272.0, 69.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [171.0, 271.0, 66.0, 55.0], "category_id": 3}, {"id": 9, "bbox": [369.0, 464.0, 34.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [410.0, 1419.0, 54.0, 53.0], "category_id": 3}, {"id": 11, "bbox": [293.0, 1149.0, 328.0, 235.0], "category_id": 1}, {"id": 12, "bbox": [777.0, 828.0, 77.0, 60.0], "category_id": 3}, {"id": 13, "bbox": [172.0, 846.0, 51.0, 50.0], "category_id": 3}, {"id": 14, "bbox": [509.0, 411.0, 269.0, 80.0], "category_id": 2}, {"id": 15, "bbox": [136.0, 0.0, 158.0, 47.0], "category_id": 2}, {"id": 16, "bbox": [55.0, 610.0, 330.0, 212.0], "category_id": 1}, {"id": 17, "bbox": [719.0, 0.0, 160.0, 52.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [2], "products": [16]}, {"reactants": [16], "conditions": [6], "products": [11]}, {"reactants": [4], "conditions": [14], "products": [3]}, {"reactants": [3], "conditions": [1], "products": [11]}], "corefs": [[5, 8], [4, 7], [2, 9], [16, 13], [3, 12], [1, 0], [11, 10]], "caption": "Table 1. Horner-Emmons reaction of aldehyde (5b) and triethyl phosphonoacetatea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 454, 753, 482], "ImageBB": [482, 74, 735, 442]}, "diagram_type": "tree"}, {"id": 665, "width": 1348, "height": 1260, "file_name": "ol402047d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [837.0, 108.0, 96.1, 248.0], "category_id": 1}, {"id": 1, "bbox": [401.0, 205.0, 145.0, 42.0], "category_id": 2}, {"id": 2, "bbox": [229.0, 0.0, 257.0, 250.0], "category_id": 1}, {"id": 3, "bbox": [1008.0, 392.0, 31.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [1103.0, 226.0, 160.0, 78.0], "category_id": 2}, {"id": 5, "bbox": [0.0, 453.0, 1348.0, 807.0], "category_id": 4}, {"id": 6, "bbox": [654.0, 211.0, 144.0, 38.0], "category_id": 2}, {"id": 7, "bbox": [93.0, 225.0, 152.0, 81.0], "category_id": 2}, {"id": 8, "bbox": [241.0, 251.0, 301.0, 46.0], "category_id": 2}, {"id": 9, "bbox": [864.0, 359.0, 35.0, 42.0], "category_id": 3}, {"id": 10, "bbox": [983.0, 105.0, 93.0, 290.0], "category_id": 1}, {"id": 11, "bbox": [619.0, 113.0, 211.0, 86.0], "category_id": 1}, {"id": 12, "bbox": [738.0, 182.0, 32.0, 31.0], "category_id": 3}, {"id": 13, "bbox": [582.0, 249.0, 230.0, 164.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [2, 1, 8, 11, 6, 13], "products": [0, 10, 4]}], "corefs": [[11, 12], [0, 9], [10, 3]], "caption": "Table 2. Structure Activity Study of Siloxane Polymers in CCRa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 771, 101], "ImageBB": [436, 112, 773, 427]}, "diagram_type": "single"}, {"id": 450, "width": 1688, "height": 992, "file_name": "op2001047-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [310.0, 551.0, 45.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [43.0, 598.3, 290.4, 177.7], "category_id": 1}, {"id": 2, "bbox": [6.0, 405.6, 364.7, 173.4], "category_id": 1}, {"id": 3, "bbox": [1023.3, 1.3, 238.4, 125.4], "category_id": 1}, {"id": 4, "bbox": [433.0, 2.3, 148.4, 126.7], "category_id": 1}, {"id": 5, "bbox": [1120.0, 152.0, 92.4, 50.0], "category_id": 3}, {"id": 6, "bbox": [727.0, 125.0, 184.7, 44.0], "category_id": 2}, {"id": 7, "bbox": [49.6, 797.6, 275.1, 183.4], "category_id": 1}, {"id": 8, "bbox": [263.0, 756.0, 54.0, 29.0], "category_id": 3}, {"id": 9, "bbox": [274.0, 946.0, 49.0, 46.0], "category_id": 3}, {"id": 10, "bbox": [7.0, 284.0, 1677.0, 708.0], "category_id": 4}, {"id": 11, "bbox": [653.0, 3.0, 337.0, 93.0], "category_id": 2}, {"id": 12, "bbox": [464.0, 165.0, 102.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [11, 6], "products": [3]}], "corefs": [[4, 12], [3, 5], [2, 0], [1, 8], [7, 9]], "caption": "Table 5. Reaction optimization for the aldol reaction of acetone with aldehydes 4a c under microwave batch and continuous \ufb02ow conditionsa ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 88, 770, 122], "ImageBB": [211, 133, 633, 381]}, "diagram_type": "single"}, {"id": 1140, "width": 1352, "height": 2000, "file_name": "ol016466j-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [750.47, 1196.6, 375.23, 66.03], "category_id": 2}, {"id": 1, "bbox": [445.28, 4.0, 45.02, 46.03], "category_id": 3}, {"id": 2, "bbox": [508.32, 556.28, 343.21, 124.06], "category_id": 2}, {"id": 3, "bbox": [750.47, 1269.63, 395.24, 63.04], "category_id": 2}, {"id": 4, "bbox": [486.3, 90.05, 287.18, 111.05], "category_id": 2}, {"id": 5, "bbox": [397.25, 492.25, 51.03, 54.02], "category_id": 3}, {"id": 6, "bbox": [264.16, 1715.86, 422.27, 110.05], "category_id": 3}, {"id": 7, "bbox": [486.3, 1188.59, 55.04, 63.04], "category_id": 3}, {"id": 8, "bbox": [132.08, 1015.51, 582.36, 234.11], "category_id": 1}, {"id": 9, "bbox": [103.06, 92.05, 1013.63, 467.23], "category_id": 1}, {"id": 10, "bbox": [103.06, 517.26, 826.52, 460.04], "category_id": 1}, {"id": 11, "bbox": [103.06, 1238.8, 1144.14, 599.12], "category_id": 1}, {"id": 12, "bbox": [750.47, 1083.54, 422.26, 116.06], "category_id": 2}, {"id": 13, "bbox": [132.08, 941.47, 658.22, 104.05], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 534, 631, 547], "ImageBB": [439, 553, 777, 1053]}, "reactions": [{"reactants": [1], "conditions": [4], "products": [9]}, {"reactants": [9], "conditions": [2], "products": [10]}, {"reactants": [8], "conditions": [12, 0, 3], "products": [11]}], "diagram_type": "tree"}, {"id": 553, "width": 1348, "height": 296, "file_name": "acs.orglett.5b02545-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [861.0, 13.0, 251.0, 144.0], "category_id": 1}, {"id": 1, "bbox": [240.0, 3.0, 252.0, 160.0], "category_id": 1}, {"id": 2, "bbox": [644.0, 48.0, 76.0, 35.0], "category_id": 2}, {"id": 3, "bbox": [542.0, 94.0, 281.0, 73.0], "category_id": 2}, {"id": 4, "bbox": [295.0, 165.0, 38.0, 29.0], "category_id": 3}, {"id": 5, "bbox": [920.0, 162.0, 45.0, 34.0], "category_id": 3}, {"id": 6, "bbox": [8.0, 219.0, 1327.0, 77.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [2, 3], "products": [0]}], "corefs": [[1, 4], [0, 5]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 632, 110], "ImageBB": [449, 116, 786, 190]}, "diagram_type": "single"}, {"id": 778, "width": 1348, "height": 1224, "file_name": "jo951899j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.0, 52.0, 275.0, 217.0], "category_id": 1}, {"id": 1, "bbox": [553.0, 275.0, 84.0, 35.0], "category_id": 2}, {"id": 2, "bbox": [162.0, 109.0, 27.0, 34.0], "category_id": 3}, {"id": 3, "bbox": [755.0, 559.9, 448.0, 232.1], "category_id": 3}, {"id": 4, "bbox": [1031.0, 703.0, 121.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [529.0, 504.0, 141.0, 180.0], "category_id": 2}, {"id": 6, "bbox": [523.0, 721.0, 148.0, 47.0], "category_id": 2}, {"id": 7, "bbox": [786.0, 866.0, 365.0, 48.0], "category_id": 2}, {"id": 8, "bbox": [153.0, 486.0, 349.0, 185.0], "category_id": 3}, {"id": 9, "bbox": [0.0, 977.0, 1348.0, 247.0], "category_id": 4}, {"id": 10, "bbox": [227.0, 872.0, 101.0, 38.0], "category_id": 3}, {"id": 11, "bbox": [147.0, 526.0, 29.0, 47.0], "category_id": 3}, {"id": 12, "bbox": [252.0, 393.0, 46.0, 34.0], "category_id": 3}, {"id": 13, "bbox": [1018.0, 229.0, 42.0, 36.0], "category_id": 3}, {"id": 14, "bbox": [158.0, 333.0, 339.0, 37.0], "category_id": 1}, {"id": 15, "bbox": [136.0, 763.0, 345.0, 49.0], "category_id": 1}, {"id": 16, "bbox": [747.0, 124.0, 447.0, 230.0], "category_id": 1}, {"id": 17, "bbox": [532.0, 5.0, 150.0, 227.0], "category_id": 2}], "reactions": [{"reactants": [0, 14], "conditions": [17, 1], "products": [16]}, {"reactants": [8, 15], "conditions": [5, 6], "products": [3]}], "corefs": [[0, 2], [14, 12], [16, 13], [8, 11], [15, 10], [3, 4]], "caption": "Table 2. Synthesis of the Azidogalactosyl Compounds", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [72, 55, 390, 67], "ImageBB": [63, 77, 400, 383]}, "diagram_type": "multiple"}, {"id": 946, "width": 1356, "height": 572, "file_name": "acs.orglett.5b02279-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [487.73, 477.8, 210.28, 48.19], "category_id": 3}, {"id": 1, "bbox": [487.73, 312.88, 262.51, 149.99], "category_id": 1}, {"id": 2, "bbox": [487.73, 194.11, 232.67, 52.94], "category_id": 3}, {"id": 3, "bbox": [480.94, 6.79, 276.09, 175.1], "category_id": 1}, {"id": 4, "bbox": [340.53, 351.57, 103.1, 42.08], "category_id": 2}, {"id": 5, "bbox": [330.35, 114.7, 108.54, 46.83], "category_id": 2}, {"id": 6, "bbox": [354.77, 40.04, 73.26, 52.26], "category_id": 2}, {"id": 7, "bbox": [741.42, 223.97, 130.92, 54.98], "category_id": 2}, {"id": 8, "bbox": [912.37, 409.93, 345.95, 51.59], "category_id": 3}, {"id": 9, "bbox": [43.41, 295.23, 288.98, 158.82], "category_id": 1}, {"id": 10, "bbox": [41.38, 0.0, 271.33, 183.25], "category_id": 1}, {"id": 11, "bbox": [56.98, 473.05, 241.49, 51.58], "category_id": 2}, {"id": 12, "bbox": [912.37, 132.35, 401.57, 270.8], "category_id": 1}], "caption": "Scheme 1. Proposed [4 + 3] Cycloadditions of in situ Generated Allylic Ylides and Aza-o-quinone Methides ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 599, 754, 629], "ImageBB": [448, 636, 787, 779]}, "reactions": [{"reactants": [10], "conditions": [6, 5], "products": [3]}, {"reactants": [9], "conditions": [4], "products": [1]}, {"reactants": [3, 1], "conditions": [7], "products": [12]}], "diagram_type": "tree"}, {"id": 335, "width": 1348, "height": 2060, "file_name": "ol300353w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [497.0, 126.0, 275.5, 109.1], "category_id": 2}, {"id": 1, "bbox": [140.0, 1811.0, 65.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [436.0, 1603.0, 68.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [893.0, 1804.0, 68.0, 61.0], "category_id": 3}, {"id": 4, "bbox": [410.9, 1447.0, 253.1, 219.0], "category_id": 1}, {"id": 5, "bbox": [775.0, 1544.0, 542.0, 253.0], "category_id": 1}, {"id": 6, "bbox": [432.7, 1680.0, 278.6, 232.9], "category_id": 2}, {"id": 7, "bbox": [802.0, 7.0, 412.0, 221.0], "category_id": 1}, {"id": 8, "bbox": [137.0, 5.0, 306.0, 231.0], "category_id": 1}, {"id": 9, "bbox": [260.0, 246.0, 73.0, 50.0], "category_id": 3}, {"id": 10, "bbox": [4.0, 414.0, 1344.0, 668.0], "category_id": 4}, {"id": 11, "bbox": [544.0, 47.0, 178.0, 56.0], "category_id": 2}, {"id": 12, "bbox": [36.0, 1530.0, 314.0, 260.0], "category_id": 1}, {"id": 13, "bbox": [974.0, 1811.0, 213.0, 56.0], "category_id": 2}, {"id": 14, "bbox": [7.0, 1291.0, 1341.0, 128.0], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [11, 0], "products": [7]}, {"reactants": [12], "conditions": [4, 6], "products": [5]}], "corefs": [[8, 9], [12, 1], [4, 2], [5, 3]], "caption": "Table 1. Conversion of Aldehydes to Syn-Aldol Products", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 522, 741, 535], "ImageBB": [436, 547, 773, 1062]}, "diagram_type": "multiple"}, {"id": 1373, "width": 1284, "height": 1172, "file_name": "op990044w-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [88.3, 73.21, 116.1, 190.72], "category_id": 1}, {"id": 1, "bbox": [235.09, 483.56, 330.15, 120.73], "category_id": 1}, {"id": 2, "bbox": [668.01, 1001.8, 82.22, 40.45], "category_id": 2}, {"id": 3, "bbox": [621.77, 90.55, 134.88, 37.24], "category_id": 2}, {"id": 4, "bbox": [621.77, 547.13, 89.28, 40.46], "category_id": 2}, {"id": 5, "bbox": [44.96, 550.99, 84.15, 41.1], "category_id": 2}, {"id": 6, "bbox": [928.15, 663.37, 48.82, 50.09], "category_id": 3}, {"id": 7, "bbox": [654.53, 940.15, 111.12, 42.38], "category_id": 2}, {"id": 8, "bbox": [398.88, 1123.17, 44.32, 46.23], "category_id": 3}, {"id": 9, "bbox": [806.76, 0.0, 328.86, 211.92], "category_id": 1}, {"id": 10, "bbox": [928.15, 289.62, 49.46, 51.38], "category_id": 3}, {"id": 11, "bbox": [283.26, 58.44, 328.87, 224.76], "category_id": 1}, {"id": 12, "bbox": [969.9, 1113.53, 186.92, 50.74], "category_id": 3}, {"id": 13, "bbox": [806.76, 399.43, 332.72, 209.35], "category_id": 1}, {"id": 14, "bbox": [8.35, 927.3, 274.27, 71.28], "category_id": 2}, {"id": 15, "bbox": [657.09, 148.98, 80.29, 41.1], "category_id": 2}, {"id": 16, "bbox": [848.51, 744.92, 435.49, 309.53], "category_id": 1}, {"id": 17, "bbox": [126.54, 296.04, 40.46, 48.17], "category_id": 3}, {"id": 18, "bbox": [0.0, 489.34, 181.13, 44.95], "category_id": 2}, {"id": 19, "bbox": [603.78, 485.49, 156.09, 45.59], "category_id": 2}, {"id": 20, "bbox": [421.36, 294.76, 66.8, 51.37], "category_id": 3}, {"id": 21, "bbox": [350.71, 665.29, 43.68, 48.17], "category_id": 3}, {"id": 22, "bbox": [73.22, 1009.5, 84.15, 41.1], "category_id": 2}, {"id": 23, "bbox": [276.2, 828.41, 333.36, 238.25], "category_id": 1}], "caption": "Scheme 1. Original route to FK453 (1)", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 580, 663, 594], "ImageBB": [448, 603, 769, 896]}, "reactions": [{"reactants": [0, 11], "conditions": [3, 15], "products": [9]}, {"reactants": [9], "conditions": [18, 5], "products": [1]}, {"reactants": [1], "conditions": [19, 4], "products": [13]}, {"reactants": [13], "conditions": [14, 22], "products": [23]}, {"reactants": [23], "conditions": [7, 2], "products": [16]}], "diagram_type": "multiple"}, {"id": 1093, "width": 1292, "height": 1488, "file_name": "jo961049j-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1105.3, 902.92, 115.17, 56.58], "category_id": 2}, {"id": 1, "bbox": [1083.57, 1437.97, 64.31, 50.03], "category_id": 3}, {"id": 2, "bbox": [376.04, 0.0, 293.39, 320.82], "category_id": 1}, {"id": 3, "bbox": [714.85, 1239.38, 205.53, 94.53], "category_id": 2}, {"id": 4, "bbox": [1010.48, 556.79, 274.02, 264.25], "category_id": 1}, {"id": 5, "bbox": [101.27, 1244.59, 188.4, 89.32], "category_id": 2}, {"id": 6, "bbox": [946.44, 2.98, 320.19, 262.76], "category_id": 1}, {"id": 7, "bbox": [930.06, 1004.16, 199.56, 93.04], "category_id": 2}, {"id": 8, "bbox": [84.89, 81.14, 210.73, 89.32], "category_id": 2}, {"id": 9, "bbox": [291.9, 755.54, 256.16, 52.85], "category_id": 2}, {"id": 10, "bbox": [130.31, 852.31, 47.66, 49.12], "category_id": 3}, {"id": 11, "bbox": [84.89, 1347.31, 218.92, 51.37], "category_id": 2}, {"id": 12, "bbox": [711.88, 850.07, 69.25, 52.85], "category_id": 3}, {"id": 13, "bbox": [496.68, 276.91, 69.25, 50.61], "category_id": 3}, {"id": 14, "bbox": [488.48, 1437.38, 61.81, 50.62], "category_id": 3}, {"id": 15, "bbox": [927.82, 384.84, 209.25, 97.51], "category_id": 2}, {"id": 16, "bbox": [968.78, 1149.31, 273.28, 284.35], "category_id": 1}, {"id": 17, "bbox": [327.64, 687.06, 176.48, 59.55], "category_id": 2}, {"id": 18, "bbox": [691.03, 907.39, 128.82, 58.06], "category_id": 2}, {"id": 19, "bbox": [711.88, 78.9, 196.58, 95.28], "category_id": 2}, {"id": 20, "bbox": [84.89, 188.33, 216.69, 54.34], "category_id": 2}, {"id": 21, "bbox": [1061.86, 274.67, 69.99, 52.11], "category_id": 3}, {"id": 22, "bbox": [1112.49, 847.1, 77.45, 54.33], "category_id": 3}, {"id": 23, "bbox": [610.61, 565.72, 344.02, 255.32], "category_id": 1}, {"id": 24, "bbox": [0.0, 525.53, 301.58, 369.95], "category_id": 1}, {"id": 25, "bbox": [374.55, 1173.87, 300.84, 263.63], "category_id": 1}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 49, 635, 63], "ImageBB": [445, 70, 768, 442]}, "reactions": [{"reactants": [24], "conditions": [8, 20], "products": [2]}, {"reactants": [2], "conditions": [19], "products": [6]}, {"reactants": [24], "conditions": [17, 9], "products": [23]}, {"reactants": [6], "conditions": [15], "products": [23]}, {"reactants": [24], "conditions": [5, 11], "products": [25]}, {"reactants": [25], "conditions": [3], "products": [16]}, {"reactants": [16], "conditions": [7], "products": [4]}], "diagram_type": "graph"}, {"id": 351, "width": 1204, "height": 1232, "file_name": "ol2017438-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [604.0, 280.0, 175.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [628.0, 6.0, 93.0, 38.0], "category_id": 2}, {"id": 2, "bbox": [837.0, 6.0, 60.0, 38.0], "category_id": 2}, {"id": 3, "bbox": [1024.0, 6.0, 180.0, 41.0], "category_id": 2}, {"id": 4, "bbox": [183.0, 11.0, 353.0, 131.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 66.0, 128.0, 176.0], "category_id": 1}, {"id": 6, "bbox": [146.17, 3.32, 146.99, 46.24], "category_id": 2}, {"id": 7, "bbox": [586.0, 35.0, 362.0, 250.0], "category_id": 1}, {"id": 8, "bbox": [4.0, 435.0, 1200.0, 797.0], "category_id": 4}, {"id": 9, "bbox": [1058.0, 277.0, 112.0, 43.0], "category_id": 3}, {"id": 10, "bbox": [151.0, 164.6, 383.1, 52.4], "category_id": 2}, {"id": 11, "bbox": [117.0, 235.0, 454.0, 83.0], "category_id": 2}, {"id": 12, "bbox": [1016.8, 47.0, 187.2, 219.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [6, 4, 10, 11], "products": [7]}, {"reactants": [7], "conditions": [], "products": [12]}], "corefs": [[7, 0], [12, 9]], "caption": "Table 2. Scope of the Asymmetric Aza-Annulationa", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 346, 101], "ImageBB": [89, 112, 390, 420]}, "diagram_type": "single"}, {"id": 1300, "width": 2820, "height": 512, "file_name": "op200351g-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1275.28, 114.28, 221.48, 63.48], "category_id": 2}, {"id": 1, "bbox": [1309.13, 292.04, 135.43, 53.61], "category_id": 2}, {"id": 2, "bbox": [2003.2, 420.42, 53.61, 47.97], "category_id": 3}, {"id": 3, "bbox": [1821.22, 208.8, 371.02, 173.53], "category_id": 1}, {"id": 4, "bbox": [1845.2, 122.74, 331.52, 62.08], "category_id": 2}, {"id": 5, "bbox": [550.18, 417.6, 43.73, 50.79], "category_id": 3}, {"id": 6, "bbox": [740.62, 327.31, 141.07, 62.08], "category_id": 2}, {"id": 7, "bbox": [2278.29, 166.48, 53.61, 50.79], "category_id": 3}, {"id": 8, "bbox": [1532.03, 14.11, 273.67, 363.99], "category_id": 1}, {"id": 9, "bbox": [1654.76, 416.19, 66.3, 55.02], "category_id": 3}, {"id": 10, "bbox": [479.64, 29.63, 253.93, 331.54], "category_id": 1}, {"id": 11, "bbox": [691.25, 115.69, 227.12, 62.07], "category_id": 2}, {"id": 12, "bbox": [1063.67, 417.6, 60.66, 50.79], "category_id": 3}, {"id": 13, "bbox": [734.98, 215.86, 138.25, 49.37], "category_id": 2}, {"id": 14, "bbox": [969.15, 25.39, 259.57, 335.78], "category_id": 1}, {"id": 15, "bbox": [1309.13, 213.03, 152.36, 62.08], "category_id": 2}], "caption": "Scheme 4. Synthesis of ketoamide 11 via azide/Staudinger sequence", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 735, 466, 750], "ImageBB": [82, 756, 787, 884]}, "reactions": [{"reactants": [10], "conditions": [11, 13, 6], "products": [14]}, {"reactants": [14], "conditions": [0, 15, 1], "products": [8]}, {"reactants": [8, 3], "conditions": [4], "products": [7]}], "diagram_type": "single"}, {"id": 1247, "width": 1348, "height": 896, "file_name": "op034064g-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [198.93, 550.28, 63.39, 53.95], "category_id": 3}, {"id": 1, "bbox": [427.53, 132.85, 88.34, 45.86], "category_id": 2}, {"id": 2, "bbox": [1086.36, 847.0, 64.73, 49.0], "category_id": 3}, {"id": 3, "bbox": [1145.7, 573.88, 202.3, 61.37], "category_id": 2}, {"id": 4, "bbox": [526.66, 376.97, 251.53, 52.6], "category_id": 2}, {"id": 5, "bbox": [700.64, 178.71, 69.45, 54.62], "category_id": 3}, {"id": 6, "bbox": [1129.51, 259.63, 195.56, 66.76], "category_id": 2}, {"id": 7, "bbox": [529.35, 457.22, 231.98, 55.29], "category_id": 2}, {"id": 8, "bbox": [1082.31, 175.33, 49.23, 47.21], "category_id": 3}, {"id": 9, "bbox": [1085.68, 498.35, 53.28, 50.58], "category_id": 3}, {"id": 10, "bbox": [218.49, 170.61, 54.62, 51.93], "category_id": 3}, {"id": 11, "bbox": [84.97, 16.18, 308.84, 152.41], "category_id": 1}, {"id": 12, "bbox": [427.53, 60.02, 91.04, 44.51], "category_id": 2}, {"id": 13, "bbox": [573.19, 12.14, 320.98, 153.08], "category_id": 1}, {"id": 14, "bbox": [0.0, 400.57, 405.28, 168.59], "category_id": 1}, {"id": 15, "bbox": [885.94, 684.15, 456.06, 155.96], "category_id": 1}, {"id": 16, "bbox": [882.03, 369.55, 386.37, 157.95], "category_id": 1}, {"id": 17, "bbox": [948.79, 2.7, 300.08, 145.3], "category_id": 1}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 594, 501, 608], "ImageBB": [440, 612, 777, 836]}, "reactions": [{"reactants": [11], "conditions": [], "products": [14]}, {"reactants": [11], "conditions": [12], "products": [13, 17]}, {"reactants": [13, 17], "conditions": [1], "products": [11]}, {"reactants": [17], "conditions": [6], "products": [16]}, {"reactants": [14], "conditions": [4], "products": [16]}, {"reactants": [16], "conditions": [7], "products": [14]}, {"reactants": [16], "conditions": [3], "products": [15]}], "diagram_type": "graph"}, {"id": 146, "width": 1352, "height": 2780, "file_name": "op700249f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [318.0, 180.0, 465.0, 96.2], "category_id": 2}, {"id": 1, "bbox": [940.0, 241.0, 134.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [8.0, 2546.0, 1344.0, 234.0], "category_id": 2}, {"id": 3, "bbox": [1.0, 317.0, 1351.0, 2183.0], "category_id": 4}, {"id": 4, "bbox": [0.0, 26.0, 359.0, 210.0], "category_id": 1}, {"id": 5, "bbox": [807.0, 26.0, 445.0, 258.0], "category_id": 1}, {"id": 6, "bbox": [97.0, 238.0, 134.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [373.0, 32.0, 343.0, 104.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [7, 0], "products": [5]}], "corefs": [[4, 6], [5, 1]], "caption": "Table 2. Scope of CuAAC to prepare C-triazole-linked glycoamino acids ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 178, 361, 205], "ImageBB": [58, 207, 396, 902]}, "diagram_type": "single"}, {"id": 547, "width": 960, "height": 2376, "file_name": "acs.orglett.5b03589-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [753.04, 253.96, 48.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [508.06, 171.13, 36.87, 40.55], "category_id": 3}, {"id": 2, "bbox": [4.0, 433.0, 956.0, 1943.0], "category_id": 4}, {"id": 3, "bbox": [341.14, 136.85, 48.15, 46.66], "category_id": 2}, {"id": 4, "bbox": [82.0, 57.0, 234.0, 127.0], "category_id": 1}, {"id": 5, "bbox": [97.0, 194.0, 214.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [341.0, 0.0, 283.0, 111.0], "category_id": 2}, {"id": 7, "bbox": [647.0, 7.0, 239.0, 224.0], "category_id": 1}, {"id": 8, "bbox": [389.0, 139.0, 231.0, 121.0], "category_id": 1}, {"id": 9, "bbox": [348.6, 333.7, 252.4, 73.3], "category_id": 2}, {"id": 10, "bbox": [395.0, 255.0, 203.9, 73.8], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [6, 3, 8, 10, 9], "products": [7]}], "corefs": [[4, 5], [8, 1], [7, 0]], "caption": "Table 2. Scope of Tandem Coupling/Cyclization Reactions with Functionalized Benzoic Acids ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 233, 777, 263], "ImageBB": [497, 269, 737, 863]}, "diagram_type": "single"}, {"id": 430, "width": 2820, "height": 808, "file_name": "op300171m-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1193.5, 77.5, 484.8, 683.7], "category_id": 1}, {"id": 1, "bbox": [937.0, 351.0, 38.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [1591.0, 341.0, 274.0, 60.0], "category_id": 2}, {"id": 3, "bbox": [677.5, 166.0, 509.5, 170.0], "category_id": 1}, {"id": 4, "bbox": [325.8, 323.3, 408.8, 244.9], "category_id": 1}, {"id": 5, "bbox": [537.0, 627.0, 40.0, 65.0], "category_id": 3}, {"id": 6, "bbox": [1305.0, 627.0, 48.0, 72.0], "category_id": 3}, {"id": 7, "bbox": [1835.6, 2.1, 475.6, 653.9], "category_id": 1}, {"id": 8, "bbox": [775.0, 442.0, 400.0, 149.0], "category_id": 2}, {"id": 9, "bbox": [1688.0, 444.0, 96.0, 58.0], "category_id": 2}, {"id": 10, "bbox": [1926.0, 658.0, 575.0, 113.8], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [3, 8], "products": [0]}, {"reactants": [0], "conditions": [2, 9], "products": [7]}], "corefs": [[4, 5], [3, 1], [0, 6]], "caption": "Table 3. Reaction Condition Optimization of Ammonolysis in the Synthesis of Vilazodone", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 636, 592, 651], "ImageBB": [82, 427, 787, 629]}, "diagram_type": "single"}, {"id": 728, "width": 1488, "height": 1812, "file_name": "ol016693l-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [885.0, 1510.0, 315.0, 109.0], "category_id": 2}, {"id": 1, "bbox": [458.0, 1681.0, 206.0, 130.0], "category_id": 1}, {"id": 2, "bbox": [413.0, 1515.0, 269.0, 96.0], "category_id": 2}, {"id": 3, "bbox": [923.0, 1689.0, 253.0, 64.0], "category_id": 2}, {"id": 4, "bbox": [114.0, 80.0, 1374.0, 1035.0], "category_id": 2}, {"id": 5, "bbox": [610.0, 1291.0, 355.1, 192.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [0], "products": [3]}, {"reactants": [5], "conditions": [2], "products": [1]}], "corefs": [], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 990, 491, 1003], "ImageBB": [408, 525, 780, 978]}, "diagram_type": "tree"}, {"id": 759, "width": 1340, "height": 1760, "file_name": "jo982004g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [810.55, 559.45, 470.01, 199.24], "category_id": 1}, {"id": 1, "bbox": [225.58, 1318.11, 355.07, 53.65], "category_id": 2}, {"id": 2, "bbox": [601.09, 613.09, 212.01, 56.2], "category_id": 2}, {"id": 3, "bbox": [675.16, 682.06, 58.76, 48.53], "category_id": 2}, {"id": 4, "bbox": [524.0, 818.7, 419.0, 287.3], "category_id": 1}, {"id": 5, "bbox": [369.3, 774.0, 53.2, 46.4], "category_id": 3}, {"id": 6, "bbox": [713.28, 1100.64, 43.0, 58.0], "category_id": 3}, {"id": 7, "bbox": [168.1, 1508.0, 523.3, 209.6], "category_id": 1}, {"id": 8, "bbox": [475.0, 244.6, 358.7, 130.4], "category_id": 1}, {"id": 9, "bbox": [741.9, 1500.4, 507.6, 212.4], "category_id": 1}, {"id": 10, "bbox": [588.0, 1355.0, 158.0, 53.3], "category_id": 2}, {"id": 11, "bbox": [234.7, 610.2, 362.5, 112.7], "category_id": 1}, {"id": 12, "bbox": [962.5, 1368.29, 44.82, 51.9], "category_id": 3}, {"id": 13, "bbox": [358.53, 1712.74, 49.55, 47.26], "category_id": 3}, {"id": 14, "bbox": [924.75, 1710.38, 49.55, 47.19], "category_id": 3}, {"id": 15, "bbox": [123.0, 1317.0, 44.7, 55.0], "category_id": 3}, {"id": 16, "bbox": [588.0, 1280.0, 132.0, 60.0], "category_id": 2}, {"id": 17, "bbox": [885.0, 1427.0, 390.0, 64.3], "category_id": 2}, {"id": 18, "bbox": [1003.0, 780.0, 44.0, 49.0], "category_id": 3}, {"id": 19, "bbox": [565.0, 393.0, 308.0, 147.0], "category_id": 3}, {"id": 20, "bbox": [666.0, 1710.0, 101.0, 50.0], "category_id": 3}, {"id": 21, "bbox": [934.0, 858.0, 364.0, 95.0], "category_id": 2}, {"id": 22, "bbox": [152.0, 667.0, 40.0, 46.0], "category_id": 3}, {"id": 23, "bbox": [784.0, 1272.0, 541.1, 104.8], "category_id": 1}], "reactions": [{"reactants": [22, 11], "conditions": [2, 3], "products": [0]}, {"reactants": [0], "conditions": [21], "products": [4]}, {"reactants": [15, 1], "conditions": [16, 10], "products": [23]}, {"reactants": [23], "conditions": [17], "products": [7, 9]}], "corefs": [[8, 19], [11, 5], [0, 18], [4, 6], [23, 12], [7, 13], [9, 14]], "caption": "Table 1. Diastereomeric Ratio (dr) of Adducts Shown in                       Scheme 2 ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [441, 486, 772, 511], "ImageBB": [426, 35, 761, 475]}, "diagram_type": "tree"}, {"id": 334, "width": 1340, "height": 732, "file_name": "ol300387f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [938.0, 232.0, 154.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [694.0, 230.0, 87.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [251.0, 228.0, 89.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [637.3, 6.9, 181.4, 194.4], "category_id": 1}, {"id": 4, "bbox": [441.7, 141.9, 118.4, 42.3], "category_id": 2}, {"id": 5, "bbox": [907.2, 4.9, 236.2, 212.1], "category_id": 1}, {"id": 6, "bbox": [414.0, 73.23, 174.0, 39.0], "category_id": 2}, {"id": 7, "bbox": [2.0, 307.0, 1338.0, 422.0], "category_id": 4}, {"id": 8, "bbox": [195.1, 3.3, 188.5, 235.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6, 4], "products": [3]}, {"reactants": [8], "conditions": [6, 4], "products": [5]}], "corefs": [[8, 2], [3, 1], [5, 0]], "caption": "Table 1. Addition to Geminal Dimethylated Cyclohex-2-enones", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 771, 100], "ImageBB": [437, 112, 772, 295]}, "diagram_type": "single"}, {"id": 748, "width": 1352, "height": 656, "file_name": "jo990938e-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1346.0, 649.0, 6.0, 5.0], "category_id": 4}, {"id": 1, "bbox": [0.0, 266.0, 1351.0, 390.0], "category_id": 4}, {"id": 2, "bbox": [406.0, 130.0, 211.0, 100.0], "category_id": 2}, {"id": 3, "bbox": [127.0, 13.0, 286.0, 222.0], "category_id": 1}, {"id": 4, "bbox": [1035.92, 183.22, 115.22, 48.94], "category_id": 3}, {"id": 5, "bbox": [735.14, 182.2, 120.31, 40.79], "category_id": 3}, {"id": 6, "bbox": [547.53, 46.6, 38.74, 43.84], "category_id": 3}, {"id": 7, "bbox": [471.7, 1.0, 130.3, 113.1], "category_id": 1}, {"id": 8, "bbox": [917.8, 16.0, 305.1, 207.7], "category_id": 1}, {"id": 9, "bbox": [633.0, 13.0, 297.0, 213.8], "category_id": 1}, {"id": 10, "bbox": [446.59, 54.24, 43.84, 39.77], "category_id": 2}, {"id": 11, "bbox": [266.0, 185.0, 47.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [10, 7, 2], "products": [9, 8]}], "corefs": [[3, 11], [7, 6], [9, 5], [8, 4]], "caption": "Table 8. Additions of Transient Chiral Allenylindium Reagents from Mesylate 11 to Representative Achiral                      Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [449, 356, 764, 393], "ImageBB": [439, 403, 777, 567]}, "diagram_type": "single"}, {"id": 1301, "width": 1352, "height": 716, "file_name": "op3000042-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [108.21, 42.61, 168.69, 62.89], "category_id": 1}, {"id": 1, "bbox": [1062.53, 273.89, 147.44, 60.87], "category_id": 2}, {"id": 2, "bbox": [971.22, 158.93, 38.55, 45.98], "category_id": 3}, {"id": 3, "bbox": [686.48, 105.5, 138.65, 55.45], "category_id": 2}, {"id": 4, "bbox": [980.69, 621.5, 38.55, 46.66], "category_id": 3}, {"id": 5, "bbox": [894.8, 0.0, 344.93, 165.69], "category_id": 1}, {"id": 6, "bbox": [837.31, 370.6, 390.92, 231.29], "category_id": 1}, {"id": 7, "bbox": [738.56, 488.95, 97.39, 52.75], "category_id": 2}, {"id": 8, "bbox": [351.7, 451.08, 308.41, 172.45], "category_id": 1}, {"id": 9, "bbox": [178.55, 158.25, 41.94, 47.34], "category_id": 3}, {"id": 10, "bbox": [363.19, 0.0, 242.81, 163.66], "category_id": 1}, {"id": 11, "bbox": [685.81, 10.14, 145.41, 58.16], "category_id": 2}, {"id": 12, "bbox": [487.64, 158.93, 43.29, 45.98], "category_id": 3}, {"id": 13, "bbox": [403.1, 623.53, 39.23, 45.99], "category_id": 3}], "caption": "Scheme 1. Ritter\u2019s originally proposed mechanism", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 365, 110], "ImageBB": [82, 116, 420, 295]}, "reactions": [{"reactants": [0, 10], "conditions": [11], "products": [5]}, {"reactants": [5], "conditions": [3], "products": [0, 10]}, {"reactants": [5], "conditions": [1], "products": [6]}, {"reactants": [6], "conditions": [], "products": [5]}, {"reactants": [6], "conditions": [7], "products": [8]}], "diagram_type": "tree"}, {"id": 928, "width": 1416, "height": 632, "file_name": "acs.oprd.5b00209-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1217.66, 90.66, 55.25, 47.46], "category_id": 3}, {"id": 1, "bbox": [771.4, 0.0, 66.58, 45.33], "category_id": 3}, {"id": 2, "bbox": [1093.7, 163.62, 162.92, 51.0], "category_id": 2}, {"id": 3, "bbox": [1103.62, 534.77, 59.5, 50.29], "category_id": 3}, {"id": 4, "bbox": [769.98, 137.41, 123.25, 94.2], "category_id": 2}, {"id": 5, "bbox": [1070.32, 87.83, 63.76, 54.54], "category_id": 3}, {"id": 6, "bbox": [609.18, 247.2, 51.01, 49.58], "category_id": 3}, {"id": 7, "bbox": [955.57, 366.19, 398.09, 148.04], "category_id": 1}, {"id": 8, "bbox": [794.77, 422.86, 46.75, 53.12], "category_id": 3}, {"id": 9, "bbox": [771.4, 49.58, 147.34, 43.21], "category_id": 2}, {"id": 10, "bbox": [1390.5, 32.0, 25.5, 43.08], "category_id": 2}, {"id": 11, "bbox": [490.89, 393.11, 225.96, 55.95], "category_id": 2}, {"id": 12, "bbox": [489.47, 488.02, 250.76, 97.74], "category_id": 2}, {"id": 13, "bbox": [424.3, 60.91, 294.68, 161.5], "category_id": 1}], "caption": "Scheme 10. Current Sulfamoylation Process", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 330, 110], "ImageBB": [82, 116, 436, 274]}, "reactions": [{"reactants": [13], "conditions": [1, 9, 4], "products": [5, 0]}, {"reactants": [], "conditions": [11, 12], "products": [8, 7]}], "diagram_type": "multiple"}, {"id": 1344, "width": 1952, "height": 1264, "file_name": "op700160a-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [258.77, 94.74, 96.67, 60.55], "category_id": 2}, {"id": 1, "bbox": [111.32, 250.03, 55.66, 58.6], "category_id": 3}, {"id": 2, "bbox": [972.58, 319.38, 52.73, 60.55], "category_id": 3}, {"id": 3, "bbox": [393.52, 52.74, 225.57, 170.92], "category_id": 1}, {"id": 4, "bbox": [1215.73, 88.88, 99.6, 65.44], "category_id": 2}, {"id": 5, "bbox": [600.54, 239.29, 140.61, 138.69], "category_id": 1}, {"id": 6, "bbox": [0.0, 79.11, 232.4, 150.41], "category_id": 1}, {"id": 7, "bbox": [838.8, 30.28, 319.32, 292.03], "category_id": 1}, {"id": 8, "bbox": [1336.81, 49.81, 230.45, 246.12], "category_id": 1}, {"id": 9, "bbox": [1700.07, 319.38, 172.83, 60.55], "category_id": 3}, {"id": 10, "bbox": [1409.07, 319.38, 124.02, 62.5], "category_id": 3}, {"id": 11, "bbox": [738.23, 322.31, 46.87, 57.62], "category_id": 3}, {"id": 12, "bbox": [1647.34, 46.88, 234.35, 249.05], "category_id": 1}], "caption": "Scheme 4. Theoretical lanthanide-catalyst-promoted formation of cis-1 and trans-1 with 3D representation", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 644, 60], "ImageBB": [166, 65, 654, 381]}, "reactions": [{"reactants": [6], "conditions": [0], "products": [3]}, {"reactants": [3, 5], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [4], "products": [8, 12]}], "diagram_type": "single"}, {"id": 1338, "width": 1352, "height": 472, "file_name": "op5003165-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [686.48, 79.87, 114.98, 33.84], "category_id": 2}, {"id": 1, "bbox": [459.91, 2.71, 206.28, 206.44], "category_id": 1}, {"id": 2, "bbox": [75.75, 223.37, 46.67, 43.32], "category_id": 3}, {"id": 3, "bbox": [18.26, 18.28, 209.67, 182.07], "category_id": 1}, {"id": 4, "bbox": [264.45, 119.81, 133.24, 74.45], "category_id": 2}, {"id": 5, "bbox": [271.89, 20.98, 119.71, 69.72], "category_id": 2}, {"id": 6, "bbox": [660.78, 256.53, 121.07, 71.08], "category_id": 2}, {"id": 7, "bbox": [654.7, 354.68, 135.26, 76.49], "category_id": 2}, {"id": 8, "bbox": [911.03, 227.43, 41.25, 37.23], "category_id": 3}, {"id": 9, "bbox": [863.01, 6.09, 206.28, 207.8], "category_id": 1}, {"id": 10, "bbox": [1166.68, 226.08, 44.64, 38.58], "category_id": 3}, {"id": 11, "bbox": [1123.4, 6.09, 209.66, 207.8], "category_id": 1}, {"id": 12, "bbox": [493.73, 228.11, 41.25, 35.19], "category_id": 3}], "caption": "Scheme 4. Synthesis of intermediate lactam (11)", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 433, 357, 448], "ImageBB": [82, 455, 420, 573]}, "reactions": [{"reactants": [3], "conditions": [5, 4], "products": [1]}, {"reactants": [1], "conditions": [0], "products": [9, 11]}, {"reactants": [9], "conditions": [6, 7], "products": [1]}], "diagram_type": "graph"}, {"id": 207, "width": 1352, "height": 560, "file_name": "op0340964-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [760.0, 370.0, 82.0, 58.0], "category_id": 2}, {"id": 1, "bbox": [757.0, 474.0, 179.0, 86.0], "category_id": 2}, {"id": 2, "bbox": [333.0, 172.0, 182.0, 91.0], "category_id": 2}, {"id": 3, "bbox": [334.0, 74.0, 77.0, 57.0], "category_id": 2}, {"id": 4, "bbox": [1021.0, 302.0, 325.0, 224.0], "category_id": 1}, {"id": 5, "bbox": [355.0, 302.0, 340.0, 226.0], "category_id": 1}, {"id": 6, "bbox": [6.0, 4.0, 270.0, 224.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 2], "products": [5]}, {"reactants": [5], "conditions": [0, 1], "products": [4]}], "corefs": [], "caption": "Figure 3. Acid-catalyzed stereoretentive hydrolysis of (R)-2- chloromandelonitrile into (R)-2-chloromandelic acid. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 751, 409, 779], "ImageBB": [73, 607, 411, 747]}, "diagram_type": "multiple"}, {"id": 1361, "width": 1356, "height": 620, "file_name": "op900197r-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [753.63, 261.37, 52.24, 44.8], "category_id": 2}, {"id": 1, "bbox": [553.52, 577.73, 48.85, 37.33], "category_id": 3}, {"id": 2, "bbox": [1322.76, 295.99, 33.24, 41.41], "category_id": 3}, {"id": 3, "bbox": [976.13, 500.33, 52.91, 40.74], "category_id": 3}, {"id": 4, "bbox": [326.28, 60.42, 90.22, 46.84], "category_id": 2}, {"id": 5, "bbox": [345.27, 401.9, 52.24, 47.52], "category_id": 2}, {"id": 6, "bbox": [106.5, 577.73, 45.45, 37.33], "category_id": 3}, {"id": 7, "bbox": [4.75, 350.98, 287.61, 197.55], "category_id": 1}, {"id": 8, "bbox": [71.9, 2.04, 188.58, 232.85], "category_id": 1}, {"id": 9, "bbox": [105.14, 242.36, 39.35, 38.7], "category_id": 3}, {"id": 10, "bbox": [521.64, 12.9, 262.52, 209.09], "category_id": 1}, {"id": 11, "bbox": [452.45, 353.02, 326.96, 195.51], "category_id": 1}, {"id": 12, "bbox": [877.09, 147.32, 327.64, 330.61], "category_id": 1}, {"id": 13, "bbox": [1192.52, 262.73, 50.88, 43.44], "category_id": 2}, {"id": 14, "bbox": [555.56, 239.64, 56.3, 41.42], "category_id": 3}], "caption": "Scheme 9. Alternative Hofmann and amine coupling sequencea ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 719, 73], "ImageBB": [424, 83, 763, 238]}, "reactions": [{"reactants": [8], "conditions": [4], "products": [10]}, {"reactants": [7], "conditions": [5], "products": [11]}, {"reactants": [10, 11], "conditions": [0], "products": [12]}, {"reactants": [12], "conditions": [13], "products": [2]}], "diagram_type": "tree"}, {"id": 163, "width": 1356, "height": 1184, "file_name": "op7000172-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [15.0, 406.0, 567.0, 247.0], "category_id": 1}, {"id": 1, "bbox": [840.7, 976.9, 481.4, 93.5], "category_id": 2}, {"id": 2, "bbox": [675.0, 479.6, 443.0, 109.4], "category_id": 2}, {"id": 3, "bbox": [829.0, 752.0, 130.0, 48.0], "category_id": 2}, {"id": 4, "bbox": [364.0, 145.0, 132.0, 51.0], "category_id": 2}, {"id": 5, "bbox": [374.0, 211.0, 118.0, 82.0], "category_id": 2}, {"id": 6, "bbox": [970.0, 147.0, 113.0, 51.0], "category_id": 2}, {"id": 7, "bbox": [663.0, 281.0, 57.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [168.0, 295.0, 66.0, 53.0], "category_id": 3}, {"id": 9, "bbox": [211.0, 703.0, 72.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [679.0, 1082.0, 51.0, 68.0], "category_id": 3}, {"id": 11, "bbox": [0.0, 46.0, 369.0, 243.0], "category_id": 1}, {"id": 12, "bbox": [671.05, 419.29, 250.89, 56.71], "category_id": 1}, {"id": 13, "bbox": [1032.59, 352.35, 72.0, 52.0], "category_id": 3}, {"id": 14, "bbox": [670.9, 606.0, 457.1, 119.0], "category_id": 1}, {"id": 15, "bbox": [908.0, 224.2, 329.0, 146.8], "category_id": 1}, {"id": 16, "bbox": [505.3, 59.8, 342.7, 217.8], "category_id": 1}, {"id": 17, "bbox": [855.94, 694.24, 51.0, 53.0], "category_id": 3}, {"id": 18, "bbox": [262.6, 811.7, 566.4, 366.3], "category_id": 1}, {"id": 19, "bbox": [896.9, 7.0, 332.1, 136.0], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [4, 5], "products": [16]}, {"reactants": [16], "conditions": [19, 6, 15], "products": [0]}, {"reactants": [0], "conditions": [12, 2, 14, 3], "products": [18]}], "corefs": [[11, 8], [16, 7], [15, 13], [0, 9], [14, 17], [18, 10]], "caption": "Table 2. Palladium content of coupling products 17, 21, 31, and 34 before and after scavenging ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 393, 400, 421], "ImageBB": [73, 85, 412, 381]}, "diagram_type": "multiple"}, {"id": 593, "width": 2816, "height": 740, "file_name": "acs.oprd.6b00128-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1970.5, 178.6, 290.9, 183.2], "category_id": 3}, {"id": 1, "bbox": [1567.9, 0.0, 391.1, 368.9], "category_id": 1}, {"id": 2, "bbox": [1202.0, 189.0, 341.0, 182.0], "category_id": 2}, {"id": 3, "bbox": [591.0, 323.0, 373.0, 84.0], "category_id": 2}, {"id": 4, "bbox": [1269.0, 81.0, 185.0, 80.0], "category_id": 2}, {"id": 5, "bbox": [976.0, 48.0, 193.5, 262.5], "category_id": 1}, {"id": 6, "bbox": [555.2, 6.9, 382.6, 285.1], "category_id": 1}, {"id": 7, "bbox": [0.0, 415.0, 2816.0, 325.0], "category_id": 4}, {"id": 8, "bbox": [739.4, 234.8, 50.6, 50.4], "category_id": 3}], "reactions": [{"reactants": [6, 5], "conditions": [4, 2], "products": [1]}], "corefs": [[6, 8]], "caption": "Table 2. PdCl2(dppf) Facilitates Coupling Reactions on a Small Scalea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 807, 481, 829], "ImageBB": [82, 834, 786, 1019]}, "diagram_type": "single"}, {"id": 467, "width": 2520, "height": 1704, "file_name": "op100267p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [407.0, 113.0, 377.0, 242.0], "category_id": 1}, {"id": 1, "bbox": [2.0, 374.0, 2518.0, 1330.0], "category_id": 4}, {"id": 2, "bbox": [1075.0, 234.0, 284.0, 110.0], "category_id": 2}, {"id": 3, "bbox": [1061.0, 1.0, 448.0, 208.0], "category_id": 2}, {"id": 4, "bbox": [1639.0, 40.0, 477.0, 315.0], "category_id": 1}, {"id": 5, "bbox": [879.9, 124.3, 157.5, 180.4], "category_id": 1}], "reactions": [{"reactants": [0, 5], "conditions": [3, 2], "products": [4]}], "corefs": [], "caption": "Table 2. Electron-de\ufb01cient amide-substituted arylboronic acid substrate scopea", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 509, 108], "ImageBB": [107, 117, 737, 543]}, "diagram_type": "single"}, {"id": 93, "width": 1344, "height": 784, "file_name": "ja053368a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [667.69, 149.08, 163.11, 35.32], "category_id": 2}, {"id": 1, "bbox": [1023.23, 33.49, 264.72, 152.62], "category_id": 1}, {"id": 2, "bbox": [212.31, 54.5, 261.22, 107.09], "category_id": 1}, {"id": 3, "bbox": [3.89, 215.64, 1334.85, 558.96], "category_id": 4}, {"id": 4, "bbox": [54.7, 66.8, 105.31, 114.06], "category_id": 1}, {"id": 5, "bbox": [494.29, 72.02, 502.92, 40.53], "category_id": 2}], "reactions": [{"reactants": [4, 2], "conditions": [5, 0], "products": [1]}], "corefs": [], "caption": "Table 2. DA Reaction of 2,3-Dimethylbutadiene with R-Acyloxyacroleina ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 338, 86], "ImageBB": [74, 85, 410, 281]}, "diagram_type": "single"}, {"id": 142, "width": 1312, "height": 636, "file_name": "op700292s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [33.9, 82.9, 154.5, 546.2], "category_id": 1}, {"id": 1, "bbox": [1243.0, 332.9, 69.0, 80.2], "category_id": 2}, {"id": 2, "bbox": [773.8, 77.9, 382.3, 557.1], "category_id": 1}, {"id": 3, "bbox": [264.9, 226.9, 85.5, 284.1], "category_id": 1}, {"id": 4, "bbox": [445.9, 377.9, 251.2, 131.5], "category_id": 2}, {"id": 5, "bbox": [425.9, 172.0, 321.2, 175.1], "category_id": 2}], "reactions": [{"reactants": [0, 3], "conditions": [5, 4], "products": [2, 1]}], "corefs": [], "caption": "Table 2. Chemical yields of 3,6-diphenyl-4-n-butylpyridazine under various experimental conditions ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 216, 759, 243], "ImageBB": [425, 45, 753, 204]}, "diagram_type": "single"}, {"id": 394, "width": 1356, "height": 1016, "file_name": "op5001385-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [78.0, 191.0, 23.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [103.0, 785.0, 85.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [863.0, 766.0, 85.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [691.0, 960.0, 506.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [689.0, 847.0, 532.0, 88.0], "category_id": 2}, {"id": 5, "bbox": [629.0, 31.0, 126.0, 58.0], "category_id": 2}, {"id": 6, "bbox": [0.0, 27.0, 218.0, 151.8], "category_id": 1}, {"id": 7, "bbox": [78.1, 325.1, 430.4, 502.8], "category_id": 1}, {"id": 8, "bbox": [814.0, 208.9, 230.6, 48.1], "category_id": 3}, {"id": 9, "bbox": [1236.55, 80.0, 114.0, 56.0], "category_id": 2}, {"id": 10, "bbox": [621.55, 119.0, 138.0, 57.0], "category_id": 2}, {"id": 11, "bbox": [878.8, 4.55, 267.9, 210.15], "category_id": 1}, {"id": 12, "bbox": [304.5, 8.0, 241.6, 177.0], "category_id": 1}, {"id": 13, "bbox": [795.6, 325.9, 482.4, 430.1], "category_id": 1}, {"id": 14, "bbox": [395.64, 186.91, 126.0, 34.0], "category_id": 2}], "reactions": [{"reactants": [6, 12], "conditions": [5, 10], "products": [11, 9]}], "corefs": [[6, 0], [11, 8], [7, 1], [13, 2]], "caption": "Figure 2. Through-space NOE interactions in 11a\u2212b.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 564, 712, 578], "ImageBB": [448, 301, 787, 555]}, "diagram_type": "single"}, {"id": 1182, "width": 1356, "height": 1796, "file_name": "ol4005905-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [850.3, 841.85, 454.81, 244.38], "category_id": 1}, {"id": 1, "bbox": [517.73, 589.38, 313.69, 63.79], "category_id": 2}, {"id": 2, "bbox": [587.53, 8.62, 77.61, 43.13], "category_id": 2}, {"id": 3, "bbox": [600.46, 401.03, 64.68, 40.96], "category_id": 2}, {"id": 4, "bbox": [677.0, 371.96, 394.41, 110.51], "category_id": 1}, {"id": 5, "bbox": [592.33, 67.38, 271.45, 243.48], "category_id": 1}, {"id": 6, "bbox": [1026.47, 434.85, 324.48, 362.07], "category_id": 1}, {"id": 7, "bbox": [219.32, 986.5, 97.97, 53.9], "category_id": 2}, {"id": 8, "bbox": [474.58, 835.56, 306.51, 278.52], "category_id": 1}, {"id": 9, "bbox": [186.96, 774.46, 185.16, 185.98], "category_id": 2}, {"id": 10, "bbox": [581.55, 778.06, 155.49, 50.31], "category_id": 3}, {"id": 11, "bbox": [17.08, 111.41, 343.35, 141.95], "category_id": 1}, {"id": 12, "bbox": [135.72, 579.5, 65.62, 53.01], "category_id": 3}, {"id": 13, "bbox": [671.7, 0.0, 201.97, 57.5], "category_id": 1}, {"id": 14, "bbox": [0.0, 1263.8, 1348.25, 532.2], "category_id": 2}, {"id": 15, "bbox": [0.0, 374.8, 556.38, 378.1], "category_id": 1}, {"id": 16, "bbox": [1122.64, 672.04, 65.62, 53.91], "category_id": 3}, {"id": 17, "bbox": [383.8, 110.51, 146.51, 64.69], "category_id": 2}, {"id": 18, "bbox": [981.53, 53.01, 280.43, 257.85], "category_id": 1}, {"id": 19, "bbox": [520.42, 492.35, 303.81, 59.3], "category_id": 2}, {"id": 20, "bbox": [929.39, 777.16, 136.63, 51.21], "category_id": 3}], "caption": "Scheme 1. Initial Unexpected Observations", "pdf": {"Page": 1, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 549, 666, 562], "ImageBB": [436, 574, 775, 1023]}, "reactions": [{"reactants": [11], "conditions": [17], "products": [5]}, {"reactants": [5], "conditions": [], "products": [18]}, {"reactants": [15], "conditions": [9, 7], "products": [8, 0]}, {"reactants": [15], "conditions": [19, 1], "products": [8, 0]}], "diagram_type": "graph"}, {"id": 741, "width": 1340, "height": 924, "file_name": "ol010283f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [893.28, 22.19, 443.0, 274.0], "category_id": 1}, {"id": 1, "bbox": [1091.0, 275.81, 83.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [631.9, 94.0, 218.2, 50.5], "category_id": 2}, {"id": 3, "bbox": [610.53, 175.9, 262.58, 49.55], "category_id": 2}, {"id": 4, "bbox": [195.0, 409.0, 1037.0, 515.0], "category_id": 4}, {"id": 5, "bbox": [239.0, 279.0, 86.0, 58.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 0.0, 548.0, 274.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [2, 3], "products": [0]}], "corefs": [[6, 5], [0, 1]], "caption": "Table 2. Effect of Ruthenium Porphyrin Catalysts on Cyclization of (-)-Menthyl-\u03b3-benzyloxy-R-diazo-\u03b2-ketoesterd ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 702, 757, 730], "ImageBB": [440, 733, 775, 964]}, "diagram_type": "single"}, {"id": 1266, "width": 2136, "height": 320, "file_name": "op060099f-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1318.57, 249.66, 98.31, 66.15], "category_id": 3}, {"id": 1, "bbox": [1807.96, 3.2, 328.04, 243.26], "category_id": 1}, {"id": 2, "bbox": [1860.32, 257.13, 255.38, 62.87], "category_id": 3}, {"id": 3, "bbox": [0.0, 4.27, 329.11, 242.19], "category_id": 1}, {"id": 4, "bbox": [1197.83, 13.87, 329.11, 213.39], "category_id": 1}, {"id": 5, "bbox": [589.83, 4.27, 330.18, 242.19], "category_id": 1}, {"id": 6, "bbox": [1597.46, 81.09, 154.94, 52.28], "category_id": 2}], "caption": "Scheme 5. Oxidation of 2,3-substituted indoles as reported by Hino et al.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 464, 483, 478], "ImageBB": [158, 482, 692, 562]}, "reactions": [{"reactants": [3], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [5]}, {"reactants": [4], "conditions": [6], "products": [1]}], "diagram_type": "single"}, {"id": 1287, "width": 2808, "height": 696, "file_name": "op200086t-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1694.07, 39.38, 118.0, 52.04], "category_id": 2}, {"id": 1, "bbox": [2160.43, 464.12, 99.74, 66.1], "category_id": 2}, {"id": 2, "bbox": [1689.86, 431.77, 108.16, 50.63], "category_id": 2}, {"id": 3, "bbox": [2015.75, 569.6, 264.08, 57.66], "category_id": 2}, {"id": 4, "bbox": [1796.61, 232.06, 144.69, 53.44], "category_id": 2}, {"id": 5, "bbox": [817.54, 225.03, 168.56, 60.47], "category_id": 2}, {"id": 6, "bbox": [515.53, 4.22, 259.87, 187.05], "category_id": 1}, {"id": 7, "bbox": [1976.42, 8.44, 283.75, 185.64], "category_id": 1}, {"id": 8, "bbox": [2052.27, 194.08, 112.38, 60.48], "category_id": 3}, {"id": 9, "bbox": [950.98, 40.79, 75.86, 50.63], "category_id": 2}, {"id": 10, "bbox": [547.7, 382.54, 210.84, 52.04], "category_id": 2}, {"id": 11, "bbox": [581.55, 195.49, 112.37, 59.07], "category_id": 3}, {"id": 12, "bbox": [1293.6, 382.54, 153.24, 56.26], "category_id": 2}, {"id": 13, "bbox": [2011.84, 380.82, 279.52, 48.71], "category_id": 2}, {"id": 14, "bbox": [849.84, 427.55, 325.9, 137.83], "category_id": 2}, {"id": 15, "bbox": [1017.0, 227.84, 188.23, 57.66], "category_id": 2}, {"id": 16, "bbox": [1224.9, 0.0, 293.58, 188.46], "category_id": 1}, {"id": 17, "bbox": [1310.59, 194.08, 110.97, 60.48], "category_id": 3}, {"id": 18, "bbox": [1569.05, 232.06, 160.14, 53.44], "category_id": 2}], "caption": "Scheme 2. Biocatalysed reduction of (E)- and (Z)-1 mediated by BY and OYE1 3", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 276, 529, 291], "ImageBB": [71, 301, 773, 475]}, "reactions": [{"reactants": [16, 15], "conditions": [9], "products": [6, 5]}, {"reactants": [16, 18], "conditions": [0], "products": [4, 7]}, {"reactants": [12, 5], "conditions": [14], "products": [10, 15]}, {"reactants": [12, 4], "conditions": [2], "products": [18, 13]}, {"reactants": [13], "conditions": [1], "products": [3]}], "diagram_type": "graph"}, {"id": 601, "width": 2816, "height": 708, "file_name": "acs.oprd.6b00011-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1545.6, 169.1, 522.4, 393.9], "category_id": 1}, {"id": 1, "bbox": [1184.0, 404.0, 195.6, 68.3], "category_id": 2}, {"id": 2, "bbox": [1126.75, 314.0, 329.0, 70.0], "category_id": 2}, {"id": 3, "bbox": [1090.1, 0.0, 394.5, 258.5], "category_id": 1}, {"id": 4, "bbox": [1.0, 619.0, 2815.0, 89.0], "category_id": 4}, {"id": 5, "bbox": [1622.0, 569.0, 295.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [1270.0, 278.0, 34.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [935.0, 551.0, 63.0, 67.0], "category_id": 3}, {"id": 8, "bbox": [744.0, 188.2, 355.4, 346.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [3, 2, 1], "products": [0]}], "corefs": [[8, 7], [3, 6], [0, 5]], "caption": "Table 4. Pd Catalyst Screen for the Stage 2 Suzuki Cross-Coupling Reaction", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 513, 110], "ImageBB": [82, 116, 786, 293]}, "diagram_type": "single"}, {"id": 1130, "width": 1176, "height": 1240, "file_name": "jo991681n-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [490.12, 262.39, 58.94, 50.25], "category_id": 3}, {"id": 1, "bbox": [327.8, 995.6, 818.71, 244.4], "category_id": 3}, {"id": 2, "bbox": [0.0, 91.81, 312.07, 74.43], "category_id": 1}, {"id": 3, "bbox": [389.0, 729.48, 455.38, 236.96], "category_id": 1}, {"id": 4, "bbox": [389.0, 658.77, 65.14, 51.49], "category_id": 3}, {"id": 5, "bbox": [671.28, 155.08, 111.05, 52.1], "category_id": 2}, {"id": 6, "bbox": [837.55, 251.23, 322.61, 50.24], "category_id": 3}, {"id": 7, "bbox": [711.61, 84.36, 39.7, 45.28], "category_id": 2}, {"id": 8, "bbox": [389.0, 14.89, 280.42, 233.85], "category_id": 1}, {"id": 9, "bbox": [210.94, 401.96, 408.23, 235.72], "category_id": 1}, {"id": 10, "bbox": [608.62, 471.44, 86.24, 47.76], "category_id": 2}, {"id": 11, "bbox": [44.67, 544.63, 114.15, 54.59], "category_id": 2}, {"id": 12, "bbox": [348.67, 91.81, 41.57, 39.08], "category_id": 2}, {"id": 13, "bbox": [302.14, 156.94, 114.77, 59.55], "category_id": 2}, {"id": 14, "bbox": [951.71, 673.66, 55.83, 48.38], "category_id": 3}, {"id": 15, "bbox": [806.53, 3.72, 342.47, 230.14], "category_id": 1}, {"id": 16, "bbox": [671.28, 346.75, 504.72, 321.94], "category_id": 1}, {"id": 17, "bbox": [201.01, 887.66, 117.26, 55.83], "category_id": 2}, {"id": 18, "bbox": [244.44, 811.37, 33.5, 46.52], "category_id": 2}, {"id": 19, "bbox": [105.47, 204.7, 55.84, 50.25], "category_id": 3}, {"id": 20, "bbox": [85.62, 477.02, 39.08, 39.08], "category_id": 2}], "caption": "Scheme 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 63, 276, 77], "ImageBB": [96, 84, 390, 394]}, "reactions": [{"reactants": [2], "conditions": [12, 13], "products": [8]}, {"reactants": [8], "conditions": [7, 5], "products": [15]}, {"reactants": [15], "conditions": [20, 11], "products": [9]}, {"reactants": [9], "conditions": [10], "products": [16]}, {"reactants": [16], "conditions": [18, 17], "products": [3]}], "diagram_type": "multiple"}, {"id": 161, "width": 1356, "height": 208, "file_name": "op700060e-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [305.0, 25.0, 79.0, 45.0], "category_id": 2}, {"id": 1, "bbox": [542.0, 6.0, 334.0, 145.3], "category_id": 1}, {"id": 2, "bbox": [1162.2, 4.0, 190.8, 152.7], "category_id": 1}, {"id": 3, "bbox": [295.0, 80.0, 98.0, 46.0], "category_id": 2}, {"id": 4, "bbox": [645.0, 132.0, 43.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [922.0, 161.0, 118.0, 45.0], "category_id": 2}, {"id": 6, "bbox": [916.0, 0.0, 196.0, 45.0], "category_id": 2}, {"id": 7, "bbox": [3.0, 0.0, 195.0, 151.0], "category_id": 1}, {"id": 8, "bbox": [923.0, 116.0, 225.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [0, 3], "products": [1]}], "corefs": [[1, 4]], "caption": "Figure 1. Approaches to 2-benzenethiopyridine, 2.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 311, 702, 325], "ImageBB": [424, 256, 763, 308]}, "diagram_type": "single"}, {"id": 776, "width": 1348, "height": 800, "file_name": "jo951899j-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.0, 97.7, 377.0, 311.3], "category_id": 1}, {"id": 1, "bbox": [851.4, 94.2, 345.3, 308.8], "category_id": 1}, {"id": 2, "bbox": [360.07, 455.15, 87.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [578.0, 129.86, 242.0, 133.5], "category_id": 2}, {"id": 4, "bbox": [180.0, 10.0, 989.0, 47.0], "category_id": 2}, {"id": 5, "bbox": [92.0, 564.0, 1155.0, 236.0], "category_id": 4}, {"id": 6, "bbox": [1061.0, 454.0, 108.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [585.0, 311.0, 155.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [3, 7], "products": [1]}], "corefs": [[0, 2], [1, 6]], "caption": "Table 5. Removal of the MEE Ester Protecting Group", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [438, 55, 755, 67], "ImageBB": [429, 66, 766, 266]}, "diagram_type": "single"}, {"id": 256, "width": 1348, "height": 1584, "file_name": "ol802073q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [313.1, 47.3, 368.9, 110.7], "category_id": 1}, {"id": 1, "bbox": [1039.0, 170.0, 39.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [882.0, 41.0, 102.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [769.0, 75.0, 64.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [435.0, 166.0, 46.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [1.0, 220.0, 1347.0, 1364.0], "category_id": 4}, {"id": 6, "bbox": [902.0, 118.0, 47.0, 45.0], "category_id": 2}, {"id": 7, "bbox": [67.0, 32.0, 162.0, 146.0], "category_id": 1}, {"id": 8, "bbox": [1035.0, 1.0, 243.0, 210.0], "category_id": 1}, {"id": 9, "bbox": [117.0, 167.0, 39.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [7, 0, 3], "conditions": [2, 6], "products": [8]}], "corefs": [[7, 9], [0, 4], [8, 1]], "caption": "Table 2. Reactions of Carbonyl Compounds with Indium and 1-Bromopent-4-en-2-ynea ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 743, 102], "ImageBB": [425, 111, 762, 507]}, "diagram_type": "single"}, {"id": 1098, "width": 1152, "height": 608, "file_name": "jo961365y-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [674.83, 550.56, 108.35, 54.14], "category_id": 3}, {"id": 1, "bbox": [5.19, 437.69, 102.0, 56.43], "category_id": 3}, {"id": 2, "bbox": [214.96, 416.38, 306.0, 48.95], "category_id": 2}, {"id": 3, "bbox": [182.11, 143.98, 414.92, 51.83], "category_id": 2}, {"id": 4, "bbox": [710.56, 3.46, 427.61, 205.02], "category_id": 1}, {"id": 5, "bbox": [182.11, 73.14, 404.55, 65.08], "category_id": 2}, {"id": 6, "bbox": [0.0, 0.0, 2.31, 3.46], "category_id": 3}, {"id": 7, "bbox": [0.0, 0.0, 2.31, 7.49], "category_id": 3}, {"id": 8, "bbox": [269.13, 478.0, 189.6, 48.95], "category_id": 2}, {"id": 9, "bbox": [874.23, 347.84, 274.31, 99.06], "category_id": 2}, {"id": 10, "bbox": [905.35, 207.9, 110.07, 51.83], "category_id": 3}, {"id": 11, "bbox": [0.0, 0.0, 2.31, 7.49], "category_id": 3}, {"id": 12, "bbox": [566.49, 320.2, 294.48, 232.67], "category_id": 1}, {"id": 13, "bbox": [3.46, 113.45, 112.37, 57.02], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [206, 49, 269, 63], "ImageBB": [97, 69, 385, 221]}, "reactions": [{"reactants": [13], "conditions": [5, 3], "products": [4]}, {"reactants": [4], "conditions": [9], "products": [12]}, {"reactants": [12], "conditions": [2, 8], "products": [1]}], "diagram_type": "tree"}, {"id": 940, "width": 1356, "height": 1492, "file_name": "acs.orglett.5b01692-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [384.19, 1237.65, 293.74, 46.57], "category_id": 2}, {"id": 1, "bbox": [702.62, 811.31, 92.59, 44.03], "category_id": 2}, {"id": 2, "bbox": [16.43, 1192.7, 333.01, 188.84], "category_id": 1}, {"id": 3, "bbox": [53.76, 1391.99, 215.04, 39.55], "category_id": 2}, {"id": 4, "bbox": [1072.23, 1115.08, 188.91, 44.78], "category_id": 2}, {"id": 5, "bbox": [1027.43, 276.16, 266.56, 247.79], "category_id": 1}, {"id": 6, "bbox": [817.61, 11.94, 123.95, 164.95], "category_id": 1}, {"id": 7, "bbox": [16.43, 659.79, 344.96, 50.76], "category_id": 2}, {"id": 8, "bbox": [1050.7, 529.18, 191.77, 41.8], "category_id": 2}, {"id": 9, "bbox": [487.58, 525.45, 435.31, 48.51], "category_id": 2}, {"id": 10, "bbox": [369.61, 765.78, 182.49, 254.72], "category_id": 1}, {"id": 11, "bbox": [516.7, 325.42, 380.06, 178.38], "category_id": 1}, {"id": 12, "bbox": [487.58, 29.11, 220.27, 115.69], "category_id": 1}, {"id": 13, "bbox": [155.31, 1100.15, 91.09, 45.53], "category_id": 2}, {"id": 14, "bbox": [992.33, 744.13, 246.41, 258.25], "category_id": 1}, {"id": 15, "bbox": [53.76, 338.85, 342.73, 170.92], "category_id": 1}, {"id": 16, "bbox": [0.0, 524.7, 450.99, 49.26], "category_id": 2}, {"id": 17, "bbox": [685.45, 882.96, 132.16, 43.29], "category_id": 2}, {"id": 18, "bbox": [935.59, 1194.94, 330.77, 204.51], "category_id": 1}, {"id": 19, "bbox": [1025.19, 1406.91, 126.93, 40.31], "category_id": 2}, {"id": 20, "bbox": [607.8, 222.42, 90.34, 46.27], "category_id": 2}, {"id": 21, "bbox": [278.51, 47.02, 90.35, 50.01], "category_id": 2}, {"id": 22, "bbox": [1036.15, 37.61, 238.22, 48.36], "category_id": 2}, {"id": 23, "bbox": [1208.1, 161.19, 82.39, 48.36], "category_id": 2}, {"id": 24, "bbox": [1134.67, 143.28, 51.94, 73.44], "category_id": 2}, {"id": 25, "bbox": [34.92, 814.95, 207.77, 111.05], "category_id": 1}, {"id": 26, "bbox": [642.11, 1022.72, 297.32, 42.99], "category_id": 2}], "caption": "Scheme 1. Strategies for NHC-Catalyzed Reactions of Enals with Nitroalkenes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 462, 780, 492], "ImageBB": [448, 498, 787, 871]}, "reactions": [{"reactants": [12, 6], "conditions": [21], "products": [15]}, {"reactants": [12, 6], "conditions": [20], "products": [11]}, {"reactants": [12, 6], "conditions": [22, 23, 24], "products": [5]}, {"reactants": [25, 10], "conditions": [1, 17], "products": [14]}, {"reactants": [25], "conditions": [13], "products": [2]}, {"reactants": [2], "conditions": [0], "products": [18]}, {"reactants": [18], "conditions": [4], "products": [14]}], "diagram_type": "graph"}, {"id": 88, "width": 1348, "height": 800, "file_name": "ja0547477-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [471.74, 6.1, 706.46, 280.6], "category_id": 1}, {"id": 1, "bbox": [738.09, 275.54, 44.69, 32.5], "category_id": 3}, {"id": 2, "bbox": [171.85, 126.1, 42.66, 33.51], "category_id": 3}, {"id": 3, "bbox": [7.16, 375.17, 1335.74, 414.73], "category_id": 4}, {"id": 4, "bbox": [272.49, 101.7, 177.87, 34.53], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [4], "products": [0]}], "corefs": [[0, 1]], "caption": "Table 1. Conditions for the Cyclization of Sulfoxide 15 to Tetracycle 42 ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 727, 88], "ImageBB": [439, 88, 776, 288]}, "diagram_type": "single"}, {"id": 542, "width": 1348, "height": 380, "file_name": "acs.orglett.6b00233-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [358.0, 239.0, 74.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [1077.1, 213.0, 73.9, 50.0], "category_id": 3}, {"id": 2, "bbox": [912.2, 13.1, 398.7, 223.9], "category_id": 1}, {"id": 3, "bbox": [576.1, 173.2, 204.4, 52.5], "category_id": 2}, {"id": 4, "bbox": [518.3, 66.1, 343.7, 64.9], "category_id": 2}, {"id": 5, "bbox": [36.1, 4.0, 399.7, 230.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [4, 3], "products": [2]}], "corefs": [[5, 0], [2, 1]], "caption": "Table 1. Study of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 506, 302, 527], "ImageBB": [82, 533, 419, 628]}, "diagram_type": "single"}, {"id": 1236, "width": 1352, "height": 1200, "file_name": "op020211j-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [488.99, 591.19, 513.34, 608.77], "category_id": 1}, {"id": 1, "bbox": [29.08, 710.24, 458.56, 62.23], "category_id": 2}, {"id": 2, "bbox": [28.8, 831.99, 298.55, 67.64], "category_id": 2}, {"id": 3, "bbox": [0.0, 280.04, 409.86, 215.1], "category_id": 1}, {"id": 4, "bbox": [411.21, 401.79, 485.61, 56.14], "category_id": 2}, {"id": 5, "bbox": [384.16, 0.0, 386.87, 58.85], "category_id": 2}, {"id": 6, "bbox": [411.21, 304.39, 493.73, 63.58], "category_id": 2}, {"id": 7, "bbox": [789.96, 12.85, 545.81, 127.17], "category_id": 1}, {"id": 8, "bbox": [879.24, 932.1, 110.92, 58.17], "category_id": 2}, {"id": 9, "bbox": [942.82, 292.21, 409.18, 340.24], "category_id": 1}, {"id": 10, "bbox": [177.2, 175.87, 41.26, 47.35], "category_id": 3}, {"id": 11, "bbox": [912.38, 179.25, 51.4, 50.73], "category_id": 3}, {"id": 12, "bbox": [200.2, 540.46, 45.99, 50.73], "category_id": 3}, {"id": 13, "bbox": [0.0, 10.15, 336.14, 125.81], "category_id": 1}, {"id": 14, "bbox": [384.16, 107.55, 282.71, 58.17], "category_id": 2}, {"id": 15, "bbox": [570.15, 1095.79, 215.75, 57.5], "category_id": 2}, {"id": 16, "bbox": [507.25, 180.6, 97.4, 49.38], "category_id": 2}, {"id": 17, "bbox": [588.12, 482.52, 84.99, 46.1], "category_id": 2}, {"id": 18, "bbox": [150.18, 913.25, 93.64, 54.89], "category_id": 2}, {"id": 19, "bbox": [1025.33, 540.46, 42.61, 50.73], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [74, 72, 412, 372]}, "reactions": [{"reactants": [13], "conditions": [5, 14, 16], "products": [7]}, {"reactants": [3], "conditions": [6, 2, 17], "products": [9]}, {"reactants": [9], "conditions": [1, 2, 18], "products": [0, 8]}], "diagram_type": "multiple"}, {"id": 705, "width": 2816, "height": 2984, "file_name": "ol035681s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [810.0, 164.0, 329.0, 131.0], "category_id": 3}, {"id": 1, "bbox": [1158.0, 14.0, 517.0, 110.0], "category_id": 2}, {"id": 2, "bbox": [1900.0, 176.0, 36.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [1168.0, 153.0, 449.0, 61.0], "category_id": 2}, {"id": 4, "bbox": [19.0, 327.0, 1320.0, 2487.0], "category_id": 4}, {"id": 5, "bbox": [1464.0, 327.0, 1352.0, 2482.0], "category_id": 4}, {"id": 6, "bbox": [8.0, 2814.0, 2808.0, 170.0], "category_id": 2}, {"id": 7, "bbox": [850.0, 5.0, 249.0, 162.0], "category_id": 1}, {"id": 8, "bbox": [1765.0, 8.0, 251.0, 200.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [1, 3], "products": [8]}], "corefs": [[7, 0], [8, 2]], "caption": "Table 1. Cu(II)-Catalyzed N-Phenylation of Aliphatic Amines, Ammonium Salts, and Anilinesa", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 573, 89], "ImageBB": [73, 96, 777, 842]}, "diagram_type": "single"}, {"id": 736, "width": 1348, "height": 2104, "file_name": "ol015948s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 324.0, 1336.0, 1780.0], "category_id": 4}, {"id": 1, "bbox": [1034.0, 5.0, 286.0, 287.0], "category_id": 1}, {"id": 2, "bbox": [690.0, 185.0, 266.0, 49.0], "category_id": 2}, {"id": 3, "bbox": [637.0, 108.0, 362.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [662.0, 58.0, 312.0, 53.0], "category_id": 2}, {"id": 5, "bbox": [308.0, 30.0, 286.0, 232.0], "category_id": 1}, {"id": 6, "bbox": [52.0, 75.0, 179.0, 137.0], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [4, 3, 2], "products": [1]}], "corefs": [], "caption": "Table 2. Direct Reductive Aminations of Carbonyl Compounds with Anilines ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 711, 104], "ImageBB": [440, 107, 777, 633]}, "diagram_type": "single"}, {"id": 199, "width": 1348, "height": 884, "file_name": "op049899l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 8.0, 1333.0, 442.0], "category_id": 4}, {"id": 1, "bbox": [1053.0, 841.0, 48.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [327.0, 818.0, 47.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [832.0, 597.0, 410.0, 210.0], "category_id": 1}, {"id": 4, "bbox": [643.0, 576.0, 153.0, 128.0], "category_id": 1}, {"id": 5, "bbox": [111.0, 590.0, 428.0, 204.0], "category_id": 1}, {"id": 6, "bbox": [649.0, 734.0, 91.0, 41.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [4, 6], "products": [3]}], "corefs": [[5, 2], [3, 1]], "caption": "Table 1. DOE results for alkylation of 6 to give 17 (% yield)", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 773, 67], "ImageBB": [439, 70, 776, 291]}, "diagram_type": "single"}, {"id": 779, "width": 1348, "height": 804, "file_name": "jo951899j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [20.0, 318.0, 184.7, 73.5], "category_id": 3}, {"id": 1, "bbox": [446.0, 313.0, 199.9, 81.1], "category_id": 3}, {"id": 2, "bbox": [841.77, 134.77, 122.0, 78.0], "category_id": 2}, {"id": 3, "bbox": [844.0, 71.2, 134.1, 43.1], "category_id": 2}, {"id": 4, "bbox": [1016.6, 0.0, 327.4, 176.8], "category_id": 1}, {"id": 5, "bbox": [482.0, 5.8, 328.0, 169.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 8.0, 289.4, 167.1], "category_id": 1}, {"id": 7, "bbox": [521.22, 224.84, 76.38, 43.06], "category_id": 2}, {"id": 8, "bbox": [323.0, 82.0, 130.0, 35.0], "category_id": 2}, {"id": 9, "bbox": [7.0, 406.0, 1341.0, 398.0], "category_id": 4}, {"id": 10, "bbox": [128.0, 207.0, 81.0, 47.0], "category_id": 3}, {"id": 11, "bbox": [665.0, 209.0, 79.0, 42.0], "category_id": 3}, {"id": 12, "bbox": [1150.0, 212.0, 73.0, 44.0], "category_id": 3}, {"id": 13, "bbox": [312.0, 183.0, 144.0, 96.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [8, 13], "products": [5]}, {"reactants": [5], "conditions": [3, 2], "products": [4]}], "corefs": [[6, 10], [5, 11], [4, 12], [6, 0], [5, 1]], "caption": "Table 1. Synthesis of N-Protected Serine and Threonine                       MEE Esters ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [430, 370, 763, 395], "ImageBB": [429, 404, 766, 605]}, "diagram_type": "single"}, {"id": 189, "width": 824, "height": 128, "file_name": "op060155c-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [613.0, 6.0, 211.0, 122.0], "category_id": 1}, {"id": 1, "bbox": [2.0, 1.0, 222.0, 124.0], "category_id": 1}, {"id": 2, "bbox": [317.0, 0.0, 214.0, 123.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [0]}], "corefs": [], "caption": "Figure 1. MeTHF production process.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 88, 290, 102], "ImageBB": [139, 53, 345, 85]}, "diagram_type": "single"}, {"id": 1370, "width": 2748, "height": 1800, "file_name": "op970113b-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1231.72, 0.0, 395.38, 395.98], "category_id": 1}, {"id": 1, "bbox": [2015.7, 1311.67, 618.6, 488.33], "category_id": 4}, {"id": 2, "bbox": [771.2, 562.34, 177.33, 77.0], "category_id": 2}, {"id": 3, "bbox": [1360.94, 1057.31, 549.88, 247.48], "category_id": 1}, {"id": 4, "bbox": [1164.36, 439.97, 171.84, 71.5], "category_id": 2}, {"id": 5, "bbox": [0.0, 455.1, 640.6, 329.98], "category_id": 1}, {"id": 6, "bbox": [2101.9, 59.12, 551.25, 269.48], "category_id": 1}, {"id": 7, "bbox": [1234.47, 661.33, 570.49, 298.67], "category_id": 1}, {"id": 8, "bbox": [2199.5, 874.45, 548.5, 269.48], "category_id": 1}, {"id": 9, "bbox": [970.53, 793.33, 180.08, 74.24], "category_id": 2}, {"id": 10, "bbox": [2099.15, 367.1, 591.11, 266.74], "category_id": 4}], "caption": "Scheme 3. Reaction pathways which can lead to relocation of the benzoyl moiety", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 49, 521, 63], "ImageBB": [82, 68, 769, 518]}, "reactions": [{"reactants": [5], "conditions": [2], "products": [0]}, {"reactants": [0], "conditions": [], "products": [6]}, {"reactants": [5], "conditions": [2], "products": [3]}, {"reactants": [3, 7], "conditions": [], "products": [8]}], "diagram_type": "tree"}, {"id": 690, "width": 1348, "height": 600, "file_name": "ol401042b-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [90.77, 288.56, 194.63, 45.84], "category_id": 2}, {"id": 1, "bbox": [757.61, 164.39, 153.99, 54.01], "category_id": 2}, {"id": 2, "bbox": [1119.58, 242.83, 81.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [26.3, 56.7, 323.2, 181.3], "category_id": 1}, {"id": 4, "bbox": [510.0, 242.28, 127.5, 43.3], "category_id": 2}, {"id": 5, "bbox": [472.7, 105.1, 201.8, 114.8], "category_id": 1}, {"id": 6, "bbox": [1000.91, 6.03, 324.09, 240.67], "category_id": 1}, {"id": 7, "bbox": [144.58, 239.72, 80.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [709.0, 80.0, 278.0, 59.0], "category_id": 2}, {"id": 9, "bbox": [7.0, 376.0, 1341.0, 224.0], "category_id": 4}], "reactions": [{"reactants": [3, 5], "conditions": [8, 1], "products": [6]}], "corefs": [[3, 7], [6, 2]], "caption": "Table 4. Scope of Substrate for Organocatalytic Annulationa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 533, 760, 549], "ImageBB": [436, 559, 773, 709]}, "diagram_type": "single"}, {"id": 441, "width": 2820, "height": 784, "file_name": "op200312m-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1532.0, 304.0, 40.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [2.0, 358.0, 2816.0, 426.0], "category_id": 4}, {"id": 2, "bbox": [1202.0, 163.0, 81.0, 50.0], "category_id": 2}, {"id": 3, "bbox": [734.5, 0.0, 414.5, 295.0], "category_id": 1}, {"id": 4, "bbox": [1364.5, 58.1, 397.4, 194.9], "category_id": 1}, {"id": 5, "bbox": [2033.08, 138.83, 55.29, 53.17], "category_id": 3}, {"id": 6, "bbox": [1931.0, 138.83, 51.04, 53.17], "category_id": 3}, {"id": 7, "bbox": [903.0, 305.0, 39.5, 43.0], "category_id": 3}, {"id": 8, "bbox": [1825.5, 140.0, 55.6, 52.7], "category_id": 3}, {"id": 9, "bbox": [1168.6, 8.0, 158.1, 143.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [9, 2], "products": [4, 8, 6, 5]}], "corefs": [[3, 7], [4, 0]], "caption": "Table 3. Levels of the five factors in the 25\u20111 fractional factorial design", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 92, 479, 109], "ImageBB": [82, 116, 787, 312]}, "diagram_type": "single"}, {"id": 319, "width": 1196, "height": 2264, "file_name": "ol3023177-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [774.5, 0.0, 270.4, 161.2], "category_id": 1}, {"id": 1, "bbox": [155.0, 39.0, 241.0, 107.0], "category_id": 1}, {"id": 2, "bbox": [891.0, 147.0, 43.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [536.0, 146.0, 47.0, 49.0], "category_id": 3}, {"id": 4, "bbox": [15.0, 249.0, 1181.0, 2015.0], "category_id": 4}, {"id": 5, "bbox": [267.0, 147.0, 39.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [482.0, 44.0, 169.0, 110.0], "category_id": 1}], "reactions": [{"reactants": [1, 6], "conditions": [], "products": [0]}], "corefs": [[1, 5], [6, 3], [0, 2]], "caption": "Table 2. Scope of H-Bonding Directed Hydroaminationa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 740, 101], "ImageBB": [455, 112, 754, 678]}, "diagram_type": "single"}, {"id": 1349, "width": 1348, "height": 440, "file_name": "op700253t-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 178.74, 186.79, 37.77], "category_id": 3}, {"id": 1, "bbox": [179.37, 109.94, 154.43, 68.8], "category_id": 2}, {"id": 2, "bbox": [192.86, 259.68, 140.26, 44.52], "category_id": 2}, {"id": 3, "bbox": [872.59, 250.91, 132.85, 109.27], "category_id": 1}, {"id": 4, "bbox": [722.89, 109.27, 93.73, 70.82], "category_id": 2}, {"id": 5, "bbox": [564.42, 250.91, 129.47, 109.27], "category_id": 1}, {"id": 6, "bbox": [839.55, 0.0, 209.04, 151.09], "category_id": 1}, {"id": 7, "bbox": [179.37, 51.26, 138.92, 40.47], "category_id": 2}, {"id": 8, "bbox": [726.94, 259.68, 95.75, 44.52], "category_id": 2}, {"id": 9, "bbox": [366.84, 251.59, 125.43, 108.59], "category_id": 1}, {"id": 10, "bbox": [1021.62, 317.01, 118.68, 44.52], "category_id": 2}, {"id": 11, "bbox": [1150.42, 0.0, 197.58, 151.09], "category_id": 1}, {"id": 12, "bbox": [1192.23, 249.56, 119.36, 110.62], "category_id": 1}, {"id": 13, "bbox": [335.82, 0.0, 194.21, 151.09], "category_id": 1}, {"id": 14, "bbox": [24.95, 0.0, 195.56, 151.09], "category_id": 1}, {"id": 15, "bbox": [192.86, 319.71, 159.14, 69.48], "category_id": 2}, {"id": 16, "bbox": [1026.34, 248.89, 96.43, 47.89], "category_id": 2}, {"id": 17, "bbox": [1007.46, 105.22, 119.36, 45.87], "category_id": 2}, {"id": 18, "bbox": [720.87, 48.56, 90.36, 45.87], "category_id": 2}, {"id": 19, "bbox": [64.74, 252.26, 117.33, 107.92], "category_id": 1}, {"id": 20, "bbox": [1020.27, 42.49, 82.95, 42.5], "category_id": 2}, {"id": 21, "bbox": [730.31, 319.71, 101.82, 68.8], "category_id": 2}, {"id": 22, "bbox": [0.0, 397.95, 204.32, 39.8], "category_id": 3}, {"id": 23, "bbox": [533.4, 0.0, 203.6, 151.09], "category_id": 1}], "caption": "Scheme 1. Preparation of chiral secondary alcohols by chemoenzymatic deracemization ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 363, 73], "ImageBB": [58, 79, 395, 189]}, "reactions": [{"reactants": [14], "conditions": [7, 1], "products": [13, 23]}, {"reactants": [13, 23], "conditions": [18, 4], "products": [6]}, {"reactants": [6], "conditions": [20, 17], "products": [11]}, {"reactants": [19], "conditions": [2, 15], "products": [9, 5]}, {"reactants": [9, 5], "conditions": [8, 21], "products": [3]}, {"reactants": [3], "conditions": [16, 10], "products": [12]}], "diagram_type": "multiple"}, {"id": 697, "width": 1352, "height": 1152, "file_name": "ol0480731-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1036.0, 68.0, 248.6, 202.0], "category_id": 1}, {"id": 1, "bbox": [597.7, 75.0, 158.0, 133.0], "category_id": 1}, {"id": 2, "bbox": [809.0, 92.0, 136.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [58.0, 0.0, 445.0, 302.0], "category_id": 1}, {"id": 4, "bbox": [96.0, 254.0, 135.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [12.0, 431.0, 1331.0, 667.0], "category_id": 4}, {"id": 6, "bbox": [791.0, 160.0, 188.0, 51.0], "category_id": 2}, {"id": 7, "bbox": [181.0, 302.0, 184.0, 59.0], "category_id": 2}], "reactions": [{"reactants": [3, 1], "conditions": [2, 6], "products": [0]}], "corefs": [[3, 4]], "caption": "Table 1. Syn-Selective Aldehyde Crotylation with (R,R)-2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 547, 380, 560], "ImageBB": [73, 561, 411, 849]}, "diagram_type": "single"}, {"id": 866, "width": 1356, "height": 908, "file_name": "jo2001534-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [356.0, 133.0, 99.0, 33.0], "category_id": 2}, {"id": 1, "bbox": [1014.0, 7.0, 337.0, 333.0], "category_id": 1}, {"id": 2, "bbox": [491.0, 21.0, 335.0, 301.0], "category_id": 1}, {"id": 3, "bbox": [1.0, 25.0, 339.0, 293.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 440.0, 1356.0, 468.0], "category_id": 4}, {"id": 5, "bbox": [1141.0, 341.0, 86.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [614.0, 340.0, 71.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [135.0, 343.0, 71.0, 34.0], "category_id": 3}, {"id": 8, "bbox": [845.0, 133.0, 133.0, 34.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [0], "products": [2]}, {"reactants": [2], "conditions": [8], "products": [1]}], "corefs": [[3, 7], [2, 6], [1, 5]], "caption": "Table 5. Yields and Substitution Patterns for Compounds 10a-e ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 672, 392, 702], "ImageBB": [71, 709, 410, 936]}, "diagram_type": "single"}, {"id": 327, "width": 1344, "height": 1948, "file_name": "ol301114z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [508.0, 345.0, 61.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [398.0, 701.0, 141.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [653.0, 600.0, 194.0, 44.0], "category_id": 2}, {"id": 3, "bbox": [7.0, 787.0, 1337.0, 1161.0], "category_id": 4}, {"id": 4, "bbox": [120.0, 695.0, 61.0, 57.0], "category_id": 3}, {"id": 5, "bbox": [1022.0, 699.0, 57.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [1094.0, 320.0, 59.0, 67.0], "category_id": 3}, {"id": 7, "bbox": [820.0, 334.0, 59.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [139.0, 345.0, 43.0, 46.0], "category_id": 3}, {"id": 9, "bbox": [750.6, 67.0, 213.4, 183.4], "category_id": 1}, {"id": 10, "bbox": [632.0, 471.0, 251.0, 90.7], "category_id": 2}, {"id": 11, "bbox": [1003.5, 426.6, 321.0, 331.3], "category_id": 1}, {"id": 12, "bbox": [399.1, 534.1, 160.4, 111.9], "category_id": 1}, {"id": 13, "bbox": [25.1, 477.0, 258.8, 195.5], "category_id": 1}, {"id": 14, "bbox": [1000.1, 54.6, 264.9, 186.8], "category_id": 1}, {"id": 15, "bbox": [25.5, 3.0, 312.5, 311.4], "category_id": 1}, {"id": 16, "bbox": [374.0, 3.0, 316.0, 310.0], "category_id": 1}], "reactions": [{"reactants": [13, 12], "conditions": [10, 2], "products": [11]}], "corefs": [[15, 8], [16, 0], [9, 7], [14, 6], [13, 4], [12, 1], [11, 5]], "caption": "Table 1. Optimization of the Reaction Conditions for the [4 \u00fe 2] Annulation ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 405, 115], "ImageBB": [71, 126, 407, 613]}, "diagram_type": "single"}, {"id": 13, "width": 1344, "height": 624, "file_name": "ja9810742-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [942.06, 132.75, 30.33, 37.18], "category_id": 3}, {"id": 1, "bbox": [251.18, 55.5, 111.86, 38.05], "category_id": 2}, {"id": 2, "bbox": [299.24, 135.32, 25.18, 37.19], "category_id": 3}, {"id": 3, "bbox": [594.48, 89.83, 169.35, 44.06], "category_id": 2}, {"id": 4, "bbox": [601.34, 4.87, 153.05, 43.19], "category_id": 2}, {"id": 5, "bbox": [839.93, 11.74, 251.75, 118.72], "category_id": 1}, {"id": 6, "bbox": [2.29, 207.41, 1338.31, 408.81], "category_id": 4}, {"id": 7, "bbox": [484.62, 51.21, 50.92, 38.91], "category_id": 3}], "reactions": [{"reactants": [1, 7], "conditions": [4, 3], "products": [5]}], "corefs": [[1, 2], [5, 0]], "caption": "Table 2. Allylation of Aldehydes 1 with 2,3-Dimethyl-4-penten-2-ol 2ba ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 262, 283, 287], "ImageBB": [74, 288, 410, 444]}, "diagram_type": "single"}, {"id": 570, "width": 1348, "height": 356, "file_name": "acs.orglett.5b01044-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [656.0, 24.0, 156.0, 77.0], "category_id": 2}, {"id": 1, "bbox": [8.0, 286.0, 1334.0, 66.0], "category_id": 4}, {"id": 2, "bbox": [654.0, 119.0, 162.0, 76.0], "category_id": 2}, {"id": 3, "bbox": [74.0, 0.0, 305.0, 210.0], "category_id": 1}, {"id": 4, "bbox": [508.0, 208.9, 50.0, 41.1], "category_id": 3}, {"id": 5, "bbox": [987.9, 211.0, 124.1, 43.0], "category_id": 3}, {"id": 6, "bbox": [433.2, 17.1, 206.8, 191.9], "category_id": 1}, {"id": 7, "bbox": [205.9, 208.9, 52.1, 40.1], "category_id": 3}, {"id": 8, "bbox": [837.9, 16.1, 434.7, 193.9], "category_id": 1}], "reactions": [{"reactants": [3, 6], "conditions": [0, 2], "products": [8]}], "corefs": [[3, 7], [6, 4], [8, 5]], "caption": "Table 1. Enantioselective Addition of o-tBu-Phenol to Ethyl(p-tolyl)ketene Catalyzed by (S)-1a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 90, 746, 125], "ImageBB": [449, 131, 786, 220]}, "diagram_type": "single"}, {"id": 1206, "width": 1348, "height": 792, "file_name": "ol800418m-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [904.29, 12.14, 341.89, 233.38], "category_id": 1}, {"id": 1, "bbox": [662.87, 685.29, 56.65, 49.91], "category_id": 3}, {"id": 2, "bbox": [249.5, 682.59, 56.65, 49.92], "category_id": 3}, {"id": 3, "bbox": [1064.1, 679.89, 58.0, 49.24], "category_id": 3}, {"id": 4, "bbox": [103.85, 0.0, 339.19, 245.52], "category_id": 1}, {"id": 5, "bbox": [504.4, 435.73, 337.85, 244.84], "category_id": 1}, {"id": 6, "bbox": [487.55, 29.0, 327.72, 95.11], "category_id": 2}, {"id": 7, "bbox": [267.71, 257.66, 36.42, 44.52], "category_id": 3}, {"id": 8, "bbox": [103.85, 433.03, 338.52, 245.52], "category_id": 1}, {"id": 9, "bbox": [1061.41, 250.91, 37.76, 45.87], "category_id": 3}, {"id": 10, "bbox": [902.26, 430.33, 338.52, 240.12], "category_id": 1}], "caption": "Scheme 3. Attempted Ring-Closing Metathesis of Enyne 5", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [440, 463, 744, 478], "ImageBB": [425, 485, 762, 683]}, "reactions": [{"reactants": [4], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [0]}], "diagram_type": "graph"}, {"id": 919, "width": 1356, "height": 1248, "file_name": "acs.joc.5b02057-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.28, 330.31, 636.96, 48.83], "category_id": 2}, {"id": 1, "bbox": [663.07, 567.78, 43.44, 37.46], "category_id": 2}, {"id": 2, "bbox": [214.0, 1153.02, 75.65, 52.22], "category_id": 2}, {"id": 3, "bbox": [16.28, 692.49, 192.65, 49.51], "category_id": 2}, {"id": 4, "bbox": [276.1, 874.94, 90.88, 49.76], "category_id": 2}, {"id": 5, "bbox": [619.32, 250.95, 47.49, 47.48], "category_id": 2}, {"id": 6, "bbox": [0.0, 417.8, 259.13, 250.95], "category_id": 1}, {"id": 7, "bbox": [0.0, 80.03, 223.85, 235.35], "category_id": 1}, {"id": 8, "bbox": [717.0, 86.14, 163.48, 212.29], "category_id": 1}, {"id": 9, "bbox": [16.28, 0.0, 223.17, 47.48], "category_id": 2}, {"id": 10, "bbox": [408.36, 911.56, 246.92, 52.23], "category_id": 2}, {"id": 11, "bbox": [438.21, 785.41, 181.79, 124.12], "category_id": 1}, {"id": 12, "bbox": [205.54, 1094.01, 98.36, 46.8], "category_id": 2}, {"id": 13, "bbox": [1095.52, 425.26, 260.48, 193.3], "category_id": 1}, {"id": 14, "bbox": [1009.37, 487.66, 87.5, 45.44], "category_id": 2}, {"id": 15, "bbox": [14.92, 760.31, 213.68, 191.95], "category_id": 1}, {"id": 16, "bbox": [987.66, 97.67, 189.26, 212.97], "category_id": 1}, {"id": 17, "bbox": [335.78, 89.53, 241.49, 211.61], "category_id": 1}, {"id": 18, "bbox": [363.59, 419.83, 256.41, 218.4], "category_id": 1}, {"id": 19, "bbox": [704.79, 1077.73, 188.58, 114.63], "category_id": 1}, {"id": 20, "bbox": [743.46, 419.83, 259.13, 191.95], "category_id": 1}, {"id": 21, "bbox": [438.21, 1094.01, 175.01, 108.52], "category_id": 1}, {"id": 22, "bbox": [704.79, 798.97, 191.97, 118.02], "category_id": 1}], "caption": "Scheme 1. Gold-Catalyzed Reactions of Organic Azides with Alkynes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 535, 784, 565], "ImageBB": [448, 572, 787, 884]}, "reactions": [{"reactants": [7], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [5, 8]}, {"reactants": [8], "conditions": [], "products": [16]}, {"reactants": [6], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [1, 20]}, {"reactants": [20], "conditions": [14], "products": [13]}, {"reactants": [15], "conditions": [4], "products": [11, 22]}, {"reactants": [11], "conditions": [], "products": [21]}, {"reactants": [21, 19], "conditions": [12, 2], "products": [15]}], "diagram_type": "graph"}, {"id": 452, "width": 1344, "height": 1008, "file_name": "op2001047-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [11.0, 276.0, 1333.0, 732.0], "category_id": 4}, {"id": 1, "bbox": [1134.5, 185.0, 87.5, 61.2], "category_id": 3}, {"id": 2, "bbox": [503.05, 192.65, 47.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [100.46, 193.3, 104.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [1033.9, 6.0, 241.8, 124.7], "category_id": 1}, {"id": 5, "bbox": [63.1, 16.8, 159.7, 129.6], "category_id": 1}, {"id": 6, "bbox": [387.0, 3.9, 237.6, 115.0], "category_id": 1}, {"id": 7, "bbox": [789.0, 33.0, 95.0, 47.0], "category_id": 2}, {"id": 8, "bbox": [700.0, 103.0, 275.0, 59.0], "category_id": 2}], "reactions": [{"reactants": [5, 6], "conditions": [7, 8], "products": [4]}], "corefs": [[5, 3], [6, 2], [4, 1]], "caption": "Table 3. Comparison between microwave batch and contin- uous \ufb02ow conditions in the Wittig reaction of aldehydes 4a c with (acetylmethylene)triphenylphosphorane (5)a ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 458, 771, 503], "ImageBB": [437, 513, 773, 765]}, "diagram_type": "single"}, {"id": 860, "width": 1356, "height": 464, "file_name": "jo200480h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [46.0, 279.0, 47.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [1088.0, 277.0, 39.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [998.0, 2.0, 354.0, 296.0], "category_id": 1}, {"id": 3, "bbox": [651.0, 62.0, 331.0, 137.0], "category_id": 2}, {"id": 4, "bbox": [658.0, 210.0, 321.0, 50.0], "category_id": 2}, {"id": 5, "bbox": [10.0, 363.0, 1339.0, 98.0], "category_id": 4}, {"id": 6, "bbox": [2.0, 130.0, 243.0, 147.0], "category_id": 1}, {"id": 7, "bbox": [261.0, 139.0, 383.0, 122.0], "category_id": 1}, {"id": 8, "bbox": [430.0, 273.0, 51.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [6, 7], "conditions": [3, 4], "products": [2]}], "corefs": [[6, 0], [7, 8], [2, 1]], "caption": "Table 1. Optimization of the Heteroannulation Reaction between 4-Acetamido-3-iodopyridine (1) and Diphenylace- tylene (2) ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 764, 137], "ImageBB": [436, 148, 775, 264]}, "diagram_type": "single"}, {"id": 1369, "width": 1300, "height": 1420, "file_name": "op970105v-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [726.19, 659.92, 263.62, 58.25], "category_id": 2}, {"id": 1, "bbox": [699.9, 1231.05, 105.88, 56.11], "category_id": 2}, {"id": 2, "bbox": [88.11, 1212.58, 102.32, 60.38], "category_id": 2}, {"id": 3, "bbox": [930.12, 815.49, 160.59, 105.84], "category_id": 2}, {"id": 4, "bbox": [726.9, 294.09, 103.03, 53.98], "category_id": 2}, {"id": 5, "bbox": [412.12, 423.37, 49.74, 44.75], "category_id": 3}, {"id": 6, "bbox": [260.07, 493.7, 436.99, 384.3], "category_id": 1}, {"id": 7, "bbox": [68.92, 269.22, 100.19, 58.25], "category_id": 2}, {"id": 8, "bbox": [687.11, 1096.08, 161.3, 95.9], "category_id": 2}, {"id": 9, "bbox": [412.12, 1368.85, 54.72, 46.89], "category_id": 3}, {"id": 10, "bbox": [574.13, 441.84, 235.91, 104.42], "category_id": 2}, {"id": 11, "bbox": [1116.29, 703.25, 33.4, 47.6], "category_id": 3}, {"id": 12, "bbox": [971.34, 1365.3, 58.97, 50.44], "category_id": 3}, {"id": 13, "bbox": [867.59, 26.28, 432.41, 466.0], "category_id": 1}, {"id": 14, "bbox": [804.35, 546.26, 162.72, 60.38], "category_id": 2}, {"id": 15, "bbox": [258.64, 939.09, 424.21, 480.91], "category_id": 1}, {"id": 16, "bbox": [687.11, 156.28, 189.01, 102.29], "category_id": 2}, {"id": 17, "bbox": [0.0, 1162.14, 44.77, 53.28], "category_id": 3}, {"id": 18, "bbox": [0.0, 229.44, 40.5, 50.44], "category_id": 3}, {"id": 19, "bbox": [989.1, 426.92, 58.27, 53.99], "category_id": 3}, {"id": 20, "bbox": [243.01, 0.0, 430.6, 476.65], "category_id": 1}, {"id": 21, "bbox": [859.07, 954.01, 431.31, 465.99], "category_id": 1}, {"id": 22, "bbox": [64.66, 179.72, 147.09, 59.67], "category_id": 2}, {"id": 23, "bbox": [68.92, 1077.61, 165.56, 96.61], "category_id": 2}, {"id": 24, "bbox": [428.47, 873.03, 61.82, 49.01], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 395, 134, 409], "ImageBB": [79, 416, 404, 771]}, "reactions": [{"reactants": [18], "conditions": [22, 7], "products": [20]}, {"reactants": [20], "conditions": [16, 4], "products": [13]}, {"reactants": [13], "conditions": [10, 14], "products": [6]}, {"reactants": [6], "conditions": [0], "products": [11]}, {"reactants": [17], "conditions": [23, 2], "products": [15]}, {"reactants": [15], "conditions": [8, 1], "products": [21]}, {"reactants": [21], "conditions": [3], "products": [11]}], "diagram_type": "tree"}, {"id": 1330, "width": 2820, "height": 1424, "file_name": "op400242j-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [427.44, 571.44, 404.88, 266.67], "category_id": 1}, {"id": 1, "bbox": [873.23, 658.91, 251.1, 57.85], "category_id": 2}, {"id": 2, "bbox": [1238.6, 1030.0, 414.75, 321.69], "category_id": 1}, {"id": 3, "bbox": [1551.78, 794.37, 71.94, 57.85], "category_id": 3}, {"id": 4, "bbox": [878.87, 716.76, 255.34, 47.98], "category_id": 2}, {"id": 5, "bbox": [1551.78, 237.04, 64.89, 55.03], "category_id": 3}, {"id": 6, "bbox": [2251.49, 794.37, 69.12, 55.02], "category_id": 3}, {"id": 7, "bbox": [1990.51, 571.44, 402.05, 262.43], "category_id": 1}, {"id": 8, "bbox": [689.83, 800.01, 46.56, 49.38], "category_id": 3}, {"id": 9, "bbox": [1635.38, 526.95, 114.85, 57.42], "category_id": 2}, {"id": 10, "bbox": [1232.96, 18.34, 517.73, 262.44], "category_id": 1}, {"id": 11, "bbox": [1785.95, 664.56, 211.61, 62.08], "category_id": 2}, {"id": 12, "bbox": [1238.6, 488.2, 407.2, 345.67], "category_id": 1}, {"id": 13, "bbox": [1553.19, 1322.06, 77.59, 59.26], "category_id": 3}], "caption": "Scheme 7. Hypothesized chlorination mechanism to form chloroimidate 18", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 507, 110], "ImageBB": [82, 116, 787, 472]}, "reactions": [{"reactants": [0], "conditions": [1, 4], "products": [10, 12, 2]}, {"reactants": [12, 9], "conditions": [11], "products": [7]}], "diagram_type": "tree"}, {"id": 408, "width": 1704, "height": 3984, "file_name": "op400278d-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [70.0, 2094.0, 1634.0, 1890.0], "category_id": 2}, {"id": 1, "bbox": [130.0, 1529.5, 235.4, 95.0], "category_id": 3}, {"id": 2, "bbox": [573.3, 1532.4, 234.1, 93.8], "category_id": 3}, {"id": 3, "bbox": [147.0, 1938.0, 271.3, 111.1], "category_id": 3}, {"id": 4, "bbox": [1040.1, 1534.0, 238.8, 91.4], "category_id": 3}, {"id": 5, "bbox": [118.0, 626.0, 265.0, 100.6], "category_id": 3}, {"id": 6, "bbox": [568.0, 625.1, 249.0, 101.0], "category_id": 3}, {"id": 7, "bbox": [1048.2, 1949.6, 231.3, 98.7], "category_id": 3}, {"id": 8, "bbox": [556.0, 1950.0, 380.6, 114.7], "category_id": 3}, {"id": 9, "bbox": [83.8, 1224.8, 335.6, 268.0], "category_id": 1}, {"id": 10, "bbox": [745.5, 776.7, 553.8, 295.3], "category_id": 1}, {"id": 11, "bbox": [199.0, 761.0, 424.5, 322.4], "category_id": 1}, {"id": 12, "bbox": [526.0, 1231.5, 328.2, 270.5], "category_id": 1}, {"id": 13, "bbox": [979.4, 1209.0, 369.4, 310.4], "category_id": 1}, {"id": 14, "bbox": [700.8, 63.5, 355.5, 100.5], "category_id": 2}, {"id": 15, "bbox": [676.4, 190.2, 387.9, 65.9], "category_id": 2}, {"id": 16, "bbox": [472.0, 4.0, 911.0, 60.0], "category_id": 2}, {"id": 17, "bbox": [1018.0, 630.0, 301.0, 96.6], "category_id": 3}, {"id": 18, "bbox": [829.0, 1080.0, 402.0, 113.0], "category_id": 3}, {"id": 19, "bbox": [295.0, 1076.0, 233.0, 104.0], "category_id": 3}, {"id": 20, "bbox": [132.3, 142.5, 119.7, 68.9], "category_id": 1}, {"id": 21, "bbox": [365.82, 213.4, 204.11, 64.34], "category_id": 2}, {"id": 22, "bbox": [75.18, 213.4, 206.33, 64.34], "category_id": 2}, {"id": 23, "bbox": [1169.4, 143.4, 172.8, 64.2], "category_id": 1}, {"id": 24, "bbox": [89.1, 345.0, 320.6, 253.0], "category_id": 1}, {"id": 25, "bbox": [943.8, 328.7, 431.9, 293.3], "category_id": 1}, {"id": 26, "bbox": [529.7, 345.0, 328.0, 257.3], "category_id": 1}, {"id": 27, "bbox": [426.1, 148.0, 120.2, 60.7], "category_id": 1}, {"id": 28, "bbox": [943.7, 1652.3, 433.5, 282.3], "category_id": 1}, {"id": 29, "bbox": [581.4, 1662.0, 332.9, 266.0], "category_id": 1}, {"id": 30, "bbox": [78.0, 1654.0, 432.6, 274.0], "category_id": 1}], "reactions": [{"reactants": [20, 27], "conditions": [16, 14, 15], "products": [23]}], "corefs": [[24, 5], [26, 6], [25, 17], [11, 19], [10, 18], [9, 1], [12, 2], [13, 4], [30, 3], [29, 8], [28, 7]], "caption": "Table 3. Room temperature aryl sul\ufb01nations mediated by pre-catalyst Pd-PEPPSI-IPentCl-picoline (35) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 773, 126], "ImageBB": [433, 131, 859, 1127]}, "diagram_type": "single"}, {"id": 1149, "width": 1352, "height": 1556, "file_name": "ol036510q-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [203.2, 1112.32, 117.56, 51.37], "category_id": 2}, {"id": 1, "bbox": [425.09, 227.29, 218.77, 93.41], "category_id": 1}, {"id": 2, "bbox": [330.1, 1059.39, 509.95, 162.68], "category_id": 1}, {"id": 3, "bbox": [814.36, 667.86, 505.28, 307.46], "category_id": 1}, {"id": 4, "bbox": [33.48, 1057.83, 168.94, 137.0], "category_id": 1}, {"id": 5, "bbox": [854.07, 194.6, 36.59, 38.14], "category_id": 3}, {"id": 6, "bbox": [293.51, 254.53, 94.99, 49.82], "category_id": 2}, {"id": 7, "bbox": [813.58, 1197.94, 509.17, 305.91], "category_id": 1}, {"id": 8, "bbox": [498.27, 1179.26, 35.81, 39.7], "category_id": 3}, {"id": 9, "bbox": [699.14, 303.57, 475.69, 252.98], "category_id": 1}, {"id": 10, "bbox": [140.92, 393.86, 33.47, 38.92], "category_id": 3}, {"id": 11, "bbox": [1271.37, 916.94, 32.7, 38.92], "category_id": 3}, {"id": 12, "bbox": [112.11, 202.38, 171.28, 135.44], "category_id": 1}, {"id": 13, "bbox": [830.71, 0.0, 289.62, 246.75], "category_id": 1}, {"id": 14, "bbox": [63.84, 1215.84, 32.7, 41.26], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 75, 265, 88], "ImageBB": [73, 93, 411, 482]}, "reactions": [{"reactants": [12, 6, 1], "conditions": [], "products": [13]}, {"reactants": [4, 0, 2], "conditions": [], "products": [3]}], "diagram_type": "tree"}, {"id": 54, "width": 2820, "height": 2000, "file_name": "ja406383h-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1524.72, 229.66, 23.37, 31.63], "category_id": 3}, {"id": 1, "bbox": [1436.32, 4.28, 305.58, 244.38], "category_id": 1}, {"id": 2, "bbox": [127.22, 288.63, 2560.9, 1540.84], "category_id": 4}, {"id": 3, "bbox": [0.0, 1850.03, 2814.0, 119.79], "category_id": 4}, {"id": 4, "bbox": [491.08, 48.0, 274.98, 168.61], "category_id": 1}, {"id": 5, "bbox": [867.04, 75.2, 125.36, 120.52], "category_id": 1}, {"id": 6, "bbox": [1073.96, 33.91, 304.13, 82.15], "category_id": 2}, {"id": 7, "bbox": [2045.98, 215.89, 278.88, 52.85], "category_id": 2}, {"id": 8, "bbox": [1121.56, 150.49, 188.04, 78.26], "category_id": 2}, {"id": 9, "bbox": [624.66, 228.69, 22.89, 31.63], "category_id": 3}, {"id": 10, "bbox": [921.93, 230.63, 24.83, 30.66], "category_id": 3}], "reactions": [{"reactants": [4, 5], "conditions": [6, 8], "products": [1]}], "corefs": [[4, 9], [5, 10], [1, 0]], "caption": "Table 4. Iridium Catalyzed Direct Amidation of Ole\ufb01nic C\u2212H Bondsa", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 480, 110], "ImageBB": [82, 116, 787, 616]}, "diagram_type": "single"}, {"id": 1232, "width": 1216, "height": 664, "file_name": "op0102013-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1166.73, 509.07, 49.27, 36.49], "category_id": 3}, {"id": 1, "bbox": [0.0, 2.43, 438.59, 313.84], "category_id": 1}, {"id": 2, "bbox": [0.0, 331.47, 491.51, 316.27], "category_id": 1}, {"id": 3, "bbox": [675.83, 620.98, 43.79, 32.85], "category_id": 3}, {"id": 4, "bbox": [130.18, 291.33, 44.4, 36.5], "category_id": 3}, {"id": 5, "bbox": [445.28, 85.76, 172.15, 77.24], "category_id": 2}, {"id": 6, "bbox": [675.83, 297.42, 52.31, 35.88], "category_id": 3}, {"id": 7, "bbox": [538.35, 330.87, 489.08, 313.23], "category_id": 1}, {"id": 8, "bbox": [129.57, 623.42, 54.75, 34.06], "category_id": 3}, {"id": 9, "bbox": [548.08, 7.91, 490.3, 313.83], "category_id": 1}, {"id": 10, "bbox": [445.28, 445.82, 151.47, 71.16], "category_id": 2}, {"id": 11, "bbox": [1020.73, 200.71, 86.38, 35.88], "category_id": 2}, {"id": 12, "bbox": [970.85, 437.3, 191.62, 77.85], "category_id": 2}, {"id": 13, "bbox": [1005.53, 115.56, 132.0, 45.62], "category_id": 2}, {"id": 14, "bbox": [970.85, 538.27, 100.98, 38.31], "category_id": 2}], "caption": "Scheme 7. Process for 16r-Me epoxide (3b)", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 689, 67], "ImageBB": [456, 72, 760, 238]}, "reactions": [{"reactants": [1], "conditions": [5], "products": [9]}, {"reactants": [9], "conditions": [13, 11], "products": [2]}, {"reactants": [2], "conditions": [10], "products": [7]}, {"reactants": [7], "conditions": [12, 14], "products": [0]}], "diagram_type": "multiple"}, {"id": 1034, "width": 1268, "height": 1716, "file_name": "jo001614p-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [420.63, 262.68, 266.97, 197.44], "category_id": 1}, {"id": 1, "bbox": [700.47, 551.11, 54.94, 69.53], "category_id": 3}, {"id": 2, "bbox": [0.0, 1072.18, 237.78, 86.7], "category_id": 1}, {"id": 3, "bbox": [830.09, 739.97, 333.07, 189.71], "category_id": 1}, {"id": 4, "bbox": [0.0, 664.42, 363.11, 123.62], "category_id": 1}, {"id": 5, "bbox": [830.09, 265.25, 293.58, 194.87], "category_id": 1}, {"id": 6, "bbox": [0.0, 265.25, 265.25, 195.73], "category_id": 1}, {"id": 7, "bbox": [420.63, 664.42, 349.37, 123.62], "category_id": 1}, {"id": 8, "bbox": [1017.23, 48.93, 159.67, 141.64], "category_id": 1}, {"id": 9, "bbox": [1110.8, 825.81, 66.1, 72.11], "category_id": 3}, {"id": 10, "bbox": [277.27, 0.0, 234.35, 111.6], "category_id": 2}, {"id": 11, "bbox": [612.05, 196.58, 112.46, 51.51], "category_id": 3}, {"id": 12, "bbox": [783.74, 999.21, 223.19, 111.6], "category_id": 2}, {"id": 13, "bbox": [130.48, 193.15, 111.59, 57.51], "category_id": 3}, {"id": 14, "bbox": [13.73, 1416.41, 517.63, 299.59], "category_id": 1}, {"id": 15, "bbox": [529.65, 1044.71, 230.05, 145.07], "category_id": 1}, {"id": 16, "bbox": [592.31, 1194.08, 95.29, 49.78], "category_id": 3}, {"id": 17, "bbox": [420.63, 460.12, 289.28, 194.0], "category_id": 1}, {"id": 18, "bbox": [78.12, 1190.64, 103.01, 54.08], "category_id": 3}, {"id": 19, "bbox": [0.0, 463.55, 303.88, 190.57], "category_id": 1}, {"id": 20, "bbox": [73.82, 88.42, 161.39, 71.25], "category_id": 1}, {"id": 21, "bbox": [280.7, 367.41, 64.39, 64.38], "category_id": 3}, {"id": 22, "bbox": [280.7, 549.39, 63.53, 69.54], "category_id": 3}, {"id": 23, "bbox": [323.62, 139.92, 143.36, 63.53], "category_id": 2}, {"id": 24, "bbox": [1080.75, 194.01, 102.15, 54.93], "category_id": 3}, {"id": 25, "bbox": [280.7, 994.06, 220.62, 113.31], "category_id": 2}, {"id": 26, "bbox": [700.47, 367.41, 62.67, 64.38], "category_id": 3}, {"id": 27, "bbox": [783.74, 0.0, 194.86, 113.31], "category_id": 2}, {"id": 28, "bbox": [310.75, 1138.28, 145.07, 60.95], "category_id": 2}, {"id": 29, "bbox": [548.53, 1637.02, 134.77, 62.67], "category_id": 3}, {"id": 30, "bbox": [1018.95, 1044.71, 235.2, 145.07], "category_id": 1}, {"id": 31, "bbox": [18.89, 1270.48, 778.58, 71.24], "category_id": 2}, {"id": 32, "bbox": [1115.09, 359.68, 64.38, 65.24], "category_id": 3}, {"id": 33, "bbox": [1179.94, 506.73, 41.2, 53.56], "category_id": 3}, {"id": 34, "bbox": [1223.2, 648.87, 41.21, 55.62], "category_id": 3}, {"id": 35, "bbox": [704.08, 755.99, 61.8, 55.62], "category_id": 3}, {"id": 36, "bbox": [830.09, 617.21, 391.91, 120.18], "category_id": 1}, {"id": 37, "bbox": [830.09, 470.42, 354.01, 126.19], "category_id": 1}, {"id": 38, "bbox": [545.96, 47.21, 184.56, 143.36], "category_id": 1}, {"id": 39, "bbox": [280.7, 751.98, 69.54, 66.1], "category_id": 3}, {"id": 40, "bbox": [1085.04, 1194.08, 94.43, 50.64], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 385, 636, 399], "ImageBB": [449, 405, 766, 834]}, "reactions": [{"reactants": [20], "conditions": [10, 23], "products": [38]}, {"reactants": [38], "conditions": [27], "products": [8]}, {"reactants": [2], "conditions": [25, 28], "products": [15]}, {"reactants": [15], "conditions": [12], "products": [30]}], "diagram_type": "multiple"}, {"id": 477, "width": 1352, "height": 3832, "file_name": "ol0703579-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.0, 256.0, 66.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [12.0, 333.0, 665.0, 1164.0], "category_id": 4}, {"id": 2, "bbox": [604.0, 174.0, 262.0, 94.0], "category_id": 2}, {"id": 3, "bbox": [599.0, 106.0, 296.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [416.0, 247.0, 112.0, 60.0], "category_id": 3}, {"id": 5, "bbox": [66.0, 62.0, 209.0, 191.0], "category_id": 1}, {"id": 6, "bbox": [339.0, 82.0, 256.0, 186.0], "category_id": 1}, {"id": 7, "bbox": [995.0, 254.0, 118.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [680.0, 328.0, 668.0, 1169.0], "category_id": 4}, {"id": 9, "bbox": [920.3, 0.0, 336.6, 303.5], "category_id": 1}], "reactions": [{"reactants": [5, 6], "conditions": [3, 2], "products": [9]}], "corefs": [[5, 0], [6, 4], [9, 7]], "caption": "Table 3. Variation of the Indole Substrate", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 665, 89], "ImageBB": [439, 93, 777, 1051]}, "diagram_type": "single"}, {"id": 448, "width": 2808, "height": 428, "file_name": "op2001047-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1598.7, 8.5, 253.2, 133.9], "category_id": 1}, {"id": 1, "bbox": [1312.0, 117.4, 195.0, 93.1], "category_id": 2}, {"id": 2, "bbox": [957.7, 8.1, 248.8, 134.3], "category_id": 1}, {"id": 3, "bbox": [1676.0, 171.0, 108.5, 57.0], "category_id": 3}, {"id": 4, "bbox": [6.0, 258.0, 2799.0, 170.0], "category_id": 4}, {"id": 5, "bbox": [1044.0, 177.0, 96.0, 54.0], "category_id": 3}, {"id": 6, "bbox": [1336.0, 0.0, 174.0, 99.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [6, 1], "products": [0]}], "corefs": [[2, 5], [0, 3]], "caption": "Table 7. Optimized reaction conditions for the \ufb02ow hydrogenation of 4-aryl-3-buten-2-ones 1a ca", "pdf": {"Page": 8, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 617, 109], "ImageBB": [71, 117, 773, 224]}, "diagram_type": "single"}, {"id": 191, "width": 1352, "height": 640, "file_name": "op0601316-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [531.0, 380.0, 238.0, 59.9], "category_id": 2}, {"id": 1, "bbox": [811.2, 0.0, 347.8, 209.9], "category_id": 1}, {"id": 2, "bbox": [867.0, 216.0, 236.3, 100.0], "category_id": 2}, {"id": 3, "bbox": [220.2, 10.0, 213.5, 192.8], "category_id": 1}, {"id": 4, "bbox": [898.2, 334.1, 256.3, 190.8], "category_id": 1}, {"id": 5, "bbox": [361.2, 358.0, 127.5, 131.7], "category_id": 1}, {"id": 6, "bbox": [28.2, 333.2, 214.5, 193.7], "category_id": 1}, {"id": 7, "bbox": [193.73, 213.91, 267.13, 62.2], "category_id": 2}, {"id": 8, "bbox": [137.0, 86.0, 41.0, 54.0], "category_id": 3}, {"id": 9, "bbox": [2.0, 539.0, 272.0, 63.0], "category_id": 2}, {"id": 10, "bbox": [301.0, 545.0, 265.0, 53.0], "category_id": 2}, {"id": 11, "bbox": [696.0, 539.0, 656.0, 101.0], "category_id": 2}, {"id": 12, "bbox": [526.0, 57.0, 241.0, 65.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [12], "products": [1]}, {"reactants": [6, 5], "conditions": [0], "products": [4]}], "corefs": [[3, 7], [1, 2], [6, 9], [5, 10], [4, 11]], "caption": "Figure 1. BAL-catalyzed carboligation.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 410, 661, 424], "ImageBB": [439, 247, 777, 407]}, "diagram_type": "multiple"}, {"id": 61, "width": 1340, "height": 800, "file_name": "ja312277g-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.12, 201.46, 43.4, 38.0], "category_id": 3}, {"id": 1, "bbox": [2.92, 570.46, 273.8, 119.0], "category_id": 1}, {"id": 2, "bbox": [1073.92, 282.46, 228.78, 189.2], "category_id": 1}, {"id": 3, "bbox": [766.12, 282.46, 228.8, 187.4], "category_id": 1}, {"id": 4, "bbox": [503.32, 280.66, 189.2, 174.8], "category_id": 1}, {"id": 5, "bbox": [28.12, 280.66, 192.8, 173.0], "category_id": 1}, {"id": 6, "bbox": [1100.92, 5.26, 234.2, 180.2], "category_id": 1}, {"id": 7, "bbox": [798.52, 7.06, 234.2, 180.2], "category_id": 1}, {"id": 8, "bbox": [499.72, 52.06, 261.2, 135.2], "category_id": 1}, {"id": 9, "bbox": [4.72, 34.06, 234.2, 144.2], "category_id": 1}, {"id": 10, "bbox": [514.12, 577.66, 273.8, 115.4], "category_id": 1}, {"id": 11, "bbox": [931.72, 575.86, 290.0, 128.04], "category_id": 1}, {"id": 12, "bbox": [272.92, 53.86, 137.0, 83.0], "category_id": 2}, {"id": 13, "bbox": [258.52, 174.46, 196.4, 36.2], "category_id": 2}, {"id": 14, "bbox": [272.92, 293.3, 137.0, 77.56], "category_id": 2}, {"id": 15, "bbox": [253.12, 410.26, 200.0, 38.0], "category_id": 2}, {"id": 16, "bbox": [307.12, 590.26, 63.2, 34.4], "category_id": 2}, {"id": 17, "bbox": [258.52, 698.26, 209.0, 90.2], "category_id": 2}, {"id": 18, "bbox": [89.32, 475.06, 44.68, 34.64], "category_id": 3}, {"id": 19, "bbox": [537.52, 203.26, 143.88, 41.24], "category_id": 3}, {"id": 20, "bbox": [527.38, 478.21, 144.92, 39.19], "category_id": 3}, {"id": 21, "bbox": [834.67, 477.17, 144.93, 39.33], "category_id": 3}, {"id": 22, "bbox": [1132.58, 478.21, 143.92, 39.29], "category_id": 3}, {"id": 23, "bbox": [963.76, 704.72, 144.36, 87.31], "category_id": 3}, {"id": 24, "bbox": [101.61, 704.72, 43.09, 33.07], "category_id": 3}, {"id": 25, "bbox": [1131.18, 204.57, 145.36, 41.09], "category_id": 3}, {"id": 26, "bbox": [853.49, 203.46, 135.33, 41.1], "category_id": 3}, {"id": 27, "bbox": [526.67, 704.72, 143.36, 87.31], "category_id": 3}], "reactions": [{"reactants": [9], "conditions": [12, 13], "products": [8, 7, 6]}, {"reactants": [5], "conditions": [14, 15], "products": [4, 3, 2]}, {"reactants": [1], "conditions": [16, 17], "products": [10, 11]}], "corefs": [[9, 0], [8, 19], [7, 26], [6, 25], [5, 18], [4, 20], [3, 21], [2, 22], [1, 24], [10, 27], [11, 23]], "caption": "Table 4. Sequential C(sp3)\u2212H Methylation", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 696, 325, 715], "ImageBB": [83, 720, 418, 920]}, "diagram_type": "multiple"}, {"id": 65, "width": 1352, "height": 1188, "file_name": "ja307151x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [290.33, 355.29, 218.56, 82.44], "category_id": 2}, {"id": 1, "bbox": [896.7, 271.76, 351.59, 42.22], "category_id": 3}, {"id": 2, "bbox": [103.15, 1014.26, 198.46, 40.68], "category_id": 3}, {"id": 3, "bbox": [970.95, 1014.26, 299.0, 42.22], "category_id": 3}, {"id": 4, "bbox": [359.94, 1103.98, 563.51, 79.35], "category_id": 3}, {"id": 5, "bbox": [579.59, 607.44, 264.97, 40.67], "category_id": 3}, {"id": 6, "bbox": [214.53, 271.76, 170.61, 42.22], "category_id": 3}, {"id": 7, "bbox": [745.11, 692.51, 204.64, 80.89], "category_id": 2}, {"id": 8, "bbox": [78.4, 5.7, 453.69, 234.03], "category_id": 1}, {"id": 9, "bbox": [854.94, 8.79, 424.29, 249.5], "category_id": 1}, {"id": 10, "bbox": [513.08, 353.75, 398.0, 234.03], "category_id": 1}, {"id": 11, "bbox": [8.79, 757.48, 394.91, 235.58], "category_id": 1}, {"id": 12, "bbox": [448.11, 760.58, 401.09, 334.57], "category_id": 1}, {"id": 13, "bbox": [893.61, 755.94, 430.48, 235.57], "category_id": 1}, {"id": 14, "bbox": [590.42, 78.4, 223.2, 40.7], "category_id": 2}, {"id": 15, "bbox": [605.89, 144.92, 176.8, 80.89], "category_id": 2}, {"id": 16, "bbox": [1001.89, 579.59, 173.7, 79.35], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [14, 15], "products": [9]}, {"reactants": [8], "conditions": [0], "products": [10]}, {"reactants": [10], "conditions": [7], "products": [12]}, {"reactants": [10], "conditions": [16], "products": [13]}], "corefs": [[8, 6], [9, 1], [10, 5], [11, 2], [12, 4], [13, 3]], "caption": "Figure 1. Formations of monodictyphenone (2) and related xanthones 3\u22126 proceed by a deoxygenation reaction and BV oxidation.2\u22125,7 Chrysophanol (7) has been shown to be a precursor of 4\u22126.4c,d,5d,7 Each deoxygenation site is highlighted by a circle. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 640, 784, 695], "ImageBB": [448, 333, 786, 630]}, "diagram_type": "tree"}, {"id": 865, "width": 1356, "height": 1376, "file_name": "jo2001534-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [146.0, 415.0, 211.0, 120.0], "category_id": 3}, {"id": 1, "bbox": [562.0, 228.0, 218.0, 112.0], "category_id": 3}, {"id": 2, "bbox": [8.0, 1008.0, 1347.0, 368.0], "category_id": 4}, {"id": 3, "bbox": [1000.0, 424.9, 198.2, 101.2], "category_id": 3}, {"id": 4, "bbox": [38.1, 803.5, 192.5, 96.0], "category_id": 3}, {"id": 5, "bbox": [616.2, 392.0, 57.0, 174.0], "category_id": 2}, {"id": 6, "bbox": [1088.0, 600.1, 264.5, 174.0], "category_id": 1}, {"id": 7, "bbox": [513.1, 606.8, 334.1, 231.4], "category_id": 1}, {"id": 8, "bbox": [882.0, 671.0, 178.9, 43.6], "category_id": 2}, {"id": 9, "bbox": [582.7, 854.2, 178.1, 101.7], "category_id": 3}, {"id": 10, "bbox": [1129.6, 799.9, 188.6, 100.5], "category_id": 3}, {"id": 11, "bbox": [789.0, 421.3, 149.2, 164.1], "category_id": 2}, {"id": 12, "bbox": [298.5, 683.4, 164.8, 47.9], "category_id": 2}, {"id": 13, "bbox": [407.2, 416.1, 147.3, 158.4], "category_id": 2}, {"id": 14, "bbox": [957.3, 234.8, 279.7, 188.0], "category_id": 1}, {"id": 15, "bbox": [551.5, 1.8, 237.6, 207.1], "category_id": 1}, {"id": 16, "bbox": [5.3, 594.8, 257.5, 183.0], "category_id": 1}, {"id": 17, "bbox": [125.7, 208.5, 256.3, 203.5], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [12], "products": [16]}, {"reactants": [7], "conditions": [8], "products": [6]}, {"reactants": [7], "conditions": [13], "products": [17]}, {"reactants": [7], "conditions": [5], "products": [15]}, {"reactants": [7], "conditions": [11], "products": [14]}], "corefs": [[7, 9], [16, 4], [6, 10], [17, 0], [15, 1], [14, 3]], "caption": "Table 6. Comparison of 5-Exo-Trig, 5-Endo-Trig, 6-Exo-Trig, 6-Endo-Trig, and 7-Endo-Trig Ring-Forming Reactions of Anion 1a- and 1d-. (Activation Barriers (Erel TS) and Reaction Energies (Erel Cycle) with Regard to the Global Minimum Structures of the Open-Chain Form (Erel = 0.0 kcal/mol)): SCS-MP2/6-311\u00feG(d,p)//B3LYP/6-31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 366, 771, 487], "ImageBB": [436, 498, 775, 842]}, "diagram_type": "tree"}, {"id": 1209, "width": 1348, "height": 956, "file_name": "ol800523j-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [758.63, 254.32, 542.17, 116.71], "category_id": 1}, {"id": 1, "bbox": [794.37, 2.7, 374.93, 51.94], "category_id": 2}, {"id": 2, "bbox": [720.19, 665.15, 540.82, 124.13], "category_id": 1}, {"id": 3, "bbox": [957.56, 372.38, 205.67, 52.62], "category_id": 3}, {"id": 4, "bbox": [493.61, 107.26, 211.07, 53.29], "category_id": 3}, {"id": 5, "bbox": [294.01, 372.38, 133.52, 51.27], "category_id": 3}, {"id": 6, "bbox": [124.08, 111.31, 69.45, 53.29], "category_id": 3}, {"id": 7, "bbox": [128.12, 840.55, 384.38, 55.99], "category_id": 3}, {"id": 8, "bbox": [722.22, 840.55, 528.68, 55.99], "category_id": 3}, {"id": 9, "bbox": [38.44, 32.38, 238.71, 89.72], "category_id": 1}, {"id": 10, "bbox": [38.44, 431.74, 475.4, 400.04], "category_id": 1}, {"id": 11, "bbox": [621.06, 437.14, 389.1, 156.5], "category_id": 2}, {"id": 12, "bbox": [441.02, 24.96, 323.68, 74.88], "category_id": 1}, {"id": 13, "bbox": [61.36, 263.09, 541.5, 111.99], "category_id": 1}, {"id": 14, "bbox": [848.99, 99.84, 296.71, 87.02], "category_id": 2}], "caption": "Scheme 3. Trapping of Isomerization Intermediate", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [462, 242, 723, 257], "ImageBB": [425, 264, 762, 503]}, "reactions": [{"reactants": [9, 12], "conditions": [1, 14], "products": [13, 0]}, {"reactants": [13, 0], "conditions": [11], "products": [10, 2]}], "diagram_type": "tree"}, {"id": 178, "width": 1300, "height": 660, "file_name": "op0602270-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 5.9, 342.2, 219.1], "category_id": 1}, {"id": 1, "bbox": [936.6, 2.0, 344.8, 224.3], "category_id": 1}, {"id": 2, "bbox": [430.0, 366.7, 415.5, 59.5], "category_id": 2}, {"id": 3, "bbox": [367.1, 482.8, 570.3, 61.7], "category_id": 2}, {"id": 4, "bbox": [1064.1, 597.9, 118.9, 51.1], "category_id": 3}, {"id": 5, "bbox": [127.88, 226.96, 88.0, 55.0], "category_id": 3}, {"id": 6, "bbox": [1068.94, 242.02, 126.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [413.6, 23.6, 412.8, 55.9], "category_id": 2}, {"id": 8, "bbox": [374.0, 141.6, 524.3, 57.8], "category_id": 2}, {"id": 9, "bbox": [276.06, 600.02, 79.0, 55.0], "category_id": 3}, {"id": 10, "bbox": [961.0, 352.0, 339.0, 223.0], "category_id": 1}, {"id": 11, "bbox": [15.0, 344.0, 233.0, 316.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [7, 8], "products": [1]}, {"reactants": [11], "conditions": [2, 3], "products": [10]}], "corefs": [[0, 5], [1, 6], [11, 9], [10, 4]], "caption": "Table 1. Hydrogenation of E-7 and Z-7 with different 4,5-dihydro-3H-dinaphtho[2,1-c;1\u2032,2\u2032-e]phosphepines (6a-6i) ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 403, 81], "ImageBB": [80, 89, 405, 254]}, "diagram_type": "multiple"}, {"id": 1116, "width": 1328, "height": 1696, "file_name": "jo982024i-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [289.25, 172.23, 112.81, 50.91], "category_id": 2}, {"id": 1, "bbox": [609.03, 319.86, 27.14, 45.81], "category_id": 3}, {"id": 2, "bbox": [290.1, 104.36, 142.5, 49.2], "category_id": 2}, {"id": 3, "bbox": [343.53, 424.21, 354.57, 400.46], "category_id": 1}, {"id": 4, "bbox": [413.94, 850.12, 309.6, 367.37], "category_id": 1}, {"id": 5, "bbox": [982.25, 426.76, 326.57, 318.16], "category_id": 1}, {"id": 6, "bbox": [1056.05, 1604.37, 189.16, 86.54], "category_id": 3}, {"id": 7, "bbox": [609.03, 1204.76, 61.92, 48.36], "category_id": 3}, {"id": 8, "bbox": [536.93, 784.79, 41.56, 45.82], "category_id": 3}, {"id": 9, "bbox": [701.49, 96.72, 336.75, 61.09], "category_id": 2}, {"id": 10, "bbox": [966.99, 0.0, 359.65, 404.7], "category_id": 1}, {"id": 11, "bbox": [782.07, 1024.05, 221.39, 50.9], "category_id": 2}, {"id": 12, "bbox": [719.3, 605.77, 271.44, 55.15], "category_id": 2}, {"id": 13, "bbox": [982.25, 853.51, 326.57, 315.62], "category_id": 1}, {"id": 14, "bbox": [0.0, 60.24, 305.36, 263.86], "category_id": 1}, {"id": 15, "bbox": [1182.44, 313.92, 46.65, 48.36], "category_id": 3}, {"id": 16, "bbox": [117.06, 1463.53, 122.14, 56.85], "category_id": 2}, {"id": 17, "bbox": [656.53, 1467.77, 310.46, 107.75], "category_id": 2}, {"id": 18, "bbox": [186.61, 315.61, 40.72, 48.36], "category_id": 3}, {"id": 19, "bbox": [58.53, 1016.41, 349.47, 56.0], "category_id": 2}, {"id": 20, "bbox": [27.99, 598.99, 357.96, 61.93], "category_id": 2}, {"id": 21, "bbox": [782.07, 960.42, 189.16, 55.14], "category_id": 2}, {"id": 22, "bbox": [454.65, 1616.25, 61.92, 40.72], "category_id": 3}, {"id": 23, "bbox": [965.29, 1287.06, 329.96, 312.22], "category_id": 1}, {"id": 24, "bbox": [743.9, 527.72, 195.09, 64.48], "category_id": 2}, {"id": 25, "bbox": [1049.26, 1164.04, 184.92, 103.51], "category_id": 3}, {"id": 26, "bbox": [1115.43, 790.73, 43.26, 43.27], "category_id": 3}, {"id": 27, "bbox": [59.38, 1395.66, 256.16, 52.6], "category_id": 2}, {"id": 28, "bbox": [363.04, 0.0, 349.48, 404.7], "category_id": 1}, {"id": 29, "bbox": [295.18, 1275.18, 343.54, 313.07], "category_id": 1}, {"id": 30, "bbox": [89.06, 948.54, 234.96, 62.78], "category_id": 2}, {"id": 31, "bbox": [27.99, 525.17, 306.21, 60.24], "category_id": 2}, {"id": 32, "bbox": [658.23, 1399.9, 324.02, 51.75], "category_id": 2}, {"id": 33, "bbox": [702.78, 173.01, 293.19, 118.09], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [77, 86, 409, 510]}, "reactions": [{"reactants": [14], "conditions": [2, 0], "products": [28]}, {"reactants": [28], "conditions": [9, 33], "products": [10]}, {"reactants": [10], "conditions": [31, 20], "products": [3]}, {"reactants": [3], "conditions": [24, 12], "products": [5]}, {"reactants": [5], "conditions": [30, 19], "products": [4]}, {"reactants": [4], "conditions": [21, 11], "products": [13]}, {"reactants": [13], "conditions": [27, 16], "products": [29]}, {"reactants": [29], "conditions": [32, 17], "products": [23]}], "diagram_type": "multiple"}, {"id": 210, "width": 1352, "height": 1144, "file_name": "op0340816-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1024.17, 961.5, 253.6, 178.6], "category_id": 1}, {"id": 1, "bbox": [787.57, 597.87, 38.56, 51.0], "category_id": 3}, {"id": 2, "bbox": [1305.53, 166.13, 44.0, 50.3], "category_id": 3}, {"id": 3, "bbox": [826.87, 173.07, 50.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [492.0, 955.9, 225.0, 182.1], "category_id": 1}, {"id": 5, "bbox": [1031.5, 434.3, 251.4, 246.0], "category_id": 1}, {"id": 6, "bbox": [501.7, 431.1, 281.1, 202.5], "category_id": 1}, {"id": 7, "bbox": [494.2, 11.0, 328.8, 197.7], "category_id": 1}, {"id": 8, "bbox": [626.33, 292.2, 63.57, 51.3], "category_id": 2}, {"id": 9, "bbox": [1182.93, 300.13, 67.47, 48.17], "category_id": 2}, {"id": 10, "bbox": [258.0, 143.0, 137.8, 55.7], "category_id": 2}, {"id": 11, "bbox": [291.1, 33.3, 90.9, 50.7], "category_id": 2}, {"id": 12, "bbox": [6.0, 8.0, 252.0, 177.0], "category_id": 1}, {"id": 13, "bbox": [1044.6, 14.0, 261.4, 235.0], "category_id": 1}, {"id": 14, "bbox": [1276.87, 602.4, 40.93, 45.0], "category_id": 3}, {"id": 15, "bbox": [721.4, 1078.53, 33.7, 45.8], "category_id": 3}, {"id": 16, "bbox": [1244.87, 1086.03, 38.13, 47.3], "category_id": 3}], "reactions": [{"reactants": [12], "conditions": [11, 10], "products": [7, 13]}, {"reactants": [7], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [], "products": [4]}, {"reactants": [13], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [], "products": [0]}], "corefs": [[7, 3], [13, 2], [6, 1], [5, 14], [4, 15], [0, 16]], "caption": "Figure 2. Production of 1,3-dichloro-2-fluorobenzene from 2,3,4-trichloro-1-benzenesulfonyl chloride. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 529, 409, 557], "ImageBB": [74, 240, 412, 526]}, "diagram_type": "tree"}, {"id": 286, "width": 1352, "height": 1152, "file_name": "ol800086s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [11.0, 294.0, 1341.0, 858.0], "category_id": 4}, {"id": 1, "bbox": [230.0, 242.0, 48.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [93.0, 0.0, 217.0, 231.0], "category_id": 1}, {"id": 3, "bbox": [15.0, 50.0, 53.0, 137.0], "category_id": 1}, {"id": 4, "bbox": [1092.0, 4.0, 240.0, 231.0], "category_id": 1}, {"id": 5, "bbox": [19.0, 231.0, 190.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [442.0, 21.0, 253.5, 96.1], "category_id": 2}, {"id": 7, "bbox": [890.0, 237.97, 103.0, 49.0], "category_id": 3}, {"id": 8, "bbox": [1157.0, 240.0, 101.1, 49.0], "category_id": 3}, {"id": 9, "bbox": [804.3, 4.0, 245.7, 227.5], "category_id": 1}, {"id": 10, "bbox": [400.0, 122.9, 334.0, 93.1], "category_id": 2}], "reactions": [{"reactants": [3, 2], "conditions": [6, 10], "products": [9, 4]}], "corefs": [[3, 5], [2, 1], [9, 7], [4, 8]], "caption": "Table 1. Alkyne Scope", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 588, 569, 601], "ImageBB": [439, 601, 777, 889]}, "diagram_type": "single"}, {"id": 458, "width": 1356, "height": 796, "file_name": "op200038y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [658.0, 219.0, 43.0, 32.0], "category_id": 3}, {"id": 1, "bbox": [929.0, 219.0, 46.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [4.0, 56.0, 245.0, 125.0], "category_id": 1}, {"id": 3, "bbox": [513.0, 8.0, 298.0, 199.0], "category_id": 1}, {"id": 4, "bbox": [265.0, 92.0, 238.0, 52.0], "category_id": 2}, {"id": 5, "bbox": [1099.0, 54.7, 253.0, 122.4], "category_id": 1}, {"id": 6, "bbox": [90.0, 217.0, 49.0, 37.0], "category_id": 3}, {"id": 7, "bbox": [823.0, 57.5, 239.0, 122.5], "category_id": 1}, {"id": 8, "bbox": [1133.0, 210.0, 206.0, 91.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4], "products": [3, 7]}], "corefs": [[2, 6], [3, 0], [7, 1], [5, 8]], "caption": "Table 2. Selective hydrolysis of diester 3c with various bases", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 247, 405, 262], "ImageBB": [71, 272, 410, 471]}, "diagram_type": "single"}, {"id": 502, "width": 1352, "height": 960, "file_name": "ol052245s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [493.0, 270.0, 188.0, 91.0], "category_id": 2}, {"id": 1, "bbox": [623.0, 382.0, 361.0, 190.0], "category_id": 1}, {"id": 2, "bbox": [427.0, 616.0, 152.0, 33.0], "category_id": 2}, {"id": 3, "bbox": [702.0, 608.0, 150.0, 50.0], "category_id": 2}, {"id": 4, "bbox": [277.0, 323.0, 94.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [495.14, 168.29, 175.0, 78.0], "category_id": 2}, {"id": 6, "bbox": [221.2, 384.9, 306.3, 183.4], "category_id": 1}, {"id": 7, "bbox": [29.7, 184.7, 386.0, 131.3], "category_id": 1}, {"id": 8, "bbox": [727.86, 567.0, 94.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [457.0, 565.0, 94.1, 45.0], "category_id": 3}, {"id": 10, "bbox": [168.9, 677.3, 430.8, 110.8], "category_id": 4}, {"id": 11, "bbox": [1089.0, 567.0, 217.0, 41.9], "category_id": 3}, {"id": 12, "bbox": [1008.0, 386.0, 327.0, 185.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 0], "products": [6, 1, 12]}], "corefs": [[7, 4], [6, 9], [1, 8], [12, 11]], "caption": "Table 1. Platinum-Catalyzed Hydrosilylation of Para- and Ortho-Substituted Alkynes 1a,b with Triethylsilanea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 296, 746, 324], "ImageBB": [439, 51, 777, 291]}, "diagram_type": "multiple"}, {"id": 564, "width": 1348, "height": 920, "file_name": "acs.orglett.5b01692-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [547.0, 591.0, 232.0, 97.0], "category_id": 3}, {"id": 1, "bbox": [26.0, 353.7, 346.0, 217.3], "category_id": 1}, {"id": 2, "bbox": [748.99, 77.67, 216.0, 83.0], "category_id": 2}, {"id": 3, "bbox": [951.3, 385.3, 360.7, 269.7], "category_id": 1}, {"id": 4, "bbox": [521.7, 371.3, 292.3, 198.7], "category_id": 1}, {"id": 5, "bbox": [1057.0, 6.67, 269.34, 269.0], "category_id": 1}, {"id": 6, "bbox": [397.7, 36.7, 248.97, 236.31], "category_id": 1}, {"id": 7, "bbox": [34.01, 66.01, 280.99, 178.69], "category_id": 1}, {"id": 8, "bbox": [515.32, 284.0, 60.0, 44.0], "category_id": 3}, {"id": 9, "bbox": [121.99, 279.66, 67.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [32.0, 597.0, 322.0, 233.0], "category_id": 3}, {"id": 11, "bbox": [1096.0, 599.0, 38.0, 47.0], "category_id": 3}, {"id": 12, "bbox": [9.0, 851.0, 1339.0, 69.0], "category_id": 4}, {"id": 13, "bbox": [739.0, 184.0, 245.0, 76.0], "category_id": 2}, {"id": 14, "bbox": [1158.0, 281.0, 83.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [7, 6], "conditions": [2, 13], "products": [5]}], "corefs": [[7, 9], [6, 8], [5, 14], [1, 10], [4, 0], [3, 11]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 362, 366, 383], "ImageBB": [82, 389, 419, 619]}, "diagram_type": "single"}, {"id": 51, "width": 1352, "height": 2500, "file_name": "ja407689a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [551.83, 4.07, 258.46, 95.26], "category_id": 2}, {"id": 1, "bbox": [403.92, 209.53, 50.09, 39.89], "category_id": 3}, {"id": 2, "bbox": [355.83, 37.58, 123.68, 153.55], "category_id": 1}, {"id": 3, "bbox": [144.54, 42.68, 79.23, 125.86], "category_id": 1}, {"id": 4, "bbox": [3.73, 292.57, 1345.98, 2201.25], "category_id": 4}, {"id": 5, "bbox": [890.62, 18.64, 318.21, 205.28], "category_id": 1}, {"id": 6, "bbox": [554.01, 135.94, 254.1, 131.69], "category_id": 2}, {"id": 7, "bbox": [160.57, 178.93, 50.81, 41.34], "category_id": 3}, {"id": 8, "bbox": [980.24, 197.87, 52.27, 41.35], "category_id": 3}], "reactions": [{"reactants": [3, 2], "conditions": [0, 6], "products": [5]}], "corefs": [[3, 7], [2, 1], [5, 8]], "caption": "Table 1. 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Oxazaborolidine bound to a polystyrene.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 541, 358, 555], "ImageBB": [105, 54, 380, 538]}, "diagram_type": "tree"}, {"id": 1309, "width": 1352, "height": 1248, "file_name": "op300170q-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1193.74, 630.58, 65.6, 56.16], "category_id": 3}, {"id": 1, "bbox": [1113.93, 418.81, 203.58, 192.83], "category_id": 1}, {"id": 2, "bbox": [528.9, 77.13, 139.32, 172.53], "category_id": 1}, {"id": 3, "bbox": [447.74, 849.8, 328.7, 74.42], "category_id": 2}, {"id": 4, "bbox": [973.25, 391.75, 67.63, 54.12], "category_id": 3}, {"id": 5, "bbox": [185.32, 1083.22, 42.61, 56.16], "category_id": 3}, {"id": 6, "bbox": [835.95, 713.8, 378.08, 462.12], "category_id": 1}, {"id": 7, "bbox": [121.74, 382.95, 72.37, 59.54], "category_id": 3}, {"id": 8, "bbox": [986.78, 1107.58, 64.25, 59.54], "category_id": 3}, {"id": 9, "bbox": [47.34, 77.13, 267.16, 329.5], "category_id": 1}, {"id": 10, "bbox": [33.14, 748.99, 365.9, 338.97], "category_id": 1}, {"id": 11, "bbox": [432.86, 151.56, 51.4, 76.45], "category_id": 2}, {"id": 12, "bbox": [808.22, 0.0, 372.67, 442.49], "category_id": 1}], "caption": "Scheme 2. Access to Key Intermediate 7 from Acetophenone 12 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 422, 417, 452], "ImageBB": [82, 461, 420, 773]}, "reactions": [{"reactants": [9, 11, 2], "conditions": [], "products": [12]}, {"reactants": [12, 1], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [3], "products": [10]}], "diagram_type": "tree"}], "roles": [{"id": 1, "name": "reactants"}, {"id": 2, "name": "conditions"}, {"id": 3, "name": "products"}]}